WO2013114148A1 - Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation - Google Patents
Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation Download PDFInfo
- Publication number
- WO2013114148A1 WO2013114148A1 PCT/IB2012/000207 IB2012000207W WO2013114148A1 WO 2013114148 A1 WO2013114148 A1 WO 2013114148A1 IB 2012000207 W IB2012000207 W IB 2012000207W WO 2013114148 A1 WO2013114148 A1 WO 2013114148A1
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- WIPO (PCT)
- Prior art keywords
- reactor
- hydrogen
- plasma
- water
- chamber
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
- C01B3/042—Decomposition of water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0203—Preparation of oxygen from inorganic compounds
- C01B13/0207—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Definitions
- the proposed group of inventions belongs to the field of petroleum chemistry, more specifically to the plants for the catalytic processing of hydrocarbon materials.
- the shortcomings of the known plant include the considerable consumption of raw materials and the strong formation of carbon dioxide and various admixtures which escape into the atmosphere.
- a plant for the synthesis of liquid fuel is known with a reforming reactor, which transforms the hydrocarbon raw material into a synthesis gas containing gaseous carbon monoxide and gaseous hydrogen as the basic constituents, with a reactor which contained in the synthesis gas
- Patent RU 2056008 Known are a process for the conversion of solid fuel and a plasma system for its production.
- Brown coals Known is a plasma system for the conversion of solid fuel with a plasma reactor, a gas generator, a desulfurizer and a
- an arc plasma is generated, and water vapor is used as the plasma-forming gas.
- the energy consumption for the hydrogenation of the hydrogen gas from the water amounts to 4.5-5.3 KWh / 1, and the reduction of the carbon by the hydrogen at 600-800 ° C causes the consumption to almost double.
- the proposed method is technologically the closest to a plant for the conversion of hydrocarbons into gaseous and liquid fuel, which consists of the following assemblies: a reactor chamber with attached at its bottom heater and catalyst, a compressor, a reactor for the synthesis of a mixture of gasoline and diesel and a rectification column connected to this reactor (Patent RU 2291350).
- the plant allows a more complete utilization of the fuel capacity of the product gas by synthesizing gaseous and liquid fuel as well as continuous operation without interruption to reload the feedstock.
- the known solution has a significant disadvantage, namely the presence of admixtures (sulfur oxides, phosphorus, silicon, iron, etc.) in the product obtained,
- Plasmochemotron comes from the technical point of view, a Plasmochemotron next, which has a vertical transparent body with conical neck, via a mounted on the neck hydrogen lattice receiver, nozzle for introducing the plasma-forming medium (water H 2 0) and for discharging the product gases a hermetic chamber in the housing between the anode and cathode electrodes, the base of the interelectrode chamber being defined by the lower end of the anode consisting of hydrogen and oxygen over inert material, and the cathode being hermetically attached to the hydrogen raster receiver; and via the power supply lines of the voltage source, which are connected to the upper channel of the hydrogen receiver and the housing wall (see Patent RU 107161).
- the known construction of the Plasmochemotron allows the splitting of the water into hydrogen and oxygen by ignition of a plasma in the water with reduced energy consumption thanks to the high-tech surface of the electrodes.
- the known construction has several disadvantages, namely: - It is difficult to manufacture, since the cathode consists of capillaries, their production
- the cathode is difficult to clean, since the entire Plasmochemotron must be broken down at regular intervals for their purification.
- the technical solution achieved by the proposed group of inventions consists in the production of such a construction of a plant for the conversion of hydrocarbon educts into gaseous and liquid fuels, which makes it possible to produce water and coal with low energy consumption gaseous and liquid hydrocarbons, which in terms of admixtures
- the technical solution is achieved in the proposed invention, characterized in that one prepares a plant for the conversion of hydrocarbon educts in gaseous and liquid fuel, which consists of: a reactor chamber with attached at its bottom heater and catalyst, a compressor, a reactor for the synthesis of a mixture from gasoline and diesel and a rectification column connected to this reactor, which is equipped according to the invention with a Plasmochemotron, a mixer for the components of the recovered synthesis gas, a water collector, a separator and a reactor for Dimethylrelihersynthese, the Plasmochemotron a water inlet and two exits one of which is connected for the purpose of discharging the recovered oxygen and water from the plasmochemotron via the water collector to the reactor chamber, which is connected via the separator to the mixer connected to the second, the discharge of water connected to the output of the plasma chemotron and via the compressor to the dimethyl ether synthesis reactor connected to the reactor for the synthesis of gasoline and diesel, the heater of the reactor chamber
- nanoporous catalysts of copper, platinum and zeolite are used at significantly higher pressures and temperatures for the treatment of the synthesis gas produced to obtain dimethyl ether, gasoline and diesel, thereby increasing speed and degree of conversion and high purity products without those for products from crude oil cracking so typical admixtures arise.
- a Plasmochemotrons consisting of a vertical and transparent housing with conical neck, a mounted on the neck hydrogen raster receiver, nozzle for introducing the plasma-forming medium (water H 2 0) and for discharging the product gases, an in-housing hermetic chamber between the anode and cathode electrodes, wherein the base of the interelectrode chamber is bounded by the lower end of the anode made of hydrogen and oxygen over inert material and the cathode is hermetically attached to the hydrogen raster receiver, and the power supply lines of the voltage source, which are connected to the upper channel of the hydrogen receiver and the wall of the housing, in which according to the invention, the cathode is designed as a palladium-coated bellows made of porous nickel and the anode as a base on the coaxially arranged un d mounted between the folds of the bellows mounted cylinder.
- the proposed invention enables the implementation of the method for splitting the water into hydrogen and oxygen (plasma generation by Capacitive discharge in the water, ie 1.1 - 1.3 kWh / 1).
- the oxygen obtained from the water can be used for the synthesis of carbon monoxide z.
- the plant for the conversion of hydrocarbon educts into gaseous and liquid fuels consists of the reactor chamber 1 with the heater 2 and the catalyst 3, the compressor 4, the reactor for the synthesis of the mixture of gasoline and diesel 5, the this connected rectification column 6, the plasma chemotron, the mixer for the components of the synthesis gas obtained 7, the water collector 8, the separator 9 and the reactor for dimethyl ether synthesis.
- the container 10 of the reactor chamber 1 are mounted on the ground: consisting of the composites Ni 3 Al and NiAl heater 2 and the attached above him reticulated catalyst 3, which consists of MgO-based porous ceramic.
- the container 10 is for loading with the processed carbon, z. B. hard coal or lignite, thought.
- Pafur are to be used ordinary coal presses, which require no further processing (grinding).
- the reactor for the dimethyl ether synthesis and the reactor for the gasoline and diesel synthesis are carried out barothermally.
- the reactor for the dimethyl ether synthesis consists of the housing 11, to which the heater 12 is attached to the voltage source 13, and the interior 14 is to be filled with the catalyst 15, for. As nanoporous copper, thought.
- the reactor for dimethyl ether synthesis consists of the housing 5, to which the heater 16 is attached to the voltage source 17, and the interior 18 is for filling with the catalyst 19, z. As platinum and zeolite thought.
- the rectification column 6 is to be filled before start of operation with a mixture of diesel and gasoline.
- the construction of the rectification column is known, the authors make no claim in this respect novelty.
- the Plasmochemotron consists of the vertical transparent housing 21 with a conical neck, in this neck 21 housed hydrogen raster receiver, the introduction port 23 for the plasma forming medium (water H 2 0) and the outlet 24 for the gaseous products, the hermetic located in the housing Interelectrode chamber 25 with anode and cathode 26 and the power supply lines 27 of the voltage source 28, which are connected to the upper channel of the hydrogen receiver and with the housing wall 20.
- the cathode 26 is designed as a bellows, consisting of porous palladium-coated nickel and is hermetically attached to the hydrogen halftone receiver 21.
- the anode consists of the base 29, on which the coaxially arranged and located between the folds 30 of the bellows cylinder 31 are attached.
- the lower base of the Interelektrodenhunt 25 is limited by the base 29 of the anode, which consists of a hydrogen and oxygen over inert material, eg. As nickel exists.
- the housing of the Plasmochemotrons can be mounted and consist of two parts to be joined together.
- the transparent design of the housing 20, z. B. organic glass, allows an observation of the process flow of plasma dissociation of water.
- Water is introduced into the housing 20 of the plasma chemotrone via the filler neck 23 for the plasma-forming medium (water H 2 O) and kept at the specified maximum level of water dissociation.
- the voltage source 28 is turned on, voltage is applied to the power supply lines 27 and controlled by observation of the plasma, so that it does not come to a violent boiling of the water.
- the electrolytic dissociation of the water is started.
- the water level is not filled up, as this destabilizes the plasma.
- the recovered oxygen is passed through the water collector 8 together with small water vapor residues, the oxygen, for. B. by condensation using a normal water-cooled zeolite capacitor is released.
- the released oxygen is passed through the reactor chamber 1 for partial oxidation of the carbon by the oxygen.
- the formation of the carbon monoxide from the coal is carried out at a temperature below the dissociation temperature, e.g. B. at 450 - 500 ° C, carried out.
- the carbon monoxide is purified before the preparation of the mixture CO + H 2 with 60% H 2 and 40% CO as constituents in the separator 9 with the aid of liquid Mattersssorbenten.
- This device and these liquid reaction sorbents are known, and the authors raise no novelty claim in this respect (http://www.mrbinist.ru).
- the recovered hydrogen and purified carbon monoxide are further fed to the mixer 7 of the syngas components where the mixture is made.
- the synthesis gas mixture is compressed to a pressure of 100-120 atm and processed in the barothermic reactor for dimethyl ether synthesis at a temperature of 260-300 ° C with a copper catalyst and dimethyl ether is formed.
- the dimethyl ether is compressed to a pressure of 100-120 atm and heated in the presence of the catalyst of nanoporous platinum and zeolite at a temperature of 320-360 ° C.
- Water was used as a material for producing hydrogen and oxygen.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
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Abstract
L'invention concerne une installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide, comprenant : une chambre de réacteur sur le fond de laquelle sont montés un réchauffeur et un catalyseur; un compresseur; un réacteur servant à synthétiser un mélange d'essence et de gazole; ainsi qu'une colonne de rectification reliée à ce réacteur. L'installation est caractérisée en ce qu'elle est équipée d'un chémotron à plasma, d'un mélangeur pour les constituants du gaz de synthèse obtenu, d'un collecteur d'eau, d'un séparateur et d'un réacteur de synthèse de diméthyléther. Le chémotron à plasma dispose d'une tubulure d'admission d'eau et de deux sorties. Une de ces sorties est raccordée à la chambre de réacteur, par l'intermédiaire du collecteur d'eau, afin d'évacuer du chémotron à plasma l'oxygène obtenu et l'eau. La chambre de réacteur est reliée par l'intermédiaire du séparateur au mélangeur, qui est raccordé à la deuxième sortie servant à évacuer l'hydrogène du chémotron à plasma, et par l'intermédiaire du compresseur au réacteur de synthèse de diméthyléther, lequel est relié au réacteur de synthèse d'essence et de gazole. Le réchauffeur de la chambre de réacteur est fabriqué en matériaux composites Νi3Αl et NiAl; le catalyseur de la chambre, qui se présente sous la forme d'un réseau en céramique poreuse à base de MgO, est disposé au-dessus du réchauffeur; les réacteurs de synthèse du diméthyléther et du mélange essence/gazole sont réalisés de manière à être barothermiques avec les réchauffeurs disposés sur leurs boîtiers; et leurs espaces intérieurs sont destinés à recevoir les catalyseurs à base de cuivre, platine et zéolite nanoporeux.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2012/000207 WO2013114148A1 (fr) | 2012-02-02 | 2012-02-02 | Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation |
PCT/IB2012/002564 WO2013114150A1 (fr) | 2012-02-02 | 2012-11-27 | Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2012/000207 WO2013114148A1 (fr) | 2012-02-02 | 2012-02-02 | Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation |
Publications (1)
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WO2013114148A1 true WO2013114148A1 (fr) | 2013-08-08 |
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Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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PCT/IB2012/000207 WO2013114148A1 (fr) | 2012-02-02 | 2012-02-02 | Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation |
PCT/IB2012/002564 WO2013114150A1 (fr) | 2012-02-02 | 2012-11-27 | Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/IB2012/002564 WO2013114150A1 (fr) | 2012-02-02 | 2012-11-27 | Installation de conversion de substances de départ hydrocarbonées en combustible gazeux et liquide et chémotron à plasma destiné à cette installation |
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WO (2) | WO2013114148A1 (fr) |
Families Citing this family (1)
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CN106530920A (zh) * | 2016-11-16 | 2017-03-22 | 上海卫星工程研究所 | 火星表面原位生物制氧方法 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3332314A1 (de) * | 1982-09-07 | 1984-03-08 | Haldor Topsoee A/S, 2800 Lyngby | Verfahren zur herstellung von kohlenwasserstoffen |
RU2056008C1 (ru) | 1992-12-22 | 1996-03-10 | Восточно-Сибирский технологический институт | Способ переработки твердого топлива и плазменная установка для его осуществления |
RU2198156C2 (ru) | 2000-06-20 | 2003-02-10 | Александров Николай Александрович | Способ получения жидких углеводородов каталитической переработкой углеводородных газов и установка для его осуществления |
RU2291350C1 (ru) | 2005-04-22 | 2007-01-10 | Владимир Александрович Глушков | Установка переработки углеводородного сырья в газообразное и жидкое топливо |
US20070244208A1 (en) * | 2006-03-20 | 2007-10-18 | Shulenberger Arthur M | Process for producing liquid fuel from carbon dioxide and water |
US20090038958A1 (en) * | 2007-07-06 | 2009-02-12 | Coyle Edward L | Method and Apparatus for a Low Cost and Carbon Free Point of Use Dissociation of Water into Elemental Gases and Production of Hydrogen Related Power |
EP2213768A1 (fr) * | 2007-11-14 | 2010-08-04 | Fidel Franco Gonzalez | Procédé et appareil permettant d'exploiter l'hydrogène |
RU2396204C2 (ru) | 2008-10-24 | 2010-08-10 | Владимир Николаевич Серебряков | Способ получения синтез-газа и продуктов органического синтеза из диоксида углерода и воды |
RU2415904C2 (ru) | 2006-03-30 | 2011-04-10 | Ниппон Стил Инджиниринг Ко., Лтд. | Система синтеза жидкого топлива |
RU107161U1 (ru) | 2010-12-24 | 2011-08-10 | Николай Викторович СТЕПАНОВ | Плазмохимотрон |
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2006055999A1 (fr) | 2004-11-29 | 2006-06-01 | Human Oxy Vertriebs Gmbh | Procede et dispositif de production d'eau a teneur accrue en oxygene |
RU56008U1 (ru) | 2006-02-20 | 2006-08-27 | Федеральное государственное унитарное предприятие "НПО Астрофизика" | Сканирующее устройство |
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2012
- 2012-02-02 WO PCT/IB2012/000207 patent/WO2013114148A1/fr active Application Filing
- 2012-11-27 WO PCT/IB2012/002564 patent/WO2013114150A1/fr active Application Filing
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DE3332314A1 (de) * | 1982-09-07 | 1984-03-08 | Haldor Topsoee A/S, 2800 Lyngby | Verfahren zur herstellung von kohlenwasserstoffen |
RU2056008C1 (ru) | 1992-12-22 | 1996-03-10 | Восточно-Сибирский технологический институт | Способ переработки твердого топлива и плазменная установка для его осуществления |
RU2198156C2 (ru) | 2000-06-20 | 2003-02-10 | Александров Николай Александрович | Способ получения жидких углеводородов каталитической переработкой углеводородных газов и установка для его осуществления |
RU2291350C1 (ru) | 2005-04-22 | 2007-01-10 | Владимир Александрович Глушков | Установка переработки углеводородного сырья в газообразное и жидкое топливо |
US20070244208A1 (en) * | 2006-03-20 | 2007-10-18 | Shulenberger Arthur M | Process for producing liquid fuel from carbon dioxide and water |
RU2415904C2 (ru) | 2006-03-30 | 2011-04-10 | Ниппон Стил Инджиниринг Ко., Лтд. | Система синтеза жидкого топлива |
US20090038958A1 (en) * | 2007-07-06 | 2009-02-12 | Coyle Edward L | Method and Apparatus for a Low Cost and Carbon Free Point of Use Dissociation of Water into Elemental Gases and Production of Hydrogen Related Power |
EP2213768A1 (fr) * | 2007-11-14 | 2010-08-04 | Fidel Franco Gonzalez | Procédé et appareil permettant d'exploiter l'hydrogène |
RU2396204C2 (ru) | 2008-10-24 | 2010-08-10 | Владимир Николаевич Серебряков | Способ получения синтез-газа и продуктов органического синтеза из диоксида углерода и воды |
RU107161U1 (ru) | 2010-12-24 | 2011-08-10 | Николай Викторович СТЕПАНОВ | Плазмохимотрон |
Non-Patent Citations (1)
Title |
---|
LOKTEV, S.M.: "Sostojanie i perspektivy Zydkix uglevodorodov iz oksida ugleroda i vodoroda (= Aktueller Stand und Perspektiven der Synthese von Flüssigkohlenwasserstoffen aus Kohlenmonoxid und Wasserstoff", 1977, IGI, pages: 14 |
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