WO2014024782A3 - グリセリンからアクリル酸を製造するための触媒とその製造方法 - Google Patents

グリセリンからアクリル酸を製造するための触媒とその製造方法 Download PDF

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Publication number
WO2014024782A3
WO2014024782A3 PCT/JP2013/070946 JP2013070946W WO2014024782A3 WO 2014024782 A3 WO2014024782 A3 WO 2014024782A3 JP 2013070946 W JP2013070946 W JP 2013070946W WO 2014024782 A3 WO2014024782 A3 WO 2014024782A3
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WO
WIPO (PCT)
Prior art keywords
catalyst
glycerin
acrylic acid
producing
production
Prior art date
Application number
PCT/JP2013/070946
Other languages
English (en)
French (fr)
Other versions
WO2014024782A2 (ja
Inventor
渉 上田
香織 小俣
康志 小林
良太 平岡
公人 奥村
Original Assignee
日本化薬株式会社
国立大学法人北海道大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日本化薬株式会社, 国立大学法人北海道大学 filed Critical 日本化薬株式会社
Publication of WO2014024782A2 publication Critical patent/WO2014024782A2/ja
Publication of WO2014024782A3 publication Critical patent/WO2014024782A3/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

【課題】　グリセリンからアクリル酸を一段反応により高収率で製造することができる、少なくともタングステン、バナジウム、ニオブおよび酸素で構成される複合金属酸化物触媒と、その製造方法を提供する。また当該発明の触媒を用いたグリセリンからアクリル酸の製造方法を提供する。 【解決手段】　グリセリンからアクリル酸を製造するために使用する、少なくともタングステン、バナジウム、ニオブおよび酸素で構成される複合金属酸化物触媒。少なくともタングステン、ニオブ及びバナジウムを有する化合物を水と混合して得られた混合液を、水熱合成によって固形分を得て、該固形分を焼成することを特徴とする当該発明の複合金属酸化物触媒の製造方法と、その触媒を用いたグリセリンからアクリル酸の製造方法の提供。
PCT/JP2013/070946 2012-08-10 2013-08-01 グリセリンからアクリル酸を製造するための触媒とその製造方法 WO2014024782A2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012-178048 2012-08-10
JP2012178048A JP2014034023A (ja) 2012-08-10 2012-08-10 グリセリンからアクリル酸を製造するための触媒とその製造方法

Publications (2)

Publication Number Publication Date
WO2014024782A2 WO2014024782A2 (ja) 2014-02-13
WO2014024782A3 true WO2014024782A3 (ja) 2014-11-27

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PCT/JP2013/070946 WO2014024782A2 (ja) 2012-08-10 2013-08-01 グリセリンからアクリル酸を製造するための触媒とその製造方法

Country Status (2)

Country Link
JP (1) JP2014034023A (ja)
WO (1) WO2014024782A2 (ja)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101616528B1 (ko) * 2013-07-16 2016-04-28 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
CN116621222B (zh) * 2023-07-24 2023-12-12 南方电网数字电网研究院有限公司 钨钒掺杂铌氧化物的制备方法、钨钒掺杂铌基材料及应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000143244A (ja) * 1998-07-24 2000-05-23 Mitsubishi Chemicals Corp 複合金属酸化物の製造方法
JP2010538050A (ja) * 2007-09-06 2010-12-09 アルケマ フランス グリセロールの反応性蒸発方法
JP2011120990A (ja) * 2009-12-09 2011-06-23 Asahi Kasei Chemicals Corp 複合金属酸化物触媒及びその製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000143244A (ja) * 1998-07-24 2000-05-23 Mitsubishi Chemicals Corp 複合金属酸化物の製造方法
JP2010538050A (ja) * 2007-09-06 2010-12-09 アルケマ フランス グリセロールの反応性蒸発方法
JP2011120990A (ja) * 2009-12-09 2011-06-23 Asahi Kasei Chemicals Corp 複合金属酸化物触媒及びその製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ALESSANDRO CHIEREGATO ET AL.: "Glycerol oxidehydration into acrolein and acrylic acid over W-V-Nb-O bronzes with hexagonal structure", CATALYSIS TODAY, vol. 197, 25 July 2012 (2012-07-25), pages 58 - 65, Retrieved from the Internet <URL:http://www.sciencedirect.com/science/article/pii/5092058611200466X> *

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Publication number Publication date
JP2014034023A (ja) 2014-02-24
WO2014024782A2 (ja) 2014-02-13

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