WO2011113305A1 - 彩釉平板玻璃及其制备方法 - Google Patents

彩釉平板玻璃及其制备方法 Download PDF

Info

Publication number
WO2011113305A1
WO2011113305A1 PCT/CN2011/000413 CN2011000413W WO2011113305A1 WO 2011113305 A1 WO2011113305 A1 WO 2011113305A1 CN 2011000413 W CN2011000413 W CN 2011000413W WO 2011113305 A1 WO2011113305 A1 WO 2011113305A1
Authority
WO
WIPO (PCT)
Prior art keywords
glass
oxide
temperature
viscosity
glaze
Prior art date
Application number
PCT/CN2011/000413
Other languages
English (en)
French (fr)
Inventor
杨德宁
Original Assignee
Yang Dening
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yang Dening filed Critical Yang Dening
Priority to EP11755622.5A priority Critical patent/EP2687492A4/en
Priority to US13/985,501 priority patent/US20150050461A1/en
Publication of WO2011113305A1 publication Critical patent/WO2011113305A1/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001—General methods for coating; Devices therefor
    • C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
    • C03C17/04—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass by fritting glass powder
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
    • C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
    • C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
    • C03C3/115—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron
    • C03C3/118—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron containing aluminium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness

Definitions

  • the present invention relates to decorative glass for use in particular prior art, and alternative ceramic plates, ceramic tiles and aluminum composite panels, decorative plastic veneers, resin-containing artificial slabs, and for interior and exterior walls, floors and countertops, kitchen-return panels
  • Various decorative sheet materials in home and engineering applications have predetermined indispensable special ranges of sodium oxide, iron oxide, aluminum oxide, silicon oxide, calcium oxide, magnesium oxide, or also titanium oxide, antimony oxide.
  • composition of the composition and the ratio of the composition of the specific ratio of silicon oxide, calcium oxide, magnesium oxide to the composition of the relationship between the change of the invention and the elimination of the boron or sodium components of the invention technical solutions and other innovative technical solutions, overcoming the various traditions
  • the technical prejudice of the composition of the solubilized component and the eutectic component must be composed of a large amount of sodium or boron component [the lower limit of the annealing temperature of the existing soda lime glass of 99.9% of the total output of the flat glass (ie, the endothermic peak starting temperature) Only 49 (TC), and can produce unexpectedly low-sodium, boron-free ingredients to economically produce low-grade glazed glass
  • the lower limit of the technical annealing temperature (ie, the endothermic peak starting temperature) 5 (TC-200 ° C can preferably be higher than the IWC-O substrate slope, and the only one that has a higher temperature lower limit than the existing one (ie, the end of the endothermic peak) Temperature) of flat glass
  • the technical tempered products can not be made into various standard plates such as 2400 1200mm to be arbitrarily cut into other sizes in the hands of the end user; [3] the melting point of the existing glazed tempered glass and all the glaze of Masek glass Both are in the T60V-S20V, because it is suitable for the temperature at which the glass tempering has softened and a little deformation, and the Masek glass softens and uses the corners to round, which is a well-known technique; [4] its hardness and wear resistance are poor, and the strength is only It is about 45-50MPa, and can not be used for home and engineering ground use; ⁇ 5] its degree is 10° 5 (Pa ⁇ s) and 10 1 (Pa ⁇ s) melting temperature, using American ⁇ rotating high temperature viscometer It can't be detected at all.
  • the existing aluminum-plastic plate decoration material is generally formed by sandwiching a layer of plastic plate between two aluminum sheets, and the defect is that [1] because the middle plastic layer is used outdoors, it will be exposed to the wind. Rain and temperature changes, and severe deformation, and because of the softness of the aluminum plastic sheet, the flatness, the flatness is poor; it is impossible to achieve the mirror finish and smoothness of glass and ceramic products. [2]
  • the surface of the printed stone pattern can only be made of organic materials, it is easy to age and change color, so it can only be used indoors, not for outdoor use;
  • the thickness of the product is 9-15mm; [3] its water absorption rate is large, up to 0.5-0.1%, easy to absorb dirt; [4] the glaze printing of its products due to the firing temperature of 110 ⁇ TC- 1200 °C, so the crystal phase of quartz crystal can not be retained (because it will melt), so its hardness is poor, not wear-resistant; [5] its process determines the energy consumption of its production is particularly large, dust and carbon dioxide, sulfur dioxide The emission is large, the weight of raw materials and finished products is large, and the transportation cost is high, so that the energy consumption of transportation is large, the water resources are wasted, the floor space is large, and the efficiency is low.
  • the production of the products is by water ball milling process and spraying.
  • artificial stone and decorative glass artificial stone has low output and low efficiency, high cost; and the decorative glaze of decorative glass is all organic material, easy to change color, and is not wearable (not used as exterior wall and ground, but tempered Printed pattern Stained glass can not be made of the specified size, can not be cut, the current inorganic glaze pattern glass, can only be used within the glass size of 5cm size Masek, the larger will be due to the 490 ° C annealing of calcium soda glass The point affects its secondary annealing, which will cause bursting, because mass production of inorganic glass glaze below 90 X: is impossible, so the industry hopes that the fine-cut standard of the fine pattern of glass Masek larger than 5cm The appearance of a size product can overcome technical difficulties.
  • the process is expressed as storing small pieces of glass frit in a mold box, so that ... crystallizes from the glass surface into the interior, and the glass frit is fused to each other to control the size of the glass frit... , obtaining a marble, granite-like appearance 9 and this document has a large number of crystallized 3 ⁇ 4 process of the fan of the real frame, it can be seen that the use of particle viscous crystallization of a color pattern of glass ceramics process .
  • the color pattern and opaque product characteristics are obviously not determined by the material composition.
  • the crystal, color and pattern of the product are determined by the surface of each glass particle added to the process described in the application document.
  • Each of its pellets is covered with crystals from the outside to the inside. It is opaque to achieve a good visible light transmittance of 40% - 95%, and it is necessary to overcome these defects.
  • the glass frit is softened and deformed, and melted and integrated into one another, and the precipitated glass crystal conforms to the size and shape of the small glass frit. (See page 7).
  • the insiders know that the main drawback is that the product cloth is loose when it is granulated, so there is a lot of unevenness in the plane of the product after firing.
  • the crystal of this kind of grain like all glass-ceramics, has to grow up.
  • the granules have a surface roughness of 0. 5mm-l.
  • the product plane is very uneven, and the mold frame is fired with refractory material, and the unevenness of the surface and the four corners is The deformation of one firing is getting bigger and bigger, so the thickness difference of the finished products is awake at 1, 5 legs - 2.
  • All products have to be flat and polished on the front and back sides, at least 3 ⁇ 4 to lmm-2 thickness, and After throwing the pros and cons, the thickness difference of the product will reach more than one side, so the defects and waste are large.
  • the difference between the thickness and the thickness of the glass of the present invention and the normal flat glass is very different from that of the internal phase. This defect is also entirely caused by its process, not by the material component, so these defects need to be overcome.
  • the first embodiment of the present invention discloses a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting-color glazed decorative flat glass, and the melting point of the glaze layer of the 10 color of the substrate glass surface is 540 ° C-730 °C
  • the substrate glass of the product is characterized in that: the substrate glass comprises a component of silicon oxide, calcium oxide, magnesium oxide, aluminum oxide, iron oxide and sodium oxide, and the content of boron oxide in the substrate glass is percentage by weight. 8% ⁇ The content of the oxidized iron is 0. 01-5%, the content of oxidized fluorine is 0-2. 8%, the content of magnesium oxide is 8. 1 ⁇ The content of the content of the calcium oxide is 1. 9 times - 4.
  • the content of calcium oxide is 1. 2 ⁇
  • the thickness of the substrate glass is less than 0. 3mm; the water absorption of the substrate glass is in the range of 0-0. 3%; the substrate glass has a flexural strength of 50-180Mpa;
  • the lower limit of the annealing temperature of the glass i.e., the endothermic temperature of the endothermic peak was 550 t: -71 (rC.
  • the substrate glass of the high-annealing temperature and high-strength, high-intensity, high-strength, high-strength, high-strength, high-strength, high-strength, high-strength, high-strength, high-strength, high-strength, and high-strength glaze. 39%.
  • the aging of the titanium oxide is 0. 0003, the content of the titanium oxide is 0. 0003, the content of the titanium oxide is 0. 0003, the content of the titanium oxide is 0. 0003 -4. 9%.
  • a high annealing temperature, high strength, environmentally-friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized by: silicon oxide, calcium oxide, oxidation by weight percentage 01-14% ⁇ The content of cerium oxide is 0. 01-14%.
  • a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a enamel glass characteristic of the product: in terms of weight percentage, the content of alumina is 01 ⁇ 2% ⁇ 0- 0. 01-30%, SiO2: 0. 6 times, calcium oxide: Magnesium oxide is 1. 3- 1. 49 times, sodium oxide is 0.
  • boron oxide is 0- 1%, the content of fluorinated fluorine is 0-1%;
  • the lower limit of annealing temperature of the substrate glass ie, the endothermic temperature of the endothermic peak
  • the viscosity of the substrate glass is l ( 5 (Pa's) ) at a temperature of 1500 ° C- 1640 ° C; temperature at which a viscosity of 101 (Pa.s) of 1450 ° C-1580 ° C; temperature at which a viscosity of 102 (Pa.s) to 1210 ° C -1350 °C
  • the viscosity at a temperature of 10 3 (Pa's) is 107 (TC-1230 ° C; the flexural strength of the substrate glass is 50-18 ° &.
  • a high annealing temperature, high strength, environmentally friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized in that: by weight percentage, the content of alumina is 8-30 %, silicon oxide: 2.0-3.6 times of calcium oxide, calcium oxide: 1.3-1.49 times of magnesium oxide, 0, 01-2% of sodium oxide, 0-1% of boron oxide, and 0-1 of fluorine oxide %; the lower limit of the annealing temperature of the substrate glass (ie, the end point of the endothermic peak) is 610 ° C - 680 ° C; the temperature of the slab glass at a viscosity of 10 5 (Pa.
  • a high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a substrate glass characterized by: 30%, Silica: Calcium oxide is 2.0-3.6 times, Calcium oxide: Magnesium oxide is 1.3-1.49 times, Sodium oxide is 0.01-2%, Boron oxide is 0-1%, and fluorinated fluorine is 0-1%.
  • the lower limit of the annealing temperature of the substrate glass is 61 (TC- 68 (TC; the substrate glass at a viscosity of 10 05 (Pa ⁇ s) at a temperature of 1550 e C-1640 ° C; viscosity was 101 (Pa 'temperature seconds) to 1450 o C-1580 ° C; viscosity temperature at 102 (Pa.s) of 1210 ° C-1350 "C; a viscosity of 10 3 (Pa' s
  • the temperature at time is 108 (TC-123 ⁇ rC; the substrate glass has a flexural strength of 130-180 MPa).
  • a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a substrate glass characterized by: 19%, Silica: Calcium oxide is 2.0-3.6 times, Calcium oxide: Magnesium oxide is 1.3-1.49 times, Sodium oxide is 0.01-2%, Boron oxide is 0-1%, and fluorinated fluorine is 0-1%.
  • the lower limit of the annealing temperature of the substrate glass ie, the endothermic peak starting temperature
  • TC ⁇ TC-68
  • the substrate glass has a temperature of 1500 ° C - 158 at a viscosity of 10 ⁇ ⁇ 5 (Pa's).
  • TC temperature at a viscosity of 10 1 (Pa's) of 1450 ° C to 1520 ° C; viscosity at a temperature of 10 2 (Pa. seconds) of 1210 ° C - 1 to 310 ° C; viscosity of 10 3
  • the temperature at (Pa ⁇ sec) was 107 (TC-11601C; the substrate glass had a flexural strength of 50-145 MPa.
  • a high annealing temperature, high strength, environmentally friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized by: oxygen percentage by weight 5-19,
  • the content of the magnesium oxide is 10. 1-19.
  • the content of the content of the magnesium oxide is 1. 0 times - 1. 6 times
  • the content of the content of the calcium oxide is 2. 0 times - 3. 6 times
  • the content of magnesium oxide is 10. 1-19 9%
  • the content of alumina is 19-39%.
  • a high annealing temperature, high strength, environmentally friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized by:
  • the substrate glass content 1 magnesium oxide accounted for 7-20%, calcium oxide is 1.0 times -1. 8 times the range of magnesium oxide, (D silica is oxidized ⁇ In the range of 2. 6 times - 5. 6 times, the amount of magnesium oxide is 2. 2 times - 3. 8 times the range, 5 alumina is 0. 1-30%, 6 sodium oxide is 0-18%, 7 yttrium oxide is 0-5%;
  • the range of the water absorption of the substrate glass of the product is in the range of 0-0. 001%;
  • the total content of magnesium oxide, calcium oxide and silicon oxide in the substrate glass of the product is 51%-100% by weight.
  • a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting color glaze decorative hand glass is characterized in that: the composite plate of the product is made of a high annealing temperature and high strength.
  • the environmentally-friendly and energy-saving low-melting glaze decorative flat glass (1) and the bonding material layer (2) and the 0.1-lmm or 1-5 female-thick metal sheet (3) are composite.
  • a high annealing temperature, high strength, environmentally friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized by: the content of alumina in the substrate glass by weight percentage 30% or less, the substrate glass has a temperature of 1 to 480 ° C to 16 to 40 ° C at a viscosity of 10 ° ⁇ 5 (Pa. sec); a temperature of 14 10 at a viscosity of 10 1 (Pa ⁇ s) °C-1600 °C; the temperature is 1180 ° C - 1340 ° C when the viscosity is 10 2 (Pa.
  • the temperature is 1040 ° C - 1220 ° C when the viscosity is 10 3 (Pa's);
  • the thickness difference of the glass of the slab is less than 0.3 ⁇ ; the water absorption of the substrate glass is in the range of 0 to 0.3%; the lower limit of the annealing temperature of the substrate glass (ie, the endothermic temperature of the endothermic peak) is 550 ° C - 710 In the range of °C;
  • the substrate glass has a flexural strength of 50-180 MPa;
  • the substrate glass has a coefficient of thermal expansion of 15 (the difference between the two ends of TC-300 °C is 1. 1 part per million. 0 ⁇
  • the difference between the values of the two ends at 550 ° C - 600 ⁇ is 1 part per million. 0 - 2 parts per million.
  • a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass is characterized in that: the surface glaze layer contains 20-70% of quartz crystal or Alumina crystals.
  • a high-annealing temperature and high-strength energy-saving low-melting-color glazed decorative flat glass has a substrate glass characterized by: (1) In terms of weight percentage, the content of the product is: 1 magnesium oxide accounts for 7-20%, calcium oxide is 1.0 times - 1.8 times that of magnesium oxide, and 3 silicon oxide is 2.6 times that of magnesium oxide - 5.6 In the range of doubling, 4 silicon oxide is in the range of 2.2 times - 3.8 times of calcium oxide, 5 aluminum oxide is 0.1-30%, 6 sodium oxide is 0-18%, and 7 cerium oxide is 0-5%;
  • the strain point temperature of the product is in the range of 560 ° C - 720 ° C;
  • the water absorption rate of the product is in the range of 0-0.001%
  • the total content of magnesium oxide, calcium oxide and silicon oxide in the product is 51%-100%.
  • a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting-color glazed decorative flat glass is characterized in that the substrate of the product is broken;
  • the content of the product is: 1
  • the content of calcium oxide is 0.6 times - 2.4 times of the content of magnesium oxide, and the content of 2 silicon oxide is 1.3 times - 5.8 times that of magnesium oxide, 3 oxidation
  • the content of silicon is 1.3 times to 5.8 times of the content of calcium oxide, 4-30% of aluminum oxide, 0-18% of 5 sodium oxide, and 0-20% of 6 cerium oxide;
  • a high annealing temperature, high strength, environmentally friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized by:
  • the content of the product is: 1 magnesium oxide accounts for 7-20%, the content of calcium oxide is 1.0 times to 1.8 times that of magnesium oxide, and the content of 3 silicon oxide is magnesium oxide content.
  • the content of silicon monoxide is 2.2 times -3.8 times of the content of calcium oxide, 0.1-30% of 5 aluminum oxide, 0-18% of 6 sodium oxide, 0-5 of bismuth oxide %;
  • the strain point temperature of the product is in the range of 560 ° C - 72 (TC;
  • the water absorption rate of the product is in the range of 0-0.001%
  • the total content of magnesium oxide, calcium oxide and silicon oxide in the product is 51%-99.9%.
  • a high annealing temperature, high strength, environmentally-friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized by: in terms of weight percentage, the content of the product: calcium oxide is Magnesium oxide is 1.15 times - 1.8 times.
  • the high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has the following features:
  • the content of the product is: 1 Magnesium oxide accounts for 9.1-22%, 2 oxidation
  • the content of calcium is 0.6 times - 2.0 times the content of magnesium oxide
  • the content of 3 silicon oxide is 2.8 times - 5.6 times the content of magnesium oxide
  • the content of 4 silicon oxide is 2.3 times - 3.8 times the content of calcium oxide.
  • 5 alumina is 0.1-30%
  • 6 sodium oxide is 0-18°/.
  • 7 yttrium oxide is 0-5%;
  • the strain point temperature of the product is in the range of 560 ° C - 720 ° C;
  • the water absorption rate of the product is in the range of 0-0.001%
  • the total content of magnesium oxide, calcium oxide and silicon oxide in the product is 51%-99.9%.
  • a high annealing temperature, high strength, environmentally friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized in that: by weight percentage, the amount of alumina in the product is up to 0. -3.8%:
  • the melting process temperature of 10 1 (Pa's) is 1300 °C - 1400 °C; the viscosity is 10 2 (Pa. seconds) of clarification, the bubble discharge process temperature is 1120 ° C - 1260 °C;
  • the molding process temperature with a viscosity of 10 3 (Pascal) is 101 (TO1060 ° C; the flexural strength of the product is 60-100 MPa.
  • a high annealing temperature, high strength, environmentally-friendly and energy-saving low-melting glaze decorative flat glass, the substrate glass of the product is characterized in that: by weight percentage, the alumina in the product is 3.8 - 15%:
  • the melting process temperature of 1 ( ⁇ (Pa ⁇ s)) is 1320 °C-143 (TC; the viscosity is 10 2 (Pa ⁇ s) clarification, the bubble discharge process temperature is 1140 ° C- 1290
  • the flexural strength of the product is 80-130 MPa.
  • a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a substrate glass characterized by: At 23%; the melting temperature of 10 1 (Pa ⁇ s) is 3360 ° C-1550 ° C; the viscosity is 10 2 (Pa ⁇ s) clarification, the bubble discharge process temperature is 1250 ° C - 1430 °C; The molding process temperature with a viscosity of 10 3 (Pa ⁇ s) is 106 ⁇ TO120 (rC; the flexural strength of the product is 100-180 MPa).
  • a high annealing temperature, high strength, environmentally-friendly and energy-saving low-melting glaze decorative flat glass the substrate glass of the product is characterized in that: the substrate glass comprises silicon oxide, magnesium oxide and calcium oxide.
  • the amount of silicon oxide in the substrate glass is 2.1 times - 6.5 times the content of magnesium oxide, and the content of silicon oxide is 1.8 1 - 4.6 times the content of calcium oxide;
  • the thickness difference of the substrate glass is less than 0.3 mm;
  • a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a substrate glass characterized by: by weight percentage, silicon oxide in the substrate glass 5 ⁇ 3. 4 ⁇
  • the amount of the amount of the oxidized magnesium is 2. 4 times - 3. 4 times.
  • the high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a substrate glass characterized by: the content of calcium oxide is the content of magnesium oxide by weight percentage 1.0 ⁇ - 1. 5 ⁇ More preferably 1. 0 times - 1. 6 times, more preferably 1. 2 times - 1. 5 times.
  • the thickness of the substrate glass of the product is 0. 3-1. 8 Sa. The thickness of the substrate glass of the high-annealing temperature and high-strength.
  • a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a thickness of 1. 8-5.
  • a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a substrate glass thickness of 5-20 fflm.
  • a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a substrate glass characterized by: 1-5%.
  • the first embodiment of the present invention provides a method for preparing an environmentally-friendly and energy-saving low-melting-point glazed decorative flat glass with high annealing temperature and high strength, which is characterized in that:
  • Step 1 Various predetermined and indispensable special ranges of sodium oxide, iron oxide, aluminum oxide, and silicon oxide required for the substrate glass component of the article according to any one of claims 1 to 6 a material of an innovative technical solution of a composition of calcium oxide, magnesium oxide, or a composition of titanium oxide, cerium oxide, and a predetermined ratio of specific beads between silicon oxide, calcium oxide, and magnesium oxide, which after mixing and stirring corresponds to The melting temperature of each glass formulation melts to form a controlled viscosity and an optimized low viscosity glass liquid, which is homogenized, clarified, and discharged to form a flowable melt;
  • Step 2 forming the glass by using any one of a float process, a flat pull process, a lattice process, a calendering process, and an overflow process, and a high annealing temperature and high intensity environmentally-friendly and energy-saving low melting point is obtained through a cooling process.
  • a glazed decorative glass substrate glass Step 3: Printing or applying a layer of a colored glaze having a melting point of 540'C-730 ° C of one or two to ten colors to form a decorative layer on the surface of the substrate glass of the molded article.
  • a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a color glaze pattern decorative layer on the surface of the product, and is provided by setting 2-100 sets, each set A monolithic printing unit consisting of 1-10 flat screen printing or roller printers or inkjet printers, in parallel arrangement, high-intensity, high-intensity, environmentally-friendly and energy-saving low-melting glaze
  • the surface of the substrate glass of the decorative flat glass is printed, and the glaze is printed, and then the glaze sintering process is performed, and the surface of the 2-100 product is produced in the same batch product to produce 1-10 colors per piece.
  • Preset different printing patterns or color glaze decorative layers of a high annealing temperature, high strength, environmentally friendly and energy-saving low-melting glaze decorative flat glass products are preset different printing patterns or color glaze decorative layers of a high annealing temperature, high strength, environmentally friendly and energy-saving low-melting glaze decorative flat glass products.
  • FIG. 1 is a high annealing temperature high-strength environmentally-friendly and energy-saving low-melting-point glaze decorative flat glass and a high-annealing high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass substrate according to an embodiment of the present invention; A schematic plan view of the glass.
  • FIG. 2 is a high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass with an embodiment of the invention, which is high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass and a preparation method thereof.
  • FIG. 3 is a high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting-point glaze decorative flat glass and a preparation method thereof, and a high-annealing-temperature high-strength environmentally-friendly and energy-saving low-melting-point glaze decorative flat glass substrate glass embodiment of the present invention
  • the surface layer is a plan view of a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting-color glazed decorative flat glass product of a decorative glaze pattern decorative layer.
  • FIG. 5 is a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting color glaze decorative flat glass and a preparation method thereof.
  • the size of the embodiment is 1220 hidden 2440 mm and the thickness is about 2-5 mm.
  • Brushing the color glaze of the predetermined three color zones to form a surface layer is a high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass product of a predetermined color glaze pattern decorative layer of about 0.1-1 mm thickness Schematic diagram of the section.
  • the surface layer is a high annealing temperature and high intensity environmental protection and energy saving low melting point glaze decorative plate.
  • the glass and the back surface are schematic diagrams of the cross-sectional structure of a new composite sheet which is formed by laminating and laminating the surface of the surface of the surface silicate glaze.
  • the glass, the back side is a schematic diagram of the cross-sectional structure of a new composite sheet with two sides, which are more than 10-30 pieces of aluminum slabs.
  • the surface layer is a high annealing temperature and high intensity environmental protection and energy-saving low-melting color glaze decoration.
  • the back side of the flat glass is overlapped and has a side of the surface silicate glaze decorative glass size each extending more than 10-30 awake aluminum plate, each of the composite composite sheet composed of the composite, on the 10-30 hidden part After the predetermined position is punched, a schematic diagram of the vertical plane structure of the wall nail mounting can be performed. Description of the reference numerals
  • the slashed part indicates the printed first glaze pattern area
  • the crosshair part indicates the printed second color area glaze pattern area
  • the small black dot part indicates the printed third color area glaze pattern area
  • the invention firstly (1) has a novel and creative environment-friendly glass substrate technical solution, which has (2) linear thermal expansion characteristics, a high annealing point, that is, an annealing temperature lower limit (ie, an endothermic peak starting temperature), and a high strength.
  • the characteristics of the glass and (3) are limited to 540 ° C - 73 (the melting temperature of TC (Note: ordinary glass Masek and ⁇ cut glass glaze are at 760 ° C 820 ° C above the melting temperature) color glaze
  • TC ordinary glass Masek and ⁇ cut glass glaze are at 760 ° C 820 ° C above the melting temperature
  • the lower limit of the annealing temperature of the substrate glass is raised from 490 ° CJ of the ordinary flat glass to a minimum of 540 ° C, preferably 600. in ° C or above 6 5 0 ° C or above 700 ° C (Note: only the conventional display glass plate almost alkali borate glasses have this property, but the industry knows that the sub-processes and material factors, market
  • the price is RMB 250,000-300,000/ton, which is 100 times more expensive than the construction of soda glass, which is about 2,000 RMB.
  • the invention is 150 220 higher than the 49 ⁇ TC of the prior art soda glass, and it is very excellent.
  • the thermal expansion linear characteristic that is, the temperature change in the temperature range near the annealing point is extremely small, so one can use a glaze having a melting point of 540 ° C - 730 ° C, preferably 600 ° C - 6 5 (TC or 6 5 0 °C- 7 00 melting point glaze, and this glaze can be produced at a low cost, and the glaze with a melting point below 54 CTC can not be produced, and there are serious environmental problems), since the invention can be annealed
  • the printed fine pattern is sintered under the spot temperature.
  • the invention provides a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass with fine glazed stone pattern, wood grain pattern printing color or monochrome product, and the product can be like the above first
  • the technical standard plates are cut at the same size as the construction requirements.
  • the high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a melting point of 1-10 colors of glaze layer on the surface of the substrate glass at 540 ° C - 730 ° C.
  • the substrate glass of the product is characterized in that the substrate glass comprises a composition of silicon oxide, calcium oxide, magnesium oxide, aluminum oxide, iron oxide and sodium oxide, and the content of boron oxide in the substrate glass is 8%,
  • the content of magnesium oxide is 8. 1%, the content of oxidized fluorine is 0-2. 8%, the content of magnesium oxide is 8.1. ⁇
  • the amount of the calcium oxide is 1. 9 times - 4.
  • the amount of calcium oxide is 1 of the content of magnesium oxide 2 ⁇
  • the thickness of the substrate glass is less than 0.3 ⁇ ; the water absorption of the substrate glass is in the range of 0-0. 3%; the substrate glass has a flexural strength of 50-180Mpa;
  • the lower limit of the annealing temperature of the substrate glass ie, the endothermic peak starting temperature is 55 (TC-710° (.
  • the content of alumina in the substrate glass is 30% by weight or less, and the substrate glass has a viscosity of 10.
  • the viscosity is 102 (Pa ⁇ s); 2.5 (Pa 'temperature during the second) 1480 o C-1640 ° C; viscosity of 101 (Pa' temperature seconds) is 1410 ° C-160 (rC
  • the temperature of the substrate is 110 (TC - 13 - 40 ° C; the viscosity is 10 3 ° C / 1220 ° C; the thickness of the substrate glass is less than 0.3.
  • the water absorption rate is in the range of 0 to 0.3%; the strain point temperature of the substrate glass is in the range of 560 ° C to 720 ° C; the substrate glass has a flexural strength of 50 to 180 MPa;
  • the difference in the coefficient of thermal expansion of the plate glass between 150 ° C and 300 ° C is 1 part per million. 0 - parts per million. 0; the difference in value between the ends of 55 ⁇ TC-600 ° C 1. 1 - 2 parts per million.
  • alumina increases the strength of the substrate glass but increases the melting temperature of the glass and the temperatures at various other viscosities.
  • the substrate glass according to the present embodiment may be added with an appropriate amount of alumina depending on the demand for strength and the temperature at various viscosities. (In addition, in this specification, the percentages of the various components in the substrate glass are percentages by weight unless otherwise specified.) Performance characteristics of the product of the present invention
  • the lower annealing temperature ie, the endothermic peak starting point temperature
  • the lower annealing temperature ie, the endothermic peak starting point temperature
  • the lower limit of the annealing temperature of the substrate glass of the present invention i.e., the endothermic peak origin temperature
  • the lower limit of the annealing temperature of the substrate glass of the embodiment of the present invention is preferably 600 ° C or 650 ⁇ or 65 (TC-70 ⁇ rC is aimed at solving the annealing temperature at a higher temperature) , Sintered glaze, will not appear the existing problem of explosive cracking that has been plagued by secondary annealing of glaze glass production.
  • Former fans existing industrial, architectural glass, such as calcium sodium flat glass, LCD glass, only about 1% or about 1-3% of alumina, and its technical solution is not easy to add more alumina, otherwise it will be The viscosity is too high to be produced, and the strength is only 45-60 MPa.
  • the substrate glass embodiment of the present invention As described in the front viscosity section, it can be known that when the oxidation is added to 20-25%, the viscosity is lower than that of the prior art, and there is a platform with a good range of control. In terms of the strength of the product, the article of the present invention can easily reach 100-160 MPa or 130-180 MPa. o
  • the flexural strength of the glass in the present specification relating to the embodiment of the present invention is obtained by cutting the sample into 50 mm X 5 and let X 5 mm Strips, using a bending strength meter, measured according to the standard GB/T3810. 4-2006.
  • the strain point is high, the linear coefficient of the expansion coefficient is prominent, and the expansion change value is extremely small in different temperature ranges.
  • the coefficient of expansion of the glass according to an embodiment of the present invention is measured in accordance with the standard GB/T 7320. 1-2000. - When the product can be heated or cooled rapidly, especially when the glaze is sintered, there will be no excessive deformation or bursting.
  • the technical solution of the substrate glass according to the embodiment of the present invention can have a better linear characteristic of the expansion coefficient, resulting in a small glass viscoelastic mutation, and the specific thermal expansion coefficient of the product is 150 ° C - 300
  • the difference between the two ends is from 1 part per million to 3. parts per million.
  • the difference between the values at the ends of 550 °C - 600 °C is from 1 part per million to 2 parts per million.
  • the difference between the values of the two ends of the 60 ⁇ TC-650 i for the alkali-free glass is from 1 part per million to 3 parts per million.
  • the difference between the two ends of the thermal expansion system of the prior art calcium sodium float glass and PDP or TFT glass is 550 parts per million, which is 5-16 times better than that of LCD calcium soda glass 550 TC-60 (TC thermal expansion)
  • the difference between the values at the two ends is 20 to 20 times better than 7-20 times.
  • This also provides a use in the glaze pattern sintering process of rapid heating or rapid cooling and the use of fireproofing of building decoration materials. It will have better deformation, stability and no mutation than the existing glass. Burst, a great advantage of the viscoelasticity of the glass when the temperature rises and falls rapidly.
  • the water absorption of the substrate glass according to the embodiment of the present invention is in the range of 0-0. 3%. Further, the substrate glass of the high-annealing-temperature high-strength environmentally-friendly and energy-saving low-melting-point glaze-decorated flat glass according to the embodiment of the present invention can be selected to have excellent transparency characteristics and water repellency.
  • the water absorption of the substrate glass according to an embodiment of the present invention is measured in accordance with the standard GB/T 3810. 3-2006.
  • the thickness difference of the substrate glass according to the embodiment of the present invention is in the range of 0.3 ⁇ .
  • the thickness difference of the substrate glass according to the embodiment of the present invention is measured by the acceptance standard GB/T1216.
  • the formulation and corresponding properties of the sample of the substrate glass under the color glaze layer according to the embodiment of the present invention are listed in Table 1 below.
  • the substrate glass of the invention can be produced at a lower cost than the current alkali-free boron plate glass, and the production efficiency is high under the condition that the lower limit of the annealing temperature (ie, the endothermic peak starting temperature) is not secondary annealing of the glaze glass. Under the conditions of several times (because of the fact that the alkali-free flat glass with the boron condition can only be used in the expensive platinum channel, the production line of 8 tons of tantalum should invest more than 1 billion yuan, and it is also due to boron.
  • the lower limit of the annealing temperature ie, the endothermic peak starting temperature
  • the corrosion of the molten pool in the composition is cold-repaired for three months every year, so it amounts to 250,000-300,000 RMB/ton, and the technical solution of the present invention can achieve the same various qualities, especially the quality intensity can be 1-2 times higher. It is produced by a large p-stage process capable of producing 300 p ⁇ -800 tons. The investment is only 3-4 billion yuan, so the cost is 50-80 times lower.) It can produce high quality and reasonable economic cost. It is not obvious that the properties of the flat glass and the lower limit of the annealing temperature (ie, the endothermic temperature of the endothermic peak), the strength, and the low cost can be solved. This is a flat plate in which the inorganic glaze has never been printed in the prior art.
  • the oxidized iron is 0. 01-5%, the oxide is 0. 01-5%, the sodium oxide is 0. 02-8. 8%, the sodium oxide is 0. 02-8. 8% And the range of the technical solution of the present invention is 1. 2-1. 6 times the range of the technical solution of the present invention.
  • the oxidized magnesium is 1. 2-1.
  • the sample inside, first of all in terms of viscosity, is better than the existing deuteration viscosity at 10 5 (Pa ⁇ s), 10 1 (Pa. sec), 10 2 sec. , homogenization viscosity, are better than the prior art 150 - 400 ° C (refer to compare Table 2 and Table 3).
  • the alumina content is in the case of the oxidized calcium, the oxidized calcium is 1. 3 to 5. 19 Among the better 30%, especially the difference between viscosity and coefficient of linear expansion and temperature index are the best.
  • the samples 1, 2 3, 4, 5, 11 are all within the content of the technical scheme of the present invention, and it can be seen that the viscosity, the strength, the expansion coefficient or the prior art TFT liquid crystal display borosilicate glass, PDP plasma display screen Glass and all the prior art flat glass are good.
  • samples 1, 2, 3, and 4 are examples of the upper limit, the lower limit, and the ratio range of the upper limit and the lower limit of the magnesium, calcium, and silicon ratios of the present invention
  • the samples 1 and 5 are the sum of silicon, calcium, and magnesium.
  • glass products such as ceramic glazed tiles, antique bricks
  • the cost is reduced, and it is expanded to a range of hundreds of times that the transparent glass is not available.
  • the technical effect and the effect of reducing the cost of the main raw materials by about 10 times (the advanced silicon material is ten times higher than the ordinary price) is very obvious.
  • Table 2 lists some of the prior art glass formulations and related properties. As can be seen from Table 2, firstly, the range of boron, iron, titanium, sodium and magnesium contained in the four samples is different from the present invention, and the ratio between silicon and calcium, and between calcium oxide and magnesium oxide is ⁇ 1. The ratio of the content of the present invention is 1. 2 times - 1. 6 times, the ratio of the content of the magnesium oxide is 1. 2 times - 1. 6 times, The silica is 1.9 times -1 times the calcium oxide content, and the silica of these products is completely different than the content of magnesium oxide and calcium oxide.
  • the technical bias has always used silicon as the skeleton of the glass and Melted and refractory matrix, so the viscosity of the melting process, especially at 10 (Pa ⁇ s), 10 Pa ⁇ s, can not be measured with a standard rotary viscometer (because its viscosity is too high) It can be seen that it is difficult to overcome energy consumption in melting, overcome defects and stones, and it is more difficult or more difficult to improve production efficiency.
  • the temperature at normal bubble and homogenization of 10 2 (Pa's) is also 150-300 ° C higher than the sample of Table 1 of the present invention, showing difficulty in discharging bubbles and homogenizing, and
  • the process platform of the invention has the advantages of energy saving and easy control.
  • the invention has great technical and easy control advantages for the forming, the flatness and the thickness difference of the product. Moreover, in terms of product strength, the article of the invention is also 2- to 3 times different in the linear expansion coefficient, especially in the variation of several important temperature zones of the linear characteristics of the glaze or fire-proof viscoelastic value on the glass. There is also a great advantage.
  • the content of alumina is defined as a percentage by weight.
  • Oxide oxide is 1. 0-3. 6 times, calcium oxide: magnesium oxide is 1. 3-1. -49 times, sodium oxide is 0. 01- 2%, boron oxide 0-1%, the content of fluorinated fluorine is 0-1%; the lower limit of annealing temperature of the substrate glass (ie, the endothermic peak endothermic temperature) is 61 ⁇ TC-710 ° C; the substrate glass has a viscosity of 10 ° ⁇ 5
  • the temperature at (Pa ⁇ s) is 1500°C to 1640°C; the temperature at a viscosity of 10 1 (Pa ⁇ s) is 1450°C to 1580°C; when the viscosity is 10 2 (Pa ⁇ s)
  • the temperature is 1210 ° C - 1350 ° C; the temperature at 10 3 (Pa ⁇ s) is 1 O: - 1230 ° C; the substrate glass has a flexural strength of 50-180 MPa.
  • the singularity of the singularity of the singularity of the singularity of the sulphate is 1. 3 - 1. 49 times, the sodium oxide is 0. 01-2%, the boron oxide is 0-1%, the fluorine oxide content is 0-1%; the annealing temperature lower limit of the substrate glass (ie, the endothermic peak starting temperature) is 610. °C-680°C; The temperature of the substrate glass is 1520 - 1640 °C at a viscosity of 10 ° 5 (Pa.
  • the content of alumina is defined as a percentage by weight.
  • the sodium oxide is 0. 01- 2 ° /.
  • the boron oxide is 0-1%, the content of the fluorine oxide is 0 - 1%; the lower limit of the annealing temperature of the substrate glass (that is, the temperature of the endothermic peak) is 610 ° C - 680 ° C; the viscosity of the substrate glass is 10
  • sec. is 1550 ° C - 164 (rC; the temperature at a viscosity of 10 1 (Pa ⁇ s) is 1450 ° C - 1580 ° C; the temperature at a viscosity of 10 2 (Pa ⁇ s) It is 1210 ° C - 1350 ° C; the viscosity at a viscosity of 10 3 (Pa's) is 1080 ° C -123 (rC; the substrate glass has a flexural strength of 130-180 MPa.
  • boron oxide is 0-1%
  • oxyfluoride content is 0-1%
  • the annealing temperature of the substrate glass is lower (ie, the end of the endothermic peak)
  • the temperature is 610 68 (TC; the substrate glass has a temperature of 1500 ° C-158 at a viscosity of 10 ° 5 (Pa.
  • the composition of the substrate glass the content of titanium oxide is 0. 0003-4. 9%.
  • the composition of the substrate glass, the weight of the cerium oxide is 0. 01-14%.
  • the sulphate content is 1. 3 times -1. 6 times, the content of silicon oxide is calcium oxide.
  • the content of the content of the magnesium oxide is 1. 3 times - 1. 6 times, the content of silicon oxide is calcium oxide.
  • the content of the magnesium oxide is 10.1 to 3. 6 times, and the content of the magnesium oxide is 10.1 to 19.9%, and the content of the alumina is 19 to 39%.
  • composition of the substrate glass is limited to:
  • the glass content of the substrate is: 1 Magnesium oxide accounts for 7-20%, 2 oxygen 2 ⁇ The oxidized magnesium is 2. 2 times - 1. 8 times the range, the SiO 2 is 2. 6 times - 5. 6 times the range, the silicon oxide is 2. 2 times the calcium oxide -3. In the range of 8 times, 5 alumina is 0.1 to 30%, 6 sodium oxide is (W8%, 7 yttrium oxide is 0-5%; in weight percentage, the oxidation of the substrate glass of the product thereof
  • the total content of magnesium, calcium oxide and silicon oxide is 51%-100%; its performance is as follows:
  • the strain point temperature of the substrate glass of the product thereof is in the range of 560 ° C - 7 20 ° C;
  • the water content of the substrate glass of the product is in the range of 0-0. 001%;
  • the composition of the substrate glass is limited by weight percentage, and the content of alumina in the substrate glass is 30% or less, and the substrate glass has a viscosity of 1 ((Pa ⁇ s)).
  • the temperature is 1480 ° C - 164 (TC; the temperature is 1410 ° C - 1600 V when the viscosity is 10 1 (Pa ⁇ s); the temperature is 1180 ° C - 13 WC when the viscosity is 10 2 (Pa's); viscosity temperature at 103 (Pa 's) for the 1040 ° C- 1220 ° C; thickness difference in the glass substrate is less than 0. 3mm; water absorption of the glass substrate in the 0-03% by 3 ⁇ 4 around; the.
  • the strain point temperature of the substrate glass is in the range of 560 ° C - 720 ° (: 3 ⁇ 4; the flexural strength of the substrate glass is 50-180 MPa; the thermal expansion coefficient of the substrate glass is between 150 ° C and 300 ° C
  • the difference is 1 part per million. 0- parts per million. 0; the difference between the values at 550 ° C - 600 ° C is 1 part per million. 0 - 2 parts per million.
  • a quartz crystal or an alumina crystal containing 20-70% is applied to the glaze layer of the surface layer of the substrate glass.
  • the thickness of the substrate glass of the product is 0. 3-1. 8mm, the thickness of the substrate glass of the product is 0. 3-1. 8mm
  • a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass has a substrate glass thickness of 1. 8- 20
  • the composition of the substrate glass is limited by weight percentage. 5% ⁇ The content of sodium oxide is 2. 1-5%.
  • the composition of the substrate glass is limited to a weight percentage of sodium oxide of 2. 1-8%.
  • the content of the sodium oxide is limited to a weight percentage of the substrate glass, and the content of sodium oxide is 2. 1-14%.
  • the composition of the substrate glass is limited to a percentage by weight of alumina of 1-19%.
  • the above is the composition and characteristics of the substrate glass of the high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass according to the embodiment of the present invention.
  • the following describes the fabrication of the high annealing temperature and high strength according to the embodiment of the present invention.
  • a high annealing temperature, high strength, environmentally-friendly and energy-saving low-melting glaze decorative flat glass and a preparation method thereof have high annealing temperature, high strength, environmental protection and energy-saving low melting point according to an embodiment of the invention.
  • reference numeral 1 denotes a substrate glass of a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass.
  • the invention discloses a high annealing temperature and high intensity environmental protection and energy-saving low-melting color glaze decorative flat glass and a preparation method thereof, and an environmentally-friendly and energy-saving low-melting color glaze decorative plate with high annealing temperature and high strength.
  • the process of the molding process is to put the predetermined raw materials into the feed bin, and then transfer the raw materials from the feed bin to the molten pool kiln, into the molten pool to melt at a predetermined temperature and discharge the bubbles, and then It is a liquid melt that enters the tin bath (a protective gas station with a nitrogen-hydrogen gas beside the tin bath inputs a protective gas into the tin bath), which is flattened, pulled, and pulled on the tin surface of the tin bath.
  • a protective gas station with a nitrogen-hydrogen gas beside the tin bath inputs a protective gas into the tin bath
  • the melting point of the colored glaze is decorated with the semi-finished glass of the glass of the glass.
  • FIG. 3 is a high annealing temperature and high intensity environmental protection and energy saving low melting.
  • Spot color glaze decorative flat glass and preparation method A high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting-point glaze decorative flat glass substrate glass is formed by a float process.
  • reference numeral 2 denotes a silo feed port
  • numeral 3 denotes a silo
  • numeral 4 denotes a predetermined mixed material
  • numeral 5 denotes a molten pool kiln mouth where the mixed raw material enters the molten pool (predetermined formulation shown by reference numeral 4)
  • the mixed raw material is thus conveyed to the molten pool of the molten pool kiln
  • reference numeral 12 denotes a float line substrate
  • reference numeral 6 denotes a molten pool kiln
  • reference numeral 7 denotes a flow guiding groove in which the liquid molten raw material in the molten bath enters the tin bath.
  • Reference numeral 8 denotes a tin bath of a float process
  • reference numeral 9 denotes a transition roll stage in which a semi-finished strip formed in the tin bath enters the annealing kiln
  • numeral 10 denotes an annealing kiln
  • reference numeral 11 denotes a cutting and dispensing station for slitting the shaped product.
  • FIG. 4 is a high annealing temperature and high intensity environmental protection and energy-saving low-melting color glaze decorative flat glass and a preparation method thereof.
  • the size of the embodiment is 1220 hidden X 2440 mm, and the predetermined three colors are printed.
  • the color glaze of the area forms a surface layer which is a high-annealing temperature high-strength environmental protection and energy-saving low-melting glaze decorative flat glass product of the predetermined decorative layer of the glaze pattern.
  • reference numeral 1 denotes a substrate glass of high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting-color glazed decorative flat glass
  • the oblique line of the numeral 21 indicates the printed first color glaze pattern area
  • the label The 31 cross-line portion indicates the printed second color area glaze pattern area
  • the 41 small black dot portion indicates the printed third color area glaze pattern area.
  • FIG. 5 is a high annealing temperature and high intensity environmental protection and energy-saving low-melting color glaze decorative flat glass and a preparation method thereof.
  • the size of the embodiment is 1220 mm X 2440 mm and the thickness is about 2-5 fine.
  • the color glaze of the predetermined three color regions is formed into a surface layer of a predetermined glaze pattern decorative layer of about 1-1.
  • the high annealing temperature and high intensity environmental protection and energy-saving low-melting color glaze decorative flat glass product Schematic diagram of the section.
  • reference numeral 1 denotes a high annealing temperature and high intensity environmentally friendly and energy-saving low-melting glaze decorative flat glass substrate glass
  • reference numeral 123 denotes an upper layer of glaze which has been printed with predetermined three pattern color glazes. Decorative layer of pattern.
  • FIG. 6 is a high annealing temperature and high intensity environmental protection and energy-saving low-melting color glaze decorative flat glass and a method for preparing the same.
  • the surface layer of the embodiment is a high annealing temperature and high intensity environmental protection and energy saving type.
  • the melting point of the glaze is decorated with flat glass, and the back is a schematic diagram of the cross-sectional structure of the new composite sheet which is formed by laminating and laminating the aluminum slabs of the surface silicate glaze.
  • reference numeral 13 denotes a high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting-color glazed decorative flat glass having a colored glaze layer
  • reference numeral 14 indicates that the overlapping rear side portion is not exceeded.
  • the surface layer has a high annealing temperature, a high-strength, environmentally-friendly and energy-saving low-melting glaze, and an aluminum plate on the side of the flat glass
  • reference numeral 15 denotes a predetermined adhesive.
  • FIG. 7 is a high annealing temperature and high intensity environmental protection and energy-saving low-melting color glaze decorative flat glass and a preparation method thereof.
  • the surface layer is a high annealing temperature and high strength-environmental energy-saving type.
  • the low-melting color glaze is decorated with flat glass, and the back is a schematic diagram of a cross-sectional structure of a new composite sheet composed of two aluminum sheets which are extended by a distance of 10-30 mm from the decorative surface of the surface silicate glaze.
  • reference numeral 13 denotes a high-annealing and high-strength environmentally-friendly and energy-saving low-melting-color glazed decorative flat glass with a colored glaze layer
  • numeral 141 indicates that two sides are overlapped and have a high annealing temperature and high strength.
  • Types of low-melting color glaze decorative flat glass each protrudes an aluminum plate of 1 Q-3Q Peng distance
  • reference numeral 15 denotes a predetermined adhesive.
  • FIG. 8 is a high annealing temperature and high intensity environmental protection and energy-saving low-melting color glaze decorative flat glass and a preparation method thereof.
  • the surface layer is a high annealing temperature and high intensity environmental protection and energy saving type.
  • Low-melting glaze decorative flat glass, the back is a new composite sheet composed of two sides with overlapping sides of the surface silicate glaze decorative glass with 10-30 sides. After the hole is punched at a predetermined position on the 30 mm extension portion, a schematic diagram of the vertical plane structure of the wall nail installation can be performed.
  • reference numeral 13 denotes a high-annealing and high-strength environmentally-friendly and energy-saving low-melting-color glazed decorative flat glass with a colored glaze layer
  • the reference number 1-41 indicates that two sides are overlapped and have a high annealing temperature and high strength.
  • the energy-saving low-melting glaze decorative flat glass each protrudes from the aluminum plate with a distance of 10-30
  • the reference numeral 16 indicates that the aluminum plate of the composite plate has a high annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decoration.
  • the flat glass extends out of the dowel mounting holes in the sides of 10-30.
  • the invention discloses a high annealing temperature and high intensity environmental protection and energy-saving low-melting-point glaze decorative flat glass and a preparation method thereof, and the glass product is produced by a float forming process, and the decorative layer of the colored glaze is printed to form a product, which is further explained.
  • the manufacturing process includes the following steps:
  • the mixture prepared in the step [1] is fed into the molten pool of the predetermined high temperature resistant kiln shown by the number 6 in the temperature zone corresponding to the melting temperature of each glass formulation (
  • the melting temperature may form a liquid melt having a good fluidity at a temperature of 1360 ° C - 146 (temperature of TC or 146 ⁇ TC - 16 8 (in the range of TC), passing through a high temperature zone.
  • the bubbles in the liquid raw material are gradually discharged, that is, a mixed raw material melt having a good fluidity which can enter the molding step is formed.
  • the melt of the mixed raw material having the better flowability of the step [3] is obtained from the molten pool kiln shown by reference numeral 6.
  • the nip of the flow guiding groove indicated by reference numeral 7 flows into the tin surface of the tin bath (also referred to as tin kiln) indicated by the numeral 8 of the float line, and is then flattened and pulled by the edge; And the traction of the tractor, polishing and flattening on the tin liquid surface, forming a semi-finished strip through the transition roller shown in Figure 9 out of the tin kiln, and then entering the annealing kiln of the cooling system of the roller conveyor shown by reference numeral 10, and then cooling Entering the cutting and dispensing station shown by reference numeral 11, after cutting and dispensing, the melting point of the enamel layer of 1-1 0 colors of the surface of the fascia glass of the present invention as shown in FIG.
  • the substrate glass comprises silicon oxide, calcium oxide, magnesium oxide, aluminum oxide, iron oxide, titanium oxide, sodium oxide, in terms of weight percent, the boron oxide content in the substrate glass is 8%, 8%, the content of oxidized fluorine is 0. 01-5%, the content of fluorinated fluorine is 0-2. 8%, ⁇ The content of the content of the calcium oxide is 1. 9 times the content of the calcium oxide.
  • the water absorption of the substrate glass is 0-0.
  • the substrate glass has a flexural strength of 50-180 MP; the slab glass has a viscosity of 10 ° ⁇ 5 (Pa.
  • the lower limit of the annealing temperature of the substrate glass ie, the endothermic peak starting temperature
  • the flexural strength of the substrate glass is 50-180 MPa
  • the difference in the coefficient of thermal expansion of the substrate glass between 150 ° C and 300 ° C is in parts per million. 1. 0- parts per million. 0; values at both ends of 550 ° C - 600 ° C The difference is 1. 1 part per million. 0.
  • the high annealing temperature and high strength of the surface glaze-free pattern shown by the number 1 The substrate glass of the low-melting color glaze decorative flat glass enters the printing position on the conveying line in sequence, and according to the predetermined pattern requirement, the color glaze printing equipment with the predetermined first, second and third color printing pattern plates is sequentially used. , respectively, the white glaze is printed on the printing pattern area indicated by the hatched portion of the smear portion of the printing pattern plate of the first color area to the high annealing temperature and high intensity environmental protection and energy saving low melting point glaze decorative flat glass shown by the numeral 1.
  • Substrate glass surface layer; the dark orange red glaze is printed on the printing pattern area indicated by the cross-hatched portion of the second color printing pattern plate to the high annealing temperature and high intensity environmentally-friendly and energy-saving low melting point color indicated by the numeral 1.
  • the base glass surface of the glazed decorative flat glass; the light orange glaze is printed on the printing pattern area indicated by the small black dot portion of the third color printing pattern plate to the high annealing temperature and high intensity environmental protection shown by the numeral 1.
  • the energy-saving low-melting color glaze is used to decorate the surface of the substrate glass of the flat glass; thus, the color glaze of the color area of the predetermined white, dark orange, and light orange is completed.
  • the thickness of the printed surface of the glaze layer is about 0.1 to 1 in the printing.
  • Orange, light orange red three glaze color zone composition pattern size is 1 220IM1 X 2440 face thickness is 2-5mm, thermal strain overflow point, that is, the lower limit of chasing fire is 55 ⁇ TC-60 ⁇ TC or 600 °
  • reference numeral 1 denotes a substrate glass having a high annealing temperature and high strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass with a surface glaze-free pattern, and a hatched portion of the numeral 21 indicates a printed first color glaze.
  • the material pattern area, the cross-hatched portion of the reference numeral 31 indicates the printed second color area glaze pattern area, and the reference numeral 41 small black dot portion indicates the printed third color area glaze pattern area.
  • the reference numeral 1 indicates a high annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative half-plate glass substrate with a surface non-glaze pattern of about 2 to 5 IM thickness.
  • glass, reference numeral I 23 denotes an upper printed a predetermined thickness of about 0. 1-1 Videos color, dark orange, light orange color region composed of three color pattern glaze enamel decoration layer pattern. Modification 1 of the second embodiment
  • the selection of the method for preparing the substrate glass of the high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting-color glaze-coated flat glass of the second embodiment can also be selected by the following process methods, such as:
  • the flat drawing process is adopted: the formed flowable melt is subjected to the drawing, forming, annealing, cooling and slitting of the flat drawing process, and then the glaze and the knot are applied.
  • ⁇ grid process the formation of the flowable melt by grid process forming, annealing, cooling, slitting, and then by applying glaze and sintering, to obtain high annealing temperature and high strength
  • the environmentally-friendly and energy-saving low-melting color glaze is decorated with the substrate glass of the flat glass;
  • the calendering process is adopted: the formed flowable melt is calendered by calendering, forming, annealing, cooling, slitting, and then applying glaze and sintering to obtain high annealing temperature and high strength.
  • the environmentally-friendly and energy-saving low-melting color glaze is decorated with the substrate glass of the flat glass;
  • the formed flowable melt is subjected to the overflow process, down, forming, annealing, cooling, slitting, and then applying glaze and sintering.
  • a high-annealing high-intensity environmentally-friendly and energy-saving low-melting-point glaze decorative flat glass substrate glass can be obtained by the above process.
  • the substrate glass comprises silicon oxide, calcium oxide, magnesium oxide, aluminum oxide, iron oxide, titanium oxide, sodium oxide, and the content of boron oxide in the substrate glass is 0-3 by weight. 9% ⁇ The content of oxidized iron is 0. 01-5%, the content of fluorinated fluorine is 0-2. 8%, the titanium oxide is 0. 0003-4. 9% 9 ⁇ - 4.
  • the 3% of the water absorption of the substrate glass is 0-0. 3%, the content of the substrate glass is less than 0. 3mm; Inner circle; bending strength of the glass substrate 50-1 let p; the substrate glass viscosity temperature of 10 ° 5 (Pa 's) is at 1480 ° C -1640 ° C; viscosity of 101 (mPa ⁇ The temperature at sec is 141 (rC-160 ⁇ TC; the temperature at a viscosity of 10 2 (Pa ⁇ s) is 1180°C-1340 e C; the temperature at a viscosity of 10 3 (Pa's) is 1040° The thickness of the substrate glass is less than 0.3 mm; the water absorption of the substrate glass is in the range of 0 to 0.3%; the lower limit of the annealing temperature of the substrate glass (ie, the endothermic temperature of the endothermic peak) is the range of 550'C- 710 °
  • the decorative layer of colored glaze on the surface of the product is made up of 2-100 sets of single-piece printing unit composed of 1-10 flat screen printing or roller printers or inkjet printers. Parallel layout method, the surface of the substrate glass of the low-melting glaze decorative flat glass with high annealing temperature and high intensity, and the glaze sintering process, the same In the production of batch products, a high annealing temperature and high-strength environmentally-friendly and energy-saving low-melting color color is produced on the surface of 2-100 pieces of products with preset different printing patterns or color glaze decorative layers of 1-10 colors. Glazed decorative flat glass products.
  • the glaze of the surface decorative layer of the product contains or corundum crystal, or quartz crystal, or alumino-feldspar crystal, or nepheline crystal, or mahosite crystal, or feldspar crystal, or mullite crystal, or Pyroxene crystal, or wollastonite crystal, or wurtzite crystal, or cordierite crystal, or calcium-magnesium olivine crystal, or enstatite crystal, or lithium-containing crystal, or spinel crystal, or rutile crystal .
  • the composite board of the product is made of a high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting color glaze decorative flat glass product (1) and a bonding material layer (2) and a thickness of 0.1-lmm or l-5mm.
  • Sheet metal ( 3 ) composite composition is made of a high-annealing temperature high-strength environmentally-friendly and energy-saving low-melting color glaze decorative flat glass product (1) and a bonding material layer (2) and a thickness of 0.1-lmm or l-5mm.
  • the 2-4 sides of the metal plate on the back surface of the composite board of the product protrudes from the edge of the flat glass product with a high annealing temperature and high strength and environmental protection and energy-saving low-melting color glaze. - 3 ⁇ distance.
  • the high-annealing temperature and high-strength T, energy-saving low-melting color glaze decorative flat glass according to the embodiment of the present invention that is, the fundamental difference from the prior art, is summarized as follows:
  • the novel technical solution of the invention in the field of flat glazed glass is as follows: the melting point of the glaze layer of 1-10 colors of the substrate glass surface is 54 ⁇ TC-730 ° C, and the characteristics of the substrate glass of the product thereof The 9%, the sodium oxide content of the substrate glass is 0. 9%, sodium oxide, the content of the boron oxide is 0. 9%, sodium oxide, the content of the boron oxide is 0. 9%, sodium oxide
  • the content of the oxidizing agent is 0. 01-5%, the content of fluorinated fluorine is 0-2. 8%, oxidation
  • the magnesium content is 9.0.
  • the thickness of the substrate glass is less than 0.3 mm; the water absorption of the substrate glass is in the range of 0-0. 3%; the flexural strength of the substrate glass is up to 50. -180MP;
  • the lower limit of the annealing temperature of the substrate glass ie, the endothermic peak starting temperature
  • TC ° C - 71
  • the invention has a lower annealing temperature (ie, an endothermic peak starting temperature) which is different from the existing calcium-sodium flat glass, and must have a high 550 ° C - 710 ° C property, and can be preferably 600 ° C under economic conditions or
  • the lower limit of the annealing temperature at 650 ° C or 700 ° C ie, the endothermic peak onset temperature
  • the present invention is first of all a combined invention.
  • the first is the color of the 1-10 colors of the present invention.
  • the melting temperature of the glaze layer is selected from the range of 540 ° C to 730 ° C, and the flat glass that must be matched with it has the following new levels of new properties different from those of the prior art flat glass.
  • the present invention discloses that the new properties of the discovered products are transferred to new types of inventions, and also produce unexpected effects (i.e., through various flat glass processing methods, in the use of new flat glass applications, [1] Excellent new adhesive warp and product at different stages of the process, ⁇ 2) Thickness difference, [3] water absorption, [4] flexural strength, [5] visible light transmittance, [6] waviness [7] Linear thermal expansion coefficient characteristics and other new properties of flat glass, new use characteristics).
  • the present invention finds new viscosity reducing temperatures and eutectic properties of products which have never been disclosed in the prior art, viscosity temperature during the melting process, homogenization, defoaming, viscosity temperature during the clarification process, In particular, it controls the flatness or thickness of the waviness, and the viscosity temperature of the process during the drawing process (or polishing in the float process).
  • the technical solution of the present invention and the new properties of the discovered products break the technical bias, and can be invented due to changes in the relationship between the elements of silicon, calcium and magnesium, and the new properties of the products produced in the use of flat glass
  • the sodium content is within 0-1%, it can be 150°C-250°C lower than the viscosity temperature of several process stages of the prior art high-sodium flat glass, which will generate a lot of energy saving and benefit the high-quality shield control product thickness.
  • 5-1. lmm LCD display such as 0. 5-1. lmm LCD display, such as 0. 5-1. lmm LCD display, such as 0. 5-1. lmm LCD display, such as 0. 5-1. lmm LCD display
  • the quality of ultra-thin flat glass reduces defects, stone rate, bubble rate, reduced unacceptable thickness and unacceptable waviness.
  • the present invention provides a viscosity adjustable range that is technically advantageous for handling the process. It fundamentally solves the technical problem that the current sodium (high sodium) flat glass "material short” product nature (that is, the "material” in the industry) has been considered by the industry.
  • the viscosity temperature control of each process stage can be controlled, and the lower limit of the annealing temperature of the substrate glass (ie, the endothermic peak starting temperature) can be achieved to a technical effect of 600"C-730 o C.
  • the technical solution of the present invention and the discovered new nature break the technical bias, and can be invented due to the change of the relationship between the elements of silicon, calcium and magnesium.
  • new product properties are produced without boron oxide.
  • the annealing temperature lower limit of the substrate glass ie, the endothermic peak starting temperature
  • the viscosity temperature of the product is 250 °C-350 °C lower than several process stages of the flat glass without alkali borosilicate glass, which will form a large-scale drawing process to achieve a new technology platform to control product quality.
  • it can achieve a higher level of thickness difference, waviness level and almost no bubble, flawless point, no stone defect quality requirements 0. 5- 2 to make the thickness of the ultra-thin product yield excellent Rate especially for the stage of bubble extraction and clarification homogenization process and forming
  • the viscosity of the thinner process stage provides a much better process control range and process control platform than the prior art.
  • the proportional relationship of the silicon, calcium and magnesium elements of the present invention changes the technical solution of the invention, overcoming the prior art technique bias of increasing the annealing temperature lower limit (i.e., the endothermic peak starting point temperature) only by increasing the aluminum or boron component.
  • the lower limit of the annealing temperature ie, the end point of the endothermic peak
  • the lower limit of the annealing temperature when the amount of the shot is less than 2% (ie, There will be a greater increase in the endothermic peak temperature (see attached sample example).
  • a further technical effect of increasing the lower limit of the annealing temperature i.e., the temperature of the endothermic peak
  • the annealing temperature i.e., the temperature of the endothermic peak
  • (C) one of the above-mentioned elements of the present invention which has a sodium content of 13% in a calcium-sodium flat glass which accounts for 99% or more of the total amount of flat glass, omits the invention to produce a substrate glass
  • the lower limit of the annealing temperature ie, the endothermic peak onset temperature
  • TC is preferably 650 ° C - 68
  • the lower limit of annealing temperature of all flat calcium sodium glass ie, endothermic
  • the peak temperature of the peak is only 490 ° C.
  • the lower limit of the annealing temperature of the non-alkaline or only 0.
  • 01-1% of sodium) boron-free flat glass of the present invention ie, the endothermic peak endothermic temperature
  • the endothermic peak endothermic temperature is 610 °.
  • C-71 (TC) because the magnesium according to the technical solution of the present invention is at least 8.1% (generally up to 12-18%), and the minimum calcium is 9.6% (generally 15-18%).
  • the composition is a substrate.
  • the reason why the lower limit of the annealing temperature of the glass (i.e., the endothermic temperature of the endothermic peak) is greatly increased is 120 V-200 V higher than the lower limit of the annealing temperature of the conventional conventional plated soda lime glass (i.e., the endothermic peak endothermic temperature).
  • the third option is to use the existing glaze with a melting point of around 490 °C (Note: Tile glaze melting Point at 95 (TC-120 ⁇ TC or so), such as the production of normal cups, small lines of decal products on the bottle, the extremely small area of the use of the barge is extremely high, it is impossible to use a lot, no large area of decorative materials, large output Economical, so there are no examples of applications.
  • the fourth option is to use the existing alkali-free boron flat glass, that is, due to the glass of the liquid crystal display, the production cost of the prior art is extremely high, the current market price is about 300,000 yuan / ton, if 0. 7MI
  • the thick enamel should reach 600 yuan / m 2 , PDP plasma glass 1. 8-2.
  • the annealing temperature of the glass that is, the endothermic peak starting temperature
  • the cost of the glass is simply impossible to have a substrate as a decorative material, instead of ceramic tiles, Even the economic viability of the highest-end ceramic tiles.
  • the above-mentioned boron-free and alkali-free element of the present invention omits the newly discovered annealing temperature lower limit (i.e., the endothermic peak starting temperature) of the invented flat glass to 60 (rC-73 (TC, and can be as described above).
  • the glass substrate of the present invention can be produced by economical feasibility of 600 ° C-73 (rC color glaze) for combination production. So this is An unsatisfactory technical effect solves the problem of replacing ceramic tiles, and solving the existing decorative materials that people have long been eager to solve without solving.
  • the prior art flat glass such as sputum, only increases the amount of calcium and magnesium, instead of having the silicon of the present invention, the mutual proportional relationship between calcium and magnesium is more than the prior art is to increase the calcium and magnesium content.
  • the viscosity temperature is still higher than the 150 ° C - 300 ° C of the present invention, and, for example, the alkali-free boron flat glass, which is added with 8-15% of the flux boron component, only 8-10% of the alumina is added.
  • the temperature of the defoaming process is as high as 1500 ° C or higher.
  • the present invention is boron-free, sodium-free, and fluorine-free (ie, 0-1%), alumina.
  • alumina boron-free, sodium-free, and fluorine-free (ie, 0-1%), alumina.
  • the viscosity temperature change of the present invention is only about 30% of alumina.
  • the viscosity temperature also rises by only about 80 °C (see the 11 sample examples in Table 1).
  • the viscosity temperature is 100 ° C - 200 ° C lower than that of a flat glass product to which 13% sodium oxide or 8-15% boron trioxide is added.
  • the invention can increase the alumina content by 19-28%, the strength can reach about 10-160 MPa or 180 MPa, which is much higher than 2-3 times of the strength of various prior art flat glass, and the viscosity temperature is from the sub-viscosity.
  • the present invention can produce a flexural strength of 90-145 MPa or 145-180 MPa when it has a high aluminum content and a boron-free content, and has a process range of more energy saving, lower cost, and greater viscosity temperature.
  • all the glazed flat glass can't be made, and the invention can also control the melting during the viscosity temperature stage of the melting process, overcome the stone and prevent the occurrence of defects which are not melted, and the thickness difference of the flat glass during clarification and control molding (because The lower the viscosity, the softer and more controlled the flat glass product in this process stage.
  • the process of controlling the thickness and the wave is controlled by the process of flattening, thinning and polishing.
  • the discovery and production of this new product property enables the invention of the combination with the colored glaze layer to produce 1- 2 leg thickness of the strength of the wall product and 2-3fflm thickness of the invention of the ground product, the current standard of the national ceramic wall hanging board 12 thick products and various other 10 thick floor products High-strength, light-thinning alternatives that produce energy, resources, logistics, and warehouses are several times the unpredictable effect of saving workers.
  • the alkali-free borosilicate glass of flat panel display can be added without 8-15% boron component, and the bubble rate is high, flatness, thickness difference, waviness
  • the product quality barrier can solve the technical bias of the prior art alkali-free boron glass production equipment that can only use the overflow process plus the platinum channel. The highest is that the float process can be used to ensure the thickness difference. Under the premise of flatness and waviness, it can increase production efficiency by dozens of times, save investment by several times, and save 20 times of the unexpected effect of the land plant.
  • the cost is greatly reduced, and it is a combination invention of the colored glazed flat glass of the present invention, and the lower limit of the annealing temperature (ie, the temperature of the endothermic peak) can be the same as the prior art alkali-free boron display glass. Underneath, the new properties of the base glass for the glaze are produced, thereby greatly reducing the cost and producing unexpected effects of the unpredictable technical feasibility of the technical basis.
  • the conventional technology considers that the raw material with a high iron content affects the blue-green defect of the glass, but the invention can increase the strength by 2-3 times in the flat glass, so the thickness can be 2-3 times, and the light transmittance will rise.
  • the greenness of the blue is less obvious, and does not affect the use of transparent and upward glazed glass.
  • the color glaze is facing up, it is possible to use a high-speed iron material with a large amount of 100 times, and it does not care about transparency, and it can save various medium-level raw materials and resources of glass, and greatly save costs. Therefore, the combined invention is a glazed flat glass product capable of producing an unexpected combination of light, thin, high-strength, large-saving glass high-end resources and saving raw material cost.
  • the flexural strength property of polyaluminum oxide, and the expected antimony component which can be added to the flat-plate alkali-bored glass guarantees the quality of the product with high bubble quality, flatness, thickness difference and waviness.
  • solve the prior art alkali-free borosilicate glass production plant can only overflow method process plus platinum-channel instrument Nissan 6-8 tons of process technology bias, but most can employ 400-800 tons produced in said large - Tuen
  • the production efficiency can be increased by several times and the economy can be saved. The investment is dozens of times, saving 20 times the unexpected effect of the land plant.
  • the technical solution of the present invention has new properties that have never been revealed and disclosed, and this property cannot be speculated beforehand, cannot be predicted and reasoned, and overcomes the tradition.
  • the technical bias of flat glass technology solves the above-mentioned major problems that people are eager to solve in the industry.
  • the technical effects have produced changes in both "quality” and "quantity”, indicating that the technical solution is non-obvious and has outstanding substantive features. , with significant technological advancement and creativity.
  • the printing glaze layer can be sintered, and a large amount of various crystals such as 30-80%, especially low-cost quartz or steel jade crystals, can be added to the glaze layer. Powder or granules, forming an unprecedented hardness of 0. 2-3 ⁇ wear-resistant surface (quartz up to 7 hardness, and steel jade can reach 9 hardness), which can not be done in ceramic production, Because the firing temperature of ceramics is between 1100 °C and 1200 °C, the stone or steel jade of the ceramic surface can only be used as the glass phase. ⁇ At 730 °C, the crystals of quartz or steel jade crystals remain.
  • the glaze combination of polished and wear-resistant products, and the 9-grade hardness of steel jade can not be polished, but can unexpectedly become the best durable non-slip or wear-resistant steel jade glazed combination invention, so the invention can form Alternative energy-saving, low-cost, high-quality wear-resistant upgrade technology. It also offers alternatives to the ceramic industry's high energy consumption, high pollution, high dust emissions, high water consumption, low output, low quality products and the entire equipment process system. Challenge.
  • the present invention can be made to have an ultrathin thickness of 0.5 to 5, and in the state of surface stress treatment without tempering, an ultrathin having a flexural strength of 50 to 180 MPa, preferably 90 to 145 MPa or 145 to 180 MPa.
  • the 2-4 sides of the metal plate of the bottom surface of the composite sheet to be overlapped with the surface layer, the high annealing temperature, the high-strength, the environment-friendly and energy-saving low-melting glaze, the edge of the decorative flat glass is extended by 10-30 Distance, the easy installation of the innovative wall application that is directly nailed into the wall or fixedly mounted with the wall dragon skeleton after punching the extended edge, so that the breakage rate is greatly reduced. Reduced, there are new product properties reproduced with good unexpected technical effects.
  • the thickness of the substrate glass of the product is 0. 3-1. 8 hidden. It is particularly light and thin, especially suitable for wall use, which is particularly energy efficient and has a high output rate.
  • the present invention relates to a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting glaze decorative flat glass, and the thickness of the substrate glass of the product is 1. 8- 20 legs. High strength, suitable for the ground, especially large The outer wall of the board uses the product.
  • the invention relates to a high-annealing temperature and high-strength environmentally-friendly and energy-saving low-melting-color glazed decorative flat glass, wherein the product has a highest strength when the content of the substrate glass is 19-39%, especially Special products for high strength requirements.
  • Ceramic tile products are used in the wall market every year for 3 billion ri.
  • the thickness of the product is 8-15 mm
  • the interior wall is 8-10 mm
  • the outer wall is 12-15 mm.
  • the product of the printed pattern (regardless of a single color or 2-10 colors) of the present invention can be made into a product of 0. 5-1. 5mm, which can make the ceramic brick wall product 6 to 10 times lighter and thinner.
  • the ceramic tile product market has an annual market of approximately 100 million users. However, the thickness of its products is 9-12mm.
  • the color glaze printing pattern of the present invention (regardless of monochrome or 2-10 colors) has three times the strength, so that the same strength is obtained as long as 3- 1 ⁇ 2 m.
  • the transparent glass side is placed on the surface, and the effect of printing the glaze pattern on the back is equivalent to the existing glazed tile (adding a transparent glaze on the surface of the ceramic pattern, and then polishing to form a glass glaze).
  • the invention forms a layer of glaze on the surface of the glass, which is equivalent to ceramic antique bricks, and has an annual output of about 3 billion n.
  • the surface of the glass of the invention is sintered at a low temperature to form a layer of colored glaze containing crystals such as quartz, and then polished, which is equivalent to the polished ceramic tile of the present invention (but the quartz content crystal of the invention reaches 50%-60%, wear resistance)
  • the hardness and antifouling performance are much better than ceramic polished tiles.
  • the product of the invention described above can be 6 times thinner than the wall tile and can be 3 times thinner than the floor tile.
  • the invention can make the building decoration ceramics 10 billion m 2 per year and grow at a rate of more than 10% per year, saving 70%-80% of raw materials in the production process, saving 70%-80% of energy, and reducing carbon emissions by 70%-80. %. (According to the calculation, if the global process equipment changes according to the float process of the present invention, the energy consumption of the three Yangtze River Three Gorges power stations will be saved)
  • [2] because it can produce large-sized thin plates such as 2400 X 1200mm or 3000 1800mm, it can also replace many aluminum plates for wall and decoration or aluminum-plastic plates of standard size, saving aluminum resources, and the resources of the invention are higher than aluminum.
  • the resource reserves are 10,000 times more, the cost is much lower, the products are more resistant to corrosion, the ⁇ is flat and sturdy, and the pattern decoration expressiveness can print all the patterns of stone and wood grain.
  • the invention is also convenient and low in cost compared with ceramic plates, slate, aluminum plates and aluminum-plastic plates in the wall mounting method.
  • [3] because of the strength and guaranteed performance conditions, it can be used in all kinds of ceramics and glass, and can be designed with wood grain, stone grain and color of 1 - 2mm thickness for Europe and America.
  • the veneer on the outer wall of the wooden structure of the houses of Australia, Russia, East Asia and South Asia, the non-load-bearing wall surface instead of the transfer and cement is high-grade, fire-proof and resistant to the sun, rain and snow, and
  • the use of the beautiful and light waterproof effect on the wall of the wooden structure upstairs also has new use value.
  • the lower limit of the annealing temperature of the substrate glass is preferably increased to 60 (TC or 650 ° C or 7 consult 30 ° C, 15 Dt higher than that of the calcium soda glass).
  • TC or 650 ° C or 7 Conduct 30 ° C, 15 Dt higher than that of the calcium soda glass.
  • TC or 650 ° C or 7 Conduct 30 ° C, 15 Dt higher than that of the calcium soda glass.
  • e C because of its very good linearity of thermal expansion, that is, the temperature change in the temperature zone near the annealing point is extremely small, so one can use a glaze with a melting point of 54 ⁇ TC-730 °C (this Glaze is different from 480 A glaze below °C, which can be produced at a low cost, and which has no environmental problems, sinters the printed fine pattern at the annealing point temperature.
  • the invention forms the convenience, high efficiency and low cost of the whole process of standard size ordering, production, supply, sale, logistics and cutting construction.
  • the present invention can be 2 to 3 times higher than the strength of about 50 MPa of the calcium-sodium flat glass and ceramic plates and bricks of the prior art, it is preferably 90-145 MPa or 145-180 MPa. Therefore, the product can be made 2-3 times, and has the same strength. In particular, instead of ceramic products, this is not available in all existing glazes or tempered glass.
  • the printing glaze layer can be sintered, "5 ⁇ to add a large amount of quartz powder or corundum crystal powder or granules such as 20-65% in the glaze layer. , the formation of the previous example of 0.
  • the decorative glass materials of the prior art are compared with the decorative glass of the present invention: 1.
  • the annealing point of the ordinary calcium soda glass is about 490 ° C, it is technically impossible to mass produce the glaze below 540 ° C (one must introduce a large amount of lead) Very toxic, two are extremely costly, three are not likely to be large), so they can only be printed on glass Boss below 5cm (because their size is very small, it is not easy to burst during annealing), so history - from the history No large-sized printed inorganic glazed glass sheets were produced.
  • the tempering technology is used to melt the glaze above 750, and the strengthening process is used to solve the annealing stress problem.
  • the size of the product is specific and cannot be cut. In the decoration engineering application, it cannot meet the requirements of the convenience characteristics such as the application construction and matching of the popular standard board.
  • the strength of the calcium soda glass is poor, it cannot be used as a ground application, and there is a defect that the edge is sharp and unsafe after being damaged.
  • High-precision printing glaze pattern including stone grain, can be produced with unprecedented high yield, low energy consumption, 3 ⁇ 4 value, high strength, light weight (0. 5- 3mm thickness), standardized size, 2400 1200mm. 3000 x 1800mm , wood grain, all kinds of high-grade carpet patterns (this is simply impossible to do with existing ceramic and decorative glass technology).
  • the printing glaze layer can be sintered, and a large amount of various crystals such as 30-80%, especially low-cost quartz or steel jade crystal powder, can be added to the glaze layer. Or granules, forming an unprecedented hardness of 0. 2- 3 ⁇ wear-resistant surface (up to 7 or 9 hardness), especially quartz or steel jade after 540 ° C to 70 (TC burning, will be very white This can also be the first ground-based application of the ultra-white hardness of 7-9 grades with zero water absorption, and the surface layer containing quartz crystal can be polished to wear. Products, non-polished products containing steel jade surface layer can be the best non-slip wear-resistant new functional decorative material products.
  • the invention is unprecedented, because the firing temperature of ceramics is between 1100 °C and 1200 ° (:, at this time, the quartz or steel jade of the ceramic surface can only become a glass phase, which becomes brittle, becomes non-wearable, and becomes transparent. The effect of the surface is impossible to super white; but in the present invention 54Q°C-73QX is burned into the temperature zone, and the quartz can maintain the crystal phase, which can form an unprecedented decorative glass-polished quartz crystal surface layer, wear resistance and zero water absorption rate on ceramic or stone or decorative glass surface.
  • the skin print cloth crystal layer products, the prior art article of Comparative artificial stone of the present invention the low yield and effectiveness, high cost, which is not a raw said production line only 2 00- 3 00 m 2, and
  • the daily production of the float line process plus the secondary firing process can reach 30,000-80,000 m 3 .
  • the existing aluminum-plastic panel decoration material, and the aluminum-added composite panel of the invention can overcome the use of the outer wall due to the expansion and contraction of the plastic panel after the sun is severely deformed and the pattern printing is an organic material, so it cannot be used as an outer wall. defect.
  • the aluminum-added composite board of the invention has the advantages of fine pattern, never fading, excellent flatness, and the same ease of installation as the aluminum-plastic board, the cost is greatly reduced, and the work efficiency is greatly increased.
  • it is also possible to use the skeleton of the dragon to be more convenient, save a large amount of installation materials and man-hours, directly fix it on the wall with expansion nails, and then glue on the side seams to form a dry hanging decoration effect of the stone.
  • all the prior art ceramic and decorative glass technologies have never disclosed or paid attention to the above technical solutions of the present invention and substantial technical effects which are not obvious.
  • the invention is particularly 0. 3 legs - 1. 6mm ultra-thin thickness product, used for countertops, kitchen panels, pull facades, furniture veneers, good strength, high hardness , ultra-thin, ultra-light, good wear resistance, good pattern effect, good flatness, good corrosion resistance, waterproof and moisture-proof layering, flame retardant, safety, environmental protection and other comprehensive advantages.
  • Equipment technology especially the high energy consumption, high pollution, high water consumption, such as water ball milling process, spray process, ceramic press process, polishing process, etc.; also due to the innovation and maturity of the process, the strength is ceramic 2-3 times (ceramic is 50MPa, the product of the invention can reach 130-160MPa), can produce ultra-thin products with only 2-2. 3mm thickness, can replace the modern building ceramic plate can only produce the process with the thinnest thickness of 6 ⁇ The products (the modern mature technology mass produced tiles are 9-15 Sa thickness products).
  • the process of the present invention can be: for modern ceramics: 1 energy saving [oil, electricity, coal] up to 60%-80%;
  • the product is only 2-5mm thick, more than the traditional process to polish and wear 1mm thickness of 10mm modern ceramic products, saving raw materials 50-80%; 3 water saving up to 80%; 4 GDP carbon dioxide emissions reduced by 60-80%; 5
  • the packaging cost can be saved by more than 50%.
  • the present invention is not only a technical solution that can be formed by simple logical reasoning or simple experiment, but the technical effect is not a technical effect that can be easily seen. And this is exactly the last ten to twenty years, thousands of companies in the global architectural decorative glass industry, architectural decorative ceramics industry, decorative board industry and hundreds of thousands of technicians are researching and solving problems that have not been solved.
  • the technical solution of the present invention solves the problem of attaching a colored glaze having a melting point of 540 ° C to 730 ° C on a glass substrate; having a predetermined special range of sodium oxide, iron oxide, aluminum oxide, silicon oxide, and oxidation
  • An innovative technical solution for calcium, magnesium oxide, or a composition of titanium oxide, cerium oxide, and a predetermined ratio of specific ratios between silica, calcium oxide, and magnesium oxide overcoming various conventional compositional solubilization components and The technical prejudice of the eutectic composition, and can produce the helpless or eutectic function that is not available, and the product A has a 1-3 times increase in strength A, environmental protection, energy saving and other technical effects;
  • the present invention can produce practical environmental protection, a large amount of energy saving, reduce carbon dioxide emissions, and make various flat glass products light and thin, especially relatively high alkali-free.
  • the above-mentioned unexpected technical effects overcome a variety of prior art biases, especially in the case of low boron, low aluminum (if the content is below 1-2%), the annealing temperature can not rise, especially the
  • An updated technical shield of the lower annealing temperature of the glass ie, the endothermic temperature of the endothermic peak
  • the viscosity temperature, strength, thickness difference and newly discovered flux or eutectic properties of the new product melting, foaming, clarification, homogenization, forming and drawing are generated, and the resulting The product can increase the alumina content to increase the strength by 1-2 times, and these products can also be combined in the production of glaze products, and the melting and tempering of the special beads.
  • the glaze cuts have produced a multi-layer invention combined with a combination of inventions that can not be speculated, unpredictable and reasoned in advance, resulting in a "quality” and “quantity” of technical effects.
  • the changes in the description indicate that the technical solution is non-obvious, with outstanding substantive features and significant technological advances, so the present invention is inventive.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Description

彩釉平板玻璃及其制备方法
技术领域
本发明涉及用于尤其是先有技术的装饰玻璃， 以及替代陶瓷板、 陶瓷砖 以及铝塑板、 装饰塑料贴面板、 含树脂人造石板， 以及用于内外墙、 地面以 及台面板、厨拒面板等家居及工程应用中的各种装饰板材料的有预定的必不 可少的特别范围内的氧化钠、 氧化铁、 氧化铝、 氧化硅、 氧化钙、 氧化镁、 或还有氧化钛、 氧化钡的成份以及预定的氧化硅、 氧化钙、 氧化镁之间的特 殊比例关系的成份的要素比例关系变化发明和对硼或钠成份的省略发明技 术方案等多种创新技术方案，克服了各种传统的必须用大量的钠或硼成份来 组成助溶成份和共熔体成份的技术偏见 [占现有平板玻璃总产量 99. 9%的钠 钙玻璃的退火温度下限（即吸热峰起点温度）仅为 49(TC ]， 并能产生预料不 到的在低钠、 无硼的成份中来经济性的、 低成地生产彩釉玻璃的高出现有技 术退火温度下限（即吸热峰起点温度） 5(TC-200°C可优选高出 IWC- O 的基板坡璃， 又比现有的唯一的虽然具有高退 温度下限（即吸热峰起点温 度）的平板玻璃充碱硼玻璃技术方案的玻璃， 但成本高出现钙钠平板玻璃达 80-100倍的产品，可见只有本发明才具有制作彩釉玻璃装饰材料的成本经济 可行性； 并且本发明强度能上升 1-3倍， 使一种高退火温度高强度的环保节 能型的低熔点彩釉装饰平板玻璃及制备方法能具有真正大生产的可控成本、 又可保障在退火点以下进行釉料烧结而有正常不破裂之成品率的无先例的 二者兼有的技术性质。 背景技术
现代墙地面装饰材料板或砖的种类多， 但都有各自的重大缺陷， 如: ( 1 )、 普通钙钠玻璃及装饰玻璃和玻璃玛赛克的主要缺陷在于， [1]其 因膨胀系数不具有线性变化特征， 所以变化差值大， 退火点下限即吸热峰起 点（一般为 490Ό左右）， 由于业内人士都知道， 很难制成低于 490°C的熔点 的无机釉料， 又由于如果用高于 49(TC的无机釉料来印刷装饰图案， 将会产 生玻璃制品的变形，尤其会产生二次退火工艺极不易控制而出现极大有爆 -裂 率，： 业内人士也知道， 在应变点温度左右， 玻璃会产生急剧变化的膨胀， 这 是现在一切钙钠玻璃根本不能形成精细的可应用的无机釉烧结的图案印刷 品的主要技术障碍。 从而只能做尺寸极小的玛赛克制品（极小的 5cm以下 寸， 才不会因退火不好而产生爆裂）； [2]而且现在只能用于单色的钢化印刷 玻璃（可以用形成表面张力来克服退火出现的问题）。 而现在技术钢化制品 是不可以作成如 2400 1200mm等各种标准板来在最终用户手中可任意切割 为其它尺寸的； [3]现有彩釉钢化玻璃和一切玛赛克玻璃的釉料的熔点都在 T60V-S20V , 因为要适应玻璃钢化时已软化有点变形的温度和玛赛克玻璃 软化使用边角变圆， 这是公知的技术； [4]其硬度和耐磨性很差， 强度仅为 45-50MPa 左右， 也不能用来作家居及工程地面使用； 〖5] 其 度为 10° 5 (帕 ·秒）和 101 (帕 ·秒）溶化蕰度， 采用美国 ΪΗΕΪΑ旋转高温粘度计根 本测不出， 只能测出粘度 101·5 (帕 ·秒）时的温度约为 1580 的熔化温度， 所以生产中有不易熔， 能耗大的缺陷 （每公斤的熔化及成型能耗达 1500大 卡）； [6]防火效果差， 易爆。
( 2 )、 现有的铝塑板装饰材料， 其一般由二层铝簿板中间夹一层塑料板 形成， 其缺陷在于， [1]由于中间的塑料层在户外使用会因风吹日晒雨淋及 温差的变化， 而产生严重变形， 而且由于铝塑料板软、 簿， 平直度、 平整度 差； 完全不可能使之达到如同玻璃及陶瓷制品的达镜面平整和光洁度。 [2] 其表面印刷石紋图案的只能用有机材料， 就必然易老化、 易变色， 所以只能 是室内应用， 更不能作户外使用；
( 3 )、 装饰塑料类贴面板， 其缺陷在于， [1]不可能作图案达镜面平整 和光洁度； 〖2]不可能作地面， 因其不耐磨； [3]没有防火阻燃效果； [4]产 品绝不能作户外使用， 不然极易老化， 极易变形。 所以不管用于装饰工程贴 面或家装工程或木质家俱贴面， 都有严重缺陷。
( 4 )、 陶瓷板及陶瓷砖， 其缺陷在于， 〖1]现在的一切陶瓷板， 由于采 用含粘土的挤出或庄制成坯再千燥或烧成工艺， 量产不可能生产 0. 3mm-i. 6mm或 2-3mm超簿化制品， 而且量产尺寸只能作到 1800 900mm (5-6) mm, 不可能生产 2400 χ UOOmm χ Q-3)麵或 3mm尺寸以上的产品； [2] 而且其制品强度不到 50ΜΡέ， 在施工及运输过程中易损， 而 99. 99%的陶瓷砖 产品的厚度都为 9-15mm; [3]其吸水率较大， 达 0. 5-0. 1%， 易吸污； [4]其 制品釉面印花时由于烧成温度达 110{TC-1200 °C ,所以不能保留石英晶体的 晶相（因其会熔掉）， 所以其制品硬度差， 不耐磨; [5]其工艺决定了其生产 的能耗特别大，粉尘及二氧化碳、二氧化硫的排放大，原料与成品的重量大， 运输成本高，使得运输的能耗都^ ί艮大， 水资源浪费大， 占地面积大， 效率低， 其制品生产是采用水法球磨工艺、 喷雾塔工艺、 陶瓷压机工艺、 水法抛光以 及磨边工艺等组成的现代陶瓷生产的装备系统进行生产的， 其能耗大、 粉尘 及污染气体排放大、 耗水高， 所以在全世界倡导绿色经济、 节能环保、 低碳 经济的今天， 这种传统装备系统下的陶瓷制品的生产工艺， 有着很大的局限 性和缺点， 有急需新发明产品的升级替代。
( 5 )、 天然石材， 其缺陷在于， 【1】不环保， 有放射性元素； 〖2Ϊ重量大， 尤其在外墙应用中， 按规范须 25薩以上的厚度才能作墙面千挂使用； [3]高 档天然石资源日益减少。
( 6 )、 人造石和装饰玻璃， 人造石的产量及功效低， 成本高； 而装饰玻 璃的图案釉全部为有机材料， 易变色，极不耐磨（不可作为外墙和地面使用， 而钢化的印刷图案彩色玻璃不能作指定尺寸的制品， 不可切割, 现在的无机 釉图案玻璃， 也只能作 5cm尺寸以内的玻璃玛赛克， 作大一点就会因钙钠玻 璃的 490°C左右的退火点影响其二次退火， 会产生爆裂现象， 因为低于 90 X：的无机玻璃釉的批量生产是不可能的， 所以业界都希望大于 5cm的玻璃玛 赛克的精细图案的可任意切割的标准尺寸的制品出现能克服技术难题。
( 7 )、 另外， 现有 种公开号为 CN 1053047A的 "具有天然大理石状表 面花紋的结晶玻璃及其生产方法"专利申请， 其工艺就决定了其必然的产品 缺陷， 而不是产品成份上决定的其产品的缺陷。
1、 其工艺表述为将小块玻璃料储集在模箱中， 使， .. ...结晶从玻璃表面 进入内部， 并且玻璃料彼此熔合一结合， 控制玻璃料大小 ... ...， 获得具有大 理石、 花岗石花紋的外观 9 而且此文件有大量结晶工 ¾过程的表迷的模真框 的， 可见其采用的是颗粒粘熔析晶的一种色彩花纹微晶玻璃的工艺。
A、 其彩色花紋和不透明的产品特征显然不是由材料成份决定的， 是由 申请文件表述的工艺方法中加入的从每一玻璃颗粒表面到内部来决定其产 品的晶体、 彩色和花纹的， 所以其每一颗粒料都从外到内长满了晶体， 是绝 不透明的, 根本不可能达到有良好的 40%- 95%的可见光透射比的制品， 而需 要克服这些缺陷。
B、 由于其工艺上是由不同大小的颗粒材料进行， 使其玻璃料软化和变 形， 并彼此熔融结合成一体， ... ...同时析出的玻璃结晶符合小块玻璃料的大 小和形状（见其第 7 页）。 业内人士都知道， 最主要的缺陷是产品布颗粒时 是松散的， 所以烧成后产品平面有大量的凹凸不平处， 这种颗粒的晶体， 正 如一切微晶玻璃一样是要长大的， 各种粒状使表面之不平度都在 0. 5mm-l. 5mm, 而且这种模框成型工艺， 产品平面很不平， 又加之模框都用 耐火材料烧制， 表面及四角的不平整度随每一次烧成变形越来越大， 所以其 成品的厚薄差都在 1， 5腿 -2醒， 所有的产品要正反面刮平抛光， 最少各刮¾ 去 lmm-2顏厚度， 而即徒刮抛正反两后， 其产品的厚薄差也会达 1麵以上， 所以其缺陷和浪费都大。与本发明玻璃及正常平板玻璃的厚薄差在 0. 3隱以 内相比较相差甚远。 这个缺陷也完全是由其工艺方法导致的， 而不是材料成 份产生的， 所以需要克服这些缺陷。
( 8 )、 现有技术的 PDP及无碱硼玻璃， 代表性的为 US2002/0011080A1 专利， 其虽然有较高应变点， 但其技术方案中缺陷在于： 其一， 由于成品含 氧化硼量达 5- 20%， 所以其多 2倍的硼的挥发会形成成份的不均， 不但对环 保危害很大，而且其制品强度不高，仅达 45-50MPa;其二，其生产成本极高， 因为其粘度高， 熔化及排泡和成型都困难， 所以仅作为价格比现浮法平板钙 钠玻璃高 50-100倍数的电子显示器玻璃， 根本不可用作为装饰玻璃， 也从 没有用于彩釉玻璃的公示或例子。
有鉴于上述现有技术的缺陷和不足，本发明人基于从事此类产品设计制 造多年的务实经验及专业知识， 积极加以研究创新， 以期能克服现有技术的 不足和缺陷， 在解决了复杂的生产工艺问题后， 提出了一种有预定的必不可 少的特别范围内的氧化钠、 氧化铁， 氧化铝、 氧化硅、 氧化钙、 氧化镁、 或 还有氧化钛、 氧化钿的成份以及预定的氧化硅、 氧化钙、 氧化镁之向的特珠 比例关系的成份的创新技术方案， 并且克服了各种传统的组成助溶成份和共 熔体成份的技术偏见， 并能产生预料不到的助溶或共熔体功能以及产生的制 品强度上升 1-3倍、 环保、 节能减排等的技术效果的， 并在玻璃基板上附着 熔点在 540°C - 730°C的彩色釉料的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃的本发明。 发明内容
本发明第一实施例公开了一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃， 其基板玻璃表面的 1 10种色彩的彩釉层的熔化点在 540 °C-730 °C , 其制品的基板玻璃的特征在于： 该基板玻璃包含氧化硅、 氧 化钙、 氧化镁、 氧化铝、 氧化铁、 氧化钠的成份， 按重量百分率计， 在该基 板玻璃中氧化硼的含量为 0-3. 9%， 氧化钠的含量为 0. 01-14%， 氧化铁舍量 为 0. 01-5%, 氧化氟的含量为 0-2. 8%， 氧化镁含量为 8. 1-22. 2%, 氧化铝含 量为 0. 01-39%, 其氧化硅的含量是氧化钙含量的 1. 9倍- 4. 1倍， 氧化钙的 含量是氧化镁的含量的 1. 2倍- 1. 6倍； 该基板玻璃的厚薄差小于 0. 3mm; 其 基板玻璃的吸水率在 0-0. 3%的范围内；其基板玻璃的抗折强度达 50-180Mpa; 其基板玻璃的退火温度下限（即吸热峰起点温度）为 550t:-71(rC。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 氧 化铝含量为 3. 1-39%。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 氧 化钛的含量是 0. 0003-4. 9%。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 其 氧化硅、 氧化钙、 氧化镁三者的含量总和为 51-99. 8%， 氧化钡的含量是 0. 01-14%。
根据本发明的第一卖施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的碁板玻璃特征在千： 按重百分率计， 氧化 铝的含量是 0. 01-30%， 氧化硅： 氧化钙为 0-3. 6倍， 氧化钙： 氧化镁为 1. 3- 1. 49倍， 氧化钠为 0. 01- 2%，氧化硼为 0-1%， 氧化氟的含量是 0-1%; 该 基板玻璃的退火温度下限（即吸热峰起点温度）为 610°C- 710°C ; 该基板玻 璃在粘度为 l ( 5 (帕 '秒）时的温度为 1500°C- 1640°C ; 粘度为 101 (帕 ·秒） 时的温度为 1450°C-1580°C ; 粘度为 102 (帕 ·秒）时的温度为 1210°C-1350 °C; 粘度为 103 (帕 '秒）时的温度为 107(TC- 1230°C; 该基板玻璃的抗折强 度为 50-18匿&。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重百分率计， 氧化 铝的含量是 8-30%,氧化硅：氧化钙为 2.0-3.6倍，氧化钙：氧化镁为 1.3-1.49 倍， 氧化钠为 0, 01- 2%，氧化硼为 0-1%, 氧化氟的含量是 0-1%; 该基板玻璃 的退火温度下限（即吸热峰起点溢度）为 610°C- 680°C; 该碁板玻璃在粘度 为 10 5 (帕 .秒）时的温度为 1520°C- 1640°C; 粘度为 101 (帕 .秒）时的温 度为 1450°C-158(TC; 粘度为 102 (帕 .秒）时的温度为 121(TC-1350°C; 粘 度为 103 (帕 ·秒） 时的温度为 107{TC- 1230°C; 该基板玻璃的抗折强度为 75 - 1讓 Pa。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重百分率计， 氧化 铝的舍量是 19-30%, 氧化硅： 氧化钙为 2.0-3.6 倍， 氧化钙： 氧化镁为 1.3-1.49倍， 氧化钠为 0.01-2%,氧化硼为 0-1%, 氧化氟的含量是 0-1%; 该 基板玻璃的退火温度下限（即吸热峰起点温度）为 61(TC- 68(TC; 该基板玻 璃在粘度为 1005 (帕 ·秒）时的温度为 1550eC-1640°C; 粘度为 101 (帕 '秒） 时的温度为 1450oC-1580°C; 粘度为 102 (帕 ·秒）时的温度为 1210°C-1350 "C; 粘度为 103 (帕 '秒）时的温度为 108(TC-123{rC; 该基板玻璃的抗折强 度为 130-180MPa。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重百分率计， 氧化 铝的舍量是 0.01- 19%， 氧化硅： 氧化钙为 2.0-3.6倍， 氧化钙： 氧化镁为 1.3-1.49倍， 氧化钠为 0.01-2%,氧化硼为 0-1%， 氧化氟的含量是 0-1%; 该 基板玻璃的退火温度下限（即吸热峰起点温度）为 61{TC-68(TC; 该基板玻 璃在粘度为 10β·5 (帕 '秒）时的温度为 1500°C- 158(TC; 粘度为 101 (帕 '秒） 时的温度为 1450°C-1520°C; 粘度为 102 (帕 .秒）时的温度为 1210°C- 1—310 °C; 粘度为 103 (帕 ·秒）时的温度为 107(TC- 11601C; 该基板玻璃的抗折强 度为 50-145MPa。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板坡璃， 其制品的基板玻璃特征在于； 按重量百分率计， 氧 化钙的含量是氧化镁的含量的 1. 3倍- 1. 6倍，氧化硅的含量是氧化钙的含量 的 2. 0倍 -3. 6倍， 氧化镁的含量为 10. 1-19. 9%, 氧化铝的含量为 19-39%。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于：
( 1 )、 按重量百分率计， 其基板玻璃含量中： ①氧化镁占 7- 20%， ②氧 化钙是氧化镁的 1. 0倍 -1. 8倍的范围内， （D氧化硅是氧化镁的 2. 6倍- 5. 6 倍的范围内， ④氧化硅是氧化钙的 2. 2 倍- 3. 8 倍的范围内， ⑤氧化铝为 0. 1-30%, ⑥氧化钠为 0—18%， ⑦氧化钡为 0-5%;
( 2 )、 其制品的基板玻璃的应变点温度在 560°C-720 °C的范围内； ( 3 )、 其制品的基板玻璃的吸水率在 0-0. 001%的范围内；
( 4 )、 按重量百分率计， 其制品的基板玻璃的中氧化镁、 氧化钙、 氧化 硅三种成份的含量总和达 51%- 100%。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰手板玻璃， 其特扭在于： 其制品的复合板是由一种高退火温戾 高强度的环保节能型的低熔点彩釉装饰平板玻璃 ( 1 )和粘合材料层（ 2 )以 及 0. 1-lmm或 1-5雌厚度的金属板材 ( 3 )复合组成。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 其 基板玻璃中氧化铝的含量小于等于 30%， 该基板玻璃在粘度为 10°· 5 (帕 .秒） 时的温度为 1— 480°C- 16— 40°C ; 粘度为 101 (帕 ·秒）时的温度为 1410°C-1600 °C ; 粘度为 102 (帕 .秒）时的温度为 1180°C- 1340 °C ; 粘度为 103 (帕 '秒） 时的温度为 1040°C- 1220°C ; 该碁板玻璃的厚薄差小于 0. 3匪； 该基板玻璃 的吸水率在 0-0. 3%的范围内； 该基板玻璃的退火温度下限（即吸热峰起点温 度）为 550°C- 710°C的范围内； 该基板玻璃的抗折强度为 50- 180MPa; 该基 板玻璃的热膨胀系数在 15(TC- 300°C的两端数值的差别为百万分之 1. 0-百万 分之 3. 0; 在 550°C- 600Ό的两端数值的差别为百万分之 1. 0-百万分之 2. 8。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品特征在于： 其表层的釉料层中含有 20-70% 的石英晶体或氧化铝晶体。
根据本发明的第一实施例的一种高退火温度高强度的钚保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： (1)、 按重量百分率计， 其制品含量中： ①氧化镁占 7-20%， ②氧化钙 是氧化镁的 1.0倍- 1.8倍的范围内， ③氧化硅是氧化镁的 2.6倍 -5.6倍的 范围内，④氧化硅是氧化钙的 2.2倍- 3.8倍的范围内，⑤氧化铝为 0.1-30%, ⑥氧化钠为 0-18%, ⑦氧化钡为 0-5%;
(2)、 其制品的应变点温度在 560°C-720°C的范围内；
( 3)、 其制品的吸水率在 0-0.001%的范围内；
(4)、 按重量百分率计， 其制品中氧化镁、 氧化钙、 氧化硅三种成份的 含量总和达 51%-100%。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板破璃特征在于；
(1)、 按重量百分率计， 其制品含量中： ①氧化钙的含量是氧化镁的 含量的 0.6倍- 2.4倍， ②氧化硅的含量是氧化镁的含量的 1.3倍 -5.8倍， ③氧化硅的含量是氧化钙的含量的 1.3倍 -5.8倍， ④氧化铝为 0.1-30%, ⑤ 氧化钠为 0-18%, ⑥氧化钡为 0-20%;
(2)、其中氧化镁、 氧化钙、 氧化硅三种成份的含量总和达 51%- 99.9%;
(3)、 其制品的吸水率在 0-0.001%的范围内。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于：
(1)、 按重量百分率计， 其制品含量中： ①氧化镁占 7-20%, ②氧化钙 的含量是氧化镁的含量的 1.0倍 -1.8倍，③氧化硅的含量是氧化镁的含量的
2.6倍 -5.6倍，④氧化硅的含量是氧化钙的含量的 2.2倍 -3.8倍，⑤氧化铝 为 0.1-30%, ⑥氧化钠为 0-18%， （Ϊ)氧化钡为 0-5%；
(2)、 其制品的应变点温度在 560°C-72(TC的范围内；
( 3)、 其制品的吸水率在 0-0.001%的范围内；
(4)、 按重量百分率计， 其制品中氧化镁、 氧化钙、 氧化硅三种成份的 含量总和达 51%-99.9%。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于； 按重量百分率计， 其 制品含量中： 氧化钙是氧化镁的 1.15倍- 1.8倍。
根据本发明的第 实施例的 种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于：
(1)、 按重量百分率计， 其制品含量中： ①氧化镁占 9.1-22%， ②氧化 钙的含量是氧化镁的含量的 0.6倍- 2.0倍，③氧化硅的含量是氧化镁的含量 的 2.8倍- 5.6倍， ④氧化硅的含量是氧化钙的含量的 2.3倍 -3.8倍的范围 内， ⑤氧化铝为 0.1-30%， ⑥氧化钠为 0-18°/。， ⑦氧化钡为 0-5%;
( 2 )、 其制品的应变点温度在 560°C- 720°C的范围内；
(3)、 其制品的吸水率在 0-0.001%的范围内；
(4)、 按重量百分率计， 其制品中氧化镁、 氧化钙、 氧化硅三种成份的 含量总和达 51%-99.9%。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 制 品中氧化铝舍量达 0-3.8%时： 粘度为 101 (帕 '秒）的熔化工艺温度为 1300 °C-1400°C; 粘度为 102 (帕 .秒） 的澄清、 排气泡工艺温度为 1120°C- 1260 °C; 粘度为 103 (帕 秒）的成型工艺温度为 101(TO1060°C; 其制品的抗折 强度达 60-100MPa。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 制 品中氧化铝舍量逸 3.8- 15%时： 粘度为 1(^(帕 ·秒）的熔化工艺温度为 1320 °C-143(TC; 粘度为 102 (帕 ·秒） 的澄清、 排气泡工艺温度为 1140°C- 1290
Figure imgf000010_0001
其制品的抗折 强度达 80-130MPa。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 制 品中氧化铝含量达 15- 23%时； 粘度为 101 (帕 ·秒）的熔化工 ¾温度为 1360 °C-1550°C; 粘度为 102 (帕 ·秒） 的澄清、 排气泡工艺温度为 1250°C- 1430 °C; 粘度为 103 (帕 ·秒）的成型工艺温度为 106{TO120(rC; 其制品的抗折 强度达 100- 180MPa。
根据本发明的笫一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 该基板玻璃包含氧化 硅、 氧化镁和氧化钙， 其中， 按重量百分率计， 在该基板玻璃中氧化硅的舍 量是氧化镁的含量的 2.1倍- 6.5倍， 氧化硅的含量是氧化钙的含量的 1.8 1 -4.6倍；
该基板玻璃的厚薄差小于 0.3mm;
其吸水率在 0-0.3%的范围内； 其抗折强度达 50- 180MPa。
根据本发明的笫一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 在 该基板玻璃中，氧化硅的舍量是氧化镁的舍量的 2. 6倍 -5倍，氧化硅的舍量 是氧化钙的含量的 2. 4倍- 3. 4倍。
根据本发明的第一实施例的 种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 氧 化钙的含量是氧化镁的含量的 1. 0倍- 1. 6倍， 更优选 1. 2倍- 1. 5倍。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃的厚度为 0. 3-1. 8薩。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃的厚戾为 1. 8-5删。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃的厚度为 5-20fflm。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 氧 化钠的含量为 0. 01-2%。
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重量百分率计， 氧 化钠的舍量为 2. 1-5%。
本发明第 实施例提供了一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃的制备方法， 其特征在于：
步骤 1， 根据权利要求 1-6的任一项所述的制品的基板玻璃组分配置所 需的各种有预定的必不可少的特别范围内的氧化钠、 氧化铁、 氧化铝、 氧化 硅、 氧化钙、 氧化镁、 或还有氧化钛、 氧化钡的成份以及预定的氧化硅、 氧 化钙、 氧化镁之间的特珠比例关系的成份的创新技术方案的原料， 经混合搅 拌之后对应于各玻璃配方的熔化温度熔化，形成可控的粘度和优化的低粘度 的玻璃液， 再均化， 澄清， 排出气泡， 形成可流动的熔融体；
步骤 2 , 采用浮法工艺、 平拉工艺、 格法工艺、 压延工艺、 溢流法工艺 中任一种工艺对玻璃进行成型，经冷却工序制得高退火温度高强度的环保节 能型的低熔点彩釉装饰平板玻璃的基板玻璃； 步骤 3 , 对成型的制品的基板玻璃的表面印刷或施布上一层由 1 种或 2-10种色彩的熔点为 540'C- 730°C的彩色釉料形成装饰层。
根椐本发明的实施例的一种高退火温度高强度的环保节能型的低熔点 彩釉装饰平板玻璃，其制品表面上的彩色釉料图案装饰层，是通过设置 2-100 套， 每套由 1-10个平面网印或滚筒印刷器或喷墨印刷器所组成的单块制品 印刷装置单元， 以并联布局的方式， 对所迷高退火温度高强度的环保节能型 的低熔点彩釉装饰平板玻璃的基板玻璃的表面， 进行彩釉料印刷， 再进行釉 料烧结工序， 所制得的在同一批次制品生产中使 2-100块制品表面产生每块 有 1-10种色彩的预设的不同印刷图案或色彩釉料装饰层的一种高退火温度 高强度的环保节能型的低熔点彩釉装饰平板玻璃制品。
根据本发明实施例的工艺方法， 其中： 其制品的复合板的背底面的金属 板的 2-4条边， 比重叠后的表层一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃制品的边部伸出了 10-30mm的距离。 附图说明
图 1是本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法的实施例的高退火温度高强度的环保节能型的低熔点彩 釉装饰平板玻璃的基板玻璃的平面示意图。
图 2是本发明 = ""种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法的实施例的高退火温度高强度的环保节能型的低熔点彩 釉装饰平板玻璃的基板玻璃的浮法工艺成型的流程示意图。
图 3是本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法的高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃的基板玻璃实施例的浮法工艺成型的状态的侧剖面示意图。
图 4是本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法实施例的尺寸是 1220隱 X 2440mm的已经印刷好预定三个 色区的彩釉料形成表层是预定彩釉料图案装饰层的一种高退火温度高强度 的环保节能型的低熔点彩釉装饰平板玻璃制品的平面示意图。
图 5是本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法实施例的尺寸是 1220隱 2440mm厚度约 2- 5mm的已经印 刷好预定三个色区的彩釉料形成表层是约 0. 1- 1mm厚度的预定彩釉料图案装 饰层的一种高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃制 品的剖面示意图。
图 6是本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法实施例的表层是一种高退火温度高强度的环保节能型的 低熔点彩釉装饰平板玻璃，背面是重叠后边部没有超出表层硅酸盐彩釉装饰 玻璃尺寸的铝板，通过粘合剂相互粘贴复合组成的新型复合板材剖面结构示 意图。
图 7是本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法实施例的表层是一种高退火温度高强度的环保节能型的 低熔点彩釉装饰平板玻璃， 背面是有 2条边比表层硅酸盐彩釉装饰玻璃尺寸 各自多伸出了 10-30讓 离的铝板，相直粘贴复合组成的新型复合板材剖面 结构示意图。
图 8是本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法实施例的采用表层是一种高退火温度高强度的环保节能 型的低熔点彩釉装饰平板玻璃 背面是重叠后有 1条边比表层硅酸盐彩釉装 饰玻璃尺寸各自多伸出了 10-30醒的铝板，相互粘贴复合组成的新型复合板 材， 在 10-30隱伸出部分上的预定位置打孔后， 可进行墙面镙釘安装的立平 面结构示意图。 附图标记说明
1 : 一种高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的 基板玻璃
2: 料仓进料口
3： 料仓
4: 预定配制的混合原料
5: 原料进入熔池的熔池窑口
6: 熔池窑
7: 导流槽
8: 锡槽 9: 过渡辊台
10: 退火窑
11 : 切割分装台
12: 浮法生产线基体
21： 斜线部分表示已印刷的第一色区彩釉料图案区
31 : 十字线部分表示已印刷的第二色区彩釉料图案区
41： 小黑点部分表示已印刷的第三色区彩釉料图案区
123： 表示上层的已印刷了预定三个图案色区彩釉料的釉料图案装饰层 13： 表示有彩釉层的高退火温度高强度的环保节能型的低熔点彩釉装饰 平板玻璃
14: 表示重叠后边部未超出表层高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃边部的铝板
141 : 表示重叠后有 2 条边比表层高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃各自多伸出了 10- 30mm距离的铝板
15 : 表示预定的粘合剂
16： 表示复合板材的背底铝板的比表层高退火温度高强度的环保节能型 的低熔点彩釉装饰平板玻璃伸出 10-30mm的边部中的镙钉安装孔 具体实施方式
本发明首创了 （1 )有新颖性、 创造性的环保型玻璃基板技术方案， 使 其具有 （2 )线性热膨胀特征， 有高退火点即退火温度下限（即吸热峰起点 温度）、 有高强度特征的玻璃与 （3 )限于 540°C- 73(TC的熔化温度的 （注： 普通玻璃玛赛克和〜切玻璃的釉料都在 760 °C 820 °C以上的熔化温度）彩釉 层的三个技术要素特征组合的新功能彩釉玻璃制品，在成本经济可行的前提 下，解决了先有技术平板玻璃不能用于非钢化的大板面彩色印刷装饰玻璃的 技术难题。
由于现有技术中只有本发明才能首创低成本、 高效率生产地使基板玻璃 退火温度下限（即吸热冷起点温皮）从普通平板玻璃的 490°CJ升到最少 540 °C ,优选为 600°C或 650°C以上或 700 °C以上（注： 现有乎板玻璃只有显示器 无碱硼玻璃才有此性能， 但业内人士都知道其由子工艺及材料等因素， 市场 价为 25万 -30万元人民币 /吨， 比建筑钠玻璃的约 2000元人民币 屯贵 100 倍）， 本发明比现有技术 钠玻璃的 49{TC高出 150 220 ， 又由于具有十 分优良的热膨胀线性特征， 即在退火点之附近温区膨胀变化极小， 所以， 其 一， 可以采用熔点在 540°C- 730°C的釉料， 优选 600°C- 65 (TC或 650°C- 700 熔点的釉料， 而这种釉料可以成本不高地大生产， 而熔化点在 54CTC以下 的釉料不可以大生产， 而且有严重的环保问题）， 由于本发明可以在退火点 温度之下烧结印刷精细图案。 所以不用采取二次退火工艺， 就可史无前例地 生产 2400 X 1200mm, 3000 x 1800mm等石材或各种如铝板材、 木质层板材、 铝塑板材、 木质复合板材、 木粉密度板、 树脂板材等图案装饰标准板尺寸的 本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的 精细彩釉石紋、木紋图案印刷彩色或单色产品， 并且产品可以如同上述的先 技术标准板材一样任意按施工要求尺寸进行切割。
下面， 对本发明的实施例进行详细的说明。
第一实施例：
根据本发明一个实施例， 种高退火温度高强度的环保节能型的低熔点 彩釉装饰平板玻璃，其基板玻璃表面的 1-10种色彩的彩釉层的熔化点在 540 °C-730°C ,其制品的基板玻璃的特征在于：该基板玻璃包含氧化硅、氧化钙、 氧化镁、 氧化铝、 氧化铁、 氧化钠的成份， 按重量百分率计， 在该基板玻璃 中氧化硼的含量为 0-3. 9% , 氧化钠的含量为 0. 01-14%， 氧化铁含量为 0. 01-5%, 氧化氟的舍量为 0-2. 8%, 氧化镁含量为 8. 1-22. 2%, 氧化铝含量 为 0. 01-39%, 其氧化硅的舍量是氧化钙含量的 1. 9倍- 4. 1倍， 氧化钙的舍 量是氧化镁的含量的 1. 2倍- 1. 6倍； 该基板玻璃的厚薄差小于 0. 3誦； 其基 板玻璃的吸水率在 0-0. 3%的范围内； 其基板玻璃的抗折强度达 50- 180Mpa; 其基板玻璃的退火温度下限（即吸热峰起点温度）为 55(TC- 710° ( 。
按重量百分率计， 该基板玻璃中氧化铝的含量小于等于 30% , 该基板玻 璃在粘度为 10。·5 (帕 '秒）时的温度为 1480oC-1640°C ; 粘度为 101 (帕 '秒） 时的温度为 1410°C-160(rC ; 粘度为 102 (帕 ·秒）时的温度为 118(TC- 13— 40 °C ; 粘度为 103 (帕 ·秒）时的温度为 1040°C- 1220 °C ; 该基板玻璃的厚薄差 小于 0. 3讓； 该基板玻璃的吸水率在 0-0. 3%的¾围内； 该基板玻璃的应变点 温度在 560°C-720°C的范围内； 该基板玻璃的抗折强度为 50-180MPa; 该基 板玻璃的热膨胀系数在 150°C-300°C的两端数值的差别为百万分之 1. 0-百万 分之 3. 0; 在 55{TC-600°C的两端数值的差别为百万分之 1. 0-百万分之 2. 8。
另外 ,加入氧化铝会使基板玻璃的强度提高但会增加玻璃的熔化温度及 其他各种粘度下的温度。根据本实施例的基板玻璃可以根据对强度的需求和 各种粘度下的温度的要求， 可以添加适当含量的氧化铝。 （另外， 在本说明 书中， 除非特别指明， 基板玻璃中各种成分的百分含量均为重量百分比。） 本发明产品的性能特征
艇
注： 本说明书所述退火温度下限（即吸热峰起点温度）是采用综合热分 析仪测定的。
本发明基板玻璃的退火温度下限（即吸热峰起点温度）为 550'C-710°C。 本发明实施例的基板玻璃的退火温度下限（即吸热峰起点温度）优选在 600 °C或 650Ό或 65(TC-70{rC之目的在于解决在较高的温度下，在退火点之下， 烧结釉料， 才不会出现现有一直困扰彩釉玻璃生产的二次退火的易爆裂技术 难题。
强度性能
前迷的（A )现有工业、 建筑玻璃， 如钙钠平板玻璃、 LCD玻璃， 仅为氧 化铝 1%左右或 1-3%左右， 而且其技术方案不易加多氧化铝， 不然就会因粘 度太高不能实施生产， 强度也仅为 45- 60MPa。
而根据本发明的基板玻璃实施例， 如前粘度部分所述， 可以知道把氧化 吕加入 20-25%时，粘度也低于先有扶术，而且有一个很好的扶术控制范围的 平台， 在制品的强度方面， 本发明制品可以 艮易达到 1 00- 160MPa 或 130-180MPao 本说明书中涉及本发明实施例的玻璃的抗折强度， 通过把样品 切成 50mm X 5讓 X 5mm的小条， 采用抗折强度仪， 按标准 GB/T3810. 4-2006 测定。
应变点高， 膨胀系数线性特征突出， 不同温度区间膨胀变化值极小
根据本发明实施例的玻璃的膨胀系数按照标准 GB/T7320. 1-2000测定。 - 制品能急剧加温或冷却时尤其彩釉烧结时不会有过多的变型或出现爆 裂。但是根据本发明实施例的基板玻璃之技术方案能有更好的膨胀系数线性 特征， 产生很小的玻璃粘弹性突变， 具体其制品的热膨胀系数在 150°C-300 的两端数值的差别为百万分之 1-百万分之 3. 0; 在 550 °C- 600 °C的两端数 值的差别为百万分之 1-百万分之 2. 8 ; 用于无碱玻璃在 60{TC-650 i的两端 数值的差别为百万分之 1-百万分之 3. 0。 比现有技术钙钠浮法玻璃和 PDP或 TFT玻璃 550Ό_600 Ό的热膨胀系两端数值的差别为百万分之 16要好出 5-16 倍， 比 LCD钙钠玻璃 550 TC-60(TC的热膨胀系两端数值的差别为百万分之 20 要好出 7 - 20倍。
这还提供了一个在急升温或急降温的彩釉图案烧结工艺及建筑装饰材 料防火的使用环境下应用， 会有比现有各种玻璃有更好的变形小、稳定而不 突变、 极不易爆裂， 在急升降温时玻璃粘弹性急变小的很大优势。
吸永率
根据本发明实施例的基板玻璃的吸水率在 0-0. 3%的范围内。另外，根据 本发明的实施例的高退火温度高强度的环保节能型的低熔点彩釉装饰平板 玻璃的基板玻璃， 其可以选择具有很好的透明特征和防水性。
根据本发明实施例的基板玻璃的吸水率是按照标准 GB/T3810. 3-2006测 定。
厚薄差 '
根据本发明实施例的基板玻璃的厚薄差在 0. 3瞧的范围内。
根椐本发明实施例的基板玻璃的厚薄差是接照标准 GB/T1216测定。 为了更详细地描述根据本发明实施例基板玻璃的技术.方案，在下面的表 1中列举出根据本发明的实施例的彩釉层之下的基板玻璃的样品的配方及相 应的性能。
可控制的经济性、 标准化及施工设计的便利性
本发明的基板玻璃可以在比现无碱硼平板玻璃成本低几十倍的条件下， 在退火温度下限（即吸热峰起点温度）合乎色釉玻璃不二次退火的条件下， 生产效率高几十倍的条件下（是由于现舍硼条件的无碱平板玻璃只能用昂贵 的铂金逋道装皇排泡， 一条曰产 8吨的生产线要投资达 10多亿人民币， 而 且还要因硼成份对熔池的腐蚀每年冷修三个月， 所以达 25万- 30万人民币 / 吨， 而本发明之技术方案可以达到同样的各种品质， 尤其是品质强度还可以 高出 1-2倍，并采用大 p屯位的可曰产 300 p屯- 800吨的工艺方法生产，投资才 3-4亿人民币， 所以成本低 50-80倍。） 能高品质的合理经济成本地大生产。 这并不是很显而易见的就能把平板玻璃的性质和退火温度下限（即吸热峰起 点温度）、 强度、 低成本地解决的， 这是对现有技术从来没有出现过无机釉 料印刷的平板玻璃在市场上的根本技术难题之一种有预料不到效果的技术 方案。 业内人士都知道， 这产生了新用途广泛的优势（而钢化釉面板是不适 用的， 不可如瓷砖一样现场切割的， 而且如印图案， 钢化板边沿一定是有 1-2讓左右的宽庋图案缺陷的， 钢化后也不能如瓷砖一样磨边的， 而本 明 可以印刷成大的 2400 X 1200mm等标准板， 可以如瓷砖一样磨边、 切割， 保 障图案的无缺陷和产品大板标准化和使用切割便利化。
见下页为附表 1
彩釉层下之基板玻璃的样品及特征（表 1 )
Figure imgf000019_0001
彩釉层下之基板玻璃的样品及特征（表 1续）
Figure imgf000020_0001
用高温旋转粘度计测不出 经推算而得到,
表 2 (现有技术）
Figure imgf000021_0001
* 用高温旋转粘度计测不出， 经推算而得到。 从上表 1可见：
对于实施例中所阐述的氧化硼在 0-3. 9%，氧化铁在 0. 01-5%，氧化钛在 0. 0003-4. 9%, 氧化钠在 0. 02-8. 8%及氧化镁在 8. 1-22. 2%,以及氧化硅： 氧 化钙是 1. 9- 4. 1倍， 氧化钙： 氧化镁是 1. 2-1. 6倍的本发明技术方案的范围 内之样品， 首先在粘度上全都好于现有一切技术的在 10 5 (帕 ·秒）、 101 (帕 .秒）时的婊化粘度， 102 .秒）时的排气泡、 澄清、 均化粘度， 都 比现有技术好 150 - 400°C (可参考比较表 2和表 3 )。 而且其线热膨胀系数 在 15(TC- 30(TC、 在 550 °C- 600 Χ:、 以及在 60(TC- 650 °C的两端数值的差值， 也比现钙钠玻璃、 PDP玻璃、 无碱液晶屏用高硼玻璃要好。
样品 6、 7、 8、 9、 10是处于一个优选的氧化钙是氧化镁的 1. 3- 1. 5倍， 氧化硅是氧化钙的 2. 1-3. 3倍的而且氧化铝含量在 19 30%的更优范围之中， 尤其粘度和线膨胀系数的差值及温度指标等技术效果指标最好。
而样品 1、 2 3、 4、 5 , 11 , 都处于本发明技术方案的内容之内， 可见 其粘度、强度、膨胀系数还是比一切现有技术的 TFT液晶显示屏硼玻璃、 PDP 等离子显示屏玻璃和一切现有技术平板玻璃好。
而样品 1、 2、 3、 4是釆用的本技术发明方案的镁、 钙、 硅比例的上限、 下限及交叉上下限的比例范围的实例， 而样品 1 和 5是硅、 钙、 镁总和为 59. 5-99. 8%的上、 下限的实例。 ' 从样品 10、 11， 由于铁含量在 1到 1. 3， 而且有较高的氧化钡、 氧化钛 含量而会变成不透明的褐黄或棕黄色， 以适应当生产釉层各外表面的如玻璃 制品时（如陶瓷的彩釉砖、 仿古砖）， 由于不在乎玻璃的透光性， 所以降成 本， 扩大为透明玻璃不可用之大上百倍的普通石笑砂原有利应用范围， 节约 资源的技术效果和降低主要原料成本 10倍左右的效果（高级的硅材料比普 通的价格高十倍以土）就十分明显。
表 2列出了一些现有技术的玻璃配方及相关的性能。 从表 2可以看出， 首先由于四种样品含有的硼、 铁、 钛、 钠、 镁的范围与本发明不一样， 又由 于硅与钙、以及氧化钙与氧化镁之间的比例关系都与本发明的特殊比例关系 完全不同， 其氧化硅与氧化钙以及氧化钙与氧化镁比例大大高出本发明， 本 发明的比例为氧化钙是氧化镁含量的 1. 2倍- 1. 6倍、氧化硅是氧化钙含量的 1. 9倍- 1倍， 而这些产品的氧化硅比氧化钙和氧化钙比氧化镁的含量都是 完全不一样的。从表 2可见其技术偏见上从来都把硅是作为玻璃的骨架和被 熔化的而且是难熔的基体，所以其粘度 尤其是 10 (帕 ·秒）、 10 帕 ·秒) 时的熔化工艺温度， 采用标准的旋转粘度计都根本测不出（因其粘度太高）， 可见其在熔化中要克服能耗， 克服碴点、 结石， 提升生产效率的难度较大或 很大。 其在正常的排气泡和均化的 102 (帕 '秒） 时的温度， 也比本发明的 表 1样品高出 150 - 300°C， 可见其排气泡和均化的困难， 和本发明的工艺 平台的节能和易控制比较优势， 对于 103 (帕 '秒）的成型工艺温度， 本发 明对于成型，对于制品的平整度、厚薄差也有很大的技术易控制的比较优势， 而且在产品强度方面， 本发明制品也是其 2- 3倍， 在线性膨胀系数， 尤其关 系到在玻璃上烧结釉料或防火防爆的粘弹性值的线性特征的几个重要温区 的差值变化上也有十分大的优势。
示例 1
在上述第一实施例的基础上， 限定按重百分率计， 氧化铝的含量是
0. 01-30%, 氧化硅： 氧化钙为 2. 0-3. 6倍， 氧化钙： 氧化镁为 1. 3-1.—49倍， 氧化钠为 0. 01- 2%,氧化硼为 0-1%， 氧化氟的含量是 0-1%; 该基板玻璃的退 火温度下限（即吸热峰起点温度）为 61{TC-710°C ;该基板玻璃在粘度为 10°· 5 (帕 ·秒） 时的温度为 1500°C- 1640°C ; 粘度为 101 (帕 ·秒） 时的温度为 1450°C-1580°C ; 粘庋为 102 (帕 ·秒） 时的温度为 1210°C-1350°C； 粘庋为 103 (帕 · 秒） 时的温度为 1 O : - 1230 °C ; 该基板玻璃的抗折强度为 50- 180MPa。
示例 2
在上述第一实施例的基础上， 限定按重百分率计 氧化铝的含量是 8-30%, 氧化硅： 氧化钙为 2. 0-3. 6倍， 氧化钙： 氧化镁为 1. 3 - 1. 49倍， 氧 化钠为 0. 01-2%，氧化硼为 0-1%， 氧化氟的含量是 0-1%; 该基板玻璃的退火 温度下限（即吸热峰起点温度）为 610°C-680°C ; 该基板玻璃在粘度为 10° 5 (帕 .秒） 时的温度为 1520 - 1640°C ; 粘度为 101 (帕 ·秒） 时的温度为 145(TC- 1580°C ; 粘度为 102 (帕 ·秒） 时的温庋为 1210。C- 1350°C ; 粘虎为 103 (帕 · 秒） 时的温度为 107(TC - 1230 °C ; 该基板玻璃的抗折强度为 75-180MPao
示例 3
在上述第一实施例的基础上， 限定按重百分率计， 氧化铝的含量是
19-30%, 氧化硅： 氧化钙为 2. 0-3. 6倍， 氧化钙： 氧化镁为 1. 3-1. 49倍， 氧化钠为 0. 01- 2°/。，氧化硼为 0-1%， 氧化氟的含量是 0 - 1%; 该基板玻璃的退 火温度下限（即吸热峰起点温度）为 610°C- 680°C;该基板玻璃在粘度为 10 (帕 .秒） 时的温度为 1550°C-164(rC ; 粘度为 101 (帕 ·秒） 时的温度为 1450°C- 1580°C; 粘度为 102 (帕 ·秒） 时的温度为 1210°C- 1350°C ; 粘度为 103 (帕 '秒） 时的温度为 1080 °C -123(rC ; 该基板玻璃的抗折强度为 130- 180MPa。
示例 4
在上迷第一实施例的基础上， 限定按重百分率计， 氧化铝的含量是 0. 01-19%, 氧化硅： 氧化钙为 2. 0-3. 6倍， 氧化钙： 氧化镁为 1. 3-1. 49倍， 氧化钠为 0. 01-2%,氧化硼为 0-1%， 氧化氟的含量是 0-1%; 该基板玻璃的退 火温度下限（即吸热峰起点温度）为 610 68(TC ;该基板玻璃在粘度为 10° 5 (帕 .秒） 时的温度为 1500°C-158(rC ; 粘度为 101 (帕 ·秒） 时的温度为 1450°C-1520°C ; 粘度为 102 (帕 ·秒） 时的温度为 1210X 1310°C ; 粘度为 103 (帕 ·秒） 时的温度为 l fHiTC -ll WC ; 该碁板玻璃的抗折玆度为 50- 145MPa。
示例 5
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 氧化钛的含量是 0. 0003-4. 9%。
示例 6
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 氧化钡的舍量是 0. 01-14%。
示例 6
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 其氧化硅、 氧化钙、 氧化镁三者的含量总和为 51-99. 8%。
示例 7
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 氧化钙的含量是氧化镁的含量的 1. 3倍 -1. 6倍，氧化硅的含量是氧化钙的含 量的 2. 0倍- 3. 6倍，氧化镁的含量为 10. 1-19. 9%,氧化铝的含量为 19-39%。
示例 8
在上述第一实施例的基础上， 对基板玻璃的成份， 限定：
( 1 )、 按重量百分率计， 其基板玻璃含量中： ①氧化镁占 7- 20%, ②氧 化钙是氧化镁的 1. 0倍- 1. 8倍的范围内， ③氧化硅是氧化镁的 2. 6倍- 5. 6 倍的范围内， ④氧化硅是氧化钙的 2. 2 倍 -3. 8 倍的范围内， ⑤氧化铝为 0. 1-30%, ⑥氧化钠为 （W8%， ⑦氧化钡为 0-5%; 按重量百分率计， 其制品 的基板玻璃的中氧化镁、 氧化钙、 氧化硅三种成份的含量总和达 51%-100%； 其性能如下：
其制品的基板玻璃的应变点温度在 560°C-720°C的范围内；
其制品的基板玻璃的 水率在 0-0. 001%的范围内；
示例 9
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 其基板玻璃中氧化铝的含量小于等于 30%，该基板玻璃在粘度为 1 ( (帕 ·秒） 时的温度为 1480°C- 164(TC ; 粘度为 101 (帕 ·秒）时的温度为 1410°C- 1600 V； 粘度为 102 (帕 '秒）时的温度为 1180°C- 13WC ; 粘度为 103 (帕 '秒） 时的温度为 1040°C- 1220°C ; 该基板玻璃的厚薄差小于 0. 3mm; 该基板玻璃 的吸水率在 0-0. 3%的¾围内； 该基板玻璃的应变点温度在 560°C- 720°(：的¾ 围内；该基板玻璃的抗折强度为 50- 180MPa;该基板玻璃的热膨胀系数在 150 °C-300°C的两端数值的差别为百万分之 1. 0-百万分之 3. 0; 在 550°C- 600°C 的两端数值的差别为百万分之 1. 0-百万分之 2. 8
示例 10
在上述第一实施例的基础上， 对基板玻璃表层的釉料层中施加含有 20-70%的石英晶体或氧化铝晶体。
示例 11
根据本发明的第一实施例的一种高追火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃的厚度为 0. 3-1. 8mm
示例 12
根据本发明的第一实施例的一种高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃， 其制品的基板玻璃的厚度为 1. 8- 20
示例 13
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 氧化钠的含量为 0. 01-2%
示例 14
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 氧化钠的含量为 2. 1-5%。
示例 15
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 氧化钠的含量为 2. 1-8%。
示例 16
在上迷第一实施例的基础上，对基板玻璃的戍份，限定接重量百分率计， 氧化钠的含量为 2. 1-14%。
示例 17
在上述第一实施例的基础上，对基板玻璃的成份，限定按重量百分率计， 氧化铝的含量为 1-19%。
以上是对根据本发明实施例的高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃的基板玻璃的组成及其特性， 下面描述制造根据本发明 实施例的高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的方 法。
第 实施例
请参阅图 1所示，是根据本发明的实施例的一种高退火温度高强度的环 保节能型的低熔点彩釉装饰平板玻璃及制备方法的高退火温度高强度的环 保节能型的低熔点彩釉装饰平板玻璃的基板玻璃制品平面示意图。 从图可 见，标号 1表示一种高退火温度高强度的环保节能型的低熔点彩釉装饰平板 玻璃的基板玻璃。
请参阅图 2所示，是本发明一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃及制备方法对高退火温庋高强庋的环保节能型的低熔 点彩釉装饰平板玻璃的基板玻璃所采用的浮法工艺成型的流程示意图。从图 可见， 其成型工艺的流程是将预定配制的原料放入进料仓， 然后从进料仓中 将原料输送到熔池窑中， 进入了熔池按预定温度进行熔融并排出气泡， 接着 是液态的熔融体， 进入到锡槽中（锡槽的旁边设有氮氢气体的保护气体站向 锡槽中输入保护气体）， 在锡槽的锡面上淌平、 经拉边、 牵引， 形成抛光平 整的半成品带， 从过渡辊台进入到退火窑进行降温冷却， 而得到制品， 再经 切割分装台上进入预定尺寸的切割分装，得到高退火温度高强度的环保节能 型的低熔点彩釉装饰手板我璃的基板玻璃半成品。
请参阅图 3所示，是本发明一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃及制备方法对高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃的基板玻璃采用浮法工艺成型的状态的侧剖面示意图。 从图可见， 标号 2表示料仓进料口， 标号 3表示料仓， 标号 4表示预定配制 的混合原料， 标号 5表示混合原料进入熔池的熔池窑口 （标号—4所示的预定 配制的混合原料由此输送到熔池窑的熔池中）， 标号 12表示浮法线基体， 标 号 6表示熔池窑， 标号 7表示溶池中的液态熔融原料体进入锡槽的导流槽， 标号 8表示浮法工艺的锡槽，标号 9表示锡槽中形成的半成品带进入退火窑 的过渡辊台， 标号 10表示退火窑， 标号 11表示将成型制品进行分切包装的 切割分装台。
请参阅图 4所示， 是本发明一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃及制备方法实施例的尺寸是 1220隱 X 2440mm的巳经印 刷好预定三个色区的彩釉料形成表层是预定彩釉料图案装饰层的一种高退 火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃制品的平面示意图。 从图可见，标号 1表示一种高退火温度高强度的环保节能型的低熔点彩釉装 饰平板玻璃的基板玻璃， 标号 21斜线部分表示已印刷的第一色区彩釉料图 案区， 标号 31十字线部分表示已印刷的第二色区彩釉料图案区， 标号 41小 黑点部分表示已印刷的第三色区彩釉料图案区。
请参阅图 5所示，是本发明一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃及制备方法实施例的尺寸是 1220mm X 2440mm厚度约 2-5細的已经印刷好预定三个色区的彩釉料形成表层是约 0. 1-1顏厚度的预 定彩釉料图案装饰层的一种高退火温度高强度的环保节能型的低熔点彩釉 装饰平板玻璃制品的剖面示意图。 从图可见， 标号 1表示一种高退火温度高 强度的环保节能型的低熔点彩釉装饰平板玻璃的基板玻璃，标号 123表示上 层的已印刷了预定三个图案色区彩釉料的釉料图案装饰层。
请参阅图 6所示， 是本发明一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃及制备方法实施例的表层是一种高退火温度高强度的 环保节能型的低熔点彩釉装饰平板玻璃， 背面是重叠后边部没有超出表层硅 酸盐彩釉装饰玻璃尺寸的铝板，通过粘合剂相互粘贴复合组成的新型复合板 材剖面结构示意图。 从图可见， 标号 13表示有彩釉层的高退火温度高强度 的环保节能型的低熔点彩釉装饰平板玻璃， 标号 14表示重叠后边部未超出 表层高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃边部的铝 板， 标号 15表示预定的粘合剂。
请参阅图 7所示，是本发明一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃及制备方法实施例的表层是一种高退火温度高强度-的 环保节能型的低熔点彩釉装饰平板玻璃， 背面是有 2条边比表层硅酸盐彩釉 装饰玻璃尺寸各自多伸出了 10-30mm距离的铝板，相互粘贴复合组成的新型 复合板材剖面结构示意图。 从图可见， 标号 1 3表示有彩釉层的高退火温度 高强度的环保节能型的低熔点彩釉装饰平板玻璃， 标号 141表示重叠后有 2 条边比表层高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃各 自多伸出了 1 Q-3Q鹏距离的铝板， 标号 15表示预定的粘合剂。
请参阅图 8所^,是本发明一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃及制备方法实施例的采用表层是一种高退火温度高强 度的环保节能型的低熔点彩釉装饰平板玻璃， 背面是重叠后有 2条边比表层 硅酸盐彩釉装饰玻璃尺寸各自多伸出了 10- 30麵的铝板，相互粘贴复合组成 的新型复合板材， 在 10-30mm伸出部分上的预定位置打孔后， 可进行墙面镙 钉安装的立平面结构示意图。 从图可见， 标号 13表示有彩釉层的高退火温 度高强度的环保节能型的低熔点彩釉装饰平板玻璃，标号 1-41表示重叠后有 2条边比表层高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃各 自多伸出了 10-30讓距离的铝板， 标号 16表示复合板材的背底铝板的比表 层高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃伸出 10-30讓 的边部中的镙钉安装孔。
现将本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃及制备方法的以浮法成型工艺方法制作其玻璃制品并印刷彩釉装饰 层形成制品， 做进一步说明，其制造过程包括以下一些步骤：
[1]、 首先， 配制原料， 根据第一实施例的玻璃各种组分范围来计算原 料配比。
[2] , 准备好如图 3所示的浮法工 ¾的包括原料仓、 熔池窑、 舍锡液的 锡窑、 以及拉边机、 牵引机、 过渡辊台、 退火窑冷却系统、 切割分装台等设 施在内的浮法生产线。
[3]、 按图 3及图 2所示的浮法工艺的生产流程， 把第 [1]步骤配制的 标号 4所示的预定配制的混合料， 从图 3的标号 2所示的料仓进料口， 以原 料输送带方式输送入标号 3所示的原料仓中， 再经标号 5所示的熔池窑口， 将第 [1]步骤配制好的混合料送入到标号 6所示的预定耐高温的熔池窑的熔 池中， 逐步在对应于各玻璃配方的熔化温度的温度区时（对于氧化铝含量为 30%以下的情况，熔化温度可以在 1360 °C-146(TC的温度或 146{TC -168(TC的 范围内）形成流动性好的液态融熔体， 经过高温区逐步排出液态原料中的气 泡， 即形成了可以进入成型工序的流动性较好的混合原料熔融体。
[4]、 按图 2所示的浮法工艺的生产流程和图 3所示， 使第 [3]步骤的可 流动性能较好的混合原料熔融体，从标号 6所示的熔池窑经标号 7所示的导 流槽的夹口， 流入到浮法生产线之标号 8所示的锡槽 (也可称为锡窑）的锡 面上， 再经淌平， 经拉边才; L 边和牽引机的牵引， 在锡液面上抛光抛平， 形 成半成品带通过标号 9所示的过渡辊台出锡窑后， 进入标号 10所示的辊道 的降温冷却系统的退火窑冷却， 再进入到标号 11所示的切割分装台， 经切 割、 分装， 即可制得如图 1所示的本发明其碁板玻璃表面的 1-1 0种色彩的 彩釉层的熔化点在 540°C- 730°C， 该基板玻璃包含氧化硅、 氧化钙、 氧化镁、 氧化铝、 氧化铁、 氧化钛、 氧化钠的成份， 按重量百分率计， 在该基板玻璃 中氧化硼的含量为 0-3. 9%， 氧化钠的含量为 0. 01-14% , 氧化铁含量为 0. 01-5%, 氧化氟的含量为 0-2. 8%, 氧化钛为 0. 0003-4. 9%, 氧化镁含量为 8. 1=22. 2%, 氧化铝含量为 0. 01-39% , 其氧化硅的含量是氧化钙含量的 1. 9 倍- 4. 1倍， 氧化钙的含量是氧化鎂的含量的 1. 2倍 -1. 6倍； 该基板玻璃的 厚薄差小于 0. 3薩； 其基板玻璃的吸水率在 0-0. 3%的范围内； 其基板玻璃的 抗折強度达 50- 180MP; 该碁板玻璃在粘度为 10°· 5 (帕 .秒）时的温度为 1480 °C-1640°C ; 粘度为 101 (帕 ·秒） 时的温度为 1410°C-160{rC ; 粘度为 102 (帕 .秒） 时的温度为 1180 °C- 1340°C ; 粘度为 103 (帕 .秒） 时的温度为 1040 °C-1220°C ; 该基板玻璃的厚薄差小于 0. 3mm; 该基板玻璃的吸水率在 0-0. 3%的范围内； 该基板玻璃的退火温度下限（即吸热峰起点温度）在 550 °C-71 (TC的范围内； 该基板玻璃的抗折强度为 50- 180MPa; 该基板玻璃的热 膨胀系数在 150 °C- 300°C的两端数值的差别为百万分之 1. 0-百万分之 3. 0; 在 550°C-600°C的两端数值的差别为百万分之 1. 0-百万分之 2. 8的一种高退 火温度高强度的环保节能型的低熔点彩釉装饰平板牧璃的碁板破璃。
[5]、 将标号 1所示的表层无釉料图案的高退火温度高强度的钚保节能 型的低熔点彩釉装饰平板玻璃的基板玻璃依次进入输送线上的印刷位，按预 定图案要求， 依次采用安装有预定第一、 第二和第三色区印刷图案版的彩釉 料印刷设备， 分别将白色釉料通过笫一色区印刷图案版的标号 21斜线部分 所示的印刷图案区印刷到标号 1所示的高退火温度高强度的环保节能型的低 熔点彩釉装饰平板玻璃的基板玻璃表层； 将深桔红色釉料通过第二色区印刷 图案版的标号 31十字线部分所示的印刷图案区印刷到标号 1所示的高退火 温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的基板玻璃表层； 将浅 桔红色釉料通过第三色区印刷图案版的标号 41 小黑点部分所示的印刷图案 区印刷到标号 1所示的高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃的基板玻璃表层； 至此即完成了预定白色、 深桔紅色， 浅桔红色的 个色区彩釉料的印刷， 在操作工¾中， 控制釉料层的印刷约为 0. 1- 1麵的厚 度。
[6]、 将印刷有预定白色、 深桔红色、 浅拮红色的三个色区彩釉料形成 的图案装饰层的高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻 璃的基板玻璃， 通过输送线进入到釉面烧结工序的辊道窑， 按业内公知的应 低于高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的基板玻 璃变形软化点温度的工艺条件下，使硅酸盐釉料以设定的不同工艺所需的不 同的温度区， 逐步进行领热并升温烧制， 再经冷却， 即可制得如图 4所示的 表面由白色、 深桔红色、 浅桔红色三个釉料色区組成图案的尺寸为 1 220IM1 X 2440麵厚度为 2-5mm、热应变溢度点即追火溢度下限在 55{TC-60{TC或 600 °C-650°C范围之内、抗折强度达 50-160MPa的高退火温度高强度的环保节能 型的低熔点彩釉装饰平板玻璃的制品。 从图 4可见， 标号 1表示表层无釉料 图案的高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的基板 玻璃， 标号 21斜线部分表示已印刷的第一色区彩釉料图案区， 标号 31十字 线部分表示已印刷的第二色区彩釉料图案区， 标号 41 小黑点部分表示已印 刷的第三色区彩釉料图案区。 而从其剖面看， 则是如图 5所示， 其标号 1表 示约 2- 5IM厚度的表层无釉料图案的高退火温度高强度的环保节能型的低熔 点彩釉装饰半板玻璃的基板玻璃， 标号 I23表示上层的已印刷了预定由色、 深桔红色、 浅桔红色三个色区组成图案的约 0. 1-1画厚度的彩釉料的釉料图 案装饰层。 第二实施例的修改 1
对上迷第二实施例的高退火温度高强度的环保节能型的低熔点彩釉装 饰平板玻璃的基板玻璃的制备方法的选择上，还可以选择釆用的以下工艺方 法进行， 如：
还可选择之 1、 采用平拉工艺： 对形成的可流动的熔融体进行有平拉工 艺特征的拉薄、 成型、 退火、 冷却、 分切制作， 再经施彩釉和绕结， 制得高 退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的基板玻璃；
或者还可选择之 2、 釆用格法工艺： 对形成的可流动的熔融体采用格法 工艺成型、 退火、 冷却、 分切制作， 再经施彩釉和烧结， 制得高退火温度高 强度的环保节能型的低熔点彩釉装饰平板玻璃的基板玻璃；
或者还可选择之 3、 采用压延工艺： 对形成的可流动的熔融体采用压延 工艺进行压延、 成型、 退火、 冷却、 分切制作， 再经施彩釉和烧结， 制得高 退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的基板玻璃；
或者还可选择之 4、 采用溢流法工艺： 对形成的可流动的熔融体釆用溢 流法工艺进行引下、 成型、 退火、 冷却、 分切制作， 再经施彩釉和烧结， 制 得高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的基板玻璃 ·， 以上工艺也均可制得到本发明其基板玻璃表面的 2-10种色彩的彩釉层 的熔化点在 540X 73{TC， 该基板玻璃包含氧化硅、 氧化钙、 氧化镁、 氧化 铝、 氧化铁、 氧化钛、 氧化钠的成份， 按重量百分率计， 在该基板玻璃中氧 化硼的含量为 0-3. 9%， 氧化钠的含量为 0. 01-14%， 氧化铁含量为 0. 01-5% , 氧化氟的含量为 0-2. 8%,氧化钛为 0. 0003-4. 9%,氧化镁含量为 8. 1-22. 2%, 氧化铝舍量为 0. 01-39%, 其氧化硅的舍量是氧化钙舍量的 1. 9倍- 4. 1倍， 氧化钙的含量是氧化镁的含量的 1. 2倍- 1. 6倍； 该基板玻璃的厚薄差小于 0. 3mm; 其基板玻璃的吸水率在 0-0. 3%的范围内； 其基板玻璃的抗折强度达 50-1讓 p; 该基板玻璃在粘度为 10° 5 (帕 '秒 )时的温度为 1480°C -1640 °C ; 粘度为 101 (帕 ·秒） 时的温度为 141(rC-160{TC ; 粘度为 102 (帕 ·秒） 时 的温度为 1180°C-1340eC ; 粘度为 103 (帕 '秒）时的温度为 1040°C-1220°C； 该基板玻璃的厚薄差小于 0. 3mm; 该基板玻璃的吸水率在 0-0. 3%的范围内； 该基板玻璃的退火温度下限（即吸热峰起点温度）在 550'C- 710°C的范围内； 该基板破璃的抗折强度为 50-l 80MPa;该基板破璃的热膨胀系数在 150 °C-300 °C的两端数值的差别为百万分之 1. 0-百万分之 3. 0; 在 55(TC-60(rC的两端 数值的差别为百万分之 1. 0-百万分之 2. 8 的一种高退火温度高强度的环保 节能型的低熔点彩釉装饰平板玻璃的基板玻璃。
第二实施例的修改 2
其制品表面上的彩色釉料图案装饰层， 是通过设置 2-100 套， 每套由 1-10 个平面网印或滚筒印刷器或喷墨印刷器所组成的单块制品印刷装置单 元， 以并联布局的方式， 对所迷高退火温度高强度的环保节能型的低熔点彩 釉装饰平板玻璃的基板玻璃的表面，进行彩釉料印刷，再进行釉料烧结工序， 所制得的在同一批次制品生产中使 2-100块制品表面产生每块有 1-10种色 彩的预设的不同印刷图案或色彩釉料装饰层的一种高退火温度高强度的环 保节能型的低熔点彩釉装饰平板玻璃制品。
第二实施例的修改 3
其制品表面装饰层的釉料中含有或刚玉晶体、 或石英晶体、 或钙铝黄长 石晶体、或霞石晶体、或镁硅钙石晶体、或钙镁黄长石晶体、或莫来石晶体、 或透辉石晶休、 或硅灰石晶体、 或硅锌矿晶体、 或堇青石晶体、 或钙镁橄槐 石晶体、 或顽辉石晶体、 或含锂晶体、 或尖晶石晶体、 或金红石晶体。
第二实施例的修改 4
其制品的复合板是由一种高退火温度高强度的环保节能型的低熔点彩 釉装饰平板玻璃制品（ 1 )和粘合材料层（ 2 ) 以及 0. 1-lmm或 l-5mm厚度的 金属板材 ( 3 ) 复合组成。
第二实施例的修改 5
其制品的复合板的背底面的金属板的 2- 4条边， 比重叠后的表层一种高 退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃制品的边部伸出 了 10- 3ϋπιπι的距离。
本发明的应用和区別于 有技术的特点：
对根据本发明实施例的高退火温度高强度的 T、保节能型的低熔点彩釉 装飾平板玻璃， 也就是其与现有技术的根本区別， 再归纳总结如下:
本发明在平板彩釉玻璃领域中有新颖性的技术方案是： 其基板玻璃表面 的 1-10种色彩的彩釉层的熔化点在 54{TC-730°C，其制品的基板玻璃的特征 在于： 该基板玻璃包含氧化硅、 氧化钙、 氧化镁、 氧化铝、 氧化铁、 氧化钠 的成份，按重量百分率计， 在该基板玻璃中氧化硼的含量为 0-3. 9%, 氧化钠 的含量为 0. 01-14%， 氧化铁含量为 0. 01-5%， 氧化氟的含量为 0-2. 8%， 氧化 镁含量为 8. 1-22. 2%, 氧化铝含量为 0. 01-39%, 其氧化硅的含量是氧化钙含 量的 1. 9倍- 4. 1倍， 氧化钙的含量是氧化镁的含量的 1. 2倍- 1. 6倍； 其基 板玻璃的厚薄差小于 0. 3mm; 其基板玻璃的吸水率在 0-0. 3%的范围内； 其基 板玻璃的抗折强度达 50-180MP; 其基板玻璃的退火温度下限（即吸热峰起点 温度）为 550 °C-71 (TC。
本发明具有退火温度下限（即吸热峰起点温度）与现有钙钠平板玻璃不 一样的必须较高的 550°C- 710 °C性质， 并且可以在经济性的前提下优选 600 °C或 650°C或 700 °C的退火温度下限（即吸热峰起点温度）， 本发明首先是一 种组合发明， 对彩釉平板玻璃而言， 首先在于， 本发明的 1-10种色彩的彩 釉层的熔化温度选择了 540°C-730 °C的范围， 而必须与之配合的平板玻璃有 以下几个层次的与现有技术平板玻璃不同的新性质特征。
其一， 对彩釉层之下的一切现有技术的平板玻璃而言， 重要的是使用一 种对铝、 硅、 钙、 镁、 铁、 钠的成份范围的选择发明和对硅、 钙、 镁成份之 间， 这些技术要素的比例关系的改变发明的技术方案为硅： 钙为 2. 0-4. 1， 钙： 镁为 1. 2-1. 6倍的范围， 而现有技术的一切平板玻璃， 最少有一个要素 比例关系的两个端值， 在本发明范围外， 也就是本发明上述的要素比例关系 的选择在一切现有技术的窄范围之内， 具有新颖性。 而且在本发明之彩釉层 平板玻璃用途中、 工艺中， 发现了新下述之产品性质， 产生了下述之预料不 到的技术效果。
其二， 本发明揭示了发现的产品的新的性质转用新用途的发明类型， 也 是产生了预料不到的效果（即通过各种平板玻璃加工方法， 在新的平板玻璃 用途方面， 能产生的【1)不同工艺阶段的优秀的新的粘麾温虎及产品， 〖2)厚 薄差， [3]吸水率， [4]抗折强度， [5]可见光透射比， [6]波纹度， [7]线性 热膨胀系数特征等平板玻璃新性质、 新用途特征）。
尤其在新用途中，本发明发现了现有技术所从来没有揭示过的产品的新 的降低粘度温度和共熔体性质， 熔化工艺阶段粘度温度， 均化， 排泡， 澄清 工艺阶段粘度温度， 尤其是控制波纹度的平整度或厚薄差、 成型工艺阶段的 拉薄（或浮法工艺中的抛光） 工艺的粘度温度。
( A )、 由于产品新的性质的发现之一克服了传统技术偏见产生的对平板— 钙钠玻璃的氧化钠技术的一种要素省略发明： 现有技术的平板玻璃， 几乎 99. 9%以上的一切建筑玻璃、一般工业玻璃， 其都含有 13%左右的钠， 主要用 来助熔， 尤其对硅成份的助熔， 形成各工艺阶段的可以控制粘度的降低。 但 本发明的技术方案和发现的产品的新性质， 打破了这种技术偏见， 可以由于 硅、 钙、 镁之间的要素关系的变化发明， 在平板玻璃的用途中， 产生的产品 新性质，在钠含量在 0-1%以内时，可以比现有技术的高钠平板玻璃的几个工 艺阶段的粘度温度低 150°C-250°C， 这将产生大量节能和有利于高品盾控制 产品厚薄差， 波紋度， 和熔化工艺不好产生的平板玻璃结石、 碴点和排泡工 艺不好产生的气泡率等缺陷， 尤其可以大幅提升有一定要求的如 0. 5-1. lmm 的 LCD显示器超薄的平板玻璃的品质， 降低碴点、 结石率、 气泡率、 降低不 合格厚薄差率和不合格波纹度率。
现有技术在操作中， 如果一丘产生任何一个工艺阶段的缺陷， 现有技术 在操作上都易于加高各工艺阶段的温度的方式来解决，但这就很易出现使熔 池垮顶， 大大缩短使用寿命。 而本发明提供了 个很有利于操控工艺的技术 操控的粘度可调范围。 从根本上解决了业内人士一直认为的现行钠（高钠） 平板玻璃 "料性短" 的产品性质 （即业内讲的 "料性"） 的技术难题。
( B )、 由于产品新的性质的发现之二， 克服了传统技术的偏见， 产生了 对无碱硼玻璃的 "氧化硼"技术要素的一种要素省略发明： 现有的尤其用于 液晶显示器的无碱硼平板玻璃， 其由于不能含超过 1%的钠， 采用了 8-15%舍 量的硼成份来作助熔剂成份， 有认为非如此方行的技术偏见， 尤其形成对硅 的助熔， 以能形成高品质的平板玻璃各工艺阶段的粘度温度的降低控制， 而 且能产生基板玻璃的退火温度下限（即吸热峰起点温度）达到 600"C-730oC 的技术效果。 但本发明的技术方案和发现的新性质， 打破了这种技术偏见， 可以由于硅、 钙、 镁之间的要素关系的变化发明， 在平板玻璃用途中， 产生 新的产品性质，在没有氧化硼舍量或仅为 0 1%时， 不但可以使基板玻璃的退 火温度下限（即吸热峰起点温度）达到 600°C-730°C , 还可以比现有技术的 以 8-15%含量的硼的产品的粘度温度， 比现无碱硼玻璃的平板玻璃的几个工 艺阶段低 250°C-350°C , 这特会形成一个很大范围的拉制工艺达到控制产品 质量的新的技术平台， 比较现有技术玻璃， 可以达到更高水平厚薄差、 波纹 度水准和几乎无气泡、 无碴点、 无结石缺陷的品质要求的 0. 5- 2讓厚度的超 薄产品的成品率 优品率 尤其是对于排气泡和澄清 均化工艺阶段和成型 拉薄的工艺阶段的粘度，都提供了一种比现有技术好得多的工艺控制范围和 工艺控制平台。
本发明之硅、 钙、 镁要素的比例关系变化发明的技术方案， 克服了现有 技术仅通过铝或硼成份加大才有产生退火温度下限（即吸热峰起点温度）上 升的技术偏见。本发明上述技术方案能产生在硼和铝低于 1%以下时退火温度 下限（即吸热峰起点温度）也能上升 100°C左右， 而且拍含量低于 2%以下时 退火温度下限（即吸热峰起点温度）还会有更大的上升（见附表样品例）。 当然如果再在以上技术方案上还加多氧化铝含量， 又可以形成进一步的使退 火温度下限（即吸热峰起点温度）上升的技术效果。 使之达到本发明的核心 的低成本、 高退火点的性质要求。
( C )、（ 1 )、本发明的一种对现有的占平板玻璃总量 99%以上的钙钠平板 玻璃中 13%的钠含量的一种上述之要素省略发明产生了可以使基板玻璃的退 火温度下限（即吸热峰起点温度） 为 610°C-71 (TC优选为 650 °C- 68(TC的产 品性质， 而现在的所有平板钙钠玻璃的退火温庹下限（即吸热峰起点温麾） 仅为 490°C。 而本发明之无碱（或仅为 0. 01-1%的钠）无硼的平板玻璃的退 火温度下限（即吸热峰起点温度）为 610°C-71 (TC , 因为按本发明的技术方 案镁最少为 8. 1% (一般达 12-18% )， 钙最少为 9. 6% (一般为 15-18% ), 这种 组成是基板玻璃的退火温度下限（即吸热峰起点温度 )大幅上升的主要原因， 能比普通的现有平板钙钠玻璃的退火温度下限（即吸热峰起点温度）高出 120 V-200V ,这是另外一种新的产品性质的发现这在本发明彩釉玻璃的技术效 果上十分重要， 正因为现有的钙钠平板玻璃的退火温度下限（即吸热峰起点 温度）仅为 490°C , 所以如杲妻作无机彩釉的烧结， 一种选择是如现玛赛克 玻璃， 只能作 2-5cm尺寸的小块， 而且使用成本低一些的低温釉（熔点约）， 其面积小， 二次退火要求不高， 才不裂。
( 2 )、 如果要第二选择， 制作 10cm、 20cm更不要说制作 60cm 60cm的 或者更大尺寸， 二次退火非常困难， 破裂率极高， 现有技术和市场上从来没 有产品大生产成功出现过。 大尺寸都用有机树脂印刷工艺， 其有在户外一定 变色和与玻璃结合不会很好的问题， 又不可以如瓷砖一样粘合， 因瓷砖胶会 腐蚀彩色树脂， 也粘不牢固。 现有技术的平板玻璃不可能用轻、 薄的玻璃彩 釉手板的尺寸产品， 替代高能耗的厚重瓷砖产品。
( 3 )、 第三选择是采用现有的 490°C左右熔点的釉料（注： 瓷砖釉料熔 点在 95(TC-120{TC左右），如制作正常的杯子、瓶子上的贴花产品的小线条， 极小面积占驳使用极高， 不可能大量运用， 没有装饰材料大面积、 大产量的 经济性可言， 所以没有任何应用的例子。
( 4 )、 而第四个选择为采用现有的无碱硼平板玻璃， 即由于液晶显示器 的玻璃， 其现有技术生产成本极高， 现市场价约 30万元 /吨， 如果 0. 7MI厚 庋的要达到 600元人民币 /m2， PDP等离子玻璃 1. 8-2. 8mm厚的也达 1000元 人民币 /n , 所以虽然其玻璃的退火温度下限（即吸热峰起点温度）可以达 到 580°C- 680 °C或 700°C， 可以用有经济性的 600°C-65{TC的熔点的釉料，但 其玻璃的成本根本不可能有作为装饰材料的基板， 替代陶瓷砖， 甚至最高端 陶瓷砖的经济可行性。 而本发明的上述无硼无碱的一种要素省略发明的平板 玻璃的新发现的退火温度下限（即吸热峰起点温度）可达 60(rC-73(TC， 而 且可以如前所述的有经济成本低， 并且品盾好、 产量大的生产方式， 生产本 发明之玻璃基板， 又可以采用有经济可行性的 600°C-73(rC的彩釉料来进行 组合生产。 所以这是一种有^料不到的技术效杲的解决了替代陶瓷砖， 解决 现有装饰材料的人们长期渴望解决而没有解决的难题。
( 5 )、 这里要说明的是， 虽然加大钙、镁的含量如达 19-50% (—般只含 钙 +镁共 10- 12% )的超过现有技术的钙钠玻璃， 可以省略硼成份就可以使玻 璃的退火温度下限（即吸热峰起点温度） 大大上升， 而且有氧化钠达 2-13% 也会大大上升， 只是比无钠或低钠的产品的退火温度下限（即吸热峰起点温 度）上升'』、一些， 但是并不是说加多钙和镁的成份就能达到生产之目的， 因 为还要必须同时具有合适于平板玻璃尤其是较低的排气泡的粘度温度的工 艺条件。 现有技术的平板我璃， 如杲只加大钙和镁的舍量， 而不是具有本发 明之硅， 钙、 镁之间的互相比例关系的比一切现有技术就是加大钙镁含量其 粘度温度还是会高于本发明 150°C- 300°C， 又比如无碱硼平板玻璃， 其加入 了 8-15%的助熔剂硼成份，才只加入了 8-10%的氧化铝，在粘度为 102(帕 '秒 ) 时的排泡工艺的温度高达 1500°C以上， 必须用一种浅熔池（玻璃液深度仅— 5-lOcm )的高昂的铂金排泡通道来完成排气泡工序， 而且 产仅几吨。 所以 其与本发明的低粘度， 又有高的退火温度下限（即吸热峰起点温度）的技术 方案之可以用几百吨日产量工艺生产（排泡区熔池深度达 70- 100cm )相比较， 其产 ά量差几十倍， 而要达到本发明大吨位产能， 要上几十条线， 而投资却 会多几十倍。也就是讲，在解决退火温度下限（即吸热峰起点温度）的上升， 使之合乎各种显示器平板玻璃和彩釉及防火防爆等平板玻璃的要求，现有一 切技术平板玻璃， 或只是加大钙 +镁达 20-50%的技术方案， 而不是采取本发 明之要素比例关系的变化发明、 选择发明的技术方案， 都是不能兼顾成本和 退火温度下限（即吸热峰起点温度）的预料不到的组合技术效杲的。
( 6 )、其产生预料不到的技术效果不仅在于能在无钠或硼的低铝和高铝 的本发明制品的退火温度下限（即吸热峰起点温庋）性质和在 liO- -SOO^ 及在 600°C- 650°C或 680°C的线性膨胀系数值， 完全可以还有高品质、 低成 本、 高几十倍生产效率等能同时兼顾地达到生产高品质平板彩釉玻璃的技术 要求和形成更好的经济成本目标。
( D )、 由于产品的新的产品性质的发现之四， 克服了传统平板玻璃的一 种认为加大氧化铝必然产生粘度温度大幅上升的技术偏见。如现有技术钙钠 玻璃， 只能加入 1%左右的氧化铝， 而现有的无碱硼平板玻璃， 也一般只加入 8%左右氧化铝来提高应变点，加多了就会使本已十分高的各阶段工艺的粘度 温度 ϋ高， 无法控制工艺应达到的品质目标。 也认为无法在可以低成本的可 控的工艺条件下，把氧化铝加到 25-30%， 以提高产品强度。但本发明的技术 方案和发现的新的平板玻璃产品性质， 打破了这种技术偏见， 本发明在不含 硼、 不含钠、 不含氟成份时（即 0-1%时）， 氧化铝含量为 3. 1%或 16%或 20% 或 25%左右时的大跨度变化时， 现有技术认为粘度会大幅上升， 但本发明的 粘度温度的变化仅为， 就是氧化铝为 30%左右时粘度温度也仅上升 80 °C左右 (见附表 1之 11个样品例）。
而且粘度温度比加入了 13%氧化钠或 8-15%氡化硼的平板玻璃产品还低 100°C-200°C。 这证明了本发明的技术方案中的硅、 钙、 镁的要素比例关系 变化范围的发明技术方案， 能和氧化铝在 25%或 30%含量时产生一种新的产 品性质， 这就是一种新的高氧化铝含量的铝、 硅、 镁、 钙的共熔体性质， 能 产生高铝含量的低粘度温度的预料不到的技术效果和进而产生的高品高强 度的预料不到的技术效果。
本发明尤其由于可以加大氧化铝的含量达 19-28%时， 强度可达约 1 0-160Mpa或 180Mpa， 大大高于各种先有技术平板玻璃强度的 2-3倍， 而 且由子粘度温度还较先有技术仅 1-25%氧化铝含量时低 150°C- 250°C , 所以 如果本发明技术方案形成无碱高硼玻璃的粘度时，那应当还有相当于加多氧 化铝到 29-39%的可以溶化的粘度空间和强度上升的较大空间（本说明书及本 发明实施例玻璃的抗折强度 * 通过把样品切成 50mm 50讓 χ 5隱的小条 采 用抗折强度仪， 按标准 GB/T3810、 4-2006测定。）。 先有技术的无碱高硼制 品， 因氧化硼成份的挥发过程， 会造成成份的不均， 使氧化铝参与的材料网 状结构受损， 大大影响应有的强度。 这是无碱高硼玻璃就是含 7-15%氧化铝 的时也强度较差的重要原因。
所以本发明能在有高铝含量和无硼含量时， 产生 90- 145MPa 或 145-180MPa的抗折强度，而且兼有更节能，更低成本和有更大的粘度温度的 工艺范围， 这是现在一切彩釉平板玻璃作不到的， 而本发明也能在熔化工艺 粘度温度阶段控制熔化， 克服结石和防止产生没有被熔化之碴点， 在澄清和 控制成型时平板玻璃的厚薄差（因为粘度越低， 此工艺阶段的平板玻璃产品 越软越有控制之范围， 反之粘度越高， 此工艺阶段平板玻璃产品越硬， 越不 好在拉引、 平拉、 或压延、 或浮法的淌平、 拉薄、 抛光等工艺阶段控制厚薄 差和波丈度）。
在上述更好的与现有技术的品质而且强度可以达到比现有的平板玻璃 高 2倍， 这种新的产品性质的发现和产生， 使与彩釉层的组合发明产生了可 以生产 1-2腿的厚度的够强度的墙面产品和 2-3fflm厚度的本产发明地面产 品，对现陶瓷的国家标准的外墙挂板 12卿厚的产品和各种其它 10卿厚的地 面产品的高强度、 轻薄化的替代， 产生能源、 资源、 物流、 仓储的几倍的节 约工的预料不到的效果。
( E )、 由于采用了一种技术要素省略的发明， 对现有技术的如无碱硼玻 璃, 而且在可以比现有技术更好的结石、 碴点、 气泡率、 平坦度度、 厚薄差 的品质控制的前提下， 在工艺温度不上升前降低且节能的前提下， 省略去硼 成份， 都可以有平板工艺的熔化、 排泡、 成型、 拉薄各阶段的更好的性质和 可加入更多氧化铝而产生的抗折强度性质， 而且预料不到的对平板显示器无 碱硼玻璃可以不加入 8-15%的硼成份， 而保证气泡率高质、平坦度、厚薄差、 波紋度的产品品质的倮障， 可以解决现有技术无碱硼破璃生产装 只能用溢 流法工艺加铂金通道的工艺的技术偏见， 更最高的是可以采用浮法工艺， 在 保障厚薄差、 平坦度、 波紋度的品质前提下， 可以提高生产效率数十倍， 可 以节约投资几十倍， 节约土地厂房 20倍的预料不到的效果。 所以成本大大 下降， 是本发明彩釉平板玻璃的组合发明， 在退火温度下限（即吸热峰起点 温度）能与现有技术之无碱硼显示器玻璃一样合乎彩釉玻璃大生产的前提之 下， 而产生新的性质的彩釉用基板玻璃， 从而大大降低成本， 产生预料不到 的经济可行性的技术基础产生之预料不到的效果。
其三， 由于新的上述产品的性质的揭示和发现， 克服了上述之多种先有 技术偏见， 在各种建筑装饰用彩釉平板玻璃领域， 产生了以下几个预料不到 的技术效果的（ 1 ) 由于粘度温度温度性质形成了可很好的提升和控制工艺 的熔化品质、 气泡品质、 平坦度、 厚薄差和波纹度品质的技术效杲； （2 )预 料不到的由于粘度温度下降的 200°C以上的节能 30%左右的效果； （3 )预料 不到的由于共熔体性盾加入大量的铝（从 1%加到 25%或 25-30% ), 产生的强 度上升 2- 3倍的技术效果； （4 )由于强度上升由此可产生的彩釉平板玻璃可 轻薄 2- 3倍的节能、 节约资源、 节约物流、 仓储 2-3倍的预料不到的技术效 果； （5 )本发明新的技术效果还在予， 由子 ^以在氧化铁含量上用子不透明 或透明度不高的装饰材料平板玻璃中加大，可以节约日益减少的优盾玻璃原 料资源， 主要璩璃原料成本下降 10倍。 传统技术认为食铁量高一些的原料 影响玻璃产生兰绿色的缺陷， 但本发明能在平板玻璃中， 可以提升强度 2-3 倍， 所以可薄 2-3倍， 透光率反而会上升， 兰绿色度反而更不明显， 不影响 透明而向上的彩釉玻璃的使用。 而彩釉面向上时， 更可以使用等量大百倍的 高铁原料， 更不在乎透明度， 更能节约玻璃的各种中等水平的原料和资源， 大大节约成本。 所以本组合发明是能产生一种预料不到的轻、 薄、 高强庋、 大大-节约玻璃高端资源、节约原料成本的综合效果的彩釉平板玻璃产品。 这 是其它现有技术达不到的既有高强度、 又轻又薄、 又节约原料资源、 又大大 节约原料成本 10倍的技术效果。（6 由于釆用了一种技术要素省略的发明， 对现有技术的如无碱硼玻璃， 而且在可以比现有技术更好的結石、 碴点、 气 泡率、 平坦度、 厚薄差的品质控制的前提下， 在工艺温度不上升前降低且节 能的前提下， 省略去硼成份， 都可以有平板工艺的熔化、 排泡、 成型、 拉薄 各盼段的吏好的性质和可加入更多氧化铝而产生的抗折强度性质， 而且预料 到的对平板充碱硼玻璃可以不加入 的蹦成份， ^保证气泡率高质、 平坦度、 厚薄差、 波紋度的产品品质的保障， 可以解决现有技术无碱硼玻璃 生产装置只能用溢流法工艺加铂金通道的日产仪 6-8吨的工艺的技术偏见， 更最高的是可以采用 400-800吨曰产的大-屯位如浮法、平拉、压延等等工艺， 在保障厚薄差、 平坦度的品质前提下， 可以提高生产效率几十倍， 可以节约 投资几十倍， 节约土地厂房 20倍的预料不到的效果。 本发明技术方案与现 有一切平板玻璃或彩釉平板玻璃技术比较，具有从来没有被揭示和公开的新 的性质， 而且这种性质是事先无法推测， 无法预测和推理出来的， 并克服了 传统的平板玻璃技术的技术偏见，解决了人们在行业中渴望解决的上述重大 问题， 技术效果产生了 "质" 和 "量" 二者的变化， 说明技术方案是非显而 易见的， 具有突出的实质性特点， 具有显著的技术进步， 具有创造性。
( F 由于本发明制品可在 700 °C以下烧结彩釉层， 所以可以烧结印刷 釉层，可以在釉层加入大量的如 30-80%的各种晶体尤其是成本低的石英或钢 玉晶体粉或粒， 形成史无前例的 0. 2-3πιιπ的耐磨表层高硬度（石英可达 7级 的硬度， 而加入钢玉则可达 9级硬度）， 而这在陶瓷生产中作不到的， 因为 陶瓷的烧成温度在 1100°C- 1200°C， 此时陶 表层的石美或钢玉只能 成我 璃相， ^在 730°C以卞， 石英或钢玉晶体还^保持结晶相， 这就能形成史充 前例的装饰玻璃抛光的石英晶体硬度达 7级耐磨面表层或刚玉晶体硬度达 9 级的耐磨表层，对陶瓷或石材的耐磨性、零吸水率、零吸污率、 高度防滑性， 是革命性的挑战性的（防滑能用于卫浴、 厨房地面、 地铁、 码头及一切人流 量大的公共场所地面）， 其中石英表层因 7级硬度是可以抛光的， 成为最优 的表层石英釉面组合抛光耐磨制品， 而钢玉的 9级硬度是不能抛光的， 但可 预料不到地成为最优的耐久的防滑或耐磨钢玉釉面组合发明制品， 所以本发 明能形成节能环保、 低成本优质耐磨的替代升级技术。 而且会对陶瓷业的高 耗能、 高污染、 高粉尘排放、 高水耗、 低产出、 低品质的制品及整个装备工 艺系统提出替代性挑战。
( G )、 本发明可以制作 0. 5- 5壓超薄厚度， 在没有进行钢化的表面应力 处理的状态下， 抗折强度达 50- 180MPa的优选为 90- 145MPa或 145-180MPa 的超薄型高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃制品， 并以其用来和薄层的金属板复合形成新型的复合板材， 以轻、 薄、 高强度的 装饰效果的目的， 达到满足更好的功能性侠用需求。
而且还可以采用使复合板材的底面金属板材的 2-4条边比重叠后的表层 高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃的边部伸出了 10- 30隱的距离， 在这伸出的边部进行打孔后采用镙钉直接钉入墙体或与墙 体龙骨架固定安装的创新的墙面应用的简便的安装方式，使折断破损率大大 降低， 有新的产品性质再现有好的预料不到的技术效果。
( H )、本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃， 其制品的基板玻璃的厚度为 0. 3-1. 8隱。 特别轻薄， 特别适合墙面 使用， 特别节能， 而且设备产出率高。
( I X本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃， 其制品的基板玻璃的厚庋为 1. 8- 20腿。 强度高，适会地面， 尤其是 超大板的外墙使用制品。
( J )、本发明一种高退火温度高强度的环保节能型的低熔点彩釉装饰平 板玻璃，其制品的基板玻璃的成份中氧化铝的含量为 19- 39%时，制品强度最 高， 尤其适合高强度要求的特别制品。
上述本发明技术方案的在彩釉玻璃的高级仿石材、仿木材等装饰效果并 有较低成本的前提下的各种新的性质的发现， 产生预料不到的技术效果， 尤 其解决了人们在建筑装饰材料行业长期渴望解决的而又没有获得成功的主 要技术重大难题是：
其一， 在全球每年年产的上百亿 m2的陶瓷砖和板材中。 陶瓷砖产品全年 每年有 30 亿 ri 用于墙面市场。 但其产品的厚度在 8- 15mm， 室内墙面的为 8-10mm, 窒外的 12- 15mm。 而本发明的印刷图案（不管单色或 2-10种色）产 品， 可以制成 0. 5-1. 5mm的产品， 可以使陶 砖墙面产品轻薄化 6- 10倍。
陶瓷砖产品地面市场每年有约 ΐ 0亿 用子地面市场。 但其产品的厚度 在 9-12mm。 而本发明的彩釉印刷图案（不管单色或 2-10种色）产品， 由于 强度可达陶瓷的三倍， 所以只要 3- ½m就有一样的强度。 其中， 把透明的玻 璃一面放在表面， 背后印彩釉图案的效果就相当于现有的抛釉砖（在陶瓷图 案表面加一层透明釉， 再抛光形成一个玻璃釉面）。 全球有 10亿 m2的产量。 其中本发明的在玻璃表面形成一层彩釉图案， 就相当于陶瓷的仿古砖， 全球 每年有约 30亿 n 的产量。 其中在本发明玻璃的表面低温烧结形成一层含晶 体如石英等的彩釉层， 再抛光， 就相当于现在陶瓷的抛光砖（但本发明石英 含量晶体达 50%-60%， 耐磨度、硬度、 防污性能比陶瓷抛光砖好很多）， 全球 每年有 30亿 n 左右。 也就是讲， 本发明高退火温度高强度的环保节能型的 低熔点彩釉装饰平板玻璃能使每年 60亿- 100亿 m2的陶瓷产品的落后生产工 艺改变。 [1]、 以上述本发明产品可以比墙面瓷砖薄 6倍， 可以比地面砖薄 3倍。 这就能解决陶瓷砖工业长期以前渴望解决的轻量化的节约原料资源， 节约 油、 电能源， 减少碳排放和粉尘排放的产业战略难题。 也就是讲， 本发明能 使建筑装饰陶瓷每年 100亿 m2并按每年 10%以上成长的产业在生产环节节约 原材料 70%-80%， 节能 70%- 80%， 减少碳排放 70%-80%。 （根据计算如果全球 性的工艺装备按本发明之浮法工艺的改变，将可节约年三个长江三峡电站的 发电量的能耗）
[2]、 由于可以生产成 2400 X 1200mm或 3000 1800mm等大尺寸的薄板 材， 还可以替代许多墙面和装修用铝板或标准尺寸的铝塑板， 节约铝资源， 而且本发明的资源比铝资源储量多数万倍，成本也低得多，产品又更耐腐蚀， 吏平整挺括， 更有图案装饰表现力， 可以印刷一切石材、 木紋等图案。 并且 在墙面要装方法上本发明也比陶瓷板、 石板、 铝板、 铝塑板方便、 成本低。
[3]、 由于可以在强度有保障的性能条件下， 采有现一切陶瓷和玻璃作 不到的又有可设计的木紋、 石纹和色彩的 1- 2mm厚度的产品， 用于欧美及澳 洲、 俄罗斯、 东亚、 南亚的木质结构的房屋的外墙的木板上的贴面， 替代转 和水泥析的非承重墙面达到高档次、防火 轻薄又耐日晒、雨雪侵蚀的效果, 而且用于木质结构楼上的墙面的具有华丽美观又轻薄防水的效果也有新的 使用价值。
(二）、 对于现有技术的装饰玻璃， 其由于只能以现在的普通钙钠玻璃 作彩釉基板的选择， 但其退火点在 490 左右， 又根本不可能批量生产 480 °C以下的釉料（一则必须引入大量的铅有剧毒， 二由成本极高）， 所以只能 在 5cm尺寸以下的玻璃玻赛克上印刷（因为其尺寸极小，在退火时不易爆裂）， 所以历史上从没生产过大尺寸的印刷无机釉玻璃板。 另外有用钢化技术在 750 °C - 830°C以上熔化釉料， 采用强化工艺解决退火应力问题。 但此种产品 尺寸特定， 不可切割， 在装饰工程应用中不能适应要求， 而且钙钠玻璃的强 庹差-， 不能作地面应用9
^本发明技术， [1]由千可以使基板玻璃退火温度下限（即吸热峰起点 温度）优选上升到 60(TC或 650 °C或 7„30 °C， 比钙钠玻璃高出 15Dt -2.0.0eC , 又由于具有十分优良的热膨胀线性特征， 即在退火点之附近温区膨胀变化极 小， 所以， 其一， 可以采用熔点在 54{TC-730°C的釉料（这种釉料不同于 480 °C以下的釉料， 这种釉料可以成本不高地大生产， 而且没什么环保问题）， 在退火点温度之下烧结印刷的精细图案。 所以不用采取二次退火工艺， 就可 史无前例地生产 2400 X 1200mm 3000 χ 1800mm等装饰板或石材或玻璃的常 用的各种标准板尺寸的精细彩釉石纹、 木纹图案产品， 并且产品可以任意按 施工要求尺寸进 切割， 本发明就形成了标准尺寸订货、 产、供、销、 物流、 可切割施工的全流程的便利性、 高效性和低成本的特征。 [2]由于本发明可 以比现有技术的钙钠平板玻璃和陶瓷板、 砖的约 50MPa的强度高出 2- 3倍， 即可优选达 90- 145MPa或 145-180MPa。 所以产品可以制得簿 2-3倍， 而有 同样的强度。 尤其是替代陶瓷产品， 这是现有一切彩釉玛骞克或钢化彩釉玻 璃作不到的。
(三）、 由于本发明制品可在 540°C- 730 °C烧结釉料，所以可以烧结印刷 釉层， "5Γ以在釉层加入大量的如 20- 65%的石英或刚玉晶体粉或粒， 史充前例 的形成 0. 2-3mm的耐磨表层高硬度（达 7级）， 而这在陶瓷中是作不到， 因 为陶瓷的烧成温度在 l l OO'C - 120(TC，此时陶瓷表层的石英只能变成玻璃相， 而在 600°C、 650°C、 7001：, 石英或刚玉还可保持晶相， 这就能史无前例的 形成装饰玻璃抛光的石荚晶体面表层， 或非抛光面形成刚玉晶体的耐磨防滑 层， 对陶瓷和石材的 [1]耐磨性能、 〖2]防滑性能、 [3]尤其抛光后表面的几 乎零吸水率和极高的防污性能、 [4]高强度及超薄性能、 [5]超轻超大板面制 品尺寸特征、 [6]上墙及干桂方式等形成了六大革命性的技术进步， 而且业 内人士都知道， 玻璃熔制工艺的粉尘比陶瓷制作工艺要少几十倍， 而且废料 的产生要少上百倍。 这会对整个陶瓷工艺装备的效率、 节能、 环保的进步。 本发明在环保上， 对陶瓷业的高耗能、 高污染、 高粉尘排放、 高水耗、 低产 出、 低品质的整个陶瓷装备工业系统产业的进步的趋势有革命性意义。
综上所述， 以上三个在建筑装饰产业， 尤其在陶瓷及装饰玻璃行业产品 和工艺中，人们一直渴望解决的^又未获得成功的三个重大技术难题的本发 明的技术方案和工艺方法， 并不是领域内技术人员只靠一般逻辑推理或者说 者简单实验能形成的技术方案或能达到的显而易见的技术效果，这说明本发 明具有显著实质性的技术进步， 所以本发明是具有创造性的。
现有技术的尤其是内外墙、 地面以及台面板、 厨拒面板等家居及工程应 用的装饰玻璃材料， 和本发明装饰玻璃相比较： 1、对于现有技术的装饰玻璃，其由于普通钙钠玻璃的退火点在 490 °C左 右， 而技术上又根本不可能批量生产 540°C以下的釉料（一则必须引入大量 的铅有剧毒， 二则成本极高， 三则不可能大生产）， 所以只能在 5cm尺寸以 下的玻璃玻赛克上印刷 （因为其尺寸极小， 在退火时不易爆裂）， 所以历史- 上从没生产过大尺寸的印刷无机釉玻璃板。 另外有用钢化技术在 750 以上 熔化釉料， 采用强化工艺解决退火应力问题。 但此种产品尺寸特定， 不可切 割， 在装饰工程应用中不能适应大众化标准板的可任意切割的应用施工、 搭 配等方便性特征需求的要求。 而且钙钠玻璃的强度差， 不能作地面应用， 又 有破损后边缘锋利、 不安全的缺陷。
而本发明技术：
[13 , 可以史无前例地高成品率， 低能耗、 ¾价值、 高强度、 轻薄型 (0. 5- 3mm厚度）、标准化尺寸地生产 2400 1200mm. 3000 x 1800mm的高精度 印刷釉图案， 包括石材紋、 木紋、 各类高级地毯图案（这是现有陶瓷及装饰 玻璃技术根本做不到的）。
[2]、 由于本发明制品可在 650°C以上烧结， 所以可以烧结印刷釉层， 可 以在釉层加入大量的如 30-80%的各种晶体尤其是成本低的石英或钢玉晶体 粉或粒， 形成史无前例的 0. 2- 3匪的耐磨表层高硬度（达 7级或 9级硬度）， 尤其是石英或钢玉在经 540°C到 70(TC的烧制， 会非常白， 这还可以史无前 例地首创零吸水率的超白的硬度达 7-9级的极耐磨的三者特征为一体的地面 应用品。 而且含石英晶体的表面层可以抛光为光洁层的耐磨制品， 含钢玉表 层的不抛光制品可以是最好的防滑耐磨的新功能装饰材料制品。 而这在 切 陶瓷产品、 工艺和装饰玻璃产品的现工艺中， 绝对是作不到的， 本发明是史 无前例的， 因为陶瓷的烧成温度在 1100°C-1200° (：， 此时陶瓷表层的石英或 钢玉只能变成玻璃相， 会变脆、 变为不耐磨、 变为透明.面的不可能超白的效 果； 而在本发明的 54Q°C- 73QX烧成温区， 石英还可保持结晶相， 这就能形 成史无前例的装饰破璃抛光的石英晶体面表层，对陶瓷或石材或装饰破璃表 层的耐磨性、 零吸水率、 零吸污率、 高度防滑性， 是革命性的挑战性的（防 滑能用于卫浴、 厨房地面、 地铁、 码头及一切人流量大的公共场所地面）， 可以形成节能环保、 低成本优质耐磨的替代升级技术。 而且会对陶瓷业的高 耗能、 高污染、 高粉尘排放、 高氷耗、 低产出、 低品质的制品及整个装备工 艺系统提出替代性挑战。 而且先有技术的一切陶瓷、 装饰玻璃技术， 从来没 有公开或关注过以上的本发明技术方案和能非显而易见的实质性袜术效果。 -
2、 比较本发明的表层印刷或布料晶体层产品， 现有技术的人造石类制 品， 其产量及功效低， 成本高， 其一条生不线曰产仅在 200-300 m2， 而浮法 线工艺加二次烧成工艺的日产可达 3万 -8万 m3。
3、 现有的铝塑板装饰材料， 而本发明加铝的复合板， 可以克服其在外 墙使用因塑板被日晒后膨胀收缩严重变形和图案印刷为有机材料，所以不能 作外墙的缺陷。 本发明加铝的复合板有图案精细， 永不褪色， 平整度极好， 而且能和铝塑板一样安装简便， 成本大大下降、 工效大大上升的优点。 而且 还可以更筒便地不用干挂龙骨架， 节约大量安装材料和工时， 直接用膨胀钉 固定在墙体上， 再在边缝打胶， 形成石材干挂装修效果。 而且先有技术的一 切陶瓷、装饰玻璃技术， 从来没有公开或关注过以上的本发明技术方案和能 非显而易见的实质性技术效果。
4、 对于先有技术的装饰图案塑料类面板， 本发明尤其 0. 3腿- 1. 6mm超 薄厚度制品， 用于台面、 卫厨面板、拉门面、 家俱贴面， 有强度好， 硬度高， 超薄、 超轻， 耐磨度好， 图案效果好， 平整度挺刮度好， 耐腐、 防水 防潮 湿起层、 阻燃、 安全、 环保等综合优势。
现有的所有先有彩釉基板玻璃技术，都从来没有公开或注重或揭示本发 明的釉料性质和根据本发明的基板玻璃的技术方案组成的 种组合发明的 整体技术方案。尤其现有的所有先有彩釉基板玻璃技术，从 "单独对比原则" 惯例来讲，都从来没有公开或注重或揭示过根据本发明第一实施例的技术方 案， 尤其是有关基板玻璃的技术方案及玻璃的退火温度下限（即唳热峰起点 温度）特征和釉料的熔点的技术方案， 所以本发明制品不但可以取代许多建 筑陶瓷产品， 由于其制造工艺完全不同于国际国内现代陶瓷生产线工艺装备 技术， 尤其是不采用其中的水法球磨工序、 喷雾工序、 陶瓷压机工序、 抛光 工序等高能耗、 高污染、 高耗水的环节； 还由于工艺的创新和成熟性， 强度 是陶瓷的 2-3倍（陶瓷为 50MPa， 本发明制品可达 130-160MPa )， 可生产仅 2-2. 3mm厚度的超薄产品， 就取代现代建筑陶瓷板只能生产最薄为 6匪厚度 的工艺的产品（现代成熟技术大量生产的瓷砖是 9-15薩厚度的产品）。所以， 本发明工艺对现代陶瓷而言， 可以： ①节能【油、 电、 煤】达 60%-80%； ②由 于产品只为 2-5mm厚、 比传统的工艺要抛光磨掉 1mm厚度的 10mm的现代陶 瓷产品，节约原材料 50-80%;③节水达 80%;④ GDP二氧化碳排放降低 60-80%; ⑤由于可采用大板的大木框包装， 比较现在陶瓷的纸箱、 泡沫箱， 节约包装 成本 50%以上。
所以本发明不但技术方案不是一种事后认为的用简单的逻辑推理或者 简单试验就可以形成的真有新颖性的技术方案， 而其技术效杲也不是能显而 易见达到的技术效果。 而且这正是近十到二十年， 全球建筑装饰玻璃行业、 建筑装饰陶瓷行业、 装饰板行业的数千家企业和数十万技术人员， 都在研究 解决的而一直没有解决的问题。 由于本发明之技术方案解决在玻璃基板上附 着熔点在 540 °C- 730 °C的彩色釉料； 有预定的必不可少的特别范围内的氧化 钠、 氧化铁、 氧化铝、 氧化硅、 氧化钙、 氧化镁、 或还有氧化钛、 氧化钡的 成份以及预定的氧化硅、 氧化钙、 氧化镁之间的特殊比例关系的成份的创新 技术方案； 克服了各种传统的组成助溶成份和共熔体成份的技术偏见， 并能 产生蓣料不到的助溶或共熔休功能以及产生的制品强 A上升 1-3倍、 环倮、 节能减排等的技术效果； 不加入有环保危害的氧化硼成份时， 本发明之除粘 度优势和强度优势的存在之外， 能产生实用性的环保， 大量的节能， 减少二 氧化碳排放， 使各种平板玻璃制品轻薄化， 尤其比较无碱高硼玻璃， 提高装 备生产寿命 6- 10倍产生的节约成本和扩大产能 10- 20倍，及产品轻量化 3-6 倍后的原料资源的数倍节约、 内陆和远洋运输的物流及仓储的 3-6倍的节能 和成本的下降等技术效果是对产业和行业性的难题的重大技术贡献的上迷 之对全球装饰建材产业而开拓的装饰玻璃新材料的产业领域及可替代陶瓷 板砖产品的技术发展趋势之人们渴望解决而又一直没有获得成 的重大技 术难题和本说明书提到的还有许多其它人们渴望解决而叉没有获得成功的 由于彩釉料的熔点创新和这种基板玻璃的应变点优良的线性膨胀系数特征、 低粘度、 高强度特征， 才能实现有产品的大尺寸标准板、 大板、 超薄板、 高 强度板、 超白又零吸水率又高硬度极耐磨高防污特征的板材、 精细图案印刷 板材、 精细图案印刷耐磨板材、 超薄高强度玻璃复合板材等无前例的各有特 征的新型装饰材料的各种技术难题。
上述预料不到的技术效果， 克服了多种现有技术偏见， 尤其是在低硼、 低铝（如含量在 1-2%以下时）退火温麾不能上升的技术偏见， 尤其是|过对 玻璃的退火温度下限（即吸热峰起点温度）的更新技术性盾， 并且由于采用 了一种 变技术要素的比例关系的改变发明和选择发明及因发现在彩釉平 板玻璃用途中的一种转用发明中产生了新产品熔制、 排泡、 澄清、 均化、 成 型与拉薄等工艺阶段的粘度温度、 强度、 厚薄差及新发现的助熔或共熔体等 性质， 和由此产生的可加大氧化铝含量使强度可上升 1-2倍的性质， 而这几 个产品' t生质还能同时在产板彩釉产品中兼有 , 而且加上特珠的熔化温麾的釉 切现有技术的彩釉制品比较，产生了多层次发明加上组合发明的一种事先无 法推测、无法预测和推理出来的上述多种技术效果，产生了技术效果的 "质" 和 "量" 的变化， 说明技术方案是非显而易见的， 具有突出实质性特点和显 著的技术进步， 所以本发明具有创造性。
以上所述， 仅是为了说明本发明较佳优选实施例而已， 其并非是对本发 明的限制，任何熟悉本项技术的人员可能利用上述揭示的技术内容加以变更 或修饰为等同变化的等效实施例，都可以按不同要求和性能实施一种高退火 温度高强度的环保节能型的低熔点彩釉装饰平板玻璃及制备方法。 可见， 凡 是未脱离本发明技术方案的内容， 尤其是权利要求之内容， 依据本发明的技 术实质对以上实施例所作的任何简单修改， 等同变化与修饰， 均仍属本发明 技术方案的范围内。

Claims

权 利 要 求 书
1、 一种高退火温度高强度的环保节能型的低熔点彩釉装饰平板玻璃， 其基板玻璃表面的 1-10种色彩的彩釉层的熔化点在 54(TC-73(TC，其制品的 基板玻璃的特征在于： 该基板玻璃包含氧化硅、 氧化钙、 氧化镁、 氧化铝、 氧化铁、 氧化钠的成份， 按重量百分率计， 在该基板玻璃中氧化硼的含量为 0-3.9%, 氧化钠的含量为 0.01-14%, 氧化铁含量为 0.01-5%， 氧化氟的含量 为 0-2.8%, 氧化镁含量为 8.1-22.2%， 氧化铝含量为 0.01-39%, 其氧化硅的 含量是氧化钙含量的 1.9倍 -4.1 倍， 氧化钙的含量是氧化镁的含量的 1.2 倍- 1.6倍；
其基板玻璃的厚薄差小于 0.3mm;
其基板玻璃的吸水率在 0-0.3%的范围内；
其基板玻璃的抗折强度达 50-180Mp;
其基板玻璃的退火温度下限（即吸热峰起点温度）为 55(TC-71{rC。
2、 根据权利要求 1 所述的^"种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重百分率计， 氧化铝 的含量是 0.01-30%, 氧化硅： 氧化钙为 2.0-3.6 倍， 氧化钙: 氧化镁为 1.3-1.49倍， 氧化钠为 0.01- 2%,氧化硼为 0-1%， 氧化氟的含量是 0-1%; 该 基板玻璃的退火温度下限（即吸热峰起点温度）为 61(TC-7i(TC; 该基板玻 璃在粘度为 10。.5 (帕 ·秒）时的温度为 1500"C-1640oC; 粘度为 101 (帕 ·秒 ) 时的温度为 145CT :- l5g()sC; 粘度为 1CI2 (帕 ·秒）时的温度为 l l0 :-1350 "C; 粘度为 103 (帕 ·秒）时的温度为 107{rC-1230°C; 该基板玻璃的抗折强 度为 50- 180MPa。
3、 根据权利要求 1所述的一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重百分率计， 氧化铝 的含量是 8-30%，氧化硅：氧化钙为 2.0-3.6倍，氧化钙:氧化镁为 1.3-1.49 倍， 氧化钠为 0.01- 2%,氧化硼为 0-1%, 氧化氟的舍量是 0-1%; 该基板玻璃 的退火温度下限（即吸热峰起点温度）为 61(TC- 68(TC; 该基板玻璃在粘度 为 10°·5 (帕 ·秒）时的温度为 1520°C- 1640°C; 粘度为 101 (帕 .秒）时的温 庹为 145{TC-1580°C; 粘度为 102 (帕 -秒）时的温度为 1210°C- 135(TC; 粘 度为 103 (帕 ·秒） 时的温度为 1070°C-123{rC; 该基板玻璃的抗折强度为 75-180MPa。
4、 根据权利要求 1 所述的一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重百分率计， 氧化铝 的含量是 19-30%,氧化硅：氧化钙为 2.0-3.6倍，氧化钙：氧化镁为 1· 3-1.49 倍， 氧化钠为 0.01-2%，氧化硼为 0-1%， 氧化氟的含量是 0-1%; 该基板玻璃 的退火温度下限（即吸热峰起点温度）为 610°C- 680'C; 该基板玻璃在粘度 为 10β·5 (帕 .秒）时的温度为 1550°C- 1640°C; 粘度为 101 (帕 *秒）时的温 度为 1450°C-1580°C; 粘度为 102 (帕 ·秒）时的温度为 1210°C-1350°C; 粘 度为 103 (帕 .秒） 时的温度为 108{TC-1230°C; 该基板玻璃的抗折强度为 130- 180MPa。
5、 根据权利要求 1 所迷的一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于： 按重百分率计， 氧化铝 的含量是 0.01-19%， 氧化硅： 氧化钙为 2.0-3.6 倍， 氧化钙： 氧化镁为 1.3-1.49倍， 氧化钠为 0.01- 2%，氧化硼为 0-1%, 氧化氟的含量是 0-1%; 该 基板玻璃的退火温度下限（即吸热峰起点温度）为 610°C- 680°C; 该基板玻 璃在粘度为 10。 5 (帕 ·秒 )时的温度为 1500。C- 1580。C; 粘度为 101 (帕 ·秒 ) 时的温度为 1450°C- 1520°C; 粘度为 102 (帕 ·秒）时的温度为 1210°C- 1310 °C; 粘度为 103 (帕 ·秒）时的温度为 107(TC- 1160Ό; 该基板玻璃的抗折强 度为 50- 145MPa。
6、 根据权利要求 1 所述的一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃， 其制品的基板玻璃特征在于：
(1 )、 按重量百分率计， 其基板玻璃含量中： ①氧化镁占 7-20%, ②氧 化钙是氧化镁的 1.0倍 -1.8倍的范围内， ③氧化硅是氧化镁的 2.6倍 -5.6 倍的范围内， ④氧化硅是氧化钙的 2.2 倍- 3.8 倍的范围内， ⑤氧化铝为 0.1-30%, ⑥氧化钠为 0-18%， ⑦氧化钡为 0-5%;
(2)、 其制品的基板玻璃的应变点温度在 560°O72{TC的范围内； ( 3 )、 其制品的基板玻璃的吸水率在 0-0.001%的范围内；
(4)、 按重量百分率计， 其制品的基板玻璃的中氧化镁、 氧化钙、 氧化 硅三种成份的含量总和达 51%-100%。
7、 根据权利要求 1-6的任一项权利要求所述的一种高退火温度高强度 的环保节能型的低熔点彩釉装饰平板玻璃的制备方法， 其特征在于： 步骤 1， 根据权利要求 1-6的任一项所述的制品的基板玻璃组分配置所 需的各种有预定的必不可少的特别范围内的氧化钠、 氧化铁、 氧化铝、 氧化 硅、 氧化钙、 氧化镁、 或还有氧化钛、 氧化钡的成份以及预定的氧化硅、 氧 化 、 氧化鎂之间的特殊比例关系的成份的创新技术方案的原料， 经混合搅 拌之后对应于各玻璃配方的熔化温度熔化， 形成可控的粘度和优化的低粘度 的玻璃液， 再均化， 澄清， 排出气泡， 形成可流动的熔融体；
步骤 2 , 釆用浮法工艺、 平拉工艺、 格法工艺、 压延工艺、 溢流法工艺 中任一种工艺对玻璃进行成型，经冷却工序制得高退火温度高强度的环保节 能型的低熔点彩釉装饰平板玻璃的基板玻璃；
步骤 3， 对成.型的制品的基板玻璃的表面印刷或施布上一层由 1 种或
2 - 10种色彩的熔点为 540°C-730°C的彩色釉料形成装饰层。
8、 根据权利要求 1所述的一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃， 其特征在于： 其制品的复合板是由一种高退火温度高 强度的环保节能型的低熔点彩釉装饰平板玻璃 ( 1 )和粘合材料层（ 2 )以及 0. 1- lmm或 1_5蘭厚度的金属板材 ( 3 ) 复合组成。
9、 根据权利要求 1所述的一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃， 其特征在于： 按重量百分率计， 其基板玻璃中氧化铝 的含量小于等于 30%， 该基板玻璃在粘度为 l ( 5 (帕 ·秒）时的温度为 1480 °C-1640°C ; 粘度为 101 (帕 '秒）时的温度为 1410°C- 1600°C ; 粘度为 (帕 .秒） 时的温度为 1180°(：-1340°(：； 粘度为 103 (帕 .秒） 时的温度为 1040 °C-1220 °C ; 该基板玻璃的厚薄差小于 0. 3薩； 该基板玻璃的吸水率在 0-0. 3%的范围内； 该基板玻璃的应变点温度在 56{TC-72{TC的范围内； 该基 板破璃的杬折强度为 50-180MPa; 该基权玻璃的热膨胀系教在 15{TC-300°C 的两端数值的差别为百万分之 1. 0-百万分之 3. 0; 在 550°C- 60(TC的两端数 值的差别为百万分之 1. 0-百万分之 2. 8。
10、根据权利要求 1所述的一种高退火温度高强度的环保节能型的低熔 点彩釉装饰平板玻璃，其特征在于： 其表层的釉料层中含有 20- 70%的石英晶 体或氧化铝晶体。
PCT/CN2011/000413 2010-03-18 2011-03-15 彩釉平板玻璃及其制备方法 WO2011113305A1 (zh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP11755622.5A EP2687492A4 (en) 2011-03-15 2011-03-15 FLAT GLASS WITH COLORED GLASS LAYER AND METHOD FOR ITS MANUFACTURE
US13/985,501 US20150050461A1 (en) 2010-03-18 2011-03-15 Plate glass with colorful glaze layer and manufacuring process thereof

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
CN201010126584 2010-03-18
CN201010126584.9 2010-03-18
CN201010160301 2010-04-30
CN201010160301.2 2010-04-30
CN201010516817.6 2010-10-15
CN201010516817 2010-10-15

Publications (1)

Publication Number Publication Date
WO2011113305A1 true WO2011113305A1 (zh) 2011-09-22

Family

ID=44648442

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2011/000413 WO2011113305A1 (zh) 2010-03-18 2011-03-15 彩釉平板玻璃及其制备方法

Country Status (2)

Country Link
US (1) US20150050461A1 (zh)
WO (1) WO2011113305A1 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108545946A (zh) * 2018-06-29 2018-09-18 佛山石湾鹰牌陶瓷有限公司 一种防滑砖及其制备方法
CN116102265A (zh) * 2021-11-09 2023-05-12 南京伟胜天成玻璃有限公司 一种彩釉玻璃制造方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150299027A1 (en) * 2010-03-18 2015-10-22 Dening Yang Energy-saving and environment protective method for preparing glass with high intensity
CN106458707B (zh) * 2014-05-21 2019-12-06 Ａｇｃ株式会社 无碱浮法平板玻璃及无碱浮法平板玻璃的制造方法
US11427498B2 (en) 2019-03-06 2022-08-30 Owens-Brockway Glass Container Inc. Three-dimensional printing of a porous matrix on a container
US11697608B2 (en) * 2019-10-01 2023-07-11 Owens-Brockway Glass Container Inc. Selective chemical fining of small bubbles in glass
CN111099815A (zh) * 2019-12-31 2020-05-05 江苏福坤玻璃有限公司 一种超白防火玻璃的加工制造方法
CN111470754B (zh) * 2020-04-09 2022-04-15 惠州市彩玉微晶新材有限公司 一种微晶玻璃压延上色的方法及其制品加工工艺
CN111896505A (zh) * 2020-06-24 2020-11-06 天津大学 一种原位、非破坏、便携式的古代青砖主要元素检测方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3929497A (en) * 1973-01-31 1975-12-30 Fiberglas Canada Ltd Crystallizable glass suitable for fiber production
CN1053047A (zh) 1990-01-05 1991-07-17 日本电气硝子株式会社 具有天然大理石状表面花纹的结晶玻璃及其生产方法
US20020011080A1 (en) 1996-08-21 2002-01-31 Nippon Electric Glass Co., Ltd. Method of producing an alkali-free glass
CN1722347A (zh) * 2004-07-15 2006-01-18 日本电气硝子株式会社 平面显示装置用玻璃基板
JP2009167089A (ja) * 2007-12-19 2009-07-30 Nippon Electric Glass Co Ltd ガラス基板

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3723082A (en) * 1971-01-06 1973-03-27 Corning Glass Works Sheet glass thickness control
US4440810A (en) * 1982-04-22 1984-04-03 Corning Glass Works Method for decorating low-expansion ceramic articles
DE3433408A1 (de) * 1984-09-12 1986-03-20 VEGLA Vereinigte Glaswerke GmbH, 5100 Aachen Farbfritte fuer emailartige dekorschichten auf floatglasscheiben
US5244484A (en) * 1990-04-03 1993-09-14 Asahi Glass Company, Ltd. Process for producing a curved glass plate partially coated with a ceramic
DE4241411C2 (de) * 1992-12-09 1995-05-11 Schott Glaswerke Auf Borosilikatglas oder Glaskeramiksubstrate aufgebrachte Dekorschichten aus keramischen Farben und Verfahren zu ihrer Herstellung
JP3173679B2 (ja) * 1992-12-21 2001-06-04 セントラル硝子株式会社 車輌窓ガラス用セラミックカラー組成物及びそれを用いた車輌窓ガラスの製法
AU1995595A (en) * 1994-03-16 1995-10-03 Ferro Corporation Lead-free glass enamels for decorating glass beverage containers and methods for using the same
US5976678A (en) * 1996-02-27 1999-11-02 Nippon Sheet Glass Co., Ltd. Colored film-covered glass articles
FR2757150B1 (fr) * 1996-12-12 1999-01-22 Saint Gobain Vitrage Procede d'emaillage de substrats en verre, composition d'email utilisee et produits obtenus
EP1029827A4 (en) * 1997-11-13 2003-07-09 Nippon Sheet Glass Co Ltd ULTRAVIOLET / INFRARED ABSORBENT GLASS, ULTRAVIOLET / INFRARED ABSORBENT GLASS PANEL, ULTRAVIOLET / INFRARED ABSORBENT GLASS PANEL COATED WITH A COLORED FILM, AND VEHICLE GLAZING
EP1013619A1 (fr) * 1998-12-22 2000-06-28 Glaverbel Substrat en verre coloré portant un revêtement
EP1013620A1 (fr) * 1998-12-22 2000-06-28 Glaverbel Verre sodo-calcique à nuance bleue
US6346493B1 (en) * 1999-10-27 2002-02-12 Ferro Corporation Decorative glass enamels
DE10030388A1 (de) * 2000-06-21 2002-01-03 Schott Glas Verfahren zur Herstellung von Glassubstraten für elektronische Speichermedien
BE1013994A3 (fr) * 2001-03-06 2003-01-14 Glaverbel Vitrage pour vehicule.
DE102004052568B4 (de) * 2004-10-29 2012-02-02 Schott Ag Dünnglas-Substrat und Verfahren zur Herstellung von Dünnglas
WO2006109450A1 (ja) * 2005-04-05 2006-10-19 Matsushita Electric Industrial Co., Ltd. ガラス板及びテレビ台
WO2007112426A2 (en) * 2006-03-28 2007-10-04 Ppg Industries Ohio, Inc. Low solar absorbing blue glass, solar reflecting coated blue glass, and insulating unit having a low solar heat gain
EA019049B1 (ru) * 2008-09-01 2013-12-30 Сэн-Гобэн Гласс Франс Способ получения стекла и полученное стекло
FR2945985B1 (fr) * 2009-05-27 2011-05-20 Saint Gobain Vitrage a faible niveau de double image.
FR2997391B1 (fr) * 2012-10-30 2014-11-21 Eurokera Plaque en verre pour dispositif de cuisson par induction

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3929497A (en) * 1973-01-31 1975-12-30 Fiberglas Canada Ltd Crystallizable glass suitable for fiber production
CN1053047A (zh) 1990-01-05 1991-07-17 日本电气硝子株式会社 具有天然大理石状表面花纹的结晶玻璃及其生产方法
US20020011080A1 (en) 1996-08-21 2002-01-31 Nippon Electric Glass Co., Ltd. Method of producing an alkali-free glass
CN1722347A (zh) * 2004-07-15 2006-01-18 日本电气硝子株式会社 平面显示装置用玻璃基板
JP2009167089A (ja) * 2007-12-19 2009-07-30 Nippon Electric Glass Co Ltd ガラス基板

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108545946A (zh) * 2018-06-29 2018-09-18 佛山石湾鹰牌陶瓷有限公司 一种防滑砖及其制备方法
CN108545946B (zh) * 2018-06-29 2021-04-27 佛山石湾鹰牌陶瓷有限公司 一种防滑砖及其制备方法
CN116102265A (zh) * 2021-11-09 2023-05-12 南京伟胜天成玻璃有限公司 一种彩釉玻璃制造方法

Also Published As

Publication number Publication date
US20150050461A1 (en) 2015-02-19

Similar Documents

Publication Publication Date Title
WO2011113305A1 (zh) 彩釉平板玻璃及其制备方法
CN103466957B (zh) 彩釉平板玻璃、制备方法及其复合板
CN115010465B (zh) 一种低温快烧陶瓷岩板及其制备方法
CN106830684B (zh) 一种反射隔热陶瓷釉面砖的制备方法
CN104003700B (zh) 一种利用废矿渣制备环保型陶瓷玻化砖的方法
WO2017084194A1 (zh) 一种热膨胀率的低差值、超高强度、高软化点、高应变点的平板玻璃的应用
CN101066837A (zh) 一种环保高耐热乳白晶瓷玻璃及其制备工艺
EP2687492A1 (en) Plate glass with colorful glaze layer and manufacuring process thereof
CN104193165B (zh) 一种组合物在有环保和节能减排的高强度、低粘度特征的平板玻璃中的应用
CN109704583A (zh) 一种微晶玻璃及其生产方法
CN108409133A (zh) 光伏玻璃瓦用光伏玻璃及制造工艺
CN111848225A (zh) 一种具有金属光泽的瓷砖生产工艺及瓷砖和金属干粒釉料
CN101412576A (zh) 一种薄型微晶玻璃墙面装饰板材的工艺方法
CN102070297A (zh) 一种高抗冲击和高抗折的特高铝硅酸盐板材及工艺方法
WO2011113302A1 (zh) 平板玻璃及其制备方法
CN106746667B (zh) 一种节能免烧透明釉料及其制备方法
CN209685571U (zh) 一种生产微晶玻璃的专用设备
WO2016086501A1 (zh) 一种高温区热膨胀系数的低差值、低析晶速度、超高强度、高软化点、防火防爆平板玻璃的应用
CN107265866B (zh) 一种以高炉熔渣为主原料的金星微晶玻璃及其制备方法
CN106567078B (zh) 一种金星搪瓷的制备方法
JP2009173526A (ja) 模様入り結晶化ガラス物品及びその製造方法
WO2016054872A1 (zh) 一种高软化点、高温区热膨胀系数的低差值、低析晶速度、防火防爆平板玻璃的应用
CN114249586A (zh) 具有立体闪光效果的黑色瓷砖及其制备方法
RU2583393C2 (ru) Плоское стекло и его способ изготовления, а также жидкокристаллические дисплеи и солнечные фотоэлектрические устройства
CN102079624A (zh) 一种在块或粒图案中有高含量晶体的板材及工艺方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11755622

Country of ref document: EP

Kind code of ref document: A1

WPC Withdrawal of priority claims after completion of the technical preparations for international publication

Ref document number: 201010126584.9

Country of ref document: CN

Date of ref document: 20120224

Free format text: WITHDRAWN AFTER TECHNICAL PREPARATION FINISHED

Ref document number: 201010160301.2

Country of ref document: CN

Date of ref document: 20120224

Free format text: WITHDRAWN AFTER TECHNICAL PREPARATION FINISHED

Ref document number: 201010516817.6

Country of ref document: CN

Date of ref document: 20120224

Free format text: WITHDRAWN AFTER TECHNICAL PREPARATION FINISHED

DPE2 Request for preliminary examination filed before expiration of 19th month from priority date (pct application filed from 20040101)
NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2011755622

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 13985501

Country of ref document: US