WO2014013120A1 - Composition détergente se présentant sous forme de pastilles effervescentes - Google Patents

Composition détergente se présentant sous forme de pastilles effervescentes Download PDF

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Publication number
WO2014013120A1
WO2014013120A1 PCT/ES2013/070509 ES2013070509W WO2014013120A1 WO 2014013120 A1 WO2014013120 A1 WO 2014013120A1 ES 2013070509 W ES2013070509 W ES 2013070509W WO 2014013120 A1 WO2014013120 A1 WO 2014013120A1
Authority
WO
WIPO (PCT)
Prior art keywords
detergent composition
detergent
composition according
tablet
composition
Prior art date
Application number
PCT/ES2013/070509
Other languages
English (en)
Spanish (es)
Inventor
Ismael DOMINGO REVELLES
Original Assignee
Proeco Quimicas, S.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Proeco Quimicas, S.L. filed Critical Proeco Quimicas, S.L.
Publication of WO2014013120A1 publication Critical patent/WO2014013120A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0052—Gas evolving or heat producing compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • the present invention relates to a universal cleansing detergent composition in the form of an effervescent tablet for dissolving in the wash water, easily transportable and storable and fast acting.
  • the present invention also relates to the use of said composition for cleaning various surfaces, such as hard surfaces such as floors, walls, glass, work surfaces, ceramics, synthetic, natural, porcelain, metal surfaces, plastic surfaces, surfaces of appliances or sanitary ware, etc., or any kind of soft surfaces such as fabrics.
  • the present invention also relates to the use of the detergent composition object of the present invention for the manufacture of effervescent tablets useful for use in immediate disintegration detergent compositions in contact with an aqueous solution.
  • the universal cleaners sector has evolved towards a considerable reduction in sales prices. This price reduction has been gradually affecting the quality of the product, producing an inverse curve in terms of quality / price ratio.
  • detergent compositions in the form of tablets have been developed in the state of the art, taking into account that they have several advantages over detergent compositions in liquid form, such as ease of use and handling, convenient dosing and ease Transport and storage and product stability and packaging savings.
  • the tablets are compact therefore use little packaging, compared to the amount of conditioned detergent product. Logistics and storage become less expensive, and for the consumer the use is easier since it is enough, for cleaning a given surface, to dissolve a tablet in a given amount of water.
  • the dosage is therefore simple and reproducible from one cleaning operation to another.
  • said tablets are generally packaged individually, or two by two, in individual sachets that make them insensitive to moisture during prolonged storage periods, since they do not run the risk of hardening, or on the contrary of break up.
  • active but chemically unstable components may be available, which are created and released only at the time of use of the cleaner. It can be a bleaching agent or biocide, for example nascent oxygen, peroxides, for example hydrogen peroxide. This involves using in the compressed two compounds that react chemically at the time of dissolution of the tablet in water, to create at least one new active compound.
  • detergents in tablets have not achieved an introduction in the market of universal detergents, despite the multiple advantages they present, especially in terms of their comfort of use: They dose easily, take up little and it is easy to know how many doses are left.
  • One of the requirements for formulating a tablet detergent is that it quickly disintegrates upon contact with the wash water.
  • tablette means any tablet or tablet obtained by a compression process.
  • a detergent tablet of the type called "universal” is understood as that which can be used for several different domestic or industrial tasks. These domestic tasks include, by way of illustration, not limitation, the cleaning of hard surfaces such as floors or work surfaces, or even the cleaning of dishes. The cleaning of the laundry can also be provided, depending on the compounds used in the tablet and its concentration.
  • “useful matter” means the materials involved in the preparations both with cleaning functions, such as active agents, and with organoleptic functions (perfumes and dyes).
  • composition object of the present invention leaves only what is useful for the purpose of the product achieving an optimal price-quality ratio.
  • the detergent tablet or tablet composition of the invention manages to provide a detergent format for dissolving in easily transportable and clean water, without degradation of its components over time, and occupying a significantly smaller volume compared to a concentrated liquid detergent, since a tablet according to the composition of the invention of about 10 grams is equivalent to a can of 750 cubic centimeters of liquid detergent. That is, in the space occupied by the liquid detergent canister, there are about seven tablets achieved with the composition of the invention.
  • The% of useful matter contained in the formulations is at least 95%, preferably greater than 96%. All the materials involved in the preparations have cleaning functions or give the product necessary organoleptic properties; unlike liquid counterparts, which have a very high percentage in water.
  • the detergent composition of the present invention comprises at least% of the following components by weight, so that the individual values of the percentages of the different components of the composition are such that the total composition never exceeds 100%:
  • the detergent composition of the present invention further comprises between 15% and 35% alkyl benzene sulfonate.
  • the composition containing alkyl benzene sulphonate is used in formulations for general cleaning, for glass cleaning, for floor cleaning and for degreasing formulations.
  • the detergent composition of the present invention additionally comprises between 15% and 30% sulfamic acid.
  • the sulfamic acid-containing composition is used in formulations for cleaning bathrooms and toilets.
  • the detergent composition of the present invention additionally comprises between 15% and 30% of an alkali, for example calcium hydroxide or the like.
  • the composition containing the alkali is used in formulations for degreasers.
  • the individual values of the percentages of the different components are such that the total composition never exceeds 100%.
  • Hydrogen carbonate as an effervescent vehicle upon contact with water, produces the perfect dissolution of the detergent in the entire volume of water immediately.
  • composition of the invention also includes the optional inclusion of the necessary amount of this component, typically an amount between 0.1% and 1% by weight on the total composition and / or perfume in an amount between 5% and 10% by weight on the total composition.
  • the different raw materials have been selected in solid and water-free form with a 100% concentration, perfumes in solid form and dyes have also been selected to give the organoleptic properties necessary for each use. .
  • the premix premix is combined with sodium hydrogencarbonate and acidulant (citric acid), which once dissolved becomes a potent stain remover and excellent natural sequestrant. All this mixing is carried out in a band mixer or vertical mixer until the mixture is equitable. Once mixed, it is passed through a mill to achieve a granulometric tuning of the product, which is subsequently passed through the mixer to achieve a completely homogeneous final mixture.
  • citric acid acidulant
  • a premix of at least dye, perfume, alkyl benzene or sulfamic acid sulfonate and ethoxylated alcohol is combined with sodium hydrogen carbonate and citric acid, which once dissolved becomes a potent stain remover and excellent natural sequestrant.
  • Citric acid between 1 5% and 20%
  • the method of use for this composition is to place a tablet in a spray bottle with 750 ce of water. Wait for the dissolution of the tablet and ready to use. Product with high cleaning power for surfaces where a neutral pH is required and vigorous cleaning is required.
  • the method of use for this composition is to place a tablet in a spray bottle with 750 ce of water. Wait for the dissolution of the tablet and you are ready to use. Spray on the surface at a rate of 0.5 ce per m 2 , wipe a clean dry cloth, preferably micro fiber.
  • Citric acid between 5% and 20%
  • This composition is to place a tablet in the mop bucket, fill with water.
  • the estimated dissolution time is similar to that of water filling.
  • the method of use for this composition is to place a tablet in a spray bottle with 750cc of water. Wait for the dissolution of the tablet and you are ready to use. Spray on the surface to be cleaned according to type of dirt. It has anti-calcareous properties and great cleaning power. Does not stain or spoil surfaces whether marble, chrome or stainless.
  • Citric acid between 5% and 15%
  • the present invention relates to a detergent tablet containing at least 95% of useful matter characterized in that it comprises at least% of the following components by weight, so that the individual values of the percentages of the different Composition components are such that the total composition never exceeds 100%:
  • the detergent composition of the present invention further comprises between 15% and 35% alkyl benzene sulfonate.
  • the composition containing alkyl benzene sulphonate is used in formulations for general cleaning, for glass cleaning, for floor cleaning and for degreasing formulations.
  • the detergent composition of the present invention additionally comprises between 15% and 30% sulfamic acid.
  • the sulfamic acid-containing composition is used in formulations for cleaning bathrooms and toilets.
  • the detergent composition of the present invention additionally comprises between 15% and 30% of an alkali, for example calcium hydroxide.
  • the alkali-containing composition is used in formulations for degreasers.
  • the individual values of the percentages of the different components are such that the total composition never exceeds 100%.
  • the detergent tablet of the present invention is effervescent.
  • the detergent tablet of the present invention contains more than 95% of useful matter.
  • the detergent composition of the present invention comprises an effervescent or disintegrating system that allows a controlled and accelerated dissolution of the tablet in the presence of water and which makes it possible to accentuate the dissolution and mixing of the compounds at the time of use.
  • the detergent tablet of the present invention is presented in single dose or single dose format or may be grouped in tubs.
  • the conditioning of the detergent tablets according to the invention is carried out by wrapping the tablets individually or in groups, in suitable containers for this use.
  • the mono doses are wrapped in a heat-sealable film, which constitutes a moisture barrier.
  • the packaging is done by known automated bagging techniques for any person skilled in the art.
  • the bags are made in a heat-sealable plastic film that has moisture barrier properties. This allows to prevent the tablets from disintegrating or on the contrary hardening by absorbing the water contained in the air during storage.
  • composition object of the present invention comprises at least 95% of useful matter, composed of anionic surfactants, non-ionic surfactants, alkalis, acids or adjuvants, compared to between 4% and 10% of useful matter that conventional cleaners can carry.
  • the detergent composition object of the present invention is in the form of self-soluble effervescent tablets, with the concentration and weight suitable for each use in such a way that the consumer only has to put a tablet of just 5 to 20 grams gr. in a mop bucket or in a spray bottle for use.
  • the detergent tablet of the present invention is used for both the domestic and industrial sectors.
  • the detergent is selected from the group consisting of scrubbers, brighteners, disinfectants, descalers, air fresheners, grease removers, particularly for ceramic, synthetic, natural, stoneware, parquet, metal, wood, ceramic hobs, glass and / or crystal

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne une composition détergente se présentant sous forme de pastilles effervescentes qui contiennent au moins 95% de matière utile, sont utilisées pour tout type de tâches liées à la propreté en général particulièrement pour des surfaces en céramique, synthétiques, naturelles, en grès, en parquet, en métal, en bois, les plaques en vitrocéramique, le verre et/ou le cristal entre autres. La présente invention concerne également l'utilisation des pastilles détergentes effervescentes en tant que détergents à désagrégation immédiate lorsqu'elles sont en contact avec une solution aqueuse.
PCT/ES2013/070509 2012-07-20 2013-07-16 Composition détergente se présentant sous forme de pastilles effervescentes WO2014013120A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES201231154A ES2443767B1 (es) 2012-07-20 2012-07-20 Composición detergente en forma de comprimido efervescente
ESP201231154 2012-07-20

Publications (1)

Publication Number Publication Date
WO2014013120A1 true WO2014013120A1 (fr) 2014-01-23

Family

ID=49948335

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/ES2013/070509 WO2014013120A1 (fr) 2012-07-20 2013-07-16 Composition détergente se présentant sous forme de pastilles effervescentes

Country Status (2)

Country Link
ES (1) ES2443767B1 (fr)
WO (1) WO2014013120A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016038449A1 (fr) 2014-09-09 2016-03-17 Graff Pehrson Vesterager Gmbh Composition détergente à teneur alcaline élevée

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2040307A1 (fr) * 1991-04-12 1992-10-13 Yogesh Sennik Comprimes de detergent efferverscent
EP1137753A2 (fr) * 1998-12-07 2001-10-04 Henkel Kommanditgesellschaft auf Aktien Detergent a action intrinseque
WO2003064579A1 (fr) * 2002-01-31 2003-08-07 Givaudan Sa Composition effervescente a base de granules
WO2004027003A1 (fr) * 2002-09-19 2004-04-01 Unilever Plc Compositions de detergent
CN101914415A (zh) * 2010-08-27 2010-12-15 郭俊华 一种泡腾洗涤剂及其制备方法
ES2379917A1 (es) * 2010-10-06 2012-05-07 Jordi Caparros Casco Composiciones detergentes.

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2040307A1 (fr) * 1991-04-12 1992-10-13 Yogesh Sennik Comprimes de detergent efferverscent
EP1137753A2 (fr) * 1998-12-07 2001-10-04 Henkel Kommanditgesellschaft auf Aktien Detergent a action intrinseque
WO2003064579A1 (fr) * 2002-01-31 2003-08-07 Givaudan Sa Composition effervescente a base de granules
WO2004027003A1 (fr) * 2002-09-19 2004-04-01 Unilever Plc Compositions de detergent
CN101914415A (zh) * 2010-08-27 2010-12-15 郭俊华 一种泡腾洗涤剂及其制备方法
ES2379917A1 (es) * 2010-10-06 2012-05-07 Jordi Caparros Casco Composiciones detergentes.

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016038449A1 (fr) 2014-09-09 2016-03-17 Graff Pehrson Vesterager Gmbh Composition détergente à teneur alcaline élevée
US10836982B2 (en) 2014-09-09 2020-11-17 Graff Pehrson Vesterager Gmbh Highly alkaline detergent composition

Also Published As

Publication number Publication date
ES2443767A1 (es) 2014-02-20
ES2443767B1 (es) 2014-11-26

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