WO2013071034A1 - Tissu à base de poly(téréphtalate de triméthylène) tissé, de poids léger, étirable - Google Patents

Tissu à base de poly(téréphtalate de triméthylène) tissé, de poids léger, étirable Download PDF

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Publication number
WO2013071034A1
WO2013071034A1 PCT/US2012/064341 US2012064341W WO2013071034A1 WO 2013071034 A1 WO2013071034 A1 WO 2013071034A1 US 2012064341 W US2012064341 W US 2012064341W WO 2013071034 A1 WO2013071034 A1 WO 2013071034A1
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WO
WIPO (PCT)
Prior art keywords
fabric
yarn
weft
warp
cotton
Prior art date
Application number
PCT/US2012/064341
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English (en)
Inventor
Akshay Kumar
Gowri NAGARAJAN
Original Assignee
E. I. Du Pont De Nemours And Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E. I. Du Pont De Nemours And Company filed Critical E. I. Du Pont De Nemours And Company
Publication of WO2013071034A1 publication Critical patent/WO2013071034A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00—Wearing apparel
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D10B2505/08—Upholstery, mattresses

Definitions

  • This invention relates to a low GSM stretchable woven fabric.
  • This invention particularly relates to low GSM stretchable woven fabric comprising a polytrimethylene terephthalate (PTT) based filament yarn in the weft direction.
  • PTT polytrimethylene terephthalate
  • Light weight woven fabrics are usually manufactured, from fine yarn count above 40s Ne or linear density less than 70s D, in gram per square meter (GSM) range of 70 to 130.
  • Ne or linear density less than 70s D
  • GSM gram per square meter
  • "Ne” or English count is the measure of fineness of yarns.
  • "D” or Denier is the system of measuring the weight of a continuous filament fiber.
  • Stretchable light weight fabrics that have a comfort fit with the body are not only comfortable but are also aesthetically appealing. This can be achieved if the yarn used to manufacture these light weight fabrics is made out of stretchable materials such as core spun yarns (CSY) with a Lycra ® /spandex core, or any stretchable yarn in the desired direction.
  • CSY core spun yarns
  • Lycra ® /spandex core or any stretchable yarn in the desired direction.
  • the sheath covering the Lycra ® / spandex (core) also needs to be minimal. This could expose parts of the core leading to damage to core filament during fabric washings, rubbing or abrasion during daily use. In a course of time desired properties such as stretchability of the fabric is lost. Although there is a demand for stretchable filament based low GSM fabric, such currently available in the market it are not very popular due to synthetic hand feel.
  • a stretchable woven fabric having a GSM of 70 -130, wherein the fabric comprises a weft direction yarn comprising polytrimethylene terephthalate being in the weft direction and a warp direction yarn comprising a staple fiber yarn being in the warp direction wherein the staple fiber yarn selected from a group consisting of polytrimethylene terephthalate, cotton, viscose, PET, and blends thereof.
  • a fabric as disclosed herein that is manufactured using a yarn made of PTT filament yarn derived from biological or petroleum sources.
  • the PTT yarn is used in the weft direction.
  • the PTT yarn may be 100% PTT filament , or the PTT filament may be optionally combined with other fibers and/or filaments used in the textile industry forming a yarn.
  • staple fiber yarn is used in the warp direction.
  • staple fiber yarn are: PTT, cotton, viscose, polyethylene terephthalate (PET) or blends thereof.
  • the invention provides a light weight woven fabrics that is comfortable to wear, has high stretch properties coupled with good stretch recovery and less growth.
  • the fabric in addition to the above features also addresses practical aspects of repeated / frequent wash wherein the fabric has excellent acid and alkali resistance.
  • the fabric also affords UV protection so that the wearer experiences reduced exposure to harmful UV rays.
  • An embodiment provides a fabric made of a yarn in the weft direction made of 100 % PTT filaments.
  • the embodiment includes another commercially available staple fiber yarn in the warp direction such as PTT, cotton, viscose, PET or blends thereof.
  • An aspect of the invention provides a woven low GSM fabric being 10 - 50 % of polytrimethylene terephthalate (PTT) based filament yarn wherein the fabric consists of a yarn made of 100% of
  • polytrimethylene terephthalate As used herein the terms polytrimethylene terephthalate or PTT have been used interchangeably.
  • GSM Global System for Mobile Communications
  • the fabric of this invention has a weft yarn of linear density of 30 to 150 denier, and preferably 35- 85 denier, and most preferably 75 denier. In another embodiment, the fabric of this invention has stretch properties in the range of 8 to 25%, preferably in the range of 12 to 20%.
  • the fabric of this invention has growth of less than 2.5%, and preferably less than 2%.
  • the fabric of this invention therefore has a high stretch recovery of 70 to 95 %.
  • the fabric of this invention has a durable press rating in the range of 3.0 - 4.0, and preferably in the range of 3.3 - 3.8.
  • the fabric of this invention has an ultraviolet protection (UVP) factor of 25- 105.
  • UVP ultraviolet protection
  • the fabric of this invention has excellent acid and alkali resistance.
  • the weight reduction seen in the fabrics of this invention during an acid and alkali treatment is much lesser as compared to PET based fabrics.
  • 70 -130 has stretch properties of 8 to 20%>, durable press rating of 3.0 - 4.0, ultraviolet protection factor of 40-105 (unit), less growth %> of l-2%> or combinations thereof.
  • a fabric consists of a yarn made up of 100% of polytrimethylene terephthalate in the weft direction.
  • the weft yarns are either all weft yarns of 100% PTT, or weft yarns being a combination of 100% PTT yarns and yarns made from other fibers like cotton, viscose, PET or blends thereof.
  • Other commercially available staple fiber yarns are used in the warp direction.
  • the warp yarns are selected from a group consisting of cotton, viscose, modal, PET, PTT, and blends thereof.
  • a fabric in another embodiment consists of a yarn made up of weft yarns being 100% PTT filaments combined with other fibers and/or filaments used in the textile industry forming a yarn, and other yarns made from other fibers like cotton, viscose, PET or blends thereof.
  • Other commercially available staple fiber yarns are used in the warp direction.
  • the warp yarns are selected from a group consisting of cotton, viscose, modal, PET, PTT, and blends thereof.
  • the polytrimethylene terephthalate used to make the yarns for the fabric are bio-based.
  • the fabrics of this invention can be for example selected from plain fabric, piece-dyed fabric, printed fabric, checked or striped fabric.
  • the fabrics of this invention are woven by the techniques well known in the art. Some examples of weaving processes include plain weaving, satin weaving, and twill weaving. In one embodiment, the process of manufacture of the plain fabric comprises the steps of;
  • processing steps may include the step of dyeing for a piece-dyed fabric.
  • the process further comprise the step of disperse printing for obtaining a printed fabric.
  • the stripped or checked variation of the fabric of this invention is manufactured by the steps comprising;
  • the fabrics can be printed.
  • the process of manufacture of the printed fabric comprises the steps of; a) beam warping;
  • the fabric has very soft handle like 100% superfine cotton and unlike other synthetic fiber/filament yarns.
  • steps in the manufacturing process can be omitted depending on the desired final product.
  • the steps of mercerization and bleaching are done only when cotton staple fiber yarns are also present in the fabric.
  • the process of dyeing is required only for colored fabrics. It is obvious for someone with skill in the art that the step of dyeing is omitted when a plain fabric is desired.
  • Core spun yarn is created by twisting staple fibers around a central filament core, usually made of polyester for extra strength. It is about 40% to 50% stronger than normally spun yarn of the same weight, and reduces the number of broken stitches when sewing seams and hems on denim.
  • GSM fabric weight measured in grams per square meter of fabric.
  • linear density refers to the weight of the yarn in a fixed length, and is measured in units called Denier, wherein Denier is a system of measuring the weight of a continuous filament fiber, in gram, in length of 9000m yarn.
  • a fine yarn has a denier in the range of 40 to 150 D. Linear Density is measured using standard ASTM
  • UPF is the ratio of the average effective radiation (UV-R) irradiance transmitted and calculated through air to the average effective UV-R irradiance transmitted and calculated through fabric.
  • the UPF value gives you an indication of how good a fabric is at blocking ultraviolet rays can be measured using method AATCC 183.
  • a fabric with a UPF of 20 will only allow l/20th of the ultraviolet rays to pass through it, a fabric with a UPF of 50 will only allow l/50th of the ultraviolet rays to pass through it e.g. a very good UPF value fabric is about 24-39 and above 39 fabric have excellent ultraviolet protection.
  • a "woven fabric” is used to define a fabric manufactured by interlacing of two sets of threads called warp and weft threads. Warp runs in the fabric in lengthwise direction and weft yarns goes in the fabric in width wise direction.
  • stretch refers to the ability of an article to be stretched at least eight percent in the warp or weft direction (that is, at least 1.08 times its original length), preferably at least ten percent, and then the fabric returns to a value closer to its original dimensions after release of the stretching force as per ASTM D3107-1980.
  • ASTM refers to American Society for Testing and Materials (ASTM International; West Conshohocken, PA). ASTM International publishes the Annual Book of ASTM Standards each year in print, CD and online versions. The online version was available by subscription and cost was based upon usage. All the standard tests mentioned in this invention are available to any user who refers to ASTM.
  • DP rating or "durable press rating (wrinkle resistance) can be used interchangeably.
  • the DP rating (as determined according to AATCC 143-1996 for garments or AATCC 124-2001 for fabrics) should be at least 3.0.
  • AATCC refers to American Association of Textile Chemists and Colorists. AATCC has developed more than 200 textile-related test methods and evaluation procedures. These methods are published each year in the AATCC Technical Manual.
  • the terms “high acid resistance” and “high alkali resistance” used herein mean the resistance of the fabrics towards alkaline conditions of uptol5% NaOH, and acidic strengths of up to 35% HC1.
  • the term “stretch property” or “stretch properties” used herein refers to the property of a fabric to extend to a certain length percentage when a fixed amount of load is applied.
  • a fabric with good stretch property is defined by the ability of the fabric to extend and recover to its maximum with minimum amount of growth left in the fabric, after removal of the applied load.
  • a good stretch property has approximate 15% stretch level. Stretch property and growth is measured using standard ASTM international procedures (see Table 1).
  • printed refers to the fabric which is printed in the fabric form.
  • beam warping refers to a process of winding the yarns on a warp beam.
  • the term "sizing” used herein refers to a process of coating the threads normally with starch.
  • the term “weaving” used herein refers to a process where the fabric is manufactured on a loom in weaving process with warp threads coming from weavers beam interlace, with weft yarns put in width wise direction.
  • the term "desizing” used herein refers to a process of removing the size applied on the warp with the help of enzyme or any other chemical.
  • the term “mercerization” used herein refers to a process of treating the fabric with alkali. This process removes convolutions form cotton fiber structure and make it round which improves the hand feel of the fabric make it more lustrous and in cotton base fabric it improves the strength of the fabric as well.
  • the term “scouring” refers to removal of impurities present in the fabric by treating it with soap and caustic.
  • Bleaching refers to a process where any contaminations, colored or oil stain etc., are removed from the fabric. Bleaching is normally done by treating the fabric with sodium
  • bleaching refers to a process where the fabric after bleaching is dyed with the color of interest.
  • the fabric is dyed for warp cotton yarn and weft PTT yarn so both the parts are dyed separately by their respective known dyeing method.
  • heat setting is a thermal process taking place mostly in dry heat (160 °C to 180 °C for 30 to 45 s) environment.
  • the effect of the process gives the fabric a dimensional stability and, very often, other desirable attributes like wrinkle resistance or temperature resistance.
  • finishing refers to a process performed on yarn or fabric after weaving or knitting to improve the look, performance, or "hand” (feel) of the finished textile or clothing.
  • finishing agents are bio-polishing, raising, fulling, calendaring, anti-microbial finish, anti-static, aero mechanical beating, non-slip finish etc. and others known in the art.
  • the term "sanforization” used herein refers to a process of treatment used for cotton fabrics mainly and most textiles made from natural or chemical fibers. It is a method of stretching, shrinking and fixing the woven cloth in both length and width, before cutting and producing to reduce the shrinkage which would otherwise occur after washing.
  • the term “yarn dyeing” used herein refers to a process the yarn used for in warp and weft yarns are needs to be dyed. This is done in a high temperature and high pressure dyeing machine.
  • sectional warping used herein refers to a process of winding the yarns on a drum as per color pattern. Once all the yarn patterns are wound on the drum they can be wound to a warper beam to insert in the fabric as per stripe effect needed in the fabric.
  • the bio-based polymers could be those such as Sorona® which is a unique polymer based on 1,3 propanediol (PDO). Its beneficial properties are derived from a unique, semi-crystalline molecular structure featuring a pronounced "kink.” When stress is exerted on the molecule, strain deformation occurs first in its crystalline, lower modulus regions. As stress is released, the crystalline structure locks in, allowing a complete recovery to the initial shape.
  • Sorona® is a unique polymer based on 1,3 propanediol (PDO). Its beneficial properties are derived from a unique, semi-crystalline molecular structure featuring a pronounced "kink.” When stress is exerted on the molecule, strain deformation occurs first in its crystalline, lower modulus regions. As stress is released, the crystalline structure locks in, allowing a complete recovery to the initial shape.
  • PET polyethylene terephthalate
  • nylon nylon
  • This example illustrates a process of making a piece-dyed fabric
  • Step 1 Beam Warping
  • Step 2 Sizing of the yarns
  • the warp and weft ends per inch are less by 10 % from the conventional fabric of same GSM to allow the space for the yarns to shrink which reveals as a stretch property in the final fabric.
  • Step 4 Desizing of the fabric
  • the fabric was padded using standard enzymatic desizing method for 15 to 20h.
  • the fabric was washed with hot water followed by a cold water wash in a Jigger machine.
  • Step 5 The fabric is heat set on a stenter at 180 °C for 30s to avoid wrinkle formation in dyeing process.
  • Step 6 Mercerization (only for cotton staple fiber yarns)
  • the fabric was then treated with 18.5 g/L solution of NaOH at 85 °C for 30 min in the Jigger machine.
  • Step 7 Bleaching (only for cotton staple fiber yarns)
  • the fabric was then treated with hydrogen peroxide solution (15 ml/kg) in a continuous bleaching range (CBR) machine.
  • the solution temperature is kept at 80 °C to 85 °C.
  • the cotton part of the fabric was dyed in black color using a standard continuous pad batch process at 25 °C for 12h.
  • the fabric was then washed in the Jigger machine.
  • the PTT part of the fabric was then dyed in black color at 110 °C for 40 min using a disperse dyeing process
  • the fabric was again washed in the same Jigger machine, and then dried in a stenter machine (Monforte) at 130 °C for 30s.
  • Aero mechanical finishing in Bianclani finishing machine, is done in the fabric for 30 to 40 min.
  • the fabric was then padded with standard finishing agents and passed through a heating chamber at 155 °C for 30 s.
  • the fabric was then passed through sanforizing machine adjusting skew, length and width shrinkage by passing over a rubber roller in a steam chamber (Monforte) at 50 mpm.
  • Table 1 below shows the properties of the piece-dyed fabric as prepared in example 1.
  • Table 2 below shows the properties of the fabric as prepared in example 1.
  • Step 1 Yam Dyeing
  • a cotton staple yam package of 900g was dyed with a hot brand reactive blue dye using a package dyeing process at a 90 °C for 6 h.
  • a yam pattem was made with the dyed cotton yam and white cotton yam by winding on the drum as per the color pattem. Then the pattemed sheet is wound on to a warper beam to insert in the fabric as per stripe effect needed in the fabric. 12 sections of such patterns were made from 660 cotton yam cones. The speed of the sectional warping machine was 550 mpm. Step 3: Sizing
  • the sheet of cotton yarns were further coated with modified starch using a sizing machine.
  • the sheet was run through a size liquor bath of size percentage of 7% concentration.
  • Other water soluble polymers may be added to the liquor bath e.g. polyvinyl alcohol (PVA), carboxymethyl cellulose (CMC), acrylates are used to protect the yarn. This process is repeated twice. After this the warp sheet is run through six big drying cylinders to avoid the sticking of yarns together in weavers beam. The dried sized yarn is finally wind on weaving beam.
  • the speed of sizing is normally kept 30 meters/min.
  • Warp count 80s Ne combed 100 % cotton compact yarn
  • the fabric was padded using standard enzymatic desizing method for 15 to 20h.
  • the fabric was washed with hot water followed by a cold water wash in a Jigger machine.
  • Step 6 Mercerization (only for cotton staple fiber yarns)
  • the fabric was then treated with 18.5 g/L solution of NaOH at 85 °C for 30 min in the Jigger machines.
  • the fabric was then padded with standard finishing agents and passed through a heating chamber at 155 °C for 30 s.
  • the fabric was then passed through sanforizing machine adjusting skew, length and width shrinkage by passing over a rubber roller in a steam chamber (Monforte) at 50 mpm.
  • Table 3 below shows the properties of the blue stripe fabric as prepared in example 2.
  • Table 4 below shows the properties of a micro striped stripe fabric as prepared in example 2.
  • This example illustrates a process of making a checked fabric.
  • a cotton staple yarn package of 900g was dyed with a hot brand reactive purple dye using a package dyeing process at a 90 °C for 6 h.
  • a yarn pattern was made with the dyed cotton and white cotton yarn by winding on the drum as per the color pattern. Then the patterned sheet is wound on to a warper beam to insert in the fabric as per checked effect needed in the fabric. 12 sections of such patterns were made from 660 cotton yarn cones. The speed of the sectional warping machine was 550 mpm.
  • Step 3 Sizing
  • the sheet of cotton yarns were further coated with modified starch using a sizing machine.
  • the sheet was run through a size liquor bath of size percentage of 7% concentration.
  • Other water soluble polymers may be added to the liquor bath e.g. polyvinyl alcohol (PVA), carboxymethyl cellulose (CMC), acrylates are used to protect the yarn. This process is repeated twice. After this the warp sheet is run through six big drying cylinders to avoid the sticking of yarns together in weavers beam. The dried sized yarn is finally wind on weaving beam.
  • the speed of sizing is normally kept 30 meters/min.
  • Warp count 80s Ne combed 100 % yarn dyed cotton compact yarn
  • Weft count 75D/72F draw textured Sorona® filament yarns+ Ne combed 100 % yarn dyed cotton compact yarn.
  • the warp and weft ends per inch are less by 7 % from the conventional fabric of same GSM.
  • Step 5 Desizing of the fabric
  • the fabric was padded using standard enzymatic desizing method for 15 to 20h.
  • the fabric was washed with hot water followed by a cold water wash in a Jigger machine.
  • Step 6 Mercerization (only for cotton staple fiber yarns)
  • the fabric was then passed through sanforizing machine adjusting skew, length and width shrinkage by passing over a rubber roller in a steam chamber (Monforte) at 50 mpm.
  • Table 5 below shows the properties of the checked fabric as prepared in example 3.
  • This example illustrates a process of making a Printed fabric
  • Step 1 Beam Warping
  • CMC carboxymethyl cellulose
  • acrylates are used to bind the size with yarn, protect the yarn from moth, insects etc., gives pliability to the threads required during weaving.
  • Two such size baths are used in sizing machine. After each size bath extra size is squeeze out from yarns. After this the warp sheet is run through six big drying cylinders to avoid the sticking of yarns together in weavers beam. The dried sized yarn is finally wind on weaver's beam.
  • the speed of sizing is normally kept 30 meters/min.
  • Warp count 80s Ne combed 100 % cotton combed compact yarn
  • Weft count 75D/72F draw textured Sorona® filament yarns
  • Step 4 Desizing of the fabric
  • the fabric was padded using standard enzymatic desizing method for 15 to 20h.
  • the fabric was washed with hot water followed by a cold water wash in a Jigger machine.
  • Step 5 Mercerization (only for cotton staple fiber yarns)
  • Step 6 Bleaching (only for cotton staple fiber yarns)
  • the fabric was printed on rotary screen printing machine using disperse dyes with following printing paste ingredients.
  • the recipe for disperse printing is as follows:
  • Print fabric is dried and cured at 180 °C for 4 min to fix the prints.
  • Step 8 Finishing
  • the fabric was then padded with standard finishing agents and passed through a heating chamber at 155 °C for 30 s
  • the fabric was then passed through Sanforizing machine adjusting skew, length and width shrinkage by passing over a rubber roller in a steam chamber (Monforte) at 50 mpm.
  • Table 6 shows the properties of the printed fabric as prepared in example 4.

Abstract

L'invention concerne un tissu tissé étirable ayant un GSM de 70 - 130, le tissu étant un fil de trame qui est un poly(téréphtalate de triméthylène) dans le sens de la trame et un fil de chaîne qui est un fil de fibres coupées dans le sens de la chaîne dans lequel le fil de fibres coupées est choisi parmi le poly(téréphtalate de triméthylène), le coton, la viscose, le PET et leurs mélanges.
PCT/US2012/064341 2011-11-11 2012-11-09 Tissu à base de poly(téréphtalate de triméthylène) tissé, de poids léger, étirable WO2013071034A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN3197DE2011 2011-11-11
IN3197/DEL/2011 2011-11-11

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WO2013071034A1 true WO2013071034A1 (fr) 2013-05-16

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106367865A (zh) * 2016-12-02 2017-02-01 江苏工程职业技术学院 一种涤纶纤维/粘胶纤维双层垫纱面料织物的生产工艺
CN112921470A (zh) * 2021-01-19 2021-06-08 上海题桥纺织染纱有限公司 一种幻彩面料及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006077338A (ja) * 2004-09-08 2006-03-23 Opelontex Co Ltd ストレッチシャツ地織物
JP2006214056A (ja) * 2005-02-07 2006-08-17 Toray Ind Inc 織物
CN102102259A (zh) * 2009-12-21 2011-06-22 苏州江枫丝绸有限公司 纤维素长丝弹力织物及其制造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006077338A (ja) * 2004-09-08 2006-03-23 Opelontex Co Ltd ストレッチシャツ地織物
JP2006214056A (ja) * 2005-02-07 2006-08-17 Toray Ind Inc 織物
CN102102259A (zh) * 2009-12-21 2011-06-22 苏州江枫丝绸有限公司 纤维素长丝弹力织物及其制造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106367865A (zh) * 2016-12-02 2017-02-01 江苏工程职业技术学院 一种涤纶纤维/粘胶纤维双层垫纱面料织物的生产工艺
CN112921470A (zh) * 2021-01-19 2021-06-08 上海题桥纺织染纱有限公司 一种幻彩面料及其制备方法

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