Classifications

• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
  • A01K63/00—Receptacles for live fish, e.g. aquaria; Terraria
  • A01K63/04—Arrangements for treating water specially adapted to receptacles for live fish
  • A01K63/045—Filters for aquaria
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/02—Types of fibres, filaments or particles, self-supporting or supported materials
  • B01D2239/025—Types of fibres, filaments or particles, self-supporting or supported materials comprising nanofibres
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/04—Additives and treatments of the filtering material
  • B01D2239/0407—Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/06—Filter cloth, e.g. knitted, woven non-woven; self-supported material
  • B01D2239/0604—Arrangement of the fibres in the filtering material
  • B01D2239/0618—Non-woven
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/12—Special parameters characterising the filtering material
  • B01D2239/1225—Fibre length
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
  • B01D2239/12—Special parameters characterising the filtering material
  • B01D2239/1233—Fibre diameter
• • C—CHEMISTRY; METALLURGY
  • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
  • C02F3/00—Biological treatment of water, waste water, or sewage
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S210/00—Liquid purification or separation
  • Y10S210/902—Materials removed
  • Y10S210/903—Nitrogenous

Definitions

• the present invention relates generally to an aquarium filter, and more particularly to filter media including nanofibers, which may provide mechanical and biological filtration.
• the filter media may include bacteria preloaded on the media for triggering biological filtration according to the nitrogen cycle.
• the filter media therefore provides relatively high efficiency biological filtration without compromising chemical and/or mechanical filtration.
• Filters have been used in aquariums for many years to remove particulate matter from the aquarium water in order to keep the aquarium clean.
• the most common type of aquarium filter is a power filter which hangs on the outside of the aquarium over the top edge. It includes a siphon tube which carries water from the aquarium into a filter box. Water entering the filter box flows over various types of filter media to remove particulate matter from the water. The water passes through filter carbon to remove chemical impurities from the water which is then pumped back into the aquarium using a pump.
• power filters include the Supreme Aqua King power filter marketed by E. G. Danner Manufacturing Co., the Second Nature Whisper power filter marketed by Willinger Bros. Mfg. Co., and the Aqua Clear power filter marketed by Rolf Hagen Manufacturing Co.
• Another type of aquarium filter is a canister type filter which may be positioned outside and below the aquarium. Intake and output hoses hang over the aquarium edge and are connected to the canister filter on the floor. Water is fed by gravity through the intake hose from the aquarium to the canister. The aquarium water is both mechanically and chemically treated and pumped back into the aquarium by a pump contained in the canister.
• canister type filters include the Hagen Fluval filter marketed by Hagen USA Mfg., Co., Marine Land Canister Filter marketed by Aquaria, Inc., and Eheim Classic Canister Filters, marketed by Eheim GmbH & Co. KG.
• An internally mounted power filter is still another type of aquarium filter.
• Such a filter comprises a small canister with a built-in pump which is submerged inside the aquarium. Water enters the bottom of the canister and flows through a filter sleeve which removes particulate and chemical waste. The filtered water is then pumped out the top of the canister and back into the aquarium.
• Examples of this type of filter are the Supreme Ovation internal filter marketed by Danner Mfg. and the Hagen Fluval internal filter sold by Hagen USA Mfg. Co.
• Still another type of filter employed in aquariums is the undergravel filter which consists of a perforated raised plate which rests on the aquarium floor.
• Riser tubes are provided on either end of the filter and extend into the top of the aquarium. Gravel is placed on top of the plate to a thickness of about 2 inches. Air lines from an external pump are placed in the riser tubes to the bottom plate and an air stone is placed at the end of the air lines. Air is forced by the pump through the air stones thereby forcing air bubbles to travel up through the tubes to the water surface creating turbulence or current. Water is then pulled through the gravel and forced up the riser tubes. Waste from the aquarium is drawn through the gravel bed where bacteria break down any ammonia or nitrites to less harmful nitrates. A biological filter does not, however, remove all chemical wastes. Examples of such undergravel filters include filters marketed by Perfecto Mfg. and Penplex Mfg.
• a wet/dry trickle type filter which includes a skimmer box that hangs inside the aquarium at the top.
• Siphon tubes are provided for carrying water from the aquarium to a prefilter which is mounted directly behind the skimmer box on the outside of the aquarium.
• Water passes through foam sleeves in a pre-filter to trap particulate matter.
• the water then travels through the hose in a tank typically positioned beneath the aquarium.
• a drip plate or spray bar in a dry chamber of filters which contains a plurality of plastic biospheres. Water drips over and through the biospheres to the bottom section of the tank.
• Wet/dry filters can include mechanical, chemical and biological filters. Examples of such filters are the Plus Series trickle filter marketed by Oceanic System, Inc. and the Perfecto Wet/Dry filtration system sold by Perfecto Mfg. Co.
• Wet/dry filters may also be built into the aquarium and form a permanent part of the tank.
• One such wet/dry filter that is permanently built into the tank is marketed by Tenecor Corporation of Tempe, Ariz.
• wet/dry filter is an internally mounted wet/dry filter which includes an integrated pump and heater for small aquariums.
• the filter is placed inside the aquarium against the rear wall with the top of the filter at the water level. Water enters the filter and then passes through the filter cartridge which removes particulate and chemical waste materials. A portion of the water is then pumped into a drip plate in a dry chamber for biological filtration. The remaining water is then pumped directly back into the aquarium so as to bypass the dry area.
• One such filter is marketed by Rolf Hagen Mfg. under the trademark "Biolife" filter.
• mechanical filtration media the means by which large particles of excess food and other debris are removed, screened, or skimmed from the water, may become clogged over time, reducing their ability to function as intended.
• Chemical filtration uses activated carbon and ammonia absorbents, such as zeolite, to remove odor, colors and harmful substances, such as ammonia, from the water.
• activated carbon will also loose its effectiveness over time and will similarly need replacement.
• a filtration device for an aquarium comprising a filtering chamber for receiving water and a filter medium therein wherein the filter medium comprises fibers having a diameter from 0.1 nm to 3000 nm and an aspect ratio of length to diameter of 5: 1 to 10,000 to 1 wherein the fibers provide for colonization of nitrosomonas bacterium and/or nitrobacteria.
• the present disclosure relates to filtering media comprising fibers having a diameter from 0.1 nm to 3000 nm and an aspect ratio of length to diameter of 5: 1 to 10,000 to 1 wherein the fibers contain nitrosomonas bacterium and/or nitrobacteria or precursors thereof.
• the present disclosure relates to a method for filtering water in an aquarium comprising supplying a filter medium wherein the filter medium comprises fibers having a diameter from 0.1 nm to 3000 nm and an aspect ratio of length to diameter of 5:1 to 10,000 to 1 wherein the fibers provide for colonization of nitrosomonas bacterium and/or nitrobacteria.
• FIG. 1 illustrates a biological filtration mechanism wherein bacteria colonies change ammonia into nitrites and then nitrites into nitrates.
• FIG. 2 illustrates an embodiment of nanofibers including bacteria colonies thereon.
• FIG. 3 illustrates a shift in ammonia, nitrite and nitrate bloom curves exhibited during tank start up when utilizing the nanofibers herein.
• FIG. 4 illustrates particles including interstices.
• FIG. 5 illustrates an embodiment of filter media including nanofibers 10 in the form of a sheet.
• FIG. 6 illustrates an embodiment including a layer of filter media and other filter media or supporting layers used therewith.
• FIG. 7 illustrates an embodiment of a filter cartridge including a batt of nanofibers positioned therein in addition to other filter media.
• bacteria present within an aquarium may convert ammonia, a by-product of the fish or other species, into nitrites and then nitrites into nitrates.
• Ammonia is relatively toxic to most aquarium fishes in low concentrations of 1 to 3 ppm.
• Nitrites may be relatively less toxic to most aquarium fishes until concentrations of 30 to 40 ppm are reached and nitrates may be safe for aquarium fishes until concentrations of 300 to 400 ppm are reached.
• Nitrates may then be taken up by aquarium plants and used as vegetation building blocks.
• the present disclosure relates generally to an aquarium filter, and more particularly to filter media including nanofibers, supporting increased bacteria growth.
• the filter media may not only provide mechanical filtering for particulate matter of smaller size, but increased biological and/or chemical filtration as well.
• the bacteria growth promoted on the filter media including nanofibers 10 herein may include, for example, the nitrosomonas bacteria which typically provide conversion of ammonia ( ⁇ 3 ⁇ 4) to nitrite (N0 2 ).
• the bacteria growth promoted herein may include the nitrobacteria, which converts nitrite (N0 2 ) to nitrate (NO 3 ).
• the development and colonization of such bacteria occurs relatively more quickly during the initial cycling of a given aquarium tank while still allowing for relatively high efficiency particle and/or chemical filtration. Reference to colonization may be understood as that situation where regions of bacteria develop on or within the nanofiber substrates.
• the filter media may include, consist essentially of, or consist of nanofibers, which may exhibit diameters (or largest linear cross-sections) in the range of 0.1 nm to 3,000 nm and an average diameter (or largest linear cross-section) of 1 ⁇ or less, including all values and ranges from 0.1 nm to 1,000 nm, such as from 100 to 900 nm, 300 to 800 nm, etc. In some embodiments, up to 80 % by weight of the fibers may fall within the range of 200 nm and 800 nm.
• the filter media including the nanofibers may exhibit relatively high surface area of greater than 2 square meters per gram and up to 50 square meters per gram, including all values and ranges therein such as 2 square meters per gram to 10 square meters per gram, etc.
• the relatively high surface area may provide a greater surface area for additional bacteria growth and/or contact with a relatively greater volume of water.
• the surface of the nanofibers may be textured to further increase the surface area, providing for further bacteria growth.
• the nanofibers may also exhibit a length to diameter ratio, i.e., aspect ratio, of 5:1 or greater and up to, for example, 10,000:1, including all values and ranges therein such as 100: 1, 500:1, 1,000: 1 etc.
• the nanofibers may be formed of a thermoplastic material including polyolefins, such as polyethyelene or polypropylene; or polyesters, such as polyethylene terephthalate or polybutylene terephthalate; as well as other materials such as nylon, acrylic, cellulose, etc.
• the fibers may be provided as a bale, woven or non-woven fabric, or batt. In some embodiments, the fabric or batt may be lofted.
• the filter media may also exhibit an average pore diameter in the range of 0.1 to 16 microns, including all values and ranges therein, such as 0.1 to 2 microns, etc. Furthermore, the filter media may exhibit a basis weight of 30 grams per square meter to 70 grams per square meter, including all values and ranges therein, such as 50 grams per square meter.
• the nanofibers 10 herein are such that they may relatively more rapidly provide for beneficial bacteria growth 12 on the surface thereof while maintaining relatively high levels of particulate filtration.
• FIG. 3 illustrates a graph of relative start up time versus toxin level.
• the use of the nanofibers herein may now allow for relatively more rapid colonization and development of biological filtration requirements at tank start-up, shifting the ammonia, nitrite and nitrate, bloom curves to the left. At least one reason for this contemplated effect is that the nanofibers, while providing relatively high surface area for the nitrifying bacteria, may still provide high flow-thru and initial exchange with ammonia.
• the relatively high aspect ratio of the fibers may provide for more efficient exchange of and removal of ammonia as relatively higher proportions are bacteria are exposed to water flowing within the filter assembly.
• the structure and geometry of the nanofibers may therefore offer unexpectedly more efficient biological filtration than the porous particulate materials used in the art.
• the nanofibers herein may allow for at least 50 % or more by weight of the bacterial growth to occur on the external surface of the fiber, including all values and ranges from 50 % to 99 % by weight.
• the bacterial growth need not rely on generally round particles, although in some embodiments, such particles may be present.
• the filter media may be pre-formed into various geometries such as balls or cylindrical batts while maintaining relatively high flow-through rates.
• FIG. 5 illustrates that the filter media 16 may also be formed into sheets 18 (or pads) of given dimensions and/or various geometries.
• the sheets may be pleated, further increasing surface area of the filter media. Therefore, it may be appreciated that the filter media may be provided as bulk media or as cartridge inserts. In the case of pleated structure, multiple sheets of pleated structure may be used depending upon the needs of a given filter system. When provided as bulk media, a given amount of media may be removed from the bulk and placed into a filter assembly. When provided as a cartridge, the cartridge may be placed into the filter assembly.
• the nanofibers may be formed into a nonwoven fabric.
• the nanofibers may be produced by electrospinning, melt blowing, or other methods that may produce fibers having an average diameter of up to 1,000 nm and greater than 0.1 nm.
• the fibers may be formed into a web directly or through processes such as carding, garneting, air lying, etc.
• the fibers may be bonded, either through thermal adherence, mechanical entanglement, chemical adhesive or solvents or combinations thereof, such as thermal point bonding, calendaring with or without embossed rollers, hydroentangling, hot air knife, ultrasonic bonding. Bonding may stabilize the nonwoven fabrics.
• An example of filter media nanofibers may include EMINUS available from MILLIKEN of Spartanburg, South Carolina, which may be provided as a nonwoven fabric or batt.
• the nanofiber filter media 16 may be used alone or in combination with one or more layers of other filter media 20 or support material 22 as illustrated in FIG. 6.
• a support layer 20 of other nonwoven or woven fabrics, or foams may be provided for use in combination with the nanofiber filter media.
• the filter media 16 may be positioned within a filter cartridge frame 26 and used in combination with other media 28 useful in the filtration or treatment of aquarium water, including but not limited to, ceramic material (inorganic non-metallic solid) such as ceramic rings, biospheres, dolomite, crushed coral, crushed clam shells and like biological media which may enhance ammonia and nitrite reduction.
• filter media that may be used in conjunction with the nanofiber media herein includes activated charcoal, zeolite and like absorbents for the absorption of odors and impurities; and foam, glass fiber and like porous constructions for removing dirt and debris. Furthermore, the filter media may be treated with various additives that may separately improve bacteria growth.
• the method may include providing filter media including nanofibers that exhibit an average diameter in the range of 0.1 nm to 1,000 nm. Furthermore, the nanofibers of the filter media may exhibit a relatively high surface area of greater than 2 square meters per gram. The relatively high surface area may result in an increase in the growth of bacteria that aids in converting ammonia to nitrites, nitrites to nitrates and combinations thereof.
• aquarium water may either be passed over the filter media and/or passed through the filter media, such that a given volume of water may contact the filter media and the bacteria colonizing thereon. Therefore, also set forth herein is a method of filtering water with filter media including the nanofibers, wherein the relatively high surface area of the filter media, i.e., greater than 2 square meters per gram, may provide increased bacteria colonization, exposure to high volumes of water and higher filtration efficiency. Again, the increased amount of bacteria may then unexpectedly provide increased efficiency in converting ammonia to nitrites and then nitrites to nitrates.
• the aquariums suitable for filtration herein may be of any general size or configuration. More typically, however, the aquariums for which the benefits of utilizing the nanofibers herein is preferably realized on aquariums of 10-1000 gallons.
• the filter media herein may therefore become part of the filter system utilized in such aquaria which filtration devices may typically rely upon a filtering chamber that contains removable filter elements, and which may be in the form of canister filters, submersible filter assemblies and/or external filter assemblies, etc.
• the nanofiber filtration system herein may be provided in a form that is preloaded with the bacteria necessary for biological filtration. That is the nanofiber filtration may include nitrosomonas and nitrobacteria so that when exposed to a source of ammonia, the nitrogen cycle immediately begins with the colonization of the indicated bacteria already present on the nanofiber surface.
• the nitrosomonas this may include, but not be limited to n. aestuarii, n. communis, n. europaea, n. halphila, n. marina, n. nitrosa, n. oligotropha, and n. ureae. In the case of nitrobacteria, this may include n.
• the level of preloaded bacteria may therefore be preferably on the level of 0.1 - 10.0 percent by weight, where the bacteria may specifically be in a relatively dormant or precursor state thereby becoming active upon exposure to water flow.
• the start-up cycling of a given tank to achieve the desired control and regulation of the nitrogen cycle is relatively more rapidly achieved and a given aquarium may be stocked with fish at a relatively more rapid level (i.e., over a relatively shorter time period).

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• Life Sciences & Earth Sciences (AREA)
• Environmental Sciences (AREA)
• Marine Sciences & Fisheries (AREA)
• Animal Husbandry (AREA)
• Biodiversity & Conservation Biology (AREA)
• Farming Of Fish And Shellfish (AREA)
• Biological Treatment Of Waste Water (AREA)
• Filtering Materials (AREA)

Priority Applications (5)

Applications Claiming Priority (2)

Publications (1)

Family

ID=47292240

Family Applications (1)

Country Status (7)

Cited By (1)

Families Citing this family (7)

Citations (4)

Family Cites Families (15)

• 2011
  • 2011-07-11 US US13/179,606 patent/US8845891B2/en active Active
• 2012
  • 2012-06-08 JP JP2014514866A patent/JP2014519332A/ja active Pending
  • 2012-06-08 CA CA2836300A patent/CA2836300A1/en not_active Abandoned
  • 2012-06-08 EP EP12796448.4A patent/EP2718238A4/en not_active Withdrawn
  • 2012-06-08 CN CN201280028094.2A patent/CN103596885A/zh active Pending
  • 2012-06-08 WO PCT/US2012/041472 patent/WO2012170764A1/en not_active Ceased
  • 2012-06-08 AU AU2012267785A patent/AU2012267785B2/en active Active

Patent Citations (4)

Non-Patent Citations (1)

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