AU2011244545A1 - Method for manufacturing smoking articles and smoking articles - Google Patents

Method for manufacturing smoking articles and smoking articles Download PDF

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Publication number
AU2011244545A1
AU2011244545A1 AU2011244545A AU2011244545A AU2011244545A1 AU 2011244545 A1 AU2011244545 A1 AU 2011244545A1 AU 2011244545 A AU2011244545 A AU 2011244545A AU 2011244545 A AU2011244545 A AU 2011244545A AU 2011244545 A1 AU2011244545 A1 AU 2011244545A1
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AU
Australia
Prior art keywords
rod
filter element
smoking article
band
patch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2011244545A
Inventor
Richard Fiebelkorn
Karl Kaljura
Leonardo Nappi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British American Tobacco Investments Ltd
Original Assignee
British American Tobacco Investments Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British American Tobacco Investments Ltd filed Critical British American Tobacco Investments Ltd
Publication of AU2011244545A1 publication Critical patent/AU2011244545A1/en
Abandoned legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/47Attaching filters or mouthpieces to cigars or cigarettes, e.g. inserting filters into cigarettes or their mouthpieces
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers
    • A24D1/025Cigars; Cigarettes with special covers the covers having material applied to defined areas, e.g. bands for reducing the ignition propensity
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24CMACHINES FOR MAKING CIGARS OR CIGARETTES
    • A24C5/00Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
    • A24C5/47Attaching filters or mouthpieces to cigars or cigarettes, e.g. inserting filters into cigarettes or their mouthpieces
    • A24C5/471Attaching filters or mouthpieces to cigars or cigarettes, e.g. inserting filters into cigarettes or their mouthpieces by means of a connecting band
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • A24D1/02Cigars; Cigarettes with special covers

Landscapes

  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The present invention relates to a method for making smoking articles, smoking articles, and more particularly to a method for manufacturing smoking articles having a reduced ignition propensity. A method of manufacturing a smoking article includes the steps of providing a filter element (40) and at least one rod (30) of smokeable material surrounded by a wrapper, wrapping a section of tipping paper (12A) around the filter element and a portion of the at least one wrapped rod and applying one or more patches (12B1, 12B2) of material to the outer surface of the wrapper. The patches can be arranged to reduce the ignition propensity of the smoking article and are applied to the outside of the wrapper, such that this can occur online during manufacture of the wrapped rod.

Description

WO 2011/131465 PCT/EP2011/054982 Method for Manufacturing Smoking Articles and Smoking Articles Field of the Invention The present invention relates to a method for making smoking articles, smoking 5 articles, and more particularly to a method for manufacturing smoking articles having a reduced ignition propensity. Background to the Invention Many different methods have been suggested for manufacturing smoking articles 10 such as cigarettes having a reduced ignition propensity i.e. a tendency to self extinguish when not drawn on by a smoker. Such smoking articles are generally referred to as having a low ignition propensity (LIP). It has been recognised that the constitution of the wrapper has a significant effect on the burn rate of a cigarette and by modifying the wrapper by various methods, a self-extinguishing 15 cigarette can be produced. One method for making wrappers for smoking articles having reduced ignition propensity is to add bands of paper to the wrapping paper, wherein the composition of the wrapper and the band paper are selected to yield a composite paper having 20 the desired burn rate, as disclosed in EP 0 483998 and EP 0 262550. The bands are typically applied to the paper before it is wrapped around a tobacco core, and when the paper is wrapped around the tobacco the bands are on the inside of the paper, facing the tobacco. When the paper is used to manufacture the cigarettes, the bands are randomly situated along the length of the cigarette. 25 To ensure that cigarettes meet the requirements for self-extinguishment which exist in various counties, the accurate positioning of the bands along the length of the cigarette can be important. However, when using banded papers, ensuring that the bands are positioned in the correct positions along the cigarette is not 30 straightforward and requires longitudinal registration of the paper, adding complexity to the cigarette manufacturing machinery.
WO 2011/131465 PCT/EP2011/054982 -2 Another method for making smoking articles having reduced ignition propensity is to apply a burn retardant additive to the smoking article wrapper, for instance cigarette paper. The burn retardant additive is typically applied as a solution in a pattern such as bands which, in the final assembled cigarette, extend around the 5 circumference of the cigarette. A method for manufacturing a suitable such banded paper is disclosed in W 098/01233. Attempts have been made to apply burn retardant additive banding during the cigarette making process. This allows the bands to be positioned at desired 10 locations by synchronising the application of the bands with cutting of the rod formed when the tobacco is wrapped in the banded paper. This overcomes the problem of positioning of the bands found with the pre-manufactured banded papers. This on line application of banding is disclosed in WO 2004/057986 and US 2004/0261805. However, these processes have additional drawbacks. One 15 problem is in the drying of the paper once the burn retardant solution has been applied. Firstly, this must be dried before the garniture section of the machine where the tobacco is wrapped in the paper, because if the paper is damp at this stage when it comes into contact with the tobacco then discolouration of the paper may occur. Furthermore, the machines used for wrapping cigarettes, which may be 20 modified to include a section for applying a burn retardant solution, apply significant tension to the paper and when the paper is damp its tensile strength is significantly reduced so that tearing of the paper easily occurs. Various heaters can be included in the machine to assist in drying the paper but to allow time for these to properly dry the paper, the machine must be slowed. The slowing of the machine 25 may also alleviate problems with tearing, but this decreases production efficiency. Summary of the Invention The present invention provides a method of manufacturing a smoking article comprising 30 providing a filter element and at least one rod of smokeable material surrounded by a wrapper, wrapping a section of tipping paper around the filter element and a portion of the at least one wrapped rod and applying one or more patches of material to the outer surface of the wrapper.
WO 2011/131465 PCT/EP2011/054982 -3 The present invention also provides a smoking article comprising a rod of smokeable material surrounded by a wrapper, a filter element at one end of the wrapped rod, a tipping paper surrounding the filter element and a portion of the wrapped rod and a patch of material applied to the outer surface of the wrapper. 5 Therefore, one or more patches are applied to the outside of the wrapper, such that this can occur online during manufacture of the wrapped rod. This allows the position of the patches relative to the filter in the final smoking article to be determined. 10 The step of applying the one or more patches of material to the wrapper of the at least one wrapped rod can be performed in association with the step of wrapping the section of tipping paper around the filter element and an end of the at least one wrapped rod. In this way, modification to existing cigarette manufacturing processes in order to apply the additional patches can be minimised and production rates are not limited by the 15 modification. The one or more patches can comprise a low porosity or non porous web material and/or can comprise a web material having a permeability of approximately 50CU or less, preferably approximately IOCU or less. The one or more patches can be bands applied 20 around the full circumference of the at least one wrapped rod, and/or applied such that the mouth-end side of the band is within the 50% of the length of the rod which is closest to the filter element. The application of the bands can include applying a second band to each rod 25 simultaneously to the application of the first band. The second band can be applied such that the mouth-end side of the second band is within the 50% of the length of the rod which is furthest from the filter element. The step of providing a filter element and at least one rod of smokeable material 30 surrounded by a wrapper can comprise providing first and second rods of smokeable material surrounded by wrappers, and a filter element interposed between the first and second rods, and the method can further comprise cutting the filter element to form two smoking articles after application of the one or more patches.
WO 2011/131465 PCT/EP2011/054982 -4 The method can also comprise splitting tipping paper from a rol to form both the patches and the section to be applied to the filter element and the ends of the wrapped rods. 5 The one or more bands can be spaced from an edge of the tipping paper and/or have a width of at least 4mm. The material for the patches can be the same as the tipping paper material, although additional printing may be used on the section of material used on the tipping paper or bands. 10 The invention is defined in the claims appended hereto. Brief Description of the Drawings Preferred embodiments of the present invention will now be described with 15 reference to the accompanying drawings, in which: Figure 1 is a schematic illustration of a method of manufacturing a smoking article according to an embodiment of the present invention; Figure 2 shows a smoking article according to an embodiment of the present 20 invention; Figure 3 shows a smoking article in which a window in a patch exposes a region of underlying wrapper; Figure 4 shows another smoking article in which a window in a patch exposes a region of underlying wrapper. 25 Detailed Description Figure 1 illustrates a method and apparatus for manufacturing smoking articles in the form of cigarettes, according to an embodiment of the invention. 30 In accordance with standard cigarette manufacturing processes, a continuous wrapped rod of tobacco 20 is supplied from a garniture region of a cigarette making machine to cutting means 21A and 21B which cut the rod 20 into lengths required for a single cigarette. The first cutting means 21A cuts the rod 20 into double WO 2011/131465 PCT/EP2011/054982 -5 length rods, each having a length required to make two cigarettes, and then second cutting means 21B cuts the double length rods into single length rods 30. Each pair of single length rods 30 is separated and a double length filter 40 is positioned between the ends of the two wrapped rods 30 such that each end of the double 5 length filter 40 abuts an end of one of the single length rods 30. Tipping paper is supplied from a reel 13 of tipping paper mounted on a bobbin. In Figure 1, the tipping paper is split longitudinally into three sections, comprising a wider central section 12A and two narrower edge sections 12B 1 , 12B 2 and adhesive 10 14 is applied to the tipping paper. Alternatively, the adhesive could be applied before splitting with dry lines provided on the gummer roller positioned to allow a clean cut to take place after application of adhesive. The sections 12A, 12B 1 , 12B 2 are then cut laterally into individual segments, each of which is applied to a double cigarette assembly. The wider central section 12A is wrapped around the centre of 15 the double cigarette assembly such that it covers the entire double length filter 40 and overlaps an end of each of the wrapped rods 30. Thus the central section 12A forms a tipping paper section 12A which attaches the double length filter to the pair of wrapped rods 30. Each of the edge sections 12B, 12B 2 comprises a patch which is wrapped around a respective one of the wrapped rods 30, spaced from a 20 respective edge of the central section 12A to form a circumferential band. The patches 12B, 12B 2 may alternatively be applied so that they only partially circumscribe the wrapped rod 30, thereby forming a partial band. The double length cigarette assembly is subsequently cut by third cutting means 50 25 at the centre of the double length filter 40 to form a cigarette pair. In the method illustrated in Figure 1, the patch sections 12B, and 12B2 form an LIP band on each wrapped rod 30 and are applied to the wrapped rods 30 online during cigarette manufacture, in a process step associated with the step of applying the 30 tipping paper section 12A to connect the filter to the wrapped rods 30. For instance, the patch sections 12B 1 and 12B 2 can be applied simultaneously to applying the tipping paper section 12A or can be otherwise applied in the same WO 2011/131465 PCT/EP2011/054982 -6 phase of manufacture as that in which the tipping paper section 12A is applied, for instance after formation of the wrapped rods 30. The cigarettes manufactured by the method illustrated in Figure 1 include only a 5 single LIP patch spaced from an edge of the tipping paper. Preferably the patch is positioned in the first 5 0 % of the exposed length (i.e. the 50% closest to the filter end) of the wrapped rod. This is because it is desirable that the cigarette self extinguish towards the end of the smoking. However, it may also be desirable to provide further patches at different positions along the wrapped rod to provide the 10 cigarette with the potential to self extinguish at different points during smoking. To provide further patches, for one or more additional bands, a wider reel 13 of tipping paper may be provided, wherein the paper is split into further longitudinal ribbons. For example, if two bands are required, the paper may be split into five ribbons. 15 Figure 2 shows a smoking article in the form of a cigarette, in accordance with an embodiment of the present invention, having two LIP bands A, B. The cigarette comprises a wrapped rod 30 and a filter attached to the wrapped rod 30 by tipping paper 2 which covers the filter and overlaps the wrapped rod 30. The wrapped rod 30 comprises a tobacco core surrounded by a paper wrapper. The length of the 20 tipping paper 2 is L, and the exposed length of the wrapped rod 1 (before the LIP bands A, B are applied) is Lw. A first LIP band A has a first width WA and is positioned spaced from an edge of the tipping paper 2 by a first distance a. A second LIP band B has a second width W and is spaced from an edge of the tipping paper 2 by a second distance b, which is longer than the first distance a. 25 The tipping paper 2 is formed from the half of the central tipping section 12A shown in Figure 1, and the first band A is formed from one of the edge patch sections 12B 1 , 12B 2 . The second band B can be formed from a further patch section of tipping paper split from the reel 13. 30 Preferably, the first band A is positioned within the first 50% of the exposed length of the wrapped rod I ie (WA+a)/ L, S 0.5. Preferably, the second band B is spaced from the first band A and positioned within the last 50% of the exposed length of WO 2011/131465 PCT/EP2011/054982 -7 the wrapped rod 1 ie (Lw-b)/ Lw < 0.5. Preferably the width of the bands are approximately the same, i.e. WA - WB. In the preferred example, given a cigarette of 83mm length , wherein the length LT 5 of the tipping paper 2 is 32mm and the exposed length of the wrapped rod I Lw is 51mm, , a=l1mm, b=31mm and WA = W, =6mm. The base material used for the LIP bands is the same as that used for the tipping paper (although different printing may be used on each section) and preferably has a porosity of approximately 5 Coresta Units (CU). 10 In an alternative to the embodiment shown in Figure 1, rather than splitting the sections 12A, 12B1, 12B2, from a single reel 13 of tipping paper, each section may be provided from a separate reel. In this case, the outer patch sections 12B, 12B2 need not be formed from the same material as the central tipping section 12A. For 15 example, the outer patch sections 12B, 12B 2 may be formed from the same material as the wrapper of the wrapped rods 30. Alternatively, the outer patch sections 12B, 12132 may be formed from an alternative material, such as a plugwrap paper or a cigarette paper having a different weight or permeability to the cigarette paper forming the wrapping of the wrapped rods 30. An example porosity is 20 approximately 5 CU. As would be appreciated by those skilled in the art, the specific values chosen for the widths WA, WB and sizes of the LIP patches, for the porosity of the LIP patches and for their position on the wrapped rod can be adjusted as appropriate to achieve 25 a required reduction in ignition propensity and the location at which this will be effective. For example, LIP band widths above approximately 4mm could be used, preferably between 4mm and 25mm and more preferably between approximately 4mm and 10mm. The porosity of the paper can be less than approximately 50CU, preferably less than 1OCU and more preferably less than or equal to 5CU. 30 In a particular example, based on LIP performance measured according to the ASTM E2187-04 method, LIP-compliant cigarettes were manufactured having a single 5CU porosity LIP band applied per cigarette in a 6mm or 8mm width and WO 2011/131465 PCT/EP2011/054982 with the mouth-end edge of the band being 50mm from the mouth end of the cigarette. The banding material was adhered to the tobacco rod with water-based glue. 5 The width of the LIP patch 12B 1 , 12B 2 may optionally be substantially equal to the length Lw of the region of wrapped tobacco rod 30 which is not covered by the sheet of tipping paper 2 connecting the wrapped rod 30 to the filter. For example, Figure 3 shows an LIP patch C which extends substantially from the edge of the tipping paper 2 which is furthest from the mouth end of the smoking article to the opposite end of the wrapped tobacco rod 10 30. As can be seen, the LIP patch C comprises one or more windows 3 which expose the underlying wrapped tobacco rod 30 to the surrounding atmosphere. Each window 3 comprises a hole in the patch C of LIP material. The windows 3 may be cut-out from the LIP sheet material before the material is applied to the wrapped rod 30. For example, the windows 3 can be cut-out from the material before the material is wound onto the bobbin 15 or reel 13. The regions of the patch C between the windows 3 fully circumscribe the wrapped tobacco rod 30. Therefore, the regions of the patch which do not align with a window 3 can be considered as corresponding to the LIP bands A, B described above. The patch C thus 20 provides the same LIP effect as the LIP patches A, B previously referred to. Specifically, burning of the wrapped tobacco rod 30 is hindered in the regions of the rod 30 which are covered by the LIP patch A, B, C whilst burning of the rod 30 is less hindered in the regions of the rod 30 which are not covered by the patch A, B, C. The rate of gaseous transfer between the tobacco and the surrounding environment, for example the 25 surrounding air, through the windows 3 in the patch C mirrors the rate of gaseous transfer through the un-banded regions of the wrapped rod 30 shown in Figure 2 and as previously described. The location of the windows 3 may be opposite to the location of the LIP bands A, B 30 described above. For example, as shown in Figure 3, a first window 3 in the LIP patch C may extend between a location which is a distance of (a+WA) from the edge of the tipping paper 2 and a location which is a distance b from the edge of the tipping paper 2. The width of the first window is therefore (b-(a+W,)). Additionally or alternatively, a second WO 2011/131465 PCT/EP2011/054982 -9 window 3 may extend between a location which is a distance of (b+WB) from the edge of the tipping paper 2 and a location which is a distance of Lw from the edge of the tipping paper 2. The width of the second window 3 is therefore (L,-(b+WB)). This is also shown in Figure 3. 5 Figure 4 shows another example, in which a window 3 extends between a location which is a distance of (a+WQ from the edge of the tipping paper 2 and a location which is a distance of L,. from the edge of the tipping paper 2. The width of the window 3 is therefore (Lw-(a+WQ). 10 Therefore, circumferential regions of LIP material are provided around the same regions of the wrapped tobacco rod 30 in both the embodiment shown in Figure 2 and the embodiments shown in Figures 3 and 4. Similarly, the wrapped tobacco rod 30 in between the circumferential regions of LIP material is largely exposed. 15 The location, number and size of the windows in the patch C can be chosen in accordance with the desired LIP effect. Optionally, windows 3 may be provided in a circumferential band around the tobacco rod 30 so that two or more windows 3 are provided at the same longitudinal location on the rod 30. The windows 3 can be of any suitable shape. 20 If the LIP patch material comprises the same material that is used for the tipping paper 2, a sheet of the material can optionally be applied over the whole length of a double length cigarette of the type shown in Figure 1 before cutting the double length filter in half. The windows 3 should be cut-out from the LIP material beforehand. 25 In Figures 3 and 4, the tipping paper 2 and patch C are shown using a different pattern in order to allow the reader to clearly distinguish between the two. However, as has been explained, the tipping paper 2 and patch C may in practice be made of the same type of material. 30

Claims (24)

1. A method of manufacturing a smoking article comprising: providing a filter element, and at least one rod of smokeable material surrounded 5 by a wrapper; wrapping a section of tipping paper around the filter element and a portion of the at least one wrapped rod; and applying one or more patches of material to the outer surface of the wrapper. 10
2. A method according to claim 1, wherein the step of applying the one or more patches of material to the wrapper of the at least one wrapped rod is performed in association with the step of wrapping the section of tipping paper around the filter element and an end of the at least one wrapped rod. 15
3. A method according to claim I or 2, wherein the one or more patches comprise a low porosity or non porous web material.
4. A method according to claim 1, 2 or 3, wherein the one or more patches comprise a web material having a permeability of about 50CU or less. 20
5. A method according to any one of the preceding claims, wherein the one or more patches are bands applied around the full circumference of the at least one wrapped rod.
6. A method according to claim 5, wherein each band is applied such that the mouth 25 end side of the band is within the 50% of the length of the rod which is closest to the filter element.
7. A method according to claim 5 or 6, wherein the application includes applying a second band to each rod simultaneously to the application of the first band. 30
8. A method according to claim 7, wherein the second band is applied such that the mouth-end side of the second band is within the 50% of the length of the rod which is furthest from the filter element. WO 2011/131465 PCT/EP2011/054982 - 1t
9. A method according to any one of claims 1 to 4, wherein the one or patches comprise a patch having a window which exposes a region of the outer surface of the wrapper. 5
10. A method according to claim 9, wherein said patch comprises a plurality of said windows.
11. A method according to claim 9 or 10, wherein said patch extends substantially from an edge of the tipping paper to an end of the rod of smokeable material which is furthest 10 from the filter.
12. A method according to any one of the preceding claims, wherein providing a filter element and at least one rod of smokeable material surrounded by a wrapper comprises providing first and second rods of smokeable material surrounded by wrappers, and a filter element interposed between the first and second rods, and wherein the method further 15 comprises cutting the filter element to form two smoking articles after application of the one or more patches.
13. A method according to any one of the preceding claims, comprising splitting tipping paper from a roll to form both the patches and the section to be applied to the 20 filter element and the ends of the wrapped rods.
14. A smoking article comprising: a rod of smokeable material surrounded by a wrapper; a filter element at one end of the wrapped rod; 25 a tipping paper surrounding the filter element and a portion of the wrapped rod; and a patch of material applied to the outer surface of the wrapper.
15. A smoking article according to claim 14, wherein the patch comprises a low 30 porosity or non porous web material.
16. A smoking article according to claim 15, wherein the patch comprise a web material having a permeability of about 50CU or less. WO 2011/131465 PCT/EP2011/054982 - 12
17. A smoking article according to any one of claims 14 to 16, wherein the patch is a band applied around the full circumference of the wrapped rod. 5
18. A smoking article according to claim 17, wherein the band is spaced from an edge of the tipping paper.
19. A smoking article according to claim 17 or 18, wherein the band is at least 4mm wide. 10
20. A smoking article according to claim 19, wherein the band is at least 6mm wide.
21. A smoking article according to any one of claims 14 to 16, wherein the patch comprises a window which exposes a region of the outer surface of the wrapper. 15
22. A smoking article according to claim 21, wherein the patch comprises a plurality of said windows.
23. A smoking article according to claim 20 or 21, wherein the patch extends 20 substantially from an edge of the tipping paper to an end of the rod of smokeable material which is furthest from the filter.
24. A smoking article according to any one of claims 14 to 20, wherein the material is the same as the tipping paper.
AU2011244545A 2010-04-22 2011-03-31 Method for manufacturing smoking articles and smoking articles Abandoned AU2011244545A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1006730.4A GB201006730D0 (en) 2010-04-22 2010-04-22 Method for manufacturing smoking articles and smoking articles
GB1006730.4 2010-04-22
PCT/EP2011/054982 WO2011131465A1 (en) 2010-04-22 2011-03-31 Method for manufacturing smoking articles and smoking articles

Publications (1)

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AU2011244545A1 true AU2011244545A1 (en) 2012-11-15

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US (1) US20130118510A1 (en)
EP (1) EP2560511A1 (en)
JP (1) JP2013524793A (en)
KR (1) KR20130050940A (en)
CN (1) CN102939020A (en)
AR (1) AR084382A1 (en)
AU (1) AU2011244545A1 (en)
BR (1) BR112012027042A2 (en)
CA (1) CA2796913A1 (en)
CL (1) CL2012002946A1 (en)
GB (1) GB201006730D0 (en)
MX (1) MX2012012134A (en)
NZ (1) NZ603134A (en)
RU (1) RU2012149551A (en)
TW (1) TW201201717A (en)
WO (1) WO2011131465A1 (en)
ZA (1) ZA201208316B (en)

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TW201201717A (en) 2012-01-16
ZA201208316B (en) 2015-06-24
WO2011131465A1 (en) 2011-10-27
MX2012012134A (en) 2013-02-27
RU2012149551A (en) 2014-05-27
EP2560511A1 (en) 2013-02-27
CA2796913A1 (en) 2011-10-27
CN102939020A (en) 2013-02-20
JP2013524793A (en) 2013-06-20
NZ603134A (en) 2014-05-30
CL2012002946A1 (en) 2013-01-11
GB201006730D0 (en) 2010-06-09
BR112012027042A2 (en) 2015-09-15
AR084382A1 (en) 2013-05-15
KR20130050940A (en) 2013-05-16

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