WO2012060768A1 - Procédé de fabrication de produits engrais à partir de résidus - Google Patents

Procédé de fabrication de produits engrais à partir de résidus Download PDF

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Publication number
WO2012060768A1
WO2012060768A1 PCT/SE2011/051295 SE2011051295W WO2012060768A1 WO 2012060768 A1 WO2012060768 A1 WO 2012060768A1 SE 2011051295 W SE2011051295 W SE 2011051295W WO 2012060768 A1 WO2012060768 A1 WO 2012060768A1
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WO
WIPO (PCT)
Prior art keywords
product
process according
phase
wet phase
agglomeration
Prior art date
Application number
PCT/SE2011/051295
Other languages
English (en)
Inventor
Gunnar Thelin
Original Assignee
Ekobalans Fenix Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ekobalans Fenix Ab filed Critical Ekobalans Fenix Ab
Priority to EP11838319.9A priority Critical patent/EP2635542A4/fr
Publication of WO2012060768A1 publication Critical patent/WO2012060768A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05B—PHOSPHATIC FERTILISERS
    • C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
    • C02F11/147—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents using organic substances
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05C—NITROGENOUS FERTILISERS
    • C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F1/00—Fertilisers made from animal corpses, or parts thereof
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00—Fertilisers from human or animal excrements, e.g. manure
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F7/00—Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00—Fertilisers from household or town refuse
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/20—Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/105—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/16—Nitrogen compounds, e.g. ammonia
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Definitions

  • the present invention relates to a process for the production of a fertilizer product from a residual product.
  • US4098006 there is disclosed a process for drying organic waste, such as sewage sludge, by contacting the organic waste with hot vapors. Partial dewatering of the organic waste is achieved by admixture with a recycled portion of dried solids followed by extrusion of the mixture. The resultant extrudate is then dried, and the unrecyded portion is extruded in a separate operation to form compacted granules said to have good flow characteristics and being suitable for application by commercial fertilizer spreaders.
  • organic waste such as sewage sludge
  • US5918448 there is described a method said to improve the dewatering and odor reduction characteristics of a liquid wastewater sludge, sediment, or soils to ultimately form a dewatered solid residual that includes nutrition enhancement of a resultant material that is suitable for distribution and marketing, and for incorporation in a fertilizer blend.
  • the method includes the addition of selective acids, such as sulphuric acid, phosphoric acid or nitric add, and bases, magnesium oxide, calcium oxide, potassium oxide, ammonia or calcium hydroxide, to the liquid sludge which forms insoluble precipitates, and enmeshes the solids in the sludge to form a granular product.
  • One aim of the present invention is to provide a process involving the optimal set of steps.
  • another purpose of the present invention is to provide improvements within different single steps of the process, such as in relation to e.g. the first treatment of the residual product and also in relation to the end treatment when providing a fertilizer product.
  • the first purpose above is achieved by a process for the production of a fertilizer product from a residual product, said process comprising the steps of:
  • the residual product used for the present invention may e.g. be sludge (wastewater sludge), digestate(s), manure residues, such as liquid manure not being fermented, or the like.
  • the step of dewatering of the residual product and the separation of the dry phase and the wet phase is normally made simultaneously.
  • process equipment types may be used to perform the process according to the pre- sent invention, such as continuous processing but also batch or semi-batch operations. Some steps are naturally performed batch-wise, however other steps may also be performed continuously.
  • a negative pressure applied from the dewatering to the stripping and subsequent reaction between ammonia ((NH 3 ), (g)) and an acid or a mixture of two or several acids and/or salt solutions This implies that a negative pressure (underpressure) is applied from the dewatering step and forward to drive any produced gaseous (volatilized) ammonia towards and into the container intended to collect this gas component, i.e. the container where ammonia is reacted with an acid or a mixture of two or several acids and/or salt solutions to produce nitrogen (N) in some solid form as a product no 3.
  • ammonia may e.g. be produced in minor amounts already at the dewatering step or for instance in the precipitation.
  • the process according to the present invention comprises dewatering/separation, precipitation, ammonia generation, acid treatment and provision of end product, the latter being made by agglomeration, such as e.g. granulation, pelletization and compaction.
  • the present invention provides a method for treatment of residual products which focuses on optimization of total yield of nutrients and hence provides economic advantages in comparison to today known processes.
  • Such known pretreatments today only have the purpose of providing a mixture which is easier to dewater.
  • the optional pretreatment is provided to optimize the total yield of nutrients as well as providing a mixture which is easy to dewater and separa- te.
  • the pretreatment is any one of flocculation, fiber addition, pH adjustment, addition of a divalent ion solution, magnetic field provision or a combination thereof.
  • flocculation is a process where colloids come out of suspension in the form of floe or flakes.
  • flocculation is performed by adding a substance, e.g. a polymer, which improves the dewatering ability of the residual product by binding organic material into larger aggregates.
  • Added fiber improves the dewatering ability as suspended organic material (SOM) is bound to the added fibers.
  • the fibers can act as "filter material" in the filtering process. When a sludge including fibers is filtered, fibers will be deposited on the filter and this will greatly enhance the specific surface area available for binding of SOM. This effect can also be used by first filtering a small amount of sludge with fiber added and then sludge without fiber. Alternatively, the sludge can be filtered through a fiber material. Fiber addition may be a better alternative than polymer addition, since the intended types of fiber is much cheaper than polymers, and the added fiber can be used as energy in the dry phase. The risk of both flocculation and fiber addition is that too large nutrient fractions are allocated to the dry phase.
  • a divalent ion solution e.g. calcium or magnesium hydroxide
  • a divalent ion solution will release positively charged nutrient ions and lower the need for pH increase later in the precipitation step, as in the above case.
  • divalent cations will not disperge the organic material, but instead bind it together.
  • a divalent calcium ion can bind to two different pieces of organic material and thus probably improve the dewatering ability.
  • the step of dewatering of the residual product and separation of the dry phase and the wet phase also involves removing of heavy metal compounds which are collected in the dry phase. Heavy metals in the residual product are to a very high degree strongly bound to the organic material. Thus a dewatering step removing organic material from the solution will simultaneously remove the bulk of the heavy metals from the solution. This effect can be increased by the addition of substances with a high capa- city of binding heavy metals.
  • the heavy metals follow the dry phase.
  • the heavy metals shall eventually also be separated from the dry phase and be deposited.
  • Such separation from the dry phase may be performed both before, such as by use of a substance with a high capacity of binding heavy metals as disclosed above, and also after the combustion of the dry phase.
  • this may be performed either by first removal of phosphor- rous and other nutrients from the ash so that the heavy metals afterwards will be found in a residue, or by first removal of the heavy metals from the ash so that the nutrients will be found in a residue. Therefore, according to one specific embodiment of the process according to the present invention, the heavy metal compounds are separated either from the dry phase (product no 1 ) before combustion, or from the ash after combustion of the dry phase
  • the dry phase may be seen as or called the organic phase.
  • organic material is intended to be collected in the dry phase.
  • Fact is that the maximum level of organic material in the wet phase is intended to be set at 5%.
  • the separation of a dry and wet phase may also be seen as a separation of organic material so that the level of such organic material is depressed in the wet phase.
  • precipitation of the wet phase to form at least phosphorous (P) in some solid form is performed after the separation step.
  • different solid P forms are possible. Examples thereof are struvite (ammonium magnesium phosphate, formula ((NH )MgPO 4 -6H 2 O)), apatites, other calcium phosphates or combinations thereof.
  • Apatite is a group of phosphate minerals, usually referring to hydroxyapatite, fluorapatite, chlor- apatite and bromapatite.
  • the formulas of the admixtures of the four most common are written as Caio(PO 4 )6(OH, F, CI, Br) 2 . It is important to understand that many other solid forms are possible according to the present invention, such as e.g. calcium phosphate (Ca3(PO 4 )2).
  • the precipitate in this example struvite, may be produced by e.g. adding magnesium dichloride (MgC ⁇ ) and sodium hydroxide (NaOH), either in one container e.g. simultaneously or in different containers sequentially. Either of them may be added first in the process.
  • the precipitate may also be produced by increasing the pH value of the wet phase by stripping CO2 (g) from the mixture. At pH value about 8-9, struvite begins to precipitate.
  • this solution is fed to a filter, where the precipitate struvite is separated and thereafter obtained by dewatering. Filtration is one suitable technique for this step, however also other separation techniques are possible to use.
  • struvite when describing precipitations, both crystalline and amorphous precipitations, as well as combinations thereof, are contemplated in relation to the present invention.
  • One advantage of producing struvite is the fact that it crystallizes very clearly.
  • seed charging may be used during the precipitation to increase the efficiency of the process step.
  • struvite may in fact be produced in minor amounts to function as a seed promoting the precipitation of other amorphous and/or crystalline precipitates. In other words, in this case struvite only functions as a precipitation promoter and is not intended as the main precipitation
  • MgC ⁇ and NaOH may be used as precipitation promoting substances for precipitation of P solids.
  • Other known such substances are magnesium sulphate (MgSO 4 ), calcium chloride (CaC ), calcium hydroxide (Ca(OH) 2 ), calcium sulphate (gypsum, CaSO 4 * 1 ⁇ 2H 2 O) and in fact also sea water or bittern, a residual product after the evaporation and crystallization of sodium chloride from brines and sea water.
  • Bittern contains, in concentrated form, the calcium and magnesium chlorides and sulfates, bromides, iodides, and other chemicals originally present in the brine. These substances are known for usage in precipitation steps as according to above.
  • green liquor sludge is used as the precipitation promoting substance.
  • Green liquor sludge is a residual product from pulping processes and it contains inter alia metal salts, mainly sulphides including magnesium sulphide.
  • potassium (K) and/or nitrogen (N) in some solid form is precipitated in the step of precipitation of the wet phase.
  • the amount of potassium in the residual product used varies a lot.
  • the purpose of the invention is of course to obtain as much potassium as possible from the start residual product. If potassium is present, it is present in the wet phase after separation according to the invention. According to the present invention it is possible to precipitate at least 50%, such as at least 70%, e.g. in the range of 70-95%, of the potassium present in the wet phase.
  • Nitrogen may be produced in different solid forms. According to one specific embodiment of the present invention, nitrogen (N) is precipitated in some solid nitrate form.
  • ammonia production is involved.
  • Such a production may comprise further processing of the wet phase before the actual stripping.
  • the wet phase is further processed to an ammonium (NH + ) enriched solution which is subsequently stripped to produce ammonia ((NH 3 ), (g)) which then is reacted with an acid or a mixture of two or several acids and/or salt solutions to produce nitrogen (N) in some solid form as a product no 3.
  • the wet phase is further processed to an ammonium (NH + ) enriched solution by contacting the remaining wet phase with at least one ion exchanger.
  • Such treatment may e.g.
  • zeolite functions as an ion exchanger, but it is important to understand that also other such exchangers may be used.
  • cleaning water solution which may be recirculated back to the dewatering or in fact used as clean process water, and ammonium solution is produced.
  • the ammonium solution is fed to a stripper, e.g. holding a pressure of 0.5-0.9 bar, where ammonia ((NH 3 ), (g)) and "clean" water solution is produced, the latter e.g. processed together with clean water solution from the ion exchange treatment.
  • the ammonia is flowed into an acid tank so that remaining nitrogen (N) is produced in some solid form.
  • Different acids may be used, such as e.g. sulphuric acid (H 2 SO 4 ), hydrochloric acid (HCI) and nitric acid (HNO3), the latter however not in clean form as ammonium nitrate (NH NO3), which is explosive, of course is undesirable.
  • HCI hydrochloric acid
  • HNO3 nitric acid
  • NH NO3 ammonium nitrate
  • a mixture of two or several acids and/or salt solutions may also be used.
  • ammonium sulphate (NH 4 ) 2 SO 4 ) is produced as the nitrogen solid form after the acid treatment.
  • the nitrogen solid form is obtained after sedimentation.
  • the present process achieves a level of at least 90% of the nitrogen (N) in the wet phase being collected in a solid form.
  • the last step according to the present process is the agglomeration of at least one of the obtained solid products from the process for the production of a fertilizer product.
  • substances from ash from combusted product no 1 i.e. obtained from the separation, or from other types of ash is admixed with at least one of the products no 2, i.e. obtained from the precipitation, and/or 3, i.e. from the acid treatment, for the production of a fertilizer product.
  • the agglomeration may according to the present invention be perfor- med in different ways and by different means. According to one specific embodiment of the present invention, the agglomeration is performed by granulation, peptization or compaction. Granulation may be preferred in some applications according to the invention. Granulation may e.g. be performed by drum granulation or by means of a fluidized bed.
  • the agglomeration step may besides the actual mechanical treatment also involve other treatment, such as e.g. adding at least one agglomeration promoting substance.
  • the agglomeration is performed by granulation and the granulation involves adding a binder, said binder in this case being the agglomeration (granulation) promoting substance.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fertilizers (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)

Abstract

La présente invention concerne un procédé de fabrication d'un produit engrais à partir d'un produit résiduel, ledit procédé comprenant les étapes consistant à déshydrater le produit résiduel et à séparer la phase sèche et la phase humide, à recueillir la phase sèche en tant que produit n°1, à faire précipiter la phase humide pour former au moins du phosphore (P) sous une forme solide en tant que produit n°2, à effectuer un stripping de la phase humide restante pour produire de l'ammoniac ((NH3), (g)) qui est ultérieurement mis à réagir avec un acide ou un mélange d'au moins deux acides et/ou solutions salines pour produire de l'azote (N) sous une forme solide en tant que produit n°3 et à agglomérer au moins l'un des produits n°2 et/ou n°3 pour la fabrication d'un produit engrais.
PCT/SE2011/051295 2010-11-01 2011-10-31 Procédé de fabrication de produits engrais à partir de résidus WO2012060768A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP11838319.9A EP2635542A4 (fr) 2010-11-01 2011-10-31 Procédé de fabrication de produits engrais à partir de résidus

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE1051144A SE535315C2 (sv) 2010-11-01 2010-11-01 Förfarande för framställning av gödningsmedelsprodukter från restprodukter
SE1051144-2 2010-11-01

Publications (1)

Publication Number Publication Date
WO2012060768A1 true WO2012060768A1 (fr) 2012-05-10

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ID=46024703

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Application Number Title Priority Date Filing Date
PCT/SE2011/051295 WO2012060768A1 (fr) 2010-11-01 2011-10-31 Procédé de fabrication de produits engrais à partir de résidus

Country Status (3)

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EP (1) EP2635542A4 (fr)
SE (1) SE535315C2 (fr)
WO (1) WO2012060768A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017140957A1 (fr) * 2016-02-19 2017-08-24 Aalto University Foundation Sr Production d'engrais minéral à partir de déchets liquides
EP3375760A1 (fr) * 2017-03-13 2018-09-19 Joachim Clemens Procédé de précipitation de phosphore et de sodium dans des eaux usées
EP4023611A1 (fr) * 2020-12-30 2022-07-06 LaBaerle Holding BV Procédé et dispositif de traitement du purin

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6464875B1 (en) * 1999-04-23 2002-10-15 Gold Kist, Inc. Food, animal, vegetable and food preparation byproduct treatment apparatus and process
WO2006005733A1 (fr) * 2004-07-08 2006-01-19 Hans Huber Ag Maschinen- Und Anlagenbau Procede et dispositif destines a la separation du phosphate de magnesium et d'ammonium (map) a partir des eaux usees
US20090206028A1 (en) * 2008-02-20 2009-08-20 Anping Jiang Combined nutrient recovery and biogas scrubbing system integrated in series with animal manure anaerobic digester

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2343832A1 (fr) * 2001-04-11 2002-10-11 Atd Waste Systems Inc. Systeme de traitement des dechets animaux

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6464875B1 (en) * 1999-04-23 2002-10-15 Gold Kist, Inc. Food, animal, vegetable and food preparation byproduct treatment apparatus and process
WO2006005733A1 (fr) * 2004-07-08 2006-01-19 Hans Huber Ag Maschinen- Und Anlagenbau Procede et dispositif destines a la separation du phosphate de magnesium et d'ammonium (map) a partir des eaux usees
US20090206028A1 (en) * 2008-02-20 2009-08-20 Anping Jiang Combined nutrient recovery and biogas scrubbing system integrated in series with animal manure anaerobic digester

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2635542A4 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017140957A1 (fr) * 2016-02-19 2017-08-24 Aalto University Foundation Sr Production d'engrais minéral à partir de déchets liquides
EP3375760A1 (fr) * 2017-03-13 2018-09-19 Joachim Clemens Procédé de précipitation de phosphore et de sodium dans des eaux usées
EP4023611A1 (fr) * 2020-12-30 2022-07-06 LaBaerle Holding BV Procédé et dispositif de traitement du purin
NL2027252B1 (en) * 2020-12-30 2022-07-21 LaBaerle Holding BV Method and device for processing liquid manure

Also Published As

Publication number Publication date
SE1051144A1 (sv) 2012-05-02
EP2635542A4 (fr) 2017-12-27
SE535315C2 (sv) 2012-06-26
EP2635542A1 (fr) 2013-09-11

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