JP4874660B2 - 気泡塔型炭化水素合成反応器 - Google Patents
気泡塔型炭化水素合成反応器 Download PDFInfo
- Publication number
- JP4874660B2 JP4874660B2 JP2006020659A JP2006020659A JP4874660B2 JP 4874660 B2 JP4874660 B2 JP 4874660B2 JP 2006020659 A JP2006020659 A JP 2006020659A JP 2006020659 A JP2006020659 A JP 2006020659A JP 4874660 B2 JP4874660 B2 JP 4874660B2
- Authority
- JP
- Japan
- Prior art keywords
- reactor
- slurry
- catalyst particles
- barrier member
- synthesis gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J4/00—Feed or outlet devices; Feed or outlet control devices
- B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
- B01J4/002—Nozzle-type elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1818—Feeding of the fluidising gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1818—Feeding of the fluidising gas
- B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/226—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement internally, i.e. the particles rotate within the vessel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/44—Fluidisation grids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/342—Apparatus, reactors with moving solid catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00132—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/00141—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
Description
(1)液体炭化水素中に固体の触媒粒子を懸濁させたスラリーを収容する反応器本体と;前記反応器本体の下部に配設され,水素および一酸化炭素を主成分とする合成ガスを下方に噴射して前記スラリーに供給する反応ガス供給部と;前記反応ガス供給部から噴射される合成ガスの噴射方向に配置され,前記スラリーの流れを制限する障壁部材と;前記反応器本体の底部に設けられ,前記液体炭化水素のみを排出する液体炭化水素排出口と;を備え,前記障壁部材は,前記反応ガス供給部から噴射される合成ガスが到達する範囲内に,前記反応器本体の高さ方向に垂直な水平面に平行となるように設置され,かつ,前記スラリー中の触媒粒子のみの流れを制限するフィルタ要素を含むことを特徴とする,気泡塔型炭化水素合成反応器。
(2)前記フィルタ要素は,前記障壁部材の一部に設けられていることを特徴とする,(1)に記載の気泡塔型炭化水素合成反応器。
まず,図1に基づいて,本発明の第1の実施形態に係る気泡塔型炭化水素合成反応器の一例としての気泡塔型スラリー床FT合成反応器1(以下,単に「FT反応器1」という。)の構成について説明する。なお,図1は,本実施形態に係るFT反応器1の全体構成を示す縦断面図である。
10 反応器本体
12 スラリー
14 液体炭化水素排出口
20 ディストリビュータ
22 合成ガス供給管
24 ノズルヘッダー
26 合成ガス供給ノズル
26a,26b,26c 合成ガス噴射口
28 気泡
30 障壁部材
32 スクリーン
32a スリット
32b ワイヤー
34 スクリーン支持部材
36 遮蔽板
40 冷却管
42 冷却管入口
44 冷却管出口
122 液体炭化水素
124 触媒粒子
200 ディストリビュータ
210 上段吹き込みノズル
220 下段吹き込みノズル
Claims (2)
- 液体炭化水素中に固体の触媒粒子を懸濁させたスラリーを収容する反応器本体と;
前記反応器本体の下部に配設され,水素および一酸化炭素を主成分とする合成ガスを下方に噴射して前記スラリーに供給する反応ガス供給部と;
前記反応ガス供給部から噴射される合成ガスの噴射方向に前記反応器本体の底部とは別途配置され,前記スラリーの流れを制限する障壁部材と;
前記反応器本体の底部に設けられ,前記液体炭化水素のみを排出する液体炭化水素排出口と;
を備え,
前記障壁部材は,前記反応ガス供給部から噴射される合成ガスが到達する範囲内に,前記反応器本体の高さ方向に垂直な水平面に平行となるように設置され,かつ,前記スラリー中の触媒粒子のみの流れを制限するフィルタ要素を含むことを特徴とする,気泡塔型炭化水素合成反応器。 - 前記フィルタ要素は,前記障壁部材の一部に設けられていることを特徴とする,請求項1に記載の気泡塔型炭化水素合成反応器。
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006020659A JP4874660B2 (ja) | 2006-01-30 | 2006-01-30 | 気泡塔型炭化水素合成反応器 |
PCT/JP2007/051854 WO2007086612A1 (en) | 2006-01-30 | 2007-01-30 | Bubble column type hydrocarbon synthesis reactor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006020659A JP4874660B2 (ja) | 2006-01-30 | 2006-01-30 | 気泡塔型炭化水素合成反応器 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007197405A JP2007197405A (ja) | 2007-08-09 |
JP4874660B2 true JP4874660B2 (ja) | 2012-02-15 |
Family
ID=38309381
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006020659A Expired - Fee Related JP4874660B2 (ja) | 2006-01-30 | 2006-01-30 | 気泡塔型炭化水素合成反応器 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP4874660B2 (ja) |
WO (1) | WO2007086612A1 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2055375B1 (en) * | 2007-10-25 | 2012-05-02 | Mitsubishi Materials Corporation | Hydrogen chloride gaz ejecting nozzle, reaction apparatus for producing thrichlorosilane and method for producing trichlorosilane |
KR100992835B1 (ko) * | 2008-02-29 | 2010-11-08 | 한국화학연구원 | 피셔-트롭쉬 합성반응용 고체촉매와 생성물의 연속분리배출장치 및 방법 |
MY158453A (en) | 2008-09-30 | 2016-10-14 | Japan Oil Gas & Metals Jogmec | Bubble column reactor and method of controlling bubble column reactor |
GB2465554B (en) | 2008-11-18 | 2013-03-13 | Gtl F1 Ag | Slurry bubble column reactor |
GB2466315B (en) | 2008-12-22 | 2013-01-09 | Gtl F1 Ag | Apparatus and method for conducting a Fischer-Tropsch synthesis reaction |
GB2471338B (en) | 2009-06-26 | 2014-12-24 | Gtl F1 Ag | Apparatus and process for three-phase reacton |
KR101210397B1 (ko) * | 2010-09-17 | 2012-12-10 | 한국화학연구원 | 합성가스로부터 탄화수소를 제조하기 위한 반응장치 |
CA2819813C (en) * | 2010-12-13 | 2017-11-14 | Sasol Technology (Proprietary) Limited | Slurry phase apparatus |
CN102441360A (zh) * | 2011-09-30 | 2012-05-09 | 常熟市申华化工贸易有限公司 | 一种化工反应器 |
JP6145348B2 (ja) | 2013-07-30 | 2017-06-07 | 新日鉄住金エンジニアリング株式会社 | 炭化水素合成用の反応器 |
PE20160984A1 (es) | 2013-12-11 | 2016-10-11 | Sasol Tech Pty Ltd | Metodo para apagar un reactor de columna de burbujas en suspension de tres fases operativas |
PT107381B (pt) * | 2013-12-23 | 2018-07-04 | Inst Superior Tecnico | Processo de oligomerização catalítica utilizando um reactor catalítico para a oligomerização de olefinas em c4-c7 |
CN105056844B (zh) * | 2015-08-07 | 2017-04-12 | 北京华福工程有限公司 | 一种乙炔加氢制乙烯浆态床的气体分布器及其应用 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4223843A (en) * | 1978-03-16 | 1980-09-23 | Texaco Inc. | Air distribution apparatus |
US5252613A (en) * | 1992-12-18 | 1993-10-12 | Exxon Research & Engineering Company | Enhanced catalyst mixing in slurry bubble columns (OP-3723) |
US7108723B2 (en) * | 2000-12-22 | 2006-09-19 | Townsend Barry W | Prosthetic foot |
KR101196278B1 (ko) * | 2004-03-08 | 2012-11-06 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 반응기용 가스 분배기 |
GB2412612B (en) * | 2004-04-02 | 2008-10-29 | Statoil Asa | Slurry bubble column reactor |
-
2006
- 2006-01-30 JP JP2006020659A patent/JP4874660B2/ja not_active Expired - Fee Related
-
2007
- 2007-01-30 WO PCT/JP2007/051854 patent/WO2007086612A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
JP2007197405A (ja) | 2007-08-09 |
WO2007086612A1 (en) | 2007-08-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4874660B2 (ja) | 気泡塔型炭化水素合成反応器 | |
JP2007197636A (ja) | 気泡塔型炭化水素合成反応器 | |
US10322393B2 (en) | Slurry phase apparatus | |
KR101129714B1 (ko) | 슬러리 기포탑 반응기 | |
JP6110847B2 (ja) | 水素転化用装置及び方法 | |
KR20070086989A (ko) | 반응기 튜브 장치 | |
US10058838B2 (en) | Method of shutting down an operating three-phase slurry bubble column reactor | |
US9833759B2 (en) | Fluid distribution device | |
EP2367616A1 (en) | Slurry bubble column reactor | |
CA2700126C (en) | Synthesis reaction system | |
JP2004307504A (ja) | 粒状床に供給される気相および液相の改良された混合および分配装置 | |
JP2006505388A (ja) | 2相並流用ベッセルに用いられるミキシング・デバイス | |
JP5389019B2 (ja) | 粒状層を含む封入体、及び同封入体内の上昇流として流通する気相及び液相の分配 | |
JP7158412B2 (ja) | 流動媒体を含むチャンバ内の多相混合物を分配するための新規な装置 | |
JPWO2007114271A1 (ja) | 気泡塔型炭化水素合成反応器 | |
KR101535058B1 (ko) | 슬러리 기포탑 반응기 | |
JP2016188296A (ja) | 気泡塔型スラリー床反応装置 | |
ITMI991767A1 (it) | Procedimento per la produzione di idrocarburi e/o idrocarburi ossigenati da gas di sintesi |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080326 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110405 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110603 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110705 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20111005 |
|
A911 | Transfer of reconsideration by examiner before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20111014 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20111101 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20111124 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141202 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141202 Year of fee payment: 3 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20141202 Year of fee payment: 3 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |