WO2013088054A1 - Dispositif electronique avec refroidissement par spreader a metal liquide - Google Patents
Dispositif electronique avec refroidissement par spreader a metal liquide Download PDFInfo
- Publication number
- WO2013088054A1 WO2013088054A1 PCT/FR2012/052873 FR2012052873W WO2013088054A1 WO 2013088054 A1 WO2013088054 A1 WO 2013088054A1 FR 2012052873 W FR2012052873 W FR 2012052873W WO 2013088054 A1 WO2013088054 A1 WO 2013088054A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- liquid metal
- spreader
- deformable material
- heat sink
- bar
- Prior art date
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
- H01L23/46—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements involving the transfer of heat by flowing fluids
- H01L23/473—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements involving the transfer of heat by flowing fluids by flowing liquids
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
- H05K7/20218—Modifications to facilitate cooling, ventilating, or heating using a liquid coolant without phase change in electronic enclosures
- H05K7/20263—Heat dissipaters releasing heat from coolant
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
- H05K7/20218—Modifications to facilitate cooling, ventilating, or heating using a liquid coolant without phase change in electronic enclosures
- H05K7/20272—Accessories for moving fluid, for expanding fluid, for connecting fluid conduits, for distributing fluid, for removing gas or for preventing leakage, e.g. pumps, tanks or manifolds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Definitions
- the invention relates to an electronic device, for example a semiconductor device, with liquid metal spreader cooling.
- the field of the invention is that of the thermal management of electronic components, for example semiconductors.
- an electronic component may be disposed on a cooling device through a metal plate a few millimeters thick. This plate is intended to expand the heat flow emitted and thus increase the flow section of the heat flow seen by the cooling device.
- the temperature gradients being inversely proportional to the exchange surface, the overall thermal management is greatly improved.
- FIG. 1 illustrates a dissipation source 10, for example an electronic component or a set of boxed components, arranged on a spreader 11, which allows the flow to bloom before reaching the cooling device 12 (the arrows represent the direction of the heat flux density ⁇ ).
- Such a spreader has an optimal thickness: below this value, the expansion is not sufficient which degrades the performance of the cooling device. Above this value, the thermal resistance brought by it becomes too important.
- the spreader must be very good conductor of heat, for example copper. However, copper is heavy, so aluminum is also used a lot. In addition, the thermal conductivity of copper is limited (400 Wm _1 .K Thus, the increase in large proportions of the The surface of a spreader does not make it possible to reduce the overall thermal resistance because the heat flow does not reach the ends of the spreader.
- a heat pipe 15 consists of a closed enclosure 16 whose internal walls are covered by a capillary network 17 saturated with liquid 18. It is generally composed of three parts called evaporator 20, condenser 21 and adiabatic zone. 22.
- the liquid 18 is transformed into vapor 23 which goes to the condenser 21.
- the liquid is returned to the evaporator by means of the capillary network 17 which acts as the engine of the heat pipe .
- the heat pipe 15 can operate in all positions and therefore out of gravity.
- the essential advantage of the heat pipe principle is that it generates between the evaporation zone 20 (hot source) and the condensation zone 21 (cold source) a very small temperature difference.
- the heat pipe plays the role of a "thermal short circuit".
- the steam zone of the heat pipes being a zone with very high equivalent thermal conductivity, it is possible to use them as a spreader.
- FIG 3 illustrates the operation of such a heat pipe 27 used as a heat spreader.
- This is known as a heat spreader or "vapor chamber”.
- the operating principle is the same as that of conventional heat pipes but the fluid paths are different because the hot source 25 (evaporator) is placed on a first face of the heat pipe and the cold source 26 (condenser) uses the entire second face.
- Two-phase fluid type solutions have limitations.
- aeronautics among the most restrictive limitations, one can cite the choice of the fluid, the resistance to acceleration, the performance for very high densities.
- the fluid used must be compatible with aeronautical constraints (fire constraint, European regulation Reach, .).
- fire constraint European regulation Reach, .
- the performance of these solutions strongly depends on the characteristics of the cold source and the two-phase fluid used.
- a cooling loop defined in the document referenced [1] at the end of the description thus uses a magnetohydrodynamic conduction pump (M HD DC) for a conductive fluid Gain type (gallium-l ndium) to cool an electronic component.
- the pump generates a pressure of the order of 25 kPa with a flow rate of 0.14 liter. min 1 , while the magnetic field applied in the pump is 0.9 T.
- This system is capable of cooling a heat flux density greater than 200 W.cm "2.
- M HD DC magnetohydrodynamic conduction pump
- the melting point of gallium-lndium is greater than 0 ° C, which causes a problem of operation at ambient temperatures below the melting temperature. Since the cold source is far from the electronic component, it may become impossible to start the device before the component overheats.
- the power supply of the electromagnetic pump (high current / low voltage) is complex and has a low efficiency.
- the document referenced [2] describes a spreader, in which a liquid metal, for example gallium or a gallium alloy such as Gallium-Indium-Etain, is circulated in channels machined in it, below one or more semiconductor components.
- a liquid metal for example gallium or a gallium alloy such as Gallium-Indium-Etain
- This liquid metal absorbs heat under the semiconductor component (s) and distributes this heat over the remaining surface.
- This Liquid metal is set in motion by a magnetohydrodynamic conduction pump, which is integrated in the spreader.
- Deposition of a protective material allows isolation between the channel walls and the liquid metal to avoid chemical interactions between them.
- Such a spreader has the following disadvantages: it requires a chemical deposit ("coating") to isolate the walls of the channel of the liquid metal. No cure for gallium dilatation, when it solidifies, is expected; such dilation may damage the spreader.
- the invention aims to overcome these disadvantages by proposing to circulate a liquid metal in a spreader made from a stack of several plates chemically compatible with gallium, the liquid metal absorbing heat under the heat source with low temperature rises and distributing this heat over the remaining surface of the spreader, an integrated dissipator on the face below the spreader to evacuate the heat of the liquid metal.
- the invention relates to an electronic device with cooling of a source of heat dissipation, by a liquid metal spreader, this device comprising at least one heat dissipation source comprising at least one electronic component, at least one pierced spreader. at least one liquid metal circulation channel forming a loop passing beneath a source of heat dissipation, at least one heat sink and at least one electromagnetic pump for moving the liquid metal in said at least one channel of in such a way that the liquid metal absorbs the heat dissipated by a source of heat dissipation and transports it to be evacuated by a heat sink, characterized in that each spreader comprises at least two plates of electrical insulating material arranged on both sides.
- the at least one electronic component may be a semiconductor component.
- the liquid metal may be chosen from: gallium, indium, bismuth, tin, alloys comprising gallium and / or indium and / or tin, sodium-potassium alloy.
- each bar of deformable material is made of expanded Teflon, closed-cell foam, open-cell foam with a sealed coating, or deformable solid or hollow plastic.
- the electrodes are in molybdenum, tungsten, stainless steel or copper coated with a protection ("Coating"). This last solution makes it possible to reduce the overall voltage drop and therefore the efficiency of the electromagnetic pump.
- the heat sink is a finned heatsink, whether or not associated with a fan, or a liquid forced convection cooler.
- Each electromagnetic pump may be a magnetohydrodynamic conduction pump (M HD DC). It can be integrated between the two plates of electrical insulating material of a spreader. These plates of electrical insulating material may be made of ceramic, AlN, Al 2 O 3 , Si 3 N 4 or SiC.
- the spreader comprises fins inside the at least one liquid metal circulation channel to increase the exchange surface with the liquid metal.
- the device of the invention comprises an electromagnetic pump assembly + a stack of several semiconductor components / liquid metal spreader / dissipator.
- a heat pipe is disposed between the liquid metal spreader and the heat sink.
- the device of the invention comprises:
- a first magnetic circuit comprising at least one bar of magnetic material and a permanent magnet
- a liquid metal circulation channel being formed around the bar of deformable material.
- the device of the invention comprises:
- Electrodes including an electrode disposed on the deformable material
- a liquid metal circulation channel being formed around the bar of deformable material.
- the device of the invention comprises:
- first liquid metal circulation channel being formed around the first bars of deformable material
- second liquid metal circulation channel being formed around the second bars of deformable material
- the high conductivity of the spreader makes it possible to evacuate densities of heat flux that are much greater than those reached with heat pipes. Values up to kW / cm 2 are envisaged.
- FIG. 1 illustrates the operating principle of a spreader type cooling device.
- Figure 2 illustrates the operating principle of a heat pipe.
- Figure 3 illustrates the operating principle of a heat pipe used as a heat spreader.
- FIG. 5 illustrates the operating principle of an electromagnetic pump used in the device of FIG. 4.
- Figures 6A and 6B illustrate a first embodiment of the device of the invention respectively in an exploded view and in a relief view.
- FIG 7 schematically illustrates the operation of an electromagnetic pump used in the device of the invention illustrated in Figures 6A and 6B.
- Figures 8A and 8B illustrate a second embodiment of the device of the invention respectively in an exploded view and in a relief view.
- Figures 9A and 9B illustrate a third embodiment of the device of the invention respectively in an exploded view and in a relief view.
- FIG. 11 illustrates the comparative performance of a liquid metal spreader according to the invention illustrated in FIG. 10A and of a copper spreader illustrated in FIG. 10B.
- FIGS 12A to 12B illustrate an alternative embodiment of the device of the invention.
- Figure 13 illustrates another alternative embodiment of the device of the invention.
- the device of the invention comprises the following elements: a source of heat dissipation 32, which comprises at least one electronic component, for example a semiconductor component,
- a liquid metal spreader 30 which is the hydraulic part used to evacuate the heat beneath the source of heat dissipation, made from two plates of electrical insulating material, for example ceramic, arranged on both sides, other of a deformable material around which is formed a channel for circulation of a liquid metal,
- the source of heat dissipation 32 is disposed on the upper face of the spreader 30.
- a heat sink 33 is disposed on the underside of the spreader 30.
- the reference 34 illustrates the circulation of liquid metal in at least one channel, in which one can add fins to increase the exchange surface.
- Reference 35 illustrates the inlet of the liquid metal and the reference 36 the outlet of the liquid metal.
- the device of the invention circulates a liquid metal, which is the coolant, in a thermal conductive substrate.
- This liquid metal absorbs heat under the electronic components 32 at low temperature elevations and distributes this heat over the remaining surface of the substrate.
- Liquid metals such as gallium alloys or molten salts such as sodium potassium have excellent physical properties.
- gallium which has a thermal conductivity close to 28 W.m _1 .K 1 value which is 40 times greater than that of water, makes it possible to reach very large convective exchange coefficients and thus a very high dissipation. important in terms of heat flow density.
- liquid metals also have the advantage of being good electrical conductors, which makes it possible to use electromagnetic or magnetohydrodynamic pumps 31, such as that illustrated in FIGS. 5 and 7, in which the use of Coupled with a magnetic field (magnetic induction B) and an electric current I create a Laplace force F driving the moving liquid metal.
- the invention makes it possible to circulate a liquid metal inside a spreader made from a stack of at least two plates of electrically insulating material chemically compatible with gallium, and a bar made of deformable material. which serves to absorb the dilation of the gallium during its solidification.
- the electromagnetic pump used to move the liquid metal can be integrated between the two plates. This liquid metal absorbs heat under the heat source with small temperature increases and distributes this heat over the remaining surface of the spreader.
- the dissipator which serves to evacuate the heat in the liquid metal, is carried on a surface of the spreader.
- FIGS. 6A and 6B illustrate a first embodiment of the device of the invention comprising two electromagnetic pumps each comprising a first and a second electromagnetic circuit generating a magnetic field, and electrodes carrying an electric current.
- a first magnetic circuit 40 comprising at least one bar of magnetic material 41 and a permanent magnet 42,
- the device of the invention has the following characteristics:
- the liquid metal may be chosen from: gallium, indium, bismuth, tin, alloys comprising gallium and / or indium and / or tin, sodium-potassium alloy.
- the role of the polymer in the invention is to seal the spreader and the mechanical strength of the stack, the frames serving as a housing for the device of the invention.
- This polymer can be a resin.
- the polymer of the polymer frames 43, 46 and 49 is soft. It then solidifies when allowed to dry.
- the bars of deformable material may be made of expanded teflon, closed cell foam, open cell foam with a sealed coating, or solid deformable plastic or hollow.
- the two plates of electrical insulating material may be made of ceramic, AlN, Al 2 O 3 , Si 3 N 4 or SiC which all meet the following three constraints: chemical compatibility with gallium, electrical insulation and good thermal conductivity.
- the electrode material which must be electrically conductive and compatible with gallium, may be molybdenum, tungsten, stainless steel or copper covered by a protective layer.
- the permanent magnets used to create the magnetic field in the channel can be in NdFeB.
- the heat sink may be a finned heatsink, associated with a fan or not, a liquid forced convection cooler.
- FIGS. 8A and 8B illustrate a second embodiment of the device of the invention, which corresponds to a power model comprising four electromagnetic pumps.
- a first ceramic plate 63 on which are arranged electronic circuits 64 or several electronic components 65,
- Figures 9A and 9B illustrate a third embodiment of the device of the invention, which corresponds to a model with two superposed channels of liquid metal circulation.
- FIG. 9A there are:
- first polymer gasket 86 with holding means 87, a second ceramic plate 88, a second polymer seal 90 with holding means 91,
- a first liquid metal circulation channel being formed around the first bars of deformable material 92, and a second liquid metal circulation channel being formed around the second bars of deformable material 93.
- FIG. 10A thus illustrates a liquid metal spreader 30 according to the invention (see FIG. FIG. 4) and FIG. 10B a spreader formed of a copper block In the latter case, the dissipation source 105 is at the center of the spreader 106 because this configuration makes it possible to obtain the smallest possible thermal resistance.
- the thermal resistance of the massive copper spreader is constant of value 0.16 KW-1, on the other hand the thermal resistance of the liquid metal spreader , for a flow rate of 1.5 l / min, is 0.09 KW-1, which corresponds to a decrease of 45%.
- FIGS. 12A and 12B illustrate an alternative embodiment of the device of the invention by using stacks of a plurality of vertically mounted semiconductor device assemblies (3D power module) 101 / liquid metal spreader 102 / heat sink 103, each associated with a electromagnetic pump 100.
- 3D power module vertically mounted semiconductor device assemblies
- a heat pipe 110 may be added between the liquid metal spreader 111 and the heat sink 112, to homogenize the temperature of the spreader and further improve its performance.
- the phase change of the liquid metal inside the spreader in this case, is better.
- the introduction of the liquid metal spreader 111 between the dissipation source 113, which is a semiconductor component, and the heat pipe makes it possible to reduce the heat density seen by the heat pipe and thus to distance its operating limits. (capillary limit and boiling limit in particular).
- the spreader comprises fins inside the liquid metal circulation channel to increase the exchange surface with the liquid metal, as illustrated for example in FIGS. 10A and 12A.
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- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
- Cooling Or The Like Of Electrical Apparatus (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201280061001.6A CN103999214B (zh) | 2011-12-13 | 2012-12-11 | 具有通过液体金属扩散器冷却的电子装置 |
JP2014546612A JP2015502054A (ja) | 2011-12-13 | 2012-12-11 | 液体金属スプレッダーによる冷却作用を備えた電子デバイス |
CA2856833A CA2856833C (fr) | 2011-12-13 | 2012-12-11 | Dispositif electronique avec refroidissement par epanouisseur de chaleur a metal liquide |
US14/365,538 US9693480B2 (en) | 2011-12-13 | 2012-12-11 | Electronic device with cooling by a liquid metal spreader |
RU2014124159/28A RU2604572C2 (ru) | 2011-12-13 | 2012-12-11 | Электронное устройство с охлаждением через распределитель с жидким металлом |
BR112014014348-0A BR112014014348B1 (pt) | 2011-12-13 | 2012-12-11 | Dispositivo eletrônico com resfriamento por espalhador com metal líquido |
EP12810386.8A EP2791971B1 (fr) | 2011-12-13 | 2012-12-11 | Dispositif electronique avec refroidissement par spreader a metal liquide |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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FR1161543 | 2011-12-13 | ||
FR1161543A FR2984074B1 (fr) | 2011-12-13 | 2011-12-13 | Dispositif electronique avec refroidissement par spreader a metal liquide |
Publications (1)
Publication Number | Publication Date |
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WO2013088054A1 true WO2013088054A1 (fr) | 2013-06-20 |
Family
ID=47505248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/FR2012/052873 WO2013088054A1 (fr) | 2011-12-13 | 2012-12-11 | Dispositif electronique avec refroidissement par spreader a metal liquide |
Country Status (9)
Country | Link |
---|---|
US (1) | US9693480B2 (fr) |
EP (1) | EP2791971B1 (fr) |
JP (1) | JP2015502054A (fr) |
CN (1) | CN103999214B (fr) |
BR (1) | BR112014014348B1 (fr) |
CA (1) | CA2856833C (fr) |
FR (1) | FR2984074B1 (fr) |
RU (1) | RU2604572C2 (fr) |
WO (1) | WO2013088054A1 (fr) |
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US9357670B2 (en) * | 2014-02-18 | 2016-05-31 | Lockheed Martin Corporation | Efficient heat transfer from conduction-cooled circuit cards |
US9894802B2 (en) * | 2014-05-29 | 2018-02-13 | Ge-Hitachi Nuclear Energy Americas Llc | Passive system of powering and cooling with liquid metal and method thereof |
WO2016165843A1 (fr) * | 2015-04-13 | 2016-10-20 | Abb Technology Ag | Module électronique de puissance |
DE102015106552B4 (de) * | 2015-04-28 | 2022-06-30 | Infineon Technologies Ag | Elektronisches Modul mit Fluid-Kühlkanal und Verfahren zum Herstellen desselben |
US20170363375A1 (en) * | 2015-06-30 | 2017-12-21 | Georgia Tech Research Corporation | Heat exchanger with variable density feature arrays |
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US10345874B1 (en) | 2016-05-02 | 2019-07-09 | Juniper Networks, Inc | Apparatus, system, and method for decreasing heat migration in ganged heatsinks |
US10104805B2 (en) * | 2016-05-09 | 2018-10-16 | The United States Of America As Represented By The Secretary Of The Army | Self cooling stretchable electrical circuit having a conduit forming an electrical component and containing electrically conductive liquid |
FR3061989B1 (fr) * | 2017-01-18 | 2020-02-14 | Safran | Procede de fabrication d'un module electronique de puissance par fabrication additive, substrat et module associes |
CN106793711A (zh) * | 2017-01-22 | 2017-05-31 | 北京态金科技有限公司 | 液态金属散热器 |
US10178813B2 (en) * | 2017-01-26 | 2019-01-08 | The United States Of America As Represented By The Secretary Of The Army | Stacked power module with integrated thermal management |
US10591964B1 (en) * | 2017-02-14 | 2020-03-17 | Juniper Networks, Inc | Apparatus, system, and method for improved heat spreading in heatsinks |
JP6885126B2 (ja) * | 2017-03-22 | 2021-06-09 | 富士電機株式会社 | インバータ装置 |
CN107706165B (zh) * | 2017-10-30 | 2023-08-15 | 广东西江数据科技有限公司 | 一种液态金属恒温散热装置 |
US10645844B2 (en) | 2018-04-17 | 2020-05-05 | Ge Aviation Systems Llc | Electronics cooling module |
CN108644631B (zh) * | 2018-06-16 | 2023-10-03 | 复旦大学 | 石墨烯掺杂液态金属散热的高功率密度紫外led光源模组 |
CN109193288B (zh) * | 2018-08-09 | 2023-10-10 | 云南科威液态金属谷研发有限公司 | 一种运动件间的导电系统 |
FR3088137B1 (fr) * | 2018-11-06 | 2020-11-27 | Inst Polytechnique Grenoble | Systeme electronique de puissance |
KR102153475B1 (ko) * | 2019-06-14 | 2020-09-08 | 연세대학교 산학협력단 | 채널 유동을 이용한 유연 히트싱크 및 이의 제조방법 |
US20230291295A1 (en) * | 2020-07-20 | 2023-09-14 | James L. Kirtley | Magnetohydrodynamic pump for molten salts and method of operating |
KR20220016680A (ko) | 2020-08-03 | 2022-02-10 | 삼성전자주식회사 | 열 전달 물질 및 그 제조 방법과 이를 포함하는 반도체 패키지 |
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- 2012-12-11 US US14/365,538 patent/US9693480B2/en active Active
- 2012-12-11 JP JP2014546612A patent/JP2015502054A/ja active Pending
- 2012-12-11 WO PCT/FR2012/052873 patent/WO2013088054A1/fr active Application Filing
- 2012-12-11 RU RU2014124159/28A patent/RU2604572C2/ru active
- 2012-12-11 CA CA2856833A patent/CA2856833C/fr active Active
- 2012-12-11 CN CN201280061001.6A patent/CN103999214B/zh active Active
- 2012-12-11 EP EP12810386.8A patent/EP2791971B1/fr active Active
- 2012-12-11 BR BR112014014348-0A patent/BR112014014348B1/pt active IP Right Grant
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Publication number | Priority date | Publication date | Assignee | Title |
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CN104409433A (zh) * | 2014-10-30 | 2015-03-11 | 中国科学院理化技术研究所 | 一种基于液态金属双电层效应驱动的双流体热扩展器 |
CN104409433B (zh) * | 2014-10-30 | 2017-01-25 | 中国科学院理化技术研究所 | 一种基于液态金属双电层效应驱动的双流体热扩展器 |
CN105572460A (zh) * | 2015-12-09 | 2016-05-11 | 广东威创视讯科技股份有限公司 | Led多屏拼接液冷智能监测方法及led多屏拼接系统 |
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JP2015502054A (ja) | 2015-01-19 |
BR112014014348B1 (pt) | 2020-09-08 |
FR2984074A1 (fr) | 2013-06-14 |
EP2791971B1 (fr) | 2016-08-31 |
CN103999214A (zh) | 2014-08-20 |
RU2014124159A (ru) | 2016-02-10 |
FR2984074B1 (fr) | 2014-11-28 |
US9693480B2 (en) | 2017-06-27 |
EP2791971A1 (fr) | 2014-10-22 |
CN103999214B (zh) | 2017-02-22 |
CA2856833A1 (fr) | 2013-06-20 |
RU2604572C2 (ru) | 2016-12-10 |
US20150289410A1 (en) | 2015-10-08 |
CA2856833C (fr) | 2021-01-19 |
BR112014014348A2 (pt) | 2017-06-13 |
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