WO2013041832A1 - Composition de détergent liquide - Google Patents

Composition de détergent liquide Download PDF

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Publication number
WO2013041832A1
WO2013041832A1 PCT/GB2012/050505 GB2012050505W WO2013041832A1 WO 2013041832 A1 WO2013041832 A1 WO 2013041832A1 GB 2012050505 W GB2012050505 W GB 2012050505W WO 2013041832 A1 WO2013041832 A1 WO 2013041832A1
Authority
WO
WIPO (PCT)
Prior art keywords
nonionic surfactant
moles
amount
composition
surfactant
Prior art date
Application number
PCT/GB2012/050505
Other languages
English (en)
Inventor
Dora Zamuner
Original Assignee
Reckitt Benckiser N.V.
Reckitt & Colman (Overseas) Limited
Scolan, Alexandre
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reckitt Benckiser N.V., Reckitt & Colman (Overseas) Limited, Scolan, Alexandre filed Critical Reckitt Benckiser N.V.
Priority to EP12709689.9A priority Critical patent/EP2683804A1/fr
Publication of WO2013041832A1 publication Critical patent/WO2013041832A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • This invention relates to aqueous liquid detergents, preferably for use as a laundry composition or in conjunction with a laundry detergent.
  • Liquid based laundry and additive compositions have been known for many years.
  • a major issue encountered with such compositions has been the achievement of a suitable viscosity for the formula: the liquid has to be viscous enough so that any particles are suspended yet have a sufficiently high degree of flow for ease of manufacture and dispense by a consumer. Further the liquid has to be stable for over time/shelf life of the product.
  • thickeners are used. These thickeners are rheology modifiers suitable for liquid detergents. They are used to associate a higher concentration of active ingredients and to aggregate them in a stable matrix.
  • thickening systems have been developed over the years but there is still room for improvement in such systems, particularly as regards to stability in the presence of oxidixing agents ⁇ such as H 2 O 2 ) , and for effectiveness in acidic water formulation.
  • oxidixing agents such as H 2 O 2
  • Different kinds of thickener are commercially available.
  • One class of thickener that is used extensively are those based upon polymeric-carboxylic acids and their salts .
  • an acidic bleach containing liquid detergent composition having a self thickening system which comprises (a) a nonionic surfactant in an amount of 10 to 15wt%,
  • a semi-polar nonionic surfactant e.g. amine oxide
  • a semi-polar nonionic surfactant e.g. amine oxide
  • the thickening system of the present invention it has been found that superior thickening of a liquid detergent composition can be achieved. Without wishing to be limited by theory it is postulated that the superior thickening effect is due to interaction between semi-polar nonionic surfactant and the nonionic surfactant, giving rise to a thickened liquid. Furthermore advantageously the thickening is achieved in the absence of conventional surfactants (such as LAS / mineral surfactants), which are associated with a negative environmental impact.
  • conventional surfactants such as LAS / mineral surfactants
  • the nonionic surfactant comprises an admixture of C 12- C 14 alcohols with 7 E ⁇ groups and C 12- C 16 alcohols with 3 EO groups.
  • the anionic surfactant comprises sodium lauryl sulfate.
  • the semi-polar nonionic surfactant comprises tri-methyl amine oxide.
  • the composition comprises from 0.001% to 99.99%, preferably 0.001% to 20%, preferably 4% to 18%, e.g. most preferably about 4.5% or 13%, by weight, of bleach.
  • the bleach is preferably peroxide bleach, most preferably hydrogen peroxide. Peroxide sources other than H2O2 can be used.
  • the composition comprises a surfactant.
  • the composition comprises from 0.001% to 99.99%, preferably 0.05% to 15%, e.g. about 7%, by weight of surfactant.
  • the surfactant is, for example, an anionic or nonionic surfactant or mixture thereof (most preferably a non- ionic surfactant) .
  • the nonionic surfactant is preferably a surfactant having a formula RO ( CH 2 CH 2 O ) n H wherein R is a mixture of linear, even carbon-number hydrocarbon chains ranginq from C 1 2 H 25 to C 16 H 33 and n represents the number of repeating units and is a number of from about 1 to about 12.
  • examples of other non-ionic surfactants include higher aliphatic primary alcohol containing about twelve to about 16 carbon atoms which are condensed with about three to thirteen moles of ethylene oxide .
  • nonionic surfactants include primary alcohol ethoxylates (available under the Neodol trade name from Shell Co.), such as Cn alkanol condensed with 9 moles of ethylene oxide (Neodol 1-9) , C12-13 alkanol condensed with 6.5 moles ethylene oxide (Neodol 23-6.5), C 12-13 alkanol with 9 moles of ethylene oxide (Neodol 23- 9) , C12-15 alkanol condensed with 7 or 3 moles ethylene oxide (Neodol 25-7 or Neodol 25-3) , C 14-15 alkanol condensed with 13 moles ethylene oxide (Neodol 45-13), Cg-n linear ethoxylated alcohol, averaging 2.5 moles of ethylene oxide per mole of alcohol (Neodol 91-2.5), and the like.
  • primary alcohol ethoxylates available under the Neodol trade name from Shell Co.
  • nonionic surfactants suitable for use in the present invention include ethylene oxide condensate products of secondary aliphatic alcohols containing 11 to 18 carbon atoms in a straight or branched chain configuration condensed with 5 to 30 moles of ethylene oxide.
  • examples of commercially available non-ionic de- tergents of the foregoing type are C 11-15 secondary alkanol condensed with either 9 moles of ethylene oxide (Tergitol 15-S-9) or 12 moles of ethylene oxide (Tergi- tol 15-S-12) marketed by Union Carbide, a subsidiary of Dow Chemical.
  • Octylphenoxy polyethoxyethanol type nonionic surfac- tants, for example, Triton X-100, as well as amine ox- ides can also be used as a nonionic surfactant in the present invention.
  • linear primary alcohol ethoxylates are available under the Tomadol trade name such as, for example, Tomadol 1-7, a Cn linear primary alcohol ethoxylate with 7 moles EO; Tomadol 25-7, a C 12- C 15 linear pri- mary alcohol ethoxylate with 7 moles EO; Tomadol 45-7, a C 14 -C 15 linear primary alcohol ethoxylate with 7 moles EO; and Tomadol 91-6, a Cg-Cu linear alcohol ethoxylate with 6 moles EO.
  • Tomadol 1-7 a Cn linear primary alcohol ethoxylate with 7 moles EO
  • Tomadol 25-7 a C 12- C 15 linear pri- mary alcohol ethoxylate with 7 moles EO
  • Tomadol 45-7 a C 14 -C 15 linear primary alcohol ethoxylate with 7 moles EO
  • Tomadol 91-6 a Cg-Cu linear alcohol ethoxylate with 6 moles
  • linear primary alcohol ethoxylates are available under the Lutensol trade name such as, for example, Lutensol A3N, a C 13-15 linear primary alcohol eth ⁇ oxylate with 3 moles EO; Lutensol LA60, a C 13-15 linear primary alcohol ethoxylate with 7 moles EO.
  • Genapol such as, for example, Genapol LA3, a C 13-15 linear primary alcohol ethoxylate with 3 moles EO; Genapol LA070, a C13-1S linear primary alcohol ethoxylate with 7 moles EO
  • Tomadol 45-7 a C 14- C 15 linear primary alcohol ethoxylate with 7 moles EO; and Tomadol 91-6, a C 9- C 11 linear alcohol ethoxylate with 6 moles EO.
  • nonionic surfactants are amine oxides, alkyl amide oxide surfactants.
  • Preferred anionic surfactants are frequently provided as alkali metal salts, ammonium salts, amine salts, ami- noalcohol salts or magnesium salts.
  • Contemplated as useful are one or more sulfate or sulfonate compounds including: alkyl benzene sulfates, alkyl sulfates, alkyl ether sulfates, alkylamidoether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkylsul- fonates, alkylamide sulfonates, alkylarylsulfonates, olefinsulfonates, paraffin sulfonates, alkyl sulfosucci- nates, alkyl ether sulfosuccinates, alkylamide sulfosuc- cinates, alkyl sulfosuccinamate, alkyl s
  • surfactants which may be used are alkyl naphtha- lene sulfonates and acyl / oleoyl sarcosinates and mixtures thereof.
  • the composition may various optional ingredients, including enzymes, builders, solvents, dye transfer inhibition agents, dye catchers, preservatives, anti- oxidants, anti-static agents, fragrances, odour absorbing components, optical brighteners, acidifying agents, alkalizing agents, thickeners (e.g. hydroxyethylcellu- lose and / or xanthan gum) .
  • the pH range of the fabric treatment composition is typically from about 1 to about 8, e.g. from 3 to 5, more preferably from 4 to 5. It has been noted that at these pH ranges the beneficial thickening interaction between the semi-polar nonionic surfactant and the nonionic surfactant is particularly enhanced.
  • the viscosity of the composition is ideally at least 800 cPs, more preferably at least 1000 cPs
  • the composition is preferably used in a washing machine cycle and / or as a pre-soaker / soaker in a clothes cleaning operation, e.g. as a fabric treatment composition.
  • Amine Oxide and anionic surfactant were blended first to build up an ionic structure at alkaline pH, in which non ionic surfactants were added to increase the viscosity up to the final target.
  • Sulphuric acid was added following a two step process in order to better control the pH drop along with hydrogen peroxide stabiliser insertion. Such a method of manufacturing avoids repetitive pH variations risking to reduce the viscosity of the base.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition de détergent liquide contenant un agent de blanchiment acide possédant un système auto-épaississant qui comprend (a) un tensioactif non ionique à une quantité de 10 à 15% en poids, (b) un tensioactif anionique à une quantité de 5 à 10% en poids, (c) un tensioactif non ionique semi-polaire (par exemple de l'oxyde d'amine) à une quantité de 0,1 à 5% en poids
PCT/GB2012/050505 2011-03-09 2012-03-07 Composition de détergent liquide WO2013041832A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12709689.9A EP2683804A1 (fr) 2011-03-09 2012-03-07 Composition de détergent liquide

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1103964.1 2011-03-09
GB201103964A GB201103964D0 (en) 2011-03-09 2011-03-09 Composition

Publications (1)

Publication Number Publication Date
WO2013041832A1 true WO2013041832A1 (fr) 2013-03-28

Family

ID=43923412

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2012/050505 WO2013041832A1 (fr) 2011-03-09 2012-03-07 Composition de détergent liquide

Country Status (3)

Country Link
EP (1) EP2683804A1 (fr)
GB (1) GB201103964D0 (fr)
WO (1) WO2013041832A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014190133A1 (fr) * 2013-05-24 2014-11-27 The Procter & Gamble Company Composition détergente à ph faible comprenant des tensioactifs non ioniques
US9840681B2 (en) 2013-05-24 2017-12-12 The Procter & Gamble Company Concentrated surfactant composition
US10519400B2 (en) 2013-05-24 2019-12-31 The Procter & Gamble Company Low PH detergent composition

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0188025A2 (fr) * 1985-01-03 1986-07-23 Unilever N.V. Compositions de blanchiment liquides
WO1996017044A1 (fr) * 1994-11-25 1996-06-06 The Procter & Gamble Company Compositions de blanchiment epaissies, et leur procede d'utilisation et de fabrication
WO1996019558A1 (fr) * 1994-12-21 1996-06-27 Solvay Interox Limited Compositions de peracide epaissies
EP0735131A2 (fr) * 1995-03-27 1996-10-02 The Procter & Gamble Company Utilisation des oxydes d'amine tensioactifs ayant une capacité améliorée pour l'enlèvement des taches
EP0842604A1 (fr) * 1996-11-13 1998-05-20 The Procter & Gamble Company Compositions vaporisables et leur utilisation pour désinfecter les surfaces
WO2003076559A1 (fr) * 2002-03-13 2003-09-18 Cognis Iberia, S.L. Solutions de peroxyde epaissies

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0188025A2 (fr) * 1985-01-03 1986-07-23 Unilever N.V. Compositions de blanchiment liquides
WO1996017044A1 (fr) * 1994-11-25 1996-06-06 The Procter & Gamble Company Compositions de blanchiment epaissies, et leur procede d'utilisation et de fabrication
WO1996019558A1 (fr) * 1994-12-21 1996-06-27 Solvay Interox Limited Compositions de peracide epaissies
EP0735131A2 (fr) * 1995-03-27 1996-10-02 The Procter & Gamble Company Utilisation des oxydes d'amine tensioactifs ayant une capacité améliorée pour l'enlèvement des taches
EP0842604A1 (fr) * 1996-11-13 1998-05-20 The Procter & Gamble Company Compositions vaporisables et leur utilisation pour désinfecter les surfaces
WO2003076559A1 (fr) * 2002-03-13 2003-09-18 Cognis Iberia, S.L. Solutions de peroxyde epaissies

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014190133A1 (fr) * 2013-05-24 2014-11-27 The Procter & Gamble Company Composition détergente à ph faible comprenant des tensioactifs non ioniques
CN105209587A (zh) * 2013-05-24 2015-12-30 宝洁公司 包含非离子表面活性剂的低ph洗涤剂组合物
US9267095B2 (en) 2013-05-24 2016-02-23 The Procter & Gamble Company Low pH detergent composition comprising nonionic surfactants
US9840681B2 (en) 2013-05-24 2017-12-12 The Procter & Gamble Company Concentrated surfactant composition
US10519400B2 (en) 2013-05-24 2019-12-31 The Procter & Gamble Company Low PH detergent composition

Also Published As

Publication number Publication date
EP2683804A1 (fr) 2014-01-15
GB201103964D0 (en) 2011-04-20

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