WO2013179223A2 - Module solaire à installer sur une pièce moulée en béton - Google Patents

Module solaire à installer sur une pièce moulée en béton Download PDF

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Publication number
WO2013179223A2
WO2013179223A2 PCT/IB2013/054404 IB2013054404W WO2013179223A2 WO 2013179223 A2 WO2013179223 A2 WO 2013179223A2 IB 2013054404 W IB2013054404 W IB 2013054404W WO 2013179223 A2 WO2013179223 A2 WO 2013179223A2
Authority
WO
WIPO (PCT)
Prior art keywords
solar module
connecting means
layer
designed
module according
Prior art date
Application number
PCT/IB2013/054404
Other languages
German (de)
English (en)
Other versions
WO2013179223A3 (fr
Inventor
Piotr DUDEK
Martin Pfeiffer
Aron GUTOWSKI
Karsten Walzer
Eginhard Wollrab
Jörg SMOLINSKI
Peter Henning
Bernd Burkhard Dr. TROMPETER
Original Assignee
Heliatek Gmbh
Reckli Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Heliatek Gmbh, Reckli Gmbh filed Critical Heliatek Gmbh
Publication of WO2013179223A2 publication Critical patent/WO2013179223A2/fr
Publication of WO2013179223A3 publication Critical patent/WO2013179223A3/fr

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80Constructional details
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K39/00Integrated devices, or assemblies of multiple devices, comprising at least one organic radiation-sensitive element covered by group H10K30/00
    • H10K39/10Organic photovoltaic [PV] modules; Arrays of single organic PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the invention relates to a solar module for arrangement on moldings made of concrete and moldings made of concrete containing a solar module.
  • Photoactive components such as solar cells
  • Photovoltaic elements are now widely used in both everyday and industrial environments. Of particular interest is the integration of photovoltaic elements in buildings
  • Solar modules characterized on silicon-based which are usually formed in a plate shape.
  • the arrangement of building surfaces is usually about
  • Stand systems on roofs or curtain systems on walls are characterized in particular by their structurally complex structure and by the overall high weight.
  • corresponding plate-shaped modules must also have a provide sufficient protection of the modules against falling, since the plate-shaped modules due to the
  • silicon-based modules require a south orientation and, if necessary, a 30 ° mounting angle for optimum efficiency, to ensure optimal solar radiation.
  • silicon-based photovoltaic modules suffer from power losses due to increased temperature in the modules due to exposure to direct sunlight
  • plate-shaped modules offer about thin-film solar cells with flexible design.
  • thin-film solar cells which have a flexible configuration and thus allow an arrangement on curved surfaces.
  • Such Solar cells preferably have active layers of amorphous silicon (-Si) or CIGS (Cu (In, Ga) (S, Se) 2).
  • the organic active layers may be composed of polymers (e.g., U.S. Patent No. 7,725,326 B2) or small molecules (e.g., EP 2385556 A1). While polymers are characterized by the fact that they can not be vaporized and therefore can only be applied from solutions, small molecules can be vaporized.
  • organic-based devices over conventional inorganic-based devices (semiconductors such as silicon, gallium arsenide) is the sometimes extremely high optical absorption coefficients (up to 2 ⁇ 10 5 cm -1 ), which offers the possibility of low material and material costs Energy expenditure to produce very thin solar cells. Further technological aspects are the low cost, the possibility of producing flexible large-area components on plastic films, and the almost unlimited possibilities of variation and the unlimited availability of organic chemistry. Another advantage is the possibility of transparent components
  • a solar cell converts light energy into electrical energy.
  • the term photoactive also refers to the conversion of light energy into electrical energy. in the
  • organic Solar cells by the light does not directly generate free charge carriers, but it formed at first excitons, ie electrically neutral excitation states (bound electron-hole pairs). Only in a second step, these excitons are separated into free charge carriers, which then contribute to the electric current flow.
  • n or p denotes an n- or p-type doping, which leads to an increase in the density of free electrons or holes in the thermal equilibrium state.
  • the n-type layer (s) or p-type layer (s) are at least partially nominally undoped and only due to the material properties (e.g.
  • i-layer designates a nominally undoped layer (intrinsic layer).
  • One or more i-layers may in this case be layers of a material as well as a mixture of two materials (so-called interpenetrating networks or bulk heterojunction, M. Hiramoto et al., Mol., Cryst., Liq., Cryst., 2006, 444). pp. 33-40).
  • the light incident through the transparent base contact generates excitons (bound electron-hole pairs) in the i-layer or in the n- / p-layer. These excitons can only be separated by very high electric fields or at suitable interfaces. Stand in organic solar cells
  • the separating interface may be between the p (n) layer and the i-layer or between two i-layers.
  • the electrons are now transported to the n-area and the holes to the p-area.
  • the transport layers are transparent or
  • Thin films certainly fulfill this criterion.
  • the use of monocrystalline organic materials is not possible and the production of multiple layers with sufficient structural perfection is still very difficult.
  • JP 2011-109051A discloses the arrangement of a
  • EP 1191605 A2 describes a glassless, flexible
  • Solar laminate for use in building technology, wherein the solar cells are applied under pressure and temperature (about 130 ° C) on a steel sheet and then attached by a rear-side adhesive layer on building exterior surfaces.
  • WO20120303971 describes a flexible one Thin layer solar cell module based on CIGS (Copper indium gallium diselenide) with several layers
  • the module has on its back an adhesive layer for placement on building exterior surfaces.
  • the object of the present invention is therefore to provide a solar module, which overcomes the disadvantages of the prior art.
  • the object is achieved by a solar module according to
  • a flexible solar module According to the invention, a flexible solar module
  • Substrate is arranged and a first and a second
  • At least one photoactive layer is arranged, which contains at least one organic material.
  • the solar module has on the photoactive component ⁇ opposite side connecting means for arrangement on the surface of a molded part made of concrete.
  • a molded part is understood to mean a three-dimensional object which, in combination with further molded parts, forms a structural unit.
  • the molded part has a non-planar surface design.
  • the Surface of the molding can be curved, wavy, curved, etc. Due to the flexible design of the solar module while an arrangement on the non-planar surface is possible.
  • the solar module is characterized in that it is light in the range of 0.5 to 1.5 kg per square meter (compared to 10 to 15 kg per square meter in conventional PV modules), which is why elaborate structures for mounting on omitted the molding or fall protection.
  • the flexible design and the low weight allow a faster, more efficient and less expensive installation to be realized.
  • the solar module is designed to be heat-insulating by means of reflective back contact. Due to the reflective back contact, the light radiated into the solar module is reflected, which is why there is no heating of the surface of the molded part, as would normally be done with solar radiation. As a result, unwanted warming or heating of the molded concrete is prevented. This is particularly advantageous if such solar modules are arranged on the surface of buildings and a heating of the building envelope is omitted.
  • Connecting means configured so that the substrate is designed as a connecting means.
  • the substrate which is designed as a connecting means, for example, directly on the surface of the molded part by means of casting, melting, gluing, pressing, etc. are integrated.
  • the connecting means is designed so that the solar module is detachably arranged on the molded part. This results in considerable advantages when maintenance or replacement of the solar module is necessary. A change of the solar module can thus be realized in a simple manner without
  • the connecting means is designed in two parts, wherein the first part of the connecting means at the
  • the second part of the connecting means is integrated into the surface of the molded part.
  • the connecting means comprises a multilayer coating system, comprising at least one adhesion layer for arranging the solar module to the molded part and at least one
  • the adhesion layer which may be embodied, for example, as an adhesive layer, serves to arrange the solar module on the molded body.
  • the at least one intermediate layer which lies between the
  • Adhesion layer and the solar module is arranged is designed so that these strains and possible cracking movements on the molding due to the own modulus of elasticity can reduce or prevent. This can be long term
  • Concrete moldings in the construction sector may vary due to the time of year
  • an intermediate layer of a material of elasticity modulus is sufficiently small in order to prevent the influence of the. Due to its own elasticity
  • Such materials may be, for example, textile woven, knitted or knitted fabrics, glass fiber fleece, carbon fiber, Composite materials, such as carbon fiber reinforced
  • Adhesion layer designed as an adhesive layer. As a result, a cohesive connection between the solar module and the molded body is realized.
  • the connecting means is designed such that the adhesion
  • connecting means and molded part is greater than the adhesion between the connecting means and the solar module.
  • the contacting of the solar module is integrated in the connecting means, so that when removing the module, the contact is removed and subsequent use of the solar module is no longer possible.
  • the solar module is designed such that the adhesion between
  • Connecting agent and substrate is greater than the adhesion between the substrate and photoactive device.
  • a theft protection is realized by that when removing the solar module from the molding due to the higher adhesion between the substrate and bonding agent over the adhesion between the substrate and photoactive device, the substrate remains on the molding while the photoactive device is detached from the substrate. This destroys the module on removal and will not be available for future use.
  • the substrate is composed of at least two layers, wherein the adhesion between these at least two layers is less than the adhesion between substrate and molding and the adhesion between substrate and photoactive
  • the solar module has a contact, which at least one
  • a contact in the form of a busbar is arranged between two photoactive components on the substrate.
  • the busbar is meandering. It is also conceivable a meandering bus bar on one
  • the invention is also the use of a Solar module according to the invention arrangement on concrete.
  • a Solar module according to the invention arrangement on concrete.
  • various functions can be realized in the field of construction industry or building integration.
  • the design of the solar module in addition to the power generation and a thermal insulation,
  • the flexible solar module as part of a
  • finishing systems for concrete surfaces based on epoxy resin and polyurethane are known.
  • the module can be used during processing of the
  • the solar module is integrated during the production of the concrete molding in this
  • the substrate is designed as a tape-shaped or film-shaped substrate. In one embodiment of this embodiment, the substrate is a metal band. In an alternative embodiment of this
  • the substrate is designed as a film-shaped substrate.
  • the film-shaped substrate is preferably made of a thermoplastic polymer selected from a group consisting of acrylonitrile-butadiene-styrene (ABS), polyamides (PA), polylactate (PLA), polymethyl methacrylate
  • PMMA polycarbonate
  • PC polyethylene terephthalate
  • PET polyethylene
  • PE polypropylene
  • PP polyvinylidene fluoride
  • PVDF polyvinyl fluoride
  • PS polystyrene
  • PEEK polyetheretherketone
  • PVC polyvinyl chloride
  • At least one organic layer of at least one organic material which is arranged between the electrode and the counterelectrode, is used in the photoactive component.
  • the photoactive layer comprises at least one organic material.
  • the active layer comprises at least one mixed layer having at least two main materials, these forming an active donor-acceptor system.
  • At least one main material is an organic material.
  • the organic material is a small molecule.
  • small molecules is understood to mean monomers which evaporate and thus on the Substrate can be deposited.
  • the organic material is at least partially polymers.
  • at least one photoactive i-layer is formed from small molecules.
  • At least one of the active mixed layers comprises as acceptor a material from the group of fullerenes or
  • At least one of the electrode and the counterelectrode is provided
  • Transport layer arranged.
  • the photoactive component is an organic solar cell.
  • the component is a pin single, pin tandem cell, pin multiple cell, nip single cell, nip tandem cell or nip multiple cell.
  • the component consists of a combination of nip, ni, ip, pnip, pni, pip, nipn, nin, ipn, pnipn, pnin or pipn structures, in which a plurality of independent combinations comprising at least one i Layer are stacked on top of each other.
  • the photoactive component between the electrode and the electrode is the photoactive component between the electrode and the electrode
  • the contacts are made of metal, a conductive oxide, in particular ITO, ZnO: Al or other TCOs or a conductive
  • Polymer in particular PEDOT: PSS or PA I.
  • polymer solar cells which comprise two or more photoactive mixed layers are also included, the mixed layers being directly adjacent to one another.
  • the materials are applied from solution and thus a further applied layer very easily causes the underlying layers to be dissolved, dissolved or changed in their morphology.
  • polymer solar cells therefore, only a very limited multiple mixed layers can be produced and only by the fact that different material and solvent systems are used, which in the production of each other hardly or hardly
  • Multiple mixed layer structure can be used very widely and can be realized with any combination of materials.
  • the device is semitransparent with a transmission of 10-80%.
  • the electrodes consist of a metal (eg Al, Ag, Au or a combination of these), a conductive oxide, in particular ITO, ZnO: Al or another TCO (Transparent Conductive Oxide), a conductive polymer, in particular PEDOT / PSS poly (3,4-ethylene dioxythiophene) poly (styrenesulfonate) or PANI (polyaniline), or a combination of these
  • a metal eg Al, Ag, Au or a combination of these
  • a conductive oxide in particular ITO, ZnO: Al or another TCO (Transparent Conductive Oxide)
  • a conductive polymer in particular PEDOT / PSS poly (3,4-ethylene dioxythiophene) poly (styrenesulfonate) or PANI (polyaniline), or a combination of these
  • the transparent electrode is selected from silver nanowire, carbon nanotube (CNT), carbon nanotube / graphene electrode, thin-film metal electrode, metal grid electrode, busbar or
  • the invention is based on some
  • Embodiments are intended to describe the invention without limiting it.
  • a solar module is arranged on a concrete part.
  • the solar module in this case comprises at least two serially connected photoactive components, which comprise a first and a second electrode and a photoactive layer system with at least one mixed layer of an acceptor donor system of organic materials.
  • the photoactive components comprise a first and a second electrode and a photoactive layer system with at least one mixed layer of an acceptor donor system of organic materials.
  • Components are arranged on a flexible substrate, which is designed for example as a PET film.
  • a connecting means for arranging on the surface of the concrete molding is arranged.
  • Connecting means is designed, for example, so that a detachable arrangement on the concrete molding is possible.
  • the connecting means is designed as a button connection. It is also conceivable execution as
  • Velcro connection wherein the barbs are arranged on the back of the module and the counterpart is arranged on the molding.
  • the barbs can also be arranged on the molded part.
  • the barbs are introduced into the surface of the molded concrete. This has the advantage that a resistant detachable arrangement on the molded part is possible, whereby a reproducible arrangement on the molded part is ensured by the integrated barbs.
  • a connecting means for non-detachable arrangement is provided on the molded part made of concrete.
  • the connecting means which is arranged on the side of the substrate opposite the photoactive components, comprises at least two
  • the intermediate layer is arranged between the adhesion layer and the substrate and is designed as a flexible layer with a modulus of elasticity of ⁇ 45 GPa.
  • the intermediate layer is designed as a glass fleece or textile fabric layer.
  • the intermediate layer serves for possible cracking in the molded part and its effects on the Solar module to prevent. In design of the molded concrete, it may be due to the drying to a
  • the intermediate layer is formed of a flexible, elastic material. As a result, resulting stresses can be reduced and possible damage to the module avoided.

Abstract

L'invention concerne un module solaire destiné à être installé sur des pièces moulées en béton et son utilisation.
PCT/IB2013/054404 2012-05-30 2013-05-28 Module solaire à installer sur une pièce moulée en béton WO2013179223A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102012104638 2012-05-30
DE102012104638.7 2012-05-30

Publications (2)

Publication Number Publication Date
WO2013179223A2 true WO2013179223A2 (fr) 2013-12-05
WO2013179223A3 WO2013179223A3 (fr) 2014-03-13

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/IB2013/054400 WO2013179220A2 (fr) 2012-05-30 2013-05-28 Module solaire à installer sur des pièces moulées
PCT/IB2013/054404 WO2013179223A2 (fr) 2012-05-30 2013-05-28 Module solaire à installer sur une pièce moulée en béton

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/IB2013/054400 WO2013179220A2 (fr) 2012-05-30 2013-05-28 Module solaire à installer sur des pièces moulées

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Country Link
WO (2) WO2013179220A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11108354B2 (en) 2018-02-28 2021-08-31 Scott Carrington Portable power generator
WO2022053458A2 (fr) 2020-09-11 2022-03-17 Armor Solar Power Films Gmbh Élément de façade pour un bâtiment, support pour un élément de façade et procédé de fabrication d'un élément de façade

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EP1191605A2 (fr) 2000-09-26 2002-03-27 Zenit Energietechnik GmbH Laminé solaire flexible sans emploi de verre
WO2004083958A2 (fr) 2003-03-19 2004-09-30 Technische Universität Dresden Composant photo-actif presentant des couches organiques
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JP2011109051A (ja) 2009-11-19 2011-06-02 Nissei Engineering Kk フレキシブル太陽電池パネル
EP2385556A1 (fr) 2010-05-04 2011-11-09 Heliatek GmbH Composant photo-actif doté de couches organiques
WO2012030397A1 (fr) 2010-08-31 2012-03-08 Det Internatonal Holding Limited Système de fiche et de culot de câble destiné à fournir une sélection de tension

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Publication number Priority date Publication date Assignee Title
US11108354B2 (en) 2018-02-28 2021-08-31 Scott Carrington Portable power generator
WO2022053458A2 (fr) 2020-09-11 2022-03-17 Armor Solar Power Films Gmbh Élément de façade pour un bâtiment, support pour un élément de façade et procédé de fabrication d'un élément de façade
DE102020211456A1 (de) 2020-09-11 2022-03-17 Armor Solar Power Films Gmbh Fassadenelement für ein Gebäude, Halterung für ein Fassadenelement und Verfahren zur Herstellung eines Fassadenelements

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Publication number Publication date
WO2013179223A3 (fr) 2014-03-13
WO2013179220A3 (fr) 2014-03-13
WO2013179220A2 (fr) 2013-12-05

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