Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J3/00—Processes of treating or compounding macromolecular substances
  • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
  • C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
  • C08J3/091—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
  • C08J3/096—Nitrogen containing compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/16—Nitrogen-containing compounds
  • C08K5/20—Carboxylic acid amides
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J11/00—Recovery or working-up of waste materials
  • C08J11/04—Recovery or working-up of waste materials of polymers
  • C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J3/00—Processes of treating or compounding macromolecular substances
  • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
  • C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
  • C08J3/091—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
  • C08J3/095—Oxygen containing compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J3/00—Processes of treating or compounding macromolecular substances
  • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
  • C08J3/09—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids
  • C08J3/091—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in organic liquids characterised by the chemical constitution of the organic liquid
  • C08J3/097—Sulfur containing compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
  • C08K5/41—Compounds containing sulfur bound to oxygen
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
  • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
  • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
  • C09D127/16—Homopolymers or copolymers of vinylidene fluoride
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/20—Diluents or solvents
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
  • C09D7/40—Additives
  • C09D7/60—Additives non-macromolecular
  • C09D7/63—Additives non-macromolecular organic
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M10/00—Secondary cells; Manufacture thereof
  • H01M10/05—Accumulators with non-aqueous electrolyte
  • H01M10/052—Li-accumulators
  • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
  • H01M4/00—Electrodes
  • H01M4/02—Electrodes composed of, or comprising, active material
  • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
  • H01M4/621—Binders
  • H01M4/622—Binders being polymers
  • H01M4/623—Binders being polymers fluorinated polymers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
  • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
  • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
  • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
  • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
  • C08J2327/16—Homopolymers or copolymers of vinylidene fluoride
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2207/00—Properties characterising the ingredient of the composition
  • C08L2207/20—Recycled plastic
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
  • Y02E60/10—Energy storage using batteries

Definitions

• the present invention relates to a composition for solubilizing a fluoropolymer.
• the invention also relates to the obtained fluoropolymer composition, the process for its preparation and its uses.
• the invention is also of use the fluoropolymer composition for coating applications.
• Fluoropolymers such as polytetrafluoroethylene, polyvinylidene fluoride are encountered in numerous technical fields.
• Polytetrafluoroethylene PTFE
• PTFE Polytetrafluoroethylene
• PVDF Polyvinylidene fluoride
• a step in which the fluoropolymer is solubilized is sometimes present in the different applications, particularly when the fluoropolymer is used in batteries, or to make membranes for water filtration.
• Lithium-ion secondary batteries have high voltage and high capacity compared to conventional nickel cadmium secondary batteries.
• lithium transition metal composite oxides such as LiCo0 2 and LiMn 2 0 4
• carbonaceous materials such as graphite and carbon fiber
• high voltage and high capacity can be achieved, and side effects such as short circuits do not occur.
• lithium secondary batteries are widely used as power sources for mobile electronic devices such as cellular phones, notebook computers, digital cameras, etc.
• the polymeric binder is usually dissolved in a solvent to form a solution having from about 1 to 15 % binder in solvent.
• Binder solutions are typically formulated with N-methyl pyrrolidone (NMP). NMP is considered to be most effective.
• NMP will be labeled as Mutagen Cat 2 / Reprotoxic R61 from June 2009 in Europe and NMP is subject to report in the Toxic Release Inventory (SARA title III section 313). There is a need for other solvents, presenting a good safety and/or environment profile.
• an adhesive formula which consists of polyvinylidene fluoride resin 3-15 wt %, N-methyl pyrrolidone or dimethyl acetamide 85-95 wt %, and ⁇ -aminopropyl triethoxy silicone, ⁇ -propyl methacrylate trimethoxy silicone or ethylamino amidopropyl trimethoxy silicone as coupling agent 1-5 wt %.
• US2005048368-A1 , JP2005072009-A, CN1591939-A, KR2005023179-A and CN10041 1232-C relate to a separator formula ; the employed organic solvent is consisting of dimethylformamide, dimethylsulfoxide, dimethylacetate, acetone, and/or N-methyl-2-pyrrolidine. Dinnethylacetamide, dimethylformamide are also classified as C R (carcinogen/mutagen/reprotoxic).
• KR2003047038-A develop composite binder for lithium battery.
• the composite electrode binder comprises polyvinylidene fluoride (PVDF) and polyimide.
• PVDF polyvinylidene fluoride
• the polyimide is 20 % polyimide solution prepared by mixing pyromellitic dianhydride and 4,4'-diaminophenyl ether in the ratio of 1/1 and dissolving the mixture in N-methylpyrrolidone.
• JP2002246029-A, WO200273720-A2, AU2002257642-A1 and AU2002257642- A8 describe a new binder composition comprising fluoro-resin-A which dissolves in a specific organic solvent and resin-B which totally or partially does not dissolve in the organic solvent.
• Fluoro-resin-A comprises fluoro-polymer-A1 whose 8 wt. % N-methylpyrroldinone solution has a viscosity of 0.3-20 Pa.s and fluoro-polymer-A2 in which polar groups are incorporated.
• the weight ratio of A B is 99/1 to 1/99.
• Poly(vinylidene fluoride-hexafluoropropylene)-based membranes for lithium batteries are disclosed in Journal of Membrane Science (2008), 310(1+2), 349- 355.
• Poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) copolymer membranes are prepared by phase inversion with poly(ethylene glycol) as additive and with THF, acetone or DMF as solvents.
• composition notably for solubilizing a fluoropolymer, comprising a solvent blend of at least :
• R 2 and R 3 identical or different, being methyl or ethyl groups ;
• DMSO DiMethylSulfoxide
• the solvent blend used in the invention presents a good HSE profile with no CMR chemicals. Therefore, risks to human health and environment are sharply decreased. Then present invention makes possible the solubilization of a fluoropolymer with solvents which are not labeled CMR,
• the solvent blend has a good solvency power for the fluoropolymer.
• the solvent blend has a freezing point lower than the one of DMSO and very convenient for the applications. It is very advantageous because the freezing point of DMSO is high (18°C) close to room temperature which can involve freezing. Moreover, the blend of the present invention is soluble in water.
• Another subject of the invention is also the obtained composition comprising a solubilized fluoropolymer and the solvent blend as described, and possibly odor mask and/or anti-freezing agent.
• a gel is a solid composed of at least two components, one of which (polymer) forms a three-dimensional network in the medium of the other component (solvents), wherein the minimum amount of the liquid is sufficient for ensuring the elastic properties of the gel.
• solvents solvents
• the present invention proposes a solvent blend for preparing a solution and/or a gel of a fluoropolymer.
• the invention also concerns the use of this composition in order to prepare a membrane or a coating on any substrate and particularly as a binder polymer for coating a battery material.
• a subject of the present invention is a composition for solubilizing a fluoropolymer, as described,
• Another subject of the present invention is a fluoropolymer composition comprising a solubilized fluoropoiymer and the solvent blend as described.
• the composition comprises typically from 0.1 to 15 % by weight of the fluoropolymer.
• the composition has generally a viscosity of lower than 1000 cP at room temperature, preferably at 27°C.
• the fluoropolymer is PVDF
• the obtained solutions of PVDF in the solvent blend of the invention have preferably a viscosity in the range of 250 to 400 cP, more preferably 300 to 400 cP at room temperature.
• the polymer involved in the composition of the invention is a fluoropolymer.
• this denotes any polymer having in its chain more than 50%, preferably more than 75%, by weight of at least one fluoromonomer chosen from the monomers containing a vinyl bond capable of opening in order to be polymerized and that contains, directly attached to this double bond, at least one fluorine atom, one fluoroalkyf group or one fluoroalkoxy group.
• fluoro homo- or copolymers are polymers or copolymers derived from tetrafluoroethylene, hexafluoropropylene, chlorotrifluoroethylene and bromotrifluoroethylene.
• fluoropolymers may also contain recurring units derived from other ethylenically unsaturated monomers containing at least as many fluorine atoms as carbon atoms, such as, for example, vinylidene fluoride, trifluoroethylene and vinyl perfluoroalkyi ethers such as perfluoro(methylvinyl) ether or perfluoro ⁇ ethylvinyl) ether.
• Polyvinylidenefluoride (PDVF) polymers are especially preferred.
• the fluoropolymer can be a copolymer of vinylidene fluoride (VDF) with comonomers such as hexafluoropropylene (HFP) and/or chlorotrifiuoroethylene (CTFE).
• HFP hexafluoropropylene
• CTFE chlorotrifiuoroethylene
• the PVDF contains, by weight, at least 50% of VDF, more preferentially at least 75% and even more preferentially at least 85%.
• the amount of comonomer can be typically of from 0-25%, preferably 0-10 % by weight.
• suitable PVDF polymers include Kynar 30 F, Kynar 741 and Kynar 461 , available from Arkema and Solef 6020 and Solef 5130, available from Solvay.
• the fluoropolymer may be a homopolymer or a copolymer, it may also comprise unfluorinated monomers such as ethylene or propylene in quantities preferably less than 25 %.
• the present invention includes the case where the fluoropolymer is mixed with minor quantities (less than 50 wt %) of another polymer such as polyurethane, polyethylene oxide, polyacrylonitrile, polymethylacrylate, polyacrylamide, polyvinylacetate, polyvinylpyrrolidone, glycol diacry!ate and combinations thereof.
• another polymer such as polyurethane, polyethylene oxide, polyacrylonitrile, polymethylacrylate, polyacrylamide, polyvinylacetate, polyvinylpyrrolidone, glycol diacry!ate and combinations thereof.
• the weight ratio between the compound of formula (I) and DMSO is preferably of from 1/99 to 99/1 , preferably of from 20/80 to 80/20, preferably of from 70/30 to 30/70. These ratios allow good properties as well a good HSE profile.
• the solvent blend can comprise further solvents.
• further solvents include :
• aliphatic hydrocarbons including, more particularly, the paraffins such as, in particular, pentane, hexane, heptane, octane, nonane, decane, undecane, dodecane or cyclohexane, and naphthalene and aromatic hydrocarbons and more particularly aromatic hydrocarbons such as, in particular, benzene, toluene, xylenes, cumene, petroleum fractions composed of a mixture of alkylbenzenes,
• perchlorinated hydrocarbons such as, in particular, tetrachtoroethylene, hexachloroethane ; partially chlorinated hydrocarbons such as dichloromethane, chloroform, 1 ,2-dich!oroethane, 1 ,1 ,1-trichloroethane, 1 ,1 ,2,2-tetrachloroethane, pentachloroethane, trichloroethylene, 1-ch!orobutane, 1 ,2-dichlorobutane ; monochlorobenzene, 1 ,2-dichlorobenzene, 1 ,3-dichlorobenzene, 1 ,4- dichlorobenzene, ,2,4-trichlorobenzene or mixture of different chlorobenzenes,
• perchlorinated hydrocarbons such as, in particular, tetrachtoroethylene, hexachloroethane ; partially chlorinated hydrocarbons such as dichlorome
• - aliphatic, cycloaliphatic or aromatic ether oxides more particularly, diethyl oxide, dipropyl oxide, diisopropyl oxide, dibutyl oxide, methyltertiobutylether, dipentyl oxide, diisopentyl oxide, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether benzyl oxide; dioxane, tetrahydrofuran (THF), - glycol ethers such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monobenzyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono-n- butyl ether,
• glycol ether esters such as ethylene glycol methyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate,
• DMAC ⁇ , ⁇ -dimethylacetamide
• DMF dimethylformamide
• NMP N-methyl-2- pyrrolidinone
• the amount of further solvents is preferably or lower than the amount of the compound of formula (I) and/or of DMSO.
• the amount of further solvent is preferably of lower then 50 % by weight, preferably of lower than 25 % of the total amount of solvents. In one embodiment of the invention, a low amount of further solvents is preferred.
• the composition comprises at least a compound of formula (I):
• R 2 and R 3 identical or different, being methyl or ethyl groups ;
• R 1 preferably represents an aliphatic acyclic and saturated group, linear or branched, having 1 to 6 carbon atoms. More preferably R 1 is an alkyl group having 1 to 6 carbon atoms. Alkyl groups may be methyl, ethyl, propyl, butyl, pentyl and hexyl. When these alkyl groups are branched or substituted, we can also cite isopropyl, tert-butyl, 2-ethylhexyl, 2-methylbutyl, 2-methylpentyl and 1- methyl pentyl. Hydrocarbonated chain may eventually be interrupted by one or more heteroatom such as O or S, or one or more functional group such as carbonyl, or carrying one or more substituent such as formyl.
• said cycle may equally comprise a -CON- group.
• the compound of formula (I) is a blend comprising:
• R 1 is a hydrogen. According to an other embodiment of the invention, R 1 is a 1-hydroxyethyi group.
• R 2 and R 3 are methyl groups.
• R 1 and R 2 may form together a cycle, said cycle having 4 carbon atoms, carbon atom of carbonyl being included and R 3 is a methyl group.
• the weight ratio between the compound of formula (I) and DMSO in the mixture (or blend) is of from 1/99 to 99/1 , preferably of from 20/80 to 80/20, preferably of from 70/30 to 30/70.
• the solvent can comprise further solvents than the compound of formula (I) and DMSO which are above described.
• the amount of further solvents is preferably or lower than the amount of the compound of formula (I) and/or of DMSO.
• the amount of further solvent is preferably of lower then 50 % by weight, preferably of lower than 25 % of the total amount of solvents.
• the composition may also comprise odor a mask agents, such as compounds containing ester, aldehyde, alcohoi, hydrocarbon and/or ketone. Odor mask can be included in the blend, the weight ratio between the compound of formula (I) / DMSO blend and the odor mask is preferable of from 0.1/99.9 to 1/99.
• the composition may also comprise an anti-freezing agent, notably a glycol anti- freezing agent, such as for example ethylene glycol or propylene glycol.
• an anti-freezing agent notably a glycol anti- freezing agent, such as for example ethylene glycol or propylene glycol.
• Anti- freezing agent can be included, the weight ratio between the compound of formula (I) / DMSO blend and the anti-freezing agent is preferable of from 1/99 to 10/90.
• Another object of the invention is the process for the preparation of the composition comprising the fluoropolymer which is called "fluoropolymer composition”.
• composition of the invention is prepared according a process comprising the steps of :
• This operation is advantageously carried out from 30 to 80°C.
• the temperature is maintained until solubilization of the fluoropolymer.
• the obtained composition is generally cooled down to room temperature.
• the process for the preparation of the fluoropolymer composition comprises the steps of : - preparing the solvent blend by mixing a compound of formula (I) and dimethyisulfoxyde,
• the temperature is maintained until solubilization of the fluoropolymer.
• the obtained composition is generally cooled down to room temperature.
• the solvent blend of the present invention can be used every time a solvent route is preferred for the use of a fluoropolymer material, preferably PVDF.
• a fluoropolymer material preferably PVDF.
• Another application of the solvent blend of the invention is in the field of recycling fluoropolymers, particularly PVDF.
• PVDF can be recovered from the backing of the photovoltaic pannels and from wire coatings.
• the fluoropolymer composition obtained from the solvent blend of the invention can be used for example, as a raw material for preparing a membrane or a foam or for coating a substrate, or as binder.
• substrates which can be coated are metal (sheet, film, and wire), plastics, textiles, glass and so on.
• the present invention also provides a process for coating a substrate comprising the steps of applying the fluoropolymer composition of the invention onto one or two sides of the substrate or parts thereof and removing the solvent.
• the solvent removal can be obtained for example by evaporation by increasing the temperature or by phase inversion technique using an additional non-solvent, for example water.
• One specific application is a process for preparing a coated battery separator.
• the separator material may be composed of a porous polyolefin, preferably polyethylene, polypropylene, or a combination of the two, coated as described below.
• separator materials include polytetrafuoroethylene, polystryrene, polyethyleneterephtalate, ethylenepropylene diene monomer (EPDM), nylon and combinations thereof.
• the process of the invention for preparing a coated battery separator comprises the steps :
• the fluoropolymer composition may be applied to one side of the separator material at a time or, in another embodiment, both sides simultaneously.
• One side of the separator material may be coated at a time with the fluoropolymer composition of the present invention.
• the coated separator is then dried by evaporation of the solvents to form a porous fluoropolymer coating on one side of the separator material. After coating the first side, the same process is used again to coat the second side of the separator.
• the separator may be coated on both sides simultaneously by running the separator material through a dipping bath of the fluoropolymer composition. The coated separator material is then dried by evaporation.
• the present invention also provides a process for preparing a battery involving the separator coated according to the invention.
• the three primary functional components of a lithium-ion battery are the anode, cathode, and electrolyte.
• the anode of a conventional lithium-ion cell is made from carbon (graphite).
• the cathode is a metal oxide (for example cobalt or manganese dioxide).
• the electrolyte is typically a mixture of organic solvents containing complexes of lithium ions.
• Sample liquid electrolyte compositions for lithium ion cells in accordance with the present invention may include solvents such as propylene carbonate, ethylene carbonate, diethyl carbonate, dimethyl carbonate, ethyl methyl carbonate, dipropyl carbonate, dimethyl sulfoxide, acetonitrile and combinations thereof, a lithium salt having Li + as the cation and one of PF 6' , AsF 6" , BF 4" , CIO 4' , CF 3 S0 3" , N(CF 3 S0 2 ) 2" as the anion.
• solvents such as propylene carbonate, ethylene carbonate, diethyl carbonate, dimethyl carbonate, ethyl methyl carbonate, dipropyl carbonate, dimethyl sulfoxide, acetonitrile and combinations thereof, a lithium salt having Li + as the cation and one of PF 6' , AsF 6" , BF 4" , CIO 4' , CF
• Fluoropolymer compositions in accordance with the present invention are formulated with high boiling point solvents which have good HSE profiles to dissolve the fluoropolymer and coat it on the separator.
• the invention also concerns then the use of the composition as a binder material used in the cathode and anode electrode slurry making process for lithium-ion batteries.

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• 2012
  • 2012-04-16 IN IN9065DEN2014 patent/IN2014DN09065A/en unknown
  • 2012-04-16 JP JP2015506060A patent/JP6261565B2/ja active Active
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