WO2014142304A1 - Procédé de traitement de surface d'un substrat de silicium, procédé de production d'un dispositif à semi-conducteur, dispositif de production de semi-conducteurs, élément de transfert et procédé de production de ce dernier ainsi que cellule solaire et procédé de production d'une cellule solaire - Google Patents

Procédé de traitement de surface d'un substrat de silicium, procédé de production d'un dispositif à semi-conducteur, dispositif de production de semi-conducteurs, élément de transfert et procédé de production de ce dernier ainsi que cellule solaire et procédé de production d'une cellule solaire Download PDF

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Publication number
WO2014142304A1
WO2014142304A1 PCT/JP2014/056888 JP2014056888W WO2014142304A1 WO 2014142304 A1 WO2014142304 A1 WO 2014142304A1 JP 2014056888 W JP2014056888 W JP 2014056888W WO 2014142304 A1 WO2014142304 A1 WO 2014142304A1
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WO
WIPO (PCT)
Prior art keywords
metal
silicon substrate
transfer member
catalytic function
silicon
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PCT/JP2014/056888
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English (en)
Japanese (ja)
Inventor
小林 光
健太郎 今村
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Kobayashi Hikaru
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Publication date
Application filed by Kobayashi Hikaru filed Critical Kobayashi Hikaru
Priority to JP2015505598A priority Critical patent/JP6359519B2/ja
Publication of WO2014142304A1 publication Critical patent/WO2014142304A1/fr

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0236Special surface textures
    • H01L31/02363Special surface textures of the semiconductor body itself, e.g. textured active layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/546Polycrystalline silicon PV cells

Definitions

  • the present invention relates to a silicon substrate surface treatment method, a semiconductor device manufacturing method, a semiconductor manufacturing device, a transfer member and a manufacturing method thereof, and a solar cell, which are related to forming a fine nanocrystal structure layer on the surface of a silicon substrate. And a method for manufacturing a solar cell.
  • the first metal is selected from the group of platinum (Pt), silver (Ag), palladium (Pd), gold (Au), rhodium (Rh) and alloys with other metals containing these.
  • the second metal is selected from the group of Ni, Fe, Cu, and Pd in addition to silver (Ag).
  • the transfer member made of the first metal is dipped in a solution prepared by dissolving the second metal and pulled up, and a small amount of trace is formed on the surface of the transfer member.
  • a silicon substrate selected from single crystal silicon, polycrystalline silicon, amorphous silicon, pseudo single crystal silicon, and silicon compound semiconductor (including silicon carbide, silicon germanium, etc.) is selectively used as the silicon substrate. Can be used.
  • a mixture of 100 ml of 50 wt% hydrogen fluoride (HF) water and 100 ml of 30 wt% hydrogen peroxide (H 2 O 2 ) aqueous solution was prepared in one container in a vinyl chloride container.
  • a chemical solution in which silver (Ag) is dissolved (a solution having the same mixing ratio of hydrogen fluoride (HF) water and hydrogen peroxide (H 2 O 2 ) as in the above) is added to silver (Ag).
  • a treatment liquid is prepared by injecting to a concentration of 1 ppm.
  • a platinum foil having a thickness of about 20 ⁇ m is wound around a roller, and the platinum foil is brought into contact with the surface of the silicon substrate.
  • the surface of the nanocrystal structure layer of the silicon substrate is treated in a 100 ml concentration of 70 wt% nitric acid (HNO 3 ) aqueous solution at room temperature for 10 minutes in a fluororesin container, and remains in the nanocrystal structure layer.
  • HNO 3 nitric acid
  • the obtained silver was dissolved, and further treated with hydrogen fluoride (HF) acid having a concentration of 5 wt% for 2 minutes, and then washed with water.
  • HF hydrogen fluoride
  • both single-crystal silicon substrates are temporarily laminated in oxygen at 600 ° C. for 30 minutes.
  • oxygen 600 ° C. for 30 minutes.
  • simultaneous diffusion treatment 970 ° C. for 15 minutes in (nitrogen (N 2 ), and the n + type region on the front side and the p side on the back side A + region was formed.
  • N 2 nitrogen
  • FIG. 17 is a current density (mA / cm 2 ) -voltage characteristic diagram obtained by light irradiation of AM1.5 of the pn junction solar cell obtained in this example.
  • high performance was obtained with a photocurrent density of 40.3 mA / cm 2 , Voc of 589 mV, and conversion efficiency of 17.6%.
  • the photocurrent density is 28.0 mA / cm 2
  • Voc is 582 mV
  • the conversion efficiency is 12.5.
  • the photocurrent density is greatly increased as seen from the characteristics of the solid line, and the increase in conversion efficiency is also remarkable. It was clear that
  • This characteristic is an example when the surface is not provided with an anti-reflective coating, the surface is not passivated, and the back surface field (BSF) is not formed and optimized. In the final product, it can be sufficiently expected that the conversion efficiency of the solar cell can be further increased.

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)
  • Weting (AREA)

Abstract

La présente invention se rapporte, dans un mode de réalisation, à un procédé de traitement de surface d'un substrat de silicium de telle sorte qu'un second métal qui comporte une minuscule fonction catalytique, soit supporté sur la surface d'un élément de transfert comprenant un premier métal qui comporte une fonction catalytique, et soit mis en contact avec le substrat de silicium ou soit mis à proximité de ce dernier dans une solution de traitement qui peut oxyder et dissoudre le silicium, ce qui permet de former une couche structurelle nanocristalline sur une section de surface du substrat de silicium. Il s'ensuit que la réflectivité d'une zone de lumière visible sur la surface du substrat de silicium est un peu réduite de pas plus de 2 à 3 % et qu'une cellule solaire qui présente une conversion photoélectrique élevée, peut être obtenue.
PCT/JP2014/056888 2013-03-15 2014-03-14 Procédé de traitement de surface d'un substrat de silicium, procédé de production d'un dispositif à semi-conducteur, dispositif de production de semi-conducteurs, élément de transfert et procédé de production de ce dernier ainsi que cellule solaire et procédé de production d'une cellule solaire WO2014142304A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2015505598A JP6359519B2 (ja) 2013-03-15 2014-03-14 シリコン基板の表面処理方法、半導体装置の製造方法、半導体の製造装置、転写用部材およびその製造方法、太陽電池および太陽電池の製造方法

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2013-052641 2013-03-15
JP2013052641 2013-03-15
JP2013150280 2013-07-19
JP2013-150280 2013-07-19
JP2013-188124 2013-09-11
JP2013188124 2013-09-11

Publications (1)

Publication Number Publication Date
WO2014142304A1 true WO2014142304A1 (fr) 2014-09-18

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PCT/JP2014/056888 WO2014142304A1 (fr) 2013-03-15 2014-03-14 Procédé de traitement de surface d'un substrat de silicium, procédé de production d'un dispositif à semi-conducteur, dispositif de production de semi-conducteurs, élément de transfert et procédé de production de ce dernier ainsi que cellule solaire et procédé de production d'une cellule solaire

Country Status (3)

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JP (1) JP6359519B2 (fr)
TW (1) TW201501193A (fr)
WO (1) WO2014142304A1 (fr)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005183505A (ja) * 2003-12-17 2005-07-07 Kansai Tlo Kk 多孔質層付きシリコン基板を製造する方法
WO2011099594A1 (fr) * 2010-02-15 2011-08-18 Kobayashi Hikaru Procédé et dispositif permettant de fabriquer des dispositifs à semi-conducteur, dispositif à semi-conducteur et élément de transfert
WO2013024746A1 (fr) * 2011-08-12 2013-02-21 Kobayashi Hikaru Procédé de fabrication de dispositif à semi-conducteur, dispositif de fabrication de dispositif à semi-conducteur, dispositif à semi-conducteur, programme de fabrication de dispositif à semi-conducteur, agent de traitement pour semi-conducteur, et élément de transfert

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7776228B2 (en) * 2006-04-11 2010-08-17 Ebara Corporation Catalyst-aided chemical processing method
US8193095B2 (en) * 2010-05-28 2012-06-05 National Taiwan University Method for forming silicon trench
JP2013041864A (ja) * 2011-08-11 2013-02-28 Hikari Kobayashi 太陽電池及び半導体装置の製造方法、並びに転写用型版

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005183505A (ja) * 2003-12-17 2005-07-07 Kansai Tlo Kk 多孔質層付きシリコン基板を製造する方法
WO2011099594A1 (fr) * 2010-02-15 2011-08-18 Kobayashi Hikaru Procédé et dispositif permettant de fabriquer des dispositifs à semi-conducteur, dispositif à semi-conducteur et élément de transfert
WO2013024746A1 (fr) * 2011-08-12 2013-02-21 Kobayashi Hikaru Procédé de fabrication de dispositif à semi-conducteur, dispositif de fabrication de dispositif à semi-conducteur, dispositif à semi-conducteur, programme de fabrication de dispositif à semi-conducteur, agent de traitement pour semi-conducteur, et élément de transfert

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DAICHI IRISH IKA ET AL.: "Ultra-low Reflectivity Si Surfaces Fabricated by Surface Structure Chemical Transfer Method", <DAI 60 KAI> EXTENDED ABSTRACTS, JAPAN SOCIETY OF APPLIED PHYSICS AND RELATED SOCIETIES, vol. 30P-A4-5, 11 March 2013 (2013-03-11), pages 16 - 120 *
FRANCISCO FRANCO JR ET AL.: "Ultra-low reflectivity poly-crystalline Si surfaces fabricated by surface structure chemical transfer method", <DAI 60 KAI> EXTENDED ABSTRACTS, JAPAN SOCIETY OF APPLIED PHYSICS AND RELATED SOCIETIES, vol. 30P-A4-6, 11 March 2013 (2013-03-11), pages 16 - 121 *

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TW201501193A (zh) 2015-01-01
JPWO2014142304A1 (ja) 2017-02-16
JP6359519B2 (ja) 2018-07-18

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