JP2000246839A - Printed resin film to be laminated to decorative panel and printed resin film laminated decorative panel - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a printed resin film to be laminated to a decorative panel excellent in design effect equal to or more than that of a decorative sheet using a conventional polyvinyl resin film, having a pattern applied by wiping printing and excellent in surface physical properties such as antistaining properties, solvent resistance or the like and a decorative panel to which the printed resin film is laminated. SOLUTION: A pattern printing layer 5 is formed on the substrate resin layer 4 or colored resin layer 6 of a polybutylene terephthalate film becoming a printed substrate and, further embossing processing is applied to the colored resin layer 6 and the formed embossed recessed parts 7 is filled with ink to provide a wiping printing layer 8 and a surface protective layer 9 to which embossing processing is selectively applied and a selectively applied gloss adjusting layer 11 are successively laminated on the wiping printing layer 8 in this order to produce a printed resin film to be laminated to a decorative panel. This film is laminated to a substrate such as a wood panel, a metal panel or an inorg. board to obtain a decorative panel.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a printed resin film for decorative laminate and a decorative plate on which the resin film is laminated, and more particularly to the exterior of home appliances such as doors and air conditioners of electric refrigerators and steel furniture. The present invention relates to a decorative board laminating resin film suitable for use in which design is particularly required, such as interior parts of elevators, buildings, and the like, and a decorative board on which the resin film is laminated.

[0002]

2. Description of the Related Art Conventionally, decorative boards used for various kinds of furniture, building interior materials, and the like include (1) a resin layer serving as a base material, which is printed using a usual method, to protect the surface of the printed layer. For this purpose, a decorative film provided with a coating layer of amino alkyd resin, urethane resin, etc., (2) After printing on the resin layer as a base material, a transparent biaxially stretched polyester film is laminated via an adhesive layer A decorative film such as a decorative film obtained by printing on a polyvinyl chloride film using a normal method, and then a transparent polyvinyl chloride film or a biaxially stretched polyester film laminated thereon, What is laminated | stacked on the board | substrates, such as a galvanized steel plate, a plywood, or MDF, via an adhesive agent is known.

However, the decorative plate laminated with the decorative film of the above (1) has insufficient strength of the decorative film. Therefore, when the V-cut processing or the like is performed, the decorative film is broken at the time of processing, and the ink at the corners is broken. However, it is not suitable for applications such as V-cut processing. The decorative board laminated with the decorative film of (2)
Excellent surface properties such as stain resistance and solvent resistance,
When the embossing is applied, the embossing is difficult to occur due to poor flexibility of the surface film and a high softening temperature. (3) Since the decorative plate laminated with the decorative film is made of a polyvinyl chloride film, the surface properties such as stain resistance and solvent resistance are inferior, and hydrogen chloride is used for incineration and disposal. There is a problem that toxic gas such as gas and harmful substances resulting therefrom are generated to pollute the environment and may damage an incinerator when incinerated.

[0004]

SUMMARY OF THE INVENTION In order to solve the above-mentioned problems, the present invention is to perform wiping printing, which is superior in design to a decorative sheet using a conventional polyvinyl chloride resin film, and is superior to a decorative sheet. It is an object of the present invention to provide a printed resin film for decorative board lamination having a picture pattern and excellent surface properties such as stain resistance and solvent resistance, and a decorative board obtained by laminating the resin film.

[0005]

According to the first aspect of the present invention, there is provided a printed resin film for laminating a decorative board, comprising a base resin layer, a printed layer, a colored resin layer, a wiping printed layer, a surface protective layer, and a gloss adjusting layer sequentially from the bottom. It is characterized by being laminated. The printed resin film for laminating a decorative plate according to claim 2 is characterized in that a colored resin layer, a wiping printed layer, a surface protective layer, and a gloss adjusting layer are sequentially laminated from the bottom. The printed resin film for laminating a decorative plate according to claim 3 is characterized in that a colored resin layer, a wiping printed layer, and a surface protective layer are sequentially laminated from the bottom. It is preferable that the printing resin film has the wiping printing layer provided on the entire surface of the coloring resin layer. The printing resin film preferably has a wiping printing layer in which the colored resin layer is embossed, and the embossed recesses formed by the embossing are filled with ink. In the printing resin film, it is preferable that the base resin layer and the colored resin layer are made of polybutylene terephthalate resin. In the printing resin film, it is preferable that the colored resin layer is made of polybutylene terephthalate resin.

According to an eighth aspect of the present invention, there is provided a decorative plate, wherein at least one surface of a substrate on which a resin film is to be laminated is laminated with any of the above-mentioned printed resin films for decorative plate lamination. It is preferable that the decorative board is formed by laminating an adhesive layer between the substrate and the printed resin film for laminating the decorative board. In the decorative plate, the substrate is preferably a metal plate. In the decorative board, the substrate is preferably a wooden board or a board.

[0007]

BEST MODE FOR CARRYING OUT THE INVENTION The inventor of the present invention has proposed a design which is superior in design to a polyvinyl chloride resin film which is liable to generate toxic gas and harmful substances due to incineration and contaminate the environment. Has a pattern and stain resistance,
As a result of intensive studies on a printable resin film to be laminated on a decorative board with excellent surface properties such as solvent resistance, a polybutylene terephthalate film was used as a base resin layer and a colored resin layer as a printing base, and a pattern printing layer was used. After further embossing the colored resin layer to form an embossed concave portion, a wiping print layer formed by filling the embossed concave portion with ink using a wiping method is provided, and selectively embossed thereon. By sequentially laminating a surface protective layer to be applied, or a gloss adjusting layer selectively further thereon, from the bottom, it is possible to obtain a resin film to be laminated on a decorative plate satisfying the above-mentioned required characteristics. I found it. Furthermore, the above-mentioned resin film is made of a metal plate, a plywood,
It has been found that the decorative plate laminated on a board or the like has excellent design properties in addition to the above-mentioned excellent film properties of the resin film.

Hereinafter, the contents of the present invention will be described. FIG. 1 is a cross-sectional view showing an example of the printed resin film for decorative laminate of the present invention. FIGS. 2 and 3 are cross-sectional views showing another example of the printed resin film of the present invention. 1 is a sectional view showing an example of a decorative board of the present invention. 1 is a printed resin film for decorative laminate lamination, 2 is a substrate, 3 is an adhesive layer, 4 is a base resin layer, 5 is a picture printed layer, 6 is a colored resin layer, 7 is an embossed recess for wiping printing, and 8 is wiping. Printing layer, 9 is a surface protective layer, 10 is embossed concave portion, 11
Denotes a gloss adjusting layer, and 12 denotes a decorative plate. As shown in FIG. 1, the printed resin film 1 for decorative laminate lamination according to the present invention forms an embossed recess 7 on the upper surface of the colored resin layer 6 by embossing, and then applies ink to the embossed recess 7 using a wiping method. Is formed, and a surface protection layer 9 is further laminated on the upper surface thereof. Further, the printed resin film 1 for decorative laminate of the present invention
As shown in FIG. 2, a surface protective layer 9 having an embossed surface may be used as the surface protective layer 9 of the printed resin film for decorative laminate lamination of FIG. Further, as shown in FIG. 3, the printed resin film for decorative laminate lamination 1 of the present invention has a base material in which a pattern print layer 5 is formed on the lower surface of the colored resin layer 6 of the decorative resin laminate print resin film of FIG. The resin layer 4 may be laminated, and a gloss adjusting layer 11 may be further provided on the surface protective layer 9 of the printed resin film for decorative laminate lamination of FIG. 2 to such an extent that the embossed concave portions 10 are not lost.

FIG. 4 shows a decorative plate 12 in which the printed resin film 1 for decorative laminate shown in FIG. 2 is laminated on a substrate 2 via an adhesive layer 3. FIG. 5 shows a decorative plate 12 in which the printed resin film 1 for decorative laminate shown in FIG. 3 is laminated on the substrate 2 via the adhesive layer 3.

The base resin layer 4 and the colored resin layer 6 used in the present invention have an intrinsic viscosity (IV) of 1.0 to 2.0.
Value), it is preferable to use a polybutylene terephthalate film having an intrinsic viscosity of 1.
5 or less, more preferably 1.2 or more from the viewpoint of water aging resistance (water deterioration resistance). Further, when the base resin layer 4 is also formed into a film using an extruder, a colored pigment may be kneaded to form a colored resin layer.

The picture printing layer 5 is a layer expressing patterns such as wood grain, stone grain, surface pattern of natural leather, cloth grain, abstract pattern, and the like. As a vehicle of the ink forming the picture printing layer 5, for example, Known materials such as cellulose derivatives such as nitrocellulose and cellulose acetate, and polyester urethane resins can be used. Among them, a nitrocellulose-alkyd resin-based ink is preferable from the viewpoint of both adhesion and thermal adhesion.

After the embossing process is performed on the colored resin layer 6 to form the embossed concave portion 7, when the wiping printing layer 8 in which the embossed concave portion 7 is filled with ink using the wiping method is provided, Embossed recess 7
As the wiping ink to be filled, paint or ink is used. For example, a synthetic resin such as a natural resin or a denatured resin thereof, a cellulose derivative, a polyester resin, an acrylic resin, and a polyurethane resin is used as a constituent material of the vehicle, and a coloring pigment, an extender pigment, and the like are added to the vehicle. Paints or inks are used.
As the vehicle to be used, a urethane two-liquid curing type is suitably used. As the wiping method, any of the conventionally used wiping methods such as a doctor blade method and a roll coating method may be used.

As the surface protective layer 10, it is preferable to use a polyester resin film, and in particular, 1.0 to 2.0.
It is more preferable to use a polybutylene terephthalate resin film having an intrinsic viscosity of 0. The polyester resin film is made of a polyester resin containing no plasticizer and no halogen element.

The materials constituting the polyester resin
As an example, a copolymerized polyester resin having the following composition is preferably used. That is, as a soft segment forming a resin, polyoxyalkylene glycol such as polyethylene glycol and polytetramethylene glycol, or HOOC- [CH ₂ ] such as polyε-caprolactone, azelaic acid, sebacic acid, dodecanedioic acid and dimer acid are used. _An aliphatic polyester composed of a fatty acid dicarboxylic acid having a molecular structure of _n- COOH and an aliphatic and / or alicyclic diol is preferably used.

The hard segments constituting the resin include aromatic terephthalates such as ethylene terephthalate, butylene terephthalate, citalohexane dimethylene terephthalate, cyclohexane dimethylene cyclohexane dicarboxylate, and butylene 2,6 naphthalenedicarboxylate. It is preferably composed of at least one selected from the group consisting of a group and / or an alicyclic ester.

Further, it is preferable that the alcohol component contains a 1,4 butanediol residue from the viewpoint of solvent resistance, and that the 1,4 butanediol residue occupies the entire alcohol component forming the copolymerized polyester. It is preferable that it is 40 mol% or more and 65 mol% or less.

If stronger adhesion to the substrate is required, good adhesion can be obtained by incorporating an ionomer resin component into a part of the resin component of the base resin layer 4. In this case, the ionomer resin component is 1 to 5 of the entire resin component.
It is preferably 0% by weight.

The printed resin film for laminating decorative boards of the present invention shown in FIG. 1 can be prepared as follows. That is, a resin which is heated and melted by an extruder and kneaded with a color pigment is extruded from a T-die onto a casting roll which has been embossed to form a colored resin layer 6 having an embossed concave portion 7 on one surface. A wiping print layer 8 formed by filling the embossed concave portions 7 with ink by wiping on the surface of the colored resin layer 6 where the embossed concave portions 7 are formed;
With the surface protective layer 9 superimposed on the upper surface thereof, it is passed through a pair of heat rolls, sandwiched and pressed, and then heat-sealed and laminated to produce one laminated film. By applying pressure while heating, the surface of the wiping print layer of the colored resin layer 6 is fused to the surface protective layer 9 to form one printed resin film 1 for decorative laminate.

When the colored resin layer 6 and the surface protective layer 9 are laminated, by using an embossing roll as the above-mentioned heat roll, lamination and embossing can be carried out simultaneously. Printing resin film 1 for laminated decorative board shown in FIG. 2 having embossed concave portions 10 formed on the surface
b can be obtained. And since the coloring resin layer 6 is excellent in embossability, clear wiping printing is possible, and since it is excellent in dimensional stability, it is possible to suppress fluctuations in expansion and contraction caused by tension and heat. An embossed decorative film having a high design property, in which the embossed patterns are synchronized. The above-mentioned steps such as lamination and embossing can be performed under the same conditions as in the conventional polyvinyl chloride resin film. Further, when the colored resin layer 6 and the surface protective layer 9 of the printed resin film for decorative laminate lamination of FIG. 2 are laminated while being embossed, a base resin layer in which the pattern printing layer 5 is provided on the lower surface of the colored resin layer 6 4, and then, as shown in FIG. 3, a gloss adjusting layer 11 is applied to the surface of the surface protective layer 9 to further improve the design property. It can also be 1.

The gloss adjusting layer 11 may be colorless and transparent, colored and transparent, or matte and transparent, and adjusts the glossiness of the surface of the printed resin film 1 for laminating decorative boards. But also serves as a surface protective layer. The gloss adjusting layer 11 can be formed by applying a paint using an appropriate vehicle.
As the vehicle, one or a mixture of two or more thermosetting resins such as a phenol resin, an unsaturated polyester resin, an epoxy resin, and a polyurethane resin can be used. Usually, an appropriate amount of a matting agent is dispersed in the paint for forming the gloss adjusting layer 11 to give a desired glossiness. Examples of the matting agent include mica, silica, alumina, calcium carbonate, diatomaceous earth, and silica sand. , A shirasu balloon or the like is used. Gravure coat,
Known coating methods such as a mouth coat and an air knife coat can be used.

Further, the printed resin film 1 for laminating a decorative board obtained by the above-mentioned method is bonded to the substrate 2 with an adhesive layer 3 interposed therebetween, so that the decorative board 12 shown in FIG. Is obtained. As the substrate 2, for example, wood veneer, wood plywood, particle board, wood plate such as MDF, steel plate, aluminum alloy plate, metal plate such as galvanized steel plate plated with zinc or zinc alloy, or gypsum board, calcium silicate board A board made of an inorganic material such as asbestos slate board is used.

Printed resin film 1 for laminated decorative board and substrate 2
As the adhesive of the adhesive layer 3 used for lamination,
Common adhesives, for example, vinyl acetate resin type, ethylene-vinyl acetate resin type, urea resin type, emulsion type adhesives such as urethane resin type are safe against fire, have no odor, and are not expensive. It is preferably used because of its low cost.

[0023]

Next, the present invention will be described in more detail by way of examples. Example 1 A commercially available polybutylene terephthalate resin kneaded with 20% by weight of a cream pigment was heated and melted by an extrusion film forming machine, extruded from a T-die onto an embossed casting roll, and embossed on one side. A colored resin layer having a concave portion and a thickness of 60 μm was formed. Then
After a two-component curable urethane-based coloring ink (manufactured by Showa Ink, PW-001) is applied to the surface having the embossed concave portions by a roll coating method, the colored ink adhering to portions other than the embossed concave portions by a doctor blade is removed. After removal by wiping, the colored ink filled in the embossed concave portions formed on the surface of the laminated film was solidified to prepare a printed resin film. Furthermore, a commercially available polybutylene terephthalate resin was used to form an embossed surface of this printed resin film on an embossed surface using an extrusion film forming machine.
A non-stretched film having a thickness of μm is stacked thereon, and the heating temperature of the roll for pressure bonding is 210 ° C., and the feeding speed of the resin film is 20 m / mi.
n, both films were heat-pressed and laminated under the conditions of a nip pressure of a pressure roll: 15 kgf / cm ² , thereby producing a printed resin film for decorative laminate lamination. Next, a polyester-based adhesive was added to a 0.5 mm thick electrogalvanized steel sheet at 10 g /
was coated at a coverage of m ^2, the veneer laminating printing resin film heating temperature: 220 ° C., the adhesive pressure: 15 kgf
/ Cm ² , and pressure bonding time: 5 seconds under heat and pressure to obtain a decorative plate.

(Example 2) A wiping print layer surface obtained by printing on the same unstretched film of polybutylene terephthalate resin as in Example 1 in the same manner as in Example 1, and the same transparent polybutylene as in Example 1 A film made of a terephthalate resin is opposed to the transparent polybutylene terephthalate film surface as the embossing roll side under the same conditions as the lamination conditions by the heat-compression bonding of Example 1, and between the embossing roll and the pressing roll formed of a silicone rubber roll. Then, the printed resin film for laminated decorative board having an embossed concave portion on the surface of the transparent polybutylene terephthalate film was prepared. Next, a polyurethane-based adhesive is applied to a 6-mm-thick wood plywood at an application amount of 50 g / m ² , and the printed resin film for decorative laminate lamination is heated at 160 ° C., adhesive pressure is 15 kgf / cm ² , and pressure-bonded. Heat bonding was performed under the conditions of time: 15 seconds to obtain a decorative plate.

Example 3 A commercially available polybutylene terephthalate resin having a thickness of 40 formed by an extrusion film forming machine.
On one side of the unstretched film of μm, a picture printing layer was printed in-line by a gravure rotary press using a nitrocellulose-alkyd ink (manufactured by Showa Ink, SAM). Then, on the printing surface of the unstretched film,
In the same manner as in Example 1, the wiping print layer surface of the unstretched film of the same polybutylene terephthalate resin printed as in Example 1 and the same transparent polybutylene terephthalate film as in Example 1 were opposed to each other. Under the same conditions as the lamination conditions by heat compression bonding, the transparent polybutylene terephthalate film surface was used as the embossing roll side,
The printed resin film for decorative laminate lamination having embossed concave portions on the surface of the transparent polybutylene terephthalate film was prepared by being passed between an embossing roll and a pressing roll made of a silicone rubber roll and pressed. Furthermore, on the embossed surface of the printed resin film for laminate laminate,
Two-part curable urethane gloss paint (Showa Ink, O
P-No. 81) was coated with a gravure roll having a plate depth of 30 μm to prepare a decorative film having excellent design properties.
Next, a polyurethane-based adhesive was applied to a gypsum board having a thickness of 8 mm at an application amount of 80 g / m ² , and the printed resin film for laminating a decorative board was heated at a temperature of 180 ° C. and an adhesive pressure was 1: 1.
Heat-press bonding was performed under the conditions of 5 kgf / cm ² and pressure bonding time: 20 seconds to obtain a decorative plate.

(Evaluation of Characteristics of Resin Film) Example 1,
The decorative boards prepared in 2 and 3 were evaluated for the following properties. (Embossability) The quality of the embossability for wiping printing of the printed resin film for laminate laminate of the present invention is determined by the degree of surface roughness of the base resin layer of the embossed resin film. In the present invention, the surface of the colored resin layer of the resin film that has been embossed using a grained engraved roll provided with irregularities of 11 μm in average surface roughness (Ra) is visually observed, and the embossability is improved. Pass / fail was evaluated based on the following three criteria. ：: good, Δ: slightly bad, ×: bad The above evaluation criteria are based on SURFCO manufactured by Tokyo Seimitsu Co., Ltd. in terms of the surface roughness (Ra: μm) of the polyvinyl chloride resin film.
Measured in accordance with JIS B0601 using an M surface roughness meter, and a case where the average surface roughness is 4 μm is regarded as a pass criterion for embossability, and the surface of the polyvinyl chloride resin film having an average surface roughness of 4 μm Those with the same or better appearance are rated as good (○), those with slightly poorer appearance compared to the surface of the polyvinyl chloride resin film but with no practical problem are rated as poor (△), and those with no embossing It was judged as defective (x).

(Stain resistance) A cloth impregnated with ethanol after drawing with black oil-based magic ink on the outermost resin film surface of the decorative board prepared in Examples 1, 2 and 3 and leaving it to stand for 24 hours. And the degree of the magic ink remaining on the resin film surface was visually observed and evaluated according to the following criteria. A: No magic ink is observed. ：: Very small amount of magic ink remaining to the extent that there is no practical problem is observed. Δ: A slight amount of magic ink remaining to such a degree as to cause a problem in practical use is observed. ×: Residual magic ink is observed to a considerable extent.

(Solvent resistance) A sponge impregnated with methyl ethyl ketone was placed on the resin film surface of the outermost layer of the decorative boards prepared in Examples 1, 2 and 3, and after standing for 24 hours, discoloration of the film surface and The degree of swelling was visually observed and evaluated according to the following criteria. A: No discoloration or swelling is observed. ：: Extremely slight discoloration or swelling, which is practically acceptable, is observed. Δ: Slight discoloration or swelling to such an extent as a practical problem is observed. X: Discoloration and swelling are recognized to a considerable extent.

(Water-Resistant Degradation Resistance) It is assumed that the decorative board of the present invention is aged for a long time in a high-temperature and high-humidity state (for example, when it is used as an interior material of a unit bath). The water deterioration resistance of the resin film was evaluated by the DuPont impact test method. The printed resin film for decorative laminate lamination prepared in Examples 1, 2 and 3 was laminated on a galvanized steel sheet having a thickness of 0.5 mm to obtain a test piece. This test piece is 60 mm
Cut out into a size of × 60 mm, immersed in demineralized water maintained at a temperature of 38 ± 2 ° C. for one month, and then dried at room temperature,
Using a DuPont impact tester, under the conditions in accordance with JIS K 5400 (impact part size 1/2 inchφ, weight 1 kg,
An impact was applied at a drop height of 50 cm). The state of the resin film after applying the impact was visually observed and evaluated according to the following five grades. ：: No crack was observed in the resin film. ：: Fine cracks are observed in a part of the resin film. Δ: Fine cracks are observed in the entire embossed portion of the resin film. ×: Large cracks are observed in the entire embossed portion of the resin film. XX: The entire resin film is significantly cracked. In the above scores, ◎ and ○ have no problem in use. This test was performed on ten test pieces. The characteristics of these decorative boards are shown below.

Embossability Contamination resistance Solvent resistance Water deterioration resistance --------------------------------------------------------------------------------------------------------- Example 1 ○ ◎ ◎ ◎ −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Example 2 ○ ○ ◎ ◎ ◎ − −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Example 3 ○ ○ ◎ ◎ As shown in Table 1, the present invention Has excellent characteristics in all of embossability, stain resistance, solvent resistance and water deterioration resistance.

[0031]

The printed resin film for decorative laminate lamination of the present invention is constructed as described above, and the base resin layer and the colored resin layer made of a polybutylene terephthalate film are excellent in the fluctuation of expansion and contraction due to heat and tension, and are excellent. Dimensional stability, it is possible to obtain a printed matter with high printing register accuracy. Furthermore, because of the excellent embossability, clear wiping printing is possible. Also, since the decorative film can be obtained under the same manufacturing method and manufacturing conditions as the conventional polyvinyl chloride resin film, there is no need for capital investment such as the addition of new equipment or the remodeling of the equipment. In the same manner as described above, it is possible to express a design pattern excellent in design property in which the printed pattern and the embossed pattern are synchronized. Furthermore, since the plasticizer is not contained in the resin constituting the base resin layer and the surface protective layer, there is no problem such as surface contamination due to bleeding of the plasticizer, and the stain resistance,
Excellent surface properties such as solvent resistance and water resistance. Furthermore, since no toxic gas such as hydrogen chloride gas is generated at the time of incineration disposal, there is no fear of polluting the environment, and it is excellent in environmental preservation.

[Brief description of the drawings]

FIG. 1 is a cross-sectional view showing an example of a printed resin film for decorative laminate according to the present invention.

FIG. 2 is a cross-sectional view showing another example of the printed resin film for laminate of the decorative board of the present invention.

FIG. 3 is a cross-sectional view showing another example of the printed resin film for decorative laminate according to the present invention.

FIG. 4 is a cross-sectional view showing an example of the decorative board of the present invention.

FIG. 5 is a sectional view showing another example of the decorative board of the present invention.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 ... Printed resin film for laminating decorative board 2 ... Substrate 3 ... Adhesive layer 4 ... Base resin layer 5 ... Picture printed layer 6 ... Colored resin layer 7 ... Wiping Embossed concave portion for printing 8: Wiping printed layer 9: Surface protective layer 10: Embossed concave portion 11: Gloss adjustment layer 12: Decorative plate

──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI Theme coat ゛ (Reference) B32B 27/36 B32B 27/36 33/00 33/00 (72) Inventor Yoshiyuki Sugimoto 1296 HigashiToyoi, Kudamatsu City, Yamaguchi Prefecture No. 1 Toyo Kohan Co., Ltd. Technical Research Institute (72) Inventor Yoshiki Takei 1296 Higashi Toyoi, Kudamatsu City, Yamaguchi Prefecture F-term in Toyo Kohan Co., Ltd. Technical Research Laboratory (reference) 4F100 AB01E AK01A AK01B AK41G AK42A AK42B AK51G AK51H AP00E AP03E AR00B AR00D AS00C AT00A AT00E BA04 BA05 BA07 BA10A BA10D CB02 J03 GB09JB31B31 J03 H09BJBJB31J08 JN21D

Claims (12)

[Claims] 1. A printed resin film for laminated decorative board, wherein a base resin layer, a printed layer, a colored resin layer, a wiping printed layer, a surface protective layer, and a gloss adjusting layer are sequentially laminated from the bottom. 2. A decorative resin laminate printing resin film in which a coloring resin layer, a wiping printing layer, a surface protection layer, and a gloss adjusting layer are sequentially laminated from the bottom. 3. A printed resin film for laminating decorative boards, wherein a colored resin layer, a wiping print layer, and a surface protective layer are sequentially laminated from the bottom. 4. The printed resin film according to claim 1, wherein the wiping print layer is provided on the entire surface of the colored resin layer. 5. The makeup according to claim 1, wherein the colored resin layer is embossed, and has a wiping print layer in which ink is filled in embossed concave portions formed by the embossing. Printed resin film for board lamination. 6. The printed resin film according to claim 1, wherein the base resin layer and the colored resin layer are made of polybutylene terephthalate resin. 7. The printed resin film according to claim 2, wherein the colored resin layer is made of a polybutylene terephthalate resin. 8. A decorative board obtained by laminating the printed resin film according to claim 1 on at least one surface of a substrate on which the resin film is laminated. 9. The decorative board according to claim 8, wherein the decorative board is laminated between the substrate and the printed resin film for decorative laminate via an adhesive layer. 10. The decorative plate according to claim 8, wherein the substrate is a metal plate. 11. The decorative board according to claim 8, wherein the substrate is a wooden board. 12. The decorative board according to claim 8, wherein the substrate is a board.