Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2/00—Disinfection or sterilisation of materials or objects, in general; Accessories therefor
  • A61L2/16—Disinfection or sterilisation of materials or objects, in general; Accessories therefor using chemical substances
  • A61L2/18—Liquid substances
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2/00—Disinfection or sterilisation of materials or objects, in general; Accessories therefor
  • A61L2/02—Disinfection or sterilisation of materials or objects, in general; Accessories therefor using physical processes
  • A61L2/03—Electric current
  • A61L2/035—Electrolysis
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2/00—Disinfection or sterilisation of materials or objects, in general; Accessories therefor
  • A61L2/16—Disinfection or sterilisation of materials or objects, in general; Accessories therefor using chemical substances
  • A61L2/22—Phase substances, e.g. smokes or aerosols
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2/00—Disinfection or sterilisation of materials or objects, in general; Accessories therefor
  • A61L2/24—Apparatus using programmed or automatic operation
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2/00—Disinfection or sterilisation of materials or objects, in general; Accessories therefor
  • A61L2/26—Accessories
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B1/00—Electrolytic production of inorganic compounds or non-metals
  • C25B1/01—Products
  • C25B1/13—Ozone
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B1/00—Electrolytic production of inorganic compounds or non-metals
  • C25B1/01—Products
  • C25B1/24—Halogens or compounds thereof
  • C25B1/26—Chlorine; Compounds thereof
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B1/00—Electrolytic production of inorganic compounds or non-metals
  • C25B1/01—Products
  • C25B1/28—Per-compounds
  • C25B1/30—Peroxides
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2103/00—Materials or objects being the target of disinfection or sterilisation
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2103/00—Materials or objects being the target of disinfection or sterilisation
  • A61L2103/05—Living organisms or biological materials
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
  • A61L2202/10—Apparatus features
  • A61L2202/11—Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
  • A61L2202/10—Apparatus features
  • A61L2202/14—Means for controlling sterilisation processes, data processing, presentation and storage means, e.g. sensors, controllers, programs
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E10/00—Energy generation through renewable energy sources
  • Y02E10/50—Photovoltaic [PV] energy

Definitions

• the invention relates to a system for producing and releasing a solution suitable for use in human hygiene, in particular to a point-of-use electrochemical system for production and release of a solution suitable for washing and disinfecting hands.
• the invention consists of a device suitable for producing and nebulising an oxidant solution having disinfecting properties, comprising a rigid body provided with a recess for the insertion of the hands, an electrochemical cell equipped with a timer su itable for producing an oxidant solution by electrolysis of an aqueous electrolytic medium during a predefined time, means for nebulising said oxidant solution inside said recess for hand insertion, at least one probe su itable for detecting hand insertion inside said recess and an actuator suitable for commanding the upload of a predefined volume of said aqueous electrolytic medium inside said electrochemical cell and the timed execution of said electrolysis, wherein the probe and the nebul ising means are connected to an electronic control board commanding the nebulisation of the prod uct oxidant sol ution based on the detection of the probe .
• the device of the invention may be used for example to produce in an efficient and cost-effective way oxidant solutions contain ing species such as active chlorine, ozone or peroxides, characterised by a high antibacterial action at the time of production but having a much too sharp time decay to allow their concentration being guaranteed even in the short term .
• active ch lori ne m ay advantag eously be used i n form of a hypochlorite and hypochlorous acid mixture at equilibrium, at a concentration preferably comprised between 20 and 300 ppm; below 20 ppm, the antibacterial action results in fact less efficient, wh ile at too high concentrations the aggressive action may result excessive for the human skin .
• a solution containing 300 ppm of active chlorine would nevertheless have an insufficient stability to be stored and suppl ied as a product for dispenser refill, unless either stabilised with caustic soda at concentrations unsuitable for application on human skin or provided in form of organic species characterised by a slow release of chlorine, which are more toxic and remarkably more expensive.
• the in- situ point-of-use production of an oxidant solution containing active chlorine can have the advantage of being directly obtained at a concentration suitable for use with no stabil isation needed .
• Oxidant solutions containing active chlorine produced by electrolysis of alkali chloride brines, for example sodium chloride may also contain a small amount of active oxygen, for example ozone or peroxide traces, which are then quickly decomposed. This can have the advantage of further increasing the efficiency of the antibacterial or biocide action of the product solution.
• the actuator of the device allows uploading a predefined volume of an electrolytic aqueous medium - for example a brine of an alkali metal chloride such as sodium or potassium chloride - to the electrochemical cell and subjecting the same to electrolysis; in one embodiment, the predefined volume of electrolyte is comprised between 1 and 20 ml. In one embodiment, the electrolysis of the electrolytic medium is carried out for a time comprised between 1 and 5 seconds until a suitable concentration of oxidant species, for example from 20 to 300 ppm of active chlorine with optional traces of ozone or peroxides, is attained.
• a suitable concentration of oxidant species for example from 20 to 300 ppm of active chlorine with optional traces of ozone or peroxides
• the insertion of the hands in the recess after operating the actuator and the completion of the electrolysis are detected by a suitable probe, which in one embodiment consists of a photocell; when the insertion of the hands is detected, the electronic control board receives the signal of the probe and commands the actuation of the nebulisation means, for example consisting of an atomiser, through which the electrolytically-produced oxidant solution is sprayed on the hands.
• a suitable probe which in one embodiment consists of a photocell
• the electronic control board when the actuator is operated for a predefined number of times, for example 2 to 5 times, with no corresponding hand insertion in the appropriate recess being detected, the electronic control board anyway commands the nebulisation of the produced oxidant solution .
• Th is can have the advantage of avoid ing that, upon repeatedly operating the actuator command ing the electrolysis of the electrolytic medium , an excessive accumu lation of the oxidant solution ta kes place or the concentration thereof is increased to excessive values.
• the actuator be operated in a rapid sequence for more than three consecutive times in order to prevent the concentration of active chlorine in the oxidant solution exceeding 300 ppm, which is considered the upper limit of the optimum interval.
• the invention consists of a device suitable for producing and nebulising an oxidant solution having disinfecting properties, comprising a rigid body provided with a recess for the insertion of the hands, an electrochemical cell provided with a timer, suitable for producing an oxidant solution by electrolysis of an aqueous electrolytic medium during a predefined time, means for nebulising said oxidant solution inside said recess for hand insertion, at least one probe suitable for detecting hand insertion inside said recess and an actuator suitable for commanding the upload of a predefined volume of said aqueous electrolytic medium inside said electrochemical cell, the timed execution of said electrolysis, wherein also the electrochemical cell , in addition to the probe and nebulisation means, is connected to an electronic control board which commands the upload of a predefined volume of electrolytic solution, the subsequent timed execution of electrolysis inside the electrolytic cel l and the subsequent nebulisation of the product oxidant solution on the basis of the detection of the probe, optionally consisting
• the device may not comprise a further actuator as said function is carried out by the probe suitable for detecting the hand insertion.
• the predefined volume of electrolyte may be comprised between 1 and 20 ml and the electrolysis of the electrolytic medium may be carried out for a time comprised between 1 and 5 seconds until a suitable concentration of oxidant species is attained, for example 20 to 300 ppm of active chlorine, with optional traces of ozone or peroxides.
• the composition of the product oxidant solution may be varied by acting on the composition of the aqueous electrolytic medium and on the nature of the electrodes, in particular of the anode, installed in the electrolytic cell, as will be evident to a person skilled in the art.
• the generation of hypochlorite or hypochlorous acid may be obtained by using diluted sodium chloride brines, optionally acidulated to shift the equilibrium towards the hypochlorous acid species, and titanium anodes activated with catalysts based on oxides of transition metals such as ruthenium, iridium, palladium, titanium, zirconium or tantalum; likewise, it is possible to produce solutions containing ozone (for example starting from tap water with anodes based on mixed oxides of tin and antimony or with deionised water with boron-doped diamond anodes), oxygen peroxide (for example from acid or alkaline electrolytes in cells provided with an air-fed gas-diffusion electrode) or active chlorine and mixed peroxidates
• the concentration of the oxidant species in the product solution may be adjusted by acting on the active surface of the electrodes, on the current density, on the electrolysed volume and on the electrolysis duration; a person skilled in the art can easily determine the most favourable parameters for the preparation of the oxidant solution in a suitable composition range.
• oxidant solutions containing active chlorine can have the advantage of providing a product with optimum disinfecting properties starting from an extremely cheap and handy electrolytic medium with reduced electrolysis times also for small size electrolytic cells: for example, a load of 6 ml of a simple sodium chloride solution at 1 -10 g/l can generate 20-300 ppm of active chlorine in a time range of 1 to 2 seconds with a total anodic area of 6 to 21 cm 2 at a current density of 1 to 2 kA/m 2 .
• the sodium chloride solution may be uploaded to the device by means of a dispenser bottle like those commonly used for drinking water distribution, housed inside the rigid body or positioned external ly thereto, for example above the device, and put in flu id communication with the cell.
• the sodium chloride solution may be fed through disposable cartridges.
• the sodium chloride brine may be prepared at the time of use, for example by dissolving a pre-dosed amount of sodium chloride, optionally as powder or tablet, in a predefined volume of water.
• the device is powered from grid, rechargeable batteries or solar panels, taken alone or in mutual combination.
• figure 1 shows the scheme of an embodiment of the device for hand disinfection according to the invention.
• a device for hand disinfection comprises a rigid body 1 provided with a recess for hand insertion 2 of suitable dimensions; inside rigid body 1 , an actuator 6, for example a start button optionally connected to a central process unit, commands the upload of a predefined quantity of electrolyte, for example a salt solution contained in a dispenser bottle 7, to an electrochemical cell 4 and the subsequent timed execution of an electrolytic process inside the same cell 4 at a predefined current density.
• a predefined quantity of electrolyte for example a salt solution contained in a dispenser bottle 7
• a suitable probe for example a photocell 3 detects the hand insertion and sends a signal to an electronic control board 8, which in turn activates the nebulisation means, for example consisting of an atomiser 5, in communication with the outlet of electrochemical cell 4 and fed with the product of the timed electrolysis consisting of an oxidant solution contain ing species with high antibacterial activity at a suitable concentration.
• the nebulisation means for example consisting of an atomiser 5
• the product of the timed electrolysis consisting of an oxidant solution contain ing species with high antibacterial activity at a suitable concentration.
• a device equivalent to the one illustrated in figure 1 was equipped with an undivided electrolytic cell provided with titan ium anodes coated with a mixture of oxides of titanium, palladium, ruthenium and iridium, arranged face-to-face at a distance of 0.15 mm and characterised by a total surface of 21 cm 2 .
• the cell was fed with a solution containing 4 g/l of sodium chloride contained in a dispenser bottle positioned above the rigid body and connected thereto by means of a calibrated loading device, commanded by a central process unit.
• the cell was also provided with an outlet for the gaseous byproducts, interfaced to a relief valve engaged on the upper surface of the rigid body.
• the process central unit was set to alternately operate one of the two electrodes as anode and the other as cathode, reversing the polarity at every next operation of the start button provided as the actuator.
• the apparatus was run by setting a load volume of 6 ml of electrolyte, varying the duration and current density of the electrolytic process.
• An electrolysis time of 2 seconds at a 2000 A/m 2 current density proved sufficient to generate an oxidant solution contain ing 300 ppm of active chlorine, mostly as hypochlorite ion, together with peroxide traces.
• the electronic control board commanding the atomiser was set to discharge the product solution five seconds after pushing the start button, even in case the hand insertion in the apparatus were not detected by the photocell.
• a person skil led in the art can easily make several changes to the described embodiments, without deviating from the scope of the invention; as said before, by acting on the electrolyte composition and the type of electrodes, different compositions of oxidant solution can be easily obtained as needed. It is also possible to substitute the undivided cell of the example, wherein each of the electrodes alternately works as anode and as cathode, with a cell provided with a separator (for example with a ceramic separator or with an ion-exchange membrane) and with non-interchangeable anode and cathode, optionally of distinct formulations.
• a separator for example with a ceramic separator or with an ion-exchange membrane

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• Health & Medical Sciences (AREA)
• Chemical & Material Sciences (AREA)
• Epidemiology (AREA)
• Life Sciences & Earth Sciences (AREA)
• Animal Behavior & Ethology (AREA)
• General Health & Medical Sciences (AREA)
• Public Health (AREA)
• Veterinary Medicine (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Inorganic Chemistry (AREA)
• Engineering & Computer Science (AREA)
• Electrochemistry (AREA)
• Materials Engineering (AREA)
• Metallurgy (AREA)
• Organic Chemistry (AREA)
• Apparatus For Disinfection Or Sterilisation (AREA)
• Water Treatment By Electricity Or Magnetism (AREA)
• Endoscopes (AREA)
• Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
• External Artificial Organs (AREA)

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Citations (10)

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• 2010
  • 2010-01-28 IT IT000109A patent/ITMI20100109A1/it unknown
• 2011
  • 2011-01-21 TW TW100102194A patent/TWI513442B/zh not_active IP Right Cessation
  • 2011-01-26 MX MX2012007566A patent/MX2012007566A/es active IP Right Grant
  • 2011-01-26 WO PCT/EP2011/051078 patent/WO2011092211A1/en not_active Ceased
  • 2011-01-26 PL PL11701134T patent/PL2528628T3/pl unknown
  • 2011-01-26 JP JP2012550430A patent/JP5870038B2/ja active Active
  • 2011-01-26 BR BR112012018371-0A patent/BR112012018371B1/pt not_active IP Right Cessation
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  • 2011-01-26 KR KR1020127021578A patent/KR101911375B1/ko active Active
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  • 2011-01-26 MA MA35146A patent/MA34003B1/fr unknown
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  • 2011-01-26 EP EP11701134.6A patent/EP2528628B1/en active Active
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  • 2011-01-26 ES ES11701134.6T patent/ES2557114T3/es active Active
  • 2011-01-27 AR ARP110100278A patent/AR084668A1/es active IP Right Grant
• 2012
  • 2012-05-24 IL IL219982A patent/IL219982A/en active IP Right Grant
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