WO2011131465A1 - Method for manufacturing smoking articles and smoking articles - Google Patents

Method for manufacturing smoking articles and smoking articles Download PDF

Info

Publication number
WO2011131465A1
WO2011131465A1 PCT/EP2011/054982 EP2011054982W WO2011131465A1 WO 2011131465 A1 WO2011131465 A1 WO 2011131465A1 EP 2011054982 W EP2011054982 W EP 2011054982W WO 2011131465 A1 WO2011131465 A1 WO 2011131465A1
Authority
WO
WIPO (PCT)
Prior art keywords
rod
filter element
smoking article
band
patch
Prior art date
Application number
PCT/EP2011/054982
Other languages
English (en)
French (fr)
Inventor
Karl Kaljura
Leonardo Nappi
Richard Fiebelkorn
Original Assignee
British American Tobacco (Investments) Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2013505386A priority Critical patent/JP2013524793A/ja
Application filed by British American Tobacco (Investments) Limited filed Critical British American Tobacco (Investments) Limited
Priority to NZ603134A priority patent/NZ603134A/en
Priority to EP11711351A priority patent/EP2560511A1/en
Priority to KR1020127030662A priority patent/KR20130050940A/ko
Priority to AU2011244545A priority patent/AU2011244545A1/en
Priority to US13/642,457 priority patent/US20130118510A1/en
Priority to CA2796913A priority patent/CA2796913A1/en
Priority to CN2011800308252A priority patent/CN102939020A/zh
Priority to MX2012012134A priority patent/MX2012012134A/es
Priority to RU2012149551/12A priority patent/RU2012149551A/ru
Priority to BR112012027042A priority patent/BR112012027042A2/pt
Publication of WO2011131465A1 publication Critical patent/WO2011131465A1/en
Priority to ZA2012/08316A priority patent/ZA201208316B/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/47Attaching filters or mouthpieces to cigars or cigarettes, e.g. inserting filters into cigarettes or their mouthpieces
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers
    • A24D1/025Cigars; Cigarettes with special covers the covers having material applied to defined areas, e.g. bands for reducing the ignition propensity
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/47Attaching filters or mouthpieces to cigars or cigarettes, e.g. inserting filters into cigarettes or their mouthpieces
    • A24C5/471Attaching filters or mouthpieces to cigars or cigarettes, e.g. inserting filters into cigarettes or their mouthpieces by means of a connecting band
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers

Definitions

  • the present invention relates to a method for making smoking articles, smoking articles, and more particularly to a method for manufacturing smoking articles having a reduced ignition propensity.
  • One method for making wrappers for smoking articles having reduced ignition propensity is to add bands of paper to the wrapping paper, wherein the composition of the wrapper and the band paper are selected to yield a composite paper having the desired burn rate, as disclosed in EP 0 483998 and EP 0 262550.
  • the bands are typically applied to the paper before it is wrapped around a tobacco core, and when the paper is wrapped around the tobacco the bands are on the inside of the paper, facing the tobacco. When the paper is used to manufacture the cigarettes, the bands are randomly situated along the length of the cigarette.
  • Another method for making smoking articles having reduced ignition propensity is to apply a burn retardant additive to the smoking article wrapper, for instance cigarette paper.
  • the burn retardant additive is typically applied as a solution in a pattern such as bands which, in the final assembled cigarette, extend around the circumference of the cigarette.
  • a method for manufacturing a suitable such banded paper is disclosed in W 098/01233.
  • the machines used for wrapping cigarettes which may be modified to include a section for applying a burn retardant solution, apply significant tension to the paper and when the paper is damp its tensile strength is significantly reduced so that tearing of the paper easily occurs.
  • Various heaters can be included in the machine to assist in drying the paper but to allow time for these to properly dry the paper, the machine must be slowed. The slowing of the machine may also alleviate problems with tearing, but this decreases production efficiency.
  • the present invention provides a method of manufacturing a smoking article comprising providing a filter element and at least one rod of smokeable material surrounded by a wrapper, wrapping a section of tipping paper around the filter element and a portion of the at least one wrapped rod and applying one or more patches of material to the outer surface of the wrapper.
  • the present invention also provides a smoking article comprising a rod of smokeable material surrounded by a wrapper, a filter element at one end of the wrapped rod, a tipping paper surrounding the filter element and a portion of the wrapped rod and a patch of material applied to the outer surface of the wrapper.
  • one or more patches are applied to the outside of the wrapper, such that this can occur online during manufacture of the wrapped rod. This allows the position of the patches relative to the filter in the final smoking article to be determined.
  • the step of applying the one or more patches of material to the wrapper of the at least one wrapped rod can be performed in association with the step of wrapping the section of tipping paper around the filter element and an end of the at least one wrapped rod. In this way, modification to existing cigarette manufacturing processes in order to apply the additional patches can be minimised and production rates are not limited by the modification.
  • the one or more patches can comprise a low porosity or non porous web material and/ or can comprise a web material having a permeability of approximately 50CU or less, preferably approximately 10CU or less.
  • the one or more patches can be bands applied around the full circumference of the at least one wrapped rod, and/ or applied such that the mouth-end side of the band is within the 50% of the length of the rod which is closest to the filter element.
  • the application of the bands can include applying a second band to each rod
  • the second band can be applied such that the mouth-end side of the second band is within the 50% of the length of the rod which is furthest from the filter element.
  • the step of providing a filter element and at least one rod of smokeable material surrounded by a wrapper can comprise providing first and second rods of smokeable material surrounded by wrappers, and a filter element interposed between the first and second rods, and the method can further comprise cutting the filter element to form two smoking articles after application of the one or more patches.
  • the method can also comprise splitting tipping paper from a roll to form both the patches and the section to be applied to the filter element and the ends of the wrapped rods.
  • the one or more bands can be spaced from an edge of the tipping paper and/ or have a width of at least 4mm.
  • the material for the patches can be the same as the tipping paper material, although additional printing may be used on the section of material used on the tipping paper or bands.
  • Figure 1 is a schematic illustration of a method of manufacturing a smoking article according to an embodiment of the present invention
  • Figure 2 shows a smoking article according to an embodiment of the present invention
  • Figure 3 shows a smoking article in which a window in a patch exposes a region of underlying wrapper
  • Figure 4 shows another smoking article in which a window in a patch exposes a region of underlying wrapper.
  • Figure 1 illustrates a method and apparatus for manufacturing smoking articles in the form of cigarettes, according to an embodiment of the invention.
  • a continuous wrapped rod of tobacco 20 is supplied from a garniture region of a cigarette making machine to cutting means 21 A and 21 B which cut the rod 20 into lengths required for a single cigarette.
  • the first cutting means 21A cuts the rod 20 into double length rods, each having a length required to make two cigarettes, and then second cutting means 21B cuts the double length rods into single length rods 30.
  • Each pair of single length rods 30 is separated and a double length filter 40 is positioned between the ends of the two wrapped rods 30 such that each end of the double length filter 40 abuts an end of one of the single length rods 30.
  • Tipping paper is supplied from a reel 13 of tipping paper mounted on a bobbin.
  • the tipping paper is split longitudinally into three sections, comprising a wider central section 12A and two narrower edge sections 12B l 5 12B 2 and adhesive 14 is applied to the tipping paper.
  • the adhesive could be applied before splitting with dry lines provided on the gummer roller positioned to allow a clean cut to take place after application of adhesive.
  • the sections 12A, 12B l 5 12B 2 are then cut laterally into individual segments, each of which is applied to a double cigarette assembly.
  • the wider central section 12A is wrapped around the centre of the double cigarette assembly such that it covers the entire double length filter 40 and overlaps an end of each of the wrapped rods 30.
  • the central section 12A forms a tipping paper section 12A which attaches the double length filter to the pair of wrapped rods 30.
  • Each of the edge sections 12B l 5 12B 2 comprises a patch which is wrapped around a respective one of the wrapped rods 30, spaced from a respective edge of the central section 12A to form a circumferential band.
  • the patches 12B 1 , 12B 2 may alternatively be applied so that they only partially circumscribe the wrapped rod 30, thereby forming a partial band.
  • the double length cigarette assembly is subsequently cut by third cutting means 50 at the centre of the double length filter 40 to form a cigarette pair.
  • the patch sections 12B 1 and 12B 2 form an LIP band on each wrapped rod 30 and are applied to the wrapped rods 30 online during cigarette manufacture, in a process step associated with the step of applying the tipping paper section 12A to connect the filter to the wrapped rods 30.
  • the patch sections 12B j and 12B 2 can be applied simultaneously to applying the tipping paper section 12A or can be otherwise applied in the same phase of manufacture as that in which the tipping paper section 12A is applied, for instance after formation of the wrapped rods 30.
  • the cigarettes manufactured by the method illustrated in Figure 1 include only a single LIP patch spaced from an edge of the tipping paper.
  • the patch is positioned in the first 50% of the exposed length (i.e. the 50% closest to the filter end) of the wrapped rod. This is because it is desirable that the cigarette self extinguish towards the end of the smoking.
  • a wider reel 13 of tipping paper may be provided, wherein the paper is split into further longitudinal ribbons. For example, if two bands are required, the paper may be split into five ribbons.
  • FIG. 2 shows a smoking article in the form of a cigarette, in accordance with an embodiment of the present invention, having two LIP bands A, B.
  • the cigarette comprises a wrapped rod 30 and a filter attached to the wrapped rod 30 by tipping paper 2 which covers the filter and overlaps the wrapped rod 30.
  • the wrapped rod 30 comprises a tobacco core surrounded by a paper wrapper.
  • the length of the tipping paper 2 is L T and the exposed length of the wrapped rod 1 (before the LIP bands A, B are applied) is L w .
  • a first LIP band A has a first width W A and is positioned spaced from an edge of the tipping paper 2 by a first distance a.
  • a second LIP band B has a second width W B and is spaced from an edge of the tipping paper 2 by a second distance b, which is longer than the first distance a.
  • the tipping paper 2 is formed from the half of the central tipping section 12A shown in Figure 1, and the first band A is formed from one of the edge patch sections 12B l5 12B 2 .
  • the second band B can be formed from a further patch section of tipping paper split from the reel 13.
  • the first band A is positioned within the first 50% of the exposed length of the wrapped rod 1 ie (W A +a)/ L w ⁇ 0.5.
  • the second band B is spaced from the first band A and positioned within the last 50% of the exposed length of the wrapped rod 1 ie (L w -b)/ L w ⁇ 0.5.
  • the base material used for the LIP bands is the same as that used for the tipping paper (although different printing may be used on each section) and preferably has a porosity of approximately 5 Coresta Units (CU).
  • each section may be provided from a separate reel.
  • the outer patch sections 12B l 5 12B 2 need not be formed from the same material as the central tipping section 12A.
  • the outer patch sections 12B l 5 12B 2 may be formed from the same material as the wrapper of the wrapped rods 30.
  • the outer patch sections 12B l 5 12B 2 may be formed from an alternative material, such as a plugwrap paper or a cigarette paper having a different weight or permeability to the cigarette paper forming the wrapping of the wrapped rods 30.
  • An example porosity is
  • the specific values chosen for the widths W A , W B and sizes of the LIP patches, for the porosity of the LIP patches and for their position on the wrapped rod can be adjusted as appropriate to achieve a required reduction in ignition propensity and the location at which this will be effective.
  • LIP band widths above approximately 4mm could be used, preferably between 4mm and 25mm and more preferably between approximately 4mm and 10mm.
  • the porosity of the paper can be less than approximately 50CU, preferably less than 10CU and more preferably less than or equal to 5CU.
  • LIP-compliant cigarettes were manufactured having a single 5CU porosity LIP band applied per cigarette in a 6mm or 8mm width and with the mouth-end edge of the band being 50mm from the mouth end of the cigarette.
  • the banding material was adhered to the tobacco rod with water-based glue.
  • the width of the LIP patch 12B l5 12B 2 may optionally be substantially equal to the length L ⁇ , of the region of wrapped tobacco rod 30 which is not covered by the sheet of tipping paper 2 connecting the wrapped rod 30 to the filter.
  • Figure 3 shows an LIP patch C which extends substantially from the edge of the tipping paper 2 which is furthest from the mouth end of the smoking article to the opposite end of the wrapped tobacco rod 30.
  • the LIP patch C comprises one or more windows 3 which expose the underlying wrapped tobacco rod 30 to the surrounding atmosphere.
  • Each window 3 comprises a hole in the patch C of LIP material.
  • the windows 3 may be cut-out from the LIP sheet material before the material is applied to the wrapped rod 30.
  • the windows 3 can be cut-out from the material before the material is wound onto the bobbin or reel 13.
  • the regions of the patch C between the windows 3 fully circumscribe the wrapped tobacco rod 30. Therefore, the regions of the patch which do not align with a window 3 can be considered as corresponding to the LIP bands A, B described above.
  • the patch C thus provides the same LIP effect as the LIP patches A, B previously referred to. Specifically, burning of the wrapped tobacco rod 30 is hindered in the regions of the rod 30 which are covered by the LIP patch A, B, C whilst burning of the rod 30 is less hindered in the regions of the rod 30 which are not covered by the patch A, B, C.
  • the rate of gaseous transfer between the tobacco and the surrounding environment, for example the surrounding air, through the windows 3 in the patch C mirrors the rate of gaseous transfer through the un-banded regions of the wrapped rod 30 shown in Figure 2 and as previously described.
  • the location of the windows 3 may be opposite to the location of the LIP bands A, B described above.
  • a first window 3 in the LIP patch C may extend between a location which is a distance of (a+W ⁇ from the edge of the tipping paper 2 and a location which is a distance b from the edge of the tipping paper 2.
  • the width of the first window is therefore ⁇ -(a+W ⁇ ).
  • a second window 3 may extend between a location which is a distance of (b+W B ) from the edge of the tipping paper 2 and a location which is a distance of L 3 ⁇ 4 , from the edge of the tipping paper 2.
  • the width of the second window 3 is therefore This is also shown in Figure 3.
  • Figure 4 shows another example, in which a window 3 extends between a location which is a distance of (a+W ⁇ from the edge of the tipping paper 2 and a location which is a distance of L 3 ⁇ 4 , from the edge of the tipping paper 2.
  • the width of the window 3 is therefore ( ⁇ -(a+W ⁇ ).
  • circumferential regions of LIP material are provided around the same regions of the wrapped tobacco rod 30 in both the embodiment shown in Figure 2 and the embodiments shown in Figures 3 and 4. Similarly, the wrapped tobacco rod 30 in between the circumferential regions of LIP material is largely exposed.
  • windows 3 may be provided in a circumferential band around the tobacco rod 30 so that two or more windows 3 are provided at the same longitudinal location on the rod 30.
  • the windows 3 can be of any suitable shape.
  • the LIP patch material comprises the same material that is used for the tipping paper 2
  • a sheet of the material can optionally be applied over the whole length of a double length cigarette of the type shown in Figure 1 before cutting the double length filter in half.
  • the windows 3 should be cut-out from the LIP material beforehand.
  • tipping paper 2 and patch C are shown using a different pattern in order to allow the reader to clearly distinguish between the two.
  • the tipping paper 2 and patch C may in practice be made of the same type of material.

Landscapes

  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Carbon And Carbon Compounds (AREA)
PCT/EP2011/054982 2010-04-22 2011-03-31 Method for manufacturing smoking articles and smoking articles WO2011131465A1 (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
US13/642,457 US20130118510A1 (en) 2010-04-22 2011-03-31 Method for Manufacturing Smoking Articles and Smoking Articles
NZ603134A NZ603134A (en) 2010-04-22 2011-03-31 Method for manufacturing smoking articles and smoking articles
EP11711351A EP2560511A1 (en) 2010-04-22 2011-03-31 Method for manufacturing smoking articles and smoking articles
KR1020127030662A KR20130050940A (ko) 2010-04-22 2011-03-31 끽연류 제조 방법 및 끽연류
AU2011244545A AU2011244545A1 (en) 2010-04-22 2011-03-31 Method for manufacturing smoking articles and smoking articles
JP2013505386A JP2013524793A (ja) 2010-04-22 2011-03-31 喫煙品の製造方法および喫煙品
CA2796913A CA2796913A1 (en) 2010-04-22 2011-03-31 Method for manufacturing smoking articles and smoking articles
RU2012149551/12A RU2012149551A (ru) 2010-04-22 2011-03-31 Способ изготовления курительных изделий и курительное изделие
MX2012012134A MX2012012134A (es) 2010-04-22 2011-03-31 Metodo para fabricar articulos para fumar y articulos para fumar.
CN2011800308252A CN102939020A (zh) 2010-04-22 2011-03-31 吸烟物品以及用于制造吸烟物品的方法
BR112012027042A BR112012027042A2 (pt) 2010-04-22 2011-03-31 método para produzir um artigo de fumo e artigo de fumo
ZA2012/08316A ZA201208316B (en) 2010-04-22 2012-11-05 Method for manufacturing smoking articles and smoking articles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1006730.4 2010-04-22
GBGB1006730.4A GB201006730D0 (en) 2010-04-22 2010-04-22 Method for manufacturing smoking articles and smoking articles

Publications (1)

Publication Number Publication Date
WO2011131465A1 true WO2011131465A1 (en) 2011-10-27

Family

ID=42270671

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/054982 WO2011131465A1 (en) 2010-04-22 2011-03-31 Method for manufacturing smoking articles and smoking articles

Country Status (17)

Country Link
US (1) US20130118510A1 (zh)
EP (1) EP2560511A1 (zh)
JP (1) JP2013524793A (zh)
KR (1) KR20130050940A (zh)
CN (1) CN102939020A (zh)
AR (1) AR084382A1 (zh)
AU (1) AU2011244545A1 (zh)
BR (1) BR112012027042A2 (zh)
CA (1) CA2796913A1 (zh)
CL (1) CL2012002946A1 (zh)
GB (1) GB201006730D0 (zh)
MX (1) MX2012012134A (zh)
NZ (1) NZ603134A (zh)
RU (1) RU2012149551A (zh)
TW (1) TW201201717A (zh)
WO (1) WO2011131465A1 (zh)
ZA (1) ZA201208316B (zh)

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WO2013068240A1 (en) * 2011-11-08 2013-05-16 British American Tobacco (Investments) Limited Smoking article
CN104703490A (zh) * 2012-10-16 2015-06-10 英美烟草(投资)有限公司 吸烟制品包裹物和制造吸烟制品的方法
CN104994755A (zh) * 2012-12-06 2015-10-21 英美烟草(投资)有限公司 与吸烟制品组装有关的改进
JP2015531232A (ja) * 2012-10-05 2015-11-02 ブリティッシュ アメリカン タバコ (インヴェストメンツ) リミテッドBritish Americantobacco (Investments) Limited 喫煙品
WO2015165683A1 (en) * 2014-04-29 2015-11-05 Tobacco Research And Development Institute (Proprietary) Limited A smoking article assembly machine for assembling smoking articles having segmented filters

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EP2712957B1 (en) * 2011-08-12 2016-07-13 Japan Tobacco, Inc. Drying device and cigarette wrapping paper manufacturing machine using the drying device
US10034988B2 (en) 2012-11-28 2018-07-31 Fontem Holdings I B.V. Methods and devices for compound delivery
WO2015042412A1 (en) 2013-09-20 2015-03-26 E-Nicotine Technology. Inc. Devices and methods for modifying delivery devices
GB201419838D0 (en) * 2014-11-07 2014-12-24 British American Tobacco Co Smoking article assembly machine and method of making a smoking article
JP6364540B2 (ja) * 2015-03-12 2018-07-25 日本たばこ産業株式会社 フィルタ付きシガレットの製造方法
GB201608928D0 (en) * 2016-05-20 2016-07-06 British American Tobacco Co Article for use in apparatus for heating smokable material
GB201608931D0 (en) * 2016-05-20 2016-07-06 British American Tobacco Co Article for use in apparatus for heating smokeable material
KR102022302B1 (ko) * 2016-10-25 2019-11-04 태영산업 주식회사 담배용 필터의 제조장치
KR101978974B1 (ko) * 2018-08-23 2019-08-28 태영산업 주식회사 담배용 베이스지관 및 그의 제조방법

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Cited By (15)

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Publication number Priority date Publication date Assignee Title
WO2013068240A1 (en) * 2011-11-08 2013-05-16 British American Tobacco (Investments) Limited Smoking article
JP2014533941A (ja) * 2011-11-08 2014-12-18 ブリティッシュ アメリカン タバコ (インヴェストメンツ) リミテッドBritish Americantobacco (Investments) Limited 喫煙品
US9247771B2 (en) 2011-11-08 2016-02-02 British American Tobacco (Investments) Limited Smoking article
US9532595B2 (en) 2012-10-05 2017-01-03 British American Tobacco (Investments) Limited Smoking article
JP2015531232A (ja) * 2012-10-05 2015-11-02 ブリティッシュ アメリカン タバコ (インヴェストメンツ) リミテッドBritish Americantobacco (Investments) Limited 喫煙品
CN104703490A (zh) * 2012-10-16 2015-06-10 英美烟草(投资)有限公司 吸烟制品包裹物和制造吸烟制品的方法
JP2015536678A (ja) * 2012-12-06 2015-12-24 ブリティッシュ アメリカン タバコ (インヴェストメンツ) リミテッドBritish Americantobacco (Investments) Limited 喫煙品組み立てに関する改良
CN104994755A (zh) * 2012-12-06 2015-10-21 英美烟草(投资)有限公司 与吸烟制品组装有关的改进
JP2017131235A (ja) * 2012-12-06 2017-08-03 ブリティッシュ アメリカン タバコ (インヴェストメンツ) リミテッドBritish American Tobacco (Investments) Limited 喫煙品組み立てに関する改良
EP2928327B1 (en) 2012-12-06 2019-06-26 British American Tobacco (Investments) Ltd Improvements relating to smoking article assembly
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WO2015165683A1 (en) * 2014-04-29 2015-11-05 Tobacco Research And Development Institute (Proprietary) Limited A smoking article assembly machine for assembling smoking articles having segmented filters
CN106455680A (zh) * 2014-04-29 2017-02-22 烟草研究和开发协会股份有限公司 组装具有分段过滤嘴的吸烟制品的吸烟制品组装机
CN106455680B (zh) * 2014-04-29 2018-05-11 烟草研究和开发协会股份有限公司 组装具有分段过滤嘴的吸烟制品的吸烟制品组装机
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US20130118510A1 (en) 2013-05-16
KR20130050940A (ko) 2013-05-16
CA2796913A1 (en) 2011-10-27
EP2560511A1 (en) 2013-02-27
CL2012002946A1 (es) 2013-01-11
NZ603134A (en) 2014-05-30
GB201006730D0 (en) 2010-06-09
MX2012012134A (es) 2013-02-27
BR112012027042A2 (pt) 2015-09-15
AR084382A1 (es) 2013-05-15
TW201201717A (en) 2012-01-16
CN102939020A (zh) 2013-02-20
AU2011244545A1 (en) 2012-11-15
ZA201208316B (en) 2015-06-24
RU2012149551A (ru) 2014-05-27
JP2013524793A (ja) 2013-06-20

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