Classifications

• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
  • C08G59/223—Di-epoxy compounds together with monoepoxy compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
  • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
  • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
  • C08G59/22—Di-epoxy compounds
  • C08G59/226—Mixtures of di-epoxy compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
  • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
  • G02F1/1333—Constructional arrangements; Manufacturing methods
  • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/30—Polarising elements
  • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
  • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
  • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
  • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
  • G02F1/1333—Constructional arrangements; Manufacturing methods
  • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
  • G02F1/133528—Polarisers
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F2201/00—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00
  • G02F2201/50—Protective arrangements
• • G—PHYSICS
  • G02—OPTICS
  • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
  • G02F2202/00—Materials and properties
  • G02F2202/28—Adhesive materials or arrangements

Definitions

• the present invention relates to a polarizing plate in which a protective film made of a transparent resin is bonded via a photocurable adhesive to a polarizer made of a polyvinyl alcohol-based resin film on which a dichroic dye is adsorbed and oriented, and the polarizing plate
• the present invention relates to a laminated optical member obtained by laminating another optical layer such as a retardation film.
• the polarizing plate is useful as one of the optical components constituting the liquid crystal display device.
• a polarizing plate usually has a structure in which protective films are laminated on both sides of a polarizer, and is incorporated in a liquid crystal display device. It is also known that a protective film is provided only on one side of a polarizer, but in many cases, a layer having another optical function is attached to the other side as a protective film instead of a simple protective film. Combined. Further, as a method for producing a polarizer, a method in which a uniaxially stretched polyvinyl alcohol-based resin film dyed with a dichroic dye is treated with boric acid, washed with water, and dried is widely adopted.
• a protective film is bonded to the polarizer immediately after washing and drying as described above. This is because the dried polarizer has a weak physical strength, and once it is wound, there is a problem that it is easily broken in the processing direction. Therefore, usually, a water-based adhesive that is an aqueous solution of a polyvinyl alcohol resin is immediately applied to the polarizer after drying, and protective films are simultaneously bonded to both sides of the polarizer via this adhesive. Usually, a triacetyl cellulose film having a thickness of 30 to 100 ⁇ m is used as the protective film.
• Triacetyl cellulose is excellent in transparency, easily forms various surface treatment layers and optical functional layers, has high moisture permeability, and can be dried after being bonded to a polarizer using an aqueous adhesive as described above. While having an excellent advantage as a protective film such that it can be performed smoothly, the polarizing plate bonded as a protective film due to its high moisture permeability is, for example, at a temperature of 70 ° C. and a relative humidity of 90 under wet heat. %, There was a problem such as easy to cause deterioration.
• an amorphous polyolefin resin having a lower moisture permeability than that of triacetyl cellulose for example, an amorphous polyolefin resin represented by a norbornene resin as a protective film.
• a protective film made of a resin with low moisture permeability such as an amorphous polyolefin resin is bonded to one surface of a polarizer, and a cellulose resin such as triacetyl cellulose is bonded to the other surface of the polarizer.
• a protective film made of a resin with high moisture permeability such as.
• Patent Document 1 discloses an adhesive mainly composed of an epoxy compound that does not contain an aromatic ring, and irradiation with active energy rays, specifically irradiation with ultraviolet rays.
• Patent Document 2 discloses a photocurable adhesive comprising a combination of an alicyclic epoxy compound and an epoxy compound having no alicyclic epoxy group, and further containing a photocationic polymerization initiator. A technique using an agent for bonding a polarizer and a protective film is disclosed.
• the adhesive of the composition specifically disclosed in Patent Document 1 and Patent Document 2 does not necessarily have a sufficiently low viscosity, and is applied to a polarizer or a protective film bonded thereto, and is uniform in a thin film. It was not always easy to form an adhesive layer. Some of these adhesives dissolve the protective film, and the dissolution sometimes causes bubble defects.
• the present inventors have intensively studied to solve such a problem, and as a result, the present invention has been completed.
• the photocationic curable component mainly comprises a specific alicyclic diepoxy compound.
• a diglycidyl compound having two epoxy groups that are not bonded to an alicyclic ring in the molecule and a divalent group having a branched structure such as a branched alkylene group as a linking group is blended, and the alicyclic
• the photo-curable adhesive having such a specific composition has a small ability to dissolve the protective film and exhibits a low viscosity at room temperature to give good coating suitability. It was found that it adheres firmly.
• the present invention includes the following.
• a polarizing plate comprising an adhesive containing 100 parts by weight of a photocationic curable component (A) and 1 to 10 parts by weight of a photocationic polymerization initiator (B), Component (A) is formed from a photocurable adhesive containing the following (A1), (A2) and (A3) in the following amounts based on the total amount thereof, A polarizing plate in which when the protective film is immersed at 23 ° C. for 2 days, the weight loss of the protective film is 0 to 30% by weight.
• each of R 1 and R 2 independently represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, and when the alkyl group has 3 or more carbon atoms, it may have an alicyclic structure;
• Y 1 to Y 4 each represent an alkanediyl group having 1 to 20 carbon atoms, and when it has 3 or more carbon atoms, it has an alicyclic structure.
• a and b each represents an integer of 0 to 20.
• Z represents a branched alkylene group having 2 to 8 carbon atoms or a divalent group represented by the formula —C m H 2m —Z 1 —C n H 2n —, where —Z 1 — represents — O—, —CO—O— or —O—CO—, wherein one of m and n represents an integer of 1 or more and the other represents an integer of 2 or more, the sum of the two being 8 or less, and C m H 2m And one of C n H 2n represents a branched divalent saturated hydrocarbon group.
• R 3 represents an alkyl group having 1 to 15 carbon atoms.
• R 3 is an alkyl group having 6 to 10 carbon atoms.
• the protective film bonded to at least one surface of the polarizer is made of a transparent resin selected from the group consisting of an amorphous polyolefin resin, a polyester resin, and a chain polyolefin resin. 4].
• a laminated optical member comprising a laminate of the polarizing plate according to any one of [1] to [6] and another optical layer.
• the alicyclic diepoxy compound (A1) and the linking group have a branched structure as the photocationic curable component (A) that is the main component of the photocurable adhesive that bonds the polarizer and the protective film.
• the photocurable adhesive has a low viscosity.
• a protective film made of a transparent resin to at least one surface of the polarizer via this photocurable adhesive, bubble defects due to dissolution of the protective film are greatly reduced, and the polarizer And a protective film having good adhesion to the protective film.
• a laminated optical member in which another optical layer is laminated on this polarizing plate also has few defects.
• the present invention provides a polarizing plate in which a protective film made of a transparent resin is bonded to a polarizer made of a polyvinyl alcohol-based resin film via a photocurable adhesive.
• the present invention also provides a laminated optical member in which another optical layer is laminated on this polarizing plate.
• the photocurable adhesive used for the production of the polarizing plate, the polarizing plate using the same, and the laminated optical member will be described in order.
• the photocurable adhesive for bonding the protective film which consists of transparent resins to the polarizer which consists of a polyvinyl alcohol-type resin film contains the following two components (A) and (B). (A) a photocationic curable component, and (B) a photocationic polymerization initiator.
• the photocationic curable component (A) which is a main component of the photocurable adhesive and provides adhesive strength by polymerization curing, contains the following three types of compounds.
• A1 An alicyclic diepoxy compound represented by the formula (I),
• A2) a diglycidyl compound represented by the formula (II), and
• A3) a monofunctional epoxy compound represented by the formula (III).
• R 1 and R 2 are each independently a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, but the alkyl group has 3 or more carbon atoms. In some cases, it may have an alicyclic structure.
• This alkyl group is represented by the 1-position where the position of the cyclohexane ring bonded to X in formula (I) is the 1-position (therefore, the positions of the epoxy groups in the two cyclohexane rings are both 3,4-position). It can be bonded to any of the 6-positions.
• this alkyl group may be a straight chain or may be branched when it has 3 or more carbon atoms.
• Typical examples of the alkyl group having an alicyclic structure include cyclopentyl and cyclohexyl.
• X connecting two 3,4-epoxycyclohexane rings is an oxygen atom, an alkanediyl group having 1 to 6 carbon atoms, or 2 represented by any one of the formulas (Ia) to (Id).
• the alkanediyl group is a concept including alkylene and alkylidene, and the alkylene may be a straight chain or may be branched when it has 3 or more carbon atoms.
• the linking groups Y 1 , Y 2 , Y 3 and Y 4 in each formula each have 1 to
• the alkanediyl group may have an alicyclic structure.
• these alkanediyl groups may be linear, or may be branched when having 3 or more carbon atoms.
• you may have an alicyclic structure.
• Typical examples of alkanediyl groups having an alicyclic structure include cyclopentylene and cyclohexylene.
• the alicyclic diepoxy compound (A1) represented by the formula (I) will be specifically described.
• X in the formula (I) is a divalent group represented by the formula (Ia), and a in the formula is
• the compound which is 0 includes 3,4-epoxycyclohexylmethanol (an alkyl group having 1 to 6 carbon atoms may be bonded to the cyclohexane ring) and 3,4-epoxycyclohexanecarboxylic acid (carbon is added to the cyclohexane ring).
• the esterified product may have an alkyl group of 1 to 6 attached thereto.
• a compound in which X in the formula (I) is a divalent group represented by the formula (Ic) includes an aliphatic dicarboxylic acid and 3,4-epoxycyclohexylmethanol (an alkyl group having 1 to 6 carbon atoms bonded to the cyclohexane ring) It may be an esterified product.
• X in the formula (I) is a divalent group represented by the formula (Id) is 3,4-epoxycyclohexylmethanol (an alkyl group having 1 to 6 carbon atoms bonded to the cyclohexane ring).
• May be an ether form (when b 0), or an alkylene glycol or polyalkylene glycol and 3,4-epoxycyclohexylmethanol (an alkyl group having 1 to 6 carbon atoms is bonded to the cyclohexane ring).
• etherified product when b> 0).
• Z is a branched alkylene group having 3 to 8 carbon atoms, or a divalent group represented by the formula —C m H 2m —Z 1 —C n H 2n —. It is.
• —Z 1 — is —O—, —CO—O— or —O—CO—
• one of m and n is an integer of 1 or more and the other is an integer of 2 or more.
• one of C m H 2m and C n H 2n is a branched divalent saturated hydrocarbon group.
• the compound in which Z is a branched alkylene group is a diglycidyl ether of a branched alkylene glycol.
• Specific examples include propylene glycol diglycidyl ether, 1,3-butanediol diglycidyl ether, 1,2-butanediol diglycidyl ether, neopentyl glycol diglycidyl ether, 3-methyl-1,5-pentanediol.
• Examples include diglycidyl ether, 2-methyl-1,8-octanediol diglycidyl ether, and 1,4-cyclohexanedimethanol.
• R 3 is an alkyl group having 1 to 15 carbon atoms.
• this alkyl group may be linear, or may be branched when it has 3 or more carbon atoms.
• This alkyl group has a relatively large number of carbon atoms, for example, preferably 6 or more, and more preferably in the range of 6 to 10 carbon atoms. Of these, a branched alkyl group is preferred.
• a typical example of the monofunctional epoxy compound represented by the formula (III) is 2-ethylhexyl glycidyl ether.
• the amount of the alicyclic diepoxy compound (A1) in the photocationic curable component (A) is 30 to 85% by weight based on the total amount of the photocationic curable component (A).
• the amount is preferably 40 to 80% by weight, more preferably 60 to 75% by weight. If the amount of the alicyclic diepoxy compound (A1) in the photocationic curable component (A) is too small, the curing becomes insufficient and the adhesion between the polarizer and the protective film decreases. On the other hand, when the amount is too large, the amount of the diglycidyl compound (A2) and the monofunctional epoxy compound (A3) described below becomes relatively small, and the viscosity of the photocurable adhesive intended in the present invention is reduced. Becomes difficult.
• the amount of the diglycidyl compound (A2) having a branched structure in the linking group in the photocationic curable component (A) is 1 to 69% by weight.
• the amount is preferably 5 to 50% by weight, more preferably 5 to 30% by weight.
• the amount of the diglycidyl compound (A2) in the photocationic curable component (A) is more than 69% by weight, the curing becomes insufficient and the adhesion between the polarizer and the protective film decreases.
• the amount of the monofunctional epoxy compound (A3) in the photocation curable component (A) is 1 to 69% by weight.
• the amount is preferably 2 to 50% by weight, more preferably 2 to 15% by weight. If the amount of the monofunctional epoxy compound (A3) in the photocationic curable component (A) is more than 69% by weight, curing is also insufficient and the adhesion between the polarizer and the protective film is lowered.
• the photocationic curable component (A) constituting the photocurable adhesive includes the alicyclic diepoxy compound (A1), the diglycidyl compound (A2) having a branched structure in the linking group, and the monofunctional epoxy compound (A3). In the proportions described above. In order to more effectively reduce the viscosity of the photocurable adhesive before curing and improve the adhesion between the polarizer and the protective film using the cured product, the total amount of the photocurable adhesive is used as a reference. The total amount of the diglycidyl compound (A2) and the monofunctional epoxy compound (A3) is preferably 25% by weight or more.
• the photocation curable component (A) is an amount described above for the alicyclic diepoxy compound (A1), the diglycidyl compound (A2) having a branched structure in the linking group, and the monofunctional epoxy compound (A3).
• Other cationically polymerizable compounds may be included.
• the photocationic curable component as described above is cured by cationic polymerization by irradiation of active energy rays to form an adhesive layer. Therefore, the photocurable adhesive composition includes a photocationic polymerization initiator.
• (B) is blended.
• the cationic photopolymerization initiator generates a cationic species or a Lewis acid upon irradiation with an active energy ray such as visible light, ultraviolet ray, X-ray, or electron beam, and initiates the polymerization reaction of the photocationic curable component (A). Is.
• the cationic photopolymerization initiator acts catalytically by light, it is excellent in storage stability and workability even when mixed with the cationic photocurable component (A).
• the compound that generates a cationic species or a Lewis acid upon irradiation with active energy rays include aromatic diazonium salts; onium salts such as aromatic iodonium salts and aromatic sulfonium salts; iron-allene complexes.
• aromatic diazonium salt examples include the following compounds. Benzenediazonium hexafluoroantimonate, Benzenediazonium hexafluorophosphate, Benzenediazonium hexafluoroborate, etc.
• aromatic iodonium salt examples include the following compounds. Diphenyliodonium tetrakis (pentafluorophenyl) borate, Diphenyliodonium hexafluorophosphate, Diphenyliodonium hexafluoroantimonate, Di (4-nonylphenyl) iodonium hexafluorophosphate, etc.
• aromatic sulfonium salt examples include the following compounds. Triphenylsulfonium hexafluorophosphate, Triphenylsulfonium hexafluoroantimonate, Triphenylsulfonium tetrakis (pentafluorophenyl) borate, 4,4′-bis [diphenylsulfonio] diphenyl sulfide bishexafluorophosphate, 4,4′-bis [di ( ⁇ -hydroxyethoxy) phenylsulfonio] diphenyl sulfide bishexafluoroantimonate, 4,4′-bis [di ( ⁇ -hydroxyethoxy) phenylsulfonio] diphenyl sulfide bishexafluorophosphate, 7- [di (p-toluyl) sulfonio] -2-isopropylthioxanthone hexafluor
• iron-allene complex examples include the following compounds. Xylene-cyclopentadienyl iron (II) hexafluoroantimonate, Cumene-cyclopentadienyl iron (II) hexafluorophosphate, Xylene-cyclopentadienyl iron (II) tris (trifluoromethylsulfonyl) methanide and the like.
• photocationic polymerization initiators may be used alone or in admixture of two or more.
• aromatic sulfonium salts are particularly preferably used because they have ultraviolet absorption characteristics even in a wavelength region near 300 nm, and therefore can provide a cured product having excellent curability and good mechanical strength and adhesive strength. It is done.
• the blending amount of the photocationic polymerization initiator (B) is 1 to 10 parts by weight with respect to 100 parts by weight of the entire photocationic curable component (A).
• the cationic photocurable component (A) can be sufficiently cured, and the resulting polarizing plate is high. Gives mechanical strength and adhesive strength.
• the amount increases, the ionic substance in the cured product increases, so that the hygroscopic property of the cured product increases and the durability performance of the polarizing plate may be lowered.
• the compounding amount of the photocationic polymerization initiator (B) is preferably 2 parts by weight or more and preferably 6 parts by weight or less per 100 parts by weight of the photocationic curable component (A).
• the photocurable adhesive of the present invention is blended in a general photocurable resin or adhesive in addition to the photocationic curable component (A) and the photocationic polymerization initiator (B) containing the epoxy compound as described above.
• Other ingredients known to do can also be included.
• Preferable examples of other components include a photosensitizer and a photosensitization aid.
• the photosensitizer is a compound that exhibits maximum absorption at a wavelength longer than the maximum absorption wavelength indicated by the photocationic polymerization initiator (B) and promotes the polymerization initiation reaction by the photocationic polymerization initiator (B).
• the photosensitizing assistant is a compound that further promotes the action of the photosensitizer. Depending on the type of the protective film, it may be preferable to add such a photosensitizer and further a photosensitizer.
• the photosensitizer is preferably a compound that exhibits maximum absorption in light having a wavelength longer than 380 nm.
• the cationic photopolymerization initiator (B) exhibits maximum absorption at a wavelength near or shorter than 300 nm, generates a cationic species or a Lewis acid in response to light having a wavelength near the wavelength, and is a photocationic curable component.
• the cationic polymerization of (A) is started.
• an anthracene compound is advantageously used.
• Specific examples of the anthracene photosensitizer include the following compounds.
• the curability of the adhesive is improved as compared with the case where it is not blended.
• Such an effect is expressed by blending 0.1 part by weight or more of the photosensitizer with respect to 100 parts by weight of the photocationic curable component (A).
• the amount of the photosensitizer increases, problems such as precipitation during low-temperature storage occur, so the amount is 2 parts by weight or less with respect to 100 parts by weight of the photocationic curable component (A).
• the amount of the photosensitizer is in the range of 0.1 to 0.5 parts by weight, more preferably 0.1 to 0.3 parts by weight with respect to 100 parts by weight of the active ingredient (A).
• naphthalene compounds are advantageously used.
• Specific examples of naphthalene-based photosensitization aids include the following compounds.
• 4-methoxy-1-naphthol 4-ethoxy-1-naphthol, 4-propoxy-1-naphthol, 4-butoxy-1-naphthol, 4-hexyloxy-1-naphthol, 1,4-dimethoxynaphthalene, 1-ethoxy-4-methoxynaphthalene, 1,4-diethoxynaphthalene, 1,4-dipropoxynaphthalene, 1,4-dibutoxynaphthalene and the like.
• the curability of the adhesive is improved as compared with the case where it is not blended.
• a naphthalene photosensitizer By blending 0.1 part by weight or more of the naphthalene photosensitizer with 100 parts by weight of the photocationic curable component (A), such an effect is exhibited.
• the amount of the naphthalene photosensitizer is increased, problems such as precipitation during low-temperature storage occur. Therefore, the amount is 5 parts by weight with respect to 100 parts by weight of the photocation curable component (A)
• the content is preferably as follows, and more preferably 3 parts by weight or less.
• the photocurable adhesive demonstrated above is used in order to manufacture a polarizing plate by bonding a protective film to the polarizer which consists of a polyvinyl alcohol-type resin film as above-mentioned. At this time, if the adhesive dissolves the protective film, as described above, the dissolution may cause bubble defects in the polarizing plate.
• a photocurable adhesive containing a photocationic curable component (A) containing the above-described specific three kinds of compounds in a predetermined ratio is employed, particularly a diglycidyl compound (A2) therein.
• An adhesive having a branched structure is used as an adhesive that hardly dissolves the protective film. That is, in this adhesive, when the protective film constituting the polarizing plate is immersed for 2 days at 23 ° C., the weight loss of the protective film becomes 0 to 30% by weight.
• the weight reduction when the protective film is immersed in the adhesive can be obtained as follows. That is, first, the transparent resin film constituting the protective film is cut into an appropriate size, and its weight is obtained. Next, the cut film was prepared in a liquid state, immersed in a photo-curable adhesive maintained at 23 ° C. and left for 2 days, then taken out, and after wiping off the adhesive adhered to the surface, Find its weight. And the weight reduction after immersion is calculated
• Weight reduction (%) (1 ⁇ film weight after immersion / film weight before immersion) ⁇ 100 Moreover, after this adhesive agent apply
• the photocationic curable component (A) by blending the above-mentioned specific three kinds of compounds at a predetermined ratio, the viscosity of the photocurable adhesive is lowered and the coating suitability is improved. Is done. Specifically, the photocurable adhesive can have a viscosity at 25 ° C. of 100 mPa ⁇ sec or less.
• a protective film made of a transparent resin is bonded to at least one surface of a polarizer made of a polyvinyl alcohol-based resin film via the photocurable adhesive described above, and the photocurable adhesive is used. Is cured into a polarizing plate.
• cured material of a photocurable adhesive agent can be raised, and the adhesiveness between a polarizer and a protective film can be improved. Therefore, the adhesive strength according to the 180 degree peeling test between the polarizer and the protective film can be 0.6 N / 25 mm or more.
• the 180 degree peeling test is performed according to JIS K 6854-2: 1999 “Adhesive—Peeling peel strength test method—Part 2: 180 degree peeling”.
• the polarizer is composed of a polyvinyl alcohol-based resin film on which a dichroic dye is adsorbed and oriented.
• the polyvinyl alcohol resin constituting the polarizer can be obtained by saponifying a polyvinyl acetate resin.
• the polyvinyl acetate resin may be a copolymer of vinyl acetate, which is a homopolymer of vinyl acetate, or a copolymer of vinyl acetate and other monomers copolymerizable therewith. Examples of other monomers copolymerized with vinyl acetate include unsaturated carboxylic acids, olefins, vinyl ethers, and unsaturated sulfonic acids.
• the degree of saponification of the polyvinyl alcohol resin is usually in the range of 85 to 100 mol%, preferably 98 to 100 mol%.
• the polyvinyl alcohol resin may be further modified, for example, polyvinyl formal or polyvinyl acetal modified with aldehydes may be used.
• the degree of polymerization of the polyvinyl alcohol resin is usually in the range of 1,000 to 10,000, preferably 1,500 to 5,000.
• the polarizer is a process of uniaxially stretching such a polyvinyl alcohol-based resin film, a step of dyeing the polyvinyl alcohol-based resin film with a dichroic dye and adsorbing the dichroic dye, and a dichroic dye being adsorbed It is manufactured through a step of treating the polyvinyl alcohol resin film with a boric acid aqueous solution.
• the uniaxial stretching may be performed before dyeing with a dichroic dye, may be performed simultaneously with dyeing with a dichroic dye, or may be performed after dyeing with a dichroic dye.
• this uniaxial stretching may be performed before boric acid treatment or during boric acid treatment.
• rolls having different peripheral speeds may be uniaxially stretched or uniaxially stretched using a hot roll.
• atmosphere may be sufficient
• stretches in the state swollen with the solvent may be sufficient.
• the draw ratio is usually about 4 to 8 times.
• the polyvinyl alcohol resin film may be immersed in an aqueous solution containing the dichroic dye.
• iodine or a dichroic organic dye is used as the dichroic dye.
• iodine When iodine is used as the dichroic dye, a method of dyeing a polyvinyl alcohol resin film by immersing it in an aqueous solution containing iodine and potassium iodide is usually employed.
• the content of iodine in this aqueous solution is usually about 0.01 to 0.5 parts by weight per 100 parts by weight of water, and the content of potassium iodide is usually about 0.5 to 10 parts by weight per 100 parts by weight of water. It is.
• the temperature of this aqueous solution is usually about 20 to 40 ° C.
• the immersion time (dyeing time) in this aqueous solution is usually about 30 to 300 seconds.
• a method of immersing and dyeing a polyvinyl alcohol-based resin film in an aqueous solution containing a water-soluble dichroic organic dye is usually employed.
• the content of the dichroic organic dye in this aqueous solution is usually about 1 ⁇ 10 ⁇ 3 to 1 ⁇ 10 ⁇ 2 parts by weight per 100 parts by weight of water.
• This aqueous solution may contain an inorganic salt such as sodium sulfate.
• the temperature of this aqueous solution is usually about 20 to 80 ° C., and the immersion time (dyeing time) in this aqueous solution is usually about 30 to 300 seconds.
• the boric acid treatment after dyeing with a dichroic dye is performed by immersing the dyed polyvinyl alcohol resin film in an aqueous boric acid solution.
• the boric acid content in the boric acid aqueous solution is usually about 2 to 15 parts by weight, preferably about 5 to 12 parts by weight per 100 parts by weight of water.
• the aqueous boric acid solution preferably contains potassium iodide.
• the content of potassium iodide in the boric acid aqueous solution is usually about 2 to 20 parts by weight, preferably 5 to 15 parts by weight per 100 parts by weight of water.
• the immersion time in the boric acid aqueous solution is usually about 100 to 1,200 seconds, preferably about 150 to 600 seconds, and more preferably about 200 to 400 seconds.
• the temperature of the boric acid aqueous solution is usually 50 ° C. or higher, preferably 50 to 85 ° C.
• the polyvinyl alcohol resin film after the boric acid treatment is usually washed with water.
• the water washing treatment is performed, for example, by immersing a boric acid-treated polyvinyl alcohol resin film in water.
• a drying process is performed to obtain a polarizer.
• the temperature of water in the water washing treatment is usually about 5 to 40 ° C., and the immersion time is usually about 2 to 120 seconds.
• the drying process performed thereafter is usually performed using a hot air dryer or a far infrared heater.
• the drying temperature is usually 40 to 100 ° C. Further, the drying process time is usually about 120 to 600 seconds.
• the thickness of the polarizer made of the polyvinyl alcohol-based resin film thus obtained can be about 10 to 50 ⁇ m.
• a protective film is bonded to the polarizer composed of the polyvinyl alcohol-based resin film described above via the photocurable adhesive described above, and the photocurable adhesive is cured to obtain a polarizing plate.
• the protective film can be composed of an acetylcellulose-based resin film such as triacetylcellulose, which has been most widely used as a protective film for polarizing plates, or a resin film having a lower moisture permeability than triacetylcellulose. Moisture permeability of triacetyl cellulose is approximately 400g / m 2 / 24hr approximately.
• the protective film bonded to at least one surface of the polarizer is composed of an acetylcellulose-based resin.
• the protective film bonded to one surface of the polarizer can be composed of an acetyl cellulose resin in which an ultraviolet absorber is blended.
• the resin constituting such a resin film with low moisture permeability include amorphous polyolefin resin, polyester resin, acrylic resin, polycarbonate resin, and chain polyolefin resin.
• amorphous polyolefin resins, polyester resins, and chain polyolefin resins are preferably used.
• a protective film made of an acetylcellulose-based resin is bonded to one surface of the polarizer via the adhesive layer, and the other surface of the polarizer is also interposed via the adhesive layer. Then, a protective film made of a transparent resin having a low moisture permeability as described above is bonded.
• An acetyl cellulose resin is a resin in which at least a part of hydroxyl groups in cellulose is acetate esterified, even if it is a mixed ester in which part is acetated and partly esterified with another acid. Good.
• Specific examples of the acetyl cellulose resin include triacetyl cellulose, diacetyl cellulose, cellulose acetate propionate, and cellulose acetate butyrate.
• An amorphous polyolefin-based resin is a polymer having a polymerized unit of cyclic olefin, such as norbornene, tetracyclododecene (also known as dimethanooctahydronaphthalene), or a compound having a substituent bonded thereto. It may be a copolymer obtained by copolymerizing a chain olefin and / or an aromatic vinyl compound.
• thermoplastic norbornene resins are typical.
• the polyester resin is a polymer obtained by condensation polymerization of a dibasic acid and a dihydric alcohol, and polyethylene terephthalate is representative.
• Acrylic resin is a polymer with methyl methacrylate as the main monomer. In addition to methyl methacrylate homopolymer, methyl methacrylate and acrylic esters and aromatic vinyl compounds such as methyl acrylate It may be a copolymer.
• the polycarbonate resin is a polymer having a carbonate bond (—O—CO—O—) in the main chain, and is typically obtained by condensation polymerization of bisphenol A and phosgene.
• the chain polyolefin-based resin is a polymer mainly containing a chain olefin such as ethylene or propylene, and can be a homopolymer or a copolymer. Among them, a propylene homopolymer and a copolymer in which a small amount of ethylene is copolymerized with propylene are representative.
• Such a protective film has various surface treatment layers such as a hard coat layer, an antireflection layer, an antiglare layer, or an antistatic layer on the surface opposite to the surface to be bonded to the polarizer. It may be.
• the protective film can have a thickness of about 5 to 150 ⁇ m including the case where such a surface treatment layer is formed. The thickness is preferably 10 ⁇ m or more, preferably 120 ⁇ m or less, more preferably 100 ⁇ m or less.
• the photocurable adhesive coating layer described above is formed on one or both of the bonding surfaces of the polarizer and the protective film, and the polarizer and the protective film are formed via the coating layer.
• the coating layer of the uncured photocurable adhesive thus bonded is cured by irradiation with active energy rays, and the protective film is fixed on the polarizer.
• the application layer of a photocurable adhesive may be formed on the bonding surface of the polarizer, or may be formed on the bonding surface of the protective film.
• various coating methods such as a doctor blade, a wire bar, a die coater, a comma coater, and a gravure coater can be used.
• a solvent that dissolves the photocurable adhesive satisfactorily without reducing the optical performance of the polarizer is used, but there is no particular limitation on the type thereof.
• the thickness of the adhesive layer is usually 20 ⁇ m or less, preferably 10 ⁇ m or less, more preferably 5 ⁇ m or less. When the adhesive layer is thick, the reaction rate of the adhesive is lowered, and the wet heat resistance of the polarizing plate tends to deteriorate.
• the corona discharge treatment, plasma treatment, flame treatment, primer treatment, or anchor coating treatment is performed before forming the coating layer of the adhesive on one or both of the bonding surfaces of both.
• Such an easy adhesion treatment may be performed.
• the light source used for irradiating active energy rays to the coating layer of the photocurable adhesive may be any one that generates ultraviolet rays, electron beams, X-rays, and the like.
• a low pressure mercury lamp, a medium pressure mercury lamp, a high pressure mercury lamp, an ultrahigh pressure mercury lamp, a chemical lamp, a black light lamp, a microwave excitation mercury lamp, a metal halide lamp, etc. having a light emission distribution at a wavelength of 400 nm or less are preferably used.
• the active energy ray irradiation intensity to the photocurable adhesive is determined for each target composition and is not particularly limited.
• the irradiation intensity in the wavelength region effective for activating the photocationic polymerization initiator is not limited. It is preferable to be 0.1 to 100 mW / cm 2 . If the light irradiation intensity on the photocurable adhesive is too small, the reaction time becomes too long. On the other hand, if the light irradiation intensity is too large, the heat radiated from the lamp and the heat generation during polymerization of the photocurable adhesive will occur. This may cause yellowing of the photocurable adhesive and deterioration of the polarizer.
• the light irradiation time to the photocurable adhesive is controlled for each composition to be cured and is not particularly limited, but the integrated light amount represented by the product of the irradiation intensity and the irradiation time is 10 to 5 It is preferably set to be 000 mJ / cm 2 . If the cumulative amount of light to the photocurable adhesive is too small, the generation of active species derived from the photocationic polymerization initiator may not be sufficient, and the resulting adhesive layer may be insufficiently cured, while that If an attempt is made to increase the integrated light quantity, the irradiation time becomes very long, which is disadvantageous for improving productivity.
• the active energy ray may be irradiated from either side of the protective film.
• one protective film contains an ultraviolet absorber and the other protective film
• the ultraviolet absorber is not contained, it is preferable to irradiate the active energy ray from the protective film side not containing the ultraviolet absorber in order to effectively utilize the irradiated active energy ray and increase the curing rate.
• the polarizing plate of the present invention can be made into a laminated optical member by laminating optical layers having optical functions other than the polarizing plate.
• a laminated optical member is obtained by laminating and attaching an optical layer to a protective film of a polarizing plate via an adhesive or a pressure-sensitive adhesive.
• a protective film may be bonded via a photocurable adhesive, and an optical layer may be laminated and bonded to the other surface of the polarizer via an adhesive or a pressure-sensitive adhesive.
• the photocurable adhesive defined in the present invention is used as an adhesive for adhering the polarizer and the optical layer, the optical layer can simultaneously be a protective film defined in the present invention.
• the reflective layer is laminated on the opposite side of the polarizing plate from the side facing the liquid crystal cell.
• a layer, a transflective layer, a light diffusing layer, a light collector, and a brightness enhancement film is laminated on the opposite side of the polarizing plate from the side facing the liquid crystal cell.
• a retardation film laminated on the side of the polarizing plate facing the liquid crystal cell, etc.
• the reflective layer, transflective layer, or light diffusing layer is a reflective polarizing plate (optical member), a transflective polarizing plate (optical member), or a diffusing polarizing plate (optical member), respectively.
• the reflective polarizing plate is used in a liquid crystal display device of a type that reflects and displays incident light from the viewing side. Since a light source such as a backlight can be omitted, the liquid crystal display device can be easily thinned.
• the transflective polarizing plate is used as a reflection type in a bright place and used in a liquid crystal display device that displays light from a backlight in a dark place.
• the optical member as a reflective polarizing plate can form a reflective layer, for example, by attaching a foil or a vapor deposition film made of a metal such as aluminum to a protective film on a polarizer.
• the optical member as a transflective polarizing plate can be formed by using the reflective layer as a half mirror, or by adhering a reflective plate containing a pearl pigment or the like and exhibiting light transmittance to the polarizing plate.
• optical members as diffusion type polarizing plates can be applied to various methods such as a method of performing a mat treatment on a protective film on a polarizing plate, a method of applying a resin containing fine particles, and a method of adhering a film containing fine particles. Use to form a fine relief structure on the surface.
• optical member that acts as a polarizing plate for both reflection and diffusion.
• the reflective layer having a fine concavo-convex structure has advantages such that incident light is diffused by irregular reflection, directivity and glare can be prevented, and uneven brightness can be suppressed.
• the resin layer or film containing fine particles also has an advantage that incident light and its reflected light are diffused when passing through the fine particle-containing layer, and brightness unevenness can be suppressed.
• the reflective layer reflecting the surface fine concavo-convex structure can be formed by directly attaching a metal to the surface of the fine concavo-convex structure by a method such as vacuum deposition, ion plating, or vapor deposition such as sputtering or plating.
• the fine particles to be blended to form the fine surface uneven structure include, for example, silica, aluminum oxide, titanium oxide, zirconia, tin oxide, indium oxide, cadmium oxide, and antimony oxide having an average particle diameter of 0.1 to 30 ⁇ m. It may be inorganic fine particles, organic fine particles such as a crosslinked or non-crosslinked polymer, and the like.
• the condensing plate is used for the purpose of optical path control and can be formed as a prism array sheet, a lens array sheet, or a dot-attached sheet.
• the brightness enhancement film is used for the purpose of improving the brightness in a liquid crystal display device.
• a plurality of thin film films having different refractive index anisotropies are laminated to produce anisotropy in reflectance.
• Examples thereof include a reflective polarization separation sheet designed as described above, an oriented film of a cholesteric liquid crystal polymer, and a circularly polarized light separation sheet in which the oriented liquid crystal layer is supported on a film substrate.
• the above-mentioned retardation film acting as an optical layer is used for the purpose of compensation of retardation by a liquid crystal cell.
• a liquid crystal cell examples thereof include a birefringent film made of a stretched film of various plastics, a film in which a discotic liquid crystal or a nematic liquid crystal is oriented and fixed, and a film substrate on which the above liquid crystal layer is formed.
• a cellulose resin film such as triacetyl cellulose is preferably used as the film substrate.
• plastic forming the birefringent film examples include amorphous polyolefin resins, polycarbonate resins, acrylic resins, chain polyolefin resins such as polypropylene, polyvinyl alcohol, polystyrene, polyarylate, polyamide, and the like. It is done.
• the stretched film can be processed by an appropriate method such as uniaxial or biaxial. Two or more retardation films may be used in combination for the purpose of controlling optical characteristics such as broadening the bandwidth.
• those including a retardation film as an optical layer other than the polarizing plate are preferably used because they can effectively ensure optical security when applied to a liquid crystal display device.
• the optimum retardation value (in-plane and thickness direction) of the retardation film may be selected according to the applied liquid crystal cell.
• the laminated optical member can be a laminate of two layers or three or more layers by combining a polarizing plate and one layer or two or more layers selected according to the purpose of use from the various optical layers described above.
• the various optical layers forming the laminated optical member are integrated with the polarizing plate using an adhesive or pressure-sensitive adhesive, but the adhesive or pressure-sensitive adhesive layer used for this purpose is good.
• a pressure-sensitive adhesive also referred to as a pressure-sensitive adhesive
• the pressure-sensitive adhesive those having an acrylic polymer, a silicone polymer, polyester, polyurethane, polyether, or the like as a base polymer can be used.
• acrylic adhesives like acrylic adhesives, it has excellent optical transparency, retains appropriate wettability and cohesion, has excellent adhesion to substrates, and has weather resistance and heat resistance.
• alkyl esters of (meth) acrylic acid having an alkyl group having 20 or less carbon atoms such as methyl, ethyl and butyl groups, and (meth) acrylic acid and hydroxyethyl (meth) acrylate An acrylic copolymer having a weight average molecular weight of 100,000 or more, in which a glass transition temperature is preferably 25 ° C. or less, more preferably 0 ° C. or less, and a functional group-containing acrylic monomer comprising Useful as a base polymer.
• the pressure-sensitive adhesive layer is formed on the polarizing plate by, for example, dissolving or dispersing the pressure-sensitive adhesive composition in an organic solvent such as toluene or ethyl acetate to prepare a 10 to 40% by weight solution, which is directly applied on the polarizing plate. It can be carried out by a coating method, a method in which an adhesive layer is previously formed on a protective film, and transferred onto a polarizing plate.
• the thickness of the pressure-sensitive adhesive layer is determined according to the adhesive force and the like, but a range of about 1 to 50 ⁇ m is appropriate.
• the pressure-sensitive adhesive layer is blended with fillers made of glass fibers, glass beads, resin beads, metal powders and other inorganic powders, pigments, colorants, antioxidants, UV absorbers, etc. as necessary. It may be.
• ultraviolet absorbers include salicylic acid ester compounds, benzophenone compounds, benzotriazole compounds, cyanoacrylate compounds, and nickel complex compounds.
• the laminated optical member can be arranged on one side or both sides of the liquid crystal cell.
• the liquid crystal cell to be used is arbitrary.
• a liquid crystal display device using various liquid crystal cells such as an active matrix drive type represented by a thin film transistor type and a simple matrix drive type represented by a super twisted nematic type. Can be formed.
• the same adhesive as described above is usually used for adhesion between the laminated optical member and the liquid crystal cell.
• Examples 1 to 4 and Comparative Examples 1 to 3 (1) Preparation of photocurable adhesive
• the photocationic curable component and the photocationic polymerization initiator described above were mixed at the blending ratio (unit: part) shown in Table 1, and then defoamed to provide photocurable adhesive.
• a drug solution was prepared.
• a photocationic polymerization initiator (b1) was mix
• Weight reduction (%) (1 ⁇ film weight after immersion / film weight before immersion) ⁇ 100
• the ternary adhesive comprising alicyclic diepoxy compound (a1) blended with diglycidyl ether (a21) having a branched alkylene as a linking group and monofunctional epoxy compound (a3) is a protective film.
• the solubility of the acetylcellulose-based resin film is small, since the blending ratio of the alicyclic diepoxy compound (a1) is large, the viscosity becomes high and the coating suitability when applied to the protective film or the polarizer is not sufficient. .
• the retardation film used in Examples 1 to 4 was bonded to one surface of a polarizer having iodine adsorbed and oriented on a polyvinyl alcohol film through the photocurable adhesive prepared in Examples 1 to 4. And, if the other surface of the polarizer is bonded with a triacetyl cellulose film having a thickness of 80 ⁇ m via the same adhesive, and irradiated with ultraviolet rays from the retardation film side, it exhibits a good adhesive force. A polarizing plate is obtained.
• the amount of the alicyclic diepoxy compound (a1) in the photocationic curable component is 50% or more, high adhesive strength can be obtained.

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