WO2012002260A1 - 面光源装置 - Google Patents
面光源装置 Download PDFInfo
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- WO2012002260A1 WO2012002260A1 PCT/JP2011/064476 JP2011064476W WO2012002260A1 WO 2012002260 A1 WO2012002260 A1 WO 2012002260A1 JP 2011064476 W JP2011064476 W JP 2011064476W WO 2012002260 A1 WO2012002260 A1 WO 2012002260A1
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- light source
- source device
- light
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Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/875—Arrangements for extracting light from the devices
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B33/00—Electroluminescent light sources
- H05B33/12—Light sources with substantially two-dimensional radiating surfaces
- H05B33/14—Light sources with substantially two-dimensional radiating surfaces characterised by the chemical or physical composition or the arrangement of the electroluminescent material, or by the simultaneous addition of the electroluminescent material in or onto the light source
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/85—Arrangements for extracting light from the devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/351—Thickness
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/85—Arrangements for extracting light from the devices
- H10K50/858—Arrangements for extracting light from the devices comprising refractive means, e.g. lenses
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/875—Arrangements for extracting light from the devices
- H10K59/879—Arrangements for extracting light from the devices comprising refractive means, e.g. lenses
Definitions
- the present invention relates to a surface light source device. Specifically, the present invention relates to a surface light source device including an organic electroluminescence element (hereinafter, appropriately referred to as “organic EL element”).
- organic EL element an organic electroluminescence element
- a surface light source device including an organic EL element can have a planar shape, and the color of the light can be white or a color close thereto. For this reason, it can be considered that a surface light source device including an organic EL element is used as a light source of a lighting fixture that illuminates a space such as a living environment or as a backlight of a display device.
- organic EL elements are low in efficiency for use in the above lighting applications. Therefore, it is desired to improve the light extraction efficiency of the organic EL element.
- As a method for improving the light extraction efficiency of an organic EL element it is known to provide various uneven structures on the light exit surface side of the organic EL element. For example, it has been proposed to provide a prism containing a fluorescent compound on the light exit surface (Patent Document 1), and to provide a microlens array (Patent Document 2). With these concavo-convex structures, good light collection can be achieved, and light extraction efficiency can be improved.
- the conventional concavo-convex structure is provided on the light exit surface, the light irradiated from the outside of the apparatus is reflected by the light exit surface, causing interference of reflected light, and rainbow-like color unevenness (hereinafter referred to as “rainbow”) on the light exit surface. May be observed).
- the display device is provided with a surface light source device that causes rainbow unevenness as described above, a plurality of reflected images are observed on the display surface of the display device, and a multi-image phenomenon may occur.
- Such rainbow unevenness significantly reduces the quality of the surface light source device as a light source, and is preferably prevented.
- the present invention has been made in view of the above-described problems, and an object thereof is to provide a surface light source device that has high light extraction efficiency, small rainbow unevenness on the light output surface, and can be easily manufactured.
- the present inventor can suppress unevenness of the rainbow by making the height of the concavo-convex structure uneven (non-uniform) and providing variation within a predetermined range, and can also extract light. We found that efficiency can be improved. It was also found that by allowing the uneven structure height to be non-uniform, the required accuracy of the uneven structure dimensions is reduced, which facilitates mass production and reduces manufacturing costs.
- the present inventor completed the present invention based on these findings. That is, according to the present invention, the following [1] to [5] are provided.
- a surface light source device including an organic electroluminescence element that has a light emitting surface and emits light from the light emitting surface, and a light emitting surface structure layer provided on the light emitting surface side of the organic electroluminescence element, The light-emitting surface structure layer is configured such that, on the surface opposite to the organic electroluminescence element, a relatively recessed portion and a relatively protruding portion are alternately arranged in an in-plane direction parallel to the surface.
- the surface light source device of the present invention has high light extraction efficiency, small rainbow unevenness on the light output surface, and can be easily manufactured.
- FIG. 1 is a perspective view schematically showing the surface light source device according to the first embodiment of the present invention.
- FIG. 2 is a diagram for explaining the surface light source device according to the first embodiment of the present invention, and is a cross-section obtained by cutting the surface light source device shown in FIG. 1 along a plane passing through line 1a-1b and perpendicular to the light exit surface. It is sectional drawing which shows this typically.
- FIG. 3 is a partial plan view schematically showing an enlarged view of a part of the light exit surface of the surface light source device according to the first embodiment of the present invention as viewed from the thickness direction of the surface light source device.
- FIG. 1 is a perspective view schematically showing the surface light source device according to the first embodiment of the present invention.
- FIG. 2 is a diagram for explaining the surface light source device according to the first embodiment of the present invention, and is a cross-section obtained by cutting the surface light source device shown in FIG. 1 along a plane passing through line 1a-1b and perpendicular to the light exit
- FIG. 4 is a partial cross-sectional view schematically showing a cross section obtained by cutting the concavo-convex structure layer according to the first embodiment of the present invention along a plane that passes through the line 3a of FIG. 3 and is perpendicular to the light exit surface.
- FIG. 5 is a perspective view schematically showing a surface light source device according to the second embodiment of the present invention.
- FIG. 6 is a diagram for explaining a surface light source device according to a second embodiment of the present invention, in which the concavo-convex structure layer of the surface light source device shown in FIG. 5 passes through the line 5a-5b and is a surface perpendicular to the light exit surface. It is sectional drawing which shows typically the cross section cut
- FIG. 7 is a cross-sectional view schematically showing a cross section of the surface light source device according to the third embodiment of the present invention cut by a plane perpendicular to the light exit surface.
- FIG. 8 is a cross-sectional view schematically showing a cross section obtained by cutting the concavo-convex structure layer of the surface light source device according to the third embodiment of the present invention along a plane perpendicular to the light exit surface.
- FIG. 9 is a perspective view schematically showing a surface light source device according to the fourth embodiment of the present invention.
- FIG. 10 is a diagram for explaining a surface light source device according to a fourth embodiment of the present invention, in which the surface light source device shown in FIG.
- FIG. 9 is cut along a plane that passes through lines 9a-9b and is perpendicular to the light exit surface. It is sectional drawing which shows this typically.
- FIG. 11 is a top view schematically showing the surface light source device according to the fifth embodiment of the present invention viewed from the thickness direction. 12 is a diagram for explaining a surface light source device according to a fifth embodiment of the present invention, in which the surface light source device shown in FIG. 11 is cut along a plane that passes through a line 11a in FIG. 11 and is perpendicular to the light exit surface. It is sectional drawing which shows the performed cross section.
- FIG. 11 is a top view schematically showing the surface light source device according to the fifth embodiment of the present invention viewed from the thickness direction.
- 12 is a diagram for explaining a surface light source device according to a fifth embodiment of the present invention, in which the surface light source device shown in FIG. 11 is cut along a plane that passes through a line 11a in FIG. 11 and is perpendicular to the light exit surface. It
- FIG. 13 is sectional drawing which shows the cross section which cut
- FIG. 14 is a perspective view schematically showing a surface light source device according to a seventh embodiment of the present invention.
- FIG. 15 is a top view schematically showing the surface light source device according to the eighth embodiment of the present invention viewed from the thickness direction.
- FIG. 16 is a diagram for explaining the surface light source device according to the eighth embodiment of the present invention, in which the surface light source device shown in FIG. 15 is cut along a plane that passes through the line 15a in FIG. 15 and is perpendicular to the light exit surface. It is sectional drawing which shows the performed cross section.
- FIG. 15 is a top view schematically showing the surface light source device according to the eighth embodiment of the present invention viewed from the thickness direction.
- FIG. 16 is a diagram for explaining the surface light source device according to the eighth embodiment of the present invention, in which the surface light source
- FIG. 17 is a top view schematically showing a modification of the concavo-convex structure layer according to the eighth embodiment when viewed from the thickness direction.
- FIG. 18 is a perspective view schematically showing a surface light source device according to the ninth embodiment of the present invention.
- FIG. 19 is a cross-sectional view schematically showing a cross section of the concavo-convex structure layer b manufactured in Example 1 taken along a plane perpendicular to the main surface.
- FIG. 20 is a diagram schematically illustrating the measurement of rainbow unevenness performed in Example 1.
- FIG. FIG. 21 is a cross-sectional view schematically showing a cross section of the concavo-convex structure layer b manufactured in Example 2 taken along a plane perpendicular to the main surface.
- FIG. 22 is a cross-sectional view schematically showing a cross section of the concavo-convex structure layer b manufactured in Example 3 taken along a plane perpendicular to the main surface.
- FIG. 1 and 2 are views for explaining a surface light source device according to a first embodiment of the present invention.
- FIG. 1 is a perspective view schematically showing the surface light source device
- FIG. 2 is a cross-sectional view schematically showing a cross section of the surface light source device shown in FIG. 1 cut along a plane that passes through line 1a-1b and is perpendicular to the light exit surface.
- the surface light source device 10 is a device having a rectangular flat plate structure and includes an organic EL element 140.
- the organic EL element 140 includes at least a first electrode layer 141, a light emitting layer 142, and a second electrode layer 143 in the order described above, and can emit light from at least one of the surfaces 144 and 145.
- the first electrode layer 141 is a transparent electrode
- the second electrode layer 143 is a reflective electrode. For this reason, the light from the light emitting layer 142 is transmitted through the first electrode layer 141, or is reflected by the second electrode layer 143 and then transmitted through the light emitting layer 142 and the first electrode layer 141. Light can be emitted from the surface 144. Therefore, in the following description, the surface 144 is referred to as a “light emitting surface”.
- the light emitting surface structure layer 100 is provided on the light emitting surface 144 side of the organic EL element 140. In the present embodiment, it is assumed that the light exit surface structure layer 100 is directly provided so as to be in contact with the light emitting surface 144.
- the surface light source device 10 of the present embodiment may include components other than the above-described members.
- the sealing substrate 151 is provided on the lower surface 145 of the organic EL element 140 in the drawing.
- an arbitrary substance such as a filler or an adhesive may exist between the surface 145 and the sealing substrate 151, or a gap may exist.
- air or other gas may be present in the space, or the space may be evacuated.
- the surface light source device 10 includes the sealing substrate 151, the organic EL element 140, and the light emitting surface structure layer 100 in this order, and can emit light from the surface 10U on the light emitting surface structure layer 100 opposite to the organic EL element 140. It has become.
- the surface 10U is located on the outermost side of the surface light source device 10, and light is emitted from the surface 10U to the outside of the surface light source device 10. Therefore, the surface 10U is referred to as a “light emitting surface”.
- the organic EL element 140 usually includes two or more electrode layers and a light emitting layer that is provided between these electrode layers and emits light when a voltage is applied from the electrodes. Prepare.
- the organic EL element layers such as an electrode and a light emitting layer constituting the organic EL element are formed on a substrate, and a sealing member for covering those layers is provided, and the layer such as the light emitting layer is sealed with the substrate and the sealing member. It is common to have a stopped configuration.
- the organic EL element that emits light from the substrate side here is called a bottom emission type
- the organic EL element that emits light from the sealing member side is called a top emission type.
- the organic EL element 140 provided in the surface light source device 10 may be any of these.
- the bottom emission type a combination of the above-described substrate and an optional layer as necessary constitutes the light-emitting surface structure layer.
- the top emission type normally, a combination including a structure on the light exit surface side such as a sealing member and an optional layer as necessary constitutes the light exit surface structure layer.
- the light emitting layer is not particularly limited, and a known layer can be appropriately selected.
- the light emitting material in the light emitting layer is not limited to one type, and two or more types may be used in combination at any ratio.
- the light emitting layer is not limited to one layer, and may be a single layer alone or a combination of a plurality of layers in order to be suitable for use as a light source. Thereby, light of white or a color close thereto can be emitted.
- the electrode of the organic EL element is not particularly limited, and a known one can be appropriately selected.
- the electrode 141 on the light emitting surface structure layer 100 side is a transparent electrode
- the electrode 143 on the opposite side is a reflective electrode, so that the light emitting surface structure layer 100 side is directed.
- An organic EL element that emits light from the light emitting surface 144 can be obtained.
- both electrodes 141 and 143 are transparent electrodes, and further have a reflecting member or a scattering member (for example, a white scattering member disposed through an air layer) on the side opposite to the light-emitting surface structure layer 100, so that Light emission to the surface structure layer 100 side can also be achieved.
- the organic EL element 140 further includes other layers (not shown) such as a hole injection layer, a hole transport layer, an electron transport layer, and an electron injection layer between the electrode 141 and the electrode 143. May further be included. Further, the organic EL element 140 may further include arbitrary components such as a wiring for energizing the electrodes 141 and 143 and a peripheral structure for sealing the light emitting layer 142.
- Examples of the material for the transparent electrode include ITO (indium tin oxide).
- Examples of the material for the hole injection layer include a starburst aromatic diamine compound.
- Examples of the material for the hole transport layer include a triphenyldiamine derivative.
- Examples of the host material for the yellow light emitting layer include triphenyldiamine derivatives, and examples of the dopant material for the yellow light emitting layer include tetracene derivatives.
- Examples of the material for the green light emitting layer include pyrazoline derivatives.
- Examples of the host material for the blue light emitting layer include anthracene derivatives, and examples of the dopant material for the blue light emitting layer include perylene derivatives.
- Examples of the material for the red light emitting layer include a europium complex.
- Examples of the material for the electron transport layer include aluminum quinoline complex (Alq).
- Examples of the material for the reflective electrode include lithium fluoride and aluminum, which are sequentially laminated by vacuum film formation.
- a light emitting layer that generates a light emission color having a complementary color relationship which is called a laminated type or a tandem type, can be obtained by appropriately combining the above or other light emitting layers.
- the combination of complementary colors can be yellow / blue, green / blue / red, or the like.
- the light emitting surface structure layer 100 is a layer provided on the light emitting surface 144 of the organic EL element 140.
- the light exit surface 10U is the surface of the light exit surface structure layer 100 opposite to the organic EL element 140.
- the light exit surface 10U is a surface exposed on the outermost surface of the surface light source device 10, and is a light exit surface as the surface light source device 10, that is, a light exit surface when light is emitted from the surface light source device 10 to the outside of the device.
- the light exit surface 10U When viewed macroscopically, the light exit surface 10U is a surface parallel to the light emitting surface 144 of the organic EL element 140 and parallel to the main surface of the surface light source device 10. However, when the light exit surface 10U is microscopically viewed, the light exit surface 10U has a concavo-convex structure, which will be described later. Therefore, in the following description, being parallel or perpendicular to the light exit surface means that it is parallel or perpendicular to the light exit surface viewed macroscopically ignoring the recesses or projections unless otherwise specified.
- the surface light source device 10 will be described in a state where the light exit surface 10U is placed so as to be parallel and upward with respect to the horizontal direction unless otherwise specified. Further, the fact that the component is “parallel” or “vertical” may include an error within a range that does not impair the effects of the present invention, for example, ⁇ 5 °.
- the light exit surface structure layer 100 includes a multilayer body 110 including the concavo-convex structure layer 111 and the base film layer 112, a support substrate 131 as a substrate, and an adhesive layer 121 that adheres the multilayer body 110 and the support substrate 131.
- the uneven structure layer 111 is a layer located on the upper surface of the surface light source device 10 (that is, the outermost layer on the light output surface side of the surface light source device 10).
- the concavo-convex structure layer 111 has a concavo-convex structure including a plurality of concave portions 113 and flat portions 114 positioned around the concave portions 113.
- the concave portion 113 is a portion that is relatively depressed as compared with the flat portion 114, the concave portion 113 hits the concave portion according to the present invention, and the flat portion 114 protrudes relative to the concave portion 113, so that the present invention is applied. It hits the convex part. And the light emission surface 10U is prescribed
- FIG. 3 is an enlarged partial plan view schematically showing a part of the light exit surface 10U of the surface light source device 10 as viewed from the thickness direction of the surface light source device 10.
- FIG. 4 is a partial cross-sectional view schematically showing a cross section of the concavo-convex structure layer 111 taken along a plane that passes through the line 3a of FIG. 3 and is perpendicular to the light exit surface 10U.
- thickness direction represents the thickness direction of the surface light source device.
- the light exit surface structure layer 100 includes, on the light exit surface 10U, a plurality of recesses 113 including slopes 11A to 11D, and a flat portion 114 positioned around the recess 113.
- the “slope” is a surface that forms an angle that is not parallel to the light exit surface 10U.
- the surface on the flat part 114 is a flat surface parallel to the light exit surface 10U.
- Each of the plurality of recesses 113 is a depression having a regular quadrangular pyramid shape. Accordingly, the slopes 11A to 11D of the recess 113 have the same shape, and the bases 11E to 11H of the regular quadrangular pyramid form a square.
- the line 3 a is a line that passes over all the vertices 11 ⁇ / b> P of the row of recesses 113 and is parallel to the bases 11 ⁇ / b> E and 11 ⁇ / b> G of the recess 113.
- each recess 113 can be usually 1 to 60 ⁇ m, preferably 2 to 50 ⁇ m.
- the depth of each recess 113 can usually be 1 to 50 ⁇ m, and preferably 2 to 40 ⁇ m.
- the concave portions 113 are continuously arranged along two orthogonal in-plane directions X and Y at a constant interval.
- the portion corresponding to the gap between the adjacent recesses 113 constitutes a flat portion 114. Therefore, the light exit surface structure layer 100 has alternately the recesses 113 and the flat portions 114 in the in-plane directions X and Y parallel to the light exit surface 10U.
- one in-plane direction X is parallel to the bases 11E and 11G.
- the plurality of recesses 113 are aligned at a constant interval 11J.
- the other in-plane direction Y is parallel to the bases 11F and 11H.
- the plurality of recesses 113 are aligned at a constant interval 11K.
- the width of the flat portion 114 which is a portion corresponding to the gap, can be usually 0.1 to 20 ⁇ m.
- the angles 11L and 11M formed by the inclined surfaces 11A to 11D constituting each of the concave portions 113 and the flat portion 114 are preferably 40 ° or more, more preferably 45 ° or more, Moreover, 70 degrees or less are preferable and 60 degrees or less are more preferable. Further, when the shape of the recess 113 is a quadrangular pyramid as in the present embodiment, the apex angle 11N is preferably 60 ° to 90 °. Furthermore, from the viewpoint of increasing the light extraction efficiency while minimizing the change in color depending on the observation angle, the angles 11L and 11M formed by the inclined surfaces 11A to 11D and the flat portion 114 are preferably large.
- the angle is not less than 60 °, and it is even more preferable that the angle be not less than 60 °.
- the upper limit of the corners 11L and 11M is usually 70 ° in consideration of maintaining the durability of the uneven structure layer 111.
- the angles 11L and 11M formed by the inclined surfaces 11A to 11D and the flat portion 114 are set to 60 °.
- the apex angle of the regular quadrangular pyramid that forms the recess 113 that is, the angle formed by the opposing inclined surfaces at the apex 11P (the angle 11N shown in FIG. 4 for the angles formed by the inclined surfaces 11B and 11D) is also 60 °. .
- the distances in the thickness direction of the surface light source device 10 between the bottoms of the adjacent concave portions 113 and the tips of the convex portions are uneven within a predetermined range.
- the bottom of the recess 113 indicates the most depressed portion in each of the recesses 113, and indicates the portion where the distance to the light emitting surface 144 in the thickness direction of the surface light source device 10 is the shortest.
- the apex 11P of each recess 113 hits the bottom of the recess 113.
- the tip of the convex portion refers to a portion that protrudes most in each convex portion, and refers to a portion that has the longest distance to the light emitting surface 144 in the thickness direction of the surface light source device 10.
- the flat portion 114 is a flat surface parallel to the light emitting surface 144, the flat portion 114 itself hits the tip of the convex portion.
- the predetermined range is a range in which the standard deviation (sample standard deviation) ⁇ is usually 0.05 ⁇ m or more, preferably 0.06 ⁇ m or more, more preferably 0.08 ⁇ m or more.
- the light extraction efficiency from the light exit surface 10U can be improved, and rainbow unevenness due to reflected light can be suppressed.
- the standard deviation ⁇ of the height difference H between adjacent irregularities may be uneven so that it falls within a predetermined range in the entire light exit surface 10U, the recess 113 and the flat portion 114 have excessively high dimensions. Since accuracy is not required, mass production is easy and manufacturing costs can be reduced.
- the lower limit value of the range of the standard deviation ⁇ of the height difference H of the adjacent unevenness is significant in that the brightness profile of the rainbow unevenness is set to 50% or less and the rainbow unevenness cannot be recognized visually.
- the upper limit of the predetermined range is a standard deviation ⁇ , which is usually 0.5 ⁇ m or less, preferably 0.4 ⁇ m or less, more preferably 0.3 ⁇ m or less. If the degree of unevenness (variation) in the height difference H between adjacent irregularities is excessively large, depending on the aspect of the irregular structure, many scratches occur in the production process of the surface light source device 10 and stable production is difficult. There is a risk.
- one or both of the height of the vertex 11P of the recess 113 and the height of the flat portion 114 are not uniform, so that the difference in height H between adjacent irregularities may be uneven.
- the heights of the vertices 11 ⁇ / b> P of the concave portion 113 are uniform, but the height of the flat portion 114 is not uniform, so that the height difference between adjacent irregularities is different.
- H is uneven.
- the height of the flat part 114 is uneven as described above, there is a step in the flat part 114, but since the degree of the unevenness is small, the step is also small. Therefore, in FIG. 1 and FIG. 3, illustration of the step in the flat portion 114 is omitted.
- the rainbow unevenness can be suppressed by making the height difference H of the adjacent unevenness uneven so that the standard deviation ⁇ falls within a predetermined range. This is probably due to the following reasons.
- the light is reflected at the light exit surface 10U, or the light that has entered the surface light source device 10 is reflected at the internal layer interface, and the reflected light is reflected. Arise.
- the reflected light may be diffracted and refracted on the light exit surface 10U when reflected by the light exit surface 10U and when exiting from the inside of the surface light source device 10 to the outside.
- the rainbow unevenness is caused by the interference of the light having the diffraction and refraction described above.
- the unevenness of the height difference H between adjacent unevenness on the light exit surface 10U can be reduced, so that the intensity of interference can be reduced, thereby eliminating rainbow unevenness. It is considered possible.
- the height difference H of the unevenness adjacent to the light exit surface 10U is obtained by randomly extracting measurement points and measuring the height (cross-sectional profile) using a laser microscope (VK-9700: manufactured by Keyence Corporation). Can be sought. Usually, the cross-sectional profile may be measured over a length of 100 ⁇ m along a predetermined measurement direction parallel to the light exit surface 10U. Based on the measured cross-sectional profile, a pair of adjacent concave and convex portions is defined as one unit of unevenness, and the maximum value (corresponding to the tip of the convex portion) and the minimum value (corresponding to the bottom of the concave portion) in this uneven unit.
- the difference is defined as the height difference H of the concavities and convexities adjacent to each other in one unit of concavity and convexity.
- the measurement is preferably performed at a plurality of locations, for example, at 15 points.
- the standard deviation ⁇ may be measured from the height difference H between the adjacent irregularities thus measured.
- what is necessary is just to set the said measurement direction parallel to the direction where the said height difference H becomes the largest, when arrangement
- the difference in height H between adjacent irregularities is the maximum value (Ra () of the center line average roughness measured on the light emitting surface 10U along various in-plane directions (various directions in a plane parallel to the light emitting surface 10U). max)) is usually in the range of 1 ⁇ m to 50 ⁇ m.
- the handling of the multilayer body 110 in the manufacturing process of the surface light source device 10 is facilitated.
- the difference TH between the height difference H of the adjacent unevenness shown in FIG. 4 and the thickness T of the uneven structure layer 111 be 0 to 30 ⁇ m.
- the ratio of the area occupied by the flat portion 114 to the total area occupied by the flat portion 114 and the area occupied by the concave portion 113 (hereinafter referred to as “flat portion ratio”). ”) Is appropriately adjusted, the light extraction efficiency of the surface light source device 10 can be improved. Specifically, by setting the flat portion ratio to 10% to 75%, good light extraction efficiency can be obtained, and the mechanical strength of the light exit surface 10U can be increased.
- the light exit surface structure layer 100 may be composed of a plurality of layers, but may be composed of a single layer. From the viewpoint of easily obtaining the light-emitting surface structure layer 100 having desired characteristics, it is preferable that the light-emitting surface structure layer 100 is composed of a plurality of layers.
- the light exit surface structure layer 100 includes a multilayer body 110 in which an uneven structure layer 111 and a base film layer 112 are combined. Thereby, the light emission surface structure layer 100 with high performance can be obtained easily.
- the concavo-convex structure layer 111 and the base film layer 112 can usually be formed of a resin composition containing a transparent resin. That the transparent resin is “transparent” means that it has a light transmittance suitable for use in an optical member.
- each layer constituting the light exit surface structure layer 100 may have a light transmittance suitable for use in an optical member, and the light exit surface structure layer 100 as a whole has a total light transmittance of 80% or more. It is sufficient to have a rate.
- the transparent resin contained in the resin composition is not particularly limited, and various resins that can form a transparent layer can be used.
- various resins that can form a transparent layer can be used.
- examples thereof include a thermoplastic resin, a thermosetting resin, an ultraviolet curable resin, and an electron beam curable resin.
- thermoplastic resins are preferable because they can be easily deformed by heat, and ultraviolet curable resins have high curability and high efficiency, so that the uneven structure layer 111 can be efficiently formed.
- thermoplastic resin examples include polyester-based, polyacrylate-based, and cycloolefin polymer-based resins.
- ultraviolet curable resin examples include epoxy resins, acrylic resins, urethane resins, ene / thiol resins, and isocyanate resins. As these resins, those having a plurality of polymerizable functional groups can be preferably used. In addition, the said resin may be used individually by 1 type, and may be used combining two or more types by arbitrary ratios.
- the material of the concavo-convex structure layer 111 constituting the multilayer body 110 a material having a high hardness at the time of curing from the viewpoint of easily forming the concavo-convex structure of the light exit surface 10U and easily obtaining the scratch resistance of the concavo-convex structure.
- a material having a pencil hardness of HB or higher is preferable, and a material of H or higher is more preferable.
- the material which becomes 2H or more is more preferable.
- the material of the base film layer 112 in order to facilitate the handling when forming the concavo-convex structure layer 111 and the handling of the multilayer body 110 after forming the multilayer body 110, a certain degree of flexibility is provided. There are preferred. By combining such materials, the multilayer body 110 that is easy to handle and excellent in durability can be obtained, and as a result, the high-performance surface light source device 10 can be easily manufactured.
- Such a combination of materials can be obtained by appropriately selecting the transparent resin exemplified above as a resin constituting each material.
- an ultraviolet curable resin such as acrylate is used as the transparent resin constituting the material of the concavo-convex structure layer 111, while the transparent resin constituting the material of the base film layer 112 is made of an alicyclic olefin polymer. It is preferable to use a film (such as a ZEONOR film described later) or a polyester film.
- the refractive index of the concavo-convex structure layer 111 and the base film layer 112 may be as close as possible.
- the refractive index difference between the uneven structure layer 111 and the base film layer 112 is preferably within 0.1, and more preferably within 0.05.
- a material of a layer that is a constituent element of the light exit surface structure layer 100 such as the concavo-convex structure layer 111 and the base film layer 112
- a material having light diffusibility may be used. Thereby, since the light which permeate
- the light diffusing material examples include a material containing particles, and an alloy resin that diffuses light by mixing two or more kinds of resins.
- a material including particles is preferable, and a resin composition including particles is particularly preferable.
- the particles may be transparent or opaque.
- the material of the particles include metals and metal compounds, and resins.
- the metal compound include metal oxides and nitrides. Specific examples of metals and metal compounds include metals having high reflectivity such as silver and aluminum; metal compounds such as silicon oxide, aluminum oxide, zirconium oxide, silicon nitride, tin-added indium oxide, and titanium oxide. be able to.
- the resin include methacrylic resin, polyurethane resin, and silicone resin.
- grain material may be used individually by 1 type, and may be used combining two or more types by arbitrary ratios.
- the shape of the particles can be, for example, a spherical shape, a cylindrical shape, a cubic shape, a rectangular parallelepiped shape, a pyramid shape, a conical shape, a star shape, or the like.
- the particle diameter of the particles is preferably 0.1 ⁇ m or more, preferably 10 ⁇ m or less, more preferably 5 ⁇ m or less.
- the particle diameter is a 50% particle diameter in an integrated distribution obtained by integrating the volume-based particle amount with the particle diameter as the horizontal axis. The larger the particle size, the larger the content ratio of particles necessary for obtaining the desired effect, and the smaller the particle size, the smaller the content.
- the particle size is smaller, desired effects such as a reduction in change in color depending on the observation angle and an improvement in light extraction efficiency can be obtained with fewer particles.
- the particle shape is other than spherical, the diameter of the sphere having the same volume is used as the particle size.
- the difference between the refractive index of the particles and the refractive index of the transparent resin is preferably 0.05 to 0.5. More preferably, it is 07 to 0.5.
- either the particle or the refractive index of the transparent resin may be larger. If the refractive index of the particles and the transparent resin is too close, the diffusion effect cannot be obtained and the color unevenness may be difficult to be suppressed. Conversely, if the difference is too large, the diffusion becomes large and the color unevenness is suppressed, but light Extraction effect may be reduced.
- the content ratio of the particles is a volume ratio in the total amount of the layer containing the particles, preferably 1% or more, more preferably 5% or more, 80% or less, and more preferably 50% or less.
- the resin composition can contain arbitrary components as necessary.
- the optional component include additives such as phenol-based and amine-based deterioration preventing agents; surfactant-based, siloxane-based antistatic agents; triazole-based, 2-hydroxybenzophenone-based light-resistant agents; Can be mentioned.
- the thickness T of the uneven structure layer 111 is not particularly limited, but is preferably 1 ⁇ m to 70 ⁇ m.
- the thickness T of the concavo-convex structure layer 111 is the distance between the surface on the base film layer 112 side where the concavo-convex structure is not formed and the flat portion 114 of the concavo-convex structure.
- the thickness of the base film layer 112 is preferably 20 ⁇ m to 300 ⁇ m.
- the surface light source device 10 of this embodiment includes a support substrate 131 between the organic EL element 140 and the multilayer body 110.
- the support substrate 131 By providing the support substrate 131, the surface light source device 10 can be given rigidity for suppressing deflection.
- the supporting substrate 131 is provided with a substrate that is excellent in the performance of sealing the organic EL element 140 and that can easily form the layers constituting the organic EL element 140 on the manufacturing process in order. Thus, the durability of the surface light source device 10 can be improved and the manufacture can be facilitated.
- Examples of the material constituting the support substrate 131 include glass and resin. In addition, the material of the support substrate 131 may be used individually by 1 type, and may be used combining two or more types by arbitrary ratios.
- the refractive index of the support substrate 131 is not particularly limited, but is preferably 1.4 to 2.0.
- the thickness of the support substrate 131 is not particularly limited, but is preferably 0.1 mm to 5 mm.
- the surface light source device 10 of this embodiment includes an adhesive layer 121 between the multilayer body 110 and the support substrate 131.
- the adhesive layer 121 is a layer that is interposed between the base film layer 112 of the multilayer body 110 and the support substrate 131 and adheres these two layers.
- the adhesive that is the material of the adhesive layer 121 is not only a narrowly defined adhesive (a so-called hot-melt type adhesive having a shear storage modulus at 23 ° C. of 1 to 500 MPa and not exhibiting tackiness at room temperature), A pressure-sensitive adhesive having a shear storage modulus at 23 ° C. of less than 1 MPa is also included.
- a material having a refractive index close to that of the support substrate 131 or the base film layer 112 and transparent can be used as appropriate. More specifically, an acrylic adhesive or a pressure-sensitive adhesive can be used.
- the thickness of the adhesive layer is preferably 5 ⁇ m to 100 ⁇ m.
- the method of manufacturing the surface light source device 10 is not particularly limited.
- each layer constituting the organic EL element 140 is laminated on one surface of the support substrate 131 and then or before that, on the other surface of the support substrate 131.
- the multilayer body 110 having the concavo-convex structure layer 111 and the base film layer 112 can be manufactured by sticking via the adhesive layer 121.
- a mold such as a mold having a desired shape is prepared, and this mold is used as a layer of a material for forming the concavo-convex structure layer 111 This can be done by transferring.
- Method 1 An unprocessed multilayer having a layer of the resin composition A constituting the base film layer 112 and a layer of the resin composition B constituting the concavo-convex structure layer 111 (the concavo-convex structure is not yet formed) A method for preparing and forming a concavo-convex structure on the surface of the raw multilayer body on the resin composition B side; and (Method 2) applying the resin composition B in a liquid state on the base film layer 112 Then, a method may be mentioned in which a mold is applied to the applied layer of the resin composition B, the resin composition B is cured in that state, and the concavo-convex structure layer 111 is formed.
- the raw multilayer body can be obtained by, for example, extrusion molding in which the resin composition A and the resin composition B are coextruded.
- An uneven structure can be formed by pressing a mold having a desired surface shape onto the surface of the unprocessed multilayer body on the resin composition B side. More specifically, a long raw multilayer body is continuously formed by extrusion molding, and the raw multilayer body is pressed with a transfer roll and a nip roll having a desired surface shape, thereby continuously. Manufacturing can be performed efficiently.
- the clamping pressure between the transfer roll and the nip roll is preferably several MPa to several tens of MPa.
- the temperature at the time of transfer is preferably Tg or more (Tg + 100 ° C.) or less, where Tg is the glass transition temperature of the resin composition B.
- the contact time between the unprocessed multilayer body and the transfer roll can be adjusted by the film feed speed, that is, the roll rotation speed, and is preferably 5 seconds or more and 600 seconds or less.
- Method 2 it is preferable to use a composition that can be cured by energy rays such as ultraviolet rays as the resin composition B constituting the concavo-convex structure layer 111.
- the resin composition B is applied on the base film layer 112, and in a state where the mold is applied, the resin composition B is located on the back side of the application surface (the side opposite to the surface on which the resin composition B is applied).
- energy rays such as ultraviolet rays from a light source
- the coating film of the resin composition B can be used as the concavo-convex structure layer 111 to obtain a multilayer body 110. it can.
- the surface light source device 10 of the present embodiment Since the surface light source device 10 of the present embodiment is configured as described above, the light emitted from the light emitting surface 144 of the organic EL element 140 passes through the light emitting surface structure layer 100 and is extracted from the light emitting surface 10U. . At this time, since the light exit surface 10U has an uneven structure having the recess 113 and the flat portion 114, the light extraction efficiency from the light output surface 10U can be increased as compared with the case where the uneven structure is not provided.
- the surface light source device 10 has uneven height differences H between adjacent irregularities on the light exit surface 10U so that the standard deviation ⁇ is within a predetermined range, rainbow unevenness due to reflected light can be suppressed. Further, when the surface light source device 10 is provided in a display device, it is possible to prevent a multi-image phenomenon. Furthermore, since the individual dimensional accuracy of the recess 113 and the flat portion 114 does not have to be high, mass production becomes easy and the manufacturing cost can be reduced.
- the surface light source device 10 of the present embodiment it is possible to prevent the light exit surface 10U from being chipped due to an external impact, thereby improving the mechanical strength of the light exit surface 10U.
- the flat portion 114 is a flat surface (flat surface).
- the height of the flat part 114 is uneven, the degree of the unevenness is small.
- the surface light source device 10 of the present embodiment it is possible to reduce the change in color depending on the observation angle.
- the light emitted from the light exit surface 10 ⁇ / b> U is diffused by the recess 113.
- the light exiting surface causes the light exiting surface to be a uniformly flat surface with a displacement of at least one of the x and y coordinates of the chromaticity coordinates in all hemispherical directions in the light exiting from the exit surface 10U
- it can be reduced. Therefore, it is possible to suppress a change in color depending on the observation angle at which the light exit surface 10U is observed.
- a spectral radiance meter is installed on the normal direction of the light exit surface 10U (that is, the direction perpendicular to the light exit surface 10U).
- a linear direction is set to 0 °
- a mechanism for rotating the light exit surface from ⁇ 90 ° to 90 ° can be provided, whereby chromaticity coordinates can be calculated from the emission spectrum measured in each direction, and the displacement can be calculated.
- the shape of the concave portion and the convex portion constituting the light exit surface is not limited to the pyramid shape exemplified in the first embodiment, and may be a truncated pyramid shape.
- the truncated pyramid shape refers to a shape in which a flat portion is provided at the top of the pyramid and the surface is flattened.
- the example is demonstrated using drawing.
- FIG. 5 and 6 are diagrams for explaining the surface light source device according to the second embodiment of the present invention.
- FIG. 5 is a perspective view schematically showing the surface light source device
- FIG. 5 is a cross-sectional view schematically showing a cross section of the concavo-convex structure layer of the surface light source device shown cut along a plane that passes through lines 5a-5b and is perpendicular to the light exit surface.
- FIG. 5 the surface light source device 20 according to the second embodiment includes the concave portion 213 formed on the light exit surface 20 ⁇ / b> U that is the surface of the uneven structure layer 211 in the multilayer body 210 constituting the light exit surface structure layer 200.
- the configuration is the same as that of the first embodiment except that the shape is different.
- the recess 213 formed on the surface of the concavo-convex structure layer 211 has a shape in which the top of a regular quadrangular pyramid is chamfered flat (pyramidal frustum shape), and has a constant interval on the light emitting surface 20U. Is provided. A gap is provided between adjacent recesses 213, and this gap constitutes a flat portion 214. Furthermore, since the concave portion 213 has a truncated pyramid shape, the concave portion 213 has a bottom surface portion 21P at the bottom as a flat surface parallel to the light output surface 20U.
- the height difference H of the unevenness adjacent to the light exit surface 20U is uneven so that the standard deviation ⁇ falls within a predetermined range.
- the bottom surface portion 21P hits the bottom of the concave portion 213, and the flat portion 214 hits the tip of the convex portion. Therefore, in the surface light source device 20, when the adjacent concave portion 213 and the convex portion 214 are compared, the distance between the bottom surface portion 21P and the flat portion 214 in the thickness direction of the surface light source device 20 (that is, the adjacent unevenness) H) is uneven so that the standard deviation ⁇ falls within a predetermined range. In the present embodiment, as shown in FIG.
- the height of the flat part 214 is uniform, but the height of the bottom surface 21P is not uniform, so that the difference in height H between adjacent irregularities is not uniform.
- An example is shown.
- the height difference H of the adjacent unevenness may be uneven due to the unevenness of the height of the flat portion 214.
- corrugation may become uneven because both the heights of the flat part 214 become uneven.
- the light extraction efficiency is increased as in the first embodiment, and , Rainbow unevenness can be suppressed. Also, if dust and debris accumulate in the recess 213, the light extraction efficiency may decrease and bright spots may be generated. However, if the bottom of the recess 213 is a flat bottom surface portion 21P, In addition, it is preferable because fragments and the like hardly accumulate. Furthermore, according to this embodiment, the same advantage as 1st embodiment can also be acquired.
- the difference 21R may normally be 20% or less of the height 21S of the pyramid when the top of the truncated pyramid is not flat and has a sharp pyramid shape.
- the shape of the recessed part 213 is a truncated pyramid shape, let the angle of slopes 212A and 213B except the bottom face part 21P be an angle of a slope.
- the light extraction efficiency can be increased by setting the angle of the inclined surface of the recess 213 to such an angle.
- the slopes are not necessarily all at the same angle, and slopes having different angles may coexist within the above range.
- the bottom of the concave portion constituting the light exit surface may be rounded.
- the example is demonstrated using drawing.
- FIG. 7 and 8 are diagrams for explaining a surface light source device according to the third embodiment of the present invention.
- FIG. 7 schematically shows a cross section of the surface light source device taken along a plane perpendicular to the light exit surface.
- FIG. 8 is a cross-sectional view schematically showing a cross section of the concavo-convex structure layer of the surface light source device taken along a plane perpendicular to the light exit surface.
- the surface light source device 30 according to the third embodiment includes a concave portion 313 formed on the light exit surface 30 ⁇ / b> U that is the surface of the uneven structure layer 311 in the multilayer body 310 constituting the light exit surface structure layer 300.
- the configuration is the same as that of the first embodiment except that the shape is different.
- the recesses 313 formed on the surface of the concavo-convex structure layer 311 have a round bottom 31P, and are provided on the light exit surface 30U at a constant interval.
- a gap is provided between adjacent recesses 313, and this gap constitutes a flat portion 314.
- the height difference H of the unevenness adjacent to the light exit surface 30U is uneven so that the standard deviation ⁇ falls within a predetermined range.
- the flat part 314 hits the tip of the convex part. Therefore, in the surface light source device 30, when the adjacent concave portion 313 and the convex portion 314 are compared, the distance between the bottom 31 ⁇ / b> P of the concave portion 313 and the flat portion 314 in the thickness direction of the surface light source device 30 (that is, adjacent).
- the height difference (H of the matching irregularities) is uneven so that the standard deviation ⁇ falls within a predetermined range. In this embodiment, as shown in FIGS.
- the height of the bottom 31 ⁇ / b> P of the recess 313 is even, but the height of the flat portion 314 is not uniform, so that the height difference between adjacent recesses and protrusions is different.
- H is uneven
- the heights of the flat portions 314 are uniform, but the heights of the bottoms 31P of the recesses 313 may be uneven, so that the difference in height H between adjacent concavities and convexities may be uneven.
- the height difference H between adjacent irregularities may be uneven due to the unevenness of the height of the flat portion 314 and the height of the flat portion 314.
- the light extraction efficiency can be increased as in the first embodiment. It is possible to increase rainbow unevenness. Further, if dust and debris accumulate in the recess 313, the light extraction efficiency may be reduced and a bright spot may be generated. However, if the bottom 31P of the recess 313 is rounded, dust, debris, etc. Is preferable because it is difficult to accumulate. Furthermore, according to this embodiment, the same advantage as 1st embodiment can also be acquired.
- the height of the bottom 31P and the top 31Q when the bottom has a rounded and pyramidal shape when the bottom has a rounded and pyramidal shape.
- the difference 31R may be usually 20% or less of the pyramid height 31S in the case of a rounded and sharp pyramid shape.
- the angles of the slopes 313A and 313B excluding the rounded portion are the slope angles. By setting the angle of the slope to such an angle, the light extraction efficiency can be increased.
- the slopes are not necessarily all at the same angle, and slopes having different angles may coexist within the above range.
- a concave and convex structure is provided on the light output surface by providing a concave portion on the light output surface, but a concave and convex structure may be provided by providing a convex portion on the light output surface.
- a concave and convex structure may be provided by providing a convex portion on the light output surface.
- FIG. 9 and 10 are views for explaining a surface light source device according to a fourth embodiment of the present invention.
- FIG. 9 is a perspective view schematically showing the surface light source device
- FIG. FIG. 9 is a cross-sectional view schematically showing a cross section of the surface light source device shown cut along a plane that passes through lines 9a-9b and is perpendicular to the light exit surface.
- the surface light source device 40 according to the fourth embodiment has a light emitting surface 40U that is a surface of the concavo-convex structure layer 411 in the multilayer body 410 constituting the light emitting surface structure layer 400 instead of the recess 113. Except that the convex part 414 is provided, it has the structure similar to 1st embodiment.
- the convex portions 414 are provided at regular intervals on the light exit surface 40U.
- a gap is provided between adjacent convex portions 414, and this gap constitutes a flat portion 413.
- the convex portion 414 is a portion that protrudes relatively as compared with the flat portion 413, and therefore corresponds to the convex portion according to the present invention, and the flat portion 413 is relatively depressed as compared with the convex portion 414. It corresponds to the recess according to the present invention.
- the light emission surface 40U is prescribed
- each of the convex portions 414 has a shape (pyramidal trapezoidal shape) in which the top of a regular quadrangular pyramid is chamfered flat. Therefore, as shown in FIG. 10, the convex portion 414 includes four inclined surfaces 414A and 414B and an upper surface portion 414U surrounded by the inclined surfaces 414A and 414B.
- the upper surface portion 414U hits the upper bottom surface of the truncated pyramid shape of the convex portion 414, and is a flat plane.
- the flat portion 413 is also a flat plane, and both the flat portion 413 and the upper surface portion 414U are parallel to the light emitting surface 40U and the light emitting surface 144.
- the height difference H of the unevenness adjacent to the light exit surface 40U is uneven so that the standard deviation ⁇ is within a predetermined range.
- the flat portion 413 hits the bottom of the concave portion
- the upper surface portion 414U hits the tip of the convex portion 414. Therefore, in the surface light source device 40, when the adjacent flat portion 413 and the convex portion 414 are compared, the distance between the flat portion 413 and the upper surface portion 414U in the thickness direction of the surface light source device 40 (that is, adjacent).
- the unevenness (height difference) H is uneven so that the standard deviation ⁇ is within a predetermined range. In the present embodiment, as shown in FIG.
- the height of the flat portion 413 is uniform, but the height of the upper surface portion 414 ⁇ / b> U is not uniform, so that the height difference H between adjacent irregularities is not uniform.
- An example is shown.
- the height difference H of the adjacent unevenness may be uneven due to uneven height of the flat portion 413, and the height of the flat portion 413 and The height difference H between adjacent irregularities may be uneven because both the heights of the upper surface portion 414U are uneven.
- the light extraction efficiency can be increased and rainbow unevenness can be suppressed as in the first embodiment.
- tip of the convex part 414 is a flat plane, the chip
- the same advantage as 1st embodiment can also be acquired.
- the shape of the concave portion and the convex portion constituting the light exit surface may be a shape other than the pyramid and the truncated pyramid described above, for example, a partial shape of a sphere.
- the concave portions and the convex portions can be arranged in an arbitrary manner other than being arranged along two orthogonal in-plane directions as exemplified in the first to fourth embodiments.
- the plurality of recesses may be arranged in only one direction on the light exit surface, or in three or more in-plane directions, or may be arranged randomly.
- drawing the example is demonstrated using drawing.
- FIGS. 11 and 12 are diagrams for explaining a surface light source device according to a fifth embodiment of the present invention
- FIG. 11 is a top view schematically showing the surface light source device as viewed from the thickness direction.
- FIG. 12 is a cross-sectional view showing a cross section of the surface light source device shown in FIG. 11 cut along a plane passing through the line 11a in FIG. 11 and perpendicular to the light exit surface 50U.
- the surface light source device 50 according to the fifth embodiment is different in the shape of the light exit surface 50 ⁇ / b> U that is the surface of the concavo-convex structure layer 511 in the multilayer body 510 constituting the light exit surface structure layer 500.
- Others have the same configuration as the first embodiment.
- the concave portion 513 formed on the surface of the concavo-convex structure layer 511 has a hemispherical shape, and has three in-plane parallel to the lines 11a, 11b, and 11c at a certain interval on the light exit surface 50U. It is continuously arranged along the direction. Lines 11a, 11b and 11c are at an angle of 60 ° to each other. Between the adjacent recesses 513, gaps are provided along the lines 11a, 11b, and 11c, and the gaps constitute a flat part 514.
- the height difference H of the unevenness adjacent to the light exit surface 50U is uneven so that the standard deviation ⁇ is within a predetermined range.
- the flat part 514 hits the tip of the convex part. Therefore, in the surface light source device 50, when the adjacent concave portion 513 and the flat portion 514 are compared, the distance between the bottom 513 ⁇ / b> P of the concave portion 513 and the flat portion 514 in the thickness direction of the surface light source device 50 (that is, adjacent).
- the height difference H of the matching irregularities is uneven so that the standard deviation ⁇ falls within a predetermined range. In the present embodiment, as shown in FIG.
- the flat portions 514 are even in height, but the bottoms 513 ⁇ / b> P of the recesses 513 are uneven in height, so that the height difference H between adjacent concavities and convexities is uneven.
- An example is shown.
- the height of the bottom 513P of the recess 513 is uniform, the height H of the adjacent unevenness may be uneven due to the unevenness of the flat portion 514, and the bottom 513P of the recess 513 may be uneven.
- the height difference H between adjacent irregularities may be uneven due to the unevenness of both the height of the flat portion 514 and the height of the flat portion 514.
- the concave portion 513 has a shape of a part of a sphere because the bottom of the concave portion 513 is rounded, so that dust, debris, and the like hardly accumulate in the concave portion 513. Furthermore, the same advantages as those of the first embodiment can be obtained.
- the tip of the convex portion constituting the light exit surface may be rounded.
- the example is demonstrated using drawing.
- FIG. 13 is sectional drawing which shows the cross section which cut
- the surface light source device 60 according to the sixth embodiment includes a hemispherical recess 513 on the light exit surface 60 ⁇ / b> U that is the surface of the uneven structure layer 611 in the multilayer body 610 constituting the light exit surface structure layer 600.
- the configuration is the same as that of the fifth embodiment except that a hemispherical convex portion 614 is provided instead of.
- the convex portions 614 are provided at regular intervals on the light exit surface 60U.
- a gap is provided between adjacent convex portions 614, and this gap constitutes a flat portion 613.
- the convex portion 614 is a portion that protrudes relatively as compared with the flat portion 613, and therefore corresponds to the convex portion according to the present invention, and the flat portion 613 is relatively depressed as compared with the convex portion 614. It corresponds to the recess according to the present invention.
- the light emission surface 60U is prescribed
- the height difference H of the unevenness adjacent to each other on the light exit surface 60U is uneven so that the standard deviation ⁇ is within a predetermined range.
- the flat portion 613 hits the bottom of the recess. Therefore, in the surface light source device 60, when the adjacent flat portion 613 and the convex portion 614 are compared, the distance between the flat portion 613 and the tip 614P of the convex portion 614 in the thickness direction of the surface light source device 60 (that is, , The height difference between adjacent irregularities) H is uneven so that the standard deviation ⁇ falls within a predetermined range.
- the height of the flat portion 613 is uniform, but the height difference H between adjacent irregularities is caused by the uneven height of the tip 614P of the convex portion 614.
- the height difference H of the adjacent irregularities may be uneven due to the unevenness of the flat portions 613.
- the height difference H between adjacent irregularities may be irregular because both the height and the height of the tip 614P of the convex part 614 are irregular.
- the light extraction efficiency is the same as in the first embodiment. And rainbow unevenness can be suppressed.
- the tip 614P of the convex portion 614 is rounded, so that it is possible to prevent foreign matter from being caught by the convex portion 614 and damaging the light exit surface 60U. Furthermore, the same advantages as those of the first embodiment can be obtained.
- the shape of the concave portion and the convex portion constituting the light output surface may be a groove shape.
- the example is demonstrated using drawing.
- FIG. 14 is a perspective view schematically showing a surface light source device according to a seventh embodiment of the present invention.
- the surface light source device 70 according to the seventh embodiment is different from the multilayer body 710 constituting the light exit surface structure layer 700 except that the shape of the light exit surface 70U that is the surface of the uneven structure layer 711 is different.
- the configuration is the same as that of the first embodiment.
- Each of the plurality of recesses 713 formed on the surface of the concavo-convex structure layer 711 has a linear, groove-like shape, and each has two flat slopes. Therefore, the cross section obtained by cutting the recess 713 along a plane perpendicular to the extending direction of the groove has a triangular shape having two hypotenuses.
- the plurality of recesses 713 are arranged in parallel on the light exit surface 70U. Accordingly, a gap is provided between the adjacent recesses 713. This gap constitutes a flat portion 714 in the light exit surface 70U. That is, in the in-plane direction parallel to the light exit surface 70U, at least in the in-plane direction perpendicular to the extending direction of the groove, the recesses 713 and the flat portions 714 exist alternately.
- the height difference H of the unevenness adjacent to the light exit surface 70U is uneven so that the standard deviation ⁇ falls within a predetermined range.
- the flat part 714 hits the tip of the convex part. Therefore, in the surface light source device 70, when the concave portion 713 and the flat portion 714 that are adjacent to each other at least in the in-plane direction perpendicular to the extending direction of the groove are compared, the surface of the bottom 713P of the concave portion 713 and the flat portion 714 The distances in the thickness direction of the light source device 70 (that is, the height difference between adjacent irregularities) H are uneven so that the standard deviation ⁇ falls within a predetermined range. In the present embodiment, as shown in FIG.
- the height of the flat portion 714 is uniform, but the height difference H between adjacent concavities and convexities is due to uneven height of the bottom 713 ⁇ / b> P of the recess 713.
- An example of irregularity is shown.
- the heights of the bottoms 713P of the recesses 713 are uniform, but the heights of the flat portions 714 may be uneven, so that the height difference H between adjacent unevennesses may be uneven.
- the height difference H between adjacent irregularities may be uneven due to the unevenness of both the height of the flat portion 714 and the height of the flat portion 714.
- the light extraction efficiency can be increased and the rainbow unevenness can be suppressed as in the first embodiment. Furthermore, the same advantages as those of the first embodiment can be obtained.
- the groove-like shape of the recess 713 is not limited to the triangular cross section exemplified above, and can take various shapes.
- the cross-sectional shape of the groove may be another polygonal shape such as a pentagon or a heptagon, or a shape other than a polygon such as a part of a circle.
- the shape of the cross section of the groove may be changed to a shape with rounded vertices or a flat chamfered shape.
- the flat portion is in two or more in-plane directions.
- the present invention is not limited to this, and the gap may be provided only in a part of two or more in-plane directions. Good.
- the example is demonstrated using drawing.
- FIGS. 15 and 16 are views for explaining the surface light source device according to the eighth embodiment of the present invention
- FIG. 15 is a top view schematically showing the surface light source device as viewed from the thickness direction.
- FIG. 16 is a cross-sectional view showing a cross section of the surface light source device shown in FIG. 15 cut along a plane that passes through the line 15a in FIG. 15 and is perpendicular to the light exit surface 80U.
- the surface light source device 80 according to the eighth embodiment is different in the shape of the light exit surface 80 ⁇ / b> U that is the surface of the concavo-convex structure layer 811 in the multilayer body 810 constituting the light exit surface structure layer 800. Others have the same configuration as the first embodiment.
- Each of the plurality of recesses 813 formed on the surface of the concavo-convex structure layer 811 has the same quadrangular pyramid shape as the recesses 113 in the first embodiment, but the gap between the recesses 813 is perpendicular to the line 15a in FIG. As a result, a flat portion 814 extending in the in-plane direction X parallel to the line 15a is formed.
- the height difference H of the adjacent unevenness is uneven so that the standard deviation ⁇ falls within a predetermined range.
- the flat part 814 hits the tip of the convex part.
- a boundary portion 815 between the concave portions 813 adjacent in the in-plane direction X also hits the tip of the convex portion.
- the surface light source device 80 when the concave portion 813 and the flat portion 814 adjacent in the in-plane direction Y are compared, or when the concave portion 813 and the boundary portion 815 adjacent in the in-plane direction X are compared,
- the distance between the bottom 813P of the concave portion 813 and the flat portion 814 in the thickness direction of the surface light source device 80 that is, the height difference between adjacent concave and convex portions
- the surface between the bottom 813P of the concave portion 813 and the boundary portion 815 The distances in the thickness direction of the light source device 80 (that is, the difference in height between adjacent irregularities) H are uneven so that the standard deviation ⁇ falls within a predetermined range.
- the flat portion 814 and the boundary portion 815 have the same height, but the unevenness of the adjacent concave and convex portions due to the unevenness of the bottom 813 ⁇ / b> P of the concave portion 813.
- An example in which the height difference H is uneven is shown.
- the height of the bottom 813P of the recess 813 is uniform, the height difference H between adjacent irregularities may be uneven due to the unevenness of the flat portion 814 and the boundary portion 815. Since the height of the bottom 813P of 813, the height of the flat portion 814, and the height of the boundary portion 815 are all uneven, the height difference H between adjacent concavities and convexities may be uneven.
- the light extraction efficiency is increased as in the first embodiment, and , Rainbow unevenness can be suppressed. Furthermore, the same advantages as those of the first embodiment can be obtained. Further, in this embodiment, as compared with the case of the first embodiment, the light emission surface is relatively scratched along a certain direction (for example, an in-plane direction X parallel to the extending direction of the flat portion 814). In some cases, the scratch resistance can be lowered, but the light extraction efficiency can be improved, so that it may be preferably used.
- the height of the boundary portion 815 between the adjacent concave portions 813 and the height of the flat portion 814 are the same as the shape of the concave portion 813, but the height of the boundary portion 815 is the height of the flat portion 814. May be different.
- the example in which the shape of the recess 813 is only a quadrangular pyramid has been taken here, other shapes may be used.
- it can also be set as the structure in which the recessed part 816 of the ridged roof shape was located in a line.
- the uneven structure layer 821 shown in FIG. 17 is a modification of the uneven structure layer 811 according to the eighth embodiment, and has the same configuration as the uneven structure layer 811 according to the eighth embodiment, except that the shape of the recess is different.
- the single-sided light-emitting surface light source device in which only one surface of the surface light source device is a light emitting surface has been described as an example.
- the surface light source device of the present invention is a surface light source device.
- a double-sided light-emitting surface light source device in which both surfaces are light-emitting surfaces may be used.
- the example is demonstrated using drawing.
- FIG. 18 is a perspective view schematically showing a surface light source device according to the ninth embodiment of the present invention.
- the surface light source device 90 according to the ninth embodiment includes a second electrode layer 943 that is a transparent electrode instead of the second electrode layer 143 that the organic EL element 940 is a reflective electrode, And it has the same structure as 1st embodiment except the point where the light emission surface structure layer 100 is provided instead of the sealing substrate 151.
- FIG. It should be noted that an arbitrary substance such as a filler or an adhesive may exist between the light emitting surface structure layer 100 on the lower side in the drawing and the second electrode 943, and a void exists. Also good. As long as there is no inconvenience such as greatly impairing the durability of the light emitting layer 142, air or other gas may be present in the space, or the space may be evacuated.
- the second electrode layer 943 is a transparent electrode, light from the light-emitting layer 142 passes through the first electrode layer 141 and the second electrode layer 943, and is emitted from both the upper side and the lower side in the figure. Light exits from the surface 10U. Therefore, the lower surface 145 of the organic EL element 940 in the figure also functions as a light emitting surface. Even in the case where light is emitted from both the front surface and the back surface, light extraction efficiency can be increased and rainbow unevenness can be suppressed as in the first embodiment.
- the surface light source device 90 of the present embodiment normally, light incident on one light exit surface 10U is transmitted through the surface light source device 90 and emitted from the other light exit surface 10U. Accordingly, the opposite side can be seen with the naked eye through the surface light source device 90, and a see-through surface light source device can be realized, so that the design can be diversified. Furthermore, the same advantages as those of the first embodiment can be obtained.
- the light emitting surface structure layer is provided so as to be in direct contact with the light emitting surface, but the light emitting surface structure layer may be provided on the light emitting surface via another arbitrary layer.
- the optional layer include a gas barrier layer that protects the organic EL element from the outside air and moisture, and an ultraviolet cut layer that blocks ultraviolet rays.
- the light emitting surface structure layer is composed of a concavo-convex structure layer, a base film layer, an adhesive layer, and a support substrate, but the light emitting surface structure layer is a layer having fewer layers than these. It may be configured from the above, or conversely, an arbitrary layer may be further included in addition to these layers.
- a coating layer may be further provided on the surface of the concavo-convex structure layer, and this may define the concavo-convex structure on the light exit surface.
- the concave portion and the convex portion are not limited to those exemplified in the above-described embodiment.
- the concave portion and the convex portion may have a pyramid shape such as a triangular pyramid, a pentagonal pyramid, a hexagonal pyramid, and a quadrangular pyramid whose bottom is not square.
- concave portions and the convex portions distributed over the entire surface of the light exit surface those having only the same shape are distributed.
- Convex parts may be mixed.
- pyramid-shaped recesses with different sizes are mixed, pyramid-shaped recesses and conical-shaped recesses are mixed, or a combination of multiple pyramids and a simple pyramid shape May be mixed.
- the concave portion 113 according to the first embodiment and the convex portion 414 according to the fourth embodiment may be combined, and both the concave portion and the convex portion may be mixed on the same light exit surface.
- the width of the concave portion and the convex portion, and the interval between the adjacent concave portions and the interval between the convex portions are constant, but the width of the concave portion and the convex portion is narrow.
- a thing and a wide thing may be mixed, and the space
- an apparatus having the same effect as the reflective electrode is configured. be able to.
- both the light emitting surfaces 144 and 145 of the organic EL element 940 are provided with the same light emitting surface structure layer 100
- the light emitting surface structure layers that are different in the light emitting surface 144 and the light emitting surface 145 are shown. May be provided in combination.
- the double-sided emission type surface light source device as long as at least one light emitting surface is provided with the light emitting surface structure layer, the other light emitting surface may not be provided with the light emitting surface structure layer.
- the surface light source device of this invention can be used for uses, such as a lighting fixture and a backlight apparatus, for example.
- the luminaire includes the surface light source device of the present invention as a light source, and further includes optional components such as a member for holding the light source and a circuit for supplying power as necessary.
- the backlight device has the surface light source device of the present invention as a light source, and further, as necessary, a housing, a circuit for supplying power, a diffusion plate for making light emitted more uniform, and a diffusion sheet And optional components such as a prism sheet.
- Applications of the backlight device include a display device such as a liquid crystal display device that displays an image by controlling pixels, and a backlight of a display device that displays a fixed image such as a signboard.
- Example 1 Production of multilayer A
- FIG. 19 schematically shows a cross section of the concavo-convex structure layer b produced in Example 1 taken along a plane perpendicular to the principal surface.
- the concavo-convex structure on the concavo-convex structure layer b was composed of a plurality of quadrangular pyramid-shaped concave portions 13 and a flat portion 14 positioned around the concave portions 13.
- the apex angle ⁇ of the recess 13 is 60 °
- the height of the apex 16 of the quadrangular pyramid of the recess 13 is constant. It was a structure in which the height of the flat portion 14 was randomly irregular.
- the measurement was performed over a length of 100 ⁇ m per one measurement location. Further, the measurement direction was fixed, and the same measurement was performed at a total of 15 measurement points.
- the average value is 24.3 ⁇ m and the standard deviation ⁇ is 0.12 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 11.5 micrometers
- the depth of the recessed part 13 was 10 micrometers
- the width dimension of the flat part 14 was 4 micrometers.
- the multilayer body A was affixed to the glass substrate via an adhesive (acrylic resin, refractive index 1.49, CS9621 manufactured by Nitto Denko Corporation) to obtain a multilayer body B with a glass substrate. Further, a light source provided with a light shielding plate with a slit having a width of 5 mm immediately before the fluorescent lamp was prepared as a light source.
- FIG. 20 schematically shows how rainbow unevenness is measured.
- the multilayer body B with a glass substrate was installed in a dark room so that the uneven surface was vertically upward and horizontal.
- the light source 1 was installed at a location 200 mm away from the multilayer B with glass substrate in the horizontal direction and 200 mm in the vertical direction. Further, from the above-mentioned multilayered body B with a glass substrate, a place where the distance from the light source was 200 mm in the horizontal direction and the vertical direction was increased by 200 mm was taken as an observation point, and the camera 2 was installed at this observation point.
- Parallel light was irradiated from the light source 1 to the multilayer body B with a glass substrate, and the reflected light reflected by the uneven surface was photographed by the camera 2 at the observation point.
- the photographed image an image in which the light source was reflected and a plurality of rainbow spots were observed as band-like images extending substantially parallel to each other.
- the luminance profile was measured using image analysis software (analySIS: manufactured by soft imaging system).
- the luminance peak value (P1) in the image in which the light source is reflected and the luminance peak value (P2) of the adjacent rainbow unevenness are extracted, and the luminance attenuation is expressed as a percentage based on the following equation.
- the rainbow unevenness image may be seen on both sides centered on the image where the light source is reflected, but the peak value on the higher luminance peak value is adopted.
- Luminance decay rate (%) P2 / P1 ⁇ 100 The larger the value of the luminance attenuation rate, the larger the rainbow unevenness, and the smaller the value, the smaller the rainbow unevenness. When it is 50% or more, the rainbow unevenness can be clearly confirmed visually.
- the luminance attenuation rate was 37.9%.
- a transparent electrode layer 100 nm On one main surface of a glass substrate having a thickness of 0.7 mm, a transparent electrode layer 100 nm, a hole transport layer 10 nm, a yellow light emitting layer 20 nm, a blue light emitting layer 15 nm, an electron transport layer 15 nm, an electron injection layer 1 nm, and a reflective electrode layer 100 nm.
- the hole transport layer to the electron transport layer were all made of an organic material. Note that the yellow light-emitting layer and the blue light-emitting layer have different emission spectra.
- each layer from a transparent electrode layer to a reflective electrode layer is as follows, respectively.
- the transparent electrode layer was formed by a reactive sputtering method using an ITO target, and the surface resistance was 10 ⁇ / ⁇ or less.
- the formation from the hole injection layer to the reflective electrode layer is carried out by placing a glass substrate on which a transparent electrode layer has already been formed in a vacuum evaporation apparatus, and successively using the resistance heating method for the materials from the hole transport layer to the reflective electrode layer. This was done by vapor deposition.
- the system internal pressure was 5 ⁇ 10 ⁇ 3 Pa and the evaporation rate was 0.1 to 0.2 nm / s.
- wiring for energization was attached to the electrode layer, and the hole transport layer to the reflective electrode layer were sealed with a sealing member to produce an organic EL element.
- the obtained organic EL element had a rectangular light emitting surface capable of emitting white light from the glass substrate side.
- Example 1 The multilayer body A was manufactured in the same manner as in Example 1 except that the shape of the metal mold was changed in the manufacture of the multilayer body A of (1-1).
- the concavo-convex structure on the concavo-convex structure layer b was almost the same as in Example 1, but the average of the height difference H of adjacent concavo-convex on the surface of the concavo-convex structure layer b (thickness 15 ⁇ m). The value was 24.3 ⁇ m and the standard deviation ⁇ was 0.03 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 11.5 micrometers
- the depth of the recessed part 13 was 10 micrometers
- the width dimension of the flat part 14 was 4 micrometers.
- Example 2 In manufacturing the multilayer body A of (1-1), the multilayer body A was manufactured in the same manner as in Example 1 except that the shape of the metal mold was changed, and a surface light source device was obtained.
- FIG. 21 schematically shows a cross section of the concavo-convex structure layer b manufactured in Example 2 taken along a plane perpendicular to the main surface. As shown in FIG. 21, in the obtained multilayer A, the concavo-convex structure on the concavo-convex structure layer b was composed of a plurality of quadrangular pyramid-shaped recesses 13.
- the apex angle ⁇ of the concave portion 13 is 90 °
- the height of the apex 16 of the quadrangular pyramid of the concave portion 13 and the convex portion are randomly arranged.
- the average value of the height difference H of adjacent unevenness on the surface of the uneven structure layer b was 25.6 ⁇ m, and the standard deviation ⁇ was 0.26 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 24 micrometers, and the depth of the recessed part 13 was 20 micrometers.
- the luminance attenuation rate was 34.1%.
- the surface light source device was observed in the same manner as in the above (2-3), it was observed that it was in a good state with less rainbow unevenness than Example 1.
- Example 3 In manufacturing the multilayer body A of (1-1), the multilayer body A was manufactured in the same manner as in Example 1 except that the shape of the metal mold was changed, and a surface light source device was obtained.
- FIG. 22 schematically shows a cross section of the concavo-convex structure layer b produced in Example 3 taken along a plane perpendicular to the main surface.
- the concavo-convex structure on the concavo-convex structure layer b was composed of a plurality of quadrangular pyramid-shaped recesses 13 and a flat portion 14 positioned around the recesses 13. .
- the apex angle ⁇ of the concave portion 13 is 60 °, and the heights of the quadrangular pyramids of the concave portion 13 are randomly irregular,
- the flat portion 14 had a uniform height.
- the average value of the height difference H of adjacent unevenness on the surface of the uneven structure layer b was 12.2 ⁇ m, and the standard deviation ⁇ was 0.43 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 11.5 micrometers
- the depth of the recessed part 13 was 10 micrometers
- the width dimension of the flat part 14 was 4 micrometers.
- Example 4 In manufacturing the multilayer body A of (1-1), the multilayer body A was manufactured in the same manner as in Example 1 except that the shape of the metal mold was changed, and a surface light source device was obtained.
- the concavo-convex structure on the concavo-convex structure layer b is almost the same as in Example 1, and the average value of the height difference H of adjacent concavo-convex on the surface of the concavo-convex structure layer b (thickness 35 ⁇ m) is The standard deviation ⁇ was 12.2 ⁇ m and 0.06 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 34 micrometers
- the depth of the recessed part 13 was 30 micrometers
- the width dimension of the flat part 14 was 2 micrometers.
- Composition (1) was produced. The content ratio of the particles was 10% by weight in the total amount of the resin composition (1).
- the resin composition (1) was applied on a base film (Zeonor film manufactured by Nippon Zeon Co., Ltd.). Thereafter, a metal mold having a predetermined shape is pressed onto the coating film of the resin composition (1), and ultraviolet rays are irradiated from the base film side with an integrated light amount of 1000 mJ / cm 2 , so that a concavo-convex structure layer is formed on the base film. b was formed. As a result, a multilayer C was obtained as a rectangular film having a layer structure of base film a-uneven structure layer b.
- the concavo-convex structure on the concavo-convex structure layer b is almost the same as in Example 1, and the average value of the height difference H of the adjacent concavo-convex on the surface of the concavo-convex structure layer b (thickness 15 ⁇ m) is The standard deviation ⁇ was 24.3 ⁇ m and 0.12 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 11.5 micrometers
- the depth of the recessed part 13 was 10 micrometers
- the width dimension of the flat part 14 was 4 micrometers.
- a surface light source device was manufactured in the same manner as the above (2-2) to obtain a surface light source device including a multilayer structure of C-adhesive layer-glass substrate-organic EL element.
- the luminance attenuation rate was 36.4%.
- the surface light source device was observed in the same manner as in (2-3), it was observed that there was little rainbow unevenness and a good state.
- the multilayer body A was manufactured in the same manner as in Example 2 except that the shape of the metal mold was changed in the manufacture of the multilayer body A of (1-1).
- the concavo-convex structure on the concavo-convex structure layer b was substantially the same as in Example 2, but the average of the height difference H of adjacent concavo-convex on the surface of the concavo-convex structure layer b (thickness 25 ⁇ m). The value was 25.6 ⁇ m and the standard deviation ⁇ was 0.02 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 24 micrometers, and the depth of the recessed part 13 was 20 micrometers.
- Example 3 In the production of the multilayer body B of (1-4), a multilayer body C was produced in the same manner as in Example 5 except that the shape of the metal mold was changed. In the obtained multilayer C, the concavo-convex structure on the concavo-convex structure layer b was almost the same as in Example 5, but the average of the height difference H of adjacent concavo-convex on the surface of the concavo-convex structure layer b (thickness 35 ⁇ m). The value was 24.3 ⁇ m and the standard deviation ⁇ was 0.01 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 34 micrometers
- the depth of the recessed part 13 was 30 micrometers
- the width dimension of the flat part 14 was 2 micrometers.
- Example 6 In producing the multilayer body B of (1-4), a multilayer body C was produced in the same manner as in Comparative Example 3 except that the shape of the metal mold was changed.
- the concavo-convex structure on the concavo-convex structure layer b was substantially the same as in Comparative Example 3, but the average of the height difference H of adjacent concavo-convex on the surface of the concavo-convex structure layer b (thickness 15 ⁇ m). The value was 24.3 ⁇ m and the standard deviation ⁇ was 0.54 ⁇ m.
- the dimension of the base of the quadrangular pyramid in the recessed part 13 was 11.5 micrometers
- the depth of the recessed part 13 was 10 micrometers
- the width dimension of the flat part 14 was 4 micrometers.
- the luminance attenuation rate was 30.1%.
- the surface light source device was manufactured in the same manner as in (2-2) and observed in the same manner as in (2-3), the rainbow unevenness was good. However, it was observed that a plurality of scratches that can be visually confirmed occurred.
- the luminance attenuation rate is low in the examples, and rainbow unevenness is hardly observed even in the visual evaluation. From this, it was confirmed that the rainbow unevenness can be suppressed when the height difference H between the adjacent irregularities is uneven so that the standard deviation ⁇ is 0.05 ⁇ m or more. Further, since scratches were observed in Example 6 having a large standard deviation ⁇ , it was also confirmed that a preferable upper limit value exists in the range of the standard deviation ⁇ in order to perform stable production.
- the surface light source device of the present invention is suitable for use in, for example, lighting fixtures and backlight devices.
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Abstract
Description
すなわち、本発明によれば以下の〔1〕~〔5〕が提供される。
前記出光面構造層は、前記有機エレクトロルミネッセンス素子とは反対側の表面に、相対的に窪んだ凹部と相対的に突出した凸部とを、前記表面に対して平行な面内方向において交互に有し、
隣り合う前記凹部の底と前記凸部の先端との、前記面光源装置の厚み方向における距離が、標準偏差0.05μm以上の範囲で不揃いになっている、面光源装置。
〔2〕 前記出光面構造層における前記有機エレクトロルミネッセンス素子とは反対側の表面が、前記面光源装置の最表面に露出している、〔1〕記載の面光源装置。
〔3〕 前記凹部又は凸部の形状が角錐形状又は角錐台形状である、〔1〕又は〔2〕に記載の面光源装置。
〔4〕 前記凸部の先端が、前記発光面に対して平行な平坦面となっている、〔1〕~〔3〕のいずれか一項に記載の面光源装置。
〔5〕 前記凹部の底及び前記凸部の先端の一方又は両方が丸みを帯びている、〔1〕~〔3〕のいずれか一項に記載の面光源装置。
図1及び図2はいずれも本発明の第一実施形態に係る面光源装置を説明する図であって、図1は面光源装置を模式的に示す斜視図であり、図2は図1に示す面光源装置を線1a-1bを通り出光面に対して垂直な面で切断した断面を模式的に示す断面図である。
例えば有機EL素子140として例示するように、有機EL素子は、通常、2層以上の電極層と、これらの電極層間に設けられ、電極から電圧を印加されることにより発光する発光層と、を備える。
透明電極の材料としては、ITO(酸化インジウムスズ)等を挙げることができる。
正孔注入層の材料としては、スターバースト系芳香族ジアミン化合物等を挙げることができる。
正孔輸送層の材料としては、トリフェニルジアミン誘導体等を挙げることができる。
黄色発光層のホスト材料としては、トリフェニルジアミン誘導体等を挙げることができ、黄色発光層のドーパント材料としては、テトラセン誘導体等を挙げることができる。
緑色発光層の材料としては、ピラゾリン誘導体等を挙げることができる。
青色発光層のホスト材料としては、アントラセン誘導体等を挙げることができ、青色発光層のドーパント材料としては、ペリレン誘導体等を挙げることができる。
赤色発光層の材料としては、ユーロピウム錯体等を挙げることができる。
電子輸送層の材料としては、アルミニウムキノリン錯体(Alq)等を挙げることができる。
反射電極の材料としては、フッ化リチウムおよびアルミニウムをそれぞれ用い、これらを順次真空成膜により積層させたもの等を挙げることができる。
出光面構造層100は、有機EL素子140の発光面144に設けられた層である。出光面10Uは、出光面構造層100における有機EL素子140とは反対側の表面である。この出光面10Uは面光源装置10の最表面に露出した面であり、面光源装置10としての出光面、即ち、面光源装置10から装置外部に光が出光する際の出光面である。
さらに、構成要素が「平行」又は「垂直」であるとは、本発明の効果を損ねない範囲、例えば±5°の範囲内で誤差を含んでいてもよい。
凹凸構造層111は、面光源装置10の上面(即ち面光源装置10の出光面側の最外層)に位置する層である。この凹凸構造層111は、複数の凹部113と、凹部113の周囲に位置する平坦部114とを含む凹凸構造を有する。ここで、前記の凹部113は平坦部114に比べて相対的に窪んでいる部分であるため本発明に係る凹部に当たり、平坦部114は凹部113に比べて相対的に突出しているため本発明に係る凸部に当たる。そして、当該凹凸構造により、出光面10Uが規定される。
以下、出光面10Uの凹凸構造について、図面を参照して詳細に説明する。
図3は、面光源装置10の出光面10Uの一部を、面光源装置10の厚み方向から見た様子を拡大して模式的に示す部分平面図である。また、図4は、凹凸構造層111を、図3の線3aを通り出光面10Uに対して垂直な面で切断した断面を模式的に示す部分断面図である。なお、以下の説明において、特に断らない限り、「厚み方向」とは面光源装置の厚み方向を表す。
本実施形態では、図4に示すように、斜面11A~11Dが平坦部114となす角11L及び11Mは60°に設定されているものとする。これにより、凹部113を構成する正四角錐の頂角、即ち頂点11Pにおいて相対向する斜面がなす角(斜面11B及び11Dがなす角については、図4に示す角11N)も60°となっている。
ここで、凹部113の底とは、凹部113それぞれにおいて最も窪んだ部分を指し、面光源装置10の厚み方向における発光面144までの距離が最も短くなる部分を指す。本実施形態では、各凹部113の頂点11Pが凹部113の底に当たる。
また、凸部の先端とは、凸部それぞれにおいて最も突出した部分を指し、面光源装置10の厚み方向における発光面144までの距離が最も長くなる部分を指す。本実施形態では平坦部114が発光面144に対して平行な平坦面となっているので、平坦部114自体が凸部の先端に当たる。
外部から出光面10Uに向けて光が照射された場合、出光面10Uで光が反射したり、面光源装置10の内部に進入した光が内部の層界面で反射したりして、反射光が生じる。前記の反射光は、出光面10Uで反射する時、および、面光源装置10の内部から外部へ出る時などに、出光面10Uにおいて回折及び屈折などを生じることがある。従来は、前記の回折及び屈折などを生じた光が干渉することにより、虹ムラを生じていたと考えられる。これに対し、本実施形態の面光源装置10では、出光面10Uにおいて隣り合う凹凸の高低差Hを不揃いにしたことにより、干渉の強さを弱めることができるようになるので、虹ムラを解消できると考えられる。
また、凹凸構造層111の厚さTに対して相対的に、隣り合う凹凸の高低差Hの好ましい範囲を定めることができる。例えば、凹凸構造層111の材料として、凹凸構造層111の耐久性の維持に有利な硬質の材料を用いた場合、凹凸構造層111の厚さTを薄くしたほうが、複層体110の可撓性が高まり、面光源装置10の製造工程における複層体110の取り扱いが容易となる。具体的には、図4に示す隣り合う凹凸の高低差Hと凹凸構造層111の厚さTとの差T-Hが、0~30μmとなるようにすることが好ましい。
出光面構造層100は、複数の層からなるものとしうるが、単一の層からなってもよい。所望の特性を備えた出光面構造層100を容易に得る観点からは、複数の層からなることが好ましい。本実施形態では、図1に示すように、出光面構造層100は、凹凸構造層111と基材フィルム層112とを組み合わせた複層体110を含むようになっているものとする。これにより、性能の高い出光面構造層100を容易に得ることができる。
粒子の粒径は、好ましくは0.1μm以上であり、好ましくは10μm以下、より好ましくは5μm以下である。ここで粒径とは、体積基準の粒子量を、粒子径を横軸にして積算した積算分布における50%粒子径のことである。粒径が大きいほど、所望の効果を得るために必要な粒子の含有割合は多くなり、粒径が小さいほど、含有量は少なくてすむ。したがって、粒径が小さいほど、観察角度による色味の変化の低減、及び光取り出し効率の向上等の所望の効果を、少ない粒子で得ることができる。なお、粒径は、粒子の形状が球状以外である場合には、その同等体積の球の直径を粒径とする。
また、基材フィルム層112の厚さは、20μm~300μmであることが好ましい。
本実施形態の面光源装置10は、有機EL素子140と複層体110との間に、支持基板131を備える。支持基板131を備えることにより、面光源装置10に、たわみを抑制する剛性を与えることができる。また、支持基板131として、有機EL素子140を封止する性能に優れて、且つ、製造工程において有機EL素子140を構成する層をその上に順次形成することを容易に行い得る基板を備えることにより、面光源装置10の耐久性を向上させ、且つ製造を容易にすることができる。
支持基板131の屈折率は、特に制限されないが、1.4~2.0とすることが好ましい。
支持基板131の厚さは、特に限定されないが、0.1mm~5mmであることが好ましい。
本実施形態の面光源装置10は、複層体110と支持基板131との間に接着層121を備える。接着層121は、複層体110の基材フィルム層112と支持基板131との間に介在して、これらの2層を接着する層である。
接着層121の材料である接着剤は、狭義の接着剤(23℃における剪断貯蔵弾性率が1~500MPaであり、常温で粘着性を示さない、いわゆるホットメルト型の接着剤)のみならず、23℃における剪断貯蔵弾性率が1MPa未満である粘着剤をも包含する。具体的には、支持基板131あるいは基材フィルム層112に近い屈折率を有し、且つ透明であるものを適宜用いることができる。より具体的には、アクリル系接着剤あるいは粘着剤が挙げられる。接着層の厚さは、5μm~100μmであることが好ましい。
面光源装置10の製造方法は、特に限定されないが、例えば、支持基板131の一方の面に有機EL素子140を構成する各層を積層し、その後又はその前に、支持基板131の他方の面に凹凸構造層111及び基材フィルム層112を有する複層体110を、接着層121を介して貼付することにより製造することができる。
(方法1)基材フィルム層112を構成する樹脂組成物Aの層及び凹凸構造層111を構成する樹脂組成物Bの層(凹凸構造はまだ形成されていない)を有する未加工複層体を用意し、かかる未加工複層体の樹脂組成物B側の面上に、凹凸構造を形成する方法;及び
(方法2)基材フィルム層112の上に、液体状態の樹脂組成物Bを塗布し、塗布された樹脂組成物Bの層に型を当て、その状態で樹脂組成物Bを硬化させ、凹凸構造層111を形成する方法
などを挙げることができる。
より具体的には、長尺の未加工複層体を押出成形により連続的に形成し、所望の表面形状を有する転写ロールとニップロールとで未加工複層体を加圧し、それにより、連続的な製造を効率的に行うことができる。転写ロールとニップロールとによる挟み圧力は、好ましくは数MPa~数十MPaである。また転写時の温度は、樹脂組成物Bのガラス転移温度をTgとすると、好ましくはTg以上(Tg+100℃)以下である。未加工複層体と転写ロールとの接触時間はフィルムの送り速度、すなわちロール回転速度によって調整でき、好ましくは5秒以上600秒以下である。
本実施形態の面光源装置10は上述したように構成されているので、有機EL素子140の発光面144から発せられた光は、出光面構造層100を透過して、出光面10Uから取り出される。この際、出光面10Uに、凹部113及び平坦部114を有する凹凸構造を有するので、凹凸構造を有さない場合と比較して、出光面10Uからの光の取出効率を高めることができる。
本発明の面光源装置において、出光面を構成する凹部及び凸部の形状は、第一実施形態において例示した角錐形状に限られず、角錐台形状であってもよい。ここで、角錐台形状とは、角錐の頂部に平坦な部分を設け、平らに面取りした形状をいう。以下、その例を、図面を用いて説明する。
図5に示す通り、第二実施形態にかかる面光源装置20は、出光面構造層200を構成する複層体210において、凹凸構造層211の表面である出光面20Uに形成された凹部213の形状が異なる他は、第一実施形態と同様の構成を有している。
また、凹部213の形状が角錐台形状となっている場合、底面部21Pを除く斜面212A及び213Bの角度を、斜面の角度とする。凹部213の斜面の角度をこのような角度とすることにより、光取出効率を高めることができる。ただし、斜面は、必ずしも全てが同じ角度である必要は無く、上記範囲内で、異なる角度を有する斜面が共存していてもよい。
本発明の面光源装置において、出光面を構成する凹部の底は、丸みを帯びていてもよい。以下、その例を、図面を用いて説明する。
図7に示す通り、第三実施形態にかかる面光源装置30は、出光面構造層300を構成する複層体310において、凹凸構造層311の表面である出光面30Uに形成された凹部313の形状が異なる他は、第一実施形態と同様の構成を有している。
また、凹部313の底が丸みを帯びた形状である場合、当該丸みを帯びた部分を除く斜面313A及び313Bの角度を、斜面の角度とする。斜面の角度をこのような角度とすることにより、光取出効率を高めることができる。ただし、斜面は、必ずしも全てが同じ角度である必要は無く、上記範囲内で、異なる角度を有する斜面が共存していてもよい。
第一~第三実施形態では出光面に凹部を設けることによって出光面に凹凸構造をもたせたが、出光面に凸部を設けることによって凹凸構造をもたせてもよい。以下、その例を、図面を用いて説明する。
図9に示す通り、第四実施形態にかかる面光源装置40は、出光面構造層400を構成する複層体410において、凹凸構造層411の表面である出光面40Uに、凹部113の代わりに凸部414が設けられていることの他は、第一実施形態と同様の構成を有している。
本発明の面光源装置において、出光面を構成する凹部及び凸部の形状は、上述した角錐及び角錐台以外の形状であってもよく、例えば球の一部の形状であってもよい。
また、出光面において、凹部及び凸部は、第一~第四実施形態において例示したように直交する2つの面内方向に沿って配列する以外にも、任意の態様で配列することができる。例えば、複数の凹部を、出光面上の1方向のみ、または、3方向以上の面内方向に沿って配列してもよく、ランダムに配置してもよい。
以下、その例を、図面を用いて説明する。
図11及び図12に示す通り、第五実施形態に係る面光源装置50は、出光面構造層500を構成する複層体510において、凹凸構造層511の表面である出光面50Uの形状が異なる他は、第一実施形態と同様の構成を有している。
本発明の面光源装置において、出光面を構成する凸部の先端は、丸みを帯びていてもよい。以下、その例を、図面を用いて説明する。
図13に示す通り、第六実施形態に係る面光源装置60は、出光面構造層600を構成する複層体610において、凹凸構造層611の表面である出光面60Uに、半球状の凹部513の代わりに半球状の凸部614が設けられていることの他は、第五実施形態と同様の構成を有している。
本発明の面光源装置において、出光面を構成する凹部及び凸部の形状は、溝状の形状であってもよい。以下、その例を、図面を用いて説明する。
複数の凹部713は、出光面70U上に平行に配列される。したがって、隣り合う凹部713の間には隙間が設けられる。この隙間が、出光面70Uにおける平坦部714を構成している。すなわち、出光面70Uに対して平行な面内方向のうち、少なくとも溝の延長方向に垂直な面内方向においては、凹部713と平坦部714とが交互に存在するようになっている。
上に述べた第一~第七実施形態のように、出光面の2方向以上の面内方向に沿って凹部又は凸部を配列した場合において、平坦部は、かかる2方向以上の面内方向のいずれにおいても隣り合う凹部又は凸部の間に隙間を設けることにより構成したが、本発明はこれに限られず、2方向以上の面内方向のうち一部の方向のみにおいて隙間を設けてもよい。以下、その例を、図面を用いて説明する。
また、ここでは凹部813の形状が四角錐のみである例を取り上げたが、それ以外の形状であってもよい。例えば、図17に示すように、寄せ棟屋根状の凹部816が複数並んだ構成とすることもできる。なお、図17に示す凹凸構造層821は第八実施形態に係る凹凸構造層811の変形例であり、凹部の形状が異なること以外は、第八実施形態に係る凹凸構造層811と同様の構成を有する。
上述した第一~第八実施形態では、面光源装置の片面だけが出光面となる片面発光型の面光源装置を例に挙げて説明したが、本発明の面光源装置は、面光源装置の両面が発光面となる両面発光型の面光源装置であってもよい。以下、その例を、図面を用いて説明する。
図18に示す通り、第九実施形態に係る面光源装置90は、有機EL素子940が反射電極である第二の電極層143の代わりに透明電極である第二の電極層943を備える点、並びに、封止基板151の代わりに出光面構造層100が設けられている点の他は、第一実施形態と同様の構成を有している。なお、図中下側の出光面構造層100と、第二の電極943との間には、充填材や接着剤等の任意の物質が存在していてもよいし、空隙が存在していてもよい。空隙には、発光層142の耐久性を大きく損なう等の不都合がない限りは空気やその他の気体が存在してもよいし、空隙内を真空としてもよい。
以上、本発明の実施形態について説明したが、本発明は上述した実施形態に限定されるものではなく、更に変更して実施してもよい。
例えば、上述した実施形態では発光面に直接に接するように出光面構造層を設けたが、出光面構造層は他の任意の層を介して発光面に設けられていてもよい。任意の層としては、例えば、有機EL素子を外気及び湿気から保護するガスバリア層、紫外線を遮断する紫外線カット層などが挙げられる。
本発明の面光源装置は、例えば、照明器具及びバックライト装置等の用途に用いることができる。
照明器具は、本発明の面光源装置を光源として有し、さらに、必要に応じて、光源を保持する部材、電力を供給する回路等の任意の構成要素を備える。
また、バックライト装置は、本発明の面光源装置を光源として有し、さらに、必要に応じて、筐体、電力を供給する回路、出光する光をさらに均一にするための拡散板、拡散シート、プリズムシート等の任意の構成要素を含む。バックライト装置の用途は、液晶表示装置等、画素を制御して画像を表示させる表示装置、並びに看板等の固定された画像を表示させる表示装置のバックライト等が挙げられる。
(1-1:複層体Aの製造)
UV(紫外線)硬化型樹脂(ウレタンアクリレート樹脂、屈折率n=1.54)を、基材フィルム(日本ゼオン社製 ゼオノアフィルム、厚み100μm、屈折率n=1.53)上に塗布した。その後、樹脂の塗膜上に所定の形状の金属型を圧接し、基材フィルム側から紫外線を1000mJ/cm2の積算光量で照射して、基材フィルム上に凹凸構造層b(厚み15μm)を形成した。これにより、基材フィルムa-凹凸構造層bの層構成を有する長方形のフィルムとして、複層体Aを得た。
凹凸構造層bの表面において、測定箇所を無作為に抽出し、レーザー顕微鏡(VK-9700:キーエンス社製)を用いて高さ(断面プロファイル)を測定した。凹凸構造層bの凹部は直交する2つの面内方向に沿って配置されているため、このうちの一方の面内方向を測定方向として採用し、この測定方向にそって断面プロファイルを測定した。測定されたプロファイルから、隣り合う一対の凹部及び凸部を凹凸一単位とし、この凹凸一単位における断面プロファイルの最大値と最小値との差を、その凹凸単位において隣り合う凹凸の高低差Hとした。前記の測定は、1箇所の測定箇所当たり100μmの長さにわたって行った。また、測定方向を固定し、同様の測定を合計15箇所の測定箇所で行った。そうして得られた計測値から、凹凸構造層bの表面における隣り合う凹凸の高低差Hの平均値及び標準偏差σを求めた結果、平均値は24.3μm、標準偏差σは0.12μmであった。なお、凹部13における四角錐の底辺の寸法は11.5μm、凹部13の深さは10μmであり、平坦部14の幅寸法は4μmであった。
複層体Aを、ガラス基板に接着剤(アクリル系樹脂、屈折率1.49、日東電工社製 CS9621)を介して貼付し、ガラス基板付複層体Bを得た。
また、蛍光灯の直前に、幅5mmのスリットをつけた遮光板を配置したものを、光源として用意した。
輝度の減衰率(%)=P2/P1×100
この輝度の減衰率の値が大きいほど虹ムラは大きく、小さいほど虹ムラは小さいことを示しており、50%以上のとき、目視で虹ムラがはっきりと確認できる。
本実施例においては、輝度の減衰率=37.9%であった。
厚さ0.7mmのガラス基板の一方の主面に、透明電極層100nm、ホール輸送層10nm、黄色発光層20nm、青色発光層15nm、電子輸送層15nm、電子注入層1nm、及び反射電極層100nmを、この順に形成した。ホール輸送層から電子輸送層までは全て有機材料により形成した。なお、黄色発光層及び青色発光層はそれぞれ異なる発光スペクトルを有している。
・透明電極層;錫添加酸化インジウム(ITO)
・ホール輸送層;4,4’-ビス[N-(ナフチル)-N-フェニルアミノ]ビフェニル(α-NPD)
・黄色発光層;ルブレン1.5重量%添加 α-NPD
・青色発光層;イリジウム錯体10重量%添加 4,4’-ジカルバゾリル-1,1’-ビフェニル(CBP)
・電子輸送層;フェナンスロリン誘導体(BCP)
・電子注入層;フッ化リチウム(LiF)
・反射電極層;Al
さらに、電極層に通電のための配線を取り付け、さらにホール輸送層から反射電極層までを封止部材により封止し、有機EL素子を作製した。得られた有機EL素子は、ガラス基板側から白色の光を出光しうる長方形の発光面を有していた。
前記(2-1)で得た有機EL素子のガラス基板側の面に、前記(1-1)で得た複層体Aを、接着剤(アクリル系樹脂、屈折率1.49、日東電工社製 CS9621)を介して貼付し、複層体A-接着層-ガラス基板-有機EL素子の層構成を含む面光源装置を得た。接着層の厚さは20μmであった。
前記(2-2)で得られた面光源装置を点灯しない状態で、前記(1-3)と同様にして観察点から表面の反射像を目視にて観察したところ、虹ムラはほとんど観察されなかった。
前記(1-1)の複層体Aの製造にあたり、金属型の形状を変更した他は、実施例1と同様にして、複層体Aを製造した。得られた複層体Aにおいて、凹凸構造層b上の凹凸構造は、実施例1とほぼ同様であったが、凹凸構造層b(厚み15μm)の表面における隣り合う凹凸の高低差Hの平均値は24.3μm、標準偏差σは0.03μmであった。なお、凹部13における四角錐の底辺の寸法は11.5μm、凹部13の深さは10μmであり、平坦部14の幅寸法は4μmであった。
前記(1-3)と同様の要領で虹ムラ評価を実施したところ、輝度減衰率=87.6%であった。
さらに、前記(2-2)と同様の要領で面光源装置を製造し、前記(2-3)と同様の要領で観察したところ、虹ムラが生じていることが観察された。
前記(1-1)の複層体Aの製造にあたり、金属型の形状を変更した他は、実施例1と同様にして、複層体Aを製造し、さらに面光源装置を得た。
図21に、実施例2で製造した凹凸構造層bを、その主面に垂直な平面で切った断面を模式的に示す。図21に示すように、得られた複層体Aにおいて、凹凸構造層b上の凹凸構造は、複数の四角錐形状の凹部13からなっていた。また、凹凸構造層bを、その主面に垂直な平面で切った断面構造は、凹部13の頂角θは90°となっていて、凹部13の四角錐の頂点16の高さおよび凸部の頂点17の高さの両方がランダムに不揃いになっている構造であった。
また、前記(1-3)と同様の要領で虹ムラ評価を実施したところ、輝度減衰率=34.1%であった。
さらに、前記(2-3)と同様の要領で面光源装置を観察したところ、実施例1よりもさらに虹ムラの少ない、良好な状態であることが観察された。
前記(1-1)の複層体Aの製造にあたり、金属型の形状を変更した他は、実施例1と同様にして、複層体Aを製造し、さらに面光源装置を得た。
図22に、実施例3で製造した凹凸構造層bを、その主面に垂直な平面で切った断面を模式的に示す。図22に示すように、得られた複層体Aにおいて、凹凸構造層b上の凹凸構造は、複数の四角錐形状の凹部13と、凹部13の周囲に位置する平坦部14からなっていた。また、凹凸構造層bを、その主面に垂直な平面で切った断面構造は、凹部13の頂角θは60°となっていて、凹部13の四角錐の高さがランダムに不揃いとなり、平坦部14の高さが一定に揃っている構造であった。
また、前記(1-3)と同様の要領で虹ムラ評価を実施したところ、輝度減衰率=47.8%であった。
さらに、前記(2-3)と同様の要領で面光源装置を観察したところ、虹ムラの少ない、良好な状態であることが観察された。
前記(1-1)の複層体Aの製造にあたり、金属型の形状を変更した他は、実施例1と同様にして、複層体Aを製造し、さらに面光源装置を得た。得られた複層体Aにおいて、凹凸構造層b上の凹凸構造は、実施例1とほぼ同様であり、凹凸構造層b(厚み35μm)の表面における隣り合う凹凸の高低差Hの平均値は12.2μm、標準偏差σは0.06μmであった。なお、凹部13における四角錐の底辺の寸法は34μm、凹部13の深さは30μmであり、平坦部14の幅寸法は2μmであった。
また、前記(1-3)と同様の要領で虹ムラ評価を実施したところ、輝度減衰率=44.0%であった。
さらに、前記(2-3)と同様の要領で面光源装置を観察したところ、虹ムラの少ない、良好な状態であることが観察された。
(1-4:複層体Bの製造)
UV(紫外線)硬化型樹脂(ウレタンアクリレート樹脂、屈折率n=1.54)に直径2μmの粒子(シリコーン樹脂)を添加し、撹拌して粒子を分散させ、凹凸構造層bの材料となる樹脂組成物(1)を製造した。粒子の含有割合は、樹脂組成物(1)全量中の10重量%とした。
前記(1-3)と同様の要領で虹ムラ評価を実施したところ、輝度減衰率=36.4%であった。
さらに、前記(2-3)と同様の要領で面光源装置を観察したところ、虹ムラの少ない、良好な状態であることが観察された。
前記(1-1)の複層体Aの製造にあたり、金属型の形状を変更した他は、実施例2と同様にして、複層体Aを製造した。得られた複層体Aにおいて、凹凸構造層b上の凹凸構造は、実施例2とほぼ同様であったが、凹凸構造層b(厚み25μm)の表面における隣り合う凹凸の高低差Hの平均値は25.6μm、標準偏差σは0.02μmであった。なお、凹部13における四角錐の底辺の寸法は24μm、凹部13の深さは20μmであった。
また、前記(1-3)と同様の要領で虹ムラ評価を実施したところ、輝度減衰率=54.8%であった。
さらに、前記(2-2)と同様の要領で面光源装置を製造し、前記(2-3)と同様の要領で観察したところ、虹ムラが生じていることが観察された。
前記(1-4)の複層体Bの製造にあたり、金属型の形状を変更した他は、実施例5と同様にして、複層体Cを製造した。得られた複層体Cにおいて、凹凸構造層b上の凹凸構造は、実施例5とほぼ同様であったが、凹凸構造層b(厚み35μm)の表面における隣り合う凹凸の高低差Hの平均値は24.3μm、標準偏差σは0.01μmであった。なお、凹部13における四角錐の底辺の寸法は34μm、凹部13の深さは30μmであり、平坦部14の幅寸法は2μmであった。
また、前記(1-3)と同様の要領で虹ムラ評価を実施したところ、輝度減衰率=67.9%であった。
さらに、前記(2-2)と同様の要領で面光源装置を製造し、前記(2-3)と同様の要領で観察したところ、虹ムラが生じていることが観察された。
前記(1-4)の複層体Bの製造にあたり、金属型の形状を変更した他は、比較例3と同様にして、複層体Cを製造した。得られた複層体Cにおいて、凹凸構造層b上の凹凸構造は、比較例3とほぼ同様であったが、凹凸構造層b(厚み15μm)の表面における隣り合う凹凸の高低差Hの平均値は24.3μm、標準偏差σは0.54μmであった。なお、凹部13における四角錐の底辺の寸法は11.5μm、凹部13の深さは10μmであり、平坦部14の幅寸法は4μmであった。
また、前記(1-3)と同様の要領で虹ムラ評価を実施したところ、輝度減衰率=30.1%であった。
さらに、前記(2-2)と同様の要領で面光源装置を製造し、前記(2-3)と同様の要領で観察したところ、虹ムラは良好であった。しかし、目視で確認できるキズが複数生じていることが観察された。
上述した実施例及び比較例の結果を、下記の表1にまとめた。なお、表1の目視評価の欄において、虹ムラがほとんど観察されなかったものを良、虹ムラが生じていることが観察されたものを不良とした。
11A~11D 斜面
11E~11H 凹部の四角錐形状の底辺
11J、11K 凹部の間隔
11L、11M 凹部の斜面と平坦部とがなす角
11N 凹部の四角錐形状の頂角
11P 凹部の四角錐形状の頂点
10U 出光面
100 出光面構造層
110 複層体
111 凹凸構造層
112 基材フィルム層
113 凹部
114 平坦部
121 接着層
131 支持基板
140 有機EL素子
141 第一の電極層
142 発光層
143 第二の電極層
144 有機EL素子の表面(発光面)
145 有機EL素子の表面
151 封止基材
20 面光源装置
20U 出光面
21P 底面部
200 出光面構造層
210 複層体
211 凹凸構造層
213 凹部
213A、212B 斜面
214 平坦部
30 面光源装置
30U 出光面
31P 底
300 出光面構造層
310 複層体
311 凹凸構造層
313 凹部
313A、313B 斜面
314 平坦部
40 面光源装置
40U 出光面
400 出光面構造層
410 複層体
411 凹凸構造層
413 平坦部
413A、413B 斜面
414 凸部
414U 上面部
50 面光源装置
50U 出光面
500 出光面構造層
510 複層体
511 凹凸構造層
513 凹部
514 平坦部
60 面光源装置
60U 出光面
600 出光面構造層
610 複層体
611 凹凸構造層
613 平坦部
614 凸部
614P 凸部の先端
70 面光源装置
70U 出光面
700 出光面構造層
710 複層体
711 凹凸構造層
713 凹部
714 平坦部
80 面光源装置
80U 出光面
800 出光面構造層
810 複層体
811 凹凸構造層
813 凹部
814 平坦部
815 凹部間の境界部分
816 凹部
821 凹凸構造層
90 面光源装置
940 有機EL素子
943 第二の電極
T 凹凸構造層の厚さ
H 隣り合う凹凸の高低差
Claims (5)
- 発光面を有し前記発光面から発光する有機エレクトロルミネッセンス素子と、前記有機エレクトロルミネッセンス素子の前記発光面側に設けられる出光面構造層とを備える面光源装置であって、
前記出光面構造層は、前記有機エレクトロルミネッセンス素子とは反対側の表面に、相対的に窪んだ凹部と相対的に突出した凸部とを、前記表面に対して平行な面内方向において交互に有し、
隣り合う前記凹部の底と前記凸部の先端との、前記面光源装置の厚み方向における距離が、標準偏差0.05μm以上の範囲で不揃いになっている、面光源装置。 - 前記出光面構造層における前記有機エレクトロルミネッセンス素子とは反対側の表面が、前記面光源装置の最表面に露出している、請求項1記載の面光源装置。
- 前記凹部又は凸部の形状が角錐形状又は角錐台形状である、請求項1に記載の面光源装置。
- 前記凸部の先端が、前記発光面に対して平行な平坦面となっている、請求項1に記載の面光源装置。
- 前記凹部の底及び前記凸部の先端の一方又は両方が丸みを帯びている、請求項1に記載の面光源装置。
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Application Number | Title | Priority Date | Filing Date |
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PCT/JP2011/064476 WO2012002260A1 (ja) | 2010-06-29 | 2011-06-23 | 面光源装置 |
Country Status (4)
Country | Link |
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US (1) | US8704441B2 (ja) |
JP (1) | JP5783175B2 (ja) |
CN (1) | CN102959759B (ja) |
WO (1) | WO2012002260A1 (ja) |
Cited By (4)
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---|---|---|---|---|
JP2012178279A (ja) * | 2011-02-25 | 2012-09-13 | Asahi Kasei Corp | 有機エレクトロルミネッセンス素子 |
KR20170037960A (ko) | 2014-07-31 | 2017-04-05 | 니폰 제온 가부시키가이샤 | 유기 el 발광 장치 |
US9871227B2 (en) | 2014-07-31 | 2018-01-16 | Zeon Corporation | Light scattering layer having particles for an organic EL light emitting device |
JP2020177234A (ja) * | 2019-04-22 | 2020-10-29 | 三星ディスプレイ株式會社Samsung Display Co.,Ltd. | ウィンドウ部材、ウィンドウ部材の製造方法、及びディスプレイモジュール |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6508060B2 (ja) * | 2013-12-27 | 2019-05-08 | 日本ゼオン株式会社 | 光学積層体および面光源装置 |
KR102645419B1 (ko) * | 2018-08-20 | 2024-03-07 | 엘지디스플레이 주식회사 | 발광 표시 장치 |
CN114089563A (zh) * | 2019-05-14 | 2022-02-25 | 瑞仪(广州)光电子器件有限公司 | 光源结构、背光模组及显示装置 |
CN113161400A (zh) * | 2021-04-22 | 2021-07-23 | 安徽熙泰智能科技有限公司 | 一种改善Micro OLED微腔室效应的CPL结构及其制备方法 |
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JP2009110873A (ja) * | 2007-10-31 | 2009-05-21 | Toppan Printing Co Ltd | 表示装置 |
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- 2011-06-23 US US13/702,124 patent/US8704441B2/en not_active Expired - Fee Related
- 2011-06-23 WO PCT/JP2011/064476 patent/WO2012002260A1/ja active Application Filing
- 2011-06-23 JP JP2012522590A patent/JP5783175B2/ja not_active Expired - Fee Related
- 2011-06-23 CN CN201180032226.4A patent/CN102959759B/zh not_active Expired - Fee Related
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JP2009110873A (ja) * | 2007-10-31 | 2009-05-21 | Toppan Printing Co Ltd | 表示装置 |
JP2010027428A (ja) * | 2008-07-22 | 2010-02-04 | Konica Minolta Opto Inc | 面発光体、及びそれを用いる表示装置、照明装置 |
JP2010097711A (ja) * | 2008-10-14 | 2010-04-30 | Toppan Printing Co Ltd | El素子およびディスプレイ装置 |
JP4711027B2 (ja) * | 2009-06-11 | 2011-06-29 | 日本ゼオン株式会社 | 面光源装置、照明器具及びバックライト装置 |
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Cited By (7)
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JP2012178279A (ja) * | 2011-02-25 | 2012-09-13 | Asahi Kasei Corp | 有機エレクトロルミネッセンス素子 |
KR20170037960A (ko) | 2014-07-31 | 2017-04-05 | 니폰 제온 가부시키가이샤 | 유기 el 발광 장치 |
US9871227B2 (en) | 2014-07-31 | 2018-01-16 | Zeon Corporation | Light scattering layer having particles for an organic EL light emitting device |
US10074828B2 (en) | 2014-07-31 | 2018-09-11 | Zeon Corporation | Light scattering layer having particles for an organic EL light-emitting device |
JP2020177234A (ja) * | 2019-04-22 | 2020-10-29 | 三星ディスプレイ株式會社Samsung Display Co.,Ltd. | ウィンドウ部材、ウィンドウ部材の製造方法、及びディスプレイモジュール |
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JP7549458B2 (ja) | 2019-04-22 | 2024-09-11 | 三星ディスプレイ株式會社 | ディスプレイモジュール |
Also Published As
Publication number | Publication date |
---|---|
JP5783175B2 (ja) | 2015-09-24 |
JPWO2012002260A1 (ja) | 2013-08-22 |
CN102959759B (zh) | 2015-07-15 |
US8704441B2 (en) | 2014-04-22 |
US20130076238A1 (en) | 2013-03-28 |
CN102959759A (zh) | 2013-03-06 |
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