WO2013051339A1 - 樹脂着色用色素組成物 - Google Patents
樹脂着色用色素組成物 Download PDFInfo
- Publication number
- WO2013051339A1 WO2013051339A1 PCT/JP2012/070311 JP2012070311W WO2013051339A1 WO 2013051339 A1 WO2013051339 A1 WO 2013051339A1 JP 2012070311 W JP2012070311 W JP 2012070311W WO 2013051339 A1 WO2013051339 A1 WO 2013051339A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dye
- pigment
- group
- red
- resin
- Prior art date
Links
- SVTDYSXXLJYUTM-UHFFFAOYSA-N CNc(cccc1C(c2ccccc22)=O)c1C2=O Chemical compound CNc(cccc1C(c2ccccc22)=O)c1C2=O SVTDYSXXLJYUTM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0034—Mixtures of two or more pigments or dyes of the same type
- C09B67/0038—Mixtures of anthraquinones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
- C08K5/08—Quinones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
Definitions
- the present invention relates to a black pigment composition suitable for resin coloring, and a resin material colored using the same. More specifically, the present invention relates to a black pigment composition comprising a specific blue pigment, a specific green pigment, and a quinone-based or anthrapyridone-based red pigment, and a resin material colored using the same.
- pigment coloring is often used for resin coloring.
- carbon black is often used from the viewpoint of performance, quality, and cost of the coloring pigment. That is, carbon black has an excellent light shielding performance because it has a light absorption band in a very wide range from the ultraviolet region to the infrared region.
- carbon black is often used for coloring resins such as electrical appliances and electronic parts that dislike light transmission because carbon black is less decomposed by ultraviolet rays and less expensive.
- the carbon black pigment has conductivity, it is difficult to use it for coloring electronic parts and the like that require electrical insulation. For this reason, black pigments with low electrical conductivity are desired, but practical black pigments that do not contain carbon black or metals are not known (see Patent Documents 1 to 6, etc.).
- an object of the present invention is to provide a new dye composition for coloring a resin black without containing carbon black or metals and having low electrical conductivity.
- the red pigment is represented by the following formula (3) [Wherein R 1 is a hydrogen atom, an unsubstituted (C1-C5) alkyl group or a hydroxy (C1-C5) alkyl group, and R 2 is a hydrogen atom, an unsubstituted (C1-C5) alkyl group, phenyl An optionally substituted (C1-C5) alkoxy group, or a substituent selected from the group consisting of an unsubstituted (C1-C5) alkyl group, an unsubstituted (C1-C5) alkoxy group, a hydroxyl group and a halogen atom R 3 is a hydrogen atom, a hydroxyl group or an amino group.
- the dye composition according to item [1] which is a quinone compound represented by the formula: [3]. Furthermore, the pigment
- Based on the total weight of the dye composition 5 to 25% by weight of the blue dye of formula (1), 20 to 75% by weight of the green dye of formula (2), and 5 to 30% by weight of formula
- the black pigment composition according to the present invention which is blended with a specific blue pigment, a specific green pigment, and a quinone or anthrapyridone red pigment, has a preferable color tone, excellent concealability and color developability, Low conductivity. Therefore, the resin material colored using this pigment composition is suitable as a material for electric products and electronic parts.
- the black pigment composition of the present invention is a mixed pigment obtained by blending the blue pigment represented by the formula (1), the green pigment represented by the formula (2), and the quinone or anthrapyridone red pigment. Containing.
- the blue pigment represented by the formula (1) is C.I. I. Solvent Blue 83.
- dye can also be manufactured based on a well-known method, you may use a commercially available pigment
- the green pigment represented by the formula (2) is C.I. I. Solvent Green 3. Although this pigment
- the quinone or anthrapyridone red pigment is not particularly limited, and a known quinone or anthrapyridone red pigment can be used.
- a known quinone or anthrapyridone red pigment can be used.
- Solvent Red 149 C.I. I. Solvent Red 150, C.I. I. Solvent Red 151, C.I. I. Solvent Red 168, C.I. I. Solvent Red 169, C.I. I. Solvent Red 181, C.I. I. Solvent Red 190, C.I. I. Solvent Red 191, C.I. I. Solvent Red 207, C.I. I. Solvent Red 222, C.I. I. Disperse Red 3, C.I. I. Disperse Red 4, C.I. I. Disperse Red 9, C.I. I. Disperse Red 11, C.I. I. Disperse Red 15, C.I. I. Disperse Red 22, C.I. I.
- Disperse Red 53 C.I. I. Disperse Red 55, C.I. I. Disperse Red 55.1, C.I. I. Disperse Red 59, C.I. I. Disperse Red 60, C.I. I. Disperse Red 70, C.I. I. Disperse Red 75, C.I. I. Disperse Red 86, C.I. I. Disperse Red 91, C.I. I. Disperse Red 92, C.I. I. Disperse Red 93, C.I. I. Disperse Red 104, C.I. I. Disperse Red 121, C.I. I. Disperse Red 127, C.I. I. Disperse Red 132, C.I. I.
- Disperse Red 146 C.I. I. Disperse Red 150, C.I. I. Disperse Red 159, C.I. I. Disperse Red 164, C.I. I. Disperse Red 165, C.I. I. Disperse Red 189, C.I. I. Disperse Red 190, C.I. I. Disperse Red 191, C.I. I. Disperse Red 204, C.I. I. Disperse Red 207, C.I. I. Disperse Red 229, C.I. I. Disperse Red 259, C.I. I. Disperse Red 260, C.I. I. Disperse Red 283, C.I. I. Disperse Red 288, C.I. I. Disperse Red 302 etc. are mentioned. Although these pigment
- the quinone-based red pigment preferably, the formula (3) [wherein R 1 is a hydrogen atom, an unsubstituted (C1-C5) alkyl group or a hydroxy (C1-C5) alkyl group, and R 2 is , A hydrogen atom, an unsubstituted (C1-C5) alkyl group, an optionally substituted (C1-C5) alkoxy group, or an unsubstituted (C1-C5) alkyl group, unsubstituted (C1-C5) It is a phenoxy group which may have a substituent selected from the group consisting of an alkoxy group, a hydroxyl group and a halogen atom, and R 3 is a hydrogen atom, a hydroxyl group or an amino group. ] The compound shown by this is mentioned.
- Examples of the unsubstituted (C1 to C5) alkyl group include linear or branched alkyl groups having 1 to 5 carbon atoms. Examples thereof include a methyl group, an ethyl group, an n-propyl group, an i-propyl group, an n-butyl group, an s-butyl group, a t-butyl group, and an n-pentyl group.
- the hydroxy (C1 to C5) alkyl group is a compound in which a hydroxyl group is substituted with the unsubstituted (C1 to C5) alkyl group.
- the substitution position is not particularly limited, and examples thereof include a 2-hydroxyethyl group.
- the (C1 to C5) alkoxy group in the (C1 to C5) alkoxy group optionally having a phenyl group is a group in which the (C1 to C5) alkyl group is bonded to an oxygen atom.
- Examples include methoxy group, ethoxy group, n-propoxy group, i-propoxy group, n-butoxy group, s-butoxy group, t-butoxy group, n-pentyloxy group and the like.
- the substitution position is not particularly limited, and examples thereof include a 2-phenethyl group.
- the phenyl group may have a substituent.
- substituents examples include a methyl group, an ethyl group, an n-propyl group, an i-propyl group, an n-butyl group, a methoxy group, and an ethoxy group.
- N-propoxy group, i-propoxy group, n-butoxy group, hydroxyl group, chloro group, bromo group and the like, and the number and position of substitution are not particularly limited.
- Examples of the substituent in the phenoxy group which may have a substituent selected from the group consisting of an unsubstituted (C1-C5) alkyl group, an unsubstituted (C1-C5) alkoxy group, a hydroxyl group and a halogen atom include, for example, Methyl, ethyl, n-propyl, i-propyl, n-butyl, methoxy, ethoxy, n-propoxy, i-propoxy, n-butoxy, hydroxyl, chloro, bromo, etc. There are no particular limitations on the number and position of substitution of the substituent.
- Examples of the quinone red dye represented by the formula (3) include C.I. I. Solvent Red 111, C.I. I. Solvent Red 146, C.I. I. Solvent Red 147, C.I. I. Solvent Red 169, C.I. I. Solvent Red 222, C.I. I. Disperse Red 4, C.I. I. Disperse Red 11, C.I. I. Disperse Red 22, C.I. I. Disperse Red 59, C.I. I. Disperse Red 75, C.I. I. Disperse red 146 etc. are mentioned.
- the black dye composition of the present invention is not particularly limited, but based on the total weight of the dye composition, 5 to 25% by weight of the blue dye represented by the formula (1), 20 to 75% by weight of the formula It is preferable to contain a green pigment represented by (2) and 5 to 30% by weight of a red pigment represented by formula (3).
- the black pigment composition of the present invention is mixed with other pigments, additives, solvents, etc., in order to adjust the color tone, or to adjust characteristics such as fastness, coloring, etc., and compoundability in the resin. May be used.
- the black pigment composition of the present invention may be composed of a pigment alone. In addition, other pigments and additives may be added separately during coloring.
- the additive examples include a dispersant, a surfactant, an ultraviolet absorber, a weathering agent, an antioxidant, an antistatic agent, a flame retardant, and other agents.
- dyes colorants other than blue, green, and red
- yellow to orange dyes can be used.
- the amount of the other dye in the black dye composition is not particularly limited, but may be 0 wt% or more and 70 wt% or less based on the total weight of the dye composition, and more generally 3 wt%. % To 50% by weight.
- yellow to orange dyes examples include azo dyes, quinone dyes, coumarin dyes, naphthalimide dyes, and the like. Some of the examples are given in the examples below, but the invention is not limited thereto. “Yellow to orange dye” as used herein refers to any of the dyes that gradually increase in darkness from the dye generally referred to as yellow, and that includes the dye generally referred to as orange. And may be expressed as “yellow to orange dye”.
- the black pigment composition of the present invention can be kneaded with resin monomers and resin pellets to obtain a colored resin material.
- the colored resin material can be colored by a commonly used method using active energy rays or heat.
- the amount of the black pigment composition used is arbitrary, but is preferably about 0.01 to 10%, particularly preferably about 0.05 to 5%, based on the resin weight.
- Examples of the resin used for coloring include phenol resin, epoxy resin, melamine resin, urea resin, polyphenylene ether resin, polyester resin, polyurethane resin, polyimide resin, polyamide resin, nylon resin, polybutylene terephthal resin, polycarbonate resin , Polyethylene resin, polypropylene resin, polychlorinated resin, silicone resin, polystyrene resin, Teflon (registered trademark) resin, polysulfone resin, polyether sulfone resin, ABS resin, polyacrylic resin, etc. is not.
- the compounds represented by formula (3-1) to formula (3-7) in the table (compound group satisfying the definition of formula (3)), and formulas (4) to (8) which are yellow to orange dyes.
- the structure of the compound represented by) is shown below.
- the substitution position of the methoxy group of the compound represented by the formula (6) is not particularly limited and may be a mixture thereof. I. Disperse yellow 71 was used.
- Examples 13 to 24 Use in various resin materials
- a polystyrene resin (trade name Stylon 666, manufactured by Asahi Kasei Kogyo Co., Ltd.) at a weight concentration of 0.2% or 1.0%, and a molding temperature of 240
- Colored polystyrene resin pieces (65 mm ⁇ 44 mm ⁇ 3 mm) were prepared at ° C. All colored polystyrene resin pieces showed excellent hiding and coloring properties.
- ABS resin (trade name ABS10 manufactured by Nippon Synthetic Chemical Co., Ltd.), polycarbonate resin (trade name Iupilon 2000 manufactured by Mitsubishi Gas Chemical Co., Ltd.), and nylon resin (trade name Amilan CM1001 manufactured by Toray Industries, Inc.)
- ABS resin trade name ABS10 manufactured by Nippon Synthetic Chemical Co., Ltd.
- polycarbonate resin trade name Iupilon 2000 manufactured by Mitsubishi Gas Chemical Co., Ltd.
- nylon resin trade name Amilan CM1001 manufactured by Toray Industries, Inc.
- the specific resistivity of the polystyrene resin pieces not containing the dye and the polystyrene resin pieces mixed with the dye compositions of Examples 5 and 7 were 10 15 ⁇ m or more.
- the specific resistance of the polystyrene resin mixed with 1.0% of the carbon black pigment of Comparative Example 1 was 10 13 ⁇ m, and the insulation was low.
- the black dye composition of the present invention is not inferior in hiding property and coloring property as compared with the carbon black pigment, has a large electrical resistivity, and exhibits excellent performance. I understood.
- the black dye composition according to the present invention has a preferable color tone, is excellent in concealability and color developability, and has a low electrical conductivity
- the resin material colored using this dye composition is a material of an electric product, an electronic material. It is suitably used as a part.
Abstract
Description
[1].下記式(1)で示される青色色素、
下記式(2)で示される緑色色素、および
キノン系もしくはアントラピリドン系の赤色色素を配合して得られる混合色素を含有する黒色用色素組成物。
[2].赤色色素が、下記式(3)
[式中、R1は、水素原子、無置換(C1~C5)アルキル基またはヒドロキシ(C1~C5)アルキル基であり、R2は、水素原子、無置換(C1~C5)アルキル基、フェニル基を有していてもよい(C1~C5)アルコキシ基、または、無置換(C1~C5)アルキル基、無置換(C1~C5)アルコキシ基、水酸基およびハロゲン原子からなる群から選ばれる置換基を有していてもよいフェノキシ基であり、R3は、水素原子、水酸基またはアミノ基である。]
で示されるキノン系化合物である上記[1]項に記載の色素組成物。
[3].更に、黄色から橙色の色素を含む上記[2]項に記載の色素組成物。
[4].色素組成物の全重量を基準として、5~25重量%の式(1)で示される青色色素、20~75重量%の式(2)で示される緑色色素、および5~30重量%の式(3)で示される赤色色素を含む上記[2]または[3]項に記載の色素組成物。
[5].上記[1]~[4]項のいずれかに記載の色素組成物で着色された樹脂材料。
該ヒドロキシ(C1~C5)アルキル基は、水酸基が前記無置換(C1~C5)アルキル基に置換した化合物である。置換位置は、特に限定されず、例えば2-ヒドロキシエチル基等が挙げられる。
黒色用色素組成物
以下の表1に示す配合割合により各色素成分を混合して、本発明の黒色用色素組成物を製造した。
各種樹脂材料への使用
ポリスチレン樹脂(旭化成工業株式会社製 商品名スタイロン666)に、実施例1~12の各色素組成物を重量濃度0.2%または1.0%で混入し、成型温度240℃にて着色ポリスチレン樹脂片(65mm×44mm×3mm)を作成した。
すべての着色ポリスチレン樹脂片が、優れた隠蔽性と発色性を示した。
すべての着色樹脂片が、優れた隠蔽性と発色性を示した。
ポリスチレン樹脂(旭化成工業株式会社製 商品名スタイロン666)に、カーボンブラック顔料(エボニック・デグサ社製 商品名NEROX305 塗料向けカーボンブラック)を、0.2%および1.0%の各々の重量濃度で混入し、成型温度240℃にて着色ポリスチレン樹脂片(65mm×44mm×3mm)を作成した。
いずれの着色ポリスチレン樹脂片も、優れた隠蔽性を示したが、カーボンブラック1.0%混入のものは表面が荒れ発色性が良くなかった。
前記の実施例5の色素組成物、実施例7の色素組成物、比較例1のカーボンブラック顔料のそれぞれを1.0%用いて、上記同様に作成した着色ポリスチレン樹脂片と、色素を入れていないポリスチレン樹脂片の比抵抗率を測定した。なお、ここでの比抵抗率の測定は、(株)三菱化学アナリテック製 ハイレスタUP MCP-HT450型 抵抗率計を使用し、JIS K6911準拠で行った。
Claims (5)
- 更に、黄色から橙色の色素を含む請求項2に記載の色素組成物。
- 色素組成物の全重量を基準として、5~25重量%の式(1)で示される青色色素、20~75重量%の式(2)で示される緑色色素、および5~30重量%の式(3)で示される赤色色素を含む請求項2または3に記載の色素組成物。
- 請求項1~4のいずれか一項に記載の色素組成物で着色された樹脂材料。
Priority Applications (2)
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JP2012558104A JP5273833B1 (ja) | 2011-10-07 | 2012-08-09 | 樹脂着色用色素組成物 |
KR1020137021494A KR101563067B1 (ko) | 2011-10-07 | 2012-08-09 | 수지 착색용 염료 조성물 |
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JP2011-222678 | 2011-10-07 | ||
JP2011222678 | 2011-10-07 |
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PCT/JP2012/070311 WO2013051339A1 (ja) | 2011-10-07 | 2012-08-09 | 樹脂着色用色素組成物 |
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JP (1) | JP5273833B1 (ja) |
KR (1) | KR101563067B1 (ja) |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111621167A (zh) * | 2020-05-13 | 2020-09-04 | 浙江博澳新材料股份有限公司 | 一种高日晒牢度型分散灰至黑的蒽醌型染料混合物 |
Citations (6)
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JP2004514008A (ja) * | 2000-11-13 | 2004-05-13 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | レーザー溶接用の着色熱可塑性樹脂組成物、そのアントラキノン着色剤およびそれからなる成形品 |
WO2006109480A1 (ja) * | 2005-03-30 | 2006-10-19 | Yamamoto Chemicals, Inc. | フタロシアニン系黒色顔料及びその用途 |
JP2006328238A (ja) * | 2005-05-26 | 2006-12-07 | Yokohama National Univ | 黒色顔料及びその製造方法 |
JP2007134361A (ja) * | 2005-11-08 | 2007-05-31 | Tokai Carbon Co Ltd | 半導体封止材用着色剤及び樹脂組成物 |
JP2009282251A (ja) * | 2008-05-21 | 2009-12-03 | Sakata Corp | ブラックマトリックス用着色組成物 |
JP2011118367A (ja) * | 2009-10-26 | 2011-06-16 | Sakata Corp | ブラックマトリックス用着色組成物 |
-
2012
- 2012-08-09 KR KR1020137021494A patent/KR101563067B1/ko active IP Right Grant
- 2012-08-09 JP JP2012558104A patent/JP5273833B1/ja active Active
- 2012-08-09 WO PCT/JP2012/070311 patent/WO2013051339A1/ja active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2004514008A (ja) * | 2000-11-13 | 2004-05-13 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | レーザー溶接用の着色熱可塑性樹脂組成物、そのアントラキノン着色剤およびそれからなる成形品 |
WO2006109480A1 (ja) * | 2005-03-30 | 2006-10-19 | Yamamoto Chemicals, Inc. | フタロシアニン系黒色顔料及びその用途 |
JP2006328238A (ja) * | 2005-05-26 | 2006-12-07 | Yokohama National Univ | 黒色顔料及びその製造方法 |
JP2007134361A (ja) * | 2005-11-08 | 2007-05-31 | Tokai Carbon Co Ltd | 半導体封止材用着色剤及び樹脂組成物 |
JP2009282251A (ja) * | 2008-05-21 | 2009-12-03 | Sakata Corp | ブラックマトリックス用着色組成物 |
JP2011118367A (ja) * | 2009-10-26 | 2011-06-16 | Sakata Corp | ブラックマトリックス用着色組成物 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111621167A (zh) * | 2020-05-13 | 2020-09-04 | 浙江博澳新材料股份有限公司 | 一种高日晒牢度型分散灰至黑的蒽醌型染料混合物 |
Also Published As
Publication number | Publication date |
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JP5273833B1 (ja) | 2013-08-28 |
KR20130119972A (ko) | 2013-11-01 |
KR101563067B1 (ko) | 2015-10-23 |
JPWO2013051339A1 (ja) | 2015-03-30 |
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