WO2014076105A8 - Verfahren zur beschichtung von metallischen oberflächen mit nanokristallinen zinkoxidschichten, wässerige zusammensetzungen hierfür und verwendung der derart beschichteten oberflächen - Google Patents

Verfahren zur beschichtung von metallischen oberflächen mit nanokristallinen zinkoxidschichten, wässerige zusammensetzungen hierfür und verwendung der derart beschichteten oberflächen Download PDF

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Publication number
WO2014076105A8
WO2014076105A8 PCT/EP2013/073668 EP2013073668W WO2014076105A8 WO 2014076105 A8 WO2014076105 A8 WO 2014076105A8 EP 2013073668 W EP2013073668 W EP 2013073668W WO 2014076105 A8 WO2014076105 A8 WO 2014076105A8
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WO
WIPO (PCT)
Prior art keywords
zinc oxide
way
oxide layers
aqueous compositions
nanocrystalline zinc
Prior art date
Application number
PCT/EP2013/073668
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English (en)
French (fr)
Other versions
WO2014076105A2 (de
WO2014076105A3 (de
Inventor
Özlem ÖZCAN
Guido Grundmeier
Peter Schubach
Original Assignee
Chemetall Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP13791796.9A priority Critical patent/EP2920108A2/de
Priority to RU2015123552A priority patent/RU2672754C2/ru
Priority to AU2013346860A priority patent/AU2013346860B2/en
Priority to US14/441,005 priority patent/US9970113B2/en
Priority to BR112015010909A priority patent/BR112015010909A2/pt
Priority to MX2015006127A priority patent/MX365287B/es
Application filed by Chemetall Gmbh filed Critical Chemetall Gmbh
Priority to CN201380070649.4A priority patent/CN105283412A/zh
Priority to CA2890827A priority patent/CA2890827A1/en
Publication of WO2014076105A2 publication Critical patent/WO2014076105A2/de
Publication of WO2014076105A8 publication Critical patent/WO2014076105A8/de
Publication of WO2014076105A3 publication Critical patent/WO2014076105A3/de
Priority to ZA2015/04445A priority patent/ZA201504445B/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125Process of deposition of the inorganic material
    • C23C18/1291Process of deposition of the inorganic material by heating of the substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82BNANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14Methods for preparing oxides or hydroxides in general
    • C01B13/18Methods for preparing oxides or hydroxides in general by thermal decomposition of compounds, e.g. of salts or hydroxides
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14Methods for preparing oxides or hydroxides in general
    • C01B13/34Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of sprayed or atomised solutions
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00Compounds of zinc
    • C01G9/02Oxides; Hydroxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • C09D5/106Anti-corrosive paints containing metal dust containing Zn
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/1208Oxides, e.g. ceramics
    • C23C18/1216Metal oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1225Deposition of multilayers of inorganic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1229Composition of the substrate
    • C23C18/1241Metallic substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/68Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/18Processes for applying liquids or other fluent materials performed by dipping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/002Pretreatement
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31652Of asbestos
    • Y10T428/31663As siloxane, silicone or silane

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Nanotechnology (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zum Beschichten von metallischen Oberflächen mit einer wässerigen Zusammensetzung, die eine wässerige Lösung eines Zink-Salzes enthält, durch Fluten, Spritzen oder/und Tauchen, dadurch gekennzeichnet, dass die anfängliche Substrattemperatur beim Spritzen oder Tauchen im Bereich von 5 bis 400 °C liegt, dass die anfängliche Substrattemperatur beim Fluten im Bereich von 100 bis 400 °C liegt und dass auf der metallischen Oberfläche eine korrosionsschützende nanokristalline Zinkoxidschicht ausgebildet wird. Die Erfindung betrifft auch die entsprechende wässerige Zusammensetzung, die nanokristalline Zinkoxidschicht und die Verwendung der beschichteten Substrate.
PCT/EP2013/073668 2012-11-19 2013-11-13 Verfahren zur beschichtung von metallischen oberflächen mit nanokristallinen zinkoxidschichten, wässerige zusammensetzungen hierfür und verwendung der derart beschichteten oberflächen WO2014076105A2 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
RU2015123552A RU2672754C2 (ru) 2012-11-19 2013-11-13 Способ нанесения покрытий на металлические поверхности при помощи нанокристаллических слоев оксида цинка, водная композиция для этого и применение поверхностей с нанесенными таким образом покрытиями
AU2013346860A AU2013346860B2 (en) 2012-11-19 2013-11-13 Method for coating metallic surfaces with nanocrystalline zinc oxide layers, aqueous compositions therefor and use of the surfaces coated in this way
US14/441,005 US9970113B2 (en) 2012-11-19 2013-11-13 Method for coating metallic surfaces with nanocrystalline zinc oxide layers, aqueous compositions therefor and use of the surfaces coated in this way
BR112015010909A BR112015010909A2 (pt) 2012-11-19 2013-11-13 processo para revestir superfícies metálicas com camadas de óxido de zinco nanocristalinas, composições aquosas para esse fim e uso das superfícies revestidas dessa maneira
MX2015006127A MX365287B (es) 2012-11-19 2013-11-13 Un método para recubrir superficies metálicas de un sustrato con una capa de óxido de zinc nanocristalino resistente a la corrosión.
EP13791796.9A EP2920108A2 (de) 2012-11-19 2013-11-13 Verfahren zur beschichtung von metallischen oberflächen mit nanokristallinen zinkoxidschichten, wässerige zusammensetzungen hierfür und verwendung der derart beschichteten oberflächen
CN201380070649.4A CN105283412A (zh) 2012-11-19 2013-11-13 用纳米晶氧化锌层涂布金属表面的方法、用于此目的的含水组合物以及这类涂布表面的用途
CA2890827A CA2890827A1 (en) 2012-11-19 2013-11-13 Method for coating metallic surfaces with nanocrystalline zinc oxide layers, aqueous compositions for same and use of such coated surfaces
ZA2015/04445A ZA201504445B (en) 2012-11-19 2015-06-19 Method for coating metallic surfaces with nanocrystalline zinc oxide layers, aqueous compositions therefor and use of the surfaces coated in this way

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012221106.3 2012-11-19
DE102012221106 2012-11-19

Publications (3)

Publication Number Publication Date
WO2014076105A2 WO2014076105A2 (de) 2014-05-22
WO2014076105A8 true WO2014076105A8 (de) 2014-07-24
WO2014076105A3 WO2014076105A3 (de) 2014-09-12

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PCT/EP2013/073668 WO2014076105A2 (de) 2012-11-19 2013-11-13 Verfahren zur beschichtung von metallischen oberflächen mit nanokristallinen zinkoxidschichten, wässerige zusammensetzungen hierfür und verwendung der derart beschichteten oberflächen

Country Status (12)

Country Link
US (1) US9970113B2 (de)
EP (1) EP2920108A2 (de)
KR (1) KR20150085071A (de)
CN (1) CN105283412A (de)
AU (1) AU2013346860B2 (de)
BR (1) BR112015010909A2 (de)
CA (1) CA2890827A1 (de)
DE (1) DE102013223048A1 (de)
MX (1) MX365287B (de)
RU (1) RU2672754C2 (de)
WO (1) WO2014076105A2 (de)
ZA (1) ZA201504445B (de)

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CN107586493A (zh) * 2016-07-06 2018-01-16 赫普有限公司 水基底漆组合物、由其获得的底漆及含该底漆的双层体系
EP3814132A4 (de) * 2018-06-28 2022-03-23 Nelumbo Inc. Gleichzeitige oberflächenmodifikationen und verfahren zur herstellung davon
US20220372626A1 (en) * 2019-09-26 2022-11-24 Nof Metal Coatings Asia Pacific Co., Ltd. Rust-proofing treatment method, and rust-proofing-treated article
CN111996521B (zh) * 2020-08-26 2021-05-18 西南交通大学 一种在生物可降解锌表面构建无机微米花嵌合金属-有机复合纳米簇改性功能层的方法
CN114182238B (zh) * 2020-09-14 2023-06-23 天津大学 一种阻变型ZnO耐蚀薄膜及其制备方法
CN113455519A (zh) * 2021-08-17 2021-10-01 福州市帕柯斯新材料有限公司 一种高浓缩安全环保长效消毒液及其制备方法
CN114985005B (zh) * 2022-07-06 2023-11-21 华东理工大学 改性纤维素纳米晶、负载型金属催化剂及其制备方法和应用

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Publication number Publication date
CN105283412A (zh) 2016-01-27
US9970113B2 (en) 2018-05-15
MX365287B (es) 2019-05-29
WO2014076105A2 (de) 2014-05-22
US20150284854A1 (en) 2015-10-08
CA2890827A1 (en) 2014-05-22
ZA201504445B (en) 2018-05-30
DE102013223048A1 (de) 2014-05-22
WO2014076105A3 (de) 2014-09-12
BR112015010909A2 (pt) 2017-07-11
MX2015006127A (es) 2015-08-05
RU2015123552A (ru) 2017-01-10
EP2920108A2 (de) 2015-09-23
AU2013346860B2 (en) 2017-07-27
RU2672754C2 (ru) 2018-11-19
AU2013346860A1 (en) 2015-06-11
KR20150085071A (ko) 2015-07-22

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