WO2012133201A1 - 蒸着粒子射出装置、蒸着粒子射出方法および蒸着装置 - Google Patents
蒸着粒子射出装置、蒸着粒子射出方法および蒸着装置 Download PDFInfo
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- WO2012133201A1 WO2012133201A1 PCT/JP2012/057544 JP2012057544W WO2012133201A1 WO 2012133201 A1 WO2012133201 A1 WO 2012133201A1 JP 2012057544 W JP2012057544 W JP 2012057544W WO 2012133201 A1 WO2012133201 A1 WO 2012133201A1
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- vapor deposition
- adherend
- injection
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- particles
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
- C23C14/042—Coating on selected surface areas, e.g. using masks using masks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
- B65D85/70—Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/243—Crucibles for source material
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/54—Controlling or regulating the coating process
- C23C14/541—Heating or cooling of the substrates
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/164—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using vacuum deposition
Definitions
- the present invention relates to a vapor deposition particle injection apparatus, a vapor deposition particle injection method, and a vapor deposition apparatus provided with the vapor deposition particle injection apparatus as a vapor deposition source.
- flat panel displays have been used in various products and fields, and further flat panel displays are required to have larger sizes, higher image quality, and lower power consumption.
- an organic EL display device including an organic EL element using electroluminescence (electroluminescence; hereinafter referred to as “EL”) of an organic material is an all-solid-state type, driven at a low voltage and has a high-speed response.
- EL electroluminescence
- the organic EL display device has, for example, a configuration in which an organic EL element connected to a TFT is provided on a substrate made of a glass substrate or the like provided with a TFT (thin film transistor).
- the organic EL element is a light emitting element that can emit light with high luminance by low-voltage direct current drive, and has a structure in which a first electrode, an organic EL layer, and a second electrode are stacked in this order. Of these, the first electrode is connected to the TFT.
- the organic EL layer a hole injection layer, a hole transport layer, an electron blocking layer, a light emitting layer, a hole blocking layer, an electron transport layer, an electron injection layer
- a hole injection layer a hole injection layer, a hole transport layer, an electron blocking layer, a light emitting layer, a hole blocking layer, an electron transport layer, an electron injection layer
- a full-color organic EL display device is generally formed by arranging organic EL elements of red (R), green (G), and blue (B) as sub-pixels on a substrate, and using TFTs. Image display is performed by selectively emitting light from these organic EL elements with a desired luminance.
- the organic EL element in the light emitting portion of such an organic EL display device is generally formed by stacking organic films.
- a light emitting layer made of an organic light emitting material that emits light of each color is formed in a predetermined pattern for each organic EL element that is a light emitting element.
- an inkjet method, a laser transfer method, or the like can be applied in addition to a vapor deposition method using a mask called a shadow mask.
- a shadow mask For film formation of a predetermined pattern by stacked vapor deposition, for example, an inkjet method, a laser transfer method, or the like can be applied in addition to a vapor deposition method using a mask called a shadow mask.
- a vacuum deposition method using a mask called a shadow mask it is most common to use a vacuum deposition method using a mask called a shadow mask.
- a vapor deposition source for evaporating or sublimating the vapor deposition material is disposed in a vacuum chamber capable of maintaining the inside in a reduced pressure state. To evaporate or sublimate the deposition material.
- FIG. 13 is a diagram schematically showing a vapor deposition apparatus using a limiting plate different from the vacuum vapor deposition apparatus described in Patent Document 1.
- a vapor deposition mask 1070 formed with a vapor deposition source 1060, a control block (corresponding to the vapor deposition flow control unit) 1085 composed of a plurality of control plates 1086, and a stripe-shaped opening 1071 extending in the Y-axis direction. And the vapor deposition source unit 1050. While the vapor deposition source unit 1050 is fixed, the substrate 1010 which is a vapor deposition target is moved in the Y-axis direction to form a film on the substrate 1010.
- the vapor deposition particles 1091 are attached to the vapor deposition surface of the substrate 1010 by moving the substrate 1010 in the Y-axis direction. A plurality of striped films parallel to the direction are formed.
- the vapor deposition particles 1091 emitted from the vapor deposition source opening 1061 of the vapor deposition source 1060 pass through the control block 1085 and reach the substrate 1010 through the vapor deposition mask 1070 for directivity control. It has become. As a result, the vapor deposition particles 1091 can be appropriately guided to the region to be vapor-deposited, so that vapor deposition blur does not occur.
- control block 1085 when the control block 1085 is used, a part of the vapor deposition particles 1091 emitted from the vapor deposition source opening 1061 of the vapor deposition source 1060 contributes to vapor deposition through the control block 1085. Since this is shielded by the control block 1085 and is not contributed to the vapor deposition and is wasted, there arises a problem that the vapor deposition rate is lowered.
- the heating temperature of the vapor deposition material may be increased in the vapor deposition source 1060.
- the vapor deposition material is organic, the thermal conductivity is low. Due to the delay in heat conduction, the vapor deposition material is heated more than necessary and thermally decomposes, resulting in a problem that the vapor deposition material deteriorates.
- the present invention has been made in view of the above problems, and an object of the present invention is to provide a vapor deposition particle injection device capable of improving the vapor deposition rate without heating the vapor deposition material more than necessary. is there.
- the vapor deposition particle injection apparatus includes an injection container having an injection port for injecting gaseous vapor deposition particles to the outside, and the vapor deposition material contained in the injection container and adhering the vapor deposition particles to the surface. It is characterized by comprising an adherend to be held and a heating device for heating the vapor deposition material held on the adherend surface to a temperature equal to or higher than a temperature at which the vapor deposition material becomes gaseous.
- the deposition rate can be improved.
- the larger the surface area of the adherend the more vapor deposition particles can be adhered to the surface and the vapor deposition material can be held, so that more gaseous vapor deposition particles can be obtained at one time. That is, the deposition rate can be further improved.
- the heating temperature for making the vapor deposition material held on the adherend surface gaseous is vaporized if the vapor deposition material is liquid. If the temperature and vapor deposition material are solid, the heating temperature is higher than the sublimation temperature, and a heating temperature as close as possible to these evaporation temperature and sublimation temperature is sufficient. Thereby, since it is not necessary to perform heating more than necessary to increase the vapor deposition rate, deterioration of the vapor deposition material due to excessive heating can be prevented.
- the vapor deposition rate can be improved without heating the vapor deposition material more than necessary.
- the vapor deposition particle injection apparatus is connected to a vapor deposition particle generation source that generates vapor deposition particles by heating vapor deposition material, and the vapor deposition particle generation source, and ejects the vapor deposition particles to the outside.
- An injection container having an injection port, an adherend that is contained in the injection container and holds vapor deposition material on the surface by adhering vapor deposition particles, and a surface temperature of the adherend in the injection container
- a surface temperature control device for controlling the vapor deposition material to be either a temperature lower than a temperature at which the vapor deposition material becomes gaseous or a temperature equal to or higher than a temperature at which the vapor deposition material becomes gaseous. Yes.
- the temperature at which gaseous vapor deposition particles are generated from the vapor deposition material is the evaporation temperature when the vapor deposition material is liquid, and the sublimation temperature when the vapor deposition material is solid.
- the surface temperature control device sets the surface temperature of the adherend to be lower than the temperature at which gaseous vapor deposition particles are generated from the vapor deposition material, It becomes possible to hold vapor deposition material by adhering gaseous vapor deposition particles.
- the surface temperature control device sets the surface temperature of the adherend to be higher than the temperature at which gaseous deposition particles are generated from the vapor deposition material, the vapor deposition material held on the surface of the adherend It becomes possible to generate gaseous vapor deposition particles from.
- gaseous deposition particles are attached to the surface of the adherend included in the injection container to hold the vapor deposition material, and then held on the adherend. Since vapor deposition particles are generated from the vapor deposition material, the vapor deposition material is put into a gaseous state at a time without increasing the heating temperature as compared with the case where the vapor deposition material is put in a crucible and heated to be gaseous.
- the deposition material to be increased can be increased. That is, the deposition rate can be improved.
- an injection container having an injection port for injecting gaseous vapor deposition particles to the outside, and the vapor deposition particles contained in the injection container and deposited on the surface by adhering the vapor deposition particles. Equipped with an adherend that holds the material and a heating device that heats the vapor deposition material held on the surface of the adherend to a temperature equal to or higher than the temperature at which the vapor deposition material becomes gaseous. Even if it does not heat above, there exists an effect that a vapor deposition rate can be improved.
- FIG. 1 It is a figure which shows the outline of the whole vapor deposition apparatus provided with the vapor deposition particle injection apparatus which concerns on one embodiment of this invention. It is a figure which shows the example of an arrangement
- (A)-(c) is a figure which shows the principle of adhesion of the vapor deposition particle in the heating plate shown in FIG. 2, and vapor deposition material becoming gaseous.
- (A)-(c) is a figure which shows the example of the to-be-adhered body which adheres vapor deposition particles other than the heating plate shown in FIG.
- FIG. It is a figure which shows schematic structure of the vapor deposition processing system provided with the vapor deposition particle injection apparatus shown in FIG. It is sectional drawing which shows schematic structure of the organic electroluminescent display apparatus of RGB full color display. It is sectional drawing of the TFT substrate in an organic electroluminescence display. It is a flowchart which shows the manufacturing process of an organic electroluminescence display in order of a process. It is a figure which shows the outline of the vapor deposition processing system for comparing with the vapor deposition processing system shown in FIG. It is a figure which shows the outline of the whole vapor deposition apparatus provided with the vapor deposition particle injection apparatus which concerns on other embodiment of this invention.
- FIG. 1 It is a figure which shows the outline of the vapor deposition material filling apparatus which makes vapor deposition particle adhere with respect to the heating plate unit used with the vapor deposition particle injection apparatus shown in FIG. It is a figure which shows the outline of the whole vapor deposition apparatus provided with the vapor deposition particle injection apparatus which concerns on other embodiment of this invention. It is a schematic block diagram of the vacuum evaporation system provided with the evaporation flow control part.
- FIG. 1 is a diagram showing an outline of a whole vapor deposition apparatus provided with a vapor deposition particle injection apparatus according to an embodiment of the present invention.
- the vapor deposition apparatus has a configuration in which a vapor deposition particle injection device 501 is provided as a vapor deposition source in a vacuum chamber 500 as shown in FIG.
- the vapor deposition particle injection device 501 includes a nozzle unit (injection container) 110 having a plurality of injection ports 111 and a vapor deposition particle generation unit (vapor deposition particle generation source) 120.
- the vapor deposition particle generator 120 heats the vapor deposition material 124 in the crucible 123 contained in the container 121 by a heater (heating member) 122 provided outside the container 121 to evaporate (the vapor deposition material is a liquid material). In some cases) or by sublimation (when the deposition material is a solid material), gaseous deposition particles are generated.
- the nozzle unit 110 and the vapor deposition particle generation unit 120 are connected by an introduction pipe (connection path) 130, and the vapor deposition particles generated by the vapor deposition particle generation unit 120 are introduced into the nozzle unit 110 through the introduction pipe 130. It is supposed to be.
- the introduction pipe 130 is provided with a valve 140, and the introduction of the vapor deposition particles generated from the vapor deposition particle generation unit 120 into the nozzle unit 110 can be stopped or started as necessary.
- the nozzle unit 110 includes a heating plate unit 100 including a plurality of heating plates (adhered bodies) 101 as adherends to which vapor deposition particles can adhere to the surface. Details of the heating plate unit 100 and the heating plate 101 will be described later.
- the vapor deposition particle injection device 501 is provided with a cooling device 150 for cooling the nozzle unit 110 from the outside and a heating device 160 for heating the nozzle unit 110 from the outside.
- the cooling device 150 cools the surface temperature of the heating plate 101 in the heating plate unit 100 in the nozzle unit 110 to a temperature lower than the temperature at which the vapor deposition material 124 becomes gaseous.
- the surface temperature of the heating plate 101 in the heating plate unit 100 in the nozzle unit 110 is heated to a temperature higher than the vapor temperature of the vapor deposition material 124.
- the cooling device 150 has a heat exchange member 151 for contacting the outer peripheral surface 110a of the nozzle portion 110 and removing heat from the nozzle portion 110.
- the heat exchange member 151 is provided so as to be able to be separated from the casing outer peripheral surface 110a of the nozzle portion 110. That is, when the cooling of the nozzle unit 110 is necessary, the cooling device 150 comes into contact with the casing outer peripheral surface 110a of the nozzle unit 110 and the nozzle unit 110 does not need to be cooled ( When the heating by the heating device 160 is started, the heat exchange member 151 is detached from the casing outer peripheral surface 110a of the nozzle unit 110.
- the heat exchange member 151 is driven by a driving mechanism (not shown).
- the heating device 160 is provided with a heating member such as a heater (not shown) inside the nozzle unit 110 and drives the heating member to heat the inside of the nozzle unit 110. That is, the heating device 160 drives the heating member to heat the inside of the nozzle portion 110 when the inside of the nozzle portion 110 is necessary and heats the inside of the nozzle portion 110 (the cooling device 150). When the cooling is started, the driving of the heating member is stopped.
- a heating member such as a heater (not shown) inside the nozzle unit 110 and drives the heating member to heat the inside of the nozzle unit 110. That is, the heating device 160 drives the heating member to heat the inside of the nozzle portion 110 when the inside of the nozzle portion 110 is necessary and heats the inside of the nozzle portion 110 (the cooling device 150).
- the nozzle unit 110 is cooled by the cooling device 150 and the nozzle unit 110 is heated by the heating device 160, whereby the surface temperature of the heating plate 101 in the heating plate unit 100 in the nozzle unit 110.
- the temperature is controlled so as to be lower than the temperature at which the vapor deposition material 124 becomes gaseous, and at or above the temperature at which the vapor deposition material 124 becomes gaseous. That is, the cooling device 150 and the heating device 160 function as a surface temperature control device that controls the surface temperature of the heating plate 101 in the heating plate unit 100 in the nozzle unit 110.
- the temperature at which gaseous vapor deposition particles are generated from the vapor deposition material 124 refers to the evaporation temperature of the vapor deposition material 124 (when the vapor deposition material is a liquid material) or the sublimation temperature (when the vapor deposition material is a solid material). .
- the cooling plate 150 causes the heating plate 101 to be heated. If the nozzle part 110 is cooled such that the surface temperature of the nozzle part 110 is lower than the temperature at which the vapor deposition material 124 becomes gaseous, the gaseous vapor deposition particles in the nozzle part 110 will be The vapor deposition material is held on the surface of the heating plate 101 by being attached to the surface of the heating plate 101.
- the heating plate 101 having vapor deposition particles attached to the surface and holding the vapor deposition material is referred to as a vapor deposition particle adhering body.
- the temperature of the vapor deposition particles attached to the surface of the heating plate 101 by the heating device 160 is If the nozzle part 110 is heated so that it may become more than the temperature which gaseous vapor deposition particle
- an evaporation mask 300 and a deposition target substrate (deposition target body) 200 are arranged above the vacuum chamber 500 so as to face the nozzle part 110 of the deposition particle injection device 501.
- the vapor deposition mask 300 and the deposition target substrate 200 are separated from each other, and the relative position between the vapor deposition mask 300 and the vapor deposition particle injection device 501 is constant. Accordingly, it is possible to perform the vapor deposition process by fixing any one of the vapor deposition mask 300 and the vapor deposition particle injection device 501 and the deposition target substrate 200 and moving the other in the substrate scanning direction.
- the vacuum chamber 500 includes a vacuum pump (not shown) that evacuates the vacuum chamber 500 via an exhaust port (not shown) provided in the vacuum chamber 500 in order to keep the vacuum chamber 500 in a vacuum state during vapor deposition. Is provided.
- the average free path of the vapor-deposited particles can provide a necessary and sufficient value when the degree of vacuum is higher than 1.0 ⁇ 10 ⁇ 3 Pa.
- the degree of vacuum is lower than 1.0 ⁇ 10 ⁇ 3 Pa, the mean free path is shortened, so that the vapor deposition particles are scattered, so that the arrival efficiency to the deposition target substrate 200 is reduced, and the collimating component Or less.
- the vacuum chamber 500 is set to a vacuum arrival rate of 1.0 ⁇ 10 ⁇ 4 Pa or more by a vacuum pump.
- a restriction plate 131 for restricting the flow of vapor deposition particles is disposed between the nozzle unit 110 and the vapor deposition mask 300 of the vapor deposition particle injection device 501 as necessary.
- the purpose of reducing the occurrence of vapor deposition blur (such as blurring at both ends of a stripe-shaped film) caused by the diffusion of vapor deposition particles, such as when the light emitting layer constituting the organic EL layer of the organic EL element is separately applied The restriction plate 131 is disposed.
- the vapor deposition material 124 is heated by the heater (heating member) 122 provided in the vapor deposition particle generation unit 120 to evaporate (when the vapor deposition material is a liquid material) or sublimate (the vapor deposition material is a solid material). In some cases, gaseous deposition particles are generated.
- the vapor deposition particles generated by the vapor deposition particle generation unit 120 are guided to the nozzle unit 110 that is being cooled by the cooling device 150 via the introduction pipe 130 connected to the vapor deposition particle generation unit 120, and each heating plate unit 100 is heated. It is attached to the surface of the plate 101. After that, the nozzle unit 110 is heated by the heating device 160, whereby the vapor deposition material held on the surface of each heating plate 101 of the heating plate unit 100 becomes a gaseous state and is mixed in the nozzle unit 110. From the injection ports 111 arranged in a line shape, the light is emitted to the outside toward the film formation substrate 200.
- the vapor deposition particles injected to the outside from the vapor deposition particle injection device 501 adhere to the deposition target substrate 200 through the vapor deposition mask 300. Thereby, a vapor deposition film is formed on the surface of the deposition target substrate 200. At this time, vapor deposition particles adhere to the deposition target substrate 200 through the vapor deposition mask 300, whereby a pattern of the vapor deposition film is formed.
- the vapor deposition mask 300 has an opening 301 (through hole) formed in a desired position and shape, and only vapor deposition particles passing through the vapor deposition mask 300 reach the deposition target substrate 200 to form a vapor deposition film pattern.
- a mask (open mask) having an opening 301 for each pixel is used.
- a mask (open mask) having an entire display area is used.
- An example of forming each pixel is a light emitting layer, and an example of forming it on the entire display region is a hole transport layer.
- the evaporation mask 300 has a size smaller than a deposition region of the deposition substrate 200 and is provided on the deposition surface 201 of the deposition substrate 200 so as to be separated from each other.
- a case will be described as an example.
- the vapor deposition mask 300 may be tightly fixed to the deposition target substrate 200 by a fixing unit (not shown), and has a size corresponding to the deposition target region in the deposition target substrate 200 (for example, the same size in plan view). May be.
- the vapor deposition mask 300 can be omitted.
- the vapor deposition mask 300 can be selectively provided, and may be one of the components constituting the vapor deposition apparatus as an accessory of the vapor deposition apparatus, or it may not be.
- FIG. 2 is a diagram illustrating an arrangement example of the heating plates 101 in the heating plate unit 100.
- a plurality of heating plates 101 are arranged in parallel as shown in FIG.
- the surfaces of the respective heating plates 101 can be maintained in a state where they are not in contact with each other.
- a linear space connected to the injection port 111 can be eliminated in the nozzle 110. Therefore, the vapor deposition particles guided to the nozzle 110 from the vapor deposition particle generator 120 through the introduction pipe 130 are prevented from being discharged from the injection port 111 to the vacuum chamber without coming into contact with the surface 101a of the heating plate 101. be able to. In other words, the probability that the vapor deposition particles 91 are attached to the surface 101a of the heating plate 101 increases.
- FIGS. 3 (a) to 3 (c) are diagrams illustrating a process until vapor deposition particles are attached to the heating plate 101 and the vapor deposition material is held, and the held vapor deposition material becomes gaseous. is there.
- the vapor deposition particles adhere to the surface 101a of the heating plate 101 as shown in FIG. 3A, and almost the entire surface 101a of the heating plate 101 as shown in FIG. 3B.
- the vapor deposition particles 91 adhere to the surface.
- the temperature of the surface 101 a of the heating plate 101 is set to a temperature lower than the temperature at which the vapor deposition material 124 becomes gaseous by the cooling of the nozzle unit 110 by the cooling device 150. . That is, the temperature of the surface 101 a of the heating plate 101 is set to a temperature lower than the evaporation temperature or the sublimation temperature of the vapor deposition material 124. For this reason, gaseous vapor deposition particles adhere to the surface 101a of the heating plate 101, and are hold
- the vapor deposition particles also adhere to the inner wall surface of the nozzle portion 110 in the vicinity of the heating plate unit 100.
- the vapor deposition particles do not adhere to the inner wall surface in the vicinity thereof. In other words, the introduction pipe 130 is not clogged.
- the vapor deposition particles need only be adhered to the surface 101a of the heating plate 101 in the stage of deposition of the vapor deposition particles on the heating plate 101, the vapor deposition rate of the vapor deposition particles from the vapor deposition particle generating unit 120 to the nozzle unit 110 is high. do not have to.
- the temperature of the surface 101 a of the heating plate 101 is set to a temperature equal to or higher than the temperature at which gaseous vapor deposition particles are generated from the vapor deposition material 124 by the heating of the nozzle unit 110 by the heating device 160.
- the temperature of the surface 101 a of the heating plate 101 is set to a temperature equal to or higher than the evaporation temperature or the sublimation temperature of the vapor deposition material 124. For this reason, the vapor deposition particles 91 adhering to the surface 101a of the heating plate 101 are emitted again as gaseous vapor deposition particles.
- the heating temperature for the vapor deposition particles 91 is changed from at least the vapor deposition material 124 to the gaseous vapor deposition particles. If the heating plate 101 is heated to a temperature equal to or higher than the temperature at which water vapor is generated, high-density vapor deposition particles can be released. As a result, the vapor deposition rate of the vapor deposition particles emitted from the heating plate 101 is improved.
- gaseous vapor deposition particles are once attached to the surface 101a of the heating plate 101, and the heating plate 101 is heated, so that a high vapor deposition rate is obtained from the injection port 111 of the nozzle unit 110. It becomes possible to inject the deposited particles.
- the internal structure of the heating plate unit 100 is not limited to a structure in which a plurality of plate-like heating plates 101 are arranged in parallel, and can have various shapes. The larger the surface area, the better.
- 4 (a) to 4 (c) are diagrams showing examples other than the heating plate as an adherend to which vapor deposition particles can adhere to the surface.
- a fin-like member as shown in FIG. 4A As an adherend, a fin-like member as shown in FIG. 4A, a mesh-like member as shown in FIG. 4B, a mesh member as shown in FIG. Examples thereof include a member having a fractal surface as shown. Also, a sponge-like member or the like may be used.
- the fractal in the fractal surface shown in FIG. 4C is a geometric concept indicating that the graphic part and the whole have a self-similar shape. By intentionally forming a surface having properties, the surface area can be increased.
- FIGS. 4 (a) to 4 (c) their shapes are described in a plane, but it is of course more preferable to form them three-dimensionally.
- the adherend constituting the heating plate unit 100 preferably has a shape having a surface area as large as possible, and the material is a material that easily transmits heat (for example, titanium, tungsten, SUS, or the like). Metal) is preferred.
- FIG. 5 is a diagram showing a schematic configuration of the vapor deposition processing system according to the present embodiment.
- the vapor deposition particle injection device 501 and the vapor deposition mask are fixed, and the film formation substrate 200 is moved (scanned) in the upward direction on the paper (in the direction orthogonal to the arrangement direction of the injection ports 111). Perform scan deposition.
- the deposition target substrate 200 is fixed, and the vapor deposition particle injection device 501 is moved in a direction orthogonal to the direction in which the injection ports 111 are arranged to perform scan vapor deposition.
- the vapor deposition processing system includes vapor deposition particle injection devices 501 arranged in parallel in the relative scanning direction of the deposition target substrate 200, and among these six columns of vapor deposition particle injection devices 501. Is integrated with the vapor deposition mask 300 to form a vapor deposition source unit 600. Only the vapor deposition particle injection device 501 constituting the vapor deposition source unit 600 indicates that the vapor deposition particles are in an injection state (deposition state), and the remaining five vapor deposition particle injection devices 501 are in a non-injection state (non-deposition state). It shows that there is.
- the heat exchange member 151 of the cooling device 150 provided in each vapor-deposited particle injection device 501 is divided into four blocks along the outer peripheral surface 110a of the nozzle unit 110 as shown in FIG. Yes.
- the heat exchange members 151 of these four blocks are separated from the casing outer peripheral surface 110a of the nozzle unit 110 during the vapor deposition operation (when heated by the heating device 150), and during the non-vapor deposition operation (when cooled by the cooling device). Is driven by a drive circuit (not shown) so as to be in close contact with the outer peripheral surface 110a of the casing of the nozzle unit 110.
- the vapor deposition particle injection device 501 in the first row constituting the vapor deposition source unit 600 is in the vapor deposition operation state, and the vapor deposition particle injection devices 501 for the remaining five columns are in the non-vapor deposition operation state. That is, in the vapor deposition particle injection device 501 constituting the vapor deposition source unit 600, the heat exchange members 151 of the four blocks are all separated from the casing outer peripheral surface 110a of the nozzle unit 110, and the remaining vapor deposition particle injection devices 501 are placed. Is in a state where all the heat exchange members 151 of the four blocks are in close contact with the outer peripheral surface 110a of the casing of the nozzle unit 110.
- vapor deposition particle injection device 501 constituting the vapor deposition source unit 600 actually performs vapor deposition on the deposition target substrate 200. That is, as shown in FIG. 5, among the six rows of vapor deposition particle injection devices 501, only one row of vapor deposition particle injection devices 501 ejects vapor deposition particles from the injection port 111 of the nozzle unit 110.
- vapor deposition source unit 600 is used as the vapor deposition particle injection apparatus 501 in the next row and vapor deposition is performed.
- the relative position between the vapor deposition particle injection device 501 and the vapor deposition mask 300 is constant.
- the deposition target substrate 200 moves in one direction (in the direction of the arrow in the figure) at a constant speed on the opposite side of the vapor deposition mask 300 from the vapor deposition particle injection device 501.
- On the upper surface of the vapor deposition particle injection device 501 a plurality of injection ports 111 each for discharging vapor deposition particles are formed, and the vapor deposition mask 300 has a plurality of openings 301 (mask openings (reference numeral 301 in FIG. 1)). Is formed.
- the vapor deposition particles emitted from the injection port 111 pass through the mask opening and adhere to the deposition target substrate 200.
- the light emitting layers 23R, 23G, and 23B are separately applied by repeatedly performing vapor deposition for each color of the light emitting layers 23R, 23G, and 23B constituting the organic EL layer (FIG. 7). Vapor deposition can be performed.
- FIG. 6 is a cross-sectional view showing a schematic configuration of the organic EL display device 1 for RGB full-color display.
- the organic EL display device 1 manufactured in the present embodiment includes an organic EL element 20 connected to the TFT 12 and an adhesive layer on the TFT substrate 10 on which the TFT 12 (see FIG. 7) is provided. 30 and the sealing substrate 40 have the structure provided in this order.
- the organic EL element 20 includes a pair of substrates (TFT substrates) by bonding the TFT substrate 10 on which the organic EL element 20 is laminated to a sealing substrate 40 using an adhesive layer 30. 10 and the sealing substrate 40).
- TFT substrates substrates
- the organic EL element 20 is sealed between the TFT substrate 10 and the sealing substrate 40 in this way, so that oxygen or moisture can enter the organic EL element 20 from the outside. It is prevented.
- FIG. 7 is a cross-sectional view showing a schematic configuration of the organic EL element 20 constituting the display unit of the organic EL display device 1.
- the TFT substrate 10 has a configuration in which a TFT 12 (switching element) and wiring 14, an interlayer insulating film 13, an edge cover 15 and the like are formed on a transparent insulating substrate 11 such as a glass substrate. ing.
- the organic EL display device 1 is a full-color active matrix type organic EL display device.
- red (R), green (G), blue On the insulating substrate 11, red (R), green (G), blue ( The pixels 2R, 2G, and 2B of the respective colors including the organic EL elements 20 of the respective colors B) are arranged in a matrix.
- the TFTs 12 are provided corresponding to the respective pixels 2R, 2G, and 2B.
- the structure of the TFT is conventionally well known. Therefore, illustration and description of each layer in the TFT 12 are omitted.
- the interlayer insulating film 13 is laminated over the entire area of the insulating substrate 11 on the insulating substrate 11 so as to cover each TFT 12 and the wiring 14.
- the first electrode 21 in the organic EL element 20 is formed on the interlayer insulating film 13.
- the interlayer insulating film 13 is provided with a contact hole 13 a for electrically connecting the first electrode 21 in the organic EL element 20 to the TFT 12. Thereby, the TFT 12 is electrically connected to the organic EL element 20 through the contact hole 13a.
- the edge cover 15 prevents the first electrode 21 and the second electrode 26 in the organic EL element 20 from being short-circuited when the organic EL layer becomes thin or the electric field concentration occurs at the end of the first electrode 21.
- This is an insulating layer.
- the edge cover 15 is formed on the interlayer insulating film 13 so as to cover the end of the first electrode 21.
- the first electrode 21 is exposed at a portion where the edge cover 15 is not provided as shown in FIG. This exposed portion becomes the light emitting portion of each pixel 2R, 2G, 2B.
- each of the pixels 2R, 2G, and 2B is partitioned by the edge cover 15 having an insulating property.
- the edge cover 15 also functions as an element isolation film.
- insulating substrate 11 for example, non-alkali glass or plastic can be used.
- alkali-free glass having a thickness of 0.7 mm is used.
- the interlayer insulating film 13 and the edge cover 15 a known photosensitive resin can be used.
- the photosensitive resin include acrylic resin and polyimide resin.
- the TFT 12 is manufactured by a known method.
- the active matrix organic EL display device 1 in which the TFT 12 is formed in each of the pixels 2R, 2G, and 2B is taken as an example.
- the present embodiment is not limited to this, and the present invention can also be applied to the manufacture of a passive matrix organic EL display device in which TFTs are not formed.
- the organic EL element 20 is a light emitting element that can emit light with high luminance by low voltage direct current drive, and a first electrode 21, an organic EL layer, and a second electrode 26 are laminated in this order.
- the first electrode 21 is a layer having a function of injecting (supplying) holes into the organic EL layer. As described above, the first electrode 21 is connected to the TFT 12 via the contact hole 13a.
- the electron transport layer 24, and the electron injection layer 25 have the structure formed in this order.
- a carrier blocking layer for blocking the flow of carriers such as holes and electrons may be inserted as necessary.
- One layer may have a plurality of functions. For example, one layer serving as both a hole injection layer and a hole transport layer may be formed.
- the stacking order is that in which the first electrode 21 is an anode and the second electrode 26 is a cathode.
- the stacking order of the organic EL layers is reversed.
- the hole injection layer is a layer having a function of increasing the efficiency of hole injection from the first electrode 21 to the organic EL layer.
- the hole transport layer is a layer having a function of improving the efficiency of transporting holes to the light emitting layers 23R, 23G, and 23B.
- the hole injection layer / hole transport layer 22 is uniformly formed on the entire display region of the TFT substrate 10 so as to cover the first electrode 21 and the edge cover 15.
- the hole injection layer / hole transport layer 22 in which the hole injection layer and the hole transport layer are integrated is provided as the hole injection layer and the hole transport layer. ing.
- this embodiment is not limited to this, and the hole injection layer and the hole transport layer may be formed as independent layers.
- light emitting layers 23R, 23G, and 23B are formed corresponding to the pixels 2R, 2G, and 2B, respectively.
- the light emitting layers 23R, 23G, and 23B are layers having a function of emitting light by recombining holes injected from the first electrode 21 side and electrons injected from the second electrode 26 side.
- the light emitting layers 23R, 23G, and 23B are each formed of a material having high light emission efficiency, such as a low molecular fluorescent dye or a metal complex.
- the electron transport layer 24 is a layer having a function of increasing the electron transport efficiency to the light emitting layers 23R, 23G, and 23B.
- the electron injection layer 25 is a layer having a function of increasing the electron injection efficiency from the second electrode 26 to the organic EL layer.
- the electron transport layer 24 is formed on the light emitting layer 23R / 23G / 23B and the hole injection layer / hole transport layer 22 so as to cover the light emitting layer 23R / 23G / 23B and the hole injection layer / hole transport layer 22.
- the TFT substrate 10 is formed uniformly over the entire display area.
- the electron injection layer 25 is uniformly formed on the entire surface of the display region of the TFT substrate 10 on the electron transport layer 24 so as to cover the electron transport layer 24.
- the electron transport layer 24 and the electron injection layer 25 may be formed as independent layers as described above, or may be provided integrally with each other. That is, the organic EL display device 1 may include an electron transport layer / electron injection layer instead of the electron transport layer 24 and the electron injection layer 25.
- the second electrode 26 is a layer having a function of injecting electrons into the organic EL layer composed of the organic layers as described above.
- the second electrode 26 is uniformly formed on the entire surface of the display region of the TFT substrate 10 on the electron injection layer 25 so as to cover the electron injection layer 25.
- organic layers other than the light emitting layers 23R, 23G, and 23B are not essential layers as the organic EL layer, and may be appropriately formed according to the required characteristics of the organic EL element 20.
- one layer may have a plurality of functions.
- a carrier blocking layer can be added to the organic EL layer as necessary.
- a carrier blocking layer as a carrier blocking layer between the light emitting layers 23R, 23G, and 23B and the electron transport layer 24, the holes are prevented from falling out to the electron transport layer 24, and the light emission efficiency is improved. can do.
- layers other than the first electrode 21 (anode), the second electrode 26 (cathode), and the light emitting layers 23R, 23G, and 23B may be inserted as appropriate.
- the first electrode 21 is formed by patterning corresponding to the individual pixels 2R, 2G, and 2B by photolithography and etching after an electrode material is formed by sputtering or the like.
- the first electrode 21 various conductive materials can be used. However, in the case of a bottom emission type organic EL element that emits light toward the insulating substrate 11, it needs to be transparent or translucent.
- the second electrode 26 needs to be transparent or translucent.
- Examples of the conductive film material used for the first electrode 21 and the second electrode 26 include ITO (Indium Tin Oxide), IZO (Indium Zinc Oxide), and gallium-doped zinc oxide (A transparent conductive material such as GZO) or a metal material such as gold (Au), nickel (Ni), or platinum (Pt) can be used.
- ITO Indium Tin Oxide
- IZO Indium Zinc Oxide
- a transparent conductive material such as GZO
- a metal material such as gold (Au), nickel (Ni), or platinum (Pt) can be used.
- a sputtering method a vacuum vapor deposition method, a CVD (chemical vapor deposition) method, a plasma CVD method, a printing method, or the like can be used.
- a vapor deposition apparatus according to this embodiment to be described later may be used for the lamination of the first electrode 21.
- Each of the light emitting layers 23R, 23G, and 23B may be a single material, or a mixed material in which a certain material is used as a host material and another material is mixed as a guest material or a dopant. .
- Examples of the material of the hole injection layer, the hole transport layer, or the hole injection layer / hole transport layer 22 include anthracene, azatriphenylene, fluorenone, hydrazone, stilbene, triphenylene, benzine, styrylamine, triphenylamine, and porphyrin. , Triazole, imidazole, oxadiazole, oxazole, polyarylalkane, phenylenediamine, arylamine, and derivatives thereof, thiophene compounds, polysilane compounds, vinylcarbazole compounds, aniline compounds, etc. Examples thereof include conjugated monomers, oligomers, and polymers.
- a material having high light emission efficiency such as a low molecular fluorescent dye or a metal complex is used.
- a material having high light emission efficiency such as a low molecular fluorescent dye or a metal complex.
- Examples of the material of the electron transport layer 24, the electron injection layer 25, or the electron transport layer / electron injection layer include tris (8-quinolinolato) aluminum complex, oxadiazole derivative, triazole derivative, phenylquinoxaline derivative, silole derivative and the like. Can be mentioned.
- the TFT substrate 10 is used as a film formation substrate (film formation object), an organic light emitting material is used as a vapor deposition material, and the first electrode 21 is formed on the film formation substrate.
- an organic EL layer is formed as a vapor deposition film using a vacuum vapor deposition method will be described as an example.
- Pixels 2R, 2G, and 2B are arranged in a matrix.
- each color of cyan (C), magenta (M), and yellow (Y) is used instead of the light emitting layers 23R, 23G, and 23B of red (R), green (G), and blue (B), for example, each color of cyan (C), magenta (M), and yellow (Y) is used. You may have a light emitting layer, and you may have the light emitting layer of each color which consists of red (R), green (G), blue (B), and yellow (Y).
- color images are displayed by selectively emitting these organic EL elements 20 with a desired luminance using the TFT 12.
- the organic EL display device 1 in order to manufacture the organic EL display device 1, it is necessary to form a light emitting layer made of an organic light emitting material that emits light of each color in a predetermined pattern for each organic EL element 20 on the deposition target substrate. is there.
- the vapor deposition mask 300 has the opening 301 at a desired position and shape. As shown in FIG. 1, the vapor deposition mask 300 is disposed apart from the film formation surface 201 of the film formation substrate 200.
- a vapor deposition particle injection device 501 is disposed as a vapor deposition source so as to face the film formation surface 201 of the film formation substrate 200.
- the organic light emitting material is emitted from the injection port 111 of the nozzle unit 110 as gaseous vapor deposition particles by heating under high vacuum to vaporize or sublimate to form a gas. .
- the vapor deposition material injected from the injection port 111 of the nozzle unit 110 as vapor deposition particles is vapor deposited on the deposition target substrate 200 through the opening 301 provided in the vapor deposition mask 300.
- an organic film having a desired film formation pattern is vapor-deposited as a vapor deposition film only at a desired position of the film formation substrate 200 corresponding to the opening 301 of the vapor deposition mask 300.
- vapor deposition is performed for every color of a light emitting layer (this is called "separate vapor deposition").
- FIG. 8 is a flowchart showing manufacturing steps of the organic EL display device 1 in the order of steps.
- the TFT substrate 10 is fabricated, and the first electrode 21 is formed on the fabricated TFT substrate 10 (S101).
- the TFT substrate 10 can be manufactured using a known technique.
- a hole injection layer and a hole transport layer are formed over the entire pixel region by vacuum deposition using an open mask as the deposition mask 300.
- the hole injection layer and the hole transport layer can be the hole injection layer / hole transport layer 22 as described above.
- the light emitting layers 23R, 23G, and 23B are separately deposited by vacuum vapor deposition (S103). Thereby, a pattern film corresponding to each pixel 2R, 2G, and 2B is formed.
- the electron transport layer 24, the electron injection layer 25, and the second electrode 26 are sequentially formed on the TFT substrate 10 on which the light emitting layers 23R, 23G, and 23B are formed, using the open mask as the vapor deposition mask 300.
- the entire pixel region is formed (S104 to S106).
- the region (display unit) of the organic EL element 20 is sealed so that the organic EL element 20 is not deteriorated by moisture or oxygen in the atmosphere with respect to the substrate on which vapor deposition has been completed (S107). .
- Sealing includes a method of forming a film that does not easily transmit moisture or oxygen by a CVD method or the like, and a method of bonding a glass substrate or the like with an adhesive or the like.
- the organic EL display device 1 is manufactured by the process as described above.
- the organic EL display device 1 can perform desired display by causing a current to flow from the driving circuit formed outside to the organic EL element 20 in each pixel to emit light.
- the first point is a decrease in the deposition rate by a mechanism that controls the deposition flow such as a limiting plate. For example, if only 1/10 of the vapor deposition flow is contributed to vapor deposition by the limiting plate, the vapor deposition rate is reduced to 1/10. For example, when the vapor deposition flow is injected from the injection port of the vapor deposition source at a vapor deposition rate of 1 nm / s, the vapor deposition rate of the vapor deposition material actually deposited on the substrate is 0.1 nm / s.
- the second point is that a high deposition rate is required in principle. That is, in the scan deposition, since the film is formed on the substrate only while passing over the opening of the small deposition mask, the length of the deposition mask in the scanning direction is divided by the scanning speed of the substrate. Only vapor deposited. For example, when the opening length of the vapor deposition mask in the scanning direction is 150 mm and the scanning speed of the substrate is 15 mm / s, the total vapor deposition time for a certain area of the substrate is 10 s. If the length of the substrate is 750 mm, the time required for vapor deposition on the entire surface of the substrate is 50 s.
- the vapor deposition rate is lowered due to the above-mentioned first problem, while a high vapor deposition rate is necessary due to the second problem.
- the total deposition time can be increased by a number of scanning processes, and a sufficient deposition film thickness can be obtained even at a low deposition rate, but the processing tact (total time required from substrate loading to dispensing) Becomes longer.
- the vapor deposition material is generally supplied in the form of powder or lump to the crucible in the vapor deposition source.
- the temperature rise of the material depends on the thermal conductivity of the material.
- Organic materials used for organic EL elements generally have a lower thermal conductivity than metals. Therefore, only the vapor deposition material in the vicinity of the inner wall of the crucible is excessively heated until the entire vapor deposition material is sufficiently heated, and deterioration due to thermal decomposition occurs. Therefore, there is a limit in improving the deposition rate by increasing the heating temperature. For example, if the deposition rate injected from the outlet of the deposition source in the above-mentioned example can be increased up to 10 nm / s without thermal degradation by increasing the heating temperature, the net deposition rate on the substrate is 1 nm / s. .
- FIG. 9 is a diagram showing an outline of a vapor deposition processing system for comparison with the vapor deposition processing system shown in FIG.
- the deposition target substrate 200 is moved in the substrate scanning direction by using six rows of vapor deposition sources 700, and vapor deposition is simultaneously performed by the five rows of vapor deposition sources 700.
- the necessary vapor deposition rate (5 nm / s) described in the second problem described above can be obtained.
- the remaining one row of vapor deposition sources 700 is used for exchanging vapor deposition materials and is in a standby state.
- the vapor deposition material is exhausted in one row of the vapor deposition source 700, another row is operated as an alternative, during which the vapor deposition material is re-supplied, and the re-supplied vapor deposition source 700 is put into a standby state instead. .
- the vapor deposition source 700 is formed integrally with the vapor deposition mask, the same number of vapor deposition masks are required as the vapor deposition source 700 increases.
- the vapor deposition mask requires high precision and fine opening processing and is expensive, leading to an increase in equipment cost.
- the evaporation source unit includes a mechanism for fixing the evaporation source and the evaporation mask, a heater, and the like, it is much heavier than the substrate, and the alignment mechanism becomes complicated and large, which is also expensive. It becomes a factor. In addition, since the inertial force increases, the alignment accuracy also decreases.
- vapor deposition flows are simultaneously ejected from a plurality of vapor deposition sources 700, a vapor deposition material is lost while the deposition target substrate 200 is not on the vapor deposition mask corresponding to the vapor deposition source 700.
- the deposition rate can be improved if the deposition flow restriction by the restriction plate is relaxed, but this is not realistic.
- loosening the restriction of the vapor deposition flow by the limiting plate means that the vapor deposition blur (the width formed by the vapor deposition film extending beyond the opening width of the vapor deposition mask) increases, the injection port, the restriction plate, the substrate,
- variations in the film thickness, position, width, etc. of the vapor deposition film pattern due to positional deviation of the vapor deposition mask opening and the like and shape accuracy increase. Since such a problem arises, it becomes difficult to form a highly accurate vapor deposition film pattern. As a result, a large-sized or high-definition organic EL display device cannot be manufactured, or the yield decreases.
- the vapor deposition apparatus can solve various problems that occur in the scan vapor deposition described above.
- the vapor deposition particle injection devices 501 are arranged in six rows in parallel in the relative scanning direction of the deposition target substrate 200. Only the vapor deposition particle injection device 501 for injecting the vapor deposition particles is integrated with the vapor deposition mask 300 to constitute the vapor deposition source unit 600. In the vapor deposition processing system shown in FIG. 9, vapor deposition particles are simultaneously ejected from five rows of vapor deposition sources 700 out of six rows of vapor deposition sources 700, whereas in the example shown in FIG. Vapor deposition particles are injected only from the apparatus 501. The remaining five rows of vapor deposition particle injection devices 501 do not inject vapor deposition particles.
- the vapor deposition particles attached to the surface 101 a of the heating plate 101 constituting the heating plate unit 100 included in the nozzle unit 110 in the vapor deposition particle emitting device 501 heat the heating plate 101. Released.
- the temperature for vapor deposition at this time may be lower than the temperature at which the crucible 123 is heated in the vapor deposition particle generation unit 120. This is because the vapor deposition particles are not a lump but adhere to the surface 101a of the heating plate 101 so that heat is easily transmitted.
- the temperature of the vapor deposition particles adhering to the surface 101a of the heating plate 101 needs to be heated to the evaporation temperature or the sublimation temperature of the vapor deposition material 124, it is released from the heating plate 101 without raising the temperature so much.
- the vapor deposition rate when the vapor deposition particles to be ejected from the ejection port 111 of the nozzle unit 110 can be increased.
- the vapor deposition rate may be set.
- the vapor deposition source unit 600 by heating the nozzle unit 110 in the vapor deposition particle injection device 501, 50 nm / s can be obtained as the vapor deposition rate of the vapor deposition particles injected from the injection port 111 of the nozzle unit 110, 5 nm / s can be obtained as the deposition rate on the net deposition target substrate 200 through the limiting plate 131.
- the vapor deposition material 124 is gasified from the vapor deposition particle generation unit 120 (FIG. 1) to the nozzle unit 110 (FIG. 1) at 10 nm / s.
- the deposited particles are supplied.
- These are simultaneously supplied to the nozzles 110 of the five rows of vapor deposition particle injection devices 501.
- the inner surface of the heating plate unit 100 included in the nozzle unit 110 and the peripheral nozzle unit 110 are cooled, and vapor deposition particles adhere to the surfaces thereof.
- the five rows of vapor deposition particle injection devices 501 that are not injecting the vapor deposition particles have the vapor deposition particle adhering body (heating plate) with the vapor deposition particles adhered inside. 101 with a vapor deposition material held on the surface 101).
- each vapor deposition particle injection device 501 constitutes the vapor deposition source unit 600
- the nozzle unit 110 is heated to obtain 50 nm / s as the vapor deposition rate of the vapor deposition particles emitted from the injection port 111. 5 nm / s can be obtained as the deposition rate on the net substrate that has undergone the above. This is the desired deposition rate as described above.
- the vapor deposition rate of the vapor deposition particles is five times, so that the time until the vapor deposition material 124 is completely consumed is 1/5 of the conventional time.
- the six rows of vapor deposition particle injection devices 501 are sequentially used one by one, the vapor deposition material 124 can be supplied to the nozzle unit 110 again while another vapor deposition particle injection device 501 is being used.
- Such a procedure can solve various problems (deterioration of the material due to an increase in the deposition rate and an increase in the heating temperature) that occur in the above-described deposition processing system shown in FIG.
- one vapor deposition mask 300 is sufficient because the vapor deposition particles are ejected from one vapor deposition particle injection device 501. Therefore, not only the number of vapor deposition masks 300 equal to the number of vapor deposition particle injection devices 501 is required, but the deposition mask 300 and the deposition substrate 200 are aligned by moving the deposition substrate 200 side instead of the deposition source unit 600 side. It is possible to suppress the complexity and cost increase of the alignment mechanism. In addition, for this reason, it is also easy to increase the number of vapor deposition particle injection devices 501 arranged in parallel.
- the heating member such as the heating plate 101 constituting the heating plate unit 100 in the nozzle unit 110 of the vapor deposition particle injection apparatus 501 serving as the vapor deposition source in advance.
- the deposition material is fixed to the surface 101a of the structure having a large surface area.
- the vapor deposition particle adhering body which vapor deposition particle adhered to the surface and hold
- this vapor deposition particle adhesion body be a sub vapor deposition particle generation part different from vapor deposition particle generation part 120.
- the deposition rate is improved by heating the sub-evaporated particle generating part at once. Thereby, the following effects are acquired.
- the vapor deposition material held on the surface of the sub vapor deposition particle generating portion can be heated quickly and uniformly without depending on the thermal conductivity of the vapor deposition material, the vapor deposition rate can be improved even at a low temperature. Moreover, thermal deterioration of the vapor deposition material can be suppressed.
- the vapor deposition material held on the heating plate 101 is removed from the step of attaching the vapor deposition particles to the heating plate 101 using the cooling device 150 and the heating device 160 inside the vapor deposition particle injection device 501.
- the heating process to make the gas again is performed, but the present invention is not limited to this.
- the process of attaching the vapor deposition particles to the heating plate 101 is performed by another apparatus, and the vapor deposition particles adhered to the heating plate 101. Only the heating process for making the gas again gaseous may be performed.
- the step of attaching vapor deposition particles to a heating plate and holding the vapor deposition material on the surface of the heating plate is performed by another device, and the vapor deposition material held by the heating plate is made gaseous again
- a vapor deposition particle injection apparatus that performs only the above will be described.
- FIG. 10 is a diagram showing an outline of the entire vapor deposition apparatus including the vapor deposition particle injection apparatus according to another embodiment of the present invention.
- the vapor deposition apparatus includes a vapor deposition particle injection device 502 having a nozzle unit (vapor deposition particle injection unit) 110 having a plurality of injection ports 111 as a vapor deposition source in a vacuum chamber 500. .
- the configuration of the vapor deposition particle injection device 502 is basically the same as that of the vapor deposition particle injection device 501 described in the first embodiment, but the vapor deposition particles are applied to the heating plate 101 of the heating plate unit 100 within the nozzle unit 110. It differs in that it is not designed to adhere.
- the deposition particles are attached to the heating plate 101 of the heating plate unit 100 in the vapor deposition material filling device 180 (FIG. 11) separately provided outside the vacuum chamber 500. Therefore, in the present embodiment, the vapor deposition particle injection system 502 is configured by the vapor deposition particle injection device 502 as the vapor deposition source and the vapor deposition material filling device 180. Details of the vapor deposition material filling device 180 will be described later.
- the heating plate unit 100 is formed into a cartridge and is detachable from the nozzle unit 110, as in the vapor deposition particle injection device 501 of the first embodiment.
- the heating plate 101 to which the vapor deposition particles as the particle generation unit are attached is heated by the heating device 160 so that the held vapor deposition material is made gaseous again, and the gaseous vapor deposition particles are ejected from the injection port 111 to the outside. It has become.
- the same effects as in the first embodiment that is, (1) because the vapor deposition particles adhering to the surface of the sub vapor deposition particle generating portion can be heated quickly and uniformly without depending on the thermal conductivity of the vapor deposition material.
- the deposition rate can be improved even at a low temperature. Moreover, thermal deterioration of the vapor deposition material can be suppressed.
- the vapor deposition material filling device 180 has substantially the same configuration as the vapor deposition particle injection device 501 shown in FIG. 1 of the first embodiment, and instead of the nozzle unit 110 including the heating plate unit 100. The difference is that a heating container (filling container) 170 containing the heating plate unit 100 is provided. However, the vapor deposition material filling device 180 is also the same in that vapor deposition particles adhere to the surface of the heating plate 101 of the heating plate unit 100, similarly to the vapor deposition particle injection device 501.
- the procedure for attaching the vapor deposition particles to the surface of the heating plate 101 of the heating plate unit 100 is the same as that in the first embodiment.
- the heating container 170 is heated to such an extent that the vapor deposition material does not adhere by the heating device 161, while the heating plate unit 100 is cooled by the cooling device 150 so that the vapor deposition material adheres. Therefore, in the heating container 170, temperature adjustment is performed so that gaseous vapor deposition particles supplied from the vapor deposition particle generation unit 120 to the introduction tube 130 can adhere to only the heating plate unit 100 as much as possible.
- the heating plate unit 100 is adapted to attach the vapor deposition particles not only to the heating plate 101 but also to a cartridge-like casing (not shown) constituting the heating plate unit 100. Thereby, in addition to the vapor deposition particles adhering to the heating plate 101, the vapor deposition particles adhering to the cartridge-like casing constituting the heating plate unit 100 can be made into a gas state at once. The deposition rate can be further improved.
- the heating plate unit 100 on which the deposition of the vapor deposition particles has been completed is taken out from the vapor deposition material filling device 180 and inserted into the nozzle portion 110 of the vapor deposition particle injection device 502 in the vacuum chamber 500. Thereafter, the nozzle unit 110 is heated by the heating device 160, whereby the vapor deposition material held on the heating plate 101 of the heating plate unit 100 becomes gaseous again, and gaseous vapor deposition particles are ejected from the ejection port 111.
- the heating plate unit 100 is fixed in the nozzle unit 110 as in the vapor deposition apparatus of the first embodiment, if the vapor deposition particles attached to the heating plate 101 in the heating plate unit 100 disappear, the heating plate unit 100 again.
- the vapor deposition particle injection devices 501 that are vapor deposition sources are arranged in a plurality of rows.
- vapor deposition is performed using the vapor deposition particle injection device 501 in which vapor deposition particles adhere to the surface of the heating plate 101 of the heating plate unit 100 among the remaining vapor deposition particle injection devices 501. Processing is performed.
- the deposition process of the vapor deposition particles to the heating plate 101 of the heating plate unit 100 is performed by the vapor deposition material filling apparatus 180 provided separately from the vapor deposition particle injection apparatus 502. Therefore, there is no cooling period (deposition period of deposited particles) of the nozzle part 110.
- the heating plate unit 100 when the vapor deposition particles adhering to the heating plate 101 of the heating plate unit 100 become a certain amount of gas, the heating plate unit 100 is taken out from the nozzle unit 110 and newly added. A heating plate unit 100 in which vapor deposition particles are attached to the heating plate 101 is attached to the nozzle portion 110.
- vapor deposition particle injection devices 502 it is not necessary to arrange a plurality of vapor deposition particle injection devices 502 as vapor deposition sources, and the vapor deposition source may be arranged in only one row.
- the vapor deposition rate in the vapor deposition particle injection device 502 of the vapor deposition apparatus is provided separately with the vapor deposition material filling device 180, so the vapor deposition rate from the crucible 123 of the vapor deposition particle generating unit 120. Does not depend on.
- the vapor deposition particle injection device 501 since the vapor deposition particle injection device 501 has the same function as the vapor deposition material filling device 180, the lower the vapor deposition rate from the crucible 123 of the vapor deposition particle generation unit 120, the more the parallel arrangement is achieved.
- the number of vapor deposition particle injection devices 501 as vapor deposition sources to be increased must be increased, and the size of the vacuum chamber 500 increases accordingly.
- the vacuum chamber 500 includes other mechanisms such as an alignment mechanism for the deposition target substrate 200 and the vapor deposition mask 300, so that the volume of the vacuum chamber 500 is increased, but the vapor deposition material filling device 180. Since it is only necessary to arrange the heating plate unit 100 in the heating container 170, the volume of the heating container 170 can be reduced. Therefore, the vapor deposition material filling device 180 can be downsized, the decompression time can be shortened, and the vapor deposition material filling device 180 can be simplified, leading to cost reduction of the equipment. At the same time, since the number of vapor deposition material filling devices 180 can be easily increased, the vapor deposition rate of the vapor deposition particle generating unit 120 can be further reduced, and thermal deterioration of the vapor deposition material can be further reduced.
- the heating plate unit 100 formed into a cartridge is replaced when the vapor deposition particles adhering to the surface of the heating plate 101 are exhausted. Sequential deposition can be performed by sequentially replacing the heating plate unit 100.
- the heating plate is heated to a temperature at which vapor deposition particles do not evaporate or sublime in the vacuum chamber 500 or a chamber attached thereto so that the vapor deposition rate can be quickly obtained when the nozzle unit 110 is charged.
- the unit 100 may be preheated.
- a plurality of nozzle portions 110 may be arranged in parallel. For example, by arranging two nozzle units 110 in parallel and using them alternately, it is possible to continue the vapor deposition even during replacement of the heating plate unit 100 or until the vapor deposition rate is stabilized. Processing can be performed.
- the configuration is basically the same as that of the vapor deposition particle injection device 501 shown in FIG. 1 of the first embodiment, but as shown in FIG. 12, instead of the vapor deposition particle injection device 501 shown in FIG.
- the vapor deposition particle injection device 503 is provided in the vapor deposition device.
- the vapor deposition particle injection device 503 includes a first heating device 162 and a second heating device 163 as shown in FIG.
- the first heating device 162 is configured to heat the nozzle part 110 that is the injection container from the outside, and the surface of the heating plate 101 of the heating plate unit 100 in the nozzle part 110 is the evaporation temperature of the vapor deposition material.
- the nozzle unit 110 is controlled to be heated so as not to be heated to the sublimation temperature.
- the second heating device 163 directly heats the heating plate unit 100 loaded in the nozzle unit 110 that is the injection container, and the surface of the heating plate 101 of the heating plate unit 100 is a deposition material. This is a device that controls the heating of the nozzle part 110 so that the evaporation temperature or the sublimation temperature becomes higher.
- the vapor deposition particle injection device 503 having the above configuration, when vapor deposition particles are attached to the heating plate 101 of the heating plate unit 100, only the first heating device 162 is driven to heat the nozzle unit 110. In this case, since the surface temperature of the heating plate 101 of the heating plate unit 100 in the nozzle unit 110 is controlled so as not to be heated to the evaporation temperature or sublimation temperature of the vapor deposition material, the gas supplied to the nozzle unit 110 The vapor-deposited particles adhere to the surface of the heating plate 101 of the heating plate unit 100.
- the second heating device 163 is driven to heat the nozzle unit 110.
- the surface of the heating plate 101 of the heating plate unit 100 is heated so as to be equal to or higher than the evaporation temperature or the sublimation temperature of the vapor deposition material, so that the vapor deposition material is gaseous from the surface of the heating plate 101 of the heating plate unit 100. It becomes a vapor deposition particle, and vapor deposition particle is inject
- the vapor deposition material held on the heating plate 101 of the heating plate unit 100 can be quickly turned into a gaseous state. Can respond. This is because when the vapor deposition particles are attached to the heating plate 101 of the heating plate unit 100, the heating by the first heating device 162 is performed, and this heating becomes the preheating to the heating plate unit 100 in the nozzle unit 110. Because.
- the nozzle unit 110 when vapor deposition particles are attached to the heating plate 101 of the heating plate unit 100, the nozzle unit 110 is positively cooled. Therefore, the heated heating plate unit 100 is heated once. However, in the present embodiment, the nozzle unit 110 is heated rather than cooled as described above.
- the nozzle portion 110 when vapor deposition particles are attached to the heating plate 101 of the heating plate unit 100, the nozzle portion 110 is not actively cooled as in the first embodiment. If the heating plate unit 100 is heated to be equal to or higher than the evaporation temperature or the sublimation temperature of the vapor deposition material, the time required for cooling the heating plate unit 100 becomes longer. For this reason, compared with the first embodiment, since it takes time to deposit the vapor deposition particles, the total vapor deposition processing time becomes longer.
- a plurality of vapor deposition particle injection devices 503 are arranged, and during the cooling period of the nozzle unit 110 of a certain vapor deposition particle injection device 503, the remaining vapor deposition particle injection devices 503 are arranged. If the vapor deposition process is performed using the vapor deposition particle injection device 503 in which vapor deposition particles are attached to the surface of the heating plate 101 of the heating plate unit 100, the total vapor deposition process can be shortened.
- the vapor deposition particle injection devices 501 to 503 are arranged below the deposition target substrate 200, and the vapor deposition particle injection devices 501 to 503 are disposed via the opening 301 of the vapor deposition mask 300.
- the case where vapor deposition particles are vapor-deposited (up-deposition) from below to above has been described as an example. However, the present invention is not limited to this.
- the vapor deposition particle injection devices 501 to 503 are provided above the deposition target substrate 200, and the vapor deposition particles are deposited (down-deposited) on the deposition target substrate 200 from above through the opening 301 of the vapor deposition mask 300. Position).
- a high-definition pattern can be formed without using a technique such as an electrostatic chuck as a substrate holding member that holds the deposition target substrate 200 in order to suppress the self-weight deflection.
- the film can be formed with high accuracy over the entire surface of the deposition target substrate 200.
- the vapor deposition particle injection devices 501 to 503 have a mechanism for injecting vapor deposition particles in the lateral direction, and the vapor deposition particle injection devices 501 to 503 are disposed on the film formation surface 201 side of the film formation substrate 200.
- the vapor deposition particles may be vapor-deposited (side-deposited) on the deposition target substrate 200 in the lateral direction through the vapor deposition mask 300 in a state where the vertical direction is faced to the side.
- the opening shape (planar shape) of the injection port 111 of the nozzle part 110 is not specifically limited, It can be set as various shapes, such as circular and square.
- injection ports 111 of the nozzle unit 110 may be arranged one-dimensionally (that is, in a line shape), or may be arranged two-dimensionally (that is, in a planar shape).
- the organic EL display device 1 includes the TFT substrate 10 and an organic layer is formed on the TFT substrate 10 has been described as an example.
- the present invention is limited to this. is not.
- the organic EL display device 1 may be a passive substrate in which a TFT is not formed on a substrate on which an organic layer is formed, instead of the TFT substrate 10, and the passive substrate is used as the film formation substrate 200. It may be used.
- the present invention is not limited to this, and instead of the organic layer, The present invention can also be applied when the second electrode 26 is deposited. Moreover, when using a sealing film for sealing of the organic EL element 20, it is applicable also when performing vapor deposition of this sealing film.
- the vapor deposition particle injection devices 501 to 503 and the vapor deposition device can be applied to all production methods and production apparatuses for depositing a patterned film by vapor deposition in addition to the method for producing the organic EL display device 1 as described above.
- the present invention can be preferably applied. Among these, it can use especially suitably for the vapor deposition method which requires the vapor deposition source of a high vapor deposition rate.
- the vapor deposition particle injection devices 501 to 503 and the vapor deposition device can be suitably applied to, for example, the manufacture of functional devices such as organic thin film transistors in addition to the organic EL display device 1, for example.
- the vapor deposition particle injection devices 501 to 503 have been described as line type vapor deposition sources.
- the present invention is not limited to this, and a crucible type vapor deposition source (point type vapor deposition source) or a surface type is not limited thereto. It does not matter as a deposition source.
- the effect exhibited in the present invention does not depend on the shape of the nozzle outlet. That is, even when a large number of injection ports are arranged, the injection port in which one long opening is formed may be used.
- the present invention is particularly effective for materials having a long deposition rate stabilization time. For example, it is possible to improve the processing tact (throughput) of a material that is likely to deteriorate due to a rapid temperature rise, such as an organic material, by rapidly reaching the deposition rate. Furthermore, the present invention is particularly effective for expensive vapor deposition materials. For example, a material for forming an organic layer of an organic EL element. By shortening the stabilization time of the vapor deposition rate and combining a plurality of vapor deposition material supply sources, the vapor deposition material can be used effectively because it can contribute to vapor deposition even when the temperature is raised or lowered.
- the vapor deposition particle injection device according to the present invention can be applied not only to the manufacture of an organic EL display device but also to other materials that form a film by vapor deposition.
- the application of the vapor deposition film pattern using the limiting plate has been described as an example.
- the present invention is not limited to this. It can also be applied when forming an organic film.
- the deposition rate can be improved by applying the method of the present invention, the deposition time can be shortened, and the processing tact of the apparatus can be improved. can do.
- the present invention can be similarly applied to an organic EL light-emitting device in which all layers are formed over the entire light-emitting region without forming a pattern with high definition as in lighting applications.
- organic EL illumination is very effective in reducing the cost by shortening the processing tact, and if the method of the present invention is used, a high vapor deposition rate can be obtained, so that the processing tact can be shortened.
- the present invention can be applied not only to the organic film but also to the deposition of the second electrode or the sealing film.
- the present invention can be applied not only to the manufacture of an organic EL display device but also to a manufacturing process or a product that forms a film by vapor deposition and requires a high vapor deposition rate.
- the adherend is provided so as to be detachable from the injection container.
- the adherend is provided so as to be detachable from the injection container, the vapor deposition particles are attached to the adherend and held by the apparatus different from the vapor deposition particle injection apparatus. It becomes possible to do.
- the vapor deposition particle injection apparatus is connected to a vapor deposition particle generation source that generates vapor deposition particles by heating vapor deposition material, and the vapor deposition particle generation source, and ejects the vapor deposition particles to the outside.
- An injection container having an injection port, an adherend that is contained in the injection container and holds vapor deposition material on the surface by adhering vapor deposition particles, and a surface temperature of the adherend in the injection container
- a surface temperature control device for controlling the vapor deposition material to be either a temperature lower than a temperature at which the vapor deposition material becomes gaseous or a temperature equal to or higher than a temperature at which the vapor deposition material becomes gaseous. Yes.
- the surface temperature control device includes: a cooling device that cools the adherend so that a surface temperature of the adherend in the injection container is lower than a temperature at which the vapor deposition material becomes gaseous; and the injection And a heating device that heats the adherend so that the surface temperature of the adherend in the container is equal to or higher than the temperature at which the vapor deposition material becomes gaseous.
- the surface temperature of the adherend heated above the temperature at which the vapor deposition material becomes gaseous by the heating device can be attached to the adherend by the cooling device. It is possible to quickly cool to a low temperature, that is, a temperature lower than the temperature at which the vapor deposition material becomes gaseous.
- the surface temperature control device includes: a first heating device that heats the surface of the adherend in the injection container to a temperature at which the vapor deposition material becomes gaseous; and the adherend in the injection container. You may be comprised with the 2nd heating apparatus which heats the surface above the temperature from which the said vapor deposition material becomes gaseous.
- a 1st heating apparatus heats the surface of the to-be-adhered body in the container for injection filled with the gaseous vapor deposition particle to temperature lower than the temperature from which vapor deposition material becomes gaseous.
- gaseous vapor deposition particles in the injection container can be adhered to the surface of the adherend, and the vapor deposition material can be held on the surface of the adherend.
- the second heating device heats the surface of the adherend in the injection container to a temperature higher than the temperature at which the vapor deposition material becomes gaseous, so that the vapor deposition material held on the adherend surface is in a gaseous state. It becomes possible to discharge vapor deposition particles.
- the surface of the adherend is heated by the first heating device. 2 Since the preheating of the surface of the adherend is performed by the heating device, the time from the start of heating of the second heating device to the release of gaseous vapor deposition particles from the vapor deposition material held on the surface of the adherend is greatly increased. It can be shortened.
- the adherend is preferably composed of a plurality of heating plates.
- the surface area for adhering vapor deposition particles can be increased. Accordingly, the number of vapor deposition particles to be attached at a time can be increased, and thus the number of gaseous vapor deposition particles released by heating the surface of the adherend can be increased. Therefore, the vapor deposition rate of the vapor deposition particles injected from the injection container can be greatly improved.
- the adherend since the adherend can increase the number of deposited particles as the surface area increases, it may be the following member having a large surface area.
- the adherend is preferably a fin-shaped member.
- the adherend is preferably a mesh member.
- the adherend is a member having a fractal surface.
- the vapor deposition particle injection system includes a vapor deposition particle generation source that generates vapor deposition particles by heating vapor deposition material, and a gaseous state generated by the vapor deposition particle generation source connected to the vapor deposition particle generation source.
- Vapor deposition material filling apparatus comprising: a filling container filled with vapor deposition particles; and a vapor deposition particle adhering means for adhering the vapor deposition particles to the surface of an adherend contained in the filling container; Including an adherend that holds a vapor deposition material obtained by adhering a vapor-deposited particle on the surface, and an injection container having an injection port for injecting gaseous vapor-deposited particles to the outside; and the injection container And a vapor deposition particle injection device including a heating device that heats the adherend to a temperature higher than a temperature at which the vapor deposition material becomes gaseous.
- the apparatus for attaching the vapor deposition particles to the adherend and holding the vapor deposition material, and vaporizing the vapor deposition material held by the adherend are ejected to the outside. Since the apparatus for vapor deposition particle injection is separately provided, the vapor deposition rate at the time of the deposition treatment of the vapor deposition particles to the adherend in the vapor deposition material filling apparatus is released from the adherend in the vapor deposition particle injection apparatus. It does not depend on the deposition rate at the time of injection of the deposited particles.
- the vapor deposition rate in the vapor deposition particle injection apparatus is not affected. That is, in the vapor deposition material filling device, the vapor deposition particles can be adhered to the adherend at a low vapor deposition rate, so that it is not necessary to raise the heating temperature for the vapor deposition particle generating source in the vapor deposition material filling device so much.
- the vapor deposition particle injection system may include a cartridge that is detachably formed on the vapor deposition material filling device and encloses the adherend.
- the vapor deposition material held in the surface of the adherend contained in the injection container having an injection port for injecting gaseous vapor deposition particles to the outside is used. It is characterized by including a heating step of heating to a temperature equal to or higher than a certain temperature.
- the deposition rate can be improved.
- the deposition rate can be further improved.
- the heating temperature for making the vapor deposition material held on the adherend surface gaseous is a liquid. If it is, the evaporating temperature is higher than the sublimation temperature if the vapor deposition material is fixed, and a heating temperature as close as possible to these evaporating temperature and sublimation temperature is sufficient. Thereby, since it is not necessary to perform heating more than necessary to increase the vapor deposition rate, deterioration of the vapor deposition material due to excessive heating can be prevented.
- the vapor deposition rate can be improved without heating the vapor deposition material more than necessary.
- the vapor deposition particle injection method includes a vapor deposition particle supply step of supplying vapor deposition particles in the form of a vapor deposition material to an injection container in which an adherend to which vapor deposition particles can adhere is encapsulated, and the vapor deposition described above. With the particles being supplied, the surface of the adherend in the injection container is adjusted to a temperature lower than the temperature at which the vapor deposition material evaporates, and the vapor deposition particles adhere to the surface of the adherend.
- the vapor deposition material holding step for holding the vapor deposition material on the surface and the vapor deposition material held on the adherend surface by the vapor deposition material holding step to a temperature equal to or higher than the temperature at which the vapor deposition material becomes gaseous.
- the temperature at which gaseous vapor deposition particles are generated from the vapor deposition material is the evaporation temperature when the vapor deposition material is liquid, and the sublimation temperature when the vapor deposition material is solid.
- the deposition material held on the adherend after the deposition particles are attached to the surface of the adherend and held on the surface of the adherend contained in the injection container. Therefore, it is possible to increase the vapor deposition material that is made gaseous at a time without increasing the heating temperature as compared with the case where the vapor deposition material is put in a crucible or the like and heated to be gaseous. That is, the deposition rate can be improved.
- the vapor deposition apparatus includes the vapor deposition particle injection apparatus as a vapor deposition source.
- the vapor deposition rate can be improved without heating the vapor deposition material more than necessary.
- the vapor deposition apparatus preferably includes a vapor deposition mask for forming a vapor deposition film pattern.
- a desired film formation pattern can be obtained by using a vapor deposition mask.
- the predetermined pattern can be an organic layer in an organic electroluminescence element.
- the said vapor deposition apparatus can be used suitably as a manufacturing apparatus of an organic electroluminescent element. That is, the said vapor deposition apparatus may be a manufacturing apparatus of an organic electroluminescent element.
- a TFT substrate / first electrode manufacturing step of manufacturing a first electrode on a TFT substrate, and at least a light emitting layer on the TFT substrate An organic layer deposition step for depositing an organic layer containing a second electrode deposition step for depositing a second electrode, and in at least one of the organic layer deposition step and the second electrode deposition step, Use a vapor deposition particle injection device.
- the vapor deposition rate can be improved without heating the vapor deposition material more than necessary.
- the vapor deposition material is not wasted, and the utilization efficiency of the vapor deposition material can be improved.
- the cost for manufacturing the organic electroluminescence element can be reduced, and as a result, the organic EL display device can be manufactured at low cost.
- the vapor deposition particle injection apparatus and vapor deposition apparatus of the present invention are suitably used for an organic EL display device manufacturing apparatus, a manufacturing method, and the like used in a film forming process such as separate formation of an organic layer in an organic EL display device, for example. Can do.
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Abstract
Description
本発明の一実施の形態について説明すれば、以下の通りである。
図1は、本発明の一実施の形態に係る蒸着粒子射出装置を備えた蒸着装置全体の概略を示す図である。
ここで、表面に蒸着粒子が付着され、蒸着材料が保持された加熱板101を蒸着粒子付着体と称する。
図2は、加熱板ユニット100内の加熱板101の配列例を示す図である。
上記加熱板ユニット100の内部構造は、図2に示すように、複数の板状の加熱板101を並列に配置した構造に限定されるものではなく、様々な形状とすることができ、その形状の表面積が大きければ大きいほどよい。
次に、上記構成の蒸着装置を用いた蒸着処理システムについて説明する。
上記有機EL表示装置の全体構成について以下に説明する。
図7は、有機EL表示装置1の表示部を構成する有機EL素子20の概略構成を示す断面図である。
絶縁基板11としては、例えば、無アルカリガラスやプラスチック等を用いることができる。本実施の形態においては、板厚0.7mmの無アルカリガラスを使用した。
有機EL素子20は、低電圧直流駆動による高輝度発光が可能な発光素子であり、第1電極21、有機EL層、第2電極26が、この順に積層されている。
第1電極21は、電極材料をスパッタ法等で形成した後、フォトリソグラフィ技術およびエッチングにより、個々の画素2R・2G・2Bに対応してパターン形成されている。
ウム亜鉛酸化物)、ガリウム添加酸化亜鉛(GZO)等の透明導電材料、金(Au)、ニッケル(Ni)、白金(Pt)等の金属材料を用いることができる。
等を用いることができる。例えば、上記第1電極21の積層に、後述する本実施の形態に係る蒸着装置を用いてもよい。
ここで、真空蒸着法を用いた成膜パターンの形成方法について、主に図8を用いて以下に説明する。
図8は、有機EL表示装置1の製造工程を工程順に示すフローチャートである。
一般的なスキャン蒸着では、以下に示す2点の問題が発生する。
本発明の他の実施の形態について説明すれば以下の通りである。なお、説明の便宜上、前記実施の形態1と同じ機能を有する部材には、同一の符号を付記し、その詳細な説明は省略する。
図10は、本発明の他の実施の形態に係る蒸着粒子射出装置を備えた蒸着装置全体の概略を示す図である。
上記蒸着材料充填装置180は、図11に示すように、前記実施の形態1の図1に示す蒸着粒子射出装置501とほぼ同じ構成であり、加熱板ユニット100を内包したノズル部110の代わりに、加熱板ユニット100を内包した加熱容器(充填容器)170が設けられている点で異なる。しかしながら、蒸着材料充填装置180においても、上記蒸着粒子射出装置501と同様に、加熱板ユニット100の加熱板101表面に蒸着粒子を付着させる点で同じである。
本発明のさらに他の実施の形態について説明すれば以下の通りである。
なお、前記実施の形態1~3では、蒸着粒子射出装置501~503が被成膜基板200の下方に配されており、蒸着粒子射出装置501~503が、蒸着マスク300の開口部301を介して、蒸着粒子を下方から上方に向かって蒸着(アップデポジション)させる場合を例に挙げて説明した。しかしながら、本発明はこれに限定されるものではない。
また、例えば、上記蒸着粒子射出装置501~503は、横方向に向けて蒸着粒子を射出する機構を有しており、被成膜基板200の被成膜面201側が蒸着粒子射出装置501~503側を向いて垂直方向に立てられている状態で、蒸着マスク300を介して蒸着粒子を横方向に被成膜基板200に蒸着(サイドデポジション)させてもよい。
また、ノズル部110の射出口111の開口形状(平面形状)は、特に限定されるものではなく、円形、方形等、様々な形状とすることができる。
2R・2G・2B 画素
10 TFT基板
11 絶縁基板
12 TFT
13 層間絶縁膜
13a コンタクトホール
14 配線
15 エッジカバー
20 有機EL素子
21 第1電極
22 正孔注入層兼正孔輸送層
23R 発光層
23R・23G・23B 発光層
24 電子輸送層
25 電子注入層
26 第2電極
30 接着層
40 封止基板
91 蒸着粒子
100 加熱板ユニット
101 加熱板
101a 表面
110 ノズル部(射出用容器)
110a 筐体外周面
111 射出口
120 蒸着粒子発生部
121 容器
122 ヒータ
124 蒸着材料
130 導入管
131 制限板
140 バルブ
150 冷却装置
151 熱交換部材
160 加熱装置
161 加熱装置
162 第1加熱装置
163 第2加熱装置
170 加熱容器
171 射出口
180 蒸着材料充填装置
200 被成膜基板
201 被成膜面
300 蒸着マスク
301 開口部
500 真空チャンバ
501 蒸着粒子射出装置
502 蒸着粒子射出装置
503 蒸着粒子射出装置
600 蒸着源ユニット
700 蒸着源
Claims (16)
- 蒸着材料を加熱して気体状の蒸着粒子を発生させる蒸着粒子発生源と、
上記蒸着粒子発生源と接続され、上記気体状の蒸着粒子を外部に射出する射出口を有する射出用容器と、
上記射出用容器に内包され、蒸着粒子を付着させることで表面に蒸着材料を保持する被付着体と、
上記射出用容器内の上記被付着体の表面温度を、上記蒸着材料が気体状になる温度よりも低い温度、または、上記蒸着材料が気体状になる温度以上の温度の何れかになるように制御する表面温度制御装置とを備えたことを特徴とする蒸着粒子射出装置。 - 上記表面温度制御装置は、
上記射出用容器内の上記被付着体の表面温度が、上記蒸着材料が気体状になる温度よりも低くなるように当該被付着体を冷却する冷却装置と、
上記射出用容器内の上記被付着体の表面温度が、上記蒸着材料が気体状になる温度以上になるように当該被付着体を加熱する加熱装置とからなることを特徴とする請求項1に記載の蒸着粒子射出装置。 - 上記表面温度制御装置は、
上記射出用容器内の上記被付着体の表面を、上記蒸着材料が気体状となる温度まで加熱する第1加熱装置と、
上記射出用容器内の上記被付着体の表面を、上記蒸着材料が気体状となる温度以上に加熱する第2加熱装置とからなることを特徴とする請求項1に記載の蒸着粒子射出装置。 - 気体状の蒸着粒子を外部に射出する射出口を有した射出用容器と、
上記射出用容器に内包され、蒸着粒子を付着させることで表面に蒸着材料を保持する被付着体と、
上記被付着体表面に保持された蒸着材料を、当該蒸着材料が気体状になる温度以上の温度に加熱する加熱装置とを備えたことを特徴とする蒸着粒子射出装置。 - 上記被付着体は、上記射出用容器から着脱可能に設けられていることを特徴とする請求項4に記載の蒸着粒子射出装置。
- 上記被付着体は、複数の加熱板からなることを特徴とする請求項1~5の何れか1項に記載の蒸着粒子射出装置。
- 上記被付着体は、ひれ状部材からなることを特徴とする請求項1~5の何れか1項に記載の蒸着粒子射出装置。
- 上記被付着体は、網目状部材からなることを特徴とする請求項1~5の何れか1項に記載の蒸着粒子射出装置。
- 上記被付着体は、フラクタル面を有することを特徴とする請求項1~5の何れか1項に記載の蒸着粒子射出装置。
- 蒸着材料を加熱して気体状の蒸着粒子を発生させる蒸着粒子発生源と、上記蒸着粒子発生源と接続され、上記蒸着粒子発生源で発生した気体状の蒸着粒子が充填される充填容器と、上記充填容器に内包された被付着体表面に、上記蒸着粒子を付着させる蒸着粒子付着手段とを備えた蒸着材料充填装置と、
上記蒸着材料充填装置によって気体状の蒸着粒子を表面に付着して得られた蒸着材料を保持した被付着体を内包し、気体状の蒸着粒子を外部に射出する射出口を有した射出用容器と、上記射出用容器に内包された被付着体の表面温度が当該蒸着材料が気体状になる温度以上に当該被付着体を加熱する加熱装置とを備えた蒸着粒子射出装置とを含むことを特徴とする蒸着粒子射出システム。 - 請求項10に記載の蒸着材料充填装置に着脱可能に形成され、上記被付着体を内包したカートリッジ。
- 気体状の蒸着粒子を外部に射出する射出口を有する射出用容器に内包された被付着体表面に保持された蒸着材料を、当該蒸着材料が気体状になる温度以上の温度に加熱する加熱工程を含むことを特徴とする蒸着粒子射出方法。
- 表面に蒸着粒子が付着可能な被付着体が内包された射出用容器に、蒸着材料を気体状にした蒸着粒子を供給する蒸着粒子供給工程と、
上記蒸着粒子が供給されている状態で、上記射出用容器内の上記被付着体の表面を、上記蒸着材料が蒸発する温度よりも低い温度に調整して、当該被付着体の表面に蒸着粒子を付着させることで、上記表面に蒸着材料を保持させる蒸着材料保持工程と、
蒸着材料保持工程により、上記被付着体表面に保持された蒸着材料を、当該蒸着材料が気体状になる温度以上の温度に加熱する加熱工程と、
上記加熱工程により、気体状となった蒸着粒子を射出口から被蒸着体に向けて射出する蒸着粒子射出工程とを含むことを特徴とする蒸着粒子射出方法。 - 蒸着源として、請求項1~9の何れか1項に記載の蒸着粒子射出装置を備えていることを特徴とする蒸着装置。
- 蒸着膜の成膜パターンを形成するための蒸着マスクを備えていることを特徴とする請求項14に記載の蒸着装置。
- 上記成膜パターンが、有機エレクトロルミネッセンス素子における有機層であることを特徴とする請求項15に記載の蒸着装置。
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CN105296934B (zh) * | 2015-11-09 | 2018-06-19 | 合肥欣奕华智能机器有限公司 | 一种线形蒸发源及蒸镀设备 |
CN105603364B (zh) * | 2016-03-16 | 2018-11-23 | 深圳市华星光电技术有限公司 | 导热装置与蒸镀坩埚 |
KR20210061639A (ko) * | 2019-11-20 | 2021-05-28 | 캐논 톡키 가부시키가이샤 | 성막 장치, 이를 사용한 성막 방법 및 전자 디바이스 제조 방법 |
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