WO2012058839A1 - Revêtement hydrosoluble pour le traitement anti-corrosion de pièces d'ingénierie résistantes au climat océanique et procédé de préparation - Google Patents

Revêtement hydrosoluble pour le traitement anti-corrosion de pièces d'ingénierie résistantes au climat océanique et procédé de préparation Download PDF

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Publication number
WO2012058839A1
WO2012058839A1 PCT/CN2010/079676 CN2010079676W WO2012058839A1 WO 2012058839 A1 WO2012058839 A1 WO 2012058839A1 CN 2010079676 W CN2010079676 W CN 2010079676W WO 2012058839 A1 WO2012058839 A1 WO 2012058839A1
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WO
WIPO (PCT)
Prior art keywords
balance
alloy powder
coating
silicon alloy
aluminum zinc
Prior art date
Application number
PCT/CN2010/079676
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English (en)
Chinese (zh)
Inventor
冯立新
张敏燕
缪强
Original Assignee
江苏麟龙新材料股份有限公司
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Application filed by 江苏麟龙新材料股份有限公司 filed Critical 江苏麟龙新材料股份有限公司
Priority to JP2013536978A priority Critical patent/JP5604010B2/ja
Priority to KR1020137014411A priority patent/KR101464287B1/ko
Publication of WO2012058839A1 publication Critical patent/WO2012058839A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/10—Anti-corrosive paints containing metal dust
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084—Inorganic compounds

Definitions

  • the present invention relates to a water-soluble aluminum-zinc-silicon coating for anti-corrosion treatment of marine weather resistant engineering parts and a preparation method thereof.
  • BACKGROUND OF THE INVENTION Engineering and equipment in offshore and marine environments are characterized by heavy rain, high temperature, salty fog and strong wind flow.
  • the service conditions are generally in accordance with ISO 9225 environmental assessment standard > C5, which is an extremely harsh environment. Exposed parts will be subjected to strong atmospheric corrosion, electrochemical corrosion and airflow erosion.
  • the service life of various steel structures is much lower than that of general inland outdoor environments.
  • the hot-dip alloy coating has a high process temperature (greater than 800 ° C), which is easy to cause deformation of the part; insufficient wear resistance and anti-erosion ability; complicated process and equipment, large-area workpiece processing and field treatment
  • process temperature greater than 800 ° C
  • metal surface anti-corrosion treatment technologies developed in the 1970s such as the common sheet-like zinc-based chromium salt protective coating, have also been used to treat corrosion protection of offshore engineering components.
  • this coating contains hexavalent chromium and is contaminated.
  • the coating has a curing temperature of up to 300 ° C, a curing time of about 30 minutes, and high energy consumption; low hardness and poor wear resistance. Workpieces are often subject to transportation, assembly, and use To scratches and scratches, affecting the appearance and corrosion resistance of the product. SUMMARY OF THE INVENTION
  • the present invention provides an aluminum-zinc-silicon coating which is environmentally friendly, water-soluble, low-temperature curing, marine weathering corrosion, and a preparation method thereof.
  • the powder comprises three basic elements of Al, Zn and Si, and further comprises one or more elements selected from the group consisting of magnesium, rare earth, titanium, nickel and manganese.
  • the organic solvent is preferably ethylene glycol.
  • the binder is preferably a borate coupling agent.
  • the corrosion inhibitor is preferably boric acid.
  • the thickener is preferably hydroxyethyl cellulose.
  • the dispersing agent is preferably polysiloxane dipropylene glycol monomethyl ether.
  • the nano-oxide particle reinforcing agent is selected from one or both of A1 2 O 3 and Si0 2 . More preferably, the average particle diameter of the A1 2 0 3 is 15 to 60 nm, and the average particle diameter of the SiO 2 is 25 to 70 nm.
  • the nano oxide particle reinforcing agent is Si0 2 and A1 2 0 3 , and the mass ratio of Si0 2 and A1 2 0 3 is 1: (1 to 3).
  • the aluminum zinc silicon alloy powder has an average diameter of 10 to 200 m.
  • the mass percentage of ⁇ in the aluminum zinc silicon alloy powder is: 35 to 58%.
  • the mass percentage of Si in the aluminum zinc silicon alloy powder is 0.3 to 4.0%.
  • the mass percentage of Mg in the aluminum zinc silicon alloy powder is 0.1 to 5.0%.
  • the mass percentage of RE in the aluminum zinc silicon alloy powder is: 0.02 to 1.0%.
  • the mass percentage of Ti in the aluminum zinc silicon alloy powder is 0.01 to 0.5%.
  • the mass percentage of Ni in the aluminum zinc silicon alloy powder is 0.1 to 3.0%.
  • the mass percentage of Mn in the aluminum zinc silicon alloy powder is 0.01 to 1.0%.
  • the balance of each component of the aluminum zinc silicon alloy powder is A1 and unavoidable impurities.
  • the present invention provides a method for preparing a coating for anti-corrosion treatment of marine weather resistant engineering parts, wherein according to the above formula, a quantitative corrosion inhibitor is weighed, dissolved in a quantitative amount of deionized water, and then bonded.
  • the coating provided by the present invention optimizes the water-soluble, chrome-free, low-temperature curing and marine weather-resistant Al-Zn-Si alloy coating by optimizing the composition and the like.
  • the coating is environmentally friendly, stable, and low in energy consumption for coating preparation.
  • the water-soluble aluminum-zinc-silicon coating provided by the invention breaks through the constraint that the aluminum-zinc-silicon coating is mainly prepared by the hot-dip method.
  • the present invention can form a metal coating by adding a binder, a dispersing agent, an organic solvent, etc., and can form a coating on the surface of the workpiece by spraying, brushing, etc., the coating preparation process temperature of the present invention.
  • Low (200 ° C) overcomes the technical problems of workpiece deformation and mechanical properties caused by high temperature of hot-dip alloy coating (more than 600 ° C); coating can be formed on the surface of the workpiece by spraying, brushing, etc.
  • the process method and equipment are simple, suitable for large and complex parts processing, and broaden the application range of the coating.
  • the engineering parts using the coating of the present invention for corrosion protection have many excellent properties, such as: excellent corrosion resistance, excellent erosion resistance, and high heat corrosion resistance, and the coating is placed under high temperature conditions for a long time. , its appearance will not change.
  • the coating prepared by the invention has strong binding force to the substrate, excellent corrosion resistance, good wear resistance and long service life.
  • the coating not only has strong adhesion to the metal substrate, but also has good adhesion with other various additional coatings, not only beautiful matt silver gray, but also can be additionally coated into various colors. It makes up for the shortcomings of low hardness in the prior art.
  • the corrosion resistance, wear resistance and erosion resistance of the coating are greatly improved compared with the hot-dip aluminum-zinc-silicon coating and the zinc-aluminum coating.
  • the marine corrosive environment such as flow provides a comprehensive corrosion resistance protection method for important engineering components such as wind power and ships.
  • the coating for anti-corrosion treatment of marine weather engineering parts developed by the invention and the preparation method thereof solve the urgent need of marine corrosion of engineering parts, and are important in the corrosion engineering of marine engineering and offshore wind power and other industrial equipments. Application prospects.
  • the invention provides a water-soluble aluminum zinc silicon coating for anti-corrosion treatment of marine weather engineering parts, wherein the coating comprises aluminum zinc silicon alloy powder, organic solvent, nano oxide particle reinforcing agent, deionized water, binder, Corrosion inhibitors, dispersants and thickeners.
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, mass percentage content of each component (%)
  • Aluminum-zinc-silicon alloy powder consists of Al, Zn, Si, Mg, and the mass percentage content of each component (%)
  • Aluminum-zinc-silicon alloy powder consists of 1, Zn, Si, RE, the mass percentage of each component
  • Aluminum-zinc-silicon alloy powder consists of Al, Zn, Si, Mg, RE, and the mass percentage content of each component (%)
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, Mg, Ti, and the mass percentage content of each component (%)
  • the powder consists of Al, Zn, Si, Mg, M, and the mass percentage of each component
  • the powder consists of Al, Zn, Si, Mg and Mn, and the mass percentage of each component
  • the powder consists of Al, Zn, Si, RE, Ti, and the mass percentage of each component
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, RE, M, and the mass percentage content of each component (%)
  • Table 14 Aluminum-zinc-silicone: The powder consists of Al, Zn, Si, RE and Mn, and the mass percentage of each component is included.
  • the powder consists of Al, Zn, Si, Ti, Ni, the mass percentage content of each component (%)
  • the powder consists of Al, Zn, Si, Ti and Mn, and the mass percentage of each component
  • the powder consists of Al, Zn, Si, M and Mn, and the mass percentage of each component is included.
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, Mg, RE, Ti, and the mass percentage content of each component (%)
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, Mg, RE, M, and the mass percentage content of each component (%)
  • Zinc-silicon alloy powder consists of Al, Zn, Si, Mg, RE and Mn, the mass percentage content of each component (%)
  • the alloy powder consists of Al, Zn, Si, Mg, Ti, M, and the mass percentage of each component (%)
  • Alloy powder consists of Al, Zn, Si, Mg, Ti and Mn, the mass percentage content of each component (%)
  • Aluminum-zinc-silicon alloy powder consists of Al, Zn, Si, Mg, M and Mn, and the mass percentage of each component (%)
  • Niobium alloy powder consists of Al, Zn, Si, RE, Ti, M, and the mass percentage of each component (
  • Alloy powder consists of Al, Zn, Si, RE, Ti and Mn, the mass percentage of each component
  • Niobium alloy powder consists of Al, Zn, Si, RE, M and Mn, the mass percentage of each component
  • the alloy powder consists of Al, Zn, Si, Ti, M and Mn, and the mass percentage of each component (%)
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, Mg, RE, Ti, M, and the mass percentage content of each component (%)
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, Mg, RE, Ti and Mn, and the mass percentage of each component (%)
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, Mg, Ti, M and Mn, the mass percentage of each component
  • Aluminum-zinc-silicon alloy powder consists of Al, Zn, Si, RE, Ti, M and Mn, and the mass percentage of each component (%)
  • Al-Zn-Si alloy powder consists of Al, Zn, Si, Mg, RE, Ti, M and Mn, and the mass percentage content of each component (%)
  • the present invention also provides a process for preparing an environmentally-friendly water-soluble aluminum-zinc-silicon coating for anti-corrosion treatment of marine weather resistant engineering parts: according to the above formula, weigh a quantitative corrosion inhibitor, and dissolve it into a quantitative deionized water. Then, adding a binder, a dispersing agent, an organic solvent, stirring to dissolve, slowly adding aluminum-zinc-silicon alloy powder and nano-oxide particle reinforcing agent under stirring, and then adding a thickener, and controlling the oil bath during the stirring process The temperature is 20-30 ° C and stirred for 0.5-lh.
  • Experimental performance data :
  • connection bolt material 40CrNiMo
  • connection bolt material 40CrNiMo
  • the various coatings of the present invention are respectively coated to form a 20 ⁇ thick coating, and then coated with a 15 ⁇ thick polysiloxane.
  • the accelerated corrosion simulation test results show that the main performance indexes achieved in the seawater splash zone environment can be achieved:
  • Neutral salt spray corrosion life greater than 1600 hours

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Powder Metallurgy (AREA)

Abstract

L'invention concerne un revêtement pour un traitement anti-corrosion de pièces d'ingénierie résistantes au climat océanique et un procédé de préparation de ce revêtement. Le revêtement contient une poudre d'alliage d'aluminium-zinc-silicium, un solvant organique, un agent de renforcement à particules de nano-oxyde, de l'eau déionisée, un liant, un inhibiteur de corrosion, un agent dispersant et un agent épaississant, la poudre d'alliage d'aluminium-zinc-silicium, le solvant organique, l'agent de renforcement à particules de nano-oxyde, l'eau déionisée, le liant, l'inhibiteur de corrosion, l'agent dispersant et l'agent épaississant = 30,0 - 50,0 g, 10,0 - 25,0 mL, 1,0 - 4,0 g, 15,0 - 30,0 mL, 2,0 - 5,0 g, 1,0 - 3,0 g, 0,1 - 2,0 mL, 0,1 - 2,0 g, et la poudre d'alliage d'aluminium-zinc-silicium contient les éléments Al, Zn, Si, etc.
PCT/CN2010/079676 2010-11-04 2010-12-10 Revêtement hydrosoluble pour le traitement anti-corrosion de pièces d'ingénierie résistantes au climat océanique et procédé de préparation WO2012058839A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2013536978A JP5604010B2 (ja) 2010-11-04 2010-12-10 耐海洋気候の防食処理用の水性塗料及びその製造方法
KR1020137014411A KR101464287B1 (ko) 2010-11-04 2010-12-10 해양 기후 저항성 방부 처리용 수용성 도료 및 그 제조 방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201010531689 2010-11-04
CN201010531689.2 2010-11-04

Publications (1)

Publication Number Publication Date
WO2012058839A1 true WO2012058839A1 (fr) 2012-05-10

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PCT/CN2010/079676 WO2012058839A1 (fr) 2010-11-04 2010-12-10 Revêtement hydrosoluble pour le traitement anti-corrosion de pièces d'ingénierie résistantes au climat océanique et procédé de préparation

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JP (1) JP5604010B2 (fr)
KR (1) KR101464287B1 (fr)
CN (32) CN102086313B (fr)
WO (1) WO2012058839A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014025015A (ja) * 2012-07-30 2014-02-06 Kubota Corp 塗料

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102086313B (zh) * 2010-11-04 2012-08-29 江苏麟龙新材料股份有限公司 含镁的耐海洋气候防腐处理用的涂料
CN102850873B (zh) * 2012-08-09 2015-03-18 义乌潘季涂料有限公司 一种荧光电泳涂料及其制备方法和应用
CN103044987B (zh) * 2013-01-03 2015-05-27 张军 一种含镍-钛-硅的无铬锌铝涂层防腐涂料
CN103087562B (zh) * 2013-01-03 2015-04-15 张军 一种含镁-钛-锰的无铬锌铝涂层防腐涂料
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CN103044984B (zh) * 2013-01-03 2015-06-17 管卫峰 一种含镍-钛-锰-硅的无铬锌铝涂层防腐涂料
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CN105295585A (zh) * 2015-11-30 2016-02-03 沈阳工业大学 海洋金属构件防污、防腐处理用新型涂料及其制备方法
CN105585883B (zh) * 2016-03-04 2017-09-19 浙江大学 用于钢筋防腐的低温烧结涂料及其涂覆方法
CN108485323A (zh) * 2018-03-29 2018-09-04 南京信息工程大学 一种涂层材料及其制备方法
CN113667382A (zh) * 2021-09-14 2021-11-19 惠州市汉惠河环境科技有限公司 一种水性重防腐底漆及其制备方法
CN116550577B (zh) * 2023-04-14 2024-02-13 烟台大学 耐海洋气候工程零件表面涂层的涂覆处理工艺

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1172135A (zh) * 1996-05-20 1998-02-04 金属涂层国际公司 可提供防腐保护的水可稀释性涂料组合物
WO2001085854A1 (fr) * 2000-05-11 2001-11-15 Dow Corning Corporation Composition de revetement
CN101338091A (zh) * 2008-08-15 2009-01-07 上海达克罗涂复工业有限公司 无铬金属防腐涂料、制备方法及使用方法
CN101693811A (zh) * 2009-09-28 2010-04-14 常州捷迈特表面工程技术有限公司 用于金属表面的无铬水性防腐蚀涂料及其制备方法
CN101748353A (zh) * 2009-12-28 2010-06-23 无锡麟龙铝业有限公司 一种耐海洋气候工程零件进行防腐处理的方法
CN102086314A (zh) * 2010-11-04 2011-06-08 江苏麟龙新材料股份有限公司 耐海洋气候防腐处理用的水溶性铝锌硅涂料

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000064024A (ja) * 1998-08-17 2000-02-29 Nittetsu Hard Kk 溶融金属耐食性皮膜形成材および皮膜形成方法
EP1330499A2 (fr) * 2000-10-11 2003-07-30 Chemteall GmbH Procede de pretraitement et d'enduction subsequente de surfaces metalliques avant le formage a l'aide d'une couche de type peinture et utilisation des substrats ainsi recouverts
EP1397443B1 (fr) * 2001-05-01 2019-07-24 Dow Silicones Corporation Composition protectrice de revetement
ATE307175T1 (de) * 2001-09-11 2005-11-15 Akzo Nobel Coatings Int Bv Beschichtungszusammensetzung für metallsubstrate
AU2003212970A1 (en) * 2002-02-08 2003-09-02 Nichols Aluminium Method and apparatus for producing a solution heat treated sheet
CN1786091A (zh) * 2005-11-14 2006-06-14 长春吉大化学有限公司 镁合金无铬达克罗溶液涂料及其生产方法
JP5190238B2 (ja) * 2006-09-28 2013-04-24 新日鐵住金株式会社 高耐食性防錆塗料、高耐食性鉄鋼材料及び鋼構造物
JP2008144059A (ja) * 2006-12-11 2008-06-26 Tsubakimoto Chain Co 水系防錆塗料
JP5130071B2 (ja) * 2007-02-08 2013-01-30 新日鐵住金株式会社 船舶鋼材の防錆方法
CN101613559A (zh) * 2008-06-25 2009-12-30 云南格兰工业发展有限公司 水性纳米锌基复合涂料
CN101333350B (zh) * 2008-07-02 2010-06-02 大连海事大学 一种导电海洋防污涂料及其制备方法
CN101343506B (zh) * 2008-08-28 2011-12-28 胡仲寅 一种锌金属涂层
CN101481553A (zh) * 2008-11-06 2009-07-15 常州市纳罗可涂料有限公司 一种常温固化的自组装复合纳米氧化物防腐涂料
CN101418154A (zh) * 2008-11-21 2009-04-29 哈尔滨工程大学 缓蚀性阴离子插层水滑石/氧化物复合材料制备及应用
CN101709162B (zh) * 2009-11-27 2014-03-05 沈阳黎明航空发动机(集团)有限责任公司 海洋环境下gh907材料制件用涂料及其制备、使用方法
CN101736222B (zh) * 2009-12-28 2012-02-22 江苏麟龙新材料股份有限公司 含铝-硅-锌-稀土-铜的热浸镀合金及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1172135A (zh) * 1996-05-20 1998-02-04 金属涂层国际公司 可提供防腐保护的水可稀释性涂料组合物
WO2001085854A1 (fr) * 2000-05-11 2001-11-15 Dow Corning Corporation Composition de revetement
CN101338091A (zh) * 2008-08-15 2009-01-07 上海达克罗涂复工业有限公司 无铬金属防腐涂料、制备方法及使用方法
CN101693811A (zh) * 2009-09-28 2010-04-14 常州捷迈特表面工程技术有限公司 用于金属表面的无铬水性防腐蚀涂料及其制备方法
CN101748353A (zh) * 2009-12-28 2010-06-23 无锡麟龙铝业有限公司 一种耐海洋气候工程零件进行防腐处理的方法
CN102086314A (zh) * 2010-11-04 2011-06-08 江苏麟龙新材料股份有限公司 耐海洋气候防腐处理用的水溶性铝锌硅涂料

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014025015A (ja) * 2012-07-30 2014-02-06 Kubota Corp 塗料

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