WO2013066474A3 - Procédés et appareil pour la fabrication et l'utilisation de structures en nanofeuille de pétale de graphène - Google Patents

Procédés et appareil pour la fabrication et l'utilisation de structures en nanofeuille de pétale de graphène Download PDF

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Publication number
WO2013066474A3
WO2013066474A3 PCT/US2012/051008 US2012051008W WO2013066474A3 WO 2013066474 A3 WO2013066474 A3 WO 2013066474A3 US 2012051008 W US2012051008 W US 2012051008W WO 2013066474 A3 WO2013066474 A3 WO 2013066474A3
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WIPO (PCT)
Prior art keywords
petal
graphitic
carbon nanotube
performance
mno
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PCT/US2012/051008
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English (en)
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WO2013066474A2 (fr
WO2013066474A9 (fr
Inventor
Jonathan Clay CLAUSSEN
Anurag Kumar
David Benjamin Jaroch
Timothy S. Fisher
David Marshall PORTERFIELD
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Purdue Research Foundation
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Publication date
Application filed by Purdue Research Foundation filed Critical Purdue Research Foundation
Priority to KR1020147006923A priority Critical patent/KR20140064872A/ko
Priority to EP12845269.5A priority patent/EP2744751A4/fr
Priority to CA2845539A priority patent/CA2845539A1/fr
Publication of WO2013066474A2 publication Critical patent/WO2013066474A2/fr
Publication of WO2013066474A9 publication Critical patent/WO2013066474A9/fr
Publication of WO2013066474A3 publication Critical patent/WO2013066474A3/fr
Priority to US14/181,106 priority patent/US10319537B2/en

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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28—Electrolytic cell components
    • G01N27/30—Electrodes, e.g. test electrodes; Half-cells
    • G01N27/327—Biochemical electrodes, e.g. electrical or mechanical details for in vitro measurements
    • G01N27/3275—Sensing specific biomolecules, e.g. nucleic acid strands, based on an electrode surface reaction
    • G01N27/3278—Sensing specific biomolecules, e.g. nucleic acid strands, based on an electrode surface reaction involving nanosized elements, e.g. nanogaps or nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0009—Forming specific nanostructures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/182—Graphene
    • C01B32/184—Preparation
    • C01B32/186—Preparation by chemical vapour deposition [CVD]
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28—Electrolytic cell components
    • G01N27/30—Electrodes, e.g. test electrodes; Half-cells
    • G01N27/308—Electrodes, e.g. test electrodes; Half-cells at least partially made of carbon
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28—Electrolytic cell components
    • G01N27/30—Electrodes, e.g. test electrodes; Half-cells
    • G01N27/327—Biochemical electrodes, e.g. electrical or mechanical details for in vitro measurements
    • G01N27/3271—Amperometric enzyme electrodes for analytes in body fluids, e.g. glucose in blood

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Immunology (AREA)
  • Biochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Pathology (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Hematology (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Des biocapteurs électrochimiques nanostructurés comportant de nanomatières à base de carbone offrent une plateforme de haute performance unique pour la détection électrochimique de nombreux agents biomoléculaires en raison de leurs propriétés mécaniques, électriques et chimiques uniques. Divers modes de réalisation selon l'invention présentent un biodétecteur nanostructuré pouvant être mis à l'échelle où des nanofeuilles de pétale de graphène (GPN) multi-couches, des nanoparticules de Pt et l'élément de bioreconnaissance (glucose oxydase) sont tous déposés in situ à partir d'un substrat à base de silicium. La polyvalence du biodétecteur est fortement augmentée par la modulation de la performance du biodétecteur (à savoir, sensibilité, limite de détection et plage de détection linéaire) par manipulation de la dimension de nanoparticules de Pt électrodéposées sur les GPN. Ce travail permet une conception robuste de détecteur qui est capable de détection de glucose polyvalente sur plus d'un mois avec une interférence minimale par des espèces électroactives endogènes (par exemple, acide ascorbique, acide urique, acétaminophène) couramment trouvées dans des échantillons de sérum humain. Une structure hybride dioxyde de manganèse/pétale graphitique sur des substrats de nanotube de carbone permet de parvenir à une capacitance spécifique élevée, une densité d'énergie élevée, une densité de puissance élevée et une longue durée de vie pour une application de supercondensateur flexible. Des pétales graphitiques verticaux de dimension nanométrique ont été préparés par dépôt chimique en phase vapeur assisté par plasma à micro-ondes sur des substrats de nanotube de carbone du commerce et par la suite revêtus par une couche mince de MnO2. L'architecture pétale graphitique/nanotube de carbone sans un quelconque liant assure un échafaudage efficace pour rendre maximale la performance électrochimique de MnO2. Le composite MnO2/pétale graphitique/nanotube de carbone est une matière d'électrode prometteuse pour des supercondensateurs à haute performance.
PCT/US2012/051008 2011-08-15 2012-08-15 Procédés et appareil pour la fabrication et l'utilisation de structures en nanofeuille de pétale de graphène WO2013066474A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020147006923A KR20140064872A (ko) 2011-08-15 2012-08-15 흑연 페탈 나노시트 구조의 용도, 및 제조 방법 및 장치
EP12845269.5A EP2744751A4 (fr) 2011-08-15 2012-08-15 Procédés et appareil pour la fabrication et l'utilisation de structures en nanofeuille de pétale de graphène
CA2845539A CA2845539A1 (fr) 2011-08-15 2012-08-15 Procedes et appareil pour la fabrication et l'utilisation de structures en nanofeuille de petale de graphene
US14/181,106 US10319537B2 (en) 2011-08-15 2014-02-14 Modified graphitic electrodes for electrochemical energy storage enhancement

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161523646P 2011-08-15 2011-08-15
US61/523,646 2011-08-15

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/032446 Continuation WO2014011239A2 (fr) 2011-08-15 2013-03-15 Électrodes en graphite modifiées pour l'amélioration de l'accumulation d'énergie

Related Child Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2013/032446 Continuation-In-Part WO2014011239A2 (fr) 2011-08-15 2013-03-15 Électrodes en graphite modifiées pour l'amélioration de l'accumulation d'énergie
US14/181,106 Continuation US10319537B2 (en) 2011-08-15 2014-02-14 Modified graphitic electrodes for electrochemical energy storage enhancement

Publications (3)

Publication Number Publication Date
WO2013066474A2 WO2013066474A2 (fr) 2013-05-10
WO2013066474A9 WO2013066474A9 (fr) 2013-06-20
WO2013066474A3 true WO2013066474A3 (fr) 2013-08-08

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Country Link
EP (1) EP2744751A4 (fr)
KR (1) KR20140064872A (fr)
CA (1) CA2845539A1 (fr)
WO (1) WO2013066474A2 (fr)

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Also Published As

Publication number Publication date
EP2744751A4 (fr) 2015-08-05
EP2744751A2 (fr) 2014-06-25
CA2845539A1 (fr) 2013-05-10
WO2013066474A2 (fr) 2013-05-10
KR20140064872A (ko) 2014-05-28
WO2013066474A9 (fr) 2013-06-20

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