WO2012005319A1 - Composition de nettoyage - Google Patents

Composition de nettoyage Download PDF

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Publication number
WO2012005319A1
WO2012005319A1 PCT/JP2011/065551 JP2011065551W WO2012005319A1 WO 2012005319 A1 WO2012005319 A1 WO 2012005319A1 JP 2011065551 W JP2011065551 W JP 2011065551W WO 2012005319 A1 WO2012005319 A1 WO 2012005319A1
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WO
WIPO (PCT)
Prior art keywords
smoothness
drying
mass
water
component
Prior art date
Application number
PCT/JP2011/065551
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English (en)
Japanese (ja)
Inventor
利江 廣畠
明宏 寺口
青野　恵
Original Assignee
ライオン株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by ライオン株式会社 filed Critical ライオン株式会社
Priority to JP2012523914A priority Critical patent/JP5697108B2/ja
Publication of WO2012005319A1 publication Critical patent/WO2012005319A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the present invention relates to a detergent composition used for washing hair and skin, such as shampoo, dandruff shampoo, tonic shampoo, rinse-in shampoo, dandruff rinse-in shampoo, treatment in shampoo, hand soap, body soap, and facial cleanser.
  • a detergent composition used for washing hair and skin such as shampoo, dandruff shampoo, tonic shampoo, rinse-in shampoo, dandruff rinse-in shampoo, treatment in shampoo, hand soap, body soap, and facial cleanser.
  • Patent Document 1 includes (a) at least one anionic surfactant selected from polyoxyethylene alkyl ether sulfate, alkyl sulfate, alkylbenzene sulfonate, and ⁇ -olefin sulfonate; (B) at least one water-soluble polymer selected from carrageenan, alginic acid, alginate, and fucoidan; (c) at least one of a nonionic surfactant and an amphoteric surfactant; and (d) a silicone compound.
  • anionic surfactant selected from polyoxyethylene alkyl ether sulfate, alkyl sulfate, alkylbenzene sulfonate, and ⁇ -olefin sulfonate
  • B at least one water-soluble polymer selected from carrageenan, alginic acid, alginate, and fucoidan
  • c at least one of a nonionic surfactant and an amphoteric surfactant
  • a hair cleanser composition containing sulfur has been proposed.
  • (B) 0.3% by mass of water-swellable clay mineral bentonite and (C) 0.5% by mass to 1% by mass of a cationic surfactant are contained.
  • the mass ratio [(C) / (B)] of the content of the cationic surfactant (C) and the content of the water-swellable clay mineral (B) is 1.7 to 3. 3, a hair cleanser composition is disclosed.
  • the content of (B) bentonite which is a water-swellable clay mineral is large and the mass ratio [(C) / (B)] is less than 5, the smoothness during rinsing is inferior. Further, there is a problem that the dry feeling after drying and the smoothness after drying are insufficient.
  • Patent Document 2 discloses an anionic detersive surfactant, (i) an aliphatic alcohol having 12 to 22 carbon atoms, a fatty acid having 12 to 22 carbon atoms, an aliphatic amide having 12 to 22 carbon atoms, and these Aqueous conditioning shampoo compositions comprising a fatty network selected from a mixture and (ii) a gel network comprising hydrophobic particles having a melting point above the melting point of the fatty substance have been proposed.
  • Example 1 of this proposal 0.1% by mass of (B ′) quaternium-18 bentonite (ie, bentonite hydrophobically modified with dimethyldi (hydrogenated tallow) ammonium cation) and (C) a cationic interface 0.1% by mass of an activator, and a mass ratio of the content of the cationic surfactant (C) and the content of the modified bentonite (B ′) [(C) / (B ′) ] Is a conditioning shampoo having a value of 1.
  • bentonite modified hydrophobically as in this proposal is used, there is a problem that the smoothness at the time of rinsing is inferior, the washing feeling, the dry feeling after drying, and the smoothness after drying become insufficient.
  • the washing has a sufficient washing feeling, smoothness at the time of rinsing, smoothness after drying, and smoothness after drying.
  • the present invention makes it a subject to solve the said conventional problems and to achieve the following objectives. That is, the present invention has a sufficient washing feeling in a composition containing a water-swellable clay mineral under high-concentration anion conditions, and has smoothness after rinsing, smoothness after drying, and smoothness after drying. It aims at providing the cleaning composition which is favorable.
  • the present invention is based on the above findings by the present inventors, and means for solving the above problems are as follows. That is, ⁇ 1> (A) 10% by mass to 30% by mass of an anionic surfactant, A cleaning composition comprising (B) 0.01% to 0.2% by weight of a water-swellable clay mineral and (C) a cationic surfactant. ⁇ 2> The mass ratio [(C) / (B)] of the content of the cationic surfactant as the component (C) and the content of the water-swellable clay mineral as the component (B) is 5 to 50 It is a cleaning composition as described in said ⁇ 1>.
  • ⁇ 3> The cleaning composition according to any one of ⁇ 1> to ⁇ 2>, further including a water-insoluble functional component other than the components (D) and (B).
  • ⁇ 4> The cleaning composition according to any one of ⁇ 1> to ⁇ 3>, wherein the swelling power of the water-swellable clay mineral as component (B) is 20 mL / 2 g to 86 mL / 2 g.
  • ⁇ 5> The cleaning composition according to any one of ⁇ 1> to ⁇ 4>, wherein the content of the cationic surfactant as the component (C) is 0.01% by mass to 5% by mass.
  • ⁇ 6> The component according to any one of ⁇ 3> to ⁇ 5>, wherein the water-insoluble functional component other than the component (B) in the component (D) is at least one of a pearl agent, a refreshing agent, and a dandruff agent.
  • the cleaning composition is at least one of a pearl agent, a refreshing agent, and a dandruff agent.
  • the cleaning composition of the present invention contains (A) an anionic surfactant, (B) a water-swellable clay mineral, and (C) a cationic surfactant, and (D) other than the component (B). It is preferable to contain a water-insoluble functional component, and other components are contained as necessary.
  • the anionic surfactant of the component (A) has a function of enhancing the feeling of washing and the smoothness at the time of rinsing.
  • the anionic surfactant of the component (A) is not particularly limited and may be appropriately selected depending on the intended purpose.
  • alkyl preferably having a carbon number of 10 to 16, linear or branched, saturated or unsaturated) Saturated
  • alkyl preferably 10 to 16 carbon atoms, straight or branched, saturated or unsaturated
  • alkyl preferably 10 to 16 carbon atoms, straight or branched chain, saturated or unsaturated
  • Sulfosuccinate acylated amino acid salt
  • polyoxyalkylene alkyl ether sulfate the alkylene moiety is preferably polyoxyethylene, polyoxypropylene, more preferably polyoxyethylene
  • alkyl preferably having 10 to 16 carbon atoms
  • benzenesulfonate N-acyl (preferably having 10 to 18 carbon atoms) -N ⁇ -olefin sulfonate such as methyl taurate, tetradecene sulfonate, higher fatty acid ester
  • anionic surfactant salts examples include alkali metal salts such as sodium salts and potassium salts, alkaline earth metal salts, ammonium salts, and alkanolamine salts.
  • alkali metal salts such as sodium salts and potassium salts
  • alkaline earth metal salts such as sodium salts and potassium salts
  • ammonium salts such as sodium salts and potassium salts
  • alkanolamine salts such as sodium salts and potassium salts
  • alkaline earth metal salts such as sodium salts and potassium salts
  • ammonium salts such as sodium salts and potassium salts
  • alkanolamine salts alkanolamine salts.
  • polyoxyethylene alkyl ether sulfate alkyl chain length is preferably 10 to 24
  • EO ethylene oxide
  • tetradecene sulfonate fatty acid stone Ken
  • alkylsulfosuccinate alkylsulfosuccinate
  • palm oil fatty acid methyl taurate
  • the alkyl chain length is 12 to 14, and the average number of moles of EO added is 2.
  • the average number of moles of EO added is 2.
  • 4 to 4 polyoxyethylene alkyl ether sulfates are especially preferred.
  • the content of the anionic surfactant as the component (A) is 10% by mass to 30% by mass, and preferably 15% by mass to 20% by mass with respect to the entire cleaning composition. When the content is less than 10% by mass, a sufficient cleaning feeling as a cleaning composition may not be obtained, and the dry feeling after drying and the smoothness after drying may decrease. When it exceeds mass%, the smoothness at the time of rinsing, the dry feeling after drying, and the smoothness after drying may decrease.
  • the water-swellable clay mineral of the component (B) has a function of imparting smoothness at the time of rinsing, a smooth feeling after drying, and a smoothness after drying.
  • the water-swellable clay mineral of component (B) is not particularly limited and may be appropriately selected depending on the intended purpose.
  • a water-swellable clay mineral having a swelling power of 20 mL / 2 g to 86 mL / 2 g is From the viewpoints of smoothness at the time of rinsing, smooth feeling after drying, and smoothness after drying, the swelling power is more preferably 60 mL / 2 g to 86 mL / 2 g.
  • the water-swellable clay mineral having a swelling power of 20 mL / 2 g to 86 mL / 2 g contains exchangeable ions that hydrate and take up water molecules between layers when added to water. It has properties such as properties, binding properties, suspension properties, and thickening properties, and exhibits properties different from those of other clay minerals.
  • the swelling force is expressed in terms of swelling volume (mL) of 2 g of clay mineral, applying the bentonite test method defined in the 15th revised Japanese Pharmacopoeia. Specifically, 2 g of clay mineral is taken and added to a 100 mL graduated cylinder containing 100 mL of water in 10 portions, and the apparent volume of the bottom of the vessel when this is left for 24 hours is read from the scale. In addition, when adding a clay mineral to water in 10 steps, after the sample added previously is almost deposited, the next sample is added.
  • water-swellable clay mineral (B) examples include natural or synthetic smectite clay minerals.
  • polar gel American Colloid, swelling power 20 mL / 2 g
  • natural Bentonite Hojun Co., Ltd., Bengel FW, swelling power 35 mL / 2 g
  • Natural bentonite Hojun Co., Ltd., Bengel, swelling power 35 mL / 2 g
  • Lucentite Lucentite
  • Bentonite Kunipia G, swelling power 86 mL) / 2g, manufactured by Kunimine Industries Co., Ltd., montmorillonite (Kunipia F, swelling power 70mL / 2g, manufactured by Kunimine Industries Co., Ltd.), Benclay (manufactured by Mizusawa Chemical Co., Ltd.), saponite (Beegam T, manufactured by Vanderbilt Corporation, swelling power 60mL / 2g), Hectorite, Sauconite, Steven Sai And the like.
  • saponite Beegam T, manufactured by Vanderbilt, swelling power 60 mL / 2 g
  • montmorillonite (Kunipia F, swelling power) in terms of smoothness at the time of rinsing, smooth feeling after drying, and smoothness after drying.
  • bentonite Kermania G, swelling power 86 mL / 2 g, manufactured by Kunimine Industries Co., Ltd.
  • the content of the water-swellable clay mineral of the component (B) is 0.01% to 0.2% by weight with respect to the entire cleaning composition. Smoothness at the time of rinsing, smoothness after drying From the viewpoint of imparting feeling and smoothness after drying, 0.03% by mass to 0.1% by mass is preferable. When the content is less than 0.01% by mass, the dry feeling after drying and the smoothness after drying become insufficient, and when it exceeds 0.2% by mass, the smoothness at the time of rinsing decreases. It may end up.
  • the cationic surfactant of component (C) contributes to improvement in smoothness during rinsing and smoothness after drying.
  • the cationic surfactant of the component (C) is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include amine salts, quaternary ammonium salts, benzethonium salts, pyridinium salts, guanidine salts, pyrrolidone. Examples thereof include carboxylates, mono-N-long chain acyl basic amino acid lower alkyl ester salts, and amidoamine type surfactants. These may be used individually by 1 type and may use 2 or more types together.
  • component (C) cationic surfactant examples include stearyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, dioleyl dimethyl ammonium chloride, didecyl dimethyl chloride.
  • stearyltrimethylammonium chloride distearyldimethylammonium chloride, behenyltrimethylammonium chloride, and dimethylaminopropylamide stearate are preferable, and stearyltrimethylammonium chloride is preferable from the viewpoint of smoothness at the time of rinsing and smoothness after drying. Particularly preferred.
  • the content of the cationic surfactant of the component (C) is preferably 0.01% by mass to 5% by mass with respect to the whole cleaning composition, and smoothness at the time of rinsing, smoothness after drying, Further, from the viewpoint of smooth feeling after drying, 0.5% by mass to 2% by mass is more preferable.
  • the content is less than 0.01% by mass, the smoothness at the time of rinsing and the smoothness after drying may be reduced.
  • the content exceeds 5% by mass, the cleaning feeling may be reduced. There is.
  • the mass ratio [(C) / (B)] of the content of the cationic surfactant as the component (C) and the content of the water-swellable clay mineral as the component (B) is preferably 5 to 50. From the viewpoints of smooth feeling after drying and smoothness after drying, 5 to 20 is more preferable. When the mass ratio [(C) / (B)] is less than 5, the smoothness at the time of rinsing may be reduced, and when it exceeds 50, the smooth feeling after drying and the smoothness after drying. May decrease.
  • the (D) water-insoluble functional component other than the component (B) is a solid that is substantially insoluble in water at room temperature and has a specific function.
  • a pearl agent a cooling agent
  • Examples include dandruff removers.
  • a clay mineral swollen with water is mixed in a high concentration anionic surfactant, the repulsive force of the clay mineral is increased under a high concentration of anion charge, and agglomeration of the clay mineral occurs.
  • the aggregation of clay minerals becomes crystal nuclei, and when (D) water-insoluble functional components such as pearl agents, cooling agents, and anti-dandruff agents are contained, the stability deteriorates at low temperatures (precipitation of crystals).
  • the cationic surfactant as the component (C) and the water-swellable clay mineral as the component (B) are included.
  • the pearl agent examples include stearic acid ester of ethylene glycol, stearic acid ester of diethylene glycol, and stearic acid ester of triethylene glycol.
  • Specific examples include ethylene glycol monostearate, ethylene glycol distearate, diethylene glycol monostearate, diethylene glycol distearate, triethylene glycol monostearate, triethylene glycol distearate and the like.
  • ethylene glycol distearate ethylene glycol distearate
  • Examples of the refreshing agent include L-menthol, camphor, borneol and the like.
  • L-menthol is particularly preferable from the viewpoint of a clean feeling after washing.
  • anti-dandruff agent examples include piroctone olamine, triclosan, trichlorocarban, isopropylmethylphenol; chlorhexidine hydrochloride other than the component (C), alkyldiaminoethylglycine, cetylpyridinium chloride, benzalkonium chloride, benzethonium chloride, etc. And a cationic surfactant.
  • piroctone olamine is particularly preferable in terms of the anti-dandruff effect.
  • the content of the water-insoluble functional component other than the component (B) in the component (D) is preferably 0.1% by mass to 3% by mass, and preferably 0.5% by mass to 2% with respect to the entire cleaning composition. More preferable is 5% by mass. When the content is less than 0.1% by mass, the effect of adding a water-insoluble functional component other than the component (B) of the component (D) may not be expressed. Low temperature stability may deteriorate.
  • nonionic surfactant semipolar surfactant, amphoteric surfactant, anionic polymer, nonionic polymer, cation Polymers, polyols, organic acids; antioxidants such as dibutylhydroxytoluene (BHT) and ⁇ -tocopherol; viscosity modifiers such as fatty acid monoethanolamide and fatty acid diethanolamide; UV absorbers, antioxidants, protein derivatives, Animal and plant extracts; Anti-inflammatory agents such as dipotassium glycyrrhizinate; Preservatives such as methylchloroisothiazolinone (Caisson CG); Citric acid; pH adjusters such as triethanolamine; Emulsifiers, hydrotropes, lower alcohols, vitamins , Animal and vegetable oils, volatile oils, hydrocarbons, ester oils, silico Down oil, dyes, and perfumes and the like.
  • BHT dibutylhydroxytoluene
  • viscosity modifiers such as fatty acid monoethanolamide and fatty
  • the method for producing the cleaning composition of the present invention is not particularly limited and may be appropriately selected depending on the purpose.
  • the components (A) to (C), preferably the component (D), If necessary, the detergent composition can be prepared by adding the other components and mixing them uniformly.
  • tubes such as an aluminum laminated tube, an EVAL tube, an aluminum tube, a glass vapor deposition plastic tube, etc.
  • Other examples include a dispenser container by mechanical or differential pressure, a squeeze container, a laminate film container, a dropper container, a stick container, and a bottle container.
  • the laminate film of the aluminum laminated tube usually has two or more layers, and examples of the material thereof include polyethylene resin, polyethylene terephthalate resin, polyester resin, biaxially stretched polypropylene resin, unstretched polypropylene resin, polyacrylonitrile resin.
  • the laminate film generally has 2 to 5 layers.
  • the material of the bottle include polyethylene resin, polypropylene resin, polyethylene terephthalate resin, polystyrene resin, polyvinyl chloride resin, ethylene-vinyl alcohol resin, acrylonitrile-styrene resin, ABS resin, polyamide resin, and glass. A combination of two or more layers can be used.
  • the cleaning composition of the present invention has a sufficient cleaning feeling in a composition containing a water-swellable clay mineral under high-concentration anion conditions, smoothness at the time of rinsing, dry feeling after drying, and after drying Since smoothness is good, it is used for washing hair and skin such as shampoo, dandruff shampoo, tonic shampoo, rinse-in shampoo, dandruff rinse-in shampoo, treatment in shampoo, hand soap, body soap, face wash, etc.
  • hair cleaning agents such as shampoos, rinse-in shampoos, dandruff rinse-in shampoos, and treatment-in shampoos are suitable.
  • Examples 1 to 30 and Comparative Examples 1 to 7 -Preparation of detergent (rinse in shampoo) composition- Cleaning compositions of Examples 1 to 30 and Comparative Examples 1 to 7 were prepared by a conventional method with respect to the compositions (unit: mass%) shown in Table 1 below. An appropriate amount of citric acid was added to adjust the pH to 5.2. Next, various properties of the obtained cleaning composition were evaluated as follows. The results are also shown in Table 1.
  • Dimethyl distearyl ammonium bentonite is a quaternary ammonium cation-modified organic bentonite and does not dissolve in water, so the swelling power was not measurable.
  • Dimethyl distearyl ammonium bentonite is a quaternary ammonium cation-modified organic bentonite and does not dissolve in water, so the swelling power was not measurable.
  • Example 31 -Dandruff rinse-in shampoo- A dandruff rinse-in shampoo having the following composition was prepared by a conventional method, and in the same manner as in Examples 1 to 30 and Comparative Examples 1 to 7, a feeling of washing, a smoothness during rinsing, a dry feeling after drying, and a smoothness after drying The low temperature stability was evaluated.
  • the pearl agent ethylene glycol distearate
  • Example 32 -Treatment in shampoo- A treatment in shampoo having the following composition was prepared by a conventional method, and in the same manner as in Examples 1 to 30 and Comparative Examples 1 to 7, washing feeling, rinsing smoothness, dry feeling after drying, and smoothness after drying And low temperature stability was evaluated.
  • the pearl agent ethylene glycol distearate
  • AES polyoxyethylene lauryl ether sulfate
  • Example 33 -hand soap- A hand soap having the following composition was prepared by a conventional method, and in the same manner as in Examples 1 to 30 and Comparative Examples 1 to 7, washing feeling, smoothness at the time of rinsing, dry feeling after drying, and smoothness after drying, And low temperature stability was evaluated.
  • Example 34 -Body Soap- A body soap having the following composition was prepared by a conventional method, and in the same manner as in Examples 1 to 30 and Comparative Examples 1 to 7, washing feeling, smoothness at the time of rinsing, dry feeling after drying, and smoothness after drying, And low temperature stability was evaluated.
  • the pearl agent ethylene glycol distearate
  • the cleaning composition of the present invention has a sufficient cleaning feeling in a composition containing a water-swellable clay mineral under high-concentration anion conditions, smoothness at the time of rinsing, dry feeling after drying, and after drying Since smoothness is good, it is used for washing hair and skin such as shampoo, dandruff shampoo, tonic shampoo, rinse-in shampoo, dandruff rinse-in shampoo, treatment in shampoo, hand soap, body soap, face wash, etc. In particular, it can be suitably used as a hair cleaning agent for shampoos, rinse-in shampoos, dandruff rinse-in shampoos, treatment-in shampoos and the like.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition de nettoyage contenant (A) de 10 à 30 % en masse d'un tensioactif anionique, (B) de 0,01 à 0,2 % en masse d'un minéral argileux gonflant dans l'eau et (C) un tensioactif cationique. Des modes de réalisation préférés comprennent un mode dans lequel le contenu du tensioactif cationique qui est le composant (C) et le contenu du minéral argileux qui est le composant (B) présentent un rapport de masse [(C)/(B)] de 5 à 50, ou (D) un mode qui contient un composant fonctionnel insoluble dans l'eau, autre que le composant (B).
PCT/JP2011/065551 2010-07-07 2011-07-07 Composition de nettoyage WO2012005319A1 (fr)

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JP2012523914A JP5697108B2 (ja) 2010-07-07 2011-07-07 洗浄剤組成物

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JP2010-154973 2010-07-07
JP2010154973 2010-07-07

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6345213A (ja) * 1986-06-06 1988-02-26 ザ、プロクタ−、エンド、ギャンブル、カンパニ− コンディショニングシャンプ−組成物
JPH04139115A (ja) * 1990-09-27 1992-05-13 Seiwa Kasei:Kk シャンプー
JP2003342131A (ja) * 2002-05-28 2003-12-03 Lion Corp 頭皮治療剤組成物
WO2004045568A1 (fr) * 2002-11-15 2004-06-03 Lion Corporation Composition de shampooing
JP2004269848A (ja) * 2002-09-30 2004-09-30 Rohm & Haas Co 高界面活性剤レベルの水性系用増粘剤
JP2008179565A (ja) * 2007-01-25 2008-08-07 Mitsubishi Chemicals Corp 洗浄剤組成物
JP2009167126A (ja) * 2008-01-16 2009-07-30 Max:Kk 洗浄料及びその製造方法
JP2010138105A (ja) * 2008-12-11 2010-06-24 Sunstar Inc 透明洗浄剤組成物

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6345213A (ja) * 1986-06-06 1988-02-26 ザ、プロクタ−、エンド、ギャンブル、カンパニ− コンディショニングシャンプ−組成物
JPH04139115A (ja) * 1990-09-27 1992-05-13 Seiwa Kasei:Kk シャンプー
JP2003342131A (ja) * 2002-05-28 2003-12-03 Lion Corp 頭皮治療剤組成物
JP2004269848A (ja) * 2002-09-30 2004-09-30 Rohm & Haas Co 高界面活性剤レベルの水性系用増粘剤
WO2004045568A1 (fr) * 2002-11-15 2004-06-03 Lion Corporation Composition de shampooing
JP2008179565A (ja) * 2007-01-25 2008-08-07 Mitsubishi Chemicals Corp 洗浄剤組成物
JP2009167126A (ja) * 2008-01-16 2009-07-30 Max:Kk 洗浄料及びその製造方法
JP2010138105A (ja) * 2008-12-11 2010-06-24 Sunstar Inc 透明洗浄剤組成物

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JPWO2012005319A1 (ja) 2013-09-05

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