WO2021128119A1 - Kit de soin des matières kératiniques - Google Patents

Kit de soin des matières kératiniques Download PDF

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Publication number
WO2021128119A1
WO2021128119A1 PCT/CN2019/128546 CN2019128546W WO2021128119A1 WO 2021128119 A1 WO2021128119 A1 WO 2021128119A1 CN 2019128546 W CN2019128546 W CN 2019128546W WO 2021128119 A1 WO2021128119 A1 WO 2021128119A1
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WO
WIPO (PCT)
Prior art keywords
kit
composition
kit according
weight
amount
Prior art date
Application number
PCT/CN2019/128546
Other languages
English (en)
Inventor
Zoe LEE
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Priority to CN201980103260.2A priority Critical patent/CN114828808B/zh
Priority to PCT/CN2019/128546 priority patent/WO2021128119A1/fr
Publication of WO2021128119A1 publication Critical patent/WO2021128119A1/fr

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0212Face masks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216Solid or semisolid forms
    • A61K8/022Powders; Compacted Powders
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241Containing particulates characterized by their shape and/or structure
    • A61K8/0279Porous; Hollow
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88Two- or multipart kits
    • A61K2800/882Mixing prior to application

Definitions

  • the present invention relates to kits for caring for the keratin materials, in particular the skin, and in particular to a kit for formulation of cosmetic products comprising at least one kit composition as a dry part.
  • the present invention relates to a mask product comprising the kits, and is prepared by the kits caring for keratin materials, particularly skin. Further, the present invention relates to use of same for caring for keratin materials, especially the skin.
  • the present invention also relates to a method for cosmetic treatment of keratinous materials such as the skin, mucous membranes, making use of the said kit.
  • masks are highly efficient products and provide skin benefits such as hydration, moisturizing, whitening, and so on.
  • tissue type category there exists a new type of “fresh mix” mask, which, upon application, the tissue is mixed with the cosmetic composition.
  • This type of mask is favored by the consumers for many aspects, such as a better stability of skin active compounds, a unique usage experience, and so on.
  • consumers tend to have more and more demand in terms of transformation during the application of the mask products, such transformation can be, for example, tissue texture transformation, color and odor change, even sound and/or bubble/gas generation.
  • bubble/gas generating ingredients There are many known bubble/gas generating ingredients. For example in the food industry, pop candy is known to generate gas and meanwhile generate popping sound.
  • compositions for caring for the skin which is efficient in the cosmetic properties such as hydration, moisturizing, skin sensory, as well as a unique usage experience like “pop candy” , and easily impregnated with improved solubility and dissolution rate.
  • a mask product which, when mixing with at least one wet part, shows an improved solubility and dissolution rate, at the same time, provides good skin conditioning benefit, in particular more hydration and unique usage experience (e.g. tactile or acoustic effect) , more skin comfort feel.
  • kit which comprises (1) a first kit composition as a dry part, comprising at least one substrate, at least one powder composition A, comprising gasified particles and optionally auxiliary powder.
  • Another subject of the present invention is a process for caring for and/or making up keratin materials, especially the skin, comprising applying the mask prepared from the kit of the present invention, for example as above, wherein said caring for comprising whitening, providing hydration, detoxing and radiance effect, as well as unique experience like popping sounds.
  • Another subject of the present invention is use of the mask prepared from the kit of the present invention for caring for and/or making up keratin materials, especially the skin.
  • the present masks obtained have the following advantages:
  • composition A comprising:
  • At least one gasified particles comprising at least one gas enclosed in a solid enveloping material, wherein said solid enveloping material is selected so that said at least one gas is released when said solid enveloping material comes into contact with water or moisture.
  • the kit further comprises a second kit composition, comprising at least one aqueous composition B, which comprises at least one water-soluble organic solvent, wherein the first kit composition and the second kit composition are separately placed from one another.
  • kits according to the present invention for caring for keratin materials, especially the skin.
  • the “keratin material” is the skin.
  • skin intend all the body skin.
  • the keratin material is the face, or the neck, especially the face.
  • the gasified particles provide a special sensation, for example, popping, crackling, or sizzling sound (pop effect) during product use.
  • the gasified particles comprise at least one gas enclosed in a solid enveloping material.
  • the solid material is selected so that the gas is released on contact with water or moisture.
  • the enclosed gas may be an inert gas or an appropriate gas mixture, and is preferably carbon dioxide, oxygen, nitrogen or air, of which carbon dioxide is especially preferred, since it provides an intense sound effect.
  • the solid enveloping material (s) is water soluble material (s) .
  • the enveloping material is preferably based on sugar, i.e. based on mono-, oligo-or polysaccharides.
  • the sugar particularly could be trehalose, sucrose, lactose, glucose, dextrose, maltose, fructose, disaccharides, trisaccharides, tetrasaccharides, pentasaccharides, hexasaccharides and higher oligo-or polysaccharides or sugar materials, or their mixtures.
  • alternative materials could be used to encapsulate the gas.
  • alternative materials comprise water soluble polymers such as polyethylene glycols (PEG) and polyvinyl alcohols (PVA) as well as blends of these with waxes, e.g. parafin.
  • the particle size for example, could be from 0.1 to 5 mm, or from 0.5 to 4.5 mm.
  • the solid enveloping material is chosen from the group consisting of maltose, sucrose, trehalose or a mixture of maltose, sucrose and trehalose, and the gas is carbon dioxide.
  • the kit could also comprise at least one auxiliary powder (s) .
  • the auxiliary powders of the present invention keep the gasified particles of the present invention dry and unmelted.
  • the examples of the auxiliary powders of the present invention comprise:
  • hydrophilic powders comprising metal oxides such as silica, metal silicates such as silica silicate or derivatives thereof, nylon, montmorillonite, mineral substances, sieves etc.
  • the water soluble polymers used can be:
  • the size of the auxiliary powders of the present invention could be from 2 to 25 ⁇ m, or from 5 to 20 ⁇ m, or from 5 to 15 ⁇ m.
  • the auxiliary powder (s) can be used in dry part (i.e. the first kit composition) or coated on gasified particles, and provide improved humidity resistance of gasified particles, especially at higher temperature and humidity condition.
  • auxiliary powder (s) that may improve humidity resistance, dispensability and dissolving rate are preferable. Thanks to the presence of auxiliary powder (s) of the present invention, the kit of the present invention has improved stability while improved dispensability and dissolving rate.
  • the auxiliary powder comprises silica, silica silyate, nylon, polyalkylsilsesquioxane, or its derivatives.
  • the auxiliary powder further comprises at least one gas-generating agent, such as chosen from sodium bicarbonate, potassium bicarbonate, sodium carbonate, potassium carbonate, and their mixtures, preferably sodium bicarbonate so as to support generation of carbon dioxide.
  • gas-generating agent such as chosen from sodium bicarbonate, potassium bicarbonate, sodium carbonate, potassium carbonate, and their mixtures, preferably sodium bicarbonate so as to support generation of carbon dioxide.
  • the substrate used in the present invention could be all kinds of suitable substrate in the cosmetic field. Particularly, is selected from the group of:
  • a water insoluble substrate that is a cosmetically and pharmaceutically acceptable substrate, and/or
  • ⁇ A a first tissue composition comprising at least one gel-forming agent that is a water soluble salt
  • first tissue composition and the second tissue composition are separately placed from one another.
  • water insoluble means that the substrate is not dissolvable in water, nor does it breaks apart upon immersion in water.
  • the material of the substrate according to the present invention is not limited, and therefore any material could be used for preparing; that is the water-insoluble substrate is all types of cosmetically and pharmaceutically acceptable substrates. Two or more materials also may be used.
  • the water insoluble substrate is a woven or nonwoven fabric made of a fiber chosen from natural fibers, semi-natural fibers, and synthetic fibers, for example, a woven or nonwoven fabric made of a fiber of the at least one water insoluble alginate solely or together with one or more other fibers chosen from natural fibers such as cotton, pulp, bamboo and cellulose fibers, semi-natural fibers such as viscose rayon fibers, synthetic fibers such as polyester fibers, polyethylene terephthalate fibers, polyethylene fibers and polypropylene fibers, or a mixture thereof. Two or more selected from the above fibers may be used in combination.
  • the material may be a film or sheet made from at least one selected from synthetic polymers such as polyethylenes and polyvinylalcohols, semi-synthetic polymers such as bio-celluloses and alginates, and natural polymers such as polysaccharides (e.g., carageenan and xanthan gum) , mucopolysaccharides (e.g., hyaluronic acid and sodium hyaluronate) , polypeptides (e.g., ⁇ -polyglutamic acid) and proteins (e.g., gelatin and collagen) .
  • the film or sheet may be in the form of a gel or a jelly which may be transparent, translucent or opaque. Two or more selected from the above substances may be used in combination.
  • the folded sheet according to the present invention may be made of two or more layers.
  • the substrate shown in Figures 1 and 2 may be a layered substrate comprising two or more stacked layers. If a layered substrate is used, the material of each stacked layer may be the same or different from each other.
  • the layered substrate may be prepared by laminating the above film or sheet made from a synthetic polymer, a semi-synthetic polymer and/or a natural polymer on the above woven or non-woven fabric.
  • the substrate could be made into a wide variety of shapes and forms such as flat pads, thick pads, thin sheets of irregular thickness, depending on the desired use and characteristic of the mask.
  • the substrate is typically designed to fit the area of the skin to which topical application is desired.
  • the substrate is designed to correspond to the shape of the face avoiding the eye, nostril, and mouth areas, as necessary.
  • Nonlimiting examples of the substrates useful in the present invention are described, for example, in the patent application WO 02/062132, or EP 2489286A.
  • Such water-insoluble substrates or masks with holes, perforation-like lines or cutting lines formed whereon could be obtained by cutting desired holes on the conventional masks that are available on the market.
  • Mentions may be made of the suitable commercially available masks such as NA60RP70 from Beijing Dongfang Dayuan Non-wovens Fabric Co., Ltd. Then by using die-cutting machine ZG-10T from Hangzhou Zhiling Co. Ltd for cutting desired holes on the mask, the water-insoluble substrates of the present invention is obtained.
  • the gel substrate according to the present invention comprises:
  • ⁇ A a first substrate composition comprising at least one gel-forming agent that is a water soluble salt
  • first substrate composition and the second substrate composition are separately placed from one another.
  • the gel-forming agent of the present invention could be water soluble polyvalent metal alginic compound, for example, alkali metal alginic compound.
  • the alkali metal alginic compound may be chosen from sodium alginate and potassium alginate, preferably sodium alginate.
  • the aqueous phase comprising at least one water soluble gelatinizing agent comprises a salt solution of calcium, a salt solution of strontium, a salt solution of zinc, a salt solution of copper, a salt solution of manganese, with an acid, in which the acid is preferably chosen from sulfuric acid and hydrochloric acid, or a mixture thereof, preferably calcium chloride, calcium sulfate, or a mixture thereof.
  • the gel substrate could be prepared comprising the following steps:
  • the gel substrate used may improve roughness of substrate and make less irritation of remained gasified particles on the skin.
  • the aqueous composition comprises at least one cosmetically acceptable water-soluble organic solvent, water, such as deionized water, optionally comprising functional agent (s) that does not deteriorate mask’s properties.
  • the water-soluble organic solvent may comprises polyol (s) or derivatives thereof and polyoxyalkylene glyceryl ether (s) .
  • polyol means a hydrocarbon-based chain comprising at least two carbon atoms, preferably from 2 to 50 carbon atoms, preferably from 4 to 40 carbon atoms, preferably comprising from 6 to 35 carbon atoms and preferentially comprising from 10 to 32 carbon atoms, and bearing at least two hydroxyl groups.
  • the polyol according to the present invention may be chosen from glycerol, propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, dipropylene glycol, diethylene glycol, 1, 3-propanediol, D-mannitol (or 1, 2, 3, 4, 5, 6-hexanehexol) , polyoxyethylene glyceryl ether such as glycereth-26, and sorbitol (or D-glucitol) , alone or as a mixture with other polyol glycol ethers (especially comprising from 3 to 30 carbon atoms) such as mono-, di-or tripropylene glycol (C1-C4) alkyl ethers or mono-, di-or triethylene glycol (C 1 -C 4 ) alkyl ethers.
  • glycerol propylene glycol
  • butylene glycol pentylene glycol
  • hexylene glycol dipropylene glycol
  • the water-soluble organic solvent preferably dipropylene glycol, polyoxyethylene glyceryl ether and its mixture, may be present in the kit in a content of between 0%and 35%by weight relative to the total weight of the kit, in particular in a content of between 2%and 30%by weight relative to the total weight of the kit, particularly in a content of between 3%and 20%by weight relative to the total weight of the kit, more particularly in a content of between 4%and 15%by weight relative to the total weight of the kit, in particular in a content of between 5%and 10%by weight relative to the total weight of the kit.
  • the specific water-soluble organic solvent used in aqueous composition B may improve dispensability and dissolving speed, in which the water-soluble organic solvent preferably selected from dipropylene glycol, polyoxyalkylene glyceryl ether such as glycereth-26 or a mixture of dipropylene glycol and glycereth-26.
  • the water-soluble organic solvent preferably selected from dipropylene glycol, polyoxyalkylene glyceryl ether such as glycereth-26 or a mixture of dipropylene glycol and glycereth-26.
  • Water that is suitable for use in the present invention may be floral water such as cornflower water and/or a mineral water and/or spring water.
  • the aqueous composition may also comprise additional water-miscible organic solvents (at room temperature: 25°C) .
  • the aqueous composition may also comprise any water-soluble or water-dispersible compound that is compatible with an aqueous composition, such as gelling agents, film-forming polymers, thickeners, and mixtures thereof.
  • the aqueous composition may also comprise viscosity increasing agent ( “thickener” or “rheology increasing agent” ) for better stability.
  • Representative viscosity increasing agents comprise thickening agents and gelling agents.
  • the viscosity increasing agent (s) that may be useful in the practice of embodiments of the disclosure comprise those conventionally used in cosmetics and pharmaceutical products. Viscosity increasing agents may be selected from, for example vegetable gums, salts, acrylate-based viscosity increasing agents and mixtures thereof.
  • the kit or products of the present invention may comprise at least one functional agent, such as, at least one active agent, for example, chosen from: desquamating or moisturizing agents; depigmenting or anti-depigmenting agents; anti-glycation agents; anti-NO agents; agents for stimulating the synthesis of dermal or epidermal macromolecules and/or for preventing their degradation; agents for stimulating fibroblast or keratinocyte proliferation and/or keratinocyte differentiation; muscle relaxants or dermo-decontracting agents; free-radical scavengers or anti-pollution agents; tensioning agents; agents acting on the capillary circulation; and mixtures thereof.
  • at least one active agent for example, chosen from: desquamating or moisturizing agents; depigmenting or anti-depigmenting agents; anti-glycation agents; anti-NO agents; agents for stimulating the synthesis of dermal or epidermal macromolecules and/or for preventing their degradation; agents for stimulating fibroblast or keratinocyte proliferation and/or
  • active agents for improving the condition of the skin in the mask such as moisturizers or agents serving to improve the natural lipid barrier, such as ceramides, cholesterol sulfates, and/or fatty acids, and mixtures thereof.
  • active agents for improving the condition of the skin in the mask such as moisturizers or agents serving to improve the natural lipid barrier, such as ceramides, cholesterol sulfates, and/or fatty acids, and mixtures thereof.
  • enzymes that have activity on the skin such as proteases, lipases, cerebrosidases, and/or melanases, and mixtures thereof.
  • active agents there are agents for drugs, peptides, proteins, detectable labels, contrast reagents, pain-killing, anesthetics, antibacterial agents, anti-yeast agents, antifungal agents, antiviral agents, anti-dermititis agents, anti-pruritic agents, anti-emetics, vascular protectors, agents against motion sickness, anti-irritants, anti-inflammatory agents, immunomodulators, anti-hyperkeratolytic agents, agents for treating dry skin, antiperspirants, anti-psoriatic agents, antidandruff agents, anti-aging agents, anti-asthmatic agents and bronchodilators, sunscreen agents, antihistamines, healing agents, corticosteroids, tanning agents, and mixtures thereof.
  • the content of the at least one active agent or other optional components in the first kit composition and/or in the second kit composition may be adjusted as a function of the intended purpose of the kit.
  • the kit of the present invention may also comprise adjuvants that are common in cosmetics and/or dermatology, such as preserving agents, antioxidants, pH modifiers (acidic or basic) , fragrances, fillers, bactericides, odor absorbers, colorants (pigments and dyes) , emulsifiers, and also lipid vesicles.
  • adjuvants that are common in cosmetics and/or dermatology, such as preserving agents, antioxidants, pH modifiers (acidic or basic) , fragrances, fillers, bactericides, odor absorbers, colorants (pigments and dyes) , emulsifiers, and also lipid vesicles.
  • the additives selected from, preservatives, such as phenoxyethanol; surfactants, comprising including silicone surfactants, W/O and O/W surfactants; oils, comprising including cosmetic oils, fatty compounds, silicone oils such as dimethicone, botanical oils and essential oils; emulsifiers, comprising including silicone emulsifiers; elastomers; fillers such as clays, talc, organic thickeners with for instance, anionic, cationic, nonionic, and amphoteric polymeric associative thickeners and combinations thereof; carbomers; polymers; penetrants; sequestrants; fragrances; dispersants; film-forming agents; ceramides; opacifiers and combinations thereof.
  • preservatives such as phenoxyethanol
  • surfactants comprising including silicone surfactants, W/O and O/W surfactants
  • oils comprising including cosmetic oils, fatty compounds, silicone oils such as dimethicone, botanical oils and essential oils
  • emulsifiers
  • the mask according to the present invention could be prepared comprising the following steps:
  • the mask according to the present invention also could be prepared comprising the following steps:
  • Another subject of the present invention is a process for caring for and/or making up keratin materials, especially the skin, comprising applying the mask prepared from the kit of the present invention, for example as above, wherein said caring for comprising whitening, providing hydration, detoxing and radiance effect, as well as unique experience like popping sounds.
  • Another subject of the present invention is use of the mask prepared from the kit of the present invention for caring for and/or making up keratin materials, especially the skin.
  • the present kit has two parts separately: (1) dry part -- (first kit composition (comprising substrate and powder (s) ) and (2) wet part -- (second kit composition (comprising aqueous composition) ) , the present kit provides increased humidity resistance of active agent, for example, gasified particles.
  • the present kit has two parts (dry part and wet part) separately, just before using, the two parts are mixed to be a mask, that provides better stability trend and more hydration and nutrition sensory touch feel.
  • the present kit provides faster dissolving rate and better dispersion rate of the powder (s) of the present invention.
  • Examples 1-3 were mixed with 30 grams of water, whereas Examples 4-6 were mixed of tissue, dry part and wet part.
  • Hydration feeling was tested by applying the Examples on the skin, respectively, and observed the skin finish in 15 min.
  • Humidity was tested using a humidity detector in the stability chamber where the Examples were placed in sealed sachets, respectively, under environmental humidity of 80%and temperature of 45°C, for 2 months.
  • the units and masks of the present invention had good properties, for example, good hydration feeling, good usage experience, good humidity resistance, good dissolving speed and good stability. Furthermore, the units and masks that comprise the auxiliary powder of the present invention (e.g. silica) had better properties (hydration feeling, usage experience, humidity resistance, dissolving speed and stability) than the units and masks without the auxiliary powder (e.g. silica) .
  • the units and masks of the present invention that comprises the water-soluble organic solvent e.g. a mixture of glycereth-26 and dipropylene glycol
  • the units and masks that comprise silica had better properties (particularly improved humidity resistance and dissolving speed) than the units and masks comprising cellulose.
  • the mask of the present invention is superior in terms of beneficial properties, e.g. good hydration feeling, usage experience, humidity resistance, dissolving speed and stability.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un kit comprenant : 1) une première composition de kit, comprenant au moins un substrat, au moins une composition de poudre A, comprenant : au moins une particule gazéifiée, lesdites particules gazéifiées comprenant au moins un gaz enfermé dans un matériau d'enveloppe solide, ledit matériau d'enveloppe solide étant choisi de telle sorte que ledit au moins un gaz soit libéré lorsque ledit matériau d'enveloppe solide entre en contact avec de l'eau. L'invention concerne également un procédé de préparation d'un masque comprenant ledit kit.
PCT/CN2019/128546 2019-12-26 2019-12-26 Kit de soin des matières kératiniques WO2021128119A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201980103260.2A CN114828808B (zh) 2019-12-26 2019-12-26 用于护理角蛋白材料的套装
PCT/CN2019/128546 WO2021128119A1 (fr) 2019-12-26 2019-12-26 Kit de soin des matières kératiniques

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2019/128546 WO2021128119A1 (fr) 2019-12-26 2019-12-26 Kit de soin des matières kératiniques

Publications (1)

Publication Number Publication Date
WO2021128119A1 true WO2021128119A1 (fr) 2021-07-01

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PCT/CN2019/128546 WO2021128119A1 (fr) 2019-12-26 2019-12-26 Kit de soin des matières kératiniques

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WO (1) WO2021128119A1 (fr)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1574207A1 (fr) * 1997-11-07 2005-09-14 Medion Research Laboratories Inc. Utilisation cosmétique de compositions visqueuses comprenant du dioxyde de carbone
US20110165211A1 (en) * 2002-07-05 2011-07-07 Masaya Tanaka Carbon dioxide external preparation, and material for formation of carbon dioxide external preparation
WO2012146546A2 (fr) * 2011-04-27 2012-11-01 L'oreal Masque cosmétique occlusif à dégagement gazeux
US20150297475A1 (en) * 2012-02-29 2015-10-22 Medion Research Laboratories Inc. Carbon-dioxide-generating cosmetic sheet product
CN106265240A (zh) * 2016-08-19 2017-01-04 上海乐宝日化股份有限公司 一种含有氢气的凝胶面膜
CN108743605A (zh) * 2018-07-02 2018-11-06 上海莎伦巍化学科技有限公司 一种二氧化碳美容皮肤外用物组合及其制备方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4275083A (en) * 1979-10-26 1981-06-23 General Foods Corporation Gasified candy enrobed with oleaginous material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1574207A1 (fr) * 1997-11-07 2005-09-14 Medion Research Laboratories Inc. Utilisation cosmétique de compositions visqueuses comprenant du dioxyde de carbone
US20110165211A1 (en) * 2002-07-05 2011-07-07 Masaya Tanaka Carbon dioxide external preparation, and material for formation of carbon dioxide external preparation
WO2012146546A2 (fr) * 2011-04-27 2012-11-01 L'oreal Masque cosmétique occlusif à dégagement gazeux
US20150297475A1 (en) * 2012-02-29 2015-10-22 Medion Research Laboratories Inc. Carbon-dioxide-generating cosmetic sheet product
CN106265240A (zh) * 2016-08-19 2017-01-04 上海乐宝日化股份有限公司 一种含有氢气的凝胶面膜
CN108743605A (zh) * 2018-07-02 2018-11-06 上海莎伦巍化学科技有限公司 一种二氧化碳美容皮肤外用物组合及其制备方法

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CN114828808A (zh) 2022-07-29

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