WO2014094519A1 - Intensificateur d'activation appliqué au ciment mélangé à une grande quantité de pierre calcaire - Google Patents
Intensificateur d'activation appliqué au ciment mélangé à une grande quantité de pierre calcaire Download PDFInfo
- Publication number
- WO2014094519A1 WO2014094519A1 PCT/CN2013/087569 CN2013087569W WO2014094519A1 WO 2014094519 A1 WO2014094519 A1 WO 2014094519A1 CN 2013087569 W CN2013087569 W CN 2013087569W WO 2014094519 A1 WO2014094519 A1 WO 2014094519A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cement
- activation enhancer
- limestone
- enhancer according
- lignin
- Prior art date
Links
- 239000004568 cement Substances 0.000 title claims abstract description 63
- 235000019738 Limestone Nutrition 0.000 title claims abstract description 48
- 239000006028 limestone Substances 0.000 title claims abstract description 48
- 230000004913 activation Effects 0.000 title claims abstract description 39
- 229920005610 lignin Polymers 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 150000002505 iron Chemical class 0.000 claims abstract description 14
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 8
- 239000003623 enhancer Substances 0.000 claims description 37
- 229920005862 polyol Polymers 0.000 claims description 36
- 150000003077 polyols Chemical class 0.000 claims description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 29
- 238000000855 fermentation Methods 0.000 claims description 14
- 230000004151 fermentation Effects 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 11
- 239000002921 fermentation waste Substances 0.000 claims description 11
- 239000002202 Polyethylene glycol Substances 0.000 claims description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 230000007935 neutral effect Effects 0.000 claims description 9
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 8
- 239000001913 cellulose Substances 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 8
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 102000004169 proteins and genes Human genes 0.000 claims description 8
- 108090000623 proteins and genes Proteins 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 6
- 240000008042 Zea mays Species 0.000 claims description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 5
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 235000005822 corn Nutrition 0.000 claims description 5
- 239000010902 straw Substances 0.000 claims description 5
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 4
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- 239000011790 ferrous sulphate Substances 0.000 claims description 3
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 3
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 claims 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims 1
- -1 alcohol amine Chemical class 0.000 abstract description 9
- 239000002002 slurry Substances 0.000 abstract description 3
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 239000002956 ash Substances 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002893 slag Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011083 cement mortar Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000010440 gypsum Substances 0.000 description 3
- 229910052602 gypsum Inorganic materials 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 206010016807 Fluid retention Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000923606 Schistes Species 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003416 augmentation Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- NVLRFXKSQQPKAD-UHFFFAOYSA-N tricarbon Chemical compound [C]=C=[C] NVLRFXKSQQPKAD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
Definitions
- the invention provides an activation enhancer applied to a large-volume limestone cement, comprising: an alcohol amine substance 5wt% ⁇ 8wt%;
- the herb fermentation residue is from 60 wt% to 70 wt% lignin, 15 wt% to 25 wt% cellulose, 2 wt% ⁇ 5wt% protein, 3wt% ⁇ 5wt% ash, the balance of water composition.
- the preparation method of the activation enhancer applied to the large-volume limestone cement is not particularly limited, and the alcohol amine-based substance, the herb lignin-based polyol, the aluminum salt, the iron salt and the water may be uniformly mixed.
- the herbage fermentation waste residue used in this embodiment is the remaining after the corn straw is fermented to produce ethanol.
- the residue consists of 65 wt% lignin, 22 wt% cellulose, 4 wt% protein, 4% ash, and the balance water.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
La présente invention concerne un intensificateur d'activation appliqué au ciment mélangé à une grande quantité de pierre calcaire, comprenant : de 5 à 8 % en poids de substance alcool amine, de 10 à 15 % en poids de polyalcool à base de lignine d'origine végétale, de 10 à 25 % en poids de sel d'aluminium, de 5 à 20 % en poids de sel de fer, et de 40 à 65 % en poids d'eau. L'intensificateur d'activation est produit à faible coût, et améliore la résistance du ciment une fois mélangé à une grande quantité de pierre calcaire ainsi que la résistance à la compression de la suspension à base de ciment durci.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210556294.7A CN103011658B (zh) | 2012-12-19 | 2012-12-19 | 应用于大掺量石灰石水泥的活化增强剂 |
CN201210556294.7 | 2012-12-19 |
Publications (1)
Publication Number | Publication Date |
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WO2014094519A1 true WO2014094519A1 (fr) | 2014-06-26 |
Family
ID=47960827
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2013/087569 WO2014094519A1 (fr) | 2012-12-19 | 2013-11-21 | Intensificateur d'activation appliqué au ciment mélangé à une grande quantité de pierre calcaire |
Country Status (2)
Country | Link |
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CN (1) | CN103011658B (fr) |
WO (1) | WO2014094519A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103011658B (zh) * | 2012-12-19 | 2014-07-02 | 山东宏艺科技股份有限公司 | 应用于大掺量石灰石水泥的活化增强剂 |
CN107572864B (zh) * | 2017-09-22 | 2020-06-19 | 右江民族医学院 | 一种透水性混凝土增强剂及制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101184702A (zh) * | 2005-06-02 | 2008-05-21 | 格雷斯公司 | 源自生物质的助磨剂 |
CN102050594A (zh) * | 2009-11-06 | 2011-05-11 | 山东宏艺科技股份有限公司 | 草本植物木质素型水泥助磨剂及其制备方法 |
CN102180616A (zh) * | 2011-05-04 | 2011-09-14 | 山东众森建材科技有限公司 | 一种大掺量石灰石复合水泥专用助磨剂及其制备方法 |
CN102372454A (zh) * | 2010-08-16 | 2012-03-14 | 广州基业长青化工有限公司 | 一种水泥助磨剂 |
CN102584078A (zh) * | 2012-03-13 | 2012-07-18 | 济南高新区工业废弃物利用研发中心 | 无氯低碱有机水泥助磨剂 |
CN103011658A (zh) * | 2012-12-19 | 2013-04-03 | 山东宏艺科技股份有限公司 | 应用于大掺量石灰石水泥的活化增强剂 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100990758B1 (ko) * | 2009-12-23 | 2010-10-29 | 주식회사 윈플로 | 고기능성이 부여된 시멘트 클링커 분쇄조제용 조성물 |
-
2012
- 2012-12-19 CN CN201210556294.7A patent/CN103011658B/zh active Active
-
2013
- 2013-11-21 WO PCT/CN2013/087569 patent/WO2014094519A1/fr active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101184702A (zh) * | 2005-06-02 | 2008-05-21 | 格雷斯公司 | 源自生物质的助磨剂 |
CN102050594A (zh) * | 2009-11-06 | 2011-05-11 | 山东宏艺科技股份有限公司 | 草本植物木质素型水泥助磨剂及其制备方法 |
CN102372454A (zh) * | 2010-08-16 | 2012-03-14 | 广州基业长青化工有限公司 | 一种水泥助磨剂 |
CN102180616A (zh) * | 2011-05-04 | 2011-09-14 | 山东众森建材科技有限公司 | 一种大掺量石灰石复合水泥专用助磨剂及其制备方法 |
CN102584078A (zh) * | 2012-03-13 | 2012-07-18 | 济南高新区工业废弃物利用研发中心 | 无氯低碱有机水泥助磨剂 |
CN103011658A (zh) * | 2012-12-19 | 2013-04-03 | 山东宏艺科技股份有限公司 | 应用于大掺量石灰石水泥的活化增强剂 |
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Publication number | Publication date |
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CN103011658B (zh) | 2014-07-02 |
CN103011658A (zh) | 2013-04-03 |
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