WO2012036377A3 - 합성가스로부터 탄화수소를 제조하기 위한 반응장치 - Google Patents

합성가스로부터 탄화수소를 제조하기 위한 반응장치 Download PDF

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Publication number
WO2012036377A3
WO2012036377A3 PCT/KR2011/005300 KR2011005300W WO2012036377A3 WO 2012036377 A3 WO2012036377 A3 WO 2012036377A3 KR 2011005300 W KR2011005300 W KR 2011005300W WO 2012036377 A3 WO2012036377 A3 WO 2012036377A3
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WIPO (PCT)
Prior art keywords
synthesis gas
catalyst
reaction device
producing hydrocarbons
particles
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PCT/KR2011/005300
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English (en)
French (fr)
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WO2012036377A2 (ko
WO2012036377A4 (ko
Inventor
하경수
김두일
정규인
배종욱
전기원
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한국화학연구원
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Application filed by 한국화학연구원 filed Critical 한국화학연구원
Priority to EP11825337.6A priority Critical patent/EP2617486A4/en
Priority to CA2812364A priority patent/CA2812364C/en
Priority to JP2013529043A priority patent/JP5665995B2/ja
Priority to US13/823,326 priority patent/US9266080B2/en
Priority to CN201180044543.8A priority patent/CN103260739B/zh
Priority to AU2011302912A priority patent/AU2011302912B2/en
Publication of WO2012036377A2 publication Critical patent/WO2012036377A2/ko
Publication of WO2012036377A3 publication Critical patent/WO2012036377A3/ko
Publication of WO2012036377A4 publication Critical patent/WO2012036377A4/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/0085—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction promoting uninterrupted fluid flow, e.g. by filtering out particles in front of the catalyst layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/006—Separating solid material from the gas/liquid stream by filtration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00893—Feeding means for the reactants
    • B01J2208/00902—Nozzle-type feeding elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00893—Feeding means for the reactants
    • B01J2208/00929—Provided with baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00938—Flow distribution elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

본 발명은 합성가스로부터 탄화수소를 제조하기 위한 반응장치에 관한 것으로서, 더욱 상세하게는 합성가스를 이용하여 피셔-트롭쉬 촉매상에서 탄화수소, 올레핀, oxygenate 등을 제조하되, 외부로 배출되는 슬러리로부터 촉매입자를 용이하게 분리시킬 수 있도록 한 합성가스로부터 탄화수소를 제조하기 위한 반응장치에 관한 것이다. 즉, 본 발명은 반응기 내부에 촉매의 뭉침 현상으로 커진 입자를 분리하기 위한 내부 필터 시스템을 설치하고, 외부에는 분리장치를 별도로 배치하여, 슬러리상에서 F-T합성을 하기에 적합한 크기의 입자들만을 재순환시킬 수 있고, 또한 슬러리상 반응기에서 미세한 촉매입자나 운전 중 발생한 깨진 촉매 등이 액상의 탄화수소, 생성수 등과 결합하여 뭉치게 된 촉매를 효과적으로 배출하고 처리시킬 수 있는 합성가스로부터 탄화수소를 제조하기 위한 반응장치를 제공하고자 한 것이다.
PCT/KR2011/005300 2010-09-17 2011-07-19 합성가스로부터 탄화수소를 제조하기 위한 반응장치 WO2012036377A2 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP11825337.6A EP2617486A4 (en) 2010-09-17 2011-07-19 Reaction device for producing hydrocarbons from synthesis gas
CA2812364A CA2812364C (en) 2010-09-17 2011-07-19 Reaction device for producing hydrocarbons from synthesis gas
JP2013529043A JP5665995B2 (ja) 2010-09-17 2011-07-19 合成ガス炉から炭化水素を製造するための反応装置
US13/823,326 US9266080B2 (en) 2010-09-17 2011-07-19 Reaction device for producing hydrocarbons from synthesis gas
CN201180044543.8A CN103260739B (zh) 2010-09-17 2011-07-19 用于由合成气来生产烃的反应装置
AU2011302912A AU2011302912B2 (en) 2010-09-17 2011-07-19 Reaction device for producing hydrocarbons from synthesis gas

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020100091348A KR101210397B1 (ko) 2010-09-17 2010-09-17 합성가스로부터 탄화수소를 제조하기 위한 반응장치
KR10-2010-0091348 2010-09-17

Publications (3)

Publication Number Publication Date
WO2012036377A2 WO2012036377A2 (ko) 2012-03-22
WO2012036377A3 true WO2012036377A3 (ko) 2012-05-31
WO2012036377A4 WO2012036377A4 (ko) 2012-07-26

Family

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PCT/KR2011/005300 WO2012036377A2 (ko) 2010-09-17 2011-07-19 합성가스로부터 탄화수소를 제조하기 위한 반응장치

Country Status (8)

Country Link
US (1) US9266080B2 (ko)
EP (1) EP2617486A4 (ko)
JP (1) JP5665995B2 (ko)
KR (1) KR101210397B1 (ko)
CN (1) CN103260739B (ko)
AU (1) AU2011302912B2 (ko)
CA (1) CA2812364C (ko)
WO (1) WO2012036377A2 (ko)

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CN103773433A (zh) * 2012-10-23 2014-05-07 中国石油天然气股份有限公司 一种劣质油品加氢处理方法

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CN102703712B (zh) * 2012-06-29 2014-06-18 阳光凯迪新能源集团有限公司 从费托合成产品中回收贵金属催化剂的组合过滤工艺
CN102728286B (zh) * 2012-07-17 2015-06-17 神华集团有限责任公司 浆态床反应设备
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CN105170036B (zh) * 2015-09-22 2017-10-10 太原理工大学 一种煤合成气浆态床制含氧燃料反应器
WO2020226747A1 (en) * 2019-05-08 2020-11-12 Exxonmobil Research And Engineering Company Removal of catalyst fines from fluidized bed effluent in the conversion of oxygenate feedstock
WO2021097794A1 (zh) * 2019-11-22 2021-05-27 南京延长反应技术研究院有限公司 一种有氧发酵系统及工艺

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103773433A (zh) * 2012-10-23 2014-05-07 中国石油天然气股份有限公司 一种劣质油品加氢处理方法
CN103773433B (zh) * 2012-10-23 2016-12-21 中国石油天然气股份有限公司 一种劣质油品加氢处理方法

Also Published As

Publication number Publication date
KR101210397B1 (ko) 2012-12-10
EP2617486A2 (en) 2013-07-24
US9266080B2 (en) 2016-02-23
CA2812364A1 (en) 2012-03-22
CN103260739A (zh) 2013-08-21
EP2617486A4 (en) 2017-08-30
CN103260739B (zh) 2015-07-15
AU2011302912B2 (en) 2015-03-12
KR20120029522A (ko) 2012-03-27
JP2013543018A (ja) 2013-11-28
US20130171040A1 (en) 2013-07-04
CA2812364C (en) 2016-03-15
WO2012036377A2 (ko) 2012-03-22
AU2011302912A1 (en) 2013-04-18
WO2012036377A4 (ko) 2012-07-26
JP5665995B2 (ja) 2015-02-04

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