WO2014148436A1 - Procédé pour fabriquer un aliment utilisant du chocolat ayant une haute tolérance à la chaleur - Google Patents

Procédé pour fabriquer un aliment utilisant du chocolat ayant une haute tolérance à la chaleur Download PDF

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Publication number
WO2014148436A1
WO2014148436A1 PCT/JP2014/057148 JP2014057148W WO2014148436A1 WO 2014148436 A1 WO2014148436 A1 WO 2014148436A1 JP 2014057148 W JP2014057148 W JP 2014057148W WO 2014148436 A1 WO2014148436 A1 WO 2014148436A1
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Prior art keywords
chocolate
dough
food
chocolates
heat resistance
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PCT/JP2014/057148
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English (en)
Japanese (ja)
Inventor
安史 金田
信宏 大坪
和季 森川
ノフィアント トリ
フランシスカ クララ
Original Assignee
不二製油株式会社
ピーティー フレイアバディ インドタマ
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Application filed by 不二製油株式会社, ピーティー フレイアバディ インドタマ filed Critical 不二製油株式会社
Priority to JP2015506769A priority Critical patent/JPWO2014148436A1/ja
Publication of WO2014148436A1 publication Critical patent/WO2014148436A1/fr

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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/32—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds
    • A23G1/40—Cocoa products, e.g. chocolate; Substitutes therefor characterised by the composition containing organic or inorganic compounds characterised by the carbohydrates used, e.g. polysaccharides
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00—Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor
    • A23G1/30—Cocoa products, e.g. chocolate; Substitutes therefor

Definitions

  • the present invention relates to a method for producing a chocolate-based food having excellent heat resistance.
  • Chocolate and chocolates are made by dispersing fine particles such as cocoa solids, milk powder, and sugars, which are other raw materials, in the continuous phase of fats and oils.
  • the typical fats and oils used in chocolate is cocoa butter, and its melting point is around 33 ° C, so it melts rapidly around body temperature and shows excellent mouth melting, while when it exceeds 35 ° C, the fats and oils are almost melted. The heat resistance is lost, and as a result, problems such as stickiness of the surface, adhesion to each other, and loss of shape retention occur.
  • various fats and oils having a melting point of 34 to 42 ° C. such as cocoa butter improved fats and cocoa butter substitute fats and oils are used as fats and oils to replace cocoa butter.
  • the heat resistance of the foods there is a limit of about 38 ° C., and there is a problem that the melting of the chocolate using the fats and oils having a melting point equal to or higher than the body temperature is drastically lowered and the taste becomes low.
  • Patent Document 1 a part or the whole of sugar is replaced with one or more alternative sugars such as crystalline glucose, fructose, crystalline sorbitol, powdered syrup, powdered hydrogenated syrup, etc., and a chocolate dough is prepared after molding.
  • This is a method of solidifying by heating for several seconds to several tens of minutes above a temperature of 0 ° C., and relates to an oily confectionery that does not become sticky even at 40 to 90 ° C. above the melting point of the fat.
  • Patent Document 2 is a method for producing a heat-resistant confectionery that absorbs moisture from a fat and sugar and has a moisture content of 3% or less as a main component, and then bakes it.
  • the present invention relates to a confectionery excellent in heat resistance that does not adhere to each other and does not impair the original texture of the oily confectionery dough.
  • Patent Document 3 is a method for producing a composite confectionery having improved heat resistance by placing or depositing chocolate on a hydrous food material and baking it. In this method, instead of the method of absorbing the surface of the oily confectionery dough of Patent Document 2, moisture transfer from the water-containing food material to the chocolate dough and / or chocolate is used to heat-resistant the chocolate after baking. It is a method of giving.
  • JP-A-52-148662 Japanese Patent No. 4126838 JP 2001-333697 A
  • Patent Document 1 is a method that can surely impart heat resistance, but in addition to the problem that it is hard and has a rough texture and the smooth texture and mouthfeel of the original chocolate cannot be obtained, ordinary chocolate It was necessary to add a heat-solidifying step that is not in the manufacturing process. Also, when preparing a chocolate dough by replacing some or all of the sugar with alternative sugars, refiners such as rolls are not easily pulverized and difficult to atomize, causing a rough texture or chocolate dough. In this conching step, there was a problem of generation of lumps (coarse particles) due to aggregation and an increase in the viscosity of the dough, and this was not a practical method.
  • Patent Document 2 requires a complicated process of spraying or applying water containing sugar or sugar on the chocolate surface after molding the chocolate to absorb moisture on the chocolate surface.
  • a baking process is essential after moisture absorption, and depending on the degree of moisture absorption and baking, the chocolate surface has a hard texture and the original soft texture of chocolate cannot be obtained.
  • Patent Document 3 uses the moisture transfer from the water-containing food material to the chocolate dough and / or chocolates, so that the trouble of absorbing moisture into the chocolate can be omitted, but the chocolate is still placed on the water-containing food material. There was a problem that the process of baking afterwards was indispensable and a problem that the original flavor and texture of chocolate were slightly lowered by baking.
  • a heat treatment step and a baking step are indispensable for imparting heat resistance, and ordinary chocolate-based composite confectionery, for example, coating chocolate and baked confectionery
  • ordinary chocolate-based composite confectionery for example, coating chocolate and baked confectionery
  • the heat treatment step and the baking step there are problems that the surface of the chocolate becomes hard, the chocolate is hard and has a rough texture, and the chocolate flavor is lowered.
  • the present inventors cool or solidify a chocolate dough containing a specific amount of milk powder, glucose and lecithin on a food or food material having a water activity of 0.4 to 0.95 or after placing it. Therefore, the chocolate dough has heat resistance exceeding the melting point of fats and oils, for example, 35 to 90 ° C. without heat treatment or baking, and the chocolate has a soft and smooth texture from the chocolate surface to the inside of the chocolate.
  • the inventors have found that it is possible to produce chocolates having excellent meltability and flavor, and previously filed a Japanese Patent Application No. 2012-274388.
  • the invention according to this application relates to chocolate containing 3 to 35% by weight of milk powder, but in both bitter chocolates of less than 3% by weight of milk powder, both heat resistance and excellent texture, mouth melt and flavor are compatible.
  • the manufacturing method of the heat-resistant chocolates to be left was left as a subject.
  • the object of the present invention is to make chocolates, particularly chocolates containing less than 3% by weight of milk powder, without requiring a heat treatment step and a baking step for imparting heat resistance, and to reduce the melting point of fats and oils in chocolates.
  • An object of the present invention is to provide a chocolate having heat resistance in a temperature range exceeding 35 ° C., for example, 35 to 90 ° C., and exhibiting the chocolate's original smooth texture, melted mouth and flavor from the chocolate surface to the inside of the chocolate, and a method for producing the chocolate.
  • the present inventors have coated a chocolate dough containing a specific amount of a specific saccharide and lecithin on a food or a food material having a water activity of 0.4 to 0.95.
  • the chocolate dough has heat resistance exceeding the melting point of fats and oils, for example, 35 to 90 ° C. without heat treatment or baking, and the chocolate itself from the chocolate surface to the inside of the chocolate.
  • the present inventors have found that it is possible to produce chocolates having a soft and smooth texture, melting in the mouth and excellent flavor, and completed the present invention.
  • the chocolate dough of the present invention there is no problem of difficulty in atomization during chocolate dough preparation, the occurrence of lumps and the problem of viscosity increase of the dough, the dough viscosity to a specific viscosity suitable for coating It can also be prepared, and there is almost no change in viscosity over time during the coating operation.
  • the present invention includes (1) chocolate containing 2 to 20% by weight of one or more sugars selected from maltose, trehalose, fructose, palatinose, reduced palatinose, maltitol, erythritol, lactitol and sorbitol.
  • a method for producing a chocolate-based food characterized by contacting with a food or a food material having an activity of 0.4 to 0.95.
  • the present invention there is heat resistance in a temperature range exceeding the melting point of fats and oils in chocolate, for example, 35 to 90 ° C. without heat treatment or baking for imparting heat resistance to the chocolate, and the chocolate surface From the inside of the chocolate to the inside of the chocolate, it becomes possible to produce chocolates that are excellent in the soft and smooth texture, melting in the mouth and flavor.
  • the chocolates in the present invention are those in which fats and oils form a continuous phase, and include chocolate and chocolate-like foods.
  • “Chocolate” includes “chocolate dough” and “quasi-chocolate dough” according to the “Fair Competition Rules for the Display of Chocolate” (March 29, 1971, Fair Trade Commission Notification No. 16), This refers to a product obtained by using a cocoa mass, cocoa butter, cocoa powder and sugars prepared from cocoa beans and adding other edible oils and fats, dairy products, fragrances and the like as necessary, followed by a normal chocolate manufacturing process.
  • cocoa butter other fats and oils saturated 1,3-position, 2-position unsaturated called CBE
  • CBE saturated 1,3-position, 2-position unsaturated
  • For rich glyceride type fats and oils laurin type called CBS, high elaidic acid type called CBR and low trans non-laurin type hard butter, and for confectionery, breads, frozen confectionery May be those using various oils or liquid oils having a high melting point to a low melting point depending on the application.
  • any components used in ordinary chocolates such as cacao mass, cocoa powder, saccharides, milk powder, fats and oils, emulsifier, fragrance, flavoring agent and coloring agent can be used. .
  • the chocolate of the present invention contains 2 to 20% by weight of one or more sugars selected from maltose, trehalose, fructose, palatinose, reduced palatinose, maltitol, erythritol, lactitol and sorbitol as essential components. is there.
  • sugars selected from maltose, trehalose, fructose, palatinose, reduced palatinose, maltitol, erythritol, lactitol and sorbitol as essential components.
  • saccharide content is less than 2% by weight, heat resistance in the temperature range exceeding the melting point of the fats and oils in the chocolate is obtained after the chocolate is brought into contact with a food or food material having a water activity of 0.4 to 0.95.
  • the problem is that the chocolate surface is sticky or sticks to fingers.
  • sugars such as sugar, lactose, glucose and other saccharides generally used for chocolates can be appropriately blended with the chocolates of the present invention.
  • Powdered milk can be appropriately blended in the chocolates of the present invention, and the blending amount is not particularly limited as long as it is less than 35% by weight.
  • the chocolate of the present invention can also be used for imparting heat resistance to foods using chocolate using bitter chocolate having a milk powder content of less than 3% by weight.
  • Milk powder in the present invention means milk powder prescribed in the Ministerial Ordinance such as milk, whole milk powder, skim milk powder obtained from raw milk, milk, special milk, cream powder, whey powder, butter milk powder, This includes sweetened milk powder and formula milk powder. When the milk powder content exceeds 35% by weight, atomization during preparation of chocolate dough becomes difficult, and the viscosity of the dough after preparation increases, making subsequent molding and coating operations difficult, which is not preferable.
  • the chocolates of the present invention preferably contain the saccharide as an essential component and limit the lecithin content.
  • the content of lecithin is preferably 0.4% by weight or less, more preferably 0.1 to 0.3% by weight, and most preferably 0.1 to 0.2% by weight.
  • the content of lecithin is 0.1% by weight or less, the viscosity of the chocolate dough becomes too high, making it difficult to mold or cast the chocolate, so polyglycerin condensed ricinolein as a viscosity modifier.
  • PGPR acid ester
  • the present invention preferably contains 0.1 to 0.5% by weight of PGPR in addition to lecithin, more preferably 0.1 to 0.3% by weight, and most preferably 0, in order to adjust the chocolate dough viscosity. .1 to 0.2% by weight.
  • the viscosity of the chocolate dough of the present invention is 2,000 to 20,000 cP in a viscosity measurement value obtained by adjusting the temperature of the fats and oils in the dough to 45 ° C. after complete melting, although it depends on the use after preparation of the dough. preferable. If the dough viscosity exceeds 20,000 cP, it is not preferable because molding of chocolate (casting) and coaching work become difficult.
  • the chocolate is used for baked confectionery or bread coating, it is preferably 2,000 to 10,000 cP, more preferably, in a viscosity measurement value obtained by adjusting the temperature of oil and fat in the dough to 45 ° C. after complete melting. 3,000 to 8,000 cP.
  • the dough viscosity is less than 2,000 cP, the coating thickness of the chocolate becomes too thin and the base is transparent, or the chocolate flavor becomes thin. Conversely, if the dough viscosity exceeds 10,000 cP, the coating thickness becomes too thick. There is a risk of further increase in viscosity during the holding time before coating, which is not preferable.
  • the chocolate-based food of the present invention retains heat resistance in the temperature range exceeding the melting point of the fats and oils in the chocolate.
  • the temperature range of 40 ° C. to 90 ° When the temperature drops below 30 ° C., whitening due to bloom may occur on the chocolate surface.
  • trans acid type hard butter containing elaidic acid as a constituent fatty acid low trans It is preferable to blend any of so-called no tempering type hard butter such as non-lauric acid type hard butter and lauric acid type hard butter.
  • Additional ingredients that may be included in the chocolates of the present invention include cocoa mass, cocoa powder, soy flour, soy milk powder, concentrated soy protein, soy protein isolate, soy whey, coffee, vanilla, caramel, fruit, nuts, and Flavors such as fruit powder and dried fruits, nuts, vanilla, herbs (e.g. mint), flavors such as vanilla flavors, herb flavors, caramel flavors, nuts, cereals, puffed products, fruits, creams, or mixtures thereof And other edible ingredients.
  • the colorant, flavoring agent, and fragrance are not limited to the aforementioned components, and any of those well known to those skilled in the art are used.
  • Emulsifiers other than lecithin and PGPR can be used as appropriate as long as the dough viscosity of chocolates and the heat resistance after heat treatment are compatible.
  • sucrose fatty acid esters, sorbitan fatty acid esters, polyglycerin fatty acid esters, fractionated lecithin, ammonium phosphate and the like can be used.
  • the purpose of use is to suppress bloom and prevent graining as a countermeasure when exposed to high temperatures above the melting point of fat during storage and transportation.
  • the chocolate dough of this invention can be prepared with the manufacturing method as follows, for example as follows. Add heat-melted cacao mass, fats and oils and emulsifiers such as lecithin, PGPR, etc. to solid raw materials such as cocoa powder, sugar, and milk powder, and mix them using a Hobart mixer. A pasty dough is prepared. The obtained dough is atomized by a refiner such as a roll so as to be smooth particles having an average particle diameter of 15 to 30 ⁇ m. Next, conching (stirring and mixing) is performed while keeping the temperature at 40 to 70 ° C. to obtain a smooth paste, and further, fats and oils, emulsifiers, flavors and the like are added and mixed to obtain a predetermined chocolate dough. When the conching temperature exceeds 80 ° C., the viscosity of the chocolate dough is remarkably increased. Therefore, the chocolate dough of the present invention is preferably conched at 40 to 70 ° C.
  • the average particle size is preferably from 15 to 30 ⁇ m, more preferably from 18 to 25 ⁇ m, most preferably from 18 to 22 ⁇ m. It is not preferable because it provides a texture that feels bad. Also, if the dough increases in viscosity in the conching process, it will cause lumps, or it will be easy to adhere to the mixer wall surface and take a long time to make a smooth paste, or the chocolate dough finally prepared The viscosity of the resin is too high, causing problems that hinder the subsequent molding process. Accordingly, it is important to set the chocolate dough so that the increase in the viscosity of the dough is within an allowable range in the conching process. It is the dough compounding of the chocolates of the present invention that matches such a compounding setting.
  • the moisture of the chocolate dough of the present invention is preferably 2% by weight or less, more preferably 1% by weight or less. If the water content exceeds the upper limit, problems such as an increase in viscosity during the preparation of the dough and occurrence of lumps tend to occur, such being undesirable. Further, the fat and oil content of the chocolate dough of the present invention is preferably 25 to 45% by weight, more preferably 30 to 40% by weight, and most preferably 32 to 38% by weight. If the fat and oil content is less than 25% by weight, the smooth texture of chocolate is impaired, and the texture becomes harsh, and depending on the storage environment, the physical properties tend to become sticky due to moisture absorption of sugar, which is not preferable. Moreover, since oil-off to the chocolate surface will become remarkable when fats and oils content exceeds 45 weight%, it is unpreferable.
  • the chocolate-based food of the present invention is a food obtained by bringing the chocolate into contact with a food or a food material having a water activity of 0.4 to 0.95.
  • the chocolates after contact are sticky to the chocolate surface or adhere to each other in a temperature range above the melting point of the fats and oils in the chocolates, for example, 35 to 90 ° C.
  • the chocolate has excellent heat resistance so that it does not lose its shape, and is excellent in chocolate's original soft and smooth texture, melting in the mouth and flavor from the chocolate surface to the inside of the chocolate.
  • the chocolate-based food of the present invention is a baked confectionery after the chocolate dough prepared by the above method is kept in a molten state at a temperature not lower than the melting point of the fats and oils in the chocolate, for example, 40 to 60 ° C. for 30 minutes or longer.
  • Baked confectionery coated with or placed with chocolate tolerants by bringing it into contact with food or food ingredients such as bread or bread by a method such as coating or placing, and finally cooling to solidify the fat in the chocolate. Foods using chocolate such as bread and bread can be obtained.
  • the reason why the chocolates of the foods using chocolates according to the present invention exhibit excellent heat resistance is not clear, but the water transfer from foods or food materials having a water activity of 0.4 to 0.95 to the chocolates brought into contact with As a result of the formation of glassy structures by the absorption of moisture by sugars selected from maltose, trehalose, fructose, palatinose, reduced palatinose, maltitol, erythritol, lactitol and sorbitol present in chocolate, chocolates It is considered that heat resistance is obtained even at 35 to 90 ° C., which is the temperature range in which the oils and fats therein melt.
  • the cooling after the contact with the food or the food material can be performed by cooling in a refrigerator at 0 to 15 ° C., cooling with cooling air such as a cooling tunnel, or cooling at room temperature below 30 ° C.
  • the water activity of the food or food material used in the present invention is preferably 0.4 to 0.95, more preferably 0.55 to 0.95, and most preferably 0.7 to 0.95. If the water activity is less than 0.4, the heat resistance of the chocolate after contact with the chocolate becomes insufficient, which is not preferable. If the water activity exceeds the upper limit, the degree of moisture transfer becomes too large, and the chocolate after contact with the chocolate fluidizes in a ganache state, and heat resistance is lost.
  • the food or food material used in the present invention is not particularly limited as long as the water activity is 0.4 to 0.95.
  • dried fruits such as koji and papaya, rice crackers, round bolo, caramel, marshmallow, jelly beans, etc. 7 to 21% by weight of dried confectionery, malong rasse, cupcake, baumkuchen, pound cake, butter cake, sponge cake, waffle, etc. % Of dessert confectionery, donuts, pies, Danish, snack bread, coppe bread, roll bread and the like with 20 to 45% by weight moisture.
  • heat resistance evaluation The chocolate dough was kept at 45 ° C. for 30 minutes or longer to be melted and coated on the surface of the food or food raw material, and allowed to stand at 20 ° C. overnight to cool and solidify the chocolate. Seal the cooled and solidified chocolate food in a gusset bag, stabilize at 20 ° C for 1 day, leave it in a constant temperature bath at 40 ° C for 1 day, touch the chocolate surface with your hand, and check if there is any sticking to your fingers, oil off It was confirmed whether or not there was any deformation.
  • Prototype example 1 7 parts of cocoa powder (11% oil), 55.9 parts of sugar, 4.8 parts of maltose monohydrate (trade name “San Marto Midori”, Hayashibara Shoji Co., Ltd.) were weighed, mixed and melted in advance. Using a mixer (AM30, Aikosha Co., Ltd.) 3.5 parts of cacao mass (oil content 55%), 21 parts of lauric acid type hard butter (trade name “Parkena H”, rising melting point 35 ° C., manufactured by Fuji Oil Co., Ltd.) Added with stirring. The obtained dough-shaped dough was finely pulverized with a roll refiner (“Three-roll mill SDY-300” manufactured by BUHLER Co., Ltd.) to obtain roll flakes.
  • a roll refiner (“Three-roll mill SDY-300” manufactured by BUHLER Co., Ltd.)
  • the obtained roll flakes were mixed with Parkena H 4 parts, lecithin 0.2 parts and PGPR (trade name: CRS75, Sakamoto Yakuhin Kogyo Co., Ltd.) 0.15 parts with a conching mixer (Shinagawa Kogyo Co., Ltd.), 55 The mixture was stirred at a medium speed while being kept at °C. After the flakes became a slightly soft dough shape, 4 parts of Parkena H was added with stirring to obtain a chocolate dough 1.
  • the chocolate dough 1 had an average particle size of 19 ⁇ m, a viscosity of 6,390 cP, and a water content of 0.8%.
  • Prototype Example 2 to Prototype Example 10 Chocolate doughs 2 to 10 were obtained by replacing the maltose monohydrate of Prototype Example 1 with the following sugars and preparing chocolate doughs as in Prototype Example 1.
  • Prototype example 2 Trehalose (manufactured by Hayashibara Corporation)
  • Prototype Example 3 Fructose (trade name “Krystar 300”, manufactured by Danisco Japan Co., Ltd.)
  • Prototype Example 4 Palatinose (trade name “Crystalline Palatinose IC”, manufactured by Mitsui Sugar Co., Ltd.)
  • Prototype Example 5 Reduced Palatinose (trade name “Powder Reduced Palatinite PNP”, manufactured by Mitsui Sugar Co., Ltd.)
  • Prototype Example 6 Maltitol (trade name “Sweet Pearl P35”, manufactured by ROQUETTE)
  • Prototype Example 7 Erythritol (trade name “Zerose Erythritol 16952”, manufactured by
  • Example 1 After holding the chocolate dough of Prototype Example 1 at 45 ° C. for 30 minutes to form a molten state, the upper half of a commercially available snack pan (water activity 0.83) is immersed in the chocolate dough 1, and the snack bread after the immersion is used. It was taken out and shaken for about 2 seconds to shake off excess chocolate dough to obtain a snack bread coated with the chocolate dough. The obtained snack bread was left at 20 ° C. overnight, filled in a gusset bag, and further stored at 20 ° C. for 3 days.
  • water activity 0.83 water activity 0.83
  • the gusset bag was opened and the heat resistance of the coated chocolates (finger, adhesion to the inner surface of the gusset bag) was evaluated. There was no adhesion to the gusset bag.
  • Example 2 to Example 9 The chocolate dough 1 of Example 1 was replaced with the chocolate doughs 2 to 9 of Prototype Example 2 to Prototype Example 9, respectively, to obtain a snack bread coated with the chocolate dough as in Example 1.
  • Example 1 When the heat resistance of the coated chocolates of the obtained chocolate-coated snack bread was evaluated in the same manner as in Example 1, none of them adhered to the fingers and hardly adhered to the gusset bag.
  • Example 1 The chocolate dough 1 of Example 1 was replaced with the chocolate dough 10 of Prototype Example 10 to obtain a snack bread coated with the chocolate dough as in Example 1.
  • the heat resistance of the obtained chocolate-coated snack bread was evaluated in the same manner as in Example 1, both the adhesion of the coated chocolate to the fingers and the adhesion to the gusset bag were intense and there was no heat resistance.
  • Table 1 shows the properties of the chocolate doughs of Examples 1 to 9 and Comparative Example 1 and the heat resistance evaluation results of the chocolate-coated snack bread. Table 1
  • the snack bread-coated chocolates containing only sugar as the saccharide of Comparative Example 1 had no heat resistance at 40 ° C.
  • the coated chocolates of Examples 1 to 9 had a soft and smooth texture from the surface to the inside.
  • Prototype Example 11 Change the 55.9 parts of sugar of Prototype Example 1 to 54.4 parts and 4.8 parts of maltose monohydrate to 6.3 parts to make a chocolate dough as in Prototype Example 1, A dough 11 was obtained.
  • the average particle diameter of the chocolate dough 11 was 19 ⁇ m, the viscosity was 6,500 cP, and the water content was 0.8%.
  • Prototype Example 12 The chocolate dough was prepared in the same manner as in Prototype Example 1 by changing 55.9 parts of sugar in Prototype Example 2 to 54.4 parts and 4.8 parts of Trehalose to 6.3 parts, and a chocolate dough 12 was obtained. .
  • the average particle diameter of the chocolate dough 12 was 19 ⁇ m, the viscosity was 6,170 cP, and the water content was 0.8%.
  • Example 10 The chocolate dough of Prototype Example 11 is held at 45 ° C. for 30 minutes to form a molten state, and then caramel (water activity 0.56) is dipped in the chocolate dough 11 and the dipped caramel is taken out with tweezers for about 2 seconds. The excess chocolate dough was shaken off to obtain a caramel covered with the chocolate dough 11.
  • caramel water activity 0.56
  • tweezers for about 2 seconds.
  • the excess chocolate dough was shaken off to obtain a caramel covered with the chocolate dough 11.
  • Example 11 instead of the caramel of Example 10, a commercially available castella (water activity 0.79) was used to obtain a castella coated with the chocolate dough 11 as in Example 1.
  • water activity 0.79 water activity 0.79
  • Example 12 It replaced with the caramel of Example 10, and obtained the snack bread by which chocolate dough 11 was coat
  • the heat resistance of the coated chocolates of the prepared chocolate-coated snack bread was evaluated in the same manner as in Example 1, there was no adhesion to fingers and almost no adhesion to gusset bags.
  • Example 13 The chocolate dough of Prototype Example 12 is held at 45 ° C. for 30 minutes to form a melt, and then caramel (water activity 0.56) is dipped in the chocolate dough 12, and the dipped caramel is removed with tweezers for about 2 seconds. The excess chocolate dough was shaken off to obtain a caramel coated with the chocolate dough 12.
  • caramel water activity 0.56
  • tweezers for about 2 seconds.
  • the excess chocolate dough was shaken off to obtain a caramel coated with the chocolate dough 12.
  • Example 14 instead of the caramel of Example 13, a commercially available castella (water activity 0.79) was used to obtain a castella coated with the chocolate dough 12 as in Example 1.
  • water activity 0.79 water activity 0.79
  • Example 15 It replaced with the caramel of Example 13, and obtained the snack bread by which chocolate dough 12 was coat
  • the heat resistance of the coated chocolates of the prepared chocolate-coated snack bread was evaluated in the same manner as in Example 1, there was no adhesion to fingers and almost no adhesion to gusset bags.
  • Comparative Example 2 In place of the caramel of Example 10, dry peanuts (water activity 0.34) were used to obtain dry peanuts coated with chocolate dough 11 as in Example 1. When the heat resistance of the prepared chocolate-coated dry peanut-coated chocolate was evaluated in the same manner as in Example 1, it had adhesion to fingers and gusset bags and was poor in heat resistance.
  • Comparative Example 3 In place of the caramel of Example 13, dry peanuts (water activity 0.34) were used to obtain dry peanuts coated with the chocolate dough 12 as in Example 1. When the heat resistance of the prepared chocolate-coated dry peanut-coated chocolate was evaluated in the same manner as in Example 1, it had adhesion to fingers and gusset bags and was poor in heat resistance.
  • Table 2 shows the heat resistance evaluation results of the coated chocolates of the chocolate-coated foods of Examples 10 to 15 and Comparative Examples 2 to 3. Table 2
  • Each of the foods using chocolate obtained by coating the chocolate containing 6.3% of maltose or trehalose of Examples 10 to 15 with a food having a water activity of 0.56 to 0.83 has a melting point of 35 ° C. of the fats and oils in the chocolate. Excellent heat resistance at 40 ° C. exceeding On the other hand, chocolate-based foods coated with dry peanuts having a water activity of 0.34 had poor heat resistance at 40 ° C. due to adhesion to fingers and gusset bags.
  • Prototype Example 13 A chocolate dough was prepared in the same manner as in Prototype Example 1 by changing 55.9 parts of sugar in Prototype Example 2 to 58.5 parts and 4.8 parts of Trehalose to 2.1 parts, and a chocolate dough 13 was obtained. .
  • Prototype Example 14 A chocolate dough was prepared in the same manner as in Prototype Example 1 by changing 55.9 parts of sugar in Prototype Example 2 to 48.1 parts and 4.8 parts of trehalose to 12.5 parts, and a chocolate dough 14 was obtained. .
  • Prototype Example 15 A chocolate dough was prepared in the same manner as in Prototype Example 1 by changing 55.9 parts of sugar in Prototype Example 2 to 45.6 parts and 4.8 parts of Trehalose to 15 parts, and a chocolate dough 15 was obtained.
  • Prototype Example 16 Prototype Example 5 was changed from 55.9 parts of sugar to 58.5 parts and reduced palatinose to 4.8 parts to 2.1 parts. It was.
  • Prototype Example 17 Change the 55.9 parts of sugar of Prototype Example 5 to 54.4 parts and 4.8 parts of reduced palatinose to 6.3 parts to make a chocolate dough as in Prototype Example 1 to obtain a chocolate dough 17 It was.
  • Prototype 18 Prototype Example 5 55.9 parts sugar was changed to 48.1 parts and reduced palatinose 4.8 parts to 12.5 parts, and the chocolate dough was prepared in the same manner as in Prototype Example 1 to obtain chocolate dough 18 It was.
  • Prototype Example 19 A chocolate dough was prepared in the same manner as in Prototype Example 1 by changing 55.9 parts of sugar in Prototype Example 5 to 45.6 parts and 4.8 parts of reduced palatinose to 15 parts.
  • Example 16 to 22 The chocolate dough 1 of Example 1 was replaced with the chocolate doughs 13 to 19 of Prototype Example 13 to Prototype Example 19, respectively, to obtain a snack bread coated with the chocolate dough as in Example 1.
  • Example 1 When the heat resistance of the coated chocolates of the obtained chocolate-coated snack bread was evaluated in the same manner as in Example 1, none of them adhered to the fingers and hardly adhered to the gusset bag.
  • Table 3 shows the properties of the chocolate doughs of Examples 16 to 22 and the heat resistance evaluation results of the chocolates covered with the chocolate-coated snack bread.
  • Prototype Example 20 A chocolate dough was obtained by replacing 55.9 parts of sugar in Prototype Example 2 with 44.5 parts of sugar and 11.4 parts of whole milk powder milk in the same manner as in Prototype Example 1. This chocolate dough contains 4.8 parts of trehalose and 11.4 parts of whole milk powder.
  • Example 23 After holding the chocolate dough 20 of Prototype Example 20 at 45 ° C. for 30 minutes to form a melt, caramel (water activity 0.56) is dipped in the chocolate dough 20 and the dipped caramel is taken out with tweezers, about 2 Shaking for 2 seconds, the excess chocolate dough was shaken off to obtain a caramel coated with the chocolate dough 20.
  • the heat resistance of the prepared chocolate-coated caramel coated chocolate was evaluated in the same manner as in Example 1. As a result, there was no adhesion to fingers and no adhesion to gusset bags.
  • Example 24 instead of the caramel of Example 23, dry papaya (dried water 0.46) coated with chocolate dough 20 in the same manner as Example 23 was obtained.
  • the heat resistance of the coated chocolates of the prepared chocolate-coated dry papaya was evaluated in the same manner as in Example 1, there was no adhesion to fingers and almost no adhesion to gusset bags.
  • Comparative Example 4 In place of the caramel of Example 23, dry peanuts obtained by coating dry peanuts (water activity 0.34) with the chocolate dough 20 as in Example 23 were obtained. When the heat resistance of the prepared chocolate-coated dry peanut-coated chocolate was evaluated in the same manner as in Example 1, there was adhesion to fingers and gusset bags and the heat resistance was poor.
  • Table 4 shows the heat resistance evaluation results of the coated chocolates of the chocolate-coated foods of Examples 23 to 24 and Comparative Example 4.
  • the foods using chocolates obtained by coating the foods of Examples 23 to 24 with the water activity of 0.56 and 0.46 and the chocolate dough 20 have excellent heat resistance at 40 ° C. exceeding the melting point 35 ° C. in the chocolate fats and oils. Indicated.
  • the chocolate-based foods obtained by coating the chocolate dough 20 on dry peanuts having a water activity of 0.34 were poor in heat resistance at 40 ° C.
  • Prototype Example 21 A chocolate dough 21 was obtained in the same manner as in Prototype Example 12, except that 0.2 part of lecithin in Prototype Example 12 with 6.3 parts of trehalose was replaced with 0.5 part in lecithin.
  • the chocolate dough 21 had an average particle size of 20 ⁇ m, a viscosity of 11,000 cP, and a water content of 0.8%.
  • the chocolate dough viscosity tended to be higher than that of Prototype Example 12 having a lecithin content of 0.2 part.
  • Example 25 After the chocolate dough 21 of Prototype Example 21 was held at 45 ° C. for 30 minutes to form a molten state, a commercially available castella (water activity 0.79) was dipped in the chocolate dough 21 and the dipped castella was taken out, and about 2 Shaking for 2 seconds, the excess chocolate dough was shaken off to obtain a castella covered with the chocolate dough.
  • a commercially available castella water activity 0.79
  • Example 1 Example 13 with a lecithin content of 0.2% showed better heat resistance than Example 25 with a lecithin content of 0.5%.
  • Prototype 22 Replacing the lauric acid type hard butter of Prototype Example 12 (trade name “Parkena H”, rising melting point 35 ° C.) with non-lauric hard butter (trade name “Melano H1000”, rising melting point 37 ° C., manufactured by Fuji Oil Co., Ltd.)
  • a chocolate dough was prepared in the same manner as in Prototype Example 1 to obtain a chocolate dough 22.
  • the chocolate dough 22 had an average particle size of 20 ⁇ m, a viscosity of 7,400 cP, and a water content of 0.8%.
  • Example 26 The chocolate dough 21 of Example 25 was replaced with the chocolate dough 22 of Prototype Example 22, and a chocolate-coated castella was obtained in the same manner as Example 25.
  • the heat resistance of the coated chocolates of the prepared chocolate-coated castella was evaluated in the same manner as in Example 1, there was no adhesion to fingers and no adhesion to gusset bags.
  • the chocolate-based foods coated with the chocolate dough 22 have excellent heat resistance at 40 ° C exceeding the melting point of 37 ° C in the fats and oils of chocolate, and the coated chocolate has a soft and smooth texture from the surface to the inside. there were.
  • Prototype Example 23 Substituting 54.4 parts of sugar of Prototype Example 22 with 34.4 parts of sugar and 15 parts of lactose, substituting 29 parts of Melano H1000 with 34 parts, and further replacing 0.15 parts by weight of PGPR with zero, Prototype Example 12 Similarly, chocolate dough 23 was obtained.
  • the chocolate dough 21 had an average particle size of 20 ⁇ m, a viscosity of 6,500 cP, and a moisture content of 0.8%, and passed without any occurrence of lumps.
  • Example 27 After holding the chocolate dough 23 of Prototype Example 23 at 45 ° C. for 30 minutes to form a molten state, the upper half of a commercially available snack bread (water activity 0.86) is dipped in the chocolate dough 23, and the snack bread after dipping Was removed and shaken for about 2 seconds to shake off the excess chocolate dough to obtain a snack bread coated with the chocolate dough.
  • a commercially available snack bread water activity 0.86
  • the snack bread after dipping was removed and shaken for about 2 seconds to shake off the excess chocolate dough to obtain a snack bread coated with the chocolate dough.
  • the heat resistance of the coated chocolates of the prepared chocolate-coated snack bread was evaluated in the same manner as in Example 1, there was no adhesion to fingers and gusset bags, and excellent heat resistance was shown.
  • the coated chocolates had a good texture that was soft and smooth from the surface to the inside.
  • a temperature range exceeding the melting point of the fat or oil for example, 35 to 90, without heat treatment or baking for imparting heat resistance. It is possible to produce foods that use chocolates that are heat-resistant at °C and that have excellent soft and smooth texture, melted mouth, and flavor from the chocolate surface to the inside of the chocolate.

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  • Polymers & Plastics (AREA)
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  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
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Abstract

L'invention concerne un procédé pour fabriquer un aliment utilisant du chocolat, ledit chocolat étant tolérant à une plage de températures élevées dépassant un point de fusion de graisses et d'huiles contenues dans des chocolats, telle que 35-90 °C, ayant une texture molle et lisse inhérente aux chocolats à partir de la surface de chocolat jusqu'au noyau de chocolat et présentant une haute capacité de fonte dans la bouche et une excellente saveur, sans entraîner de traitement de chauffage ou de cuisson pour conférer une tolérance à la chaleur aux chocolats, en particulier aux chocolats ayant une faible teneur en poudre de lait. L'invention concerne un aliment utilisant du chocolat, ledit chocolat étant tolérant à une plage de températures élevées dépassant un point de fusion de graisses et d'huiles, telle que 35-90 °C, ayant une texture molle et lisse inhérente aux chocolats à partir de la surface de chocolat jusqu'au noyau de chocolat et présentant une haute capacité de fonte dans la bouche et une excellente saveur, qui est obtenu en recouvrant un aliment ou une matière alimentaire ayant une activité d'eau de 0,4-0,95 avec une pâte de chocolat contenant une quantité spécifique de saccharide(s) et de lécithine spécifiques, ou en plaçant ladite pâte de chocolat sur ledit aliment ou matière alimentaire, puis en solidifiant la pâte de chocolat par refroidissement, sans chauffer ni cuire la pâte de chocolat.
PCT/JP2014/057148 2013-03-19 2014-03-17 Procédé pour fabriquer un aliment utilisant du chocolat ayant une haute tolérance à la chaleur WO2014148436A1 (fr)

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WO2017170676A1 (fr) * 2016-03-31 2017-10-05 株式会社 ロッテ Confiserie et son procédé de fabrication
JP2019170287A (ja) * 2018-03-29 2019-10-10 不二製油株式会社 低発汗コーティング用油性食品およびこれに被覆された食品の発汗抑制方法
JP2019180241A (ja) * 2018-03-31 2019-10-24 不二製油株式会社 低発汗被覆用油性食品およびこれに被覆された食品の発汗防止方法
JP7327699B1 (ja) 2023-03-31 2023-08-16 不二製油株式会社 水分を含有するパン生地又は焼菓子生地との同時焼成用チョコレート類

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WO1991000691A1 (fr) * 1989-07-13 1991-01-24 Fuji Oil Company, Limited Procede de fabrication d'un aliment contenant du chocolat, et chocolat utilise a cet effet
WO1999065323A1 (fr) * 1998-06-16 1999-12-23 Davila Victor R Procede permettant de fabriquer des compositions de chocolat et de type chocolat resistantes a la chaleur et a viscosite apparente reduite, et produits ainsi fabriques
WO2001065947A1 (fr) * 2000-03-07 2001-09-13 Fuji Oil Company, Limited Procede de preparation de confiseries hautement stables a la chaleur
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WO2013099810A1 (fr) * 2011-12-29 2013-07-04 不二製油株式会社 Procédé de production de chocolats tolérant la chaleur
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JPS52148662A (en) * 1976-06-03 1977-12-10 Morinaga & Co Production of and apparatus for oily confection with excellent heat stability
JPS56169546A (en) * 1980-12-05 1981-12-26 Morinaga & Co Ltd Preparation of oily or fatty cake having improved heat resistance
WO1991000691A1 (fr) * 1989-07-13 1991-01-24 Fuji Oil Company, Limited Procede de fabrication d'un aliment contenant du chocolat, et chocolat utilise a cet effet
WO1999065323A1 (fr) * 1998-06-16 1999-12-23 Davila Victor R Procede permettant de fabriquer des compositions de chocolat et de type chocolat resistantes a la chaleur et a viscosite apparente reduite, et produits ainsi fabriques
WO2001065947A1 (fr) * 2000-03-07 2001-09-13 Fuji Oil Company, Limited Procede de preparation de confiseries hautement stables a la chaleur
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WO2012121327A1 (fr) * 2011-03-08 2012-09-13 株式会社明治 Pâtisserie cuite
WO2013099810A1 (fr) * 2011-12-29 2013-07-04 不二製油株式会社 Procédé de production de chocolats tolérant la chaleur
JP2014087319A (ja) * 2012-10-31 2014-05-15 Fuji Oil Co Ltd 耐熱性チョコレート類の製造方法

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017170676A1 (fr) * 2016-03-31 2017-10-05 株式会社 ロッテ Confiserie et son procédé de fabrication
TWI755385B (zh) * 2016-03-31 2022-02-21 日商樂天股份有限公司 糕點的製造方法
JP2019170287A (ja) * 2018-03-29 2019-10-10 不二製油株式会社 低発汗コーティング用油性食品およびこれに被覆された食品の発汗抑制方法
JP7155575B2 (ja) 2018-03-29 2022-10-19 不二製油株式会社 低発汗コーティング用油性食品およびこれに被覆された食品の発汗抑制方法
JP2019180241A (ja) * 2018-03-31 2019-10-24 不二製油株式会社 低発汗被覆用油性食品およびこれに被覆された食品の発汗防止方法
JP7099012B2 (ja) 2018-03-31 2022-07-12 不二製油株式会社 低発汗被覆用油性食品およびこれに被覆された食品の発汗防止方法
JP7327699B1 (ja) 2023-03-31 2023-08-16 不二製油株式会社 水分を含有するパン生地又は焼菓子生地との同時焼成用チョコレート類

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