WO2012173960A1 - Receptor-catalyst growth process for carbon nanotubes - Google Patents

Receptor-catalyst growth process for carbon nanotubes Download PDF

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Publication number
WO2012173960A1
WO2012173960A1 PCT/US2012/042001 US2012042001W WO2012173960A1 WO 2012173960 A1 WO2012173960 A1 WO 2012173960A1 US 2012042001 W US2012042001 W US 2012042001W WO 2012173960 A1 WO2012173960 A1 WO 2012173960A1
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WO
WIPO (PCT)
Prior art keywords
substrate
carbon
catalyst
gas
temperature
Prior art date
Application number
PCT/US2012/042001
Other languages
English (en)
French (fr)
Inventor
Khalid Lafdi
Li LINGCHUAN
Matt BOHELE
Alex LAGOUNOV
Original Assignee
University Of Dayton
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Filing date
Publication date
Application filed by University Of Dayton filed Critical University Of Dayton
Priority to JP2014515910A priority Critical patent/JP2014523385A/ja
Priority to EP12730308.9A priority patent/EP2718228A1/en
Publication of WO2012173960A1 publication Critical patent/WO2012173960A1/en

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/70—Nanostructure
    • Y10S977/724—Devices having flexible or movable element
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/70—Nanostructure
    • Y10S977/755—Nanosheet or quantum barrier/well, i.e. layer structure having one dimension or thickness of 100 nm or less
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/70—Nanostructure
    • Y10S977/778—Nanostructure within specified host or matrix material, e.g. nanocomposite films
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/84—Manufacture, treatment, or detection of nanostructure
    • Y10S977/89—Deposition of materials, e.g. coating, cvd, or ald
    • Y10S977/891—Vapor phase deposition
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
PCT/US2012/042001 2011-06-13 2012-06-12 Receptor-catalyst growth process for carbon nanotubes WO2012173960A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2014515910A JP2014523385A (ja) 2011-06-13 2012-06-12 カーボンナノチューブ用レセプタ−触媒成長工程
EP12730308.9A EP2718228A1 (en) 2011-06-13 2012-06-12 Receptor-catalyst growth process for carbon nanotubes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161496098P 2011-06-13 2011-06-13
US61/496,098 2011-06-13

Publications (1)

Publication Number Publication Date
WO2012173960A1 true WO2012173960A1 (en) 2012-12-20

Family

ID=46395706

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/042001 WO2012173960A1 (en) 2011-06-13 2012-06-12 Receptor-catalyst growth process for carbon nanotubes

Country Status (4)

Country Link
US (1) US8895105B2 (ja)
EP (1) EP2718228A1 (ja)
JP (1) JP2014523385A (ja)
WO (1) WO2012173960A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103991858A (zh) * 2014-05-23 2014-08-20 东华大学 一种含乳糖酸修饰的多壁碳纳米管复合材料的制备方法
JP2015143169A (ja) * 2013-12-25 2015-08-06 日立造船株式会社 カーボンナノチューブ生成用基板、カーボンナノチューブ生成用基板の製造方法及びカーボンナノチューブ生成用基板の再利用方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103827025B (zh) * 2011-09-14 2016-08-24 株式会社藤仓 碳纳米纤维形成用构造体、碳纳米纤维构造体及其制造方法以及碳纳米纤维电极
WO2013180764A1 (en) 2012-01-20 2013-12-05 Free Form Fibers Llc High strength ceramic fibers and methods of fabrication
CN103145186A (zh) * 2013-04-08 2013-06-12 上海电力学院 一种具有有序宏观结构的纳米多孔BiVO4及其制备方法
JP6656620B2 (ja) * 2015-07-22 2020-03-04 国立研究開発法人産業技術総合研究所 カーボンナノチューブ被膜部材とその製造方法
WO2017223399A1 (en) * 2016-06-23 2017-12-28 Free Form Fibers, Llc Nanofiber-coated fiber and methods of making
WO2019005525A1 (en) 2017-06-26 2019-01-03 Free Form Fibers, Llc HIGH-TEMPERATURE VITRO CERAMIC MATRIX WITH INCORPORATED FIBER REINFORCEMENT FIBERS
WO2019005911A1 (en) 2017-06-27 2019-01-03 Free Form Fibers, Llc HIGH PERFORMANCE FUNCTIONAL FIBROUS STRUCTURE
CN109336096B (zh) * 2018-10-19 2023-09-26 深圳市纳设智能装备有限公司 一种开放式连续生长碳纳米材料的设备及制备方法
CN110483049B (zh) * 2019-09-23 2020-06-16 四川大学 可回弹的磁性碳泡沫及其制备方法
US11761085B2 (en) 2020-08-31 2023-09-19 Free Form Fibers, Llc Composite tape with LCVD-formed additive material in constituent layer(s)
CN112264019B (zh) * 2020-11-16 2023-10-13 南京工业大学 一种以废石膏为载体的合成碳纳米管催化剂及其制备方法和应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007136613A2 (en) * 2006-05-17 2007-11-29 University Of Dayton Method of growing carbon nanomaterials on various substrates

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4595734A (en) 1980-02-04 1986-06-17 Interplastic Corporation Molding compositions
US4349462A (en) 1980-12-24 1982-09-14 Sohio Catalytic material
US5165909A (en) 1984-12-06 1992-11-24 Hyperion Catalysis Int'l., Inc. Carbon fibrils and method for producing same
EP0222492A2 (en) 1985-10-31 1987-05-20 General Motors Corporation Pressure pulse stimulation of graphite fibre growth
DE69115076T2 (de) 1990-02-20 1996-05-09 Nat Starch Chem Invest Diarylacetylen endgekappte Polyimide.
AU8101491A (en) 1990-06-29 1992-01-23 Gui Gerard De Jager A process for manufacturing reinforced composites and filament material for use in said process
US5597611A (en) 1990-10-01 1997-01-28 Fiber Materials, Inc. Reinforced carbon composites
US5024818A (en) 1990-10-09 1991-06-18 General Motors Corporation Apparatus for forming carbon fibers
US5618875A (en) 1990-10-23 1997-04-08 Catalytic Materials Limited High performance carbon filament structures
US5374415A (en) 1993-02-03 1994-12-20 General Motors Corporation Method for forming carbon fibers
US6346189B1 (en) 1998-08-14 2002-02-12 The Board Of Trustees Of The Leland Stanford Junior University Carbon nanotube structures made using catalyst islands
US6401526B1 (en) 1999-12-10 2002-06-11 The Board Of Trustees Of The Leland Stanford Junior University Carbon nanotubes and methods of fabrication thereof using a liquid phase catalyst precursor
JP3491747B2 (ja) * 1999-12-31 2004-01-26 喜萬 中山 カーボンナノコイルの製造方法及び触媒
US20030099592A1 (en) 2000-03-03 2003-05-29 Rodriguez Nelly M. Method for preparing carbon nanostructures
WO2001085612A2 (en) 2000-05-11 2001-11-15 Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence Process for preparing carbon nanotubes
US6495258B1 (en) 2000-09-20 2002-12-17 Auburn University Structures with high number density of carbon nanotubes and 3-dimensional distribution
US6831017B1 (en) * 2002-04-05 2004-12-14 Integrated Nanosystems, Inc. Catalyst patterning for nanowire devices
TW200307773A (en) 2002-05-22 2003-12-16 Showa Denko Kk Process for producing vapor-grown carbon fibers
FR2844510B1 (fr) 2002-09-12 2006-06-16 Snecma Propulsion Solide Structure fibreuse tridimensionnelle en fibres refractaires, procede pour sa realisation et application aux materiaux composites thermostructuraux
JP2005056940A (ja) * 2003-08-07 2005-03-03 Tdk Corp 電子デバイス用基板、電子デバイスおよびそれらの製造方法
US7338684B1 (en) 2004-02-12 2008-03-04 Performance Polymer Solutions, Inc. Vapor grown carbon fiber reinforced composite materials and methods of making and using same
US20070084346A1 (en) * 2005-09-30 2007-04-19 Paul Boyle Nanostructures containing carbon nanotubes and methods of their synthesis and use
US10131991B2 (en) * 2010-02-24 2018-11-20 Uchicago Argonne, Llc Method for depositing transparent conducting oxides

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007136613A2 (en) * 2006-05-17 2007-11-29 University Of Dayton Method of growing carbon nanomaterials on various substrates

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
BRONIKOWSKI MICHAEL ET AL: "Growth of carbon nanotube bundle arrays on silicon surfaces", JOURNAL OF VACUUM SCIENCE AND TECHNOLOGY: PART A, AVS /AIP, MELVILLE, NY., US, vol. 24, no. 4, 22 June 2006 (2006-06-22), pages 1318 - 1322, XP012091077, ISSN: 0734-2101, DOI: 10.1116/1.2172943 *
CONROY D ET AL: "Carbon nanotube reactor: Ferrocene decomposition, iron particle growth, nanotube aggregation and scale-up", CHEMICAL ENGINEERING SCIENCE, OXFORD, GB, vol. 65, no. 10, 15 May 2010 (2010-05-15), pages 2965 - 2977, XP026999993, ISSN: 0009-2509, [retrieved on 20100125] *
DMITRY LYSENKOV ET AL: "Nonaligned Carbon Nanotubes Anchored on Porous Alumina: Formation, Process Modeling, Gas-Phase Analysis, and Field-Emission Properties", SMALL, vol. 3, no. 6, 4 June 2007 (2007-06-04), pages 974 - 985, XP055040906, ISSN: 1613-6810, DOI: 10.1002/smll.200600595 *
KONYA Z ET AL: "Metal mixtures catalysed carbon nanotube synthesis", AIP CONFERENCE PROCEEDINGS, AMERICAN INSTITUTE OF PHYSICS, NEW YORK, US, vol. 486, 1 January 1999 (1999-01-01), pages 249 - 253, XP008157113, ISSN: 0094-243X, [retrieved on 20080410], DOI: HTTP://DX.DOI.ORG/10.1063/1.59856 *
LEE ET AL: "Multi-barrier layer-mediated growth of carbon nanotubes", THIN SOLID FILMS, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, vol. 516, no. 11, 13 March 2008 (2008-03-13), pages 3646 - 3650, XP022525985, ISSN: 0040-6090, DOI: 10.1016/J.TSF.2007.08.106 *
MARK H. RÜMMELI ET AL: "Investigating the Outskirts of Fe and Co Catalyst Particles in Alumina-Supported Catalytic CVD Carbon Nanotube Growth", ACS NANO, vol. 4, no. 2, 23 February 2010 (2010-02-23), pages 1146 - 1152, XP055040807, ISSN: 1936-0851, DOI: 10.1021/nn9016108 *
VENEGONI D ET AL: "Parametric study for the growth of carbon nanotubes by catalytic chemical vapor deposition in a fluidized bed reactor", CARBON, ELSEVIER, OXFORD, GB, vol. 40, no. 10, 1 August 2002 (2002-08-01), pages 1799 - 1807, XP004371679, ISSN: 0008-6223, DOI: 10.1016/S0008-6223(02)00057-X *
WEI LIN ET AL: "Synthesis of High-Quality Vertically Aligned Carbon Nanotubes on Bulk Copper Substrate for Thermal Management", IEEE TRANSACTIONS ON ADVANCED PACKAGING, IEEE SERVICE CENTER, PISCATAWAY, NJ, USA, vol. 33, no. 2, 1 May 2010 (2010-05-01), pages 370 - 376, XP011346335, ISSN: 1521-3323, DOI: 10.1109/TADVP.2009.2034335 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015143169A (ja) * 2013-12-25 2015-08-06 日立造船株式会社 カーボンナノチューブ生成用基板、カーボンナノチューブ生成用基板の製造方法及びカーボンナノチューブ生成用基板の再利用方法
CN103991858A (zh) * 2014-05-23 2014-08-20 东华大学 一种含乳糖酸修饰的多壁碳纳米管复合材料的制备方法

Also Published As

Publication number Publication date
US8895105B2 (en) 2014-11-25
JP2014523385A (ja) 2014-09-11
US20120315467A1 (en) 2012-12-13
EP2718228A1 (en) 2014-04-16

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