WO2011066270A2 - Hydrogénation de matières carbonées solides à l'aide de catalyseurs mixtes - Google Patents

Hydrogénation de matières carbonées solides à l'aide de catalyseurs mixtes Download PDF

Info

Publication number
WO2011066270A2
WO2011066270A2 PCT/US2010/057773 US2010057773W WO2011066270A2 WO 2011066270 A2 WO2011066270 A2 WO 2011066270A2 US 2010057773 W US2010057773 W US 2010057773W WO 2011066270 A2 WO2011066270 A2 WO 2011066270A2
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
carbonaceous material
zinc
coal
metal
Prior art date
Application number
PCT/US2010/057773
Other languages
English (en)
Other versions
WO2011066270A3 (fr
Inventor
Alexander E. Kuperman
Jinyi Han
Original Assignee
Chevron U.S.A. Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron U.S.A. Inc. filed Critical Chevron U.S.A. Inc.
Priority to CA2781416A priority Critical patent/CA2781416A1/fr
Publication of WO2011066270A2 publication Critical patent/WO2011066270A2/fr
Publication of WO2011066270A3 publication Critical patent/WO2011066270A3/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086Characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20Sulfiding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Cette invention concerne des systèmes et des procédés de conversion d'une matière carbonée solide en un produit liquide, comprenant le maintien d'une matière carbonée solide en présence d'au moins une source active de zinc à une température de réaction supérieure à 350°C et à une pression se situant dans la plage de 300 à 5 000 livres par pouce carré au manomètre pendant une durée suffisante pour former un produit liquide.
PCT/US2010/057773 2009-11-24 2010-11-23 Hydrogénation de matières carbonées solides à l'aide de catalyseurs mixtes WO2011066270A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2781416A CA2781416A1 (fr) 2009-11-24 2010-11-23 Hydrogenation de matieres carbonees solides a l'aide de catalyseurs mixtes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/625,390 US20110120914A1 (en) 2009-11-24 2009-11-24 Hydrogenation of solid carbonaceous materials using mixed catalysts
US12/625,390 2009-11-24

Publications (2)

Publication Number Publication Date
WO2011066270A2 true WO2011066270A2 (fr) 2011-06-03
WO2011066270A3 WO2011066270A3 (fr) 2011-11-24

Family

ID=44061314

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/057773 WO2011066270A2 (fr) 2009-11-24 2010-11-23 Hydrogénation de matières carbonées solides à l'aide de catalyseurs mixtes

Country Status (3)

Country Link
US (1) US20110120914A1 (fr)
CA (1) CA2781416A1 (fr)
WO (1) WO2011066270A2 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CO5980161A1 (es) * 2008-09-02 2008-11-28 Univ Nac De Colombia Proceso de preparacion de catalizadores utiles en la licuefaccion directa de carbon y el catalizador asi obtenido
CN113617296B (zh) * 2020-05-08 2023-08-25 北京机械设备研究所 一种二氧化碳催化加氢系统及方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223698A (en) * 1961-01-09 1965-12-14 Inst Noguchi Method for liquefying lignin
US4441983A (en) * 1982-08-19 1984-04-10 Air Products And Chemicals, Inc. Zinc sulfide liquefaction catalyst
US4617106A (en) * 1985-07-26 1986-10-14 Air Products And Chemicals, Inc. Catalysts for coal liquefaction processes

Family Cites Families (80)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3645885A (en) * 1970-05-04 1972-02-29 Exxon Research Engineering Co Upflow coal liquefaction
US4077667A (en) * 1974-04-08 1978-03-07 Allerheiligen Arnold G Means for cushioning wooden pews or the like
AU506174B2 (en) * 1976-05-28 1979-12-13 Kobe Steel Limited Coal liquefaction
US4077867A (en) * 1976-07-02 1978-03-07 Exxon Research & Engineering Co. Hydroconversion of coal in a hydrogen donor solvent with an oil-soluble catalyst
US4155832A (en) * 1977-12-23 1979-05-22 The United States Of America As Represented By The United States Department Of Energy Hydrogenation process for solid carbonaceous materials
US4369106A (en) * 1980-04-10 1983-01-18 Exxon Research And Engineering Co. Coal liquefaction process
US4450066A (en) * 1980-09-02 1984-05-22 Exxon Research And Engineering Co. Hydrothermal pretreatment to prevent scale during liquefaction of certain solid carbonaceous materials
JPS5761082A (en) * 1980-09-30 1982-04-13 Kobe Steel Ltd Liquefaction of coal
US4485008A (en) * 1980-12-05 1984-11-27 Exxon Research And Engineering Co. Liquefaction process
US4417972A (en) * 1981-11-04 1983-11-29 Exxon Research And Engineering Co. Recovery of coal liquefaction catalysts
US4401549A (en) * 1981-11-17 1983-08-30 Uop Inc. Liquefaction of calcium-containing coals
US4447972A (en) * 1981-12-15 1984-05-15 Mccabe Stanley G Laundry spreader, counter, and folder
US4401550A (en) * 1982-01-11 1983-08-30 Uop Inc. Liquefaction of calcium-containing coals
US4485006A (en) * 1982-03-04 1984-11-27 Exxon Research And Engineering Co. Start-up method for a hydrorefining process
US4434043A (en) * 1982-06-01 1984-02-28 Exxon Research And Engineering Co. Recovery of catalyst from coal liquefaction residues
US4578176A (en) * 1982-06-09 1986-03-25 Institute Of Gas Technology Fuel production by free fall countercurrent flow
JPS59109588A (ja) * 1982-12-15 1984-06-25 Kobe Steel Ltd 褐炭の液化方法
IT1163480B (it) * 1983-06-08 1987-04-08 Anic Spa Procedimento a piu' stadi per la liquefazione diretta del carbone
US5484755A (en) * 1983-08-29 1996-01-16 Lopez; Jaime Process for preparing a dispersed Group VIB metal sulfide catalyst
US5094991A (en) * 1983-08-29 1992-03-10 Chevron Research Company Slurry catalyst for hydroprocessing heavy and refractory oils
US4573176A (en) * 1983-11-18 1986-02-25 Rca Corporation Fractional frequency divider
US4493761A (en) * 1983-12-05 1985-01-15 Standard Oil Company (Indiana) Catalytic hydroliquefaction using a Cr-Mo-Group VIII catalyst
US4917791A (en) * 1984-06-01 1990-04-17 Kang Chia Chen Chu Process and catalysts for hydroconversion of coal or petroleum asphaltene to distillate liquids
US4595486A (en) * 1985-02-01 1986-06-17 Allied Corporation Electrochemical gas sensor
US4617105A (en) * 1985-09-26 1986-10-14 Air Products And Chemicals, Inc. Coal liquefaction process using pretreatment with a binary solvent mixture
US4824568A (en) * 1986-05-16 1989-04-25 Millipore Corporation Composite ultrafiltration membranes
US5236881A (en) * 1986-08-22 1993-08-17 Coal Industry (Patents) Limited Coal extract hydrocracking catalyst
US4923836A (en) * 1987-07-16 1990-05-08 Union Oil Company Of California Ni/Cu absorbent/catalyst for desulfurization and isomerization of N-paraffins
US4824558A (en) * 1987-09-04 1989-04-25 Exxon Research And Engineering Company Coal liquefaction process with metal/iodine cocatalyst
US4831003A (en) * 1987-09-14 1989-05-16 Exxon Research And Engineering Company Catalyst composition and process of making
US5051389A (en) * 1987-09-16 1991-09-24 Exxon Research And Engineering Company Catalyst composition prepared by vapor depositing onto a carbon support
US4948523A (en) * 1987-09-30 1990-08-14 Amoco Corporation Chlorine-free silver protective lubricant composition (I)
US4816141A (en) * 1987-10-16 1989-03-28 Hri, Inc. Catalytic two-stage liquefaction of coal utilizing cascading of used ebullated-bed catalyst
CA1317585C (fr) * 1988-02-02 1993-05-11 Chandra Prakash Khulbe Procede d'hydrocraquage de produits petroliers lourds, en presence de bouillie de fer-charbon
US5070064A (en) * 1989-08-07 1991-12-03 Exxon Research And Engineering Company Catalyst pretreatment method
US5336395A (en) * 1989-12-21 1994-08-09 Exxon Research And Engineering Company Liquefaction of coal with aqueous carbon monoxide pretreatment
US5151173A (en) * 1989-12-21 1992-09-29 Exxon Research And Engineering Company Conversion of coal with promoted carbon monoxide pretreatment
US5183561A (en) * 1990-01-25 1993-02-02 Mobil Oil Corp. Demetallation of hydrocarbon feedstocks with a synthetic mesoporous crystalline material
JPH04505472A (ja) * 1990-02-15 1992-09-24 アモコ・コーポレイシヨン 石炭液化前処理
US5015366A (en) * 1990-04-10 1991-05-14 The United States Of America As Represented By The United States Department Of Energy Process and apparatus for coal hydrogenation
US5039392A (en) * 1990-06-04 1991-08-13 Exxon Research And Engineering Company Hydroconversion process using a sulfided molybdenum catalyst concentrate
US5200063A (en) * 1990-06-21 1993-04-06 Exxon Research And Engineering Company Coal hydroconversion process comprising solvent enhanced pretreatment with carbon monoxide
US5001369A (en) * 1990-07-02 1991-03-19 Micron Technology, Inc. Low noise output buffer circuit
BR9004200A (pt) * 1990-08-24 1992-03-03 Petroleo Brasileiro Sa Processo de desparafinacao de formacoes produtoras
US5336441A (en) * 1991-05-29 1994-08-09 Petrolite Corporation Corrosion inhibition in highly acidic environments by use of pyridine salts in combination with certain cationic surfactants
US5246570A (en) * 1992-04-09 1993-09-21 Amoco Corporation Coal liquefaction process using soluble molybdenum-containing organophosphorodithioate catalyst
GB2267233B (en) * 1992-05-15 1996-09-04 Nikki Universal Co Ltd Hydrodesulfurization catalyst and preparation thereof
US5783065A (en) * 1992-09-03 1998-07-21 University Of Utah Research Foundation Method for coal liquefaction
US5338441A (en) * 1992-10-13 1994-08-16 Exxon Research And Engineering Company Liquefaction process
US5344553A (en) * 1993-02-22 1994-09-06 Mobil Oil Corporation Upgrading of a hydrocarbon feedstock utilizing a graded, mesoporous catalyst system
US5332489A (en) * 1993-06-11 1994-07-26 Exxon Research & Engineering Co. Hydroconversion process for a carbonaceous material
US5389230A (en) * 1993-06-11 1995-02-14 Exxon Research & Engineering Co. Catalytic hydroconversion process
US5489375A (en) * 1994-06-08 1996-02-06 Amoco Corporation Resid hydroprocessing method
JP3338190B2 (ja) * 1994-08-17 2002-10-28 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
US5489875A (en) * 1994-09-21 1996-02-06 Simon Fraser University Adaptive feedforward linearizer for RF power amplifiers
US5464034A (en) * 1994-09-27 1995-11-07 Kestin; Hesh Pocket-portable rain covering
US5573556A (en) * 1994-11-03 1996-11-12 Exxon Research And Engineering Company Conversion of solid carbonaceous material using polyoxoanions
US5620591A (en) * 1994-12-22 1997-04-15 Exxon Research & Engineering Company Hydroconversion process with plug-flow molybdenum catalyst concentrate preparation
JP2853612B2 (ja) * 1995-08-30 1999-02-03 日本電気株式会社 半導体記憶装置
US6139723A (en) * 1996-02-23 2000-10-31 Hydrocarbon Technologies, Inc. Iron-based ionic liquid catalysts for hydroprocessing carbonaceous feeds
US6190542B1 (en) * 1996-02-23 2001-02-20 Hydrocarbon Technologies, Inc. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds
JP3715729B2 (ja) * 1996-10-21 2005-11-16 株式会社神戸製鋼所 石炭の液化方法
US5728656A (en) * 1997-03-20 1998-03-17 Chevron Chemical Company Lower-ash lubricating oil having ultra-neutral zinc dialkyldithiophosphates
US5744026A (en) * 1997-04-10 1998-04-28 Eastman Chemical Company Catalyst system and process for benzyl ether fragmentation and coal liquefaction
US6153155A (en) * 1997-12-31 2000-11-28 Exxon Research And Engineering Company Recovery of the transition metal component of catalyst used in heavy feed hydroconversion
US6064043A (en) * 1999-06-01 2000-05-16 France/Scott Fetzer Company Dryer control circuit
US7095708B1 (en) * 1999-06-23 2006-08-22 Cingular Wireless Ii, Llc Methods and apparatus for use in communicating voice and high speed data in a wireless communication system
US6153156A (en) * 1999-08-02 2000-11-28 Gnb Technologies, Inc. Method for purifying leady oxides
US6569516B1 (en) * 1999-12-10 2003-05-27 Nitto Denko Corporation Transparent laminate and plasma display panel filter utilizing same
US6551965B2 (en) * 2000-02-14 2003-04-22 Chevron Oronite Company Llc Marine diesel engine lubricating oil composition having improved high temperature performance
GB0011115D0 (en) * 2000-05-09 2000-06-28 Infineum Int Ltd Lubricating oil compositions
TW504497B (en) * 2000-05-23 2002-10-01 Sumitomo Chemical Co Alpha-alumina powder and heat-conductive sheet containing the same
DE10143742A1 (de) * 2001-09-06 2003-03-27 Consortium Elektrochem Ind Verfahren zur Herstellung von alpha-Halogenketonen
US7163911B2 (en) * 2003-05-22 2007-01-16 Chevron Oronite Company Llc Carboxylated detergent-dispersant additive for lubricating oils
US20050043191A1 (en) * 2003-08-22 2005-02-24 Farng L. Oscar High performance non-zinc, zero phosphorus engine oils for internal combustion engines
ITMI20032207A1 (it) * 2003-11-14 2005-05-15 Enitecnologie Spa Procedimento integrato per la conversione di cariche contenenti carbone in prodotti liquidi.
US8030258B2 (en) * 2005-07-29 2011-10-04 Chevron Oronite Company Llc Overbased alkaline earth metal alkylhydroxybenzoates having low crude sediment
JP3920304B1 (ja) * 2005-11-22 2007-05-30 株式会社神戸製鋼所 低品位炭を原料とする固形燃料の製造方法および製造装置
US8460407B2 (en) * 2008-02-13 2013-06-11 David Walker Taylor Form of coal particles
US8123934B2 (en) * 2008-06-18 2012-02-28 Chevron U.S.A., Inc. System and method for pretreatment of solid carbonaceous material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3223698A (en) * 1961-01-09 1965-12-14 Inst Noguchi Method for liquefying lignin
US4441983A (en) * 1982-08-19 1984-04-10 Air Products And Chemicals, Inc. Zinc sulfide liquefaction catalyst
US4617106A (en) * 1985-07-26 1986-10-14 Air Products And Chemicals, Inc. Catalysts for coal liquefaction processes

Also Published As

Publication number Publication date
WO2011066270A3 (fr) 2011-11-24
US20110120914A1 (en) 2011-05-26
CA2781416A1 (fr) 2011-06-03

Similar Documents

Publication Publication Date Title
US8123934B2 (en) System and method for pretreatment of solid carbonaceous material
US8206577B2 (en) System and method for pretreatment of solid carbonaceous material
JP6097224B2 (ja) 水素化処理触媒を作製するための方法
US20110120915A1 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
Pradhan et al. Finely dispersed iron, iron-molybdenum, and sulfated iron oxides as catalysts for coprocessing reactions
EA016893B1 (ru) Объемный катализатор гидрогенизации и его применение
KR20130133817A (ko) 수소화처리 촉매 및 이의 제조방법
GB1576039A (en) Hydroconversion of an oil-coal mixture
US3165463A (en) Hydrorefining of crude oil and catalyst therefor
Mochida et al. Progresses of coal liquefaction catalysts in Japan
US20110120916A1 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
US20110120914A1 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
US20110120918A1 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
JPH02107335A (ja) 重油コークス操作に由来する石油コークスの存在下での重油の水素化分解
US20110120917A1 (en) Hydrogenation of solid carbonaceous materials using mixed catalysts
US5454934A (en) Coal liquefaction using atomically dispersed metals
EP2564924A2 (fr) Catalyseur ultra-dispersé et son procédé de préparation
Tian et al. Direct liquefaction of coal using ferric-sulfide-based, mixed-metal catalysts containing Mg or Mo
AU2015201948A1 (en) System and method for pretreatment of solid carbonaceous material
JPH05214345A (ja) 石炭の液化方法及びそれに用いる触媒組成物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10833848

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2781416

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 10833848

Country of ref document: EP

Kind code of ref document: A2