WO2013127647A1 - Polyetheresterpolyole und ihre verwendung zur herstellung von polyurethan-hartschaumstoffen - Google Patents
Polyetheresterpolyole und ihre verwendung zur herstellung von polyurethan-hartschaumstoffen Download PDFInfo
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/36—Hydroxylated esters of higher fatty acids
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/482—Mixtures of polyethers containing at least one polyether containing nitrogen
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/284—Compounds containing ester groups, e.g. oxyalkylated monocarboxylic acids
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
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- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/487—Polyethers containing cyclic groups
- C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
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- C—CHEMISTRY; METALLURGY
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
- C08G18/5027—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups directly linked to carbocyclic groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
Definitions
- the invention relates to polyetheresterpolyols, polyol mixtures containing them, to a process for the production of rigid polyurethane foams using the polyetheresterpolyols and to the rigid polyurethane foams themselves.
- Polyurethane rigid foams have long been known and described many times.
- the use of the rigid polyurethane foams is mainly for heat insulation, for example in refrigerators, transport or buildings and for the production of components, in particular sandwich elements.
- Suitable rigid polyurethane foams can be prepared in a known manner by reacting organic polyisocyanates with one or more compounds having at least two reactive hydrogen atoms in the presence of blowing agents, catalysts and optionally auxiliaries and / or additives.
- polyether alcohols and / or polyester alcohols are preferably used in the preparation of the polyurethanes.
- the selection of the polyols takes place in particular taking into account the costs and the desired application properties (for example EP-A 1 632 51 1, US Pat. No. 6,495,722, WO 2006/108833).
- polyols with high functionality and low molecular weight are used to produce isocyanate-based rigid foams to ensure optimum cross-linking of the foams.
- the preferably used polyether alcohols usually have a functionality of 4 to 8 and a hydroxyl number in the range between 300 to 600, in particular between 400 and 500 mg KOH / g.
- polyols with very high functionality and hydroxyl numbers in the range between 300 and 600 have a very high viscosity. Furthermore, it is known that such polyols are very polar and thus have a poor solvent power for hydrocarbons. To remedy this deficiency, polyether alcohols having functionalities of 2 to 4 and hydroxyl numbers of 100 to 350 mg KOH / g are frequently added to the polyol component. It is also known that the flowability of polyol components based on highly functional, polar polyols is not always satisfactory.
- the phase stability should be obtained by the use of the polyetherresterpolyole invention.
- Polyetheresterpolyolen with a higher propellant solubility formulations with a higher proportion of high-functionality crosslinker polyols should be used, which should have a higher compressive strength.
- such formulations should have a low viscosity and good processing properties, in particular have a good flowability and allow rapid removal from the mold.
- polyetheresterpolyols comprising the reaction product of a1) from 5 to 63% by weight of one or more polyols or polyamines or mixtures thereof with an average functionality of from 2.5 to 8,
- the network density of a resulting foam can be increased and thus its compressive strength can be improved. This makes it possible to produce components with lower density but otherwise the same mechanical properties.
- the polyetherester polyols allow formulations for foams with increased compressive strengths and improved release properties. Surprisingly, these formulations show very good flow properties, although very little or no low viscosity polyols having a functionality of 2 to 4 and an OH number of less than 300 (so-called flow polyols) are used.
- the polyols, polyamines or mixtures of polyols and / or polyamines a1) preferably have an average functionality of from 3 to 7, particularly preferably from 3.5 to 6.5.
- Preferred polyols or polyamines of component a1) are selected from the group consisting of sugars and sugar alcohols (glucose, mannitol, sucrose, pentaerythritol, sorbitol), polyhydric phenols, resoles, such as oligomeric condensation products of phenol and formaldehyde, trimethylolpropane, glycerol, toluylene diamine, ethylenediamine, ethylene glycols, propylene glycol and water.
- sugars and sugar alcohols such as sucrose and sorbitol, glycerol, water and ethylene glycols, and mixtures thereof, particular preference being given to mixtures of retaining two or more compounds selected from sucrose, glycerin, water and diethylene glycol.
- component a1) contains a mixture of glycerol and sucrose.
- the proportion of polyols and / or polyamines a1) in the polyetherresterenpolyolen invention is generally from 5 to 63 wt .-%, preferably 20 to 50 wt .-%, particularly preferably 30 to 40 wt .-% and in particular 32 to 38 Wt .-%, based on the weight of the polyetheresterpolyols.
- the fatty acid or fatty acid monoester a2) is selected from the group consisting of polyhydroxy fatty acids, ricinoleic acid, hydroxyl-modified oils, hydroxyl-modified fatty acids and fatty acid esters based on miyristoleic acid, palmitoleic acid, oleic acid, stearic acid, palmitic acid, vaccenic acid, petroseic acid , Gadoleic acid, erucic acid, nervonic acid, linoleic acid, ⁇ - and ⁇ -linolenic acid, stearidonic acid, arachidonic acid, timnodonic acid, clupanodonic acid and cervonic acid.
- Preferred fatty acid monoesters are the methyl esters. Preference is given to oleic acid, stearic acid, palmitic acid, linolenic acid and their monoesters, as well as mixtures thereof.
- fatty acids or fatty acid monoesters are used, in particular in the form of fatty acid methyl esters, biodiesel or pure fatty acids. Particular preference is given to biodiesel and pure fatty acids, particular preference being given to pure fatty acids, preferably oleic acid and stearic acid, in particular oleic acid.
- the fatty acid or fatty acid monoester a2) is oleic acid or stearic acid or a derivative of these fatty acids, particularly preferred are oleic acid, oleic acid methyl ester, stearic acid and stearic acid methyl ester.
- the fatty acid or fatty acid monoester typically serves to improve blowing agent solubility in the production of polyurethane foams.
- the fatty acid and fatty acid monoester content of the polyetherester polyols according to the invention is generally from 2 to 50% by weight, preferably from 5 to 35% by weight, more preferably from 8 to 30% by weight and in particular from 12 to 30% by weight, based on the Weight of polyetherester polyols.
- Suitable alkylene oxides a3) having 2 to 4 carbon atoms are, for example, tetrahydrofuran, 1, 3-propylene oxide, 1, 2 or 2,3-butylene oxide, styrene oxide and preferably ethylene oxide and 1, 2-propylene oxide.
- the alkylene oxides can be used individually, alternately in succession or as mixtures.
- Preferred alkylene oxides are propylene oxide and ethylene oxide, particularly preferred are mixtures of ethylene oxide and propylene oxide with> 50% by weight of propylene oxide, particular preference being given to pure propylene oxide.
- the alkoxylation catalyst used is an amine, preferably dimethylethanolamine or imidazole, particularly preferably imidazole.
- the proportion of alkylene oxides in the polyetherester polyols according to the invention is generally from 35 to 70% by weight, preferably from 38 to 65% by weight, particularly preferably
- the polyetherester polyols according to the invention have an OH number of 300 to 800 mg KOH / g, preferably from 400 to 700 mg KOH / g, more preferably from 450 to 550 mg KOH / g and in particular from 475 to 550 mg KOH / g.
- the polyetherester polyols according to the invention have an average functionality of from 2.5 to 8, preferably from 3 to 7, particularly preferably from 3.5 to 6 and in particular from 4.5 to 5.5.
- the viscosity of the polyetherester polyols according to the invention is generally ⁇
- mPas preferably ⁇ 30,000 mPas, more preferably ⁇ 25,000 mPas and especially ⁇ 20,000 mPas, each measured at 25 ° C according to DIN 53018.
- the use of oleic acid methyl ester as component a2) leads to a low viscosity.
- the invention relates to a process for the production of rigid polyurethane foams by reacting
- the present invention also provides a polyol mixture comprising the components B) to G), ie
- G optionally further auxiliaries and / or additives.
- rigid polyurethane foams including rigid polyisocyanurate foams, obtainable by the process according to the invention, and the use of the polyether ester polyols according to the invention for the production of rigid polyurethane foams.
- the proportion of the polyetherester polyols B) according to the invention is> 25% by weight, preferably> 40% by weight, more preferably> 50% by weight and, with particular preference,> 52% by weight, based on the sum of Components B) to G).
- Polyurethane rigid foams also include rigid polyisocyanurate foams.
- Suitable organic polyisocyanates A) are the aliphatic, cycloaliphatic, araliphatic and preferably aromatic polyfunctional isocyanates known per se.
- the organic polyisocyanates may optionally be modified.
- alkylenediisocyanates having 4 to 12 carbon atoms in the alkylene radical such as 1,12-dodecanediisocyanate, 2-ethyltetramethylenediisocyanate 1, 4, 2-methylpentamethylenediisocyanate-1, 5, tetramethylenediisocyanate-1, 4, and preferably hexamethylenediisocyanate-1, 6; Cycloaliphatic diisocyanates such as cyclohexane-1, 3- and 1, 4-diisocyanate and any mixtures of these isomers, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane (IPDI), 2,4- and 2,6 Hexahydrotoluylene diisocyanate and the corresponding mixtures of isomers, 4,4'-, 2,2'- and 2,4'-dicyclohexylmethane diisocyanate and the corresponding isomer mixture
- the organic di- and polyisocyanates can be used individually or in the form of their mixtures.
- Preferred polyisocyanates are tolylene diisocyanate (TDI), diphenylmethane diisocyanate (MDI) and in particular mixtures of diphenylmethane diisocyanate and polyphenylene polymethylene polyisocyanates (polymer MDI or PMDl).
- modified polyvalent isocyanates i. Products obtained by chemical reaction of organic polyisocyanates used. Examples which may be mentioned are ester, urea, biuret, allophanate, carbodiimide, isocyanurate, uretdione, carbamate, and / or urethane groups-containing polyisocyanates.
- Suitable polyester polyols C) can be prepared, for example, from organic dicarboxylic acids having 2 to 12 carbon atoms, preferably aromatic or a mixture of aromatic and aliphatic dicarboxylic acids, and polyhydric alcohols, preferably diols, having 2 to 12 carbon atoms, preferably 2 to 6 carbon atoms.
- Suitable dicarboxylic acids are, for example: succinic acid, glutaric acid, adipic acid, suberic acid, azelaic acid, sebacic acid, decanedicarboxylic acid, maleic acid, fumaric acid, phthalic acid, isophthalic acid and terephthalic acid.
- the dicarboxylic acids can be used both individually and in admixture.
- dicarboxylic acid derivatives for example dicarboxylic acid esters of alcohols having 1 to 4 carbon atoms, or dicarboxylic acid anhydrides.
- aromatic dicarboxylic acids phthalic acid, phthalic anhydride, terephthalic acid and / or isophthalic acid are preferably used in admixture or alone.
- the aliphatic dicarboxylic acids used are preferably dicarboxylic acid mixtures of succinic, glutaric and adipic acid in proportions of, for example, from 20 to 35:35 to 50:20 to 32 parts by weight, and in particular adipic acid.
- dihydric and polyhydric alcohols in particular diols, are: ethanediol, diethylene glycol, 1,2- or 1,3-propanediol, dipropylene glycol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 1, 10-decanediol, glycerol, trimethylolpropane and pentaerythritol.
- ethane diol diethylene glycol, 1, 4-butanediol, 1, 5-pentanediol, 1, 6-hexanediol or mixtures of at least two of said diols, in particular mixtures of 1, 4-butanediol, 1, 5-pentanediol and 1, 6-hexanediol.
- polyester polyols from lactones, for example ⁇ -caprolactone or hydroxycarboxylic acids, for example co-hydroxycaproic acid.
- polyester polyols C are also bio-based starting materials and / or their derivatives in question, such as.
- the content of the polyester polyols C) is generally 0 to 25 wt .-%, based on the sum of components B) to G). In a preferred embodiment of the invention, no further polyester polyols C) are used.
- Preferred polyester polyols C) are prepared from adipic acid, phthalic anhydride and / or terephthalic anhydride as dicarboxylic acids and propylene glycol, dipropylene glycol, ethylene glycol, diethylene glycol, glycerol and / or trimethylolpropane as alcohol component and oleic acid or castor oil and have an OH number of 150 to 400 and a functionality of 2 to 4.5 on.
- polyether polyols D which have been prepared by known processes, for example by anionic polymerization with alkali metal hydroxides, e.g. Sodium or potassium hydroxide or alkali alcoholates, e.g. Sodium methylate, sodium or potassium or potassium isopropylate, as catalysts and with the addition of at least one starter molecule containing 2 to 8, preferably 2 to 6, bonded reactive hydrogen atoms, or by cationic polymerization with Lewis acids such as antimony pentachloride, borofluoride etherate u.a. or bleaching earth, are prepared as catalysts from one or more alkylene oxides having 2 to 4 carbon atoms in the alkylene radical.
- alkali metal hydroxides e.g. Sodium or potassium hydroxide or alkali alcoholates, e.g. Sodium methylate, sodium or potassium or potassium isopropylate
- Lewis acids such as antimony pentachloride, borofluoride etherate u.a. or bleaching earth
- Suitable alkylene oxides are, for example, tetrahydrofuran, 1, 3-propylene oxide, 1, 2 or 2,3-butylene oxide, styrene oxide and preferably ethylene oxide and 1, 2-propylene oxide.
- the alkylene oxides can be used individually, alternately in succession or as mixtures.
- Preferred alkylene oxides are propylene oxide and ethylene oxide, particularly preferred is propylene oxide.
- Suitable starter molecules are, for example: water, organic dicarboxylic acids, such as succinic acid, adipic acid, phthalic acid and terephthalic acid, aliphatic and aromatic, optionally N-mono-, N, N- and N, N'-dialkyl-substituted diamines having 1 to 4 carbon atoms in the alkyl radical, such as optionally mono- and dialkyl-substituted ethylenediamine, diethylenetriamine, triethylenetetramine, 1,3-propylenediamine, 1,3- or 1,4-butylenediamine, 1, 2-, 1, 3-, 1, 4-, 1, 5 and 1, 6-hexamethylenediamine, phenylenediamines, 2,3-, 2,4- and 2,6-toluenediamine and 4,4'-, 2,4'- and 2,2'-diaminodiphenylmethane.
- organic dicarboxylic acids such as succinic acid, adipic acid, phthal
- alkanolamines e.g. Ethanolamine, N-methyl and N-ethylethanolamine
- dialkanolamines e.g. Diethanolamine, N-methyl and N-ethyldiethanolamine
- trialkanolamines e.g. Triethanolamine, and ammonia.
- dihydric or polyhydric alcohols such as ethanediol, propanediol-1, 2 and -1, 3, diethylene glycol, dipropylene glycol, butanediol-1, 4, hexanediol-1, 6, glycerol, trimethylolpropane, pentaerythritol, sorbitol and sucrose.
- Particularly preferred are the abovementioned primary amines, for example 2,3-toluenediamine.
- the polyether polyols D preferably polyoxypropylene polyols and / or polyoxyethylene polyols, have a functionality of preferably 2 to 6 and in particular 2 to 5 and number average molecular weights of 150 to 3000, preferably 200 to 1500 and in particular 250 to 750.
- the invention uses a propoxylated toluenediamine, in particular 2,3-toluenediamine as polyether polyol D).
- polyether polyols are polymer-modified polyether polyols, preferably graft polyether polyols, in particular those based on styrene and / or acrylonitrile, which are prepared by in situ polymerization of acrylonitrile, styrene or preferably mixtures of styrene and acrylonitrile, for example in a weight ratio of 90:10 to 10:90 , preferably 70: 30 to 30: 70, in expediently the abovementioned polyether polyols analogously to the specifications of the German patent specifications DE 1 1 1 394, 12 22 669 (US 3,304,273, 3,383,351, 3,523,093), 1 1 52 536 (GB 1040452) and 1,152,537 (GB 987,618), as well as polyetherpolyol dispersions which are described as disperse phase usually, in an amount of 1 to 50 wt .-%, preferably 2 to 25 wt .-%, contain:
- the polyether polyols may also be used in the form of mixtures. Furthermore, they can be mixed with the graft polyether polyols or polyester polyols and the hydroxyl-containing polyester amides, polyacetals, polycarbonates and / or polyether polyamines.
- hydroxyl-containing polyacetals are e.g. the compounds which can be prepared from glycols, such as diethylene glycol, triethylene glycol, 4,4'-dihydroxyethoxydiphenyldimethylmethane, hexanediol and formaldehyde. Polymerization of cyclic acetals also makes it possible to prepare suitable polyacetals.
- Hydroxyl-containing polycarbonates are those of the type known per se, for example, by reacting diols such as propanediol 1, 3, butanediol-1, 4 and / or hexanediol-1, 6, diethylene glycol, triethylene glycol or tetraethylenglykol with Diaryl carbonates, eg Diphenyl carbonate, alkylene carbonate or phosgene can be prepared.
- diols such as propanediol 1, 3, butanediol-1, 4 and / or hexanediol-1, 6, diethylene glycol, triethylene glycol or tetraethylenglykol
- Diaryl carbonates eg Diphenyl carbonate, alkylene carbonate or phosgene can be prepared.
- the polyester amides include e.g. the predominantly linear condensates obtained from polybasic, saturated and / or unsaturated carboxylic acids or their anhydrides and polybasic saturated and / or unsaturated aminoalcohols or mixtures of polyhydric alcohols and aminoalcohols and / or polyamines.
- Suitable polyether polyamines can be prepared from the above polyether polyols by known methods. Examples include the cyanoalkylation of polyoxyalkylene polyols and subsequent hydrogenation of the nitrile formed (US Pat. No. 3,267,050) or the partial or complete amination of polyoxyalkylene polyols with amines or ammonia in the presence of hydrogen and catalysts (DE 12 15 373).
- the proportion of the polyether polyols D) is 75 to 55 wt .-%, preferably 55 to 30 wt .-%, particularly preferably 30 to 5 wt .-%, based on the sum of components B) to G).
- Propellants E) used to make the rigid polyurethane foams preferably include water and physical blowing agents such as low boiling hydrocarbons and mixtures thereof. Suitable liquids are which are inert to the organic, optionally modified polyisocyanates and have boiling points below 100 ° C, preferably below 50 ° C at atmospheric pressure, so that they evaporate under the influence of the exothermic polyaddition reaction.
- alkanes such as heptane, hexane, n- and iso-pentane, preferably technical mixtures of n- and isopentanes, n- and isobutane and propane, cycloalkanes, such as cyclopentane and / or Cyclohexane, ethers, such as furan, dimethyl ether and diethyl ether, ketones, such as acetone and methyl ethyl ketone, alkyl carboxylates, such as methyl formate, dimethyl oxalate and ethyl acetate.
- alkanes such as heptane, hexane, n- and iso-pentane
- propane cycloalkanes, such as cyclopentane and / or Cyclohexane
- ethers such as furan, dimethyl ether and diethyl ether
- ketones such as acetone and methyl eth
- low-boiling liquids with one another and / or with other substituted or unsubstituted hydrocarbons.
- organic carboxylic acids such as formic acid, acetic acid, oxalic acid, ricinoleic acid and carboxyl-containing compounds.
- no formic acid and no halogenated hydrocarbons are used as the blowing agent.
- blowing agents are completely dissolved in the polyol component (i.e., B + C + E + F + G) or are metered in just prior to foaming the polyol component via a static mixer.
- the amount used of the physical blowing agent or the blowing agent mixture is from 1 to 45 wt .-%, preferably 10 to 30 wt .-%, particularly preferably 10 to 20 wt .-%, each based on the sum of components B) to G ).
- Water as blowing agent is preferably added to component B) in an amount of from 0.2 to 5% by weight, based on component B).
- the addition of water can be done in combination with the use of the other blowing agents described. Preference is given to using water in combination with pentane.
- catalysts F) for the production of the rigid polyurethane foams in particular compounds are used which greatly accelerate the reaction of the reactive hydrogen atoms, in particular hydroxyl groups, containing compounds of component B) to G) with the organic, optionally modified polyisocyanates A).
- basic polyurethane catalysts for example tertiary amines, such as triethylamine, tributylamine, dimethylbenzylamine, dicyclohexylmethylamine, dimethylcyclohexylamine, ⁇ , ⁇ , ⁇ ', ⁇ '-tetramethyldiaminodiethyl ether, Bis (dimethylaminopropyl) urea, N-methyl- or N-ethylmorpholine, N-cyclohexylmorpholine, ⁇ , ⁇ , ⁇ ', ⁇ '-tetramethylethylenediamine, ⁇ , ⁇ , ⁇ , ⁇ -tetramethylbutanediamine, N, N, N, N-tetramethylhexanediamine-1, 6, pentamethyldiethylenetriamine, dimethylpiperazine, N-dimethylaminoethylpiperidine, 1, 2-dimethylimidazole, 1-azabicyclo-
- metal salts are also suitable, such as iron (II) chloride, zinc chloride, lead octoate and preferably tin salts, such as tin dioctoate, tin diethylhexoate and dibutyltin dilaurate, and in particular mixtures of tertiary amines and organic tin salts.
- amidines such as 2,3-dimethyl-3,4,5,6-tetrahydropyrimidine
- tetraalkylammonium hydroxides such as tetramethylammonium hydroxide
- alkali metal hydroxides such as sodium hydroxide and alkali metal alkoxides, such as sodium methoxide and potassium isopropylate
- alkali metal salts of long-chain fatty acids having 10 to 20 carbon atoms and optionally pendant OH groups Preferably used are 0.001 to 5 wt .-%, in particular 0.05 to 2 wt .-% catalyst or catalyst combination, based on the weight of components B) to G). It is also possible to run the reactions without catalysis. In this case, the catalytic activity of amines started polyols is exploited.
- catalysts which form isocyanurate groups for example ammonium ion or alkali metal salts alone or in combination with tertiary amines.
- isocyanurate groups for example ammonium ion or alkali metal salts alone or in combination with tertiary amines.
- the formation of isocyanurate leads to flame-resistant PIR foams, which are preferably used in industrial rigid foam, for example in construction as an insulating board or sandwich panels.
- auxiliaries and / or additives G may be added to the reaction mixture for producing the rigid polyurethane foams.
- auxiliaries and / or additives G include surfactants, foam stabilizers, Cell regulators, fillers, dyes, pigments, flame retardants, hydrolysis protectants, fungistatic and bacteriostatic substances.
- surface-active substances are e.g. Compounds which serve to assist the homogenization of the starting materials and, if appropriate, are also suitable for regulating the cell structure of the plastics.
- emulsifiers such as the sodium salts of castor oil sulfates or fatty acids, and salts of fatty acids with amines, e.g. diethylamine, stearic acid diethanolamine, diethanolamine ricinoleic acid, salts of sulfonic acids, e.g.
- Alkali or ammonium salts of dodecylbenzene or dinaphthylmethanedisulfonic acid and ricinoleic acid Alkali or ammonium salts of dodecylbenzene or dinaphthylmethanedisulfonic acid and ricinoleic acid;
- Foam stabilizers such as siloxane-oxalkylene copolymers and other organopolysiloxanes, ethoxylated alkylphenols, ethoxylated fatty alcohols, paraffin oils, castor oil or ricinoleic acid esters, turkey red oil and peanut oil, and cell regulators, such as paraffins, fatty alcohols and dimethylpolysiloxanes.
- the above-described oligomeric acrylates having polyoxyalkylene and fluoroalkane radicals are also suitable as side groups.
- the surface-active substances are usually used in amounts of from 0.01 to 5% by weight, based on the weight of components B) to G).
- Fillers are the usual conventional organic and inorganic fillers, reinforcing agents, weighting agents, agents for improving the abrasion behavior in paints, coating agents, etc., to be understood.
- inorganic fillers such as silicate minerals, for example phyllosilicates such as antigorite, serpentine, hornblende, amphiboles, chrysotile and talc, metal oxides such as kaolin, aluminas, titanium oxides and iron oxides, metal salts such as chalk, barite and inorganic pigments such as cadmium sulfide
- silicate minerals for example phyllosilicates such as antigorite, serpentine, hornblende, amphiboles, chrysotile and talc
- metal oxides such as kaolin, aluminas, titanium oxides and iron oxides
- metal salts such as chalk
- barite and inorganic pigments such as cadmium sulfide
- kaolin China
- Suitable organic fillers are, for example: carbon, melamine, rosin, cyclopentadienyl resins and graft polymers and cellulose fibers, polyamide, polyacrylonitrile, polyurethane, polyester terieriern based on aromatic and / or aliphatic dicarboxylic acid esters and in particular carbon fibers.
- the inorganic and organic fillers may be used singly or as mixtures and are added to the reaction mixture in amounts of from 0.5 to 50% by weight, preferably from 1 to 40% by weight, based on the weight of components A) to E), added, but the content of mats, nonwovens and fabrics made of natural and synthetic fibers can reach values up to 80 wt .-%.
- the optionally modified organic polyisocyanates A), the specific polyetherester polyols B) according to the invention, optionally the polyester polyols C) and optionally the polyetherols and / or further compounds having at least two isocyanate-reactive groups D) in such amounts Implementation brought that the equivalence ratio of NCO groups of the polyisocyanates A) to the sum of the reactive hydrogen atoms of the components B), optionally C) optionally D) and E) and F), 1 to 3: 1, preferably 1, 1 to 2: 1 and in particular 1, to 1, 5: 1.
- the polyol component comprises
- blowing agent E 10 to 25% by weight of blowing agent E
- auxiliaries and / or additives G 1 to 4% by weight of auxiliaries and / or additives G
- the polyol component comprises
- blowing agent E 10 to 20% by weight of blowing agent E
- the rigid polyurethane foams are advantageously produced by the one-shot process, for example by means of the high-pressure or low-pressure technique in open or closed molds, for example metallic molds. conditions. Also common is the continuous application of the reaction mixture on suitable conveyor belts for the production of panels.
- the starting components are mixed at a temperature of 15 to 90 ° C, preferably from 20 to 60 ° C and in particular from 20 to 35 ° C, and introduced into the open or optionally under elevated pressure in the closed mold.
- the mixing can, as already stated, be carried out mechanically by means of a stirrer or a stirring screw.
- the mold temperature is expediently from 20 to 110.degree. C., preferably from 30 to 70.degree. C., and in particular from 40 to 60.degree.
- the rigid polyurethane foams produced by the process according to the invention have a density of from 10 to 300 g / l, preferably from 15 to 100 g / l and in particular from 20 to 40 g / l.
- the pentane solubility was determined by gradually adding pentane to the component to be measured. Pentane was added and mixed in exactly 100 g of the component to be investigated, depending on the expected pentane solubility. If the mixture was neither turbid nor biphasic, additional pentane had to be added and mixed again.
- the glass was allowed to stand open at room temperature until the excess pentane evaporated and the remaining solution clear, and then the recovered amount of pentane was recovered.
- the glass was sealed and allowed to stand at room temperature until two phases had formed. This was followed by evaporation and weighing back.
- Pentane compatibility of polyetherester polyols according to the invention in comparison to conventional polyols is sucrose / glycerol / PO polyol having an OH number of 450 and a functionality of 5.0.
- the inventive examples have additional to the starting materials sucrose / glycerol / PO the stated proportion (in wt .-%) of fatty acid or fatty acid esters.
- the comparative example shows that the pentane compatibility of the polyols can be increased by the concomitant use of fatty acids and fatty acid monoesters.
- Polyol C from vicinal TDA 24.9%; PO 75.1%; OH number 400 mg KOH / g; Polyol D from vicinal TDA 9.2%; EO 8.6%; PO 82.2; OH number 160 mg KOH / g; Polyol E is a polyetherol based on sucrose, glycerol and propylene oxide, KOH-catalyzed, with a functionality of 5.1 and an OH number of 450 mg KOH / g;
- Stabilizer 1 silicone-containing foam stabilizer (Tegostab ® B8474 from Evonik)
- Stabilizer 2 silicone-containing foam stabilizer (Tegostab ® B8491 from Evonik)
- Catalyst 1 dimethylcyclohexylamine (DMCHA)
- Catalyst 2 pentamethyldiethylenetriamine (PMDETA)
- Catalyst 3 N, N, N-tris-dimethylaminopropylhexahydrotriazine
- Isocyanate polymer MDI with an NCO content of 31.5% by weight (Lupranat® M20)
- a polyol component was prepared from the indicated raw materials (all data in% by weight) from the indicated raw materials (all data in% by weight) a polyol component was prepared.
- a high-pressure Puromat® PU 30/80 IQ (Elastogran GmbH) with a discharge rate of 250 g / sec.
- the polyol component was mixed with the requisite amount of the indicated isocyanate so that an isocyanate index (unless otherwise noted) of 1.167 was achieved.
- the reaction mixture was injected into temperature-controlled molding tools measuring 2000 mm ⁇ 200 mm ⁇ 50 mm or 400 ⁇ 700 mm ⁇ 90 mm, where it was allowed to foam.
- the overfilling was 14.5%, ie 14.5% more reaction mixture was used than would have been necessary for complete foaming of the mold.
- Example 2 shows, compared with the formulation according to Comparative Example 1, an increased compressive strength of 5.26% with constant flow and release properties. This was not expected since it is known to those skilled in the art that the increased use of crosslinker polyols and the reduction in the level of flow polyol results in the deterioration of flow properties.
- Example 3 surprisingly shows a 0.22% -0.49% lower after-drive and thus an improvement in the mold release properties, as well as an improved flowability.
- Viscosity (25 ° C): 20477 mPas
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyethers (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014009272A MX358478B (es) | 2012-03-01 | 2013-02-18 | Polioles de poliéter-éster y el uso de los mismos para la producción de materiales de espumas rígidas de poliuretano. |
EP13704466.5A EP2820057B1 (de) | 2012-03-01 | 2013-02-18 | Polyetheresterpolyole und ihre verwendung zur herstellung von polyurethan-hartschaumstoffen |
PL13704466T PL2820057T3 (pl) | 2012-03-01 | 2013-02-18 | Polieteroestropoliole i ich zastosowanie do wytwarzania sztywnych poliuretanowych tworzyw piankowych |
JP2014559147A JP6211012B2 (ja) | 2012-03-01 | 2013-02-18 | ポリエーテルエステルポリオールおよび硬質ポリウレタンフォームを製造するためのその使用方法 |
KR1020147027053A KR102060628B1 (ko) | 2012-03-01 | 2013-02-18 | 폴리에테르에스테르 폴리올 및 경질 폴리우레탄 폼을 제조하기 위한 이의 용도 |
AU2013225268A AU2013225268B2 (en) | 2012-03-01 | 2013-02-18 | Polyetherester polyols and use thereof for producing polyurethane hard foam materials |
RU2014139360A RU2626960C2 (ru) | 2012-03-01 | 2013-02-18 | Простые полиэфиры сложных полиэфирполиолов и их применение для получения жестких пенополиуретанов |
CN201380011986.6A CN104144960A (zh) | 2012-03-01 | 2013-02-18 | 聚醚酯多元醇及其用于制备硬质聚氨酯泡沫材料的用途 |
BR112014019688A BR112014019688A8 (pt) | 2012-03-01 | 2013-02-18 | Polieteréster poliol, processo para produzir espumas rígidas de poliuretano, espuma rígida de poliuretano, mistura de poliol, e, uso de polieteréster polióis |
Applications Claiming Priority (2)
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EP12157691.2 | 2012-03-01 | ||
EP12157691 | 2012-03-01 |
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WO2013127647A1 true WO2013127647A1 (de) | 2013-09-06 |
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PCT/EP2013/053152 WO2013127647A1 (de) | 2012-03-01 | 2013-02-18 | Polyetheresterpolyole und ihre verwendung zur herstellung von polyurethan-hartschaumstoffen |
Country Status (10)
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EP (1) | EP2820057B1 (de) |
JP (1) | JP6211012B2 (de) |
KR (1) | KR102060628B1 (de) |
CN (1) | CN104144960A (de) |
AU (1) | AU2013225268B2 (de) |
BR (1) | BR112014019688A8 (de) |
MX (1) | MX358478B (de) |
PL (1) | PL2820057T3 (de) |
RU (1) | RU2626960C2 (de) |
WO (1) | WO2013127647A1 (de) |
Cited By (9)
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CN103897200A (zh) * | 2014-03-31 | 2014-07-02 | 东南大学 | 一种制备聚氨酯聚合物网络的方法 |
US8987518B2 (en) | 2013-02-28 | 2015-03-24 | Basf Se | Polyamines and process for preparation thereof |
WO2016188774A1 (en) | 2015-05-27 | 2016-12-01 | Basf Se | Use of a composition for stabilizing a geological formation in oil fields, gas fields, water pumping fields, mining or tunnel constructions |
WO2017072152A1 (de) | 2015-10-28 | 2017-05-04 | Basf Se | Polyetherester und ihre verwendung zur herstellung von polyurethan-hartschaumstoffen |
US10100513B2 (en) | 2012-11-05 | 2018-10-16 | Basf Se | Process for producing profiled elements |
WO2020165135A1 (en) | 2019-02-11 | 2020-08-20 | Basf Se | Acrylic copolymer capsule designed to open up at < 90°c for controlled release of in-situ forming pu/pir catalyst |
WO2020260235A1 (en) * | 2019-06-28 | 2020-12-30 | Basf Se | Polyol component and use thereof for the production of rigid polyurethane foams |
US10899866B2 (en) | 2015-08-10 | 2021-01-26 | Construction Research & Technology Gmbh | Process for producing a ring-opening polymerization product |
US11292868B2 (en) | 2013-11-29 | 2022-04-05 | Basf Se | Polyurethane system with long pot life and rapid hardening |
Families Citing this family (3)
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DE102016122276A1 (de) | 2016-11-18 | 2018-05-24 | H & S Anlagentechnik Gmbh | Recyclingpolyol |
CN110218293B (zh) * | 2019-06-26 | 2021-07-23 | 山东宏鑫源钢板有限公司 | 铝镁锰聚氨酯屋面板及其制备工艺 |
CN110591047A (zh) * | 2019-09-10 | 2019-12-20 | 华南理工大学 | 一种可降解聚醚型聚氨酯及其制备方法 |
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US10100513B2 (en) | 2012-11-05 | 2018-10-16 | Basf Se | Process for producing profiled elements |
US8987518B2 (en) | 2013-02-28 | 2015-03-24 | Basf Se | Polyamines and process for preparation thereof |
US11292868B2 (en) | 2013-11-29 | 2022-04-05 | Basf Se | Polyurethane system with long pot life and rapid hardening |
CN103897200A (zh) * | 2014-03-31 | 2014-07-02 | 东南大学 | 一种制备聚氨酯聚合物网络的方法 |
US10781353B2 (en) | 2015-05-27 | 2020-09-22 | Basf Se | Use of a composition for stabilizing a geological formation in oil fields, gas fields, water pumping fields, mining or tunnel constructions |
WO2016188774A1 (en) | 2015-05-27 | 2016-12-01 | Basf Se | Use of a composition for stabilizing a geological formation in oil fields, gas fields, water pumping fields, mining or tunnel constructions |
US10899866B2 (en) | 2015-08-10 | 2021-01-26 | Construction Research & Technology Gmbh | Process for producing a ring-opening polymerization product |
WO2017072152A1 (de) | 2015-10-28 | 2017-05-04 | Basf Se | Polyetherester und ihre verwendung zur herstellung von polyurethan-hartschaumstoffen |
US10723831B2 (en) | 2015-10-28 | 2020-07-28 | Basf Se | Polyetheresters and their use in rigid polyurethane foams |
WO2020165135A1 (en) | 2019-02-11 | 2020-08-20 | Basf Se | Acrylic copolymer capsule designed to open up at < 90°c for controlled release of in-situ forming pu/pir catalyst |
WO2020260235A1 (en) * | 2019-06-28 | 2020-12-30 | Basf Se | Polyol component and use thereof for the production of rigid polyurethane foams |
CN114072450A (zh) * | 2019-06-28 | 2022-02-18 | 巴斯夫欧洲公司 | 多元醇组分及其用于制备硬质聚氨酯泡沫的用途 |
CN114072450B (zh) * | 2019-06-28 | 2023-12-01 | 巴斯夫欧洲公司 | 多元醇组分及其用于制备硬质聚氨酯泡沫的用途 |
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Publication number | Publication date |
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JP6211012B2 (ja) | 2017-10-11 |
EP2820057B1 (de) | 2021-05-26 |
BR112014019688A2 (de) | 2017-06-20 |
AU2013225268A1 (en) | 2014-08-28 |
PL2820057T3 (pl) | 2021-12-27 |
MX2014009272A (es) | 2014-09-22 |
RU2014139360A (ru) | 2016-04-20 |
EP2820057A1 (de) | 2015-01-07 |
KR20140129307A (ko) | 2014-11-06 |
MX358478B (es) | 2018-08-22 |
RU2626960C2 (ru) | 2017-08-02 |
BR112014019688A8 (pt) | 2017-07-11 |
JP2015513588A (ja) | 2015-05-14 |
AU2013225268B2 (en) | 2016-05-05 |
KR102060628B1 (ko) | 2019-12-30 |
CN104144960A (zh) | 2014-11-12 |
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