WO2012146546A2 - Masque cosmétique occlusif à dégagement gazeux - Google Patents

Masque cosmétique occlusif à dégagement gazeux Download PDF

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Publication number
WO2012146546A2
WO2012146546A2 PCT/EP2012/057305 EP2012057305W WO2012146546A2 WO 2012146546 A2 WO2012146546 A2 WO 2012146546A2 EP 2012057305 W EP2012057305 W EP 2012057305W WO 2012146546 A2 WO2012146546 A2 WO 2012146546A2
Authority
WO
WIPO (PCT)
Prior art keywords
layer
absorbent
cosmetic
chemical means
acid
Prior art date
Application number
PCT/EP2012/057305
Other languages
English (en)
Other versions
WO2012146546A3 (fr
Inventor
Dominique Bordeaux
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Publication of WO2012146546A2 publication Critical patent/WO2012146546A2/fr
Publication of WO2012146546A3 publication Critical patent/WO2012146546A3/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212—Face masks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/362—Polycarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/06—Preparations for care of the skin for countering cellulitis
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/08—Anti-ageing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/22—Gas releasing

Definitions

  • the present invention relates to cosmetic masks with gas evolution for the application of a care product. It also relates to the processes using such masks.
  • Cosmetic product is understood to mean a product as defined in Council Directive 93/35/EEC of 14 June 1993.
  • Masks that release CO 2 were initially used to treat scars. They later proved effective for reducing subcutaneous fat, or even for firming and thus redefining the oval of the face. Moreover, they are effective for minimizing freckles, acne and atopic dermatitis.
  • Such masks are applied to the face where they release CO 2 which is absorbed by the skin.
  • CO 2 promotes an increase in the supply of oxygen (O 2 ) which is required for cell metabolism. Specifically it reaches the blood vessels of the skin, thus increasing the partial pressure of CO 2 which results in blood acidification. This leads to the release of O 2 from haemoglobin (Bohr effect). The cells that are locally richer in O 2 will see their metabolism intensify. Mechanisms such as skin renewal are then accelerated, thus making it possible to treat signs of ageing or even scars. This improvement in metabolism also enables the face to be made lighter and whitened.
  • An improvement in the skin condition may also be the result of the prevention of inflammation. This mechanism is cancelled out owing to the absorption of CO 2 between the layers of phospholipids - main elements of the skin that are formed of bilayers - which contributes to tissue densification. (One of the main elements of the skin is called the phospholipid, formed of bilayers. CO 2 is absorbed between the phospholipid layers and densifies the tissues. This is one of the reasons why CO 2 can improve the skin condition while preventing inflammation.)
  • compositions are applied to the face and optionally covered with a nonwoven fabric.
  • the latter is simply laid on the CO 2 composition, matching up as best possible the shapes of the face.
  • such compositions are not yet entirely satisfactory and their efficacy is not yet optimal.
  • the CO 2 losses depend on the position of the CO 2 bubbles relative to the surface of the gel. Consequently, the CO 2 gel itself risks not being applied homogeneously to the face.
  • the CO 2 will not necessarily be sent to and concentrated on the skin, but it may just as well emerge from the gel via the nonwoven fabric.
  • the problem addressed by the invention is to provide a mask with gas evolution that improves the condition of the skin more than the masks of the prior art, both from the point of view of caring for the skin or the hydration thereof and from the point of view of slowing down the ageing process.
  • the mask proposed contains, in one of the layers that constitutes it (the absorbent layer) one portion of the formula, in the form of powder or anhydrous paste, which will generate CO 2 by reacting with the solution containing the acid.
  • This mask is designed starting from an "elastic-absorbent" nonwoven fabric constituted of a layer of a “non-absorbent” elastic nonwoven fabric or material, combined with a layer of an "absorbent” inelastic or not very elastic nonwoven fabric.
  • This nonwoven fabric may be stretched on several occasions without causing the disintegration, crinkling, tearing or separation of the "absorbent" inelastic layer that constitutes it.
  • This mask in addition to its elastic and absorbent properties, possesses:
  • the mask by being stretched, will also cause a stretching of the skin underneath, hence a lasting lift effect since the mask is then optionally attached or fastened by rubber bands and does not return to its initial shape,
  • the air impermeability of the elastic layer will prevent the formula impregnated in the absorbent layer from evaporating. It will also prevent the loss of the CO 2 generated and concentrate it in and orient it towards the skin, due to its impermeability properties.
  • a cosmetic support S especially a mask comprising:
  • a first layer made of an absorbent and inelastic nonwoven fabric comprising a first chemical means capable of reacting with a second chemical means in order to release a gas
  • the first layer comprising at least two corrugations, such that the first layer is placed in discontinuous contact with the second layer.
  • Another subject of the invention is a cosmetic process comprising the following steps:
  • a cosmetic support S especially a cosmetic mask capable of giving rise to gas evolution comprising:
  • a cosmetic support S the first layer of which comprises at least two corrugations, such that the first layer is placed in discontinuous contact with the second layer.
  • the gas is CO 2 .
  • this absorbent layer does not tear during the stretching of the mask over the face
  • the release of gas is more homogeneous on the skin, due to the fact that the powder is trapped between the corrugations of the first layer. Therefore, during the transport or handling of the support, the powder migrates very little and it also remains distributed in the spaces formed by the corrugations of the first layer. Moreover, by using an elastic second layer, it is possible to correctly follow the features of the face and to fit it to each contour of the face, for a better efficacy of the gas evolution.
  • Supports S are, for example, chosen from masks, wipes, patches, and in general all types of porous substrates.
  • these supports have an oblong structure, namely of thickness smaller than the dimensions of the plane in which they are defined.
  • Another impregnated support may, for example, be a flocked applicator, this applicator comprising, for example, a body made of elastomer or of plastic, covered on its surface with a flocking coating impregnated with the first means.
  • the support may be cut so as to be in the form of a disc, a mask, a towel, a glove, a precut roll or any other form suitable for a cosmetic use.
  • the first layer of the absorbent nonwoven fabric has a succession of generally uniform corrugations. These corrugations may be comparable to portions of circles having a perimeter (P). This layer may be attached to the second layer chemically by adhesive bonding, or thermally by melting.
  • the elastic second layer expands and the inelastic first layer stretches, without tearing, little by little.
  • the corrugations disappear to form, in the end, only a smooth nonwoven fabric that can be positioned on the skin. This operation can be repeated several times in order to correctly position the cosmetic support on the skin without destroying the inelastic layer.
  • the absorbent layer may be constituted of one or more consolidated webs of fibres. These fibres may be natural, modified natural, or artificial fibres. In general, the absorbent layer is made of a nonwoven fabric.
  • nonwoven fabric is understood to mean a substrate comprising fibres, in which substrate the individual fibres or the filaments are arranged in a disordered manner in a structure in the form of a sheet and which are neither woven nor knitted.
  • the fibres of the nonwoven fabric body are generally bonded together, either under the effect of a mechanical action (for example needle punching, air jet, etc.), or under the effect of a thermal action, or by addition of a binder.
  • Such a nonwoven fabric is, for example, defined by the standard ISO 9092 as a web or sheet of directionally or randomly orientated fibres, bonded by friction and/or cohesion and/or adhesion, excluding paper and products which are woven, knitted, tufted or stitch-bonded incorporating binding yarns or filaments.
  • a nonwoven fabric differs from a paper due to the length of the fibres used. In paper, the fibres are shorter. However, there are nonwoven fabrics based on cellulose fibre, which are manufactured by a wet-laid process and that have short fibres like in paper. The difference between a nonwoven fabric and a paper is generally the absence of hydrogen bonding between the fibres in a nonwoven fabric.
  • Layer 1 is a first layer of absorbent and inelastic nonwoven fibres comprising a first chemical means.
  • absorbent agent is understood to mean any compound capable of rapidly trapping a large amount of water.
  • the organic absorbent agent is therefore generally a hydrophilic or amphiphilic compound.
  • absorbent agent is understood to mean any compound having a static water absorption capacity, at ambient temperature (25°C), greater than or equal to 3 times its weight.
  • the absorbent agents are chosen from compounds having a static water absorption capacity greater than or equal to 5 times their weight, and preferably greater than or equal to 15 times their weight.
  • the compound to be tested in an amount of x grams, is placed in a beaker; water is added in an amount of 3x grams (preferably 5x grams and better still 15x grams). It is left to rest, without stirring, for 1 minute.
  • the compound can be considered to be an absorbent agent within the meaning of the invention.
  • the breaking force of the sheet measured according to the standard ED ANA WSP 110.4(05), is between 10% and 1000%, advantageously between 10% and 500%; - the material is elastically deformable, at least for stretching of greater than 1% and especially between 1% and 200%, when it is stretched according to the standard ED ANA WSP 110.4(05).
  • COMPOSITION OF LAYER 2 COMPOSITION OF LAYER 2:
  • the non-absorbent elastic layer may be constituted of a film of one or more elastic polymers or of one or more consolidated webs of elastic fibres.
  • the elastic layer may comprise one or more of the following characteristics, taken separately or in any technically possible combination(s):
  • the breaking force of the sheet measured according to the standard ED ANA WSP 110.4(05), is between 10% and 1000%, advantageously between 10% and 500%;
  • the material is elastically deformable, at least for stretching of greater than 1% and especially between 1% and 200%, when it is stretched according to the standard ED ANA WSP 110.4(05).
  • Layer 2 is non-absorbent: it does not satisfy the test for measuring the water absorption capacity described above.
  • the chemical means 4 is advantageously a powder, or a mixture of powders or else an anhydrous paste or a mixture of pastes (powders mixed in an anhydrous binder).
  • the chemical means 4 is chosen from carbonates or bicarbonates.
  • the alkali or alkaline-earth metal carbonate or bicarbonate is chosen for its reactivity with respect to the associated organic acid. The choice thereof falls within the competence of a person skilled in the art.
  • carbonate or bicarbonate compounds that may be used in the context of the present invention, mention may be made especially of sodium carbonate, sodium bicarbonate, potassium carbonate or potassium bicarbonate, magnesium carbonate, magnesium bicarbonate, calcium carbonate and calcium bicarbonate, and mixtures thereof.
  • Sodium bicarbonate is very particularly suitable for the invention.
  • its amount is also adjusted with regard to that of the associated organic acid. It may especially vary from 1 to 15%, in particular from 2 to 8% by weight of the composition containing it.
  • the molar ratio between the organic acid and the carbonate or bicarbonate ranges from 0.5 to 10, in particular from 1 to 8 and preferably from 1 to 7.
  • the chemical means 5 is an organic acid.
  • any organic acid that is compatible with cosmetic topical use will be chosen, especially from C2 to C22 carboxylic acids.
  • the acid in accordance with the invention is advantageously soluble in water.
  • organic acid that is suitable within the context of the present invention, mention may especially be made of citric acid, tartaric acid, ascorbic acid, succinic acid, malic acid, malonic acid, fumaric acid, glutaric acid, adipic acid, pimelic acid, maleic acid, phthalic acid, glutamic acid, aspartic acid, glycolic acid, tartronic acid, hydroxybenzoic acid, salicylic acid, tropic acid, cinnamic acid, phenylacetic acid, nicotinic acid, sorbic acid and trimellitic acid, and mixtures thereof.
  • the organic acid is citric acid.
  • the effervescent reaction induced by bringing into contact an organic acid and a carbonate or bicarbonate takes place in an aqueous medium.
  • aqueous medium is understood to mean any medium containing water molecules that are capable of reacting with said organic acid and said carbonate or bicarbonate.
  • compositions containing the organic acid may be in any galenic form conventionally used for application to the skin.
  • compositions according to the invention may be more or less fluid and may have the appearance of a cream, an ointment, a milk, a lotion, a serum, a paste or a foam.
  • compositions may contain other compounds on condition that these, on the one hand, are compatible with the latter and, on the other hand, are not of a nature to adversely affect the manifestation of the expected effervescent reaction.
  • At least the composition comprising the organic acid comprises at least one fatty phase formed from at least one oil.
  • the width of a corrugation is between 1 mm and 25 mm and preferably between 5 mm and 10 mm,
  • the height of a corrugation is less than 10 mm, preferably less than
  • the gas released is CO 2 and the first chemical means 4 comprises at least one carbonate and the second chemical means 5 comprises at least one acid,
  • the acid is chosen from formic, acetic, propionic, butyric, valeric, oxalic, malonic, succinic, glutaric, adipic, pimelic, fumaric, maleic, phthalic, isophthalic, terephthalic, glutamic, asparagic, glycolic, malic, tartaric, citric, lactic, hydroxyacrylic, alpha-oxybutyric, glyceric, tartronic, salicylic, gallic, tropic, ascorbic, gluconic and phosphoric acids and the carbonate is chosen from ammonium, potassium, calcium, and sodium carbonates, sodium and potassium bicarbonate and sodium, calcium and potassium sesquicarbonates.
  • FIG. 1 represents a perspective view of a mask outside of the invention
  • FIG. 2 represents a perspective view of a mask according to the invention
  • FIG. 3 represents a cross section along the XZ plane of a mask used according to the invention, before being impregnated with chemical reactants,
  • Figure 4 represents a cross section along the XZ plane of the mask from Figure 3 after having been impregnated with powder and before being brought into contact with the liquid,
  • Figure 5 represents a cross section along the XZ plane of the mask from Figure 4 during the reaction between the powder and the liquid
  • FIG. 6 represents a cross section along the XZ plane of the stretched mask from Figure 5.
  • the mask represented is not part of the invention. Specifically, there are two areas of contact PI and P2 between the absorbent inelastic layer 1 and the non-absorbent elastic layer 2. These areas PI and P2 define a corrugation. It has approximately the shape of a semi-cylinder 7 cut longitudinally.
  • the mask represented in Figure 2 is part of the invention. Specifically, there are three areas of contact PI and P2 and P3 between the absorbent inelastic layer 1 and the non-absorbent elastic layer 2. The areas PI and P2 define a first corrugation 7. The areas P2 and P3 define a second corrugation 8.
  • the mask represented in cross section along the XZ plane in Figure 3 comprises 5 corrugations 7, 8, 9, 10 and 11. This mask does not yet comprises any chemical reactant.
  • Chosen as powder 4 are, for example, CaCl 2 , NaHC0 3 , CaC0 3 , from the perspective of CO 2 evolution, or else clays or zeolites, from the perspective of exothermic reaction and release of heat.
  • the user deposits an acid 5, such as citric acid, on the mask that is impregnated with powder 4.
  • an acid 5 such as citric acid
  • the citric acid 5 may be poured over the mask from a bottle.
  • a reaction occurs between the powder 5 and the acid 4 that results in evolution of CO 2 .
  • the device (F) is pulled on both sides as shown in Figure 5, the elastic layer 2 expands and the inelastic layer 1 stretches, without tearing, little by little.
  • the cosmetic preparation is expelled outwards (desorption) under the effect of the force exerted on the nonwoven fabric.
  • the corrugations disappear to form, in the end, only a smooth nonwoven fabric that can be positioned on the skin 3 as represented in Figure 6.
  • the CO 2 Via an occlusive effect, due to the barrier of the elastic layer, and via a pressure effect, due to the force produced by the elastic layer, the CO 2 is kept in contact with the skin and is sent to penetrate therein. This results in a diffusion into the skin, for an increase in the efficacy of the CO 2 .

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Gerontology & Geriatric Medicine (AREA)
  • Cosmetics (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)

Abstract

L'invention porte sur un support cosmétique S, en particulier un masque, comprenant : une première couche (1) constituée d'un non-tissé absorbant et inélastique comprenant un premier moyen chimique (4) pouvant réagir avec un second moyen chimique (5) afin de libérer un gaz et une seconde couche non absorbante et élastique (2), la première couche (1) comprenant au moins deux ondulations, de façon à ce que la première couche (1) soit mise en contact de façon discontinue avec la seconde couche (2).
PCT/EP2012/057305 2011-04-27 2012-04-20 Masque cosmétique occlusif à dégagement gazeux WO2012146546A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR1153593 2011-04-27
FR1153593A FR2974499B1 (fr) 2011-04-27 2011-04-27 Masque cosmetique occlusif a degagement gazeux
US201161482229P 2011-05-04 2011-05-04
US61/482,229 2011-05-04

Publications (2)

Publication Number Publication Date
WO2012146546A2 true WO2012146546A2 (fr) 2012-11-01
WO2012146546A3 WO2012146546A3 (fr) 2012-12-20

Family

ID=44549216

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2012/057305 WO2012146546A2 (fr) 2011-04-27 2012-04-20 Masque cosmétique occlusif à dégagement gazeux

Country Status (2)

Country Link
FR (1) FR2974499B1 (fr)
WO (1) WO2012146546A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3040275A1 (fr) * 2015-08-28 2017-03-03 Oreal Article cosmetique destine a etre applique sur une surface corporelle, utilisation et procede associes
WO2021128119A1 (fr) * 2019-12-26 2021-07-01 L'oreal Kit de soin des matières kératiniques

Citations (2)

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Publication number Priority date Publication date Assignee Title
WO1999024043A1 (fr) 1997-11-07 1999-05-20 Medion Research Laboratories Inc. Compositions visqueuses contenant du dioxyde de carbone
WO2004004745A1 (fr) 2002-07-05 2004-01-15 Neochemir Inc. Preparation a usage externe a base de dioxyde de carbone et substance destinee a la formation d'une preparation a usage externe a base de dioxyde de carbone

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US5814178A (en) * 1995-06-30 1998-09-29 Kimberly-Clark Worldwide, Inc. Process for making a bulked fabric laminate
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US7045029B2 (en) * 2001-05-31 2006-05-16 Kimberly-Clark Worldwide, Inc. Structured material and method of producing the same
KR101333245B1 (ko) * 2005-01-28 2013-11-26 네오케미아 가부시키가이샤 이산화탄소 외용제 제조용 조성물
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Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
WO1999024043A1 (fr) 1997-11-07 1999-05-20 Medion Research Laboratories Inc. Compositions visqueuses contenant du dioxyde de carbone
EP1043023A1 (fr) 1997-11-07 2000-10-11 Medion Research Laboratories Inc. Compositions visqueuses contenant du dioxyde de carbone
WO2004004745A1 (fr) 2002-07-05 2004-01-15 Neochemir Inc. Preparation a usage externe a base de dioxyde de carbone et substance destinee a la formation d'une preparation a usage externe a base de dioxyde de carbone
EP1541155A1 (fr) 2002-07-05 2005-06-15 Neochemir Inc. Preparation a usage externe a base de dioxyde de carbone et substance destinee a la formation d'une preparation a usage externe a base de dioxyde de carbone

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3040275A1 (fr) * 2015-08-28 2017-03-03 Oreal Article cosmetique destine a etre applique sur une surface corporelle, utilisation et procede associes
WO2017036974A1 (fr) * 2015-08-28 2017-03-09 L'oreal Article cosmétique destiné à être appliqué sur une surface du corps, ainsi qu'utilisation et procédé associés
WO2021128119A1 (fr) * 2019-12-26 2021-07-01 L'oreal Kit de soin des matières kératiniques
CN114828808A (zh) * 2019-12-26 2022-07-29 莱雅公司 用于护理角蛋白材料的套装
CN114828808B (zh) * 2019-12-26 2024-06-18 莱雅公司 用于护理角蛋白材料的套装

Also Published As

Publication number Publication date
WO2012146546A3 (fr) 2012-12-20
FR2974499B1 (fr) 2013-09-13
FR2974499A1 (fr) 2012-11-02

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