WO2014134186A1 - Systèmes et dispositifs de stockage réversible d'énergie thermique à base d'un hydrure métallique, et procédé pour des applications haute température - Google Patents

Systèmes et dispositifs de stockage réversible d'énergie thermique à base d'un hydrure métallique, et procédé pour des applications haute température Download PDF

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Publication number
WO2014134186A1
WO2014134186A1 PCT/US2014/018723 US2014018723W WO2014134186A1 WO 2014134186 A1 WO2014134186 A1 WO 2014134186A1 US 2014018723 W US2014018723 W US 2014018723W WO 2014134186 A1 WO2014134186 A1 WO 2014134186A1
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WO
WIPO (PCT)
Prior art keywords
metal
metal hydride
reservoir
bed
heat
Prior art date
Application number
PCT/US2014/018723
Other languages
English (en)
Inventor
Ewa Carin Ellinor Ronnebro
Greg A. Whyatt
Michael R. Powell
Original Assignee
Battelle Memorial Institute
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Battelle Memorial Institute filed Critical Battelle Memorial Institute
Publication of WO2014134186A1 publication Critical patent/WO2014134186A1/fr

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/003—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using thermochemical reactions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0026—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14—Thermal energy storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

L'invention concerne des systèmes et des dispositifs d'extraction et de stockage d'énergie thermique haute température, et des procédés qui permettent de stocker de manière réversible de la chaleur haute température dans des lits d'hydrure métallique composés de métaux contenant du titane ou d'un alliage de métaux de transition qui forment des hydrures de manière réversible à hautes températures supérieures à environ 600°C et à basses températures inférieures ou égales à 100°C. L'invention permet d'obtenir une efficacité exergétique de 96% ou plus.
PCT/US2014/018723 2013-02-26 2014-02-26 Systèmes et dispositifs de stockage réversible d'énergie thermique à base d'un hydrure métallique, et procédé pour des applications haute température WO2014134186A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201361769628P 2013-02-26 2013-02-26
US61/769,628 2013-02-26
US14/189,942 US20140238634A1 (en) 2013-02-26 2014-02-25 Reversible metal hydride thermal energy storage systems, devices, and process for high temperature applications
US14/189,942 2014-02-25

Publications (1)

Publication Number Publication Date
WO2014134186A1 true WO2014134186A1 (fr) 2014-09-04

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2014/018723 WO2014134186A1 (fr) 2013-02-26 2014-02-26 Systèmes et dispositifs de stockage réversible d'énergie thermique à base d'un hydrure métallique, et procédé pour des applications haute température

Country Status (2)

Country Link
US (1) US20140238634A1 (fr)
WO (1) WO2014134186A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9777968B1 (en) * 2013-10-21 2017-10-03 Hrl Laboratories, Llc Metal hydride-based thermal energy storage systems
US10443954B1 (en) * 2014-12-05 2019-10-15 Savannah River Nuclear Solutions, Llc High performance metal hydride based thermal energy storage systems for concentrating solar power
WO2016210433A1 (fr) * 2015-06-26 2016-12-29 The Regents Of The University Of California Synthèse à haute température pour production et stockage d'énergie
JP6930405B2 (ja) * 2017-12-06 2021-09-01 株式会社豊田中央研究所 化学蓄熱反応器
CN109448799B (zh) * 2018-09-03 2021-11-09 岭东核电有限公司 金属冷却快堆金属燃料多物理场模型耦合方法
US11976235B2 (en) 2020-10-27 2024-05-07 Battelle Savannah River Alliance, Llc High temperature thermochemical energy storage materials
US11946700B2 (en) * 2022-02-16 2024-04-02 Rowe Holding Gmbh Heat storage system and method for storing and extracting heat

Citations (5)

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EP0220678A1 (fr) * 1985-10-28 1987-05-06 Energy Conversion Devices, Inc. Matériaux pour le stockage d'hydrogène utilisables dans des pompes à chaleur
US4995235A (en) * 1988-03-17 1991-02-26 Huit Gesellschaft Fur-Hydrid-Und Wasserstofftechnik M.B.H. Method and apparatus for compressing hydrogen gas
US5122338A (en) * 1989-04-14 1992-06-16 Wallace W Edward Hydrogen heat pump alloy combination
US5797269A (en) * 1996-02-23 1998-08-25 Sanyo Electric Co., Ltd. Hydrogen storage containers
EP1286406A2 (fr) * 2001-08-16 2003-02-26 Asia Pacific Fuel Cell Technologies, Ltd. Réservoir de stockage d'hydrure métallique et sa fabrication

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US4039023A (en) * 1976-02-25 1977-08-02 The United States Of America As Represented By The Secretary Of The Navy Method and apparatus for heat transfer, using metal hydrides
DE2715990A1 (de) * 1977-04-09 1978-10-12 Daimler Benz Ag Standheizung durch hydride in wasserstoff-fahrzeugen
US4200144A (en) * 1977-06-02 1980-04-29 Standard Oil Company (Indiana) Hydride heat pump
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US4449515A (en) * 1979-07-16 1984-05-22 Seige Corporation Apparatus for collecting, intensifying and storing solar energy
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EP0220678A1 (fr) * 1985-10-28 1987-05-06 Energy Conversion Devices, Inc. Matériaux pour le stockage d'hydrogène utilisables dans des pompes à chaleur
US4995235A (en) * 1988-03-17 1991-02-26 Huit Gesellschaft Fur-Hydrid-Und Wasserstofftechnik M.B.H. Method and apparatus for compressing hydrogen gas
US5122338A (en) * 1989-04-14 1992-06-16 Wallace W Edward Hydrogen heat pump alloy combination
US5797269A (en) * 1996-02-23 1998-08-25 Sanyo Electric Co., Ltd. Hydrogen storage containers
EP1286406A2 (fr) * 2001-08-16 2003-02-26 Asia Pacific Fuel Cell Technologies, Ltd. Réservoir de stockage d'hydrure métallique et sa fabrication

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