WO2012165694A1 - Appareil de stérilisation et procédé pour appareil de traitement d'eau - Google Patents

Appareil de stérilisation et procédé pour appareil de traitement d'eau Download PDF

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Publication number
WO2012165694A1
WO2012165694A1 PCT/KR2011/004812 KR2011004812W WO2012165694A1 WO 2012165694 A1 WO2012165694 A1 WO 2012165694A1 KR 2011004812 W KR2011004812 W KR 2011004812W WO 2012165694 A1 WO2012165694 A1 WO 2012165694A1
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WO
WIPO (PCT)
Prior art keywords
water
sterilizing
electrode
pipe
washing
Prior art date
Application number
PCT/KR2011/004812
Other languages
English (en)
Inventor
Soo-Young Lee
Il Chu
Sul-Hee PARK
Hyang-Kyun Oh
Eun-Sook Kwon
Ji-Yoo PARK
Original Assignee
Woongjin Coway Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Woongjin Coway Co., Ltd. filed Critical Woongjin Coway Co., Ltd.
Priority to CN201180071319.8A priority Critical patent/CN103562141B/zh
Publication of WO2012165694A1 publication Critical patent/WO2012165694A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D35/00—Filtering devices having features not specifically covered by groups B01D24/00 - B01D33/00, or for applications not specifically covered by groups B01D24/00 - B01D33/00; Auxiliary devices for filtration; Filter housing constructions
    • B01D35/14—Safety devices specially adapted for filtration; Devices for indicating clogging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D35/00—Filtering devices having features not specifically covered by groups B01D24/00 - B01D33/00, or for applications not specifically covered by groups B01D24/00 - B01D33/00; Auxiliary devices for filtration; Filter housing constructions
    • B01D35/16—Cleaning-out devices, e.g. for removing the cake from the filter casing or for evacuating the last remnants of liquid
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • C02F1/4674—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation with halogen or compound of halogens, e.g. chlorine, bromine
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104—Devices therefor; Their operating or servicing
    • C02F1/46109—Electrodes
    • C02F2001/46133—Electrodes characterised by the material
    • C02F2001/46138—Electrodes comprising a substrate and a coating
    • C02F2001/46142—Catalytic coating
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/46—Apparatus for electrochemical processes
    • C02F2201/461—Electrolysis apparatus
    • C02F2201/46105—Details relating to the electrolytic devices
    • C02F2201/4612—Controlling or monitoring

Definitions

  • the present invention relates to a sterilizing apparatus and method for a water treatment apparatus, which can sterilize and/or wash a storage tank of a water treatment apparatus and a passage connected thereto, and more particularly, to a sterilizing apparatus and method for a water treatment apparatus, which generates sterilizing/washing water containing a sterilizing material and/or a washing material by applying power to an electrode, and supplies the sterilizing/washing water to a passage, a storage tank or a water outlet cock provided inside the water treatment apparatus, whereby the passage, the storage tank or the water outlet cock may be sterilized and/or washed.
  • the term "sterilizing/washing water” refers to water containing a sterilizing material and/or a washing material generated by an electrode to which power is applied.
  • the water treatment apparatus water treatment device
  • the water treatment apparatus may be used for various purposes, for example, for industrial or home (business) uses, to treat wastewater or typical water or produce ultrapure water
  • the present invention relates to a water treatment apparatus used for drinking purposes and a sterilizing method thereof.
  • the water treatment apparatus for drinking purposes filters raw water and generates purified water for drinking purposes.
  • the water treatment apparatus is called a water purifier in a narrow sense.
  • Such a water purifier may be configured to receive raw water and supply a user with room-temperature purified water filtered by a filtering unit, or may be configured to heat/cool room-temperature purified water and supply a user with hot or cold water.
  • one of water treatment apparatuses for drinking purposes is a functional water generator that supplies a variety of functional water, such as deionized water, carbonated water, and oxygenated water, as well as purified water.
  • a water heater, a water cooler or an ice maker that heats or cools water, supplied from a water supply unit such as a water bottle, or makes ice.
  • water treatment apparatus is used as a generic term to refer to a multifunctional apparatus having the functions of a water purifier, a functional water generator, a water heater, a water cooler, and an ice maker.
  • the water purifier will be taken as an example, but it should be understood that the water purifier is merely an example of the water treatment apparatus of the present invention.
  • water purifiers are classified into ultra-filtration water purifiers and reverse osmosis water purifiers, depending on a purifying method.
  • a reverse osmosis water purifier may be provided with a filter unit, including a sediment filter, a pre-carbon filter, a reverse osmosis membrane filter, and a post-carbon filter.
  • the sediment filter receives raw water from a raw water supply and removes dust particles, sediment or various floating matter through a fine filter of about 5 microns.
  • the pre-carbon filter removes a harmful chemical such as a carcinogenic material (THM), a synthetic detergent, or an insecticide, and residual chloride, through an absorption method using activated carbon.
  • the reverse osmosis membrane filter is provided with a 0.0001-micron reverse osmosis membrane.
  • the reverse osmosis membrane filter filters a heavy metal (e.g., lead, arsenic, etc.), sodium, and germs, and discharges condensed water through a drain pipe.
  • the post-carbon filter removes unpleasant tastes, smells, and pigments from the water filtered by the reverse osmosis membrane filter.
  • an ultra-filtration water purifier uses an ultra-filtration filter instead of the reverse osmosis membrane filter.
  • the ultra-filtration filter is a porous filter having pores of several tens to hundreds of nanometers in size, and removes contaminants from water through numerous fine pores distributed on the surface of the membrane.
  • microorganisms or germs remaining in pores of the post-carbon filter may be introduced to a storage tank of the water purifier.
  • microorganisms may re-proliferate inside the storage tank.
  • external germs or microorganisms may penetrate into water stored in the storage tank, or slime may be created on the inner walls of the storage tank.
  • a storage tank may be sterilized through the addition of a separate sterilizing substance to the storage tank in order to sterilize bacteria or microorganisms proliferating in the storage tank.
  • a manager of a water purifier has to supply the sterilizing substance, and the cost of sterilizing the water purifier is added, to increase service costs, making a user potentially reluctant to use it.
  • the water purifier itself is not to be sterilized and washed and a service manager has to perform the sterilizing/washing processes, it makes it onerous to perform sterilizing/washing processes, decreasing the reliability of the water purifier.
  • the condition of the sterilizing substance being dissolved or eluted is different depending on the operating conditions of the water purifier (for example, a raw water pressure, flow amount, etc.).
  • a sterilizing substance concentration may be relatively high, and on the contrary, in a case of the flow amount being excessive, the sterilizing substance concentration becomes lower, thereby causing difficulties in controlling the sterilizing process.
  • the sterilizing substance concentration being high, it may smell unpleasant.
  • a sterilizing material produced from the sterilizing substance consists mainly of material having a low pH or a very high level of OCl-, it may smells unpleasant, and a sterilizing performance may be 1/7, comparing to that of HOCl, and thus, a much larger amount of OCl- sterilizing material may be required in order to sterilize a tank having the same capacity.
  • An aspect of the present invention provides a sterilizing apparatus and method for a water treatment apparatus, which can simply sterilize the water treatment apparatus.
  • An aspect of the present invention also provides a sterilizing apparatus and method for a water treatment apparatus, which can generate sterilizing water even without using separate sterilizing chemicals.
  • An aspect of the present invention also provides a sterilizing apparatus and method for a water treatment apparatus, which can stably generate high-concentration sterilizing water in a short time.
  • An aspect of the present invention also provides a sterilizing apparatus and method for a water treatment apparatus, which can perform not only a sterilizing operation but also a rinsing operation.
  • An aspect of the present invention also provides a sterilizing apparatus and method for a water treatment apparatus, which can sterilize not only a storage tank provided at the water treatment apparatus, but also a water outlet cock and a passage communicated with the storage tank.
  • a sterilizing apparatus for a water treatment apparatus including: an electrode sterilizing module configured to apply a voltage to an electrode to produce sterilizing/washing water containing a sterilizing material or a washing material; and a connecting member configured to connect the electrode sterilizing module to a passage of the water treatment apparatus to supply the sterilizing/washing water to the water treatment apparatus.
  • the connecting member may include at least one connecting pipe connected to a water outlet of the water treatment apparatus, and a circulation pipe connected to a filter passage pipe of the water treatment apparatus, a tank water inlet passage pipe, and a storage tank.
  • the connecting pipe may be detachably connected to at least one of a water outlet cock and a drain pipe constituting the water outlet
  • the circulation pipe may be detachably connected to the filter passage pipe, the tank water inlet passage pipe, or the storage tank.
  • the electrode sterilizing module may include an electrode part configured to apply a voltage to an electrode to produce sterilizing/washing water containing a sterilizing material or a washing material, and a pump configured to provide to supply the sterilizing/washing water produced in the electrode part to the passage of the water treatment apparatus. Then, the electrode part may produce sterilizing/washing water containing a mixed oxidant through electrolysis.
  • the electrode sterilizing module may further include a passage converting unit configured to sequentially open some passages communicated with the connecting pipe.
  • the electrode sterilizing module may further include a manifold configured to supply water introduced through a plurality of introduction openings communicated with the connecting pipe to the electrode part.
  • the electrode sterilizing module may further include a concentration sensor configured to detect a concentration of a sterilizing material or a washing material contained in water introduced to the electrode part.
  • the electrode sterilizing module may further include a water outlet passage converting valve configured to convert a passage to a discharge opening to discharge water introduced to the electrode sterilizing module to the outside.
  • a water outlet passage converting valve configured to convert a passage to a discharge opening to discharge water introduced to the electrode sterilizing module to the outside.
  • the electrode sterilizing module may further include an electrolyte supply unit configured to supply an electrolyte or a salt to the electrode part. Then, the electrolyte supply unit may be installed to be spaced apart from a water inlet side of the electrode part or installed on a discharge side of the electrode part.
  • the electrode sterilizing module may further include a water inlet opening for receiving water from a filter passage pipe or a tank water inlet passage pipe of the water treatment apparatus, a water inlet passage converting valve configured to convert a passage to selectively supply water introduced to the water inlet opening and water introduced through the connecting member to the electrode part, and a control unit configured to control driving of the electrode part, a pump, and a water inlet passage converting valve.
  • the filter part of the water treatment apparatus may include a reverse osmosis membrane filter
  • the electrode sterilizing module includes a water inlet opening for receiving water from the filter passage pipe of the water treatment apparatus
  • the filter passage pipe of the water treatment apparatus connected to the water inlet opening is a passage pipe through clean water flows after passing through at least one of the filters installed in the filter part and before being introduced to the reverse osmosis membrane filter.
  • the electrode sterilizing module may include an auxiliary tank for accommodating water provided by a user, and the water accommodating in the auxiliary tank is introduced to the electrode part. Then, the water accommodated in the auxiliary tank may be introduced to the electrode part through the water inlet passage converting valve.
  • the electrode sterilizing module may further include a display unit configured to display a state of an operation of the electrode sterilizing module, and may further include a manipulation unit for manipulating an operation of the electrode sterilizing module.
  • a method of sterilizing a water treatment apparatus through an electrode sterilizing module including an electrode part configured to apply a voltage to an electrode to produce sterilizing/washing water containing a sterilizing material or a washing material, the method including the operations of: installing a connecting member for connecting a passage of the water treatment apparatus and a passage of the electrode sterilizing module of a sterilizing apparatus; and producing sterilizing/washing water in the electrode sterilizing module and supplying the sterilizing/washing water to the water treatment apparatus.
  • the operation of installing a connecting member may include the operations of connecting at least one connecting pipe to a water outlet of the water treatment apparatus, and connecting a circulation pipe to a filter passage pipe, a tank water inlet passage pipe, and a storage tank of the water treatment apparatus.
  • the connecting pipe may be detachably connected at least one of a water outlet cock and a drain pipe of the water outlet, and a water outlet cock and a drain pipe are maintained in an open state after the connecting pipe is connected in the operation of connecting the connecting pipe.
  • the operation of producing sterilizing/washing water may include the operations of introducing water from the connecting pipe into the electrode sterilizing module, applying a voltage to the electrode part to produce sterilizing/washing water, and circulating the sterilizing water to the filter passage pipe, the tank water inlet passage pipe, or the storage tank through the circulation pipe.
  • some of the passages communicated with the connecting pipe may be sequentially opened.
  • the electrode part may be driven until a concentration detected by a concentration sensor for detecting a concentration of a sterilizing material or a washing material contained in the water introduced to the electrode part reaches a predetermined value.
  • the sterilizing/washing water may be produced by supplying an electrolyte or a salt to the electrode part.
  • water may be initially supplied from the filter passage pipe or the tank water inlet passage pipe of the water treatment apparatus to produce sterilizing/washing water, and water is supplied from the connecting pipe to produce sterilizing/water water after a lapse of a period of time.
  • the filter part of the water treatment apparatus may include a reverse osmosis membrane filter, and the filter passage pipe is a passage pipe through which clean water flows before being introduced to the reverse osmosis membrane filter and after passing through at least one filter.
  • water may be initially supplied from an auxiliary tank accommodating the water provided by the user, and water may be supplied from the connecting pipe to produce the sterilizing/washing water after a lapse of a period of time.
  • the sterilizing/washing water may be pressurized to be supplied to the filter passage pipe, the tank water inlet passage pipe, or the storage tank.
  • the method may further include the operation of stopping driving of the electrode part for a predetermined time, after a period of time lapses after the operation of producing the sterilizing/washing water is performed or a concentration of the sterilizing material or the washing material contained in the water introduced to the electrode part is above a predetermined value. Then, in the stopping operation, there may be no flow of water between the water treatment apparatus and the sterilizing/washing apparatus.
  • the method may further include the operation of discharging the sterilizing/washing water through a discharge opening of the electrode sterilizing module.
  • the method may further include the operations of stopping driving of the electrode part for a predetermined time, after a period of time lapses after the operation of producing the sterilizing/washing water is performed or a concentration of the sterilizing material or the washing material contained in the water introduced to the electrode part is above a predetermined value; discharging the sterilizing/washing water through the discharge opening of the electrode sterilizing module; and supplying rinsing water into the filter passage pipe, the tank water inlet passage pipe, or the storage tank after the sterilizing/washing water discharging operation.
  • the water introduced from the filter passage pipe installed in the filter part may be supplied to the tank water inlet passage pipe or the storage tank of the water treatment apparatus with the electrode part not being driven.
  • the rinsing water supplying operation may be performed for a predetermined time or until the storage tank is full.
  • the method may further include the operation of discharging rinsing water through a discharge opening of the electrode sterilizing module after the rinsing water supplying operation.
  • the method may further include the operation of separating the passage of the water treatment apparatus and the connecting member connected to a passage of the electrode sterilizing module.
  • the connecting member such as the connection pipe or the circulation pipe
  • the sterilizing water is generated by the electrode, thus making it possible to simply sterilize the water treatment apparatus.
  • the circulation pipe is connected to the passage pipe provided at the filter part of the front end of the storage tank, thereby making it possible to also sterilize the passage pipe provided at the filter part.
  • the electrolyte supply unit is provided, thereby making it possible to increase the sterilizing efficiency even in the reverse osmosis membrane filter type water purifier and complete the sterilizing operation in a short time. Also, a desired concentration of the sterilizing water is achieved through the concentration sensor, thereby making it possible to provide a stable sterilizing operation even without using unnecessary power or electrolyte.
  • the sterilizing water is generated by the electrode part without using separate sterilizing chemicals, it is not necessary to perform a neutralizing operation for reduction of the toxicity of the sterilizing chemicals, thus making it possible to greatly reduce the sterilizing time.
  • the sterilizing apparatus is connected to the passage provided at the filter part of the water treatment apparatus, thereby making it possible to supply water suitable for generation of high-concentration sterilizing water. Also, the supplied water can be used for the rinsing operation, thus facilitating the sterilizing operation and the rinsing operation.
  • FIG. 1 is a schematic view illustrating an internal structure of a sterilizing apparatus for a water treatment apparatus according to an embodiment of the present invention
  • FIGS. 2 through 4 are schematic views illustrating various connection states of the sterilizing apparatus of FIG. 1 to a water treatment apparatus;
  • FIGS. 5 through 9 are schematic views illustrating various embodiments of a sterilizing apparatus for a water treatment apparatus according to the present invention.
  • FIG. 10 is a schematic view illustrating a connection state of the sterilizing apparatus of FIG. 8 to a water treatment apparatus
  • FIGS. 11 and 12 are schematic views illustrating another embodiment of a sterilizing apparatus for a water treatment apparatus according to the present invention.
  • FIG. 13 is a schematic view illustrating a connection state of the sterilizing apparatus of FIG. 11 to a water treatment apparatus
  • FIG. 14 is a schematic view illustrating a connection state of the sterilizing apparatus of FIG. 9 to another type of water treatment apparatus
  • FIG. 15 is a schematic view illustrating a connection state of a sterilizing apparatus according to another embodiment of the present invention to a water treatment apparatus.
  • FIGS. 16 and 17 are flowcharts illustrating a sterilizing method for a water treatment apparatus according to an embodiment of the present invention.
  • FIGS. 1 through 4 a sterilizing apparatus for a water treatment apparatus according to the first embodiment of the present invention will be described with reference to FIGS. 1 through 4.
  • the sterilizing apparatus 100 includes an electrode sterilizing module 100a and a connecting member 190.
  • the electrode sterilizing module 100a applies a voltage to an electrode, and produces sterilizing/washing water containing a sterilizing material or a washing material
  • the connecting member 190 connects the electrode sterilizing module 100a and a passage of the water treatment apparatus 200, and supplies the sterilizing/washing water to the water treatment apparatus 200.
  • the connecting member 190 includes at least one connecting pipe 180 connected to a water outlet 260 of the water treatment apparatus 200, and a circulation pipe 191 connected to filter passage pipes L1, L2, L3, and L4, a tank water inlet passage pipe L5, or a storage tank 220 of the water treatment apparatus 200.
  • the filter passage pipes L1, L2, L3, and L4 refer to passage pipes introduced to filters 210, 220, 230, and 240, in which case raw water (tap water) flows though the first passage pipe L1 and clean water filtered by a sediment filter 211 flows through the second passage pipe L2.
  • the filter passage pipes L1, L2, L3, and L4 and a tank water inlet passage pipe L5 are generally referred to as passage pipes.
  • connection pipe 180 is detachably connected to at least one of water outlet cocks 261 and 262 and drain pipes 263 and 264 of the water outlet 260 of the water treatment apparatus 200, and the circulation pipe 191 is detachably connected to the filter passage pipes L1, L2, L3, and L4, the tank water inlet passage pipe L5, or the storage tank 220.
  • the storage tank 220 includes a clean water tank 230, a cold water tank 240, and a hot water tank 250
  • a first connection pipe 181 may be connected to a cold/clean water outlet cock 161 for discharging the water contained in the clean water tank 230 and the cold water tank 240
  • a second connection pipe 182 may be connected to the hot water outlet cock 262 for discharging the water contained in the hot water tank 240.
  • a third connection pipe 183 may be connected to a cold/clean water drain pipe 263 for discharging the water contained in the clean water tank 230 and the cold water tank 240 and a fourth connection pipe 184 may be connected to a hot water drain pipe 264 for discharging the water contained in the hot water tank 250.
  • the number of connection pipes and the types of passages connected to the connection pipes may be different according to the configuration of the water treatment apparatus 200.
  • connection pipe 180 may additionally be installed.
  • the circulation pipe 191 may be connected to the filter passage pipes L1, L2, L3, and L4, the tank water inlet passage pipe L5, or the storage tank 220 to sterilize the storage tank 220 of the water treatment apparatus 200 and passages (including water outlet cocks) connected to it.
  • the electrode sterilizing module 100a may include a housing 101, and an electrode part 170 and a pump 140 installed within the housing 101, and may optionally include a passage converting unit 110, a concentration sensor 120, a water outlet passage converting valve 160, and a control unit C in addition.
  • the electrode part 170 produces sterilizing/washing water (sterilizing/washing water refers to water capable of performing at least one of a sterilizing function and a washing function in the specification) containing a sterilizing material or a washing material when a voltage is applied to an electrode within the electrode part 170.
  • sterilizing/washing water refers to water capable of performing at least one of a sterilizing function and a washing function in the specification
  • the electrode part 170 may be configured to produce sterilizing/washing water containing a sterilizing and/or a washing material such as a mixed oxidant (MO) by electrolysis (the term 'electrolysis' includes a oxidation-reduction reaction in the specification) of introduced water.
  • a sterilizing and/or a washing material such as a mixed oxidant (MO)
  • electrolysis the term 'electrolysis' includes a oxidation-reduction reaction in the specification
  • the electrode part 170 water passes between electrodes of opposite polarities to sterilize or destroy microorganisms or germs remaining in the water.
  • the sterilization of clean water through electrolysis is complexly performed by a direct oxidation reaction in which microorganisms are directly oxidized in a positive electrode and an indirect oxidation reaction in which various mixed oxidants (MOs), such as residual chloride, ozone, OH radicals, oxygen radicals, which can be produced by a positive electrode to oxidize microorganisms.
  • MOs mixed oxidants
  • ruthenium (Ru) may be preferably coated on an electrode body of a positive electrode so that a sterilizing material may be produced without adding a separate electrolyte (including both a salt and a chloride in specification).
  • Ruthenium (Ru) serves as a catalyst which reduces a potential difference when Cl - is reduced to Cl 2 , and Cl 2 produced in water by ruthenium is immediately dissolved by water to become hypochlorous acid (HOCl).
  • the flow rate of water and voltage condition may be set to maximize the activity of the ruthenium (Ru) catalyst.
  • ruthenium (Ru) is coated on an electrode body of a positive electrode (more particularly, it is ruthenium oxide (RuOx) that is present on a surface of the electrode because, after ruthenium is coated on the electrode, ruthenium oxide is created by heating and oxidizing the ruthenium-coated electrode at a high temperature (since ruthenium is coated in the initial stage of production of the electrode, the expression "ruthenium is coated” includes a state of changing ruthenium into ruthenium oxide in the specification).
  • a maximum voltage is set to 30 V, and more preferably to 24 V while power is set below 12 W.
  • the life of the electrode generally may become shorter but can be prevented from being shorter as the electrode can be driven at a low current. It is preferable to make current lower to further increase the life of the ruthenium coated electrode, and accordingly it is preferable to form a negative electrode, i.e. a counterpart electrode of titanium (Ti) without separate coating.
  • a ruthenium (Ru) coated electrode and titanium (Ti) are respectively used as a positive electrode and a negative electrode and the interval between the electrodes is adjusted without adding a chloride (an electrolyte) separately, making it possible to produce a sterilizing material with a desired concentration at the low current and low power.
  • a chloride an electrolyte
  • the materials of the electrodes of the electrode part 170 according to the present invention are not limited to the above-listed material, but may be modified according to various embodiments.
  • the electrode part 170 preferably includes one positive electrode, and two negative electrodes disposed on opposite sides of the positive electrode.
  • one sheet of positive electrodes and one sheet of negative electrodes or one sheet of positive electrodes and one sheet of negative electrodes may be used, it is more preferable that one sheet of positive electrodes and two sheets of negative electrodes are used to be disposed in the sequence of a negative electrode, a positive electrode, and a negative electrode in order to minimize current value while realizing the concentration of a sterilizing material.
  • the electrode part 170 according to the embodiment of the present invention can be driven at a low current and a low power, for example, at a maximum current of 0.5 A or less, and preferably, at 0.35 A or less, and at a maximum voltage of 50 V or less, and preferably 24 V or less. It is apparent that the electrode part 170 may be managed at a power consumption of below 12 W.
  • sterilizing/washing water electrolytic sterilizing water
  • electrolytic sterilizing water has different types of chlorides existing in water according to their pH levels and has different sterilizing forces, and may be classified into various types such as strongly acidic electrolytic water, weakly acidic electrolytic water, strongly alkaline electrolytic water, and electrolytic sodium hypochlorite (NaOCl) water.
  • the materials and intervals of electrodes, the magnitude of power applied (voltage or current) applied thereto, an addition of an electrolyte or a salt (including a chloride), and the type of added electrolyte or a salt (including a chloride) may be different to produce various types of sterilizing/washing water (electrolytic sterilizing water), and all electrode parts that can produce sterilizing/washing water (electrolytic sterilizing water) through electrodes pertain to the category of the electrode part 170 according to the present invention.
  • an electrode part that can produce sterilizing/washing water using an electrolyte or a salt (including a chloride) supplied from an electrolyte supply unit 130 also pertains to the electrode part 170 according to the present invention.
  • the pump 140 provides pressure so that the sterilizing/washing water produced in the electric part 170 can be supplied to the passages of the water treatment apparatus 200.
  • the water introduced to the sterilizing apparatus 100 through the pump 140 may be changed to sterilizing/washing water and may be supplied into the passages of the water treatment apparatus 200, e.g. the filter passage pipes L1, L2, L3, and L4, the tank water inlet passage pipe L5 or the storage tank 220 through the pump 140.
  • the passage converting unit 110 may be configured to sequentially open some of the passages communicated with one or more connection pipes 180 connected to the water outlet 260 of the water treatment apparatus 200.
  • the passage converting unit 110 may be configured to sequentially open a plurality of introduction openings 111, 112, 113, and 114 one by one and block the remaining introduction openings, or sequentially open some introduction openings in batches and maintain the remaining introduction openings in a closed state.
  • first introduction opening 111 to which the first connection pipe 181 is connected, the second introduction opening 112, to which the second connection pipe 182 is connected, etc. may be sequentially opened
  • first introduction opening 111 and the third introduction opening 183 connected to the first connection pipe 181 and the third connection pipe 183 may be simultaneously opened so that the passages of the first connection pipe 181 and the third connection pipe 183 connected to the cold water tank 240 can be opened simultaneously and the remaining introduction openings 112 and 114 can be blocked
  • the second introduction opening 112 and the fourth introduction opening 114 can be opened simultaneously and the remaining introduction openings 111 and 113 can be blocked.
  • the storage tank 220 of the water treatment apparatus 200 and the passages connected to the storage tank 220 corresponding to the opened introduction openings may be sequentially sterilized and washed by sequentially opening some passages of the passage converting unit 110.
  • the passage converting unit 110 may employ various known valves or an opening/closing unit such as a plurality of solenoids or disk valves.
  • the concentration sensor 120 detects a concentration of a sterilizing material or a washing material contained in water introduced to the electrode part 170.
  • the concentration sensor 120 may be a sensor configured to measure an ion concentration, but is not limited thereto only if it can detect a concentration of a sterilizing material or a washing material.
  • the water outlet passage converting valve 160 converts a passage to a discharge opening 161 to discharge the water introduced to the electrode sterilizing module 100a to the outside. That is, as illustrated in FIG. 1, the water outlet passage converting valve 160 converts a passage between a passage for sending the water introduced through the water inlets 111, 112, 113, and 114 through the electrode part 170 and a passage for discharging the water through a discharge pipe 195 connected to the discharge opening 161. After the water treatment apparatus 200 completes a sterilizing/washing operation, the water outlet passage converting valve 160 discharges sterilizing/washing water to the outside or converts a passage to a water outlet side 171 when rinsing water is discharged to the outside.
  • a control unit C may be installed to control driving of the passage converting unit 110, the concentration sensor 120, the pump 140, the water outlet passage converting valve 160, and the electrode part 170.
  • the control unit C drives the pump 140 and the electrode part 170 in the initial stage of a sterilizing/washing operation, controls a passage opening/closing operation of the passage converting unit 110 to sequentially sterilize and wash various passages of the water treatment apparatus 200, and stops driving of the pump 140 and the electric part 170 if a concentration detected by the concentration sensor 120 is equal to or greater than a preset value.
  • the control unit C controls driving of the water outlet passage converting valve 160, the pump 140, and the electrode part 170 so that it may convert a passage of the water outlet passage converting vale 160 and drive only the pump 140 with the electrode part 170 not being driven to discharge sterilizing/washing water to the outside through the discharge opening 161 when a sterilizing/washing operation is completed.
  • the electrode sterilizing module 100a may further include a display D for displaying a state of an operation of the electrode sterilizing module 100a and a manipulation unit B for manipulating an operation of the electrode sterilizing module 100a, and the displayed and manipulated contents by them may be variously modified and changed.
  • the manipulation unit B may include various selection buttons such as a sterilization starting button, a sterilization stopping button, and an inlet selecting button
  • the display D may be configured to display a sterilization state, a waiting state, a rinsing state, a completion state, and an error state using an illumination and an alarm.
  • the water purifier 200 of FIGS. 2 through 4 will be described as an example of the water treatment apparatus 200 in which the sterilizing apparatus 100 of FIG. 1 can be used.
  • a general water purifier 200 includes a filter part 210, a storage tank 220, and a water outlet 260.
  • the filter part 210 is adapted to sequentially filter and purify raw water, and may include a sediment filter 211, a pre-carbon filter 212, a reverse osmosis membrane filter (ultra filtration filter) 313, and a post-carbon filter 214.
  • the types, number, and sequence of the filters may be changed according to a filtering method of the water treatment apparatus (water purifier) and a filtering performance required by the water treatment apparatus (water purifier).
  • an ultra filtration filter may be installed instead of the reverse osmosis membrane filter 213.
  • Such an ultra filtration filter is a porous filter having pores of several tens to hundreds of nanometers in size, and contaminants in water are removed through numerous fine pores distributed on a surface of the membrane.
  • each filter 211, 212, 213, and 214 includes a filter case having a filter element therein, and an outer case for receiving the filter case.
  • Each filter 211, 212, 213, and 214 has a cartridge structure in which after the raw water introduced to the outer case is filtered by the filter element in the filter case, it is discharged to the outside of the outer case.
  • the filter part 210 having the filters 211, 212, 213, and 214 is not specifically limited to an independent cartridge form, but may be a complex filter having two or more filter functions.
  • the sediment filter 211 and the pre-carbon filter 212 may constitute a single pre-processing complex filter.
  • the sediment filter 211 serves to receive raw water from a raw water supply and absorb and remove relatively large particles of floating matter and solid materials such as sand particles contained in the raw water.
  • a raw water blocking valve V for selectively blocking the raw water supplied from the raw water supply unit may be installed at a front end of the sediment filter 211; however, the installation location of the raw water blocking valve V is not limited thereto, and the raw water blocking valve V only need to block supply of raw water.
  • the pre-carbon filter 212 serves to receive the water which has passed through the sediment filter 211 and remove harmful chemicals such as a volatile organic composition, a carcinogenic material, a synthetic detergent, and an insecticide, and a residual chloride (for example, HOCL or ClO) contained in the water through an absorption method using activated carbon.
  • harmful chemicals such as a volatile organic composition, a carcinogenic material, a synthetic detergent, and an insecticide, and a residual chloride (for example, HOCL or ClO) contained in the water through an absorption method using activated carbon.
  • the reverse osmosis membrane filter 213 receives the water filtered by the pre-carbon filter 212, and removes heavy metals and fine organic/inorganic materials such as a metal ions and germs through a membrane having fine pores.
  • a drain pipe DL for discharging water generated by filtering raw water, i.e. waste water (generally referred to "condensed water” in the art) is connected to the reverse osmosis membrane filter 213.
  • the post-carbon filter 214 serves to absorb and remove unpleasant tastes, smells, and pigments from the water filtered by the reverse osmosis membrane filter 213, and the clean water filtered by the post-carbon filter 214 is received in the storage tank 220 through a clean water line.
  • the filter part 210 may include a pressurizing pump 215 for supplying water to the reverse osmosis membrane filter 213 with a pumping pressure.
  • the passage pipes L1, L2, L3, L4, and L5 are connected to the filter part 210, the final filter 214 of the filter part 210 and the storage tank 220 are connected to each other through a tank water inlet passage pipe L5.
  • a tank water inlet passage pipe L5 an entire passage pipe connecting the final filter 214 of the filter part 210 and the storage tank 220 will be referred to as "a tank water inlet passage pipe L5" even when other members are installed.
  • the storage tank 220 stores the clean water purified by the filter part 210, and the clean water is discharged through the water outlet cocks 261 and 262.
  • the storage tank 220 stores the clean water which has passed through the filter part 210, and may include at least one of a clean water tank 230 for storing clean water at a normal temperature, a cold water tank 240 for cooling and storing clean water, and a hot water tank 250 for heating and storing clean water. Then, the clean water tank 230 and the cold water tank 240 may be installed separately, but may be divided within a single space through a partition wall (separator) in which water can be circulated.
  • the water outlet cocks 261 and 262 may be installed as a water outlet part 260 for supplying the water accommodated within the storage tank 220 to the user.
  • the cold/clean water outlet cock 261 may be configured to supply the user with clean water or cold water according to selection of the user
  • the hot water outlet cock 262 may be configured to supply hot water by the user.
  • FIGS. 2 through 4 illustrate that clean water and cold water can be supplied to the user through one of the cold/clean water outlet cocks 261, water outlet cocks for respectively supplying clean water and cold water may be installed separately.
  • Drain pipes 263 and 264 may be installed as the water outlet part 260 connected to the storage tank 220.
  • the drain pipes 263 and 264 are used to evacuate the storage tank 220 when the storage tank 220 is washed or when sterilizing/washing water or rinsing water is discharged from the storage tank 220. Then, the cold/clean water drain pipe 263 is connected to the cold water tank 240 to discharge clean water and cold water, and the hot water drain pipe 264 is connected to the hot water tank 250 to discharge hot water.
  • the process of connecting the sterilizing apparatus 100 to the water treatment apparatus 200 of FIGS. 2 through 4 is performed by connecting the connection pipe 180 and the circulation pipe 191 of the sterilizing apparatus 100 to the water treatment apparatus 200.
  • the cold/clean water outlet cock 261 and the first introduction opening 111 are connected through the first connection pipe 181, and the hot water outlet cock 262 and the second introduction opening 112 are connected through the second connection pipe 182.
  • the cold/clean water drain pipe 263 and the third introduction opening 113 are connected through the third connection pipe 183 and the hot water drain pipe 264 and the fourth introduction opening 114 are connected through the fourth connection pipe 184.
  • the storage tank 220 (or the clean water tank 230) and the water outlet opening 171 are connected through the circulation pipe 191.
  • the circulation pipe 191 may be connected to the tank water inlet passage pipe L5 through a connector 265, etc.
  • the filter passage pipes L1, L2, L3, and L4 may be connected to each other by a connecting mechanism such as a tube or a connector and the circulation pipe 191 may be connected to the filter passage pipes L1, L2, L3, and L4 through the connector 265.
  • FIG. 4 illustrates that the circulation pipe 191 is connected through the connector 265 at a front end of the sediment filter 210 after all the filters are removed
  • the filters 220, 230, and 240 other than the sediment filter 210 may be removed and after the filter passage pipes L2, L3, and L4 between the separated filters are connected to each other by connecting mechanisms C2, C3, and C4, the circulation pipe 191 may be connected to the passage pipe L2.
  • the method of connecting the circulation pipe 191 to the filter passage pipes L1, L2, L3, and L4 may be modified in various ways.
  • the circulation pipe 191 may be connected to the filter passage pipes L1, L2, L3, and L4 in the same or a similar manner to FIG. 4, even in the second through seventh embodiments.
  • connection of the passages is completed by connecting the discharge pipe 195 to the discharge opening 161.
  • control unit C controls the passage converting unit 110 to open one or some of the introduction openings 111, 112, 113, and 114 and drives the pump 140 and the electrode part 170 so that sterilizing/washing water produced in the electrode part 170 may flow to the storage tank 220 (see FIG. 2), the tank water inlet passage pipe L5 (see FIG. 3) or the filter passage pipes L1, L2, L3, and L4 (see FIG. 4) through the circulation pipe 191 and may be introduced to the electrode sterilizing module 100a through the water outlet 260.
  • another tank may be sterilized and washed by changing a passage of the passage converting unit 110.
  • the first introduction opening 111 and the third introduction opening 113 are opened primarily and the clean water tank 230, the cold water tank 240, and the cold/clean water outlet cock 261 are sterilized and washed
  • the hot water tank 250 and the hot water outlet cock 262 are sterilized and washed by opening the second introduction opening 112 and the fourth introduction opening 114.
  • a concentration detected by the concentration sensor 120 is equal to or greater than a preset value, the electrode part 170 does not need to be driven to sterilize and wash the hot water tank 250, in which case only the pump 140 may be driven.
  • the introduction openings 111, 112, 113, and 114 may be sequentially opened one by one to wash the passages connected to them.
  • control unit C converts the passage of the water outlet passage converting valve 160 to the discharge opening 161 to allow the sterilizing/washing water to be discharged to the outside.
  • the completion of the water discharging operation may be determined by using detection of a low-level sensor installed in the storage tank 220 or driving the pump 140 for a predetermined time, considering the capacity of the storage tank 220, or may be determined by detecting an overload generated when water is not introduced to the pump 140.
  • a rinsing operation of the storage tank 220 may be performed manually or by using the water which has passed through the filter part 110, and the sterilizing apparatus 100 may be separated from the water treatment apparatus 200 before or after the rinsing operation.
  • the sterilizing apparatus 100 of FIG. 5 is the same as the sterilizing apparatus 100 shown in FIGS. 1 through 4 except that a manifold 111' is installed instead of the passage converting unit 110.
  • a manifold 111' is installed instead of the passage converting unit 110.
  • the manifold 110' of FIG. 5 is connected to a plurality of introduction openings 111, 112, 113, and 114 connected to a connection pipe 180 to merge the introduced water and provide the merged water to the electrode part 170.
  • connection pipes 180 since all the passages of the water treatment apparatus 200 to which connection pipes 180 are connected may be washed simultaneously, using the manifold 110', sterilizing/washing time can be shortened.
  • connection structure between the sterilizing apparatus 100 of FIG. 5 and the water treatment apparatus is the same as that of FIG. 2 except that passages for the introduction openings 111, 112, 113, and 114 are not converted, and a detailed description thereof will be omitted.
  • the sterilizing apparatus 100 of FIGS. 6 and 7 is the same as the sterilizing apparatus 100 of FIGS. 1 through 4 except that an electrolyte supply unit 130 is additionally installed.
  • an electrolyte supply unit 130 is additionally installed.
  • the electrolyte supply unit 130 serves to smoothly produce a sterilizing material or a washing material and supply an electrolyte or a salt (including a chloride) to the electrode part 170 to obtain highly concentrated sterilizing/washing water.
  • chlorides such as NaCl, KCl, and NaOCl are supplied to help produce a sterilizing material.
  • a salt or an electrolyte other than a chloride may also be supplied.
  • the electrolyte supply unit 130 may be constituted by a system for dosing an electrolyte in a liquid state, but may be configured to dissolve a solid electrolyte or a salt while water is flowing into the electrolyte supply unit 130 with the solid electrolyte or the salt (including a chloride) being accommodated within the electrolyte supply unit 130 for the sake of convenience.
  • a plurality of communication holes may be formed in the electrolyte supply unit 130 and a cover may be installed at an upper end of the electrolyte supply unit 130 to supply an electrolyte or a salt.
  • the electrolyte supply unit 130 is preferably spaced apart from a water inlet side of the electrode part 170. That is, as the electrolyte supply unit 130 is spaced apart from the electrode part 170 (for example, an electrolyte is supplied through a pump), a highly concentrated electrolyte or a salt (including a chloride) which has not been dissolved is prevented from directly contacting an electrode, making it possible to prevent damage to the electrode installed in the electrode part 170.
  • the electrolyte supply unit 130 may be installed at a discharge side of the electrode part 170 so that after the electrolyte or the salt (including a chloride) supplied from the electrolyte supply unit 130 is introduced to the storage tank 220 through the circulation pipe 191 and is dissolved and mixed sufficiently, it can be supplied to the electrode unit 170.
  • connection structure of the sterilizing apparatus 100 illustrated in FIGS. 6 and 7 and the water treatment apparatus 200 is the same as those of FIG. 2, and a detailed description thereof will be omitted.
  • the sterilizing apparatus 100 of FIGS. 8 through 10 is the same as the sterilizing apparatus of FIGS. 1 through 4 according to the first embodiment of the present invention except that a water inlet opening 151 and a water inlet passage converting valve 150 are installed, and is the same as the sterilizing apparatus 100 of FIG. 6 according to the third embodiment of the present invention except that the sterilizing apparatus 100 of FIG. 9 employs a water inlet opening 151 and a water inlet passage converting valve 150.
  • a description of the same or similar configurations will be omitted to avoid unnecessary repetition, and only unique configurations will be described.
  • the sterilizing apparatus 100 of FIGS. 8 through 10 includes a water inlet opening 151 for receiving water from the passage pipes L1, L2, L3, L4, and L5 of the water treatment apparatus 200, and a water inlet passage converting valve 150 for converting a passage to selectively supply the water introduced through the water inlet opening 151 and the water introduced through the connection pipe 180 to the electrode part 170.
  • the passage pipes L1, L2, L3, L4, and L5 of the water treatment apparatus 200 connected to the water inlet pipe 151 are preferably passage pipes L1, L2, and L3.
  • the total dissolved solids (TDS) of the water passing through the reverse osmosis membrane filter 313 is reduced, and when water is introduced to the electrode part 170 to produce sterilizing/washing water, the amount of a sterilizing material or a washing material may not be sufficient. Since the water which has not passed through the reverse osmosis membrane filter 213 is discharged as living water (waste water, condensed water) through a drain pipe DL, water may be wasted.
  • the filter passage pipes L1, L2, and L3 installed at a front end of the reverse osmosis membrane filter 213 is connected to the water inlet opening 151 and the water flowing through the filter passage pipes L1, L2, and L3 is used as the water initially introduced to the electrode part 170
  • the total dissolved solids (TDS) introduced to the electrode part increases, making it possible to improve the amount of a produced sterilizing material or a washing material, to reach a concentration of the sterilizing/washing water necessary for a sterilizing/washing operation in a short time (for example, the concentration may be set to 0.05 ppm or more, i.e.
  • the filter passage pipes L1, L2, L3, and L4 connected to the water inlet opening 161 may preferably be the second passage pipe L2 and the third passage pipe L3 through which the clean water flows before being introduced to the reverse osmosis membrane filter after it passes through at least one filter installed in the filter part.
  • the sterilizing/washing water may be created in the electrode part 170 using raw water introduced from the first passage pipe L1 and an electrolyte supplied from the electrolyte supply unit 130.
  • the sterilizing/washing water may be created in the electrode part 170 using the clean water filtered by the sediment filter 211 and the pre-carbon filter 212 and the electrolyte supplied from the electrolyte supply unit 130.
  • the sterilizing/washing water may be created in the electrode part 170 using the water introduced to the inlet opening 151 from the fourth passage pipe L4 or the tank inlet passage pipe L5 and the electrolyte supplied from the electrolyte supply unit 130.
  • TDS total dissolved solids
  • FIG. 10 a connection structure of the sterilizing apparatus 100 and the water treatment apparatus 200 shown in FIG. 8 and FIG. 9 are the same as that of FIG. 2 except for an additional connection of the inlet opening 151, and thus only a different construction will be described so as to avoid unnecessary repetition.
  • the inlet opening 151 of the sterilizing apparatus 100 may connect with passage pipes L1, L2, L3, L4, and L5 of the water treatment apparatus 200 (passage pipes L1, L2, and L3 provided at a front end of the reverse osmosis membrane filter 213 when the sediment filter 210 includes the reverse osmosis membrane filter 213) through a connection pipe 185.
  • the connection pipe 185 may use one of the passage pipes L1, L2, and L3 provided at a front end of the reverse osmosis membrane filter 213 or may connect with the passage pipes L1, L2, and L3 through a separate connector to be used.
  • connection pipe 185 may connect with the passage pipes L1, L2, L3, L4, and L5 through a connector to be used.
  • the circulation pipe 191 may be connected to the storage tank 220.
  • sterilizing operation is performed in the same manner as in FIG. 2.
  • FIG. 10 shows reverse osmosis membrane filter by way of example in an electrode part 170 in an early sterilizing operation to create sterilizing/washing water of relatively higher concentration and to supply it to a storage tank 220 of the water treatment apparatus 200.
  • a passage of a passage converting valve 150 may be converted to introduce water introduced through the connection pipe 180 to the electrode part 170. Through this, an operation creating the sterilizing/washing water may continue.
  • a water level of the storage tank 220 may be significantly increased to cause an overflow. Accordingly, water is supplied through the passage pipes L1, L2, L3, L4, and L5 for only a predetermined time, considering a capacity of the storage tank 220. Afterwards, water in the storage tank 220 may be circulated to create the sterilizing/washing water.
  • the concentration sensor 120 stops driving of the pump 140 and the electrode part 170 and maintains an idle state for a predetermined time. Subsequently, a passage of the water outlet passage converting valve 160 is converted to an outlet opening 161 side to provide the sterilizing/washing water to an exterior.
  • water from passage pipes L1, L2, and L3 may be supplied to the inlet opening 151, it may be used as washing water. That is, for washing, in a state in which a passage of the passage converting valve 150 is converted to a connected state of the inlet opening 151 and the electrode part 170 and the electrode part 170 is not driven, when driving the pump 140, water introduced through the passage pipes L1, L2, L3, L4, and L5 may be introduced to the storage tank 220 through the sterilizing apparatus 100. Accordingly, if the storage tank 220 is filled with washing water, a passage of the water outlet passage converting valve 160 may be converted to again charge the washing water, thereby charging the washing water to the exterior.
  • the sterilizing apparatus 100 shown in FIG. 10 includes a control unit C.
  • the control unit C controls driving of a passage converting unit 110, the electrode part 170, the pump 140, the passage converting valve 150, and the outlet passage converting value 160.
  • the sterilizing apparatus 100 of FIGS. 11 through 13 is the same as the sterilizing apparatus of FIGS. 1 through 4 according to the first embodiment of the present invention except that an auxiliary tank 155 and a water inlet passage converting valve 150 are installed, and the sterilizing apparatus 100 of FIG. 12 is the same as the sterilizing apparatus of FIGS. 1 through 4 according to the first embodiment of the present invention except that the auxiliary tank 155 is added.
  • the sterilizing apparatus 100 of FIG. 12 is the same as the sterilizing apparatus of FIGS. 1 through 4 according to the first embodiment of the present invention except that the auxiliary tank 155 is added.
  • the sterilizing apparatus 100 of FIGS. 11 through 13 according to the fifth embodiment of the present invention includes an auxiliary tank 155.
  • the auxiliary tank 155 stores water fed thereinto by a user and the water accommodated in the auxiliary tank 155 is fed to the electrode part 170.
  • the water accommodated in the auxiliary tank 155 may be fed to the electrode part 170 through the water inlet passage converting valve 150 or due to head difference as illustrated in FIG. 12.
  • a user may feed water containing a large amount of the total dissolved solids (TDS) such as drinking water to the auxiliary tank 155 and the electrode part 170 produces the sterilizing/washing water using the fed water so that the sterilizing/washing water may be obtained in the early stage.
  • TDS total dissolved solids
  • the sterilizing/washing water may be obtained by keeping the water introduced to the auxiliary tank 155 within the electrode part 170 to which electric power is applied for a predetermined time. Then, after a predetermined period of time has elapsed, the pump 140 is driven such that the water in the water treatment apparatus 200 may be introduced to the sterilizing apparatus 100.
  • the electrode part 170 and the pump 140 may be driven at the same time.
  • the electrolyte supply unit 130 may be added and electrolyte or salt may be directly inserted into the auxiliary tank 155.
  • the sterilizing apparatus 100 of FIG. 14 according to the sixth embodiment of the present invention is the same as the sterilizing apparatus 100 of FIG. 9 according to the fourth embodiment, except that the water treatment apparatus 200 connected thereto is modified.
  • the water treatment apparatus 200 of FIG. 14 is different from the water treatment apparatus 200 of FIGS. 4, 10, and 13 in view of including a temperature variation unit 220' instead of the storage tank 220.
  • the water treatment apparatus 200 as illustrated in FIGS. 2 through 4, 10, and 13 includes a storage tank 220 storing water but the water treatment apparatus 200 of FIG. 14 does not include the storage tank 220.
  • the temperature variation unit 220' of the water treatment apparatus 200 of FIG. 14 may include a room temperature feeding unit 270 feeding the water passing through the filter part 210 at room temperature, a cold water feeding unit 280 having an instant cooler cooling and feeding the water, and a hot water feeding unit 290 having an instant heater heating and feeding the water.
  • the room temperature feeding unit 270, water feeding forward the cold water feeding unit 280, and the hot water feeding unit 290 may be performed by switching passages with a water passage switching valve V1 according to user's choice.
  • the water treatment apparatus 200 of FIG. 14 does not include a tank
  • the water treatment apparatus 200 does not include a drain so that the connection pipes 183 and 184 connected to the drain pipes 263 and 264 of FIG. 2 are not connected thereto.
  • the circulation pipe 191 may be connected to the tank water inlet passage pipe L5 or the tank water inlet passage pipe L5 may be directly connected to the water outlet side 171 when the tank water inlet passage pipe L5 is sufficiently long.
  • the sterilizing apparatus 100 connected to the water treatment apparatus 200 must be operated such that a passage corresponding to the unconnected introduction openings 113 and 114 when a passage is selected using the passage converting unit 110.
  • the manipulation unit B of the sterilizing apparatus 100 may include an inlet selecting button (not shown).
  • the water inlet passage converting valve 150 of FIG. 14, similar as the fourth embodiment of FIG. 10, connects a passage between the water inlet opening 151 and the electrode part 170 for the production of the sterilizing/washing water to be fed to the water treatment apparatus 200 in the early stage of the sterilizing/washing, and connects a passage between the introduction openings 111, 112, 113, and 114 and the electrode part 170 after an amount of water sufficient to circulate the sterilizing/washing water between the sterilizing apparatus 100 and the water treatment apparatus 200 is fed thereinto.
  • connection of a passage between the sterilizing apparatus 100 and the water treatment apparatus 200 is the same as the case of FIG. 10 except for the unconnected connection pipes 183 and 184, description for sterilizing/washing and rinsing will be omitted.
  • the sterilizing apparatus 100 of FIG. 15 according to the seventh embodiment of the present invention is similar as the fifth embodiment of FIGS. 11 through 13 in view of including the auxiliary tank 155, but has some differences such as the installing position and function of the auxiliary tank 155.
  • the water treatment apparatus 200 of FIG. 15 is the same as the water treatment apparatus 200 of FIG. 14.
  • the water treatment apparatus 200 of FIG. 14 In order to avoid repetition, a description of identical or similar parts will be omitted and only parts different from the above-mentioned embodiments will be described.
  • the auxiliary tank 155 provided in the sterilizing apparatus 100 of FIG. 15 is configured to feed water to the water treatment apparatus 200 for the sterilizing/washing of the water treatment apparatus 200.
  • the auxiliary tank 155 provided in the water treatment apparatus 200 of FIG. 15 accommodates the amount of water enabling circulation of the sterilizing/washing water between the sterilizing apparatus 100 and the water treatment apparatus 200.
  • the sterilizing apparatus 100 of FIG. 15 includes a tank performing the function of the storage tank 220 in the water treatment apparatus 200 of FIGS. 2 through 4, 10, and 13 as an auxiliary tank 155.
  • the sterilizing apparatus 100 according to the seventh embodiment is substantially similar as other embodiments in view of the sterilizing/washing except for the auxiliary tank 155, a detailed description thereof will be omitted.
  • the water treatment apparatus 200 is sterilized and washed with the electrode sterilizing module 100a including the electrode part 170 producing the sterilizing/washing water containing the sterilizing material or the washing material by applying electric power to the electrodes.
  • the sterilizing/washing method S100 may be performed by the above-mentioned sterilizing apparatus 100 but the present invention is not limited thereto.
  • the method S100 of sterilizing a water treatment apparatus 200 includes the operations of: installing a connecting member 190 for connecting a passage of the water treatment apparatus 200 and a passage of the electrode sterilizing module 100a (S110); and producing sterilizing/washing water in the electrode sterilizing module 100a and supplying the sterilizing/washing water to the water treatment apparatus 200 (S120).
  • the method S100 further includes an operation of stopping driving of the electrode part 170 for a predetermined time, after a period of time lapses after the operation of producing the sterilizing/washing water is performed or a concentration of the sterilizing material or the washing material contained in the water introduced to the electrode part 170 is above a predetermined value (S130), the operation of discharging the sterilizing/washing water through a discharge opening 161 of the sterilizing apparatus 100 (S140), and the operation of separating the passage of the water treatment apparatus 200 and the connecting member 190 connected to a passage of the electrode sterilizing module 100a (S170).
  • the operation S110 of installing a connecting member includes the operations of connecting at least one connecting pipe 180 to a water outlet 260 of the water treatment apparatus 200, and connecting a circulation pipe 191 to filter passage pipes (L1, L2, L3, and L4), a tank water inlet passage pipe (L5), and a storage tank 220 of the water treatment apparatus 200.
  • the connecting pipe 180 is detachably connected at least one of water outlet cocks 261 and 262 and drain pipes 263 and 264 of the water outlet 260.
  • the water outlet cocks 261 and 262 are required to be opened so that water can be introduced when the sterilizing apparatus 100 is operated. Then, when the water outlet cocks 261 and 262 are mechanical valves, the water outlet cocks 261 and 262 are opened, and when the water outlet cocks 261 and 262 are electronic valves, an electronic valve opening button installed in the water treatment apparatus 200 is pressurized or a valve can be maintained in an opened state by installing a separate cable to apply an opening signal to the electronic valve.
  • the drain pipes 263 and 264 and the raw water blocking valve V are preferably opened.
  • operation S120 of producing sterilizing/washing water includes the operations of introducing water from the connecting pipe 180 into the electrode sterilizing module 100a, applying a voltage to the electrode part 170 to produce sterilizing/washing water, and supplying the sterilizing water to the filter passage pipes L1, L2, L3, and L4, the tank water inlet passage pipe L5, or the storage tank 220 through the circulation pipe 191.
  • the water introducing operation, the sterilizing/washing water producing operation, and the circulation operation may be performed simultaneously, but their order may be varied according to the details of the sterilizing apparatus 100.
  • the circulation operation and the water introducing operation may be performed simultaneously by driving the pump 140, and the sterilizing/washing water producing operation by driving the electrode part 170 may be performed in a state in which water is introduced into the electrode part 170.
  • the electrode part 170 may be operated in a state in which water is introduced to the electrode part 170 through the water inlet opening 151, and then the pump 140 may be driven, or the two operations may be performed simultaneously.
  • some of the passages communicated with the connecting pipe 180 may be sequentially opened through the passage converting unit 110.
  • the first to fourth introducing openings may be sequentially opened
  • the cold/clean water outlet cocks 161 connected to the clean water tank 230 and the cold water tank 240 and the first to third introducing openings 111 to 113 connected to the cold/clean water drain pipe 263 may be opened first
  • the second introducing opening 112 and the fourth introducing opening 114 connected to the hot water tank 250 may be opened after the sterilizing operation.
  • the electrode part 170 is driven until a concentration detected by a concentration sensor 120 for detecting a concentration of a sterilizing material or a washing material contained in the water introduced to the electrode part 170 reaches a predetermined value.
  • the sterilizing/washing water is produced by supplying an electrolyte or a salt to the electrode part 170 (See FIGS. 6, 7, 9, 14, and 15).
  • water is initially supplied from the filter passage pipe or the tank water inlet passage pipe of the water treatment apparatus to produce sterilizing/washing water, and a passage of the water inlet passage converting valve 150 may be converted after a lapse of a predetermined time to produce sterilizing/washing water from the water supplied from the connecting pipe 180.
  • the passage pipes L1, L2, and L3 installed at a front end of the reverse osmosis membrane filter 213 are preferably connected to the water inlet opening 151.
  • the sterilizing/washing water producing operation water is initially supplied from an auxiliary tank 155 accommodating the water provided by the user, and water is supplied from the connecting pipe 180 to produce the sterilizing/washing water after a lapse of a period of time.
  • the sterilizing/washing water is pressurized to be supplied to the filter passage pipes L1, L2, L3, and L4, the tank water inlet passage pipe L5, or the storage tank 220.
  • the operation S130 of stopping driving of the electrode part 170 for a predetermined time after a period of time lapses after the operation of producing the sterilizing/washing water is performed or a concentration of the sterilizing material or the washing material contained in the water introduced to the electrode part 170 is above a predetermined value. However, if a concentration of the sterilizing/washing water is high, the operation 130 may not be performed.
  • the produced sterilizing/washing water is maintained in the storage tank 220 and the passages and the water outlet cocks 261 and 262 connected to it for a predetermined time to perform a sterilizing operation. To achieve this, as driving of the pump 140 is stopped, there is no water flow between the water treatment apparatus 200 and the sterilizing apparatus, stopping driving of the electrode part 170 for a predetermined time.
  • the sterilizing/washing water producing/supplying operation S120 or the completion of the sterilizing/washing water producing/supplying operation S120 and the operation S130, the sterilizing/washing water is discharged through the discharge opening 161 of the electrode sterilizing unit 100.
  • the pump 140 is driven with a passage of the water outlet passage converting valve 160 being converted toward the discharge opening 161. Then, the electrode part 170 is not operated.
  • the sterilizing/washing water discharging operation S140 may be completed by driving the pump 140 for a predetermined time, or preventing an overload by preventing water from being introduced to the pump 140.
  • the rinsing operation may be performed manually, or the sterilizing apparatus 100 may be separated from the water treatment apparatus 200 after the completion of the manual rinsing operation (S170).
  • the operation S170 of separating the sterilizing apparatus 100 from the water treatment apparatus 200 may be performed, in which case the clean water may be supplied into the storage tank 220 through the filter part 2109 to perform a rinsing operation.
  • the rinsing water supplying operation S150 and the rinsing water discharging operation S160 are performed after the sterilizing/washing water discharging operation S140, and then the sterilizing apparatus separating operation S170 is performed.
  • rinsing water is supplied to the tank water inlet passage pipe L5 or the storage tank 220 of the water treatment apparatus 200.
  • the sterilizing apparatus 100 of FIGS. 10 and 14 since the passage pipes (L1, L2, L3; L4 and L5 in the case of an ultra filtration filter) of the water treatment apparatus 200 is connected to the water inlet opening 151, the sterilizing apparatus 100 can be receive water from the water treatment apparatus 200.
  • a passage is converted through the water inlet passage converting valve 150 with the water inlet opening 151 and the electrode part 170 being connected and the pump 140 is driven with the electrode part 170 not being driven, the water introduced from the passage pipes (L1, L2, L3; L4 and L5 in the case of an ultra filtration filter) through the water inlet opening 151 can be supplied to the storage tank 220 via the water outlet opening 171, and the water serves as rinsing water.
  • the water level of the storage tank 220 can be maintained for a predetermined time and the water level of the storage tank 220 may be full. Then, the full water level can be detected by confirmation of the user or a full level sensor of the storage tank 220.
  • a waiting operation may be performed in a similar manner to the sterilizing/washing water producing/supplying operation S120, and then the rinsing water discharging operation S160 may be performed.
  • the rinsing water discharging operation S160 may be performed by driving the pump 140 with a passage of the water outlet passage converting valve 160 being converted to the discharge opening.
  • the rinsing water discharging operation S160 may be completed by driving the pump 140 for a predetermined time or preventing an overload by preventing water from being introduced to the pump 140.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

L'invention porte sur un appareil de stérilisation pour un appareil de traitement d'eau, lequel appareil de stérilisation comprend : un module de stérilisation d'électrode configuré pour appliquer une tension à une électrode pour produire de l'eau de stérilisation/lavage contenant un matériau stérilisant ou un matériau de lavage ; et un élément de liaison configuré de façon à relier le module de stérilisation d'électrode à un passage de l'appareil de traitement d'eau pour alimenter l'appareil de traitement d'eau en eau de stérilisation/lavage.
PCT/KR2011/004812 2011-06-02 2011-06-30 Appareil de stérilisation et procédé pour appareil de traitement d'eau WO2012165694A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201180071319.8A CN103562141B (zh) 2011-06-02 2011-06-30 用于水处理设备的消毒设备和方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2011-0053494 2011-06-02
KR20110053494 2011-06-02

Publications (1)

Publication Number Publication Date
WO2012165694A1 true WO2012165694A1 (fr) 2012-12-06

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PCT/KR2011/004812 WO2012165694A1 (fr) 2011-06-02 2011-06-30 Appareil de stérilisation et procédé pour appareil de traitement d'eau

Country Status (4)

Country Link
KR (4) KR101181328B1 (fr)
CN (1) CN103562141B (fr)
MY (1) MY175377A (fr)
WO (1) WO2012165694A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105849050A (zh) * 2013-12-23 2016-08-10 豪威株式会社 Cdi式水处理装置
CN110963604A (zh) * 2019-12-05 2020-04-07 王�华 一种便于移动的医疗废水处理装置
CN111470678A (zh) * 2020-05-27 2020-07-31 宁波蓝野医疗器械有限公司 前端进水消毒系统
EP4361110A1 (fr) * 2022-10-31 2024-05-01 Pool Technologie Dispositif de production d'hypochlorite de sodium

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101987792B1 (ko) * 2012-11-22 2019-06-12 웅진코웨이 주식회사 수처리장치의 살균방법
KR102170139B1 (ko) * 2013-04-12 2020-10-26 쿠쿠홈시스 주식회사 제빙기 및 제빙방법
KR102211119B1 (ko) * 2013-12-23 2021-02-04 코웨이 주식회사 Cdi 방식의 수처리 장치
KR101717109B1 (ko) 2015-02-10 2017-03-16 엘지전자 주식회사 물공급장치 살균 방법
KR101772527B1 (ko) * 2015-02-10 2017-08-29 엘지전자 주식회사 살균 시스템
CN104843904A (zh) * 2015-05-22 2015-08-19 佛山市顺德区美的饮水机制造有限公司 净水设备、过滤系统及其水过滤方法
CN106565039B (zh) * 2015-10-08 2021-02-12 福库好希士株式会社 水处理系统、水处理系统的杀菌方法以及杀菌杯
KR102565811B1 (ko) * 2016-05-04 2023-08-11 코웨이 주식회사 수처리기의 살균 방법
KR102442479B1 (ko) * 2017-06-30 2022-09-13 쿠쿠홈시스 주식회사 수처리장치와 수처리장치의 살균방법
CN110169856A (zh) * 2019-05-08 2019-08-27 苏州欧圣电气股份有限公司 护理机及其排污管路的浸泡消毒方法
KR20230036676A (ko) 2021-09-08 2023-03-15 한남대학교 산학협력단 배관 세척용 살균세정장치 및 이를 이용한 배관의 세척방법

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100531667B1 (ko) * 2005-05-31 2005-11-29 이근섭 저수조를 자동으로 살균할 수있는 정수기 및 그 정수기의살균방법
KR20090047585A (ko) * 2007-11-08 2009-05-13 주식회사 웰테크놀러지 저수조 및 수 라인을 자동으로 소독하는 정수기 및 그정수기의 소독방법
KR20100062596A (ko) * 2008-12-02 2010-06-10 웅진코웨이주식회사 순환 전해살균가능한 정수기
KR20100131241A (ko) * 2009-06-05 2010-12-15 웅진코웨이주식회사 수처리 기기용 세척장치
KR20110001969A (ko) * 2009-06-29 2011-01-06 웅진코웨이주식회사 전해살균장치를 구비한 수처리 장치

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2121460U (zh) * 1991-08-02 1992-11-11 韩洪军 小型次氯酸钠发生器
CN2130093Y (zh) * 1992-07-07 1993-04-21 韩洪军 小型家用消毒器
US5944978A (en) * 1997-08-21 1999-08-31 Omco Co., Ltd. Cleaning method of an electrolyzed water forming apparatus and an electrolyzed water forming apparatus having mechanism for conducting the method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100531667B1 (ko) * 2005-05-31 2005-11-29 이근섭 저수조를 자동으로 살균할 수있는 정수기 및 그 정수기의살균방법
KR20090047585A (ko) * 2007-11-08 2009-05-13 주식회사 웰테크놀러지 저수조 및 수 라인을 자동으로 소독하는 정수기 및 그정수기의 소독방법
KR20100062596A (ko) * 2008-12-02 2010-06-10 웅진코웨이주식회사 순환 전해살균가능한 정수기
KR20100131241A (ko) * 2009-06-05 2010-12-15 웅진코웨이주식회사 수처리 기기용 세척장치
KR20110001969A (ko) * 2009-06-29 2011-01-06 웅진코웨이주식회사 전해살균장치를 구비한 수처리 장치

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105849050A (zh) * 2013-12-23 2016-08-10 豪威株式会社 Cdi式水处理装置
JP2017500201A (ja) * 2013-12-23 2017-01-05 コーウェイ カンパニー リミテッドＣｏｗａｙ Ｃｏ．， Ｌｔｄ． Ｃｄｉ方式の水処理装置
CN105849050B (zh) * 2013-12-23 2019-06-14 豪威株式会社 Cdi式水处理装置
US11084740B2 (en) 2013-12-23 2021-08-10 Coway Co., Ltd. CDI-type water treatment method
CN110963604A (zh) * 2019-12-05 2020-04-07 王�华 一种便于移动的医疗废水处理装置
CN111470678A (zh) * 2020-05-27 2020-07-31 宁波蓝野医疗器械有限公司 前端进水消毒系统
EP4361110A1 (fr) * 2022-10-31 2024-05-01 Pool Technologie Dispositif de production d'hypochlorite de sodium
FR3141457A1 (fr) * 2022-10-31 2024-05-03 Pool Technologie dispositif de production d’hypochlorite de sodium

Also Published As

Publication number Publication date
KR20120135140A (ko) 2012-12-12
CN103562141A (zh) 2014-02-05
KR101181329B1 (ko) 2012-09-13
MY175377A (en) 2020-06-23
KR20120135141A (ko) 2012-12-12
KR101308123B1 (ko) 2013-09-26
CN103562141B (zh) 2015-12-09
KR101181328B1 (ko) 2012-09-11
KR101734194B1 (ko) 2017-05-24

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