WO2012141647A1 - Powder based balancing layer - Google Patents

Powder based balancing layer Download PDF

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Publication number
WO2012141647A1
WO2012141647A1 PCT/SE2012/050386 SE2012050386W WO2012141647A1 WO 2012141647 A1 WO2012141647 A1 WO 2012141647A1 SE 2012050386 W SE2012050386 W SE 2012050386W WO 2012141647 A1 WO2012141647 A1 WO 2012141647A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
applying
balancing
core
mix
Prior art date
Application number
PCT/SE2012/050386
Other languages
French (fr)
Inventor
Niclas HÅKANSSON
Hans Persson
Jan Jacobsson
Original Assignee
Ceraloc Innovation Belgium Bvba
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to PL12771822T priority Critical patent/PL2697060T3/en
Priority to NZ615287A priority patent/NZ615287B2/en
Priority to CN201280016762.XA priority patent/CN103459145B/en
Priority to RU2013148006/13A priority patent/RU2591466C2/en
Priority to EP12771822.9A priority patent/EP2697060B1/en
Priority to ES12771822T priority patent/ES2805332T3/en
Priority to BR112013025558-7A priority patent/BR112013025558B1/en
Priority to AU2012243457A priority patent/AU2012243457B2/en
Application filed by Ceraloc Innovation Belgium Bvba filed Critical Ceraloc Innovation Belgium Bvba
Priority to CA2832040A priority patent/CA2832040C/en
Priority to MX2013011536A priority patent/MX342546B/en
Publication of WO2012141647A1 publication Critical patent/WO2012141647A1/en
Priority to UAA201312541A priority patent/UA112982C2/en
Priority to ZA2013/07461A priority patent/ZA201307461B/en
Priority to HRP20200960TT priority patent/HRP20200960T1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/15—Impregnating involving polymerisation including use of polymer-containing impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/02—Staining or dyeing wood; Bleaching wood
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
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    • B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/06—Making particle boards or fibreboards, with preformed covering layers, the particles or fibres being compressed with the layers to a board in one single pressing operation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
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    • B27N7/00—After-treatment, e.g. reducing swelling or shrinkage, surfacing; Protecting the edges of boards against access of humidity
    • B27N7/005—Coating boards, e.g. with a finishing or decorating layer
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    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/02—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board the layer being formed of fibres, chips, or particles, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard
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    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/042—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
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    • B32B21/14—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood board or veneer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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    • C08J7/04—Coating
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/10—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of wood or with an outer layer of wood
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/04—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/04—Flooring or floor layers composed of a number of similar elements only of wood or with a top layer of wood, e.g. with wooden or metal connecting members
    • E04F15/045—Layered panels only of wood
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2200/00—Wooden materials to be treated
    • B27K2200/10—Articles made of particles or fibres consisting of wood or other lignocellulosic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
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    • B27N3/04—Manufacture of substantially flat articles, e.g. boards, from particles or fibres from fibres
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    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B32B2310/08—Treatment by energy or chemical effects by wave energy or particle radiation
    • B32B2310/0806—Treatment by energy or chemical effects by wave energy or particle radiation using electromagnetic radiation
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    • C—CHEMISTRY; METALLURGY
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/31982—Wood or paper

Definitions

  • the disclosure generally relates to the field of panels with a decorative surface layer and a balancing and/or protective layer, preferably floor and wall panels.
  • the disclosure relates to production methods to produce such panels.
  • Embodiments of the present invention are particularly suitable for use in production of floating floors, which are formed of floor panels comprising a core and a decorative wear resistant solid surface layer comprising fibres, binders and wear resistant particles that have been applied on the core as a powder as described in WO 2009/065769.
  • the field of application comprises products with other types of decorative layers such as paper based, laminated panels (DPL), where a balancing and/or a protecting layer is used.
  • DPL laminated panels
  • the following description of technique, problems of known systems and objects and features of the embodiments of the invention will therefore, as a non-restrictive example, be aimed above all at this field of application and in particular at floorings which are similar to traditional floating wood fibre based laminate floorings.
  • the invention does not exclude floors that are glued down to a sub floor.
  • Embodiments of the invention can also be used in building panels such as for example wall panels, ceilings, and furniture components and similar.
  • Wood fibre based direct pressed laminated flooring usually comprises a core of a 6-12 mm fibre board, a 0.2 mm thick upper decorative surface layer of laminate and a 0.1 -0.2 mm thick lower balancing and/or protective layer of laminate, plastic, paper or like material.
  • the surface layer of a laminate floor is characterized in that the decorative and wear properties are generally obtained with two separate layers one over the other.
  • the decorative layer is generally a printed paper and the wear layer is a transparent overlay paper, which comprises small aluminium oxide particles.
  • the printed decorative paper and the overlay are impregnated with melamine formaldehyde resin and laminated to a wood fibre based core under heat and pressure.
  • the balancing layer is used to keep the panel flat after production and when the panel is exposed to variations in moisture conditions that cause the surface layer to swell and shrink.
  • WFF Wood Fibre Floor
  • the wear resistant particles are preferably aluminium oxide particles, the binders are preferably thermosetting resins such as amino resins and the fibres are preferably wood based.
  • Other suitable wear resistant materials are for example silica or silicon carbide.
  • decorative particles such as for example colour pigments are included in the homogenous mix. In general all these materials are preferably applied in dry form as a mixed powder on a HDF core and cured under heat and pressure to a 0.1 - 1 .0 mm solid layer.
  • the wear resistant surface layer which is a homogenous mix, can be made much thicker and a wear resistance is achieved, which is considerably higher.
  • the homogenous surface layer can comprise particles that have a
  • Powder technology is very suitable to produce solid decorative surface layer, which are much thicker than conventional laminate surface layers.
  • Such solid powder based layers create a much higher tension on the panel when they shrink (or swell) during curing and balancing is a problem. It is therefore difficult to produce a panel with a thick and a high quality surface, which is also well balanced after pressing as well as stable and flat in variable moisture conditions.
  • surface layer is meant all types of surface layers, which give the panel its decorative properties and its wear resistance.
  • WFF mix is meant a mix of materials comprising fibres, binders, wear resistant particles and, optionally, a colour substance, which is preferably applied as powder on a carrier.
  • WFF floor is meant a floor panel comprising a solid surface, which is obtained by a WFF mix that is preferably applied as dry powder on a core, such as for example HDF, and cured under heat and pressure.
  • the new "paper free" WFF floors with a solid surface comprising a WFF mix of fibres, preferably wood fibres, small hard wear resistant particles and a binder are produced according to a production method where the WFF mix is applied in powder form on a core.
  • the wood fibres are generally refined, mechanically worked, and of the same type as used in HDF and particleboard, i.e. treated in a way that the lignin content is essentially unchanged. They comprise natural resins such as lignin.
  • the wear resistant particles are preferably aluminium oxide particles.
  • the surface layer comprises preferably also colour pigments or other decorative materials or chemicals.
  • Processed fibres e.g. bleached wood fibres may also be used.
  • Processed fibres may be semi-transparent, and are preferably transparent in a cured binder.
  • a preferred binder is melamine or urea formaldehyde resin. Any other binder, preferably synthetic thermosetting or thermoplastic resins, may be used.
  • the WFF layer is generally scattered in dry powder form on a wood based core, such as for example HDF.
  • the backside of the core is covered by a balancing layer, which comprises one or several papers impregnated with melamine resin in order to get a balanced product after pressing.
  • the panel is generally produced with a surface that is slightly convex in order to be able to stay flat even in very dry conditions.
  • the total build up with decorative layer, core and balancing or protective layer is transferred into a press, where the decorative layer and the balancing or protective layer are cured, under the influence of heat and pressure.
  • a protective layer is meant a layer adapted to protect the backside of the core.
  • MF melamine formaldehyde
  • Paper based backer materials can create problems as the paper always has a dominating fibre direction either in the production direction or perpendicular to the production direction.
  • the shrinkage during curing is always higher in the transverse direction of the fibres as the fibres can be packed together closer in this direction.
  • the implication of this behaviour is that the balancing layer has different shrinkage in the production direction compared with the transverse direction.
  • the backer is used to balance the decorative layer, which may as an example comprise a powder mix with random fibre direction
  • the consequence is that an optimised balancing only can be obtained in one direction, either along or perpendicular to the production direction. It is also complicated to adapt the thickness of the paper to different thicknesses of the surface layer.
  • the paper based balancing layer offer the advantages that the paper is rather easy to transport together with the core under the scattering units and into a press.
  • the balancing layer can be created with a powder layer that is applied on the backside of the core.
  • This known disclosure does not show how a powder layer on a back side of a core should be handled in order to allow a cost efficient production, especially when discontinuous presses are used which require that the core with its powder based layers can be fed in high speed with clamping devices into a press.
  • An objective of certain embodiments of the invention is to provide a building panel, preferably a floor panel with a decorative surface layer and a balancing and/or protective layer which can be produced in a cost efficient way.
  • a first aspect of the invention is a method of manufacturing a building panel with a decorative surface layer, a core and a balancing and/or protective layer.
  • the method comprises the steps below and preferably performed in the listed sequence:
  • the method offers the advantages that a powder based balancing or protective layer can be applied in a cost efficient way by scattering on a core.
  • the powder may be fixed to the core with a liquid substance that swells, partly dissolves or dissolves the resin, thereby making the powder tacky and stick together.
  • a drying step removes part of the water thus leaving the powder glued not only to itself but also to the core.
  • the attachment makes the first layer stable such that the core with the first layer can be turned and fed under scattering units and into a press.
  • a paper based balancing or protective layer can be replaced in a cost efficient way by a wood fibre based layer with random fibre direction that has similar shrinkage properties as the decorative surface layer.
  • the building panel may be a floor panel.
  • the core may be a HDF or MDF board.
  • the second layer may comprise a veneer layer.
  • the veneer layer forms the decorative surface layer.
  • the second layer may comprise a sheet-shaped layer of wood.
  • a curable lacquer may be applied on top of the veneer layer.
  • the second layer may comprise a first paper sheet.
  • the second layer forming the decorative surface layer is a laminate such as a DPL (direct pressed laminate) or HPL (high pressure laminate).
  • the second layer may further comprise a second paper sheet.
  • the first and/or the second paper sheet may be impregnated with a
  • thermosetting resin such as melamine formaldehyde.
  • the first paper sheet may be arranged such that the fibre direction of the first paper sheet is extending in a first direction
  • the second paper sheet may be arranged such that the fibre direction of the second paper sheet is extending in a second direction, said second direction being transverse to the first direction
  • the second layer may comprise a second powder based mix comprising wood fibres, binders, preferably a thermosetting binder, and wear resistant particles.
  • the second layer can be applied in the same way as the powder based balance or protective layer by scattering on the core.
  • the method may comprise the further step of applying a print or a colour substance into the second mix.
  • a second aspect of the invention is a method of manufacturing a building panel with a decorative surface layer, a core and a balancing and/or protective layer.
  • the method comprises the steps below and is preferably performed in the listed sequence:
  • a first layer of a first powder based mix comprising wood fibres and a thermosetting binder on a carrier, preferably of a thin material with a thickness that does not exceed the thickness of the decorative surface layer;
  • the method offers the advantages that a powder based balancing or protective layer can be applied in a cost efficient way by scattering on a carrier that keeps the powder based balancing or protective layer connected to the core during transport to the device that applies the surface layer and finally when the core is fed into the press.
  • the building panel may be a floor panel.
  • the core may be a HDF or MDF board.
  • the carrier may be a fibre based material.
  • the second layer may comprise a veneer layer.
  • the veneer layer forms the decorative surface layer.
  • a curable lacquer or powder mix layer may be applied on top of the veneer layer.
  • the second layer may comprise a first paper sheet.
  • the second layer forming the decorative layer is a laminate such as a DPL (direct pressed laminate) or HPL (high pressure laminate).
  • the second layer may further comprise a second paper sheet.
  • the first and/or the second paper sheet may be impregnated with a
  • thermosetting resin such as melamine formaldehyde.
  • the first paper sheet may be arranged such that the fibre direction of the first paper sheet is extending in a first direction
  • the second paper sheet may be arranged such that the fibre direction of the second paper sheet is extending in a second direction, said second direction being transverse to the first direction
  • the second layer may comprise a second powder based mix comprising wood fibres, binders, preferably a thermosetting binder, and wear resistant particles.
  • the second layer can be applied in the same way as the powder based balance or protective layer by scattering on a core.
  • the method may comprise the further step of applying a print or a colour substance into the second mix.
  • a third aspect of the invention is a method of manufacturing a separate and continuous powder based balancing and/or protective layer, which is essentially uncured.
  • the method comprises the steps below and is preferably performed in the listed sequence:
  • the separate and continuous powder based balancing or protective layer may be used in a method for producing a building panel which method comprises the steps below and is preferably performed in the listed sequence:
  • the method offers the advantages that a powder based balancing or protective layer can be produced as a separate uncured layer that can be handled as a conventional paper based balancing or protective layer.
  • the moisture that preferably comprises water, may be sprayed on the powder such that the binder, preferably a melamine resin, moisture swells, partly dissolves or dissolve the resin, thereby making the powder tacky and stick together.
  • the fibres in the mix will be connected to each other when the water dries.
  • the fibres may also be connected by applying heat, e.g., IR heating, thereby removing the moisture and connecting the fibres in the mix.
  • a powder based uncured balancing or protective layer may be formed as a flexible thin sheet and a core material may be placed over the balancing or protective layer.
  • the surface layer may comprise a powder based surface layer, at least one paper sheet or a veneer layer.
  • a fourth aspect of the invention is a separate and continuous powder based balancing and/or protective layer, which is essentially uncured.
  • the separate layer comprises powder mix comprising connected fibres and an essentially uncured thermosetting binder.
  • the powder based balancing or protective layer is preferably produced according to the method of the third aspect.
  • a fifth aspect of the invention is a building panel, comprising a core, preferably a wood-based core such as MDF or HDF board, a decorative surface layer arranged on a first surface of said core, the decorative surface layer comprising at least one paper layer, and a balancing layer arranged on a second surface of said core, said second surface being opposite to said first surface, wherein the balancing layer is formed of a powder based mix comprising wood fibres and a thermosetting binder.
  • the building panel is preferably produced according to the first or second aspect of the invention.
  • Figs 1 a-e illustrate a method to form a balancing and/or protective layer.
  • Figs 2a-e Illustrate a method to form a balancing and/or protective layer.
  • Fig 3 illustrates a building panel wherein the decorative layer is laminate.
  • Fig 4 illustrates a building panel wherein the decorative layer is a veneer layer.
  • the powder intended to be used as a balancing and/or protective layer 3 is applied as a first powder mix on a core 2, preferably a MDF or HDF material, preferably by one or several scattering units 1 1 as shown in figure 1 a.
  • Figure 1 b shows that the powder is thereafter pre-stabilized by a fluid 7, preferable based on water, which is applied by a stabilizing device 9.
  • the first powder layer is thereafter dried. Such drying can be performed off-line in a controlled environment or in-line by applying heat 8 with a heating device 10 on the powder mix 3.
  • the heating device 10 may comprise infrared light.
  • Oversized or undersized fibres from the hammer mill that produces the fibres for the surface layer may be used in the balancing or protective layer mix.
  • the fibre size is not as critical as in a powder based surface layer and may vary from a fibre length of several mm to less than 0.1 mm. The most preferred average fibre length is 0, 1 -1 ,0 mm.
  • a second powder based surface layer mix 1 is thereafter applied on the upper side of the core 2 as showed in fig. 1 d.
  • a digital print 4 may be printed into the surface layer 1 .
  • the surface layer 1 preferably also comprises wood fibres, a colour substance, thermosetting binders and aluminium oxide particles.
  • the wood fibres in both the first and second powder mixes in all embodiments of the invention may be virgin, unrefined, refined and/or processed, comprising lignin and without lignin, e.g. a-cellulose fibres or holocellulose.
  • a mixture of refined and unrefined fibres may also be used.
  • vegetable fibres as jute, linen, flax, cotton, hemp, bamboo, bagasse and sisal may be used.
  • mineral fibres and carbon fibres may be used.
  • the second layer forming the decorative surface layer may comprise at least one paper sheet 21 adapted to form a laminate, which is shown in fig. 3.
  • Said at least one paper sheet 21 may be arranged on the upper side of the core.
  • the second layer comprises a first paper sheet 21 and a second paper sheet 22.
  • the first and second paper sheets 21 , 22 may be arranged such that the fibre direction of the first paper sheet 21 is extending in a first direction, and the fibre direction of the second paper sheet 22 is extending in a second direction being opposite to the first direction.
  • the second layer has fibre directions in more than one direction. Thereby, during shrinkage, the second layer obtains properties more similar to the balancing or protective layer having a random fibre direction compared to a surface layer having only one dominating fibre direction.
  • the first paper sheet 21 may be a printed paper.
  • the second paper sheet 22 may be a transparent overlay paper.
  • the second paper sheet 22 may form a wear layer and may comprise small aluminium oxide particles.
  • the first and second paper sheets 21 , 22 may be impregnated with melamine resin such that they can be laminated to the core under heat and pressure simultaneously as curing the balancing and/or protective layer.
  • the second paper sheet 22 may be arranged on top of the first paper sheet 21 .
  • the second layer may comprise a veneer layer 23 or sheet-shaped layer of wood arranged on the upper side of the core, which is shown in fig. 4.
  • the second layer may further comprise a curable lacquer layer applied on top of the veneer layer or sheet-shaped layer of wood.
  • the curable lacquer layer may be cured simultaneously as curing the balancing and/or protective layer.
  • decor layers may also be used as a second layer, such as cork, rubber, plastics, especially a thermoplastic decor layer.
  • the core 2 with the surface layer 1 and the balancing or protective layer 3 is thereafter fed into a press where the layers are cured under heat and pressure.
  • the balancing layer may be optimized in thickness and material composition in order to create a perfect balancing of the surface layer.
  • the fibre orientation in the layers may be essentially the same.
  • Recycled fibres from the machining of the panels may be used in the balancing or protective layer mix.
  • the balancing or protective layer 3 may preferably comprise a homogenous powder mixture comprising about 50 weight % recycled MDF fibres with a moisture content of preferably 3-8 % and about 50 weight % Melamine
  • Formaldehyde (MF) resin (Prefere 4865, Dynea).
  • the MF resin amount can vary between 30-70 w-%, preferably 40-65 w-% and most preferably 45-60 w-%.
  • the fibre content may vary from 30 - 70%, most preferably between 40-55%.
  • thermosetting particles pigments, hard particles, release agents, wetting agents and similar materials are included into the mix.
  • the thermosetting plastic particles may be mixed at random into the powder or applied as a separate thin layer and may be used to provide a sealing against moisture penetration into the core.
  • the core of an HDF board preferably has a moisture content of 0-8 %.
  • the scattering unit 1 1 may have capacity of scattering of 100-1000 g/m 2 with a tolerance of +/- 5% as measured using a calibration cup with an area of 100x100 mm cross- and length wise the board.
  • the amount of stabilization fluid may vary between 0 up to 200 g/m 2 .
  • the scattering unit 1 1 may comprise a needle belt and a scattering roller 12.
  • the scattering roller is provided with needles in the range of about 30-120, preferably about 50-100, and most preferably about 70-90 needles per cm 2 .
  • the needle length is about 0.5-2.5 mm, preferably about 1 -2 mm and most preferably about 1 .5 mm.
  • the scattering unit may be provided with a needle belt with needles with a preferred length of about 15-20 mm, a preferred frequency in the range of about 500-1000 rpm preferably about 1000 rpm, and a stroke length of about +/- 3 mm.
  • the stabilizing device 9 and the heating device 8 may be used to stabilize the surface layer 1 and/or the balancing or protective layer 3.
  • the stabilization device 9 may stabilize the powder using steam, nozzle spray coating or ultra sonic spray coating.
  • Stabilization fluid may comprise solvents such as non-polar solvents, polar aprotic solvents and polar protic solvents or mixtures thereof.
  • Preferred solvents are polar protic solvents such as isopropanol, ethanol and water. Most preferred is water.
  • the stabilization fluid can further comprise additives such as wetting agents, defoamers, release agents, anti-slip agents and catalysts.
  • Figures 2a-2e show how a powder based balancing or protective layer can be applied by applying the powder based balancing or protective layer as a first mix 3 on a carrier 5. The core is applied on the mix (fig 2c) and a powder based surface layer 1 is applied on the core 2.
  • a surface layer of at least one paper sheet 21 or veneer layer 23 is applied to the core for forming a decorative surface layer, as described above with reference to figs. 3 and 4.
  • Stabilizing and/or heating of the balancing and/or surface layers may be made as described above.
  • the core and layers are fed into a press and cured under heat and pressure to a building panel as shown in figure 2e.
  • the carrier may be a paper with a weight of for example 100 - 200 gr. It may also be a non woven fibre based material or a foil.
  • Powder may also be applied on a carrier that preferably is a conveyor belt 1 1 and stabilized with fluid and dried such that it can be released from the conveyor 1 1 and handled as a separate sheet without the carrier 5 as shown in figure 2b.
  • a carrier that preferably is a conveyor belt 1 1 and stabilized with fluid and dried such that it can be released from the conveyor 1 1 and handled as a separate sheet without the carrier 5 as shown in figure 2b.
  • Such a separate and continuous sheet or layer is essentially uncured.
  • the sheet or layer may be flexible such that it may be bent.
  • the powder may comprise fibres, preferably wood fibres, and a thermosetting binder.
  • example 1 the powder formulation for the balancing layer used comprising 50 weight-% recycled MDF fibre (Valinge Innovation Sweden), 50 weight-% Melamine Formaldehyde resin (Prefere 4865, Dynea).
  • Example 1 Powder based product obtained through heat compression of product produced with powder based balancing layer and a treated powder as decorative layer.
  • a balancing layer was formed by scattering 500 g/m 2 of powder on a 9.7 mm HDF core.
  • 40 g/m 2 of stabilisation fluid with 5 w-% wetting agent, 6 w-% release agent and 3 w-% catalyst was applied by spraying on the powder based balancing layer mix
  • the powder and the stabilisation fluid were applied at a line speed of 2.7 m/min.
  • the powder based balancing layer was dried at the same line speed with IR with an effect of 19 kW.
  • the resulting intermediate product with a stabilized powder based balancing layer was turned 180° and stacked on a pallet before use in the next operation where a decorative surface layer of 500 gr/m 2 was applied in powder form on the core.
  • the core with the surface and balancing layers was pressed in a press with a pressure of 40 kg/cm 2 , during 25 seconds.
  • the upper press table applied a heat of 170 degrees C on the surface layer and the lower press table applied a heat of 175 degrees C on balancing layer.
  • Example 2 Powder based product obtained through heat compression of product produced with powder based balancing layer and a treated powder as decorative layer.
  • a balancing layer was formed by scattering 320 g/m 2 of powder on a 9.7 mm HDF core.
  • the powder and the stabilisation fluid were applied at a line speed of 2.0 m/min.
  • the powder based balancing layer was dried at the same line speed with IR with an effect of 19 kW.
  • the resulting intermediate product with a stabilized powder based balancing layer was turned 180° and feed into the next operation where a decorative surface layer of 550 gr/m 2 was applied in powder form on the core.
  • the core with the surface and balancing layers was pressed in a press with a pressure of 40 kg/cm 2 , during 37 seconds.
  • the upper press table applied a heat of 184°C on the surface layer and the lower press table applied a heat of 175°C on balancing layer.
  • a panel with a small pre tension backwards and a slightly convex surface was obtained.
  • the balancing layer may be provided with an orientation in some embodiments.
  • the wood fibres based the balancing layer generally has a random fibre direction.
  • an orientation may be formed in the balancing layer. Such orientation may be provided with by means of scattering the powder in a specific pattern, by a pattern in the press plate, or by means of a rake forming a pattern.
  • the steps of the method claims do not necessarily have to be performed in the above described order. It is for example contemplated that the second layer may be applied before the first layer, and that the core is turned after the second layer has been applied. Thereafter the first layer is applied, liquid is applied, the first powder based mix is dried and the core is turned with the dried first powder based mix such that the first powder based mix points downwards.

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Abstract

A method to produce a building panel comprising a decorative surface layer, a core and a balancing and/or protective layer is disclosed.

Description

POWDER BASED BALANCING LAYER
Technical field
The disclosure generally relates to the field of panels with a decorative surface layer and a balancing and/or protective layer, preferably floor and wall panels. The disclosure relates to production methods to produce such panels.
Field of Application
Embodiments of the present invention are particularly suitable for use in production of floating floors, which are formed of floor panels comprising a core and a decorative wear resistant solid surface layer comprising fibres, binders and wear resistant particles that have been applied on the core as a powder as described in WO 2009/065769. The field of application comprises products with other types of decorative layers such as paper based, laminated panels (DPL), where a balancing and/or a protecting layer is used. The following description of technique, problems of known systems and objects and features of the embodiments of the invention will therefore, as a non-restrictive example, be aimed above all at this field of application and in particular at floorings which are similar to traditional floating wood fibre based laminate floorings. The invention does not exclude floors that are glued down to a sub floor. Embodiments of the invention can also be used in building panels such as for example wall panels, ceilings, and furniture components and similar.
Background
Wood fibre based direct pressed laminated flooring (DPL) usually comprises a core of a 6-12 mm fibre board, a 0.2 mm thick upper decorative surface layer of laminate and a 0.1 -0.2 mm thick lower balancing and/or protective layer of laminate, plastic, paper or like material.
The surface layer of a laminate floor is characterized in that the decorative and wear properties are generally obtained with two separate layers one over the other. The decorative layer is generally a printed paper and the wear layer is a transparent overlay paper, which comprises small aluminium oxide particles. The printed decorative paper and the overlay are impregnated with melamine formaldehyde resin and laminated to a wood fibre based core under heat and pressure. The balancing layer is used to keep the panel flat after production and when the panel is exposed to variations in moisture conditions that cause the surface layer to swell and shrink.
Recently new "paper free" Wood Fibre Floor (WFF) types have been developed with solid surfaces comprising a substantially homogenous mix of fibres, binders and wear resistant particles.
The wear resistant particles are preferably aluminium oxide particles, the binders are preferably thermosetting resins such as amino resins and the fibres are preferably wood based. Other suitable wear resistant materials are for example silica or silicon carbide. In most applications decorative particles such as for example colour pigments are included in the homogenous mix. In general all these materials are preferably applied in dry form as a mixed powder on a HDF core and cured under heat and pressure to a 0.1 - 1 .0 mm solid layer.
Several advantages over known technology and especially over conventional laminate floorings can be obtained:
• The wear resistant surface layer, which is a homogenous mix, can be made much thicker and a wear resistance is achieved, which is considerably higher.
• New and very advanced decorative effects can be obtained with deep embossing and by separate decorative materials, which can be
incorporated into the homogenous surface layer and coordinated with the embossing.
• An increased impact resistance can be reached with a homogenous
surface layer, which is thicker and has a higher density. · The homogenous surface layer can comprise particles that have a
positive impact on sound and moisture properties.
• Production costs can be reduced since low cost and even recycled
materials can be used and several production steps can be eliminated.
Powder technology is very suitable to produce solid decorative surface layer, which are much thicker than conventional laminate surface layers. Such solid powder based layers create a much higher tension on the panel when they shrink (or swell) during curing and balancing is a problem. It is therefore difficult to produce a panel with a thick and a high quality surface, which is also well balanced after pressing as well as stable and flat in variable moisture conditions.
Definition of Some Terms
By "surface layer" is meant all types of surface layers, which give the panel its decorative properties and its wear resistance. By a "WFF mix" is meant a mix of materials comprising fibres, binders, wear resistant particles and, optionally, a colour substance, which is preferably applied as powder on a carrier.
By "WFF floor" is meant a floor panel comprising a solid surface, which is obtained by a WFF mix that is preferably applied as dry powder on a core, such as for example HDF, and cured under heat and pressure.
Known Technique and Problems thereof
The new "paper free" WFF floors with a solid surface comprising a WFF mix of fibres, preferably wood fibres, small hard wear resistant particles and a binder are produced according to a production method where the WFF mix is applied in powder form on a core. The wood fibres are generally refined, mechanically worked, and of the same type as used in HDF and particleboard, i.e. treated in a way that the lignin content is essentially unchanged. They comprise natural resins such as lignin. The wear resistant particles are preferably aluminium oxide particles. The surface layer comprises preferably also colour pigments or other decorative materials or chemicals. Processed fibres e.g. bleached wood fibres may also be used. Processed fibres may be semi-transparent, and are preferably transparent in a cured binder.
A preferred binder is melamine or urea formaldehyde resin. Any other binder, preferably synthetic thermosetting or thermoplastic resins, may be used. The WFF layer is generally scattered in dry powder form on a wood based core, such as for example HDF.
The backside of the core is covered by a balancing layer, which comprises one or several papers impregnated with melamine resin in order to get a balanced product after pressing. The panel is generally produced with a surface that is slightly convex in order to be able to stay flat even in very dry conditions. The total build up with decorative layer, core and balancing or protective layer is transferred into a press, where the decorative layer and the balancing or protective layer are cured, under the influence of heat and pressure.
By a protective layer is meant a layer adapted to protect the backside of the core.
The curing of a melamine formaldehyde (MF) resin involves shrinkage of the MF resin matrix and the balancing layer is needed to balance the shrinkage forces from the decorative layer.
Paper based backer materials can create problems as the paper always has a dominating fibre direction either in the production direction or perpendicular to the production direction. The shrinkage during curing is always higher in the transverse direction of the fibres as the fibres can be packed together closer in this direction. The implication of this behaviour is that the balancing layer has different shrinkage in the production direction compared with the transverse direction.
As the backer is used to balance the decorative layer, which may as an example comprise a powder mix with random fibre direction, the consequence is that an optimised balancing only can be obtained in one direction, either along or perpendicular to the production direction. It is also complicated to adapt the thickness of the paper to different thicknesses of the surface layer.
However, the paper based balancing layer offer the advantages that the paper is rather easy to transport together with the core under the scattering units and into a press.
It is known from WO 2009/065769 that the balancing layer can be created with a powder layer that is applied on the backside of the core. This known disclosure does not show how a powder layer on a back side of a core should be handled in order to allow a cost efficient production, especially when discontinuous presses are used which require that the core with its powder based layers can be fed in high speed with clamping devices into a press. The above description of various known aspects is the applicants'
characterization of such, and is not an admission that any of the description is prior art.
Objects and Summary
An objective of certain embodiments of the invention is to provide a building panel, preferably a floor panel with a decorative surface layer and a balancing and/or protective layer which can be produced in a cost efficient way.
A first aspect of the invention is a method of manufacturing a building panel with a decorative surface layer, a core and a balancing and/or protective layer. The method comprises the steps below and preferably performed in the listed sequence:
• applying a first layer of a first powder based mix, comprising wood fibres and a thermosetting binder on a core; · applying a liquid substance on the first powder based mix;
• drying the first powder based mix;
• turning the core with the dried first powder based mix such that the first powder based mix points downwards;
• applying a second layer on the upper part of the core; and · curing the first and second layers simultaneously by providing heat and pressure, wherein the first layer forms the balancing and/or protective layer and the second layer forms the decorative surface layer in the building panel.
The method offers the advantages that a powder based balancing or protective layer can be applied in a cost efficient way by scattering on a core. The powder may be fixed to the core with a liquid substance that swells, partly dissolves or dissolves the resin, thereby making the powder tacky and stick together. A drying step removes part of the water thus leaving the powder glued not only to itself but also to the core. The attachment makes the first layer stable such that the core with the first layer can be turned and fed under scattering units and into a press. A paper based balancing or protective layer can be replaced in a cost efficient way by a wood fibre based layer with random fibre direction that has similar shrinkage properties as the decorative surface layer.
The building panel may be a floor panel.
The core may be a HDF or MDF board.
The second layer may comprise a veneer layer. Thereby, the veneer layer forms the decorative surface layer. The second layer may comprise a sheet-shaped layer of wood. A curable lacquer may be applied on top of the veneer layer.
The second layer may comprise a first paper sheet. In this embodiment, the second layer forming the decorative surface layer is a laminate such as a DPL (direct pressed laminate) or HPL (high pressure laminate).
The second layer may further comprise a second paper sheet.
The first and/or the second paper sheet may be impregnated with a
thermosetting resin such as melamine formaldehyde.
The first paper sheet may be arranged such that the fibre direction of the first paper sheet is extending in a first direction, and the second paper sheet may be arranged such that the fibre direction of the second paper sheet is extending in a second direction, said second direction being transverse to the first direction.
The second layer may comprise a second powder based mix comprising wood fibres, binders, preferably a thermosetting binder, and wear resistant particles. Thereby, the second layer can be applied in the same way as the powder based balance or protective layer by scattering on the core.
The method may comprise the further step of applying a print or a colour substance into the second mix.
A second aspect of the invention is a method of manufacturing a building panel with a decorative surface layer, a core and a balancing and/or protective layer. The method comprises the steps below and is preferably performed in the listed sequence:
• applying a first layer of a first powder based mix, comprising wood fibres and a thermosetting binder on a carrier, preferably of a thin material with a thickness that does not exceed the thickness of the decorative surface layer;
• placing the core material on the first powder based mix;
• applying a second layer on the upper part of the core; and · curing the first and second layers by providing heat and pressure wherein the first layer forms the balancing and/or protective layer and the second layer forms the decorative surface layer of the building panel.
The method offers the advantages that a powder based balancing or protective layer can be applied in a cost efficient way by scattering on a carrier that keeps the powder based balancing or protective layer connected to the core during transport to the device that applies the surface layer and finally when the core is fed into the press.
The building panel may be a floor panel.
The core may be a HDF or MDF board.
The carrier may be a fibre based material.
The second layer may comprise a veneer layer. Thereby, the veneer layer forms the decorative surface layer. A curable lacquer or powder mix layer may be applied on top of the veneer layer.
The second layer may comprise a first paper sheet. In this embodiment, the second layer forming the decorative layer is a laminate such as a DPL (direct pressed laminate) or HPL (high pressure laminate).
The second layer may further comprise a second paper sheet.
The first and/or the second paper sheet may be impregnated with a
thermosetting resin such as melamine formaldehyde.
The first paper sheet may be arranged such that the fibre direction of the first paper sheet is extending in a first direction, and the second paper sheet may be arranged such that the fibre direction of the second paper sheet is extending in a second direction, said second direction being transverse to the first direction.
The second layer may comprise a second powder based mix comprising wood fibres, binders, preferably a thermosetting binder, and wear resistant particles. Thereby, the second layer can be applied in the same way as the powder based balance or protective layer by scattering on a core.
The method may comprise the further step of applying a print or a colour substance into the second mix.
A third aspect of the invention is a method of manufacturing a separate and continuous powder based balancing and/or protective layer, which is essentially uncured. The method comprises the steps below and is preferably performed in the listed sequence:
• applying a powder mix comprising fibres and a thermosetting binder on a carrier;
• applying moisture on the powder mix such that the powder mix is
connected together to an essential uncured balancing and/or protective layer; and
• releasing the uncured balancing and/or protective layer from the carrier. The separate and continuous powder based balancing or protective layer may be used in a method for producing a building panel which method comprises the steps below and is preferably performed in the listed sequence:
• placing the uncured balancing and/or protective layer under a core
material; · applying a surface layer on the core material; and
• curing the surface layer and the uncured balancing and/or protective layer under heat and pressure.
The method offers the advantages that a powder based balancing or protective layer can be produced as a separate uncured layer that can be handled as a conventional paper based balancing or protective layer. The moisture, that preferably comprises water, may be sprayed on the powder such that the binder, preferably a melamine resin, moisture swells, partly dissolves or dissolve the resin, thereby making the powder tacky and stick together. The fibres in the mix will be connected to each other when the water dries. The fibres may also be connected by applying heat, e.g., IR heating, thereby removing the moisture and connecting the fibres in the mix. A powder based uncured balancing or protective layer may be formed as a flexible thin sheet and a core material may be placed over the balancing or protective layer.
The surface layer may comprise a powder based surface layer, at least one paper sheet or a veneer layer.
A fourth aspect of the invention is a separate and continuous powder based balancing and/or protective layer, which is essentially uncured. The separate layer comprises powder mix comprising connected fibres and an essentially uncured thermosetting binder.
The powder based balancing or protective layer is preferably produced according to the method of the third aspect.
A fifth aspect of the invention is a building panel, comprising a core, preferably a wood-based core such as MDF or HDF board, a decorative surface layer arranged on a first surface of said core, the decorative surface layer comprising at least one paper layer, and a balancing layer arranged on a second surface of said core, said second surface being opposite to said first surface, wherein the balancing layer is formed of a powder based mix comprising wood fibres and a thermosetting binder.
The building panel is preferably produced according to the first or second aspect of the invention.
Brief Description of the Drawings
The invention will in the following be described in connection to preferred embodiments and in greater detail with reference to the appended exemplary drawings, wherein,
Figs 1 a-e illustrate a method to form a balancing and/or protective layer.
Figs 2a-e Illustrate a method to form a balancing and/or protective layer.
Fig 3 illustrates a building panel wherein the decorative layer is laminate.
Fig 4 illustrates a building panel wherein the decorative layer is a veneer layer. Detailed Description of Embodiments
The powder intended to be used as a balancing and/or protective layer 3 is applied as a first powder mix on a core 2, preferably a MDF or HDF material, preferably by one or several scattering units 1 1 as shown in figure 1 a. Figure 1 b shows that the powder is thereafter pre-stabilized by a fluid 7, preferable based on water, which is applied by a stabilizing device 9. The first powder layer is thereafter dried. Such drying can be performed off-line in a controlled environment or in-line by applying heat 8 with a heating device 10 on the powder mix 3. The heating device 10 may comprise infrared light.
The water based fluid 7 and the following drying 8, attaches the powder layer 3 to the core 2, to such an extent that the core 2 with the powder can be turned 180° to bring the powder based balancing or protective layer 3 downwards, as shown in figure 1 c, such that it may be transported further along the production line or be stacked on a pallet for intermediate storage before further production takes place.
Oversized or undersized fibres from the hammer mill that produces the fibres for the surface layer may be used in the balancing or protective layer mix. The fibre size is not as critical as in a powder based surface layer and may vary from a fibre length of several mm to less than 0.1 mm. The most preferred average fibre length is 0, 1 -1 ,0 mm.
A second powder based surface layer mix 1 is thereafter applied on the upper side of the core 2 as showed in fig. 1 d. A digital print 4 may be printed into the surface layer 1 . The surface layer 1 preferably also comprises wood fibres, a colour substance, thermosetting binders and aluminium oxide particles.
The wood fibres in both the first and second powder mixes in all embodiments of the invention may be virgin, unrefined, refined and/or processed, comprising lignin and without lignin, e.g. a-cellulose fibres or holocellulose. A mixture of refined and unrefined fibres may also be used. It is also contemplated that vegetable fibres as jute, linen, flax, cotton, hemp, bamboo, bagasse and sisal may be used. Also mineral fibres and carbon fibres may be used.
As an alternative to the second powder based surface layer mix, the second layer forming the decorative surface layer may comprise at least one paper sheet 21 adapted to form a laminate, which is shown in fig. 3. Said at least one paper sheet 21 may be arranged on the upper side of the core. Preferably, the second layer comprises a first paper sheet 21 and a second paper sheet 22. The first and second paper sheets 21 , 22 may be arranged such that the fibre direction of the first paper sheet 21 is extending in a first direction, and the fibre direction of the second paper sheet 22 is extending in a second direction being opposite to the first direction. By arranging the fibre direction of the sheets transversely, the second layer has fibre directions in more than one direction. Thereby, during shrinkage, the second layer obtains properties more similar to the balancing or protective layer having a random fibre direction compared to a surface layer having only one dominating fibre direction.
The first paper sheet 21 may be a printed paper. The second paper sheet 22 may be a transparent overlay paper. The second paper sheet 22 may form a wear layer and may comprise small aluminium oxide particles. The first and second paper sheets 21 , 22 may be impregnated with melamine resin such that they can be laminated to the core under heat and pressure simultaneously as curing the balancing and/or protective layer. The second paper sheet 22 may be arranged on top of the first paper sheet 21 .
Alternatively, the second layer may comprise a veneer layer 23 or sheet-shaped layer of wood arranged on the upper side of the core, which is shown in fig. 4. The second layer may further comprise a curable lacquer layer applied on top of the veneer layer or sheet-shaped layer of wood. The curable lacquer layer may be cured simultaneously as curing the balancing and/or protective layer.
Other decor layers may also be used as a second layer, such as cork, rubber, plastics, especially a thermoplastic decor layer.
The core 2 with the surface layer 1 and the balancing or protective layer 3 is thereafter fed into a press where the layers are cured under heat and pressure. The balancing layer may be optimized in thickness and material composition in order to create a perfect balancing of the surface layer. The fibre orientation in the layers may be essentially the same.
Recycled fibres from the machining of the panels, for example when a mechanical locking system is formed, may be used in the balancing or protective layer mix.
The balancing or protective layer 3 may preferably comprise a homogenous powder mixture comprising about 50 weight % recycled MDF fibres with a moisture content of preferably 3-8 % and about 50 weight % Melamine
Formaldehyde (MF) resin (Prefere 4865, Dynea). The MF resin amount can vary between 30-70 w-%, preferably 40-65 w-% and most preferably 45-60 w-%. The fibre content may vary from 30 - 70%, most preferably between 40-55%.
If needed the powder formulation can be modified such that thermosetting particles, pigments, hard particles, release agents, wetting agents and similar materials are included into the mix. The thermosetting plastic particles may be mixed at random into the powder or applied as a separate thin layer and may be used to provide a sealing against moisture penetration into the core.
The core of an HDF board preferably has a moisture content of 0-8 %.
The scattering unit 1 1 may have capacity of scattering of 100-1000 g/m2 with a tolerance of +/- 5% as measured using a calibration cup with an area of 100x100 mm cross- and length wise the board. The amount of stabilization fluid may vary between 0 up to 200 g/m2.
The scattering unit 1 1 may comprise a needle belt and a scattering roller 12. The scattering roller is provided with needles in the range of about 30-120, preferably about 50-100, and most preferably about 70-90 needles per cm2. The needle length is about 0.5-2.5 mm, preferably about 1 -2 mm and most preferably about 1 .5 mm. Several scattering units 1 1 may be used to even out differences in the applied powder mixture.
Furthermore, the scattering unit may be provided with a needle belt with needles with a preferred length of about 15-20 mm, a preferred frequency in the range of about 500-1000 rpm preferably about 1000 rpm, and a stroke length of about +/- 3 mm.
The stabilizing device 9 and the heating device 8 may be used to stabilize the surface layer 1 and/or the balancing or protective layer 3.
The stabilization device 9 may stabilize the powder using steam, nozzle spray coating or ultra sonic spray coating.
Stabilization fluid may comprise solvents such as non-polar solvents, polar aprotic solvents and polar protic solvents or mixtures thereof. Preferred solvents are polar protic solvents such as isopropanol, ethanol and water. Most preferred is water. The stabilization fluid can further comprise additives such as wetting agents, defoamers, release agents, anti-slip agents and catalysts. Figures 2a-2e show how a powder based balancing or protective layer can be applied by applying the powder based balancing or protective layer as a first mix 3 on a carrier 5. The core is applied on the mix (fig 2c) and a powder based surface layer 1 is applied on the core 2. Alternatively, a surface layer of at least one paper sheet 21 or veneer layer 23 is applied to the core for forming a decorative surface layer, as described above with reference to figs. 3 and 4. Stabilizing and/or heating of the balancing and/or surface layers may be made as described above. The core and layers are fed into a press and cured under heat and pressure to a building panel as shown in figure 2e. The carrier may be a paper with a weight of for example 100 - 200 gr. It may also be a non woven fibre based material or a foil.
Powder may also be applied on a carrier that preferably is a conveyor belt 1 1 and stabilized with fluid and dried such that it can be released from the conveyor 1 1 and handled as a separate sheet without the carrier 5 as shown in figure 2b. Such a separate and continuous sheet or layer is essentially uncured. The sheet or layer may be flexible such that it may be bent. The powder may comprise fibres, preferably wood fibres, and a thermosetting binder.
EXAMPLE
In example 1 below the powder formulation for the balancing layer used comprising 50 weight-% recycled MDF fibre (Valinge Innovation Sweden), 50 weight-% Melamine Formaldehyde resin (Prefere 4865, Dynea).
Example 1 : Powder based product obtained through heat compression of product produced with powder based balancing layer and a treated powder as decorative layer. A balancing layer was formed by scattering 500 g/m2 of powder on a 9.7 mm HDF core.
40 g/m2 of stabilisation fluid with 5 w-% wetting agent, 6 w-% release agent and 3 w-% catalyst was applied by spraying on the powder based balancing layer mix The powder and the stabilisation fluid were applied at a line speed of 2.7 m/min. The powder based balancing layer was dried at the same line speed with IR with an effect of 19 kW. The resulting intermediate product with a stabilized powder based balancing layer was turned 180° and stacked on a pallet before use in the next operation where a decorative surface layer of 500 gr/m2 was applied in powder form on the core. The core with the surface and balancing layers was pressed in a press with a pressure of 40 kg/cm2, during 25 seconds. The upper press table applied a heat of 170 degrees C on the surface layer and the lower press table applied a heat of 175 degrees C on balancing layer.
A panel with a small pre tension backwards and a slightly convex surface was obtained.
In example 2 below the powder formulation for the balancing layer used comprising 42 weight-% recycled MDF fibre (Valinge Innovation Sweden), 58 weight-% Melamine Formaldehyde resin (Prefere 4865, Dynea).
Example 2: Powder based product obtained through heat compression of product produced with powder based balancing layer and a treated powder as decorative layer.
A balancing layer was formed by scattering 320 g/m2 of powder on a 9.7 mm HDF core.
40 g/m2 of stabilisation fluid with 1 wt-% wetting agent, 6 wt-% rerelease agent and 1 wt-% catalyst was applied by spraying on the powder based balancing layer mix
The powder and the stabilisation fluid were applied at a line speed of 2.0 m/min. The powder based balancing layer was dried at the same line speed with IR with an effect of 19 kW. The resulting intermediate product with a stabilized powder based balancing layer was turned 180° and feed into the next operation where a decorative surface layer of 550 gr/m2 was applied in powder form on the core.
The core with the surface and balancing layers was pressed in a press with a pressure of 40 kg/cm2, during 37 seconds. The upper press table applied a heat of 184°C on the surface layer and the lower press table applied a heat of 175°C on balancing layer. A panel with a small pre tension backwards and a slightly convex surface was obtained.
It is contemplated that there are numerous modifications of the embodiments described herein, which are still within the scope of the invention as defined by the appended claims.
For example, it is contemplated that the balancing layer may be provided with an orientation in some embodiments. The wood fibres based the balancing layer generally has a random fibre direction. However, in order to form a balancing layer having similar properties as the decorative surface layer, an orientation may be formed in the balancing layer. Such orientation may be provided with by means of scattering the powder in a specific pattern, by a pattern in the press plate, or by means of a rake forming a pattern.
The steps of the method claims do not necessarily have to be performed in the above described order. It is for example contemplated that the second layer may be applied before the first layer, and that the core is turned after the second layer has been applied. Thereafter the first layer is applied, liquid is applied, the first powder based mix is dried and the core is turned with the dried first powder based mix such that the first powder based mix points downwards.

Claims

1 . A method of manufacturing a building panel (6) with a decorative surface layer (1 ), a core (2) and a balancing and/or protective layer (3), wherein the method comprises the steps:
• applying a first layer (3) of a first powder based mix (3), comprising wood fibres and a thermosetting binder on a core (6);
• applying a liquid substance on the first powder based mix;
• drying the first powder based mix; · turning the core (2) with the dried first powder based mix such that the first powder based mix points downwards;
• applying a second layer (1 ) on the upper part of the core (2); and
• curing the first (3) and second (1 ) layers by providing heat and pressure, wherein the first layer forms the balancing and/or protective layer (3) and the second layer (1 ) forms the decorative surface layer in the building panel (6).
2. The method as claimed in claim 1 , wherein the building panel is a floor panel.
3. The method as claimed in claim 1 or 2, wherein the core is a HDF or MDF board.
4. The method as claimed in any one of claims 1 -3, wherein the step of applying said second layer (1 ) comprises applying a veneer layer.
5. The method as claimed in any one of claims 1 -3, wherein the step of applying said second layer (1 ) comprises applying a first paper sheet.
6. The method as claimed in claim 5, wherein the step of applying said second layer (1 ) further comprising applying a second paper sheet.
7. The method as claimed in claim 6, wherein the step of applying said first and second paper sheets comprises arranging said first paper sheet such that the fibre direction of the first paper sheet is extending in a first direction, and arranging said second paper sheet such that the fibre direction of the second paper sheet is extending in a second direction, said second direction being transverse to the first direction.
8. The method as claimed in any one of claims 1 -3, wherein the step of applying the second layer (1 ) comprises applying a second powder based mix (1 ) comprising wood fibres, binders, preferably a thermosetting binder, and wear resistant particles.
9. The method as claimed in claim 8, wherein the method comprises the further step of applying a print (4) or a colour substance into the second mix (1 ).
10. A method of manufacturing a building panel (6) with a decorative surface layer (1 ), a core (2) and a balancing and/or protective layer (3), wherein the method comprises the steps of:
• applying a first layer (3) of a first powder based mix (3), comprising wood fibres and a thermosetting binder on a carrier (5), which preferably is of a thin material with a thickness that does not exceed the thickness of the decorative surface layer (1 );
• placing the core (2) on the first powder based mix (3);
• applying a second layer (1 ) on the upper part of the core; and
• curing the first (3) and second (1 ) layers by providing heat and pressure, wherein the first layer forms the balancing and/or protective layer (3) and the second layer forms the decorative surface layer (1 ) of the building panel (6).
1 1 . The method as claimed in claim 10, wherein the building panel is a floor panel.
12. The method as claimed in claim 10 or 1 1 , wherein the core is a HDF or MDF board.
13. The method as claimed in any one of the preceding claims 10-12, wherein the carrier is a fibre based material.
14. The method as claimed in any one of claims 10-13, wherein the step of applying said second layer (1 ) comprises applying a veneer layer.
15. The method as claimed in any one of claims 10-13, wherein the step of applying said second layer (1 ) comprises applying a first paper sheet.
16. The method as claimed in claim 15, wherein the step of applying said second layer (1 ) further comprising applying a second paper sheet.
17. The method as claimed in claim 16, wherein the step of applying said first and second paper sheet comprises arranging said first paper sheet such that the fibre direction of the first paper sheet is extending in a first direction, and arranging said second paper sheet such that the fibre direction of the second paper sheet is extending in a second direction, said second direction being transverse to the first direction.
18. The method as claimed in any one of claims 10-13, wherein the step of applying said second layer (1 ) comprises applying a second powder based mix (1 ) comprising wood fibres, binders, preferably a thermosetting binder, and wear resistant particles.
19. A method of manufacturing a separate and continuous powder based balancing and/or protective layer (3), which is essentially uncured, wherein the method comprises the steps of:
• applying a powder mix (3), comprising fibres and a thermosetting binder, on a carrier (1 1 ),
• applying moisture (7) on the powder mix (3) such that the powder mix is connected together to an uncured balancing and/or protective layer (3); and
• releasing the uncured balancing and/or protective layer (3) from the
carrier (1 1 ).
20. The method as claimed in claim 19, wherein the fibres are wood fibres and the binder a melamine resin.
21 . A separate and continuous powder based balancing and/or protective layer (3), which is essentially uncured, comprising
a powder mix (3) comprising connected fibres and an essentially uncured thermosetting binder.
22. The balancing and/or protective layer according to claim 21 , wherein said layer is flexible.
23. The balancing and/or protective layer according to claim 21 or 22, wherein the connected fibres are wood fibres.
24. A building panel, comprising
a core (2), preferably a wood-based core such as MDF or HDF board, a decorative surface layer (1 ) arranged on a first surface of said core, the decorative surface layer comprising at least one paper layer (21 ; 22), and
a balancing layer (3) arranged on a second surface of said core (2), said second surface being opposite to said first surface,
wherein the balancing layer (3) is formed of a powder based mix comprising wood fibres and a thermosetting binder.
PCT/SE2012/050386 2011-04-12 2012-04-11 Powder based balancing layer WO2012141647A1 (en)

Priority Applications (13)

Application Number Priority Date Filing Date Title
BR112013025558-7A BR112013025558B1 (en) 2011-04-12 2012-04-11 method of making a building panel
CN201280016762.XA CN103459145B (en) 2011-04-12 2012-04-11 Balance layer based on powder
RU2013148006/13A RU2591466C2 (en) 2011-04-12 2012-04-11 Balancing layer on powder base
EP12771822.9A EP2697060B1 (en) 2011-04-12 2012-04-11 Method of manufacturing a building panel
ES12771822T ES2805332T3 (en) 2011-04-12 2012-04-11 Manufacturing method of a building panel
PL12771822T PL2697060T3 (en) 2011-04-12 2012-04-11 Method of manufacturing a building panel
AU2012243457A AU2012243457B2 (en) 2011-04-12 2012-04-11 Powder based balancing layer
NZ615287A NZ615287B2 (en) 2011-04-12 2012-04-11 Powder based balancing layer
CA2832040A CA2832040C (en) 2011-04-12 2012-04-11 Powder based balancing layer
MX2013011536A MX342546B (en) 2011-04-12 2012-04-11 Powder based balancing layer.
UAA201312541A UA112982C2 (en) 2011-04-12 2012-11-04 BALANCING BOWL BASED ON POWDER BASE
ZA2013/07461A ZA201307461B (en) 2011-04-12 2013-10-07 Powder based balancing layer
HRP20200960TT HRP20200960T1 (en) 2011-04-12 2020-06-17 Method of manufacturing a building panel

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US201161474498P 2011-04-12 2011-04-12
SE1150320 2011-04-12
SE1150320-8 2011-04-12
US61/474,498 2011-04-12
US201161557734P 2011-11-09 2011-11-09
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US61/557,734 2011-11-09

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CA2832040C (en) 2020-08-25
CN103459145A (en) 2013-12-18
US20120263965A1 (en) 2012-10-18
US20150275526A1 (en) 2015-10-01
AU2012243457A1 (en) 2013-09-26
CA2832040A1 (en) 2012-10-18
BR112013025558B1 (en) 2021-01-12
US10214913B2 (en) 2019-02-26
MX342546B (en) 2016-10-03
RU2013148006A (en) 2015-05-20
EP2697060B1 (en) 2020-06-10
RU2591466C2 (en) 2016-07-20
MX2013011536A (en) 2013-12-06
EP2697060A4 (en) 2014-11-12
EP2697060A1 (en) 2014-02-19
CN103459145B (en) 2016-06-29
PL2697060T3 (en) 2020-11-02
ZA201307461B (en) 2015-01-28
MY161172A (en) 2017-04-14
AU2012243457B2 (en) 2015-07-16
BR112013025558A2 (en) 2016-12-27
US9085905B2 (en) 2015-07-21

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