WO2012133402A1

WO2012133402A1 - Decorative material for floor

Info

Publication number: WO2012133402A1
Application number: PCT/JP2012/057922
Authority: WO
Inventors: 孝志土井; 将徳上野; 宏平入山; 直規中島
Original assignee: 大日本印刷株式会社
Priority date: 2011-03-31
Filing date: 2012-03-27
Publication date: 2012-10-04
Also published as: CN107288305A; KR20130132605A; HK1198339A1; CN103890294A; JP6300427B2; KR20160043131A; JP2012214981A

Abstract

The present invention provides a decorative material for floors which, even when an excessive load is applied thereto in daily lives (for example, when heavy furniture or a desk is dragged), is inhibited from suffering blushing or dents. This decorative material for floors specifically comprises a woody base and a decorative sheet laminated thereto, and is characterized in that (1) the decorative sheet includes a surface protective layer as an outermost layer, the surface protective layer having a thickness of 12-50 µm and a Martens hardness of 50-150 N/mm², and (2) the woody base comprises one or more woody layers, the woody layer which is in contact with the decorative sheet having a maximum density of 0.8-1.2 g/cm³ and an average density of 0.7 g/cm³ or higher.

Description

Floor decorative material

The present invention relates to a floor covering material in which generation of whitening and dents is suppressed even when an excessive load is applied in daily life (for example, when a heavy furniture or desk is dragged).

Conventionally, as a decorative material for a floor of a house, a material in which a decorative sheet having a design of natural wood is pasted on the front surface of a wooden base material made of various plywoods or wood fiber boards is known (Patent Document 1). etc).

Conventional flooring materials are also said to have scratch resistance suitable for daily life, but when excessive loads are applied, such as dragging heavy furniture or desks, whitening and There is a problem that dents (scratches) occur, and further improvement in scratch resistance is desired.

As a measure for improving the scratch resistance, for example, the surface coating film hardness of the decorative sheet may be increased, but if it is too hard, the coating sheet becomes brittle and a coating film crack (whitening damage) is likely to occur. Although it is conceivable to increase the thickness of the coating film, if it is too thick, the coating film becomes brittle, and in this case, coating film cracking easily occurs. Therefore, it is difficult to solve the problem of improving scratch resistance simply by increasing the hardness and thickness of the surface coating film of the decorative sheet.

On the other hand, whitening scratches and dent scratches on flooring decorative materials are also related to the physical properties of the wooden substrate. Specifically, if the wooden base material is too soft, it will not change even if the surface coating film hardness of the decorative sheet is hard, and dents will easily occur, and if the wooden base material is too hard, the surface coating of the decorative sheet will continue. Concentration of the load on the film tends to cause whitening damage regardless of the physical properties of the surface coating film.

Therefore, in consideration of the balance between the wooden base material and the decorative sheet, it is desired to develop a decorative material for floors in which the occurrence of whitening and dents is suppressed even when an excessive load is applied.

JP 2006-97321 A

It is an object of the present invention to provide a floor covering material in which the occurrence of whitening and dents is suppressed even when an excessive load is applied in daily life (for example, when a heavy furniture or desk is dragged).

As a result of intensive studies, the present inventor has found that the above object can be achieved by setting the physical properties of the surface protective layer and the woody base material, which are the outermost layers of the decorative sheet, to a specific range, and to complete the present invention. It came.

That is, the present invention relates to the following floor decorative material.
1. a flooring decorative material in which a decorative sheet is laminated on a wooden substrate,
(1) The decorative sheet has a surface protective layer thickness of 12 to 50 μm as an outermost layer, and a Martens hardness of the surface protective layer of 50 to 150 N / mm ² .
(2) The wooden substrate is composed of one or more wooden layers, and the maximum density of the wooden layer in contact with the decorative sheet is 0.8 to 1.2 g / cm ³ , and The average density of the wood layer in contact with the decorative sheet is 0.7 g / cm ³ or more,
A decorative material for floors.
2. The floor decorative material according to item 1, wherein the surface protective layer contains an ionizing radiation curable resin.
3. The floor decorative material according to Item 1, wherein the surface protective layer contains an electron beam curable resin.
4. The floor decorative material according to any one of items 1 to 3, wherein the surface protective layer has a thickness of 20 to 40 μm.
5. The floor decorative material according to any one of Items 1 to 4, wherein the wood layer is a wood veneer, wood plywood, wood fiber board, or particle board.

Hereinafter, the floor decorative material of the present invention will be described in detail.

The floor decorative material of the present invention has a decorative sheet laminated on a wooden substrate,
(1) The decorative sheet has a surface protective layer thickness of 12 to 50 μm as an outermost layer, and a Martens hardness of the surface protective layer of 50 to 150 N / mm ² .
(2) The wooden substrate is composed of one or more wooden layers, and the maximum density of the wooden layer in contact with the decorative sheet is 0.8 to 1.2 g / cm ³ , and The average density of the wood layer in contact with the decorative sheet is 0.7 g / cm ³ or more.

The floor decorative material of the present invention having the above-described characteristics particularly has a surface protective layer thickness of 12 to 50 μm, a Martens hardness of 50 to 150 N / mm ² , and among the wooden substrates, In the daily life, the maximum density of the wood layer in contact with the sheet is 0.8 to 1.2 g / cm ³ and the average density of the wood layer in contact with the decorative sheet is 0.7 g / cm ³ or more. Even when an excessive load is applied (for example, when heavy furniture or a desk is dragged), the occurrence of whitening scratches and dent scratches is suppressed.

Hereinafter, each structure of the decorative material for floors of this invention is demonstrated.
(Wood base)
The wood base material used in the present invention comprises one wood layer or two or more wood layers. That is, in the case of two or more layers, two or more wood layers are laminated.

Each wood layer includes wood veneer, wood plywood, wood fiberboard, particle board (PB), etc. In the case of wood veneer and wood plywood, tree species such as cedar, firewood, lawan, teak, eucalyptus, etc. is there. The wood fiberboard includes medium density wood fiberboard (MDF), high density wood fiberboard (HDF) and the like. Strictly speaking, the wood plywood is obtained by bonding a plurality of thin plates, but in this specification, the wood plywood itself means one wood layer.

In the present invention, a wood layer having a maximum density of 0.8 to 1.2 g / cm ³ and an average density of 0.7 g / cm ³ or more is used as the wood layer in contact with the decorative sheet. That is, the maximum density and the average density mean physical properties of the wood layer when it is composed of one layer of wood, and physical properties of the wood layer of the outermost layer (decorative sheet side) when it is composed of two or more layers. Means. Note that the above description of “wood layer in contact with the decorative sheet” means a wooden layer closest to the decorative sheet, and in fact, indirectly through an adhesive layer between the wooden layer and the decorative sheet. It also includes the case where it touches.

Maximum density of the wood layer in contact with the decorative sheet (hereinafter also referred to as "the wood layer") may be any 0.8 ~ 1.2g / cm ^3, preferably 0.9 ~ 1.1g / cm ^3. The maximum density is based on the density distribution, considering that the density near the surface of the wood layer is higher than that near the center due to the manufacturing method, especially in the case of wood fiberboard and particleboard. It means the maximum density at. Therefore, in the case of the wood single plate and the wood plywood, the case where the density distribution is small may be considered. In such a case, the maximum density and the average density are considered to be approximately the same. The average density may be 0.7 g / cm ³ or more, preferably 0.75 to 0.85 g / cm ³ .

The maximum density and the average density in the present specification are values measured by the following procedure with reference to FIG.
(1) Irradiate a certain amount of gamma rays in the plane direction (x direction) of the wood layer. Multiple points are irradiated continuously so that there are 25 points for a thickness of 1 mm (that is, 300 points when the thickness of the wood layer is 12 mm as shown in FIG. 2).
(2) Measure and record the radiation dose of gamma rays that have passed through the wood layer.
(3) Calculate the amount of transmission loss of γ rays by subtracting the amount of radiation after transmission in (2) from the amount of γ rays irradiated to the wood layer.
(4) The transmission loss amount per unit length is calculated by dividing the transmission loss amount of γ rays calculated in (3) above by the length (L) in the irradiation direction (x direction).
(5) Perform steps (1) to (4) on a resin plate (standard sample: density 1 g / cm ³ ) for which the density has already been specified. Transmission loss per unit length of γ rays in the standard sample Calculate the amount.
(6) Calculate the density of the wood layer by comparing the transmission loss per unit length of the wood layer with the transmission loss per unit length of the standard sample.
(7) The maximum value of the calculated multi-point density (300 points when the thickness of the wood layer is 12 mm as shown in Fig. 2) is the maximum density, and the value obtained by dividing the sum of the multi-point densities by the number of points Average density.

When the wooden substrate is composed of two or more wooden layers, the density of the remaining layers (lower layers) excluding the outermost layer is not particularly limited.

The thickness of the wood substrate is not particularly limited, but is preferably about 2 to 15 mm, more preferably about 6 to 12 mm.
(Decorative sheet)
A decorative sheet is laminated on the wooden substrate. The decorative sheet is not particularly limited as long as the thickness of the outermost surface protective layer is 12 to 50 μm and the Martens hardness is 50 to 150 N / mm ² . For example, what has a picture layer (solid ink layer / pattern ink layer), a transparent resin layer, and the said surface protective layer in order on a base material sheet is preferable.

Hereinafter, this decorative sheet will be exemplarily described.

Base sheets include 1) thin paper, fine paper, kraft paper, Japanese paper, titanium paper, resin-impregnated paper, paper reinforced paper, 2) wood fiber, glass fiber, asbestos, polyester fiber, vinylon fiber, rayon. Examples thereof include one or two or more laminates of woven or non-woven fabric made of fibers and the like, and 3) sheets made of synthetic resin such as polyolefin, polyester, polyacryl, polyamide, polyurethane, and polystyrene.

The thickness of the base sheet is preferably about 20 to 300 μm. The substrate sheet may be colored as necessary. Further, the surface may be subjected to surface treatment such as corona discharge treatment, plasma treatment, or ozone treatment.

The pattern layer is composed of a pattern ink layer and / or a solid ink layer. The pattern layer can be formed by a printing method such as gravure printing, offset printing or silk screen printing. Examples of the pattern of the pattern ink layer include a wood grain pattern, a stone pattern, a cloth pattern, a skin pattern, a geometric pattern, characters, symbols, line drawings, various abstract patterns, and the like. The solid ink layer is obtained by solid printing of colored ink. The pattern layer is composed of one or both of a pattern ink layer and a solid ink layer.

As the ink used for the pattern layer, as a vehicle, chlorinated polyolefin such as chlorinated polyethylene and chlorinated polypropylene, polyester, polyurethane composed of isocyanate and polyol, polyacryl, polyvinyl acetate, polyvinyl chloride, vinyl chloride-vinyl acetate A polymer, a cellulose-based resin, a polyamide-based resin, or the like may be used alone or in combination of two or more, and an ink may be used by adding a pigment, a solvent, various auxiliary agents, and the like. Among these, from the viewpoint of environmental problems, adhesion to the printing surface, and the like, one or a mixture of two or more of polyester, polyurethane made of isocyanate and polyol, polyacryl, polyamide-based resin, and the like is preferable.

The transparent resin layer is not particularly limited as long as it is a transparent resin layer. For example, the transparent resin layer can be suitably formed of a transparent thermoplastic resin.

Specifically, soft, semi-rigid or rigid polyvinyl chloride, polyethylene terephthalate, polybutylene terephthalate, polyamide, polyethylene, polypropylene, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, ethylene-acrylic acid ester copolymer Examples thereof include polymers, ionomers, polyacrylic acid esters, and polymethacrylic acid esters. Among the above, polyolefin resins such as polypropylene are preferable.

The transparent resin layer may be colored. In this case, a colorant may be added to the thermoplastic resin. As the colorant, pigments or dyes used in the picture layer can be used.

For the transparent resin layer, fillers, matting agents, foaming agents, flame retardants, lubricants, antistatic agents, antioxidants, UV absorbers, light stabilizers, radical scavengers, soft components (eg rubber) Various additives such as may be included.

The surface protective layer is the outermost layer. In the present invention, the thickness of the surface protective layer is 12 to 50 μm, and the Martens hardness is 50 to 150 N / mm ² . The thickness of the surface protective layer is preferably 20 to 40 μm from the viewpoint of improving scratch resistance. The Martens hardness is preferably 70 to 140 N / mm ² .

The Martens hardness of the surface protective layer can be appropriately adjusted by 1) mixing two or more kinds of resins having different hardnesses, or 2) mixing an elastomer with the resin. In addition, when using an ionizing radiation curable resin, which will be described later, for the surface protective layer, it is possible to change the number of polymerizable functional groups contained in one molecule or to mix resins having different functional group numbers. The hardness can be adjusted to a desired value.

In addition, the Martens hardness in this specification is a value measured using a surface film physical property tester (PICODENTOR HM-500, manufactured by Fisher Instruments Co., Ltd.), and a specific measurement method is as follows. is there. In this measurement method, using the diamond indenter (Vickers indenter) shown in Fig. 1 (a), the diamond indenter was pushed into the measurement sample as shown in Fig. 1 (b), and the diagonal line of the pyramid-shaped depression formed on the surface The surface area A (mm ² ) is calculated from the length of and the hardness is obtained by dividing the test load F (N). As shown in FIG. 1 (c), the indentation conditions were as follows. First, a load of 0 to 5 mN was applied for 10 seconds, then a 5 mN load was maintained for 5 seconds, and finally 5 Unloading up to 0 mN in 10 seconds. And the hardness calculated | required by F / A based on the surface area A and the test load F is the said Martens hardness. In addition, in this specification, in order to avoid the influence of the hardness of layers other than a surface protective layer, the Martens hardness of the cross section of the surface protective layer was measured. In this case, the decorative sheet is embedded with a resin (cold-curing type epoxy two-component curable resin), left to cure at room temperature for 24 hours or more, and then the cured embedded sample is mechanically polished to a surface protective layer. The cross section was exposed, and the Martens hardness of the cross section was measured by pushing a diamond indenter into the cross section (at a position avoiding the fine particles such as inorganic filler in the surface protective layer).

The resin for forming the surface protective layer can be appropriately selected within a range in which a predetermined Martens hardness can be obtained, but a curable type such as a thermosetting resin or an ionizing radiation curable resin (for example, an electron beam curable resin). Resins are preferred. In particular, ionizing radiation curable resins are preferable from the viewpoint of high surface hardness, productivity, and the like.

Examples of thermosetting resins include unsaturated polyester resins, polyurethane resins (including two-component curable polyurethane), epoxy resins, amino alkyd resins, phenol resins, urea resins, diallyl phthalate resins, melamine resins, guanamine resins, and melamines. -Urea cocondensation resin, silicon resin, polysiloxane resin and the like.

A curing agent such as a crosslinking agent and a polymerization initiator and a polymerization accelerator can be added to the resin. For example, as curing agents, isocyanates, organic sulfonates, etc. can be added to unsaturated polyester resins, polyurethane resins, etc., organic amines, etc. can be added to epoxy resins, peroxides such as methyl ethyl ketone peroxide, azoisobutyl nitrile, etc. A radical initiator can be added to the unsaturated polyester resin.

Examples of the method for forming the surface protective layer with a thermosetting resin include a method in which a solution of a thermosetting resin is applied by a coating method such as a roll coating method or a gravure coating method and then dried and cured. The coating amount of the solution is about 12 to 50 μm, preferably about 20 to 40 μm in terms of solid content.

The ionizing radiation curable resin is not limited as long as it is a resin that undergoes a crosslinking polymerization reaction upon irradiation with ionizing radiation and changes to a three-dimensional polymer structure. For example, one or more prepolymers, oligomers, and monomers having a polymerizable unsaturated bond or epoxy group that can be cross-linked by irradiation with ionizing radiation in the molecule can be used. Examples thereof include acrylate resins such as urethane acrylate, polyester acrylate, and epoxy acrylate; silicon resins such as siloxane; polyester resins; epoxy resins and the like.

Ionizing radiation includes visible light, ultraviolet light (near ultraviolet light, vacuum ultraviolet light, etc.), X-rays, electron beams, ion beams, etc. Among them, ultraviolet light and electron beams are preferable.

As the ultraviolet light source, an ultra-high pressure mercury lamp, a high pressure mercury lamp, a low pressure mercury lamp, a carbon arc lamp, a black light fluorescent lamp, or a metal halide lamp can be used. The wavelength of ultraviolet rays is about 190 to 380 nm.

As the electron beam source, for example, various electron beam accelerators such as a cockcroft-wald type, a bandegraft type, a resonant transformer type, an insulating core transformer type, a linear type, a dynamitron type, and a high frequency type can be used. The energy of the electron beam is preferably about 100 to 1000 keV, more preferably about 100 to 300 keV. The irradiation amount of the electron beam is preferably about 2 to 15 Mrad.

The ionizing radiation curable resin is sufficiently cured when irradiated with an electron beam, but it is preferable to add a photopolymerization initiator (sensitizer) when cured by irradiation with ultraviolet rays.

Examples of the photopolymerization initiator in the case of a resin system having a radically polymerizable unsaturated group include acetophenones, benzophenones, thioxanthones, benzoin, benzoin methyl ether, Michler benzoylbenzoate, Michler ketone, diphenyl sulfide, dibenzyl disulfide. , Diethyl oxide, triphenylbiimidazole, isopropyl-N, N-dimethylaminobenzoate and the like can be used. In the case of a resin system having a cationic polymerizable functional group, for example, at least one kind such as an aromatic diazonium salt, an aromatic sulfonium salt, a metallocene compound, a benzoin sulfonic acid ester, and a freeloxysulfoxonium diallyl iodosyl salt. Can be used.

The addition amount of the photopolymerization initiator is not particularly limited, but is generally about 0.1 to 10 parts by mass with respect to 100 parts by mass of the ionizing radiation curable resin.

As a method of forming a protective layer with an ionizing radiation curable resin, for example, a solution of an ionizing radiation curable resin may be applied by a coating method such as a gravure coating method or a roll coating method. The coating amount of the solution is generally about 12 to 50 μm, preferably about 20 to 40 μm as a solid content.

In the case of further imparting scratch resistance and abrasion resistance to the surface protective layer formed from the ionizing radiation curable resin, an inorganic filler may be blended. Examples of inorganic fillers include powdered aluminum oxide, silicon carbide, silicon dioxide, calcium titanate, barium titanate, magnesium pyroborate, zinc oxide, silicon nitride, zirconium oxide, chromium oxide, iron oxide, boron nitride, Diamond, gold sand, glass fiber, etc. are mentioned.

The amount of the inorganic filler added is about 1 to 80 parts by mass with respect to 100 parts by mass of the ionizing radiation curable resin.

Lamination of each layer constituting the decorative sheet is, for example, known in the art such as a two-component curable urethane resin on the pattern layer after a pattern layer (solid ink layer, pattern ink layer) is formed in order on one side of the base sheet by printing. A transparent resin layer is laminated by a dry lamination method, a T-die extrusion method, or the like through a dry lamination adhesive, and a surface protective layer is further formed.

An uneven pattern may be formed by embossing from the surface protective layer side. The concavo-convex pattern can be formed by heating press, hairline processing or the like. Examples of the uneven pattern include a conduit groove, a stone plate surface unevenness, a cloth surface texture, a satin finish, a grain, a hairline, and a line groove.

A known adhesive can be used for laminating the decorative sheet on the wood substrate. Examples of the adhesive include polyvinyl acetate, polyvinyl chloride, vinyl chloride / vinyl acetate copolymer, ethylene / acrylic acid copolymer, ionomer, butadiene / acrylonitrile rubber, neoprene rubber, natural rubber, and the like as active ingredients. Adhesives to be used. The thickness of the adhesive layer is not limited, but is preferably about 0.1 to 50 μm.

The floor decorative material of the present invention particularly has a surface protective layer thickness of 12 to 50 μm, a Martens hardness of 50 to 150 N / mm ² , and is in contact with the decorative sheet of the wooden substrate. When the maximum density of the wood layer is 0.8 to 1.2 g / cm ³ and the average density of the wood layer in contact with the decorative sheet is 0.7 g / cm ³ or more, an excessive load is applied in daily life. Even when added (for example, when heavy furniture or a desk is dragged), the occurrence of whitening scratches and dent scratches is suppressed.

It is a figure which shows the diamond indenter (a) used for the measurement of the Martens hardness in this specification, the schematic diagram (b) of pushing operation, and an example (c) of pushing load and displacement. It is a figure which shows an example (b) of the concept of the irradiation direction of a gamma ray with respect to the wood layer used for calculation of the maximum density in this specification, the number of points (a), and the maximum density. Note that FIG. 2 is an example when a wood layer having a thickness of 12 mm is used. Since it is 12 mm, γ-ray irradiation is performed at 300 points in (a). Further, (b) is a diagram showing the density measured at the 300 points on the horizontal axis (thickness direction z) and the vertical axis (density g / cm ³ ).

Hereinafter, the present invention will be described in more detail with reference to examples and comparative examples. However, the present invention is not limited to the examples.

The following components were used as components constituting the ionizing radiation curable resin.
-Bifunctional urethane acrylate oligomer (polyol component is polyester diol, glass transition point: 25 ° C, molecular weight 1500)
-Hexafunctional aliphatic urethane acrylate oligomer (Glass transition temperature: 200 ° C or higher, molecular weight 1500, Kyoeisha Chemical Co., Ltd. UA306H)
Here, the bifunctional urethane acrylate oligomer means a urethane acrylate oligomer having two polymerizable unsaturated bonds in one molecule, and the hexafunctional urethane acrylate oligomer means a polymerizable unsaturated bond in one molecule. It means 6 urethane acrylate oligomers.

Example 1
A primer layer was provided on the back surface of a colored polypropylene film (base material sheet) having a thickness of 60 μm. Next, a pattern layer was formed on the surface of the base sheet by printing, and an adhesive layer was further formed on the pattern printing layer. A sheet of transparent polypropylene resin having a thickness of 80 μm was laminated on the adhesive layer by extrusion lamination. After the surface of the transparent polypropylene resin was subjected to corona discharge treatment, a primer layer was formed by applying a two-component curable urethane resin.

The surface is coated with 15 μm of ionizing radiation curable resin whose main component is the following composition by roll coating, and then using an electron beam irradiation device in an environment with an oxygen concentration of 200 ppm or less under the conditions of an acceleration voltage of 175 keV and 5 Mrad. A surface protective layer was formed by irradiating and curing with an electron beam to prepare a decorative sheet. The Martens hardness in the cross-sectional direction of the surface protective layer was 110 N / mm ² (average value of 10 measured values).

・ 80 parts by weight of bifunctional urethane acrylate oligomer ・ 20 parts by weight of 6 functional aliphatic urethane acrylate oligomer ・ 14 parts by weight of matting agent (11 μm silica) HDF (2.7 mm) and softwood plywood (9 mm) are combined The wood substrate was bonded to the HDF side with an adhesive (BA-10L / BA-11B) manufactured by Chuo Rika Kogyo Co., Ltd., and floor processing was performed to produce a floor decorative material 303 mm wide × 1818 mm long.

Comparative Example 1
A primer layer was provided on the back surface of a colored polypropylene film (base material sheet) having a thickness of 60 μm. Next, a pattern layer was formed on the surface of the base sheet by printing, and an adhesive layer was further formed on the pattern printing layer. A transparent polypropylene resin sheet was laminated on the adhesive layer by extrusion lamination. The surface of the 80 μm thick transparent polypropylene resin was subjected to corona discharge treatment, and then a primer layer was formed by applying a two-component curable urethane resin.

The surface is coated with 15 μm of ionizing radiation curable resin whose main component is the following composition by roll coating, and then using an electron beam irradiation device in an environment with an oxygen concentration of 200 ppm or less under the conditions of an acceleration voltage of 175 keV and 5 Mrad. A surface protective layer was formed by irradiating and curing with an electron beam to prepare a decorative sheet. The Martens hardness in the cross-sectional direction of the surface protective layer was 210 N / mm ² (average value of 10 measured values).

・ 50 parts by weight of bifunctional urethane acrylate oligomer ・ 50 parts by weight of 6 functional aliphatic urethane acrylate oligomer ・ 14 parts by weight of matting agent (11 μm silica) Combined HDF (2.7 mm) and softwood plywood (9 mm) The wood substrate was bonded to the HDF side with an adhesive (BA-10L / BA-11B) manufactured by Chuo Rika Kogyo Co., Ltd., and floor processing was performed to produce a floor decorative material 303 mm wide × 1818 mm long.

Examples 2 to 9 and Comparative Examples 2 to 11
By adjusting the content of each oligomer of Example 1 and Comparative Example 1 and changing the configuration of each layer, floor decorative materials as shown in Tables 1 to 4 were produced.

Test Example A coin scratch test and a steel ball drop test were performed on the floor decorative materials prepared in each Example and Comparative Example. Each test method and evaluation criteria are as follows.
(Coin scratch test)
A 100-yen coin inclined at 45 ° was brought into contact with the surface of the test piece, and the scratched state was evaluated when dragged in the horizontal direction while applying the following load.

3kg load, 5kg load, 7kg load Evaluation criteria are as follows.

◎: Whitening scratches and significant dents do not occur even at 7kg load.

○: Whitening and significant dents do not occur even at 5kg load.

△: No whitening or significant dents occur even at 3kg load.

X: Whitening and / or significant dents occurred at 3 kg load.
(Steel ball drop test)
A 300 g steel ball was dropped onto a test piece from a height of 50 cm, and the appearance and the amount of dents were evaluated.

○: There is no surface crack and the dent amount is 300 μm or less.

X: There is a surface crack or the dent amount is 300 μm or more.

Each evaluation result is shown in Tables 1-4.

Claims

A decorative floor material in which a decorative sheet is laminated on a wooden substrate,
(1) The decorative sheet has a surface protective layer thickness of 12 to 50 μm as an outermost layer, and a Martens hardness of the surface protective layer of 50 to 150 N / mm 2 .
(2) The wooden substrate is composed of one or more wooden layers, and the maximum density of the wooden layer in contact with the decorative sheet is 0.8 to 1.2 g / cm 3 , and The average density of the wood layer in contact with the decorative sheet is 0.7 g / cm 3 or more,
A decorative material for floors.
2. The floor decorative material according to claim 1, wherein the surface protective layer contains an ionizing radiation curable resin.
2. The floor decorative material according to claim 1, wherein the surface protective layer contains an electron beam curable resin.
4. The floor decorative material according to claim 1, wherein the surface protective layer has a thickness of 20 to 40 μm.
The flooring decorative material according to any one of claims 1 to 4, wherein the wood layer is a wood veneer, wood plywood, wood fiber board or particle board.