WO2011054298A1 - 综合处理生活污水和有机垃圾的方法及其设备 - Google Patents
综合处理生活污水和有机垃圾的方法及其设备 Download PDFInfo
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- WO2011054298A1 WO2011054298A1 PCT/CN2010/078402 CN2010078402W WO2011054298A1 WO 2011054298 A1 WO2011054298 A1 WO 2011054298A1 CN 2010078402 W CN2010078402 W CN 2010078402W WO 2011054298 A1 WO2011054298 A1 WO 2011054298A1
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- Prior art keywords
- stacking
- sewage
- supernatant
- tank
- biogas
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
- C02F3/305—Nitrification and denitrification treatment characterised by the denitrification
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M21/00—Bioreactors or fermenters specially adapted for specific uses
- C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M45/00—Means for pre-treatment of biological substances
- C12M45/04—Phase separators; Separation of non fermentable material; Fractionation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/24—Treatment of water, waste water, or sewage by flotation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/005—Black water originating from toilets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Definitions
- the invention provides a method for comprehensively treating domestic sewage and organic garbage, and a device for comprehensively treating domestic sewage and organic garbage, and can simultaneously treat domestic sewage and organic waste in an efficient and environmentally friendly manner, thereby achieving the goal of low pollution emission.
- Landfill and incineration are routine waste disposal methods. However, landfills not only occupy a large area, are difficult to locate, and are difficult to recover useful resources, but also leachate, malodor and landfill gas in the landfill process will cause harm to the surrounding environment; Increasingly, the initial investment and operating costs of landfill are also increasing. Although waste incineration can achieve the greatest reduction and harmlessness, it is not suitable because of the initial investment and operating costs, secondary pollution of incineration tail gas, and high requirements for raw material calorific value and water content. Used to treat organic waste.
- the treatment of fecal sewage mainly uses the natural discharge method to directly discharge the fecal sewage into the river channel, or use the septic tank to separate the sediment and discharge it into the sewer line, and then use the aerobic biological aeration process or the A2/0 sewage treatment process.
- the sewage treatment plant covers a large area, the air pollution is serious, and the sludge discharge problem is difficult to solve. In addition, improper use of garbage is actually a waste of resources.
- Chinese invention patent publication CN 13 M313A discloses a kind of fecal sewage, organic waste
- the integrated waste treatment device divides the human fecal sewage into the feces by flotation in the manure water separation tank, separates the sewage by the overflow method, and the separated feces overflow into the storage tank, and the organic garbage is crushed by the crusher. After being transported into the storage tank, the feces and organic waste in the storage tank are heated into the digestion tank to generate biogas.
- the method of the friendship mainly utilizes the anaerobic digestion of the separated and pulverized fecal waste, which has a long reaction time and low efficiency, and particularly requires a longer digestion time for substances which are difficult to digest under anaerobic conditions. In addition, some pollutants still exist after biogas fermentation and should not be directly discharged.
- Chinese Patent Publication No. CN 101 191 116 A discloses a combined fermentation tank comprising a stacking tank equipped with a heat exchanger and an internal circulation biogas reactor.
- the raw materials having solid form or viscous shape such as straw, grass, processed pomace, processed medicinal slag, etc., are directly poured into a stacking pond for stacking, and the acidified liquid produced by the fermentation passes through the grille at the bottom of the stacking pond.
- the biogas is produced by anaerobic fermentation through a discharge pipe into a biogas reactor. It is forgiven that the combined fermentation tank has a large area, a long reaction time, and is in contact with external systems, and is not suitable for the treatment of garbage in daily life.
- the stacking pond and the biogas reactor are always connected, which is not conducive to the anaerobic digestion reaction of the biogas counter-catheter, which is difficult to control and has low gas production efficiency.
- some pollutants still exist after biogas fermentation and should not be directly discharged.
- the invention provides a method and a device for comprehensively treating domestic sewage and organic waste; the invention can simultaneously treat domestic sewage and organic waste efficiently and environmentally, thereby achieving the goal of low pollution discharge and even substantially pollution-free discharge.
- the present invention provides a method of comprehensively treating domestic sewage and organic waste, including the steps of:
- Multi-phase separation Domestic sewage is separated into supernatant by superphase, floating liquid, sediment liquid, grid separation and exhaust gas, and the floating liquid, grid separation and organic waste are mixed and pulverized, and then mixed with the sediment liquid to become high.
- Concentrated sewage domestic sewage is separated into supernatant by superphase, floating liquid, sediment liquid, grid separation and exhaust gas, and the floating liquid, grid separation and organic waste are mixed and pulverized, and then mixed with the sediment liquid to become high.
- Biogas generation Biogas is generated from the supernatant of domestic sewage and the clinker clinker to generate and discharge biogas;
- step d Optional biological nitrogen and phosphorus removal: The biological denitrification and dephosphorization treatment of the water from the biogas generation step and/or the supernatant of step a is carried out to discharge clean water and organic fertilizer.
- the stack digestion is parallel stack digestion, using at least three parallel stack digestion units.
- the scum and/or sludge that are difficult to digest in the biogas generation and nitrogen and phosphorus removal processes are returned to the stacking step for review.
- the invention provides an apparatus for integrated treatment of biological sewage and organic waste, comprising a multiphase separation unit, a stacking unit, a biogas generating unit, and optionally a biological nitrogen removal and dedusting unit in series.
- the present invention provides a multiphase separation device for separating domestic sewage, including a domestic sewage water inlet, a stone removal chamber, a stone discharge port, an automatic separation composed of a shaped grid and a separation crucible.
- the present invention provides a method of multiphase separation of domestic sewage, comprising the steps of:
- the sewage flows vertically downwards, and the microbubbles generated by the microbubble generating device adsorb the suspended matter, raise it, and discharge the floating liquid, or use the sludge to adjust, adsorb the organic pollutants, accelerate the precipitation, and form a floating liquid with a light specific gravity. Separate and rise and discharge the floating tears; d.
- the sewage continues to descend, and the lower end of the vertical partition between the upper floating liquid chamber and the supernatant liquid chamber changes direction upwards, enters the supernatant liquid chamber, and the sediment remains at the bottom, and the sediment liquid is discharged. ;
- the supernatant is formed by the sewage, and the supernatant is discharged.
- the method and apparatus for comprehensively treating domestic sewage and organic waste of the present invention are widely used.
- the method of the invention is a full biotechnology process, adopting a complete set of equipment for factory production, fully enclosed operation, no leakage, no secondary pollution, and an innovative invention process.
- Figure 1 is a flow chart of a method for comprehensively treating domestic sewage and organic waste.
- Figure 2 is a multiphase separation device - process flow diagram.
- Figure 3 is a schematic diagram of the automatic grid device and the principle of stone separation.
- Figure 4 is a schematic diagram of the function of the multiphase separation device.
- Figure 5 is a parallel stacking digestion unit - process flow chart.
- Figure 6 is a schematic diagram of a powerful gas agitator.
- Figure 7 is a schematic diagram of the performance of biological activities during the stacking period.
- Figure 8 is a schematic diagram of the function of the parallel stacking digestion unit.
- Figure 9 is a high-efficiency biogas generating device - process flow chart.
- Figure 10 is a schematic diagram of the function of the efficient biogas generating device.
- Figure 1 1 is a biological nitrogen and phosphorus removal combined device - process flow chart.
- Figure 12 is a schematic diagram of a biological nitrogen and phosphorus removal combined device.
- Figure 13 shows a water sample of the separated supernatant, supernatant, and sediment.
- Figure 14 shows a micrograph of the supernatant.
- Figure 15 shows a photograph of the open mirror of the floating liquid.
- Figure 16 shows the microscopy of the infusion: a mirror image.
- Figure 17 is a flow chart of the process of double-tank series denitrification and phosphorus removal.
- Figure 18 is a flow chart of an apparatus and method for comprehensively treating domestic sewage and organic waste.
- Figure 19 is a schematic diagram of the equipment for comprehensive treatment of domestic sewage and organic waste. detailed description
- the domestic sewage mentioned here refers to any sewage generated during the life of human beings and is one of the main sources of pollution of water bodies.
- Domestic sewage is, for example, fecal sewage and/or washing sewage.
- Domestic sewage contains a lot of organic matter, such as cellulose, starch, sugar, fat and protein. : Also often contains pathogens, 'viruses and parasite eggs; inorganic salts such as chlorides, sulfates, phosphates, bicarbonates and sodium, potassium, calcium, magnesium and so on.
- the overall characteristics are high in nitrogen, sulfur and phosphorus: under the action of anaerobic bacteria, it is easy to produce odorous substances.
- the organic waste mentioned here refers to domestic garbage mainly composed of organic matter, mainly Paper, fiber, bamboo, kitchen garbage, etc.
- the kitchen garbage is a food residue produced by a family, a restaurant, a unit canteen, etc., and is composed of a degradable organic substance having a high water content and being easily spoiled. More than 50% of urban domestic waste is organic waste, and it is growing year by year.
- the integrated method for treating domestic sewage and organic waste of the present invention comprises four steps of multiphase separation, heaping, biogas generation and biological nitrogen and phosphorus removal (see Fig. 1).
- the domestic sewage and organic waste treatment method of the invention is a full biotechnology process, adopting a complete set of factory-produced equipment, fully enclosed operation, no leakage, no secondary pollution.
- the multiphase separation apparatus of the present invention comprises a pretreatment equipment Y, a pretreatment equipment tank II, a mixing pulverizer, a high pressure exhaust gas storage tank and a batch conveying device (see Fig. 2).
- a pretreatment equipment tank I and the tank II There is no connection between the pretreatment equipment tank I and the tank II, and there is no connection between the high pressure exhaust gas storage tank and the batch conveying device.
- the pretreatment equipment tank 1/tank II is connected to a mixing pulverizer, a high pressure exhaust gas storage tank and a batch conveying device, respectively, and the mixing pulverizer is connected to the batch conveying device.
- the pretreatment equipment tank I and the tank II are separate devices for separately separating the fecal sewage and the washing sewage.
- the pretreatment equipment tank I and tank II are respectively provided with a fecal/washing sewage inlet, a fecal/washing sewage exhaust outlet, a fecal/sewage supernatant outlet, a fecal/washing sewage floating liquid outlet, and a fecal/washing sewage grid separation outlet. And the feces/washing sewage sludge outlet.
- the mixing pulverizer is provided with an organic garbage feed port, a fecal/washing sewage floating liquid inlet, a fecal/washing sewage grid separation inlet, and a mixed pulverized material outlet.
- the high-pressure exhaust gas storage tank is provided with a fecal/washing sewage exhaust gas inlet, a high-pressure exhaust gas upper outlet 1 and a high-pressure exhaust gas upper outlet 2 .
- the batch conveying device has a mixing device, and the material conveying device is provided with a fecal/washing sewage sediment inlet, a mixed pulverized material inlet and a high-concentration sewage outlet.
- the pretreatment equipment tank is equipped with a sand separation device and an automatic grid separation device, including a domestic sewage water inlet, a sand separation chamber, a sand discharge port, a shaped grid, a grid separation outlet, a floating liquid chamber and a supernatant.
- Liquid chamber (see Figure 3).
- the water inlet is located at the upper part of the sand separation chamber, and the sand stone discharge port is located at the lower part of the sand separation chamber, and the slope for separating the sand stone is at an angle to the horizontal.
- the angle of the slope to the horizontal is not less than 30 degrees. In this hair In a preferred embodiment of the invention, the angle of the ramp to the horizontal is 30 degrees.
- the automatic grid separating device of the invention is composed of a special-shaped grid. Considering the complicated manufacturing process of the shaped grid and the high production cost, the automatic grid machine used in the invention can be produced by the engineering plastic molding process, thereby saving cost.
- the upper floating liquid chamber and the supernatant liquid chamber are located at the lower part of the pretreatment equipment, and the two chambers are separated by a vertical partition, and the volume of the supernatant liquid chamber is not to be smaller than the volume of the upper floating liquid chamber. In one embodiment of the invention, the volume of the supernatant chamber is three times that of the upper float chamber.
- a microbubble generating device is disposed in the middle of the upper floating chamber.
- a sludge regulating release device is provided in the middle of the upper floating liquid chamber, which for example is to be fed by biogas generated by a pump such as a Nikoni pump.
- the oxygen sludge and the bottom liquid are released for anaerobic sludge conditioning treatment, and the microbubble generating device itself can be used as a sludge conditioning release device.
- the sand and stone separating device of the invention can also be used together with the sand lifting machine, and the sand lifting machine can be designed by using the stripping principle, and the operation is convenient.
- an auxiliary tank is added before the pretreatment equipment tank, and the auxiliary tank is provided with a sand separation device and an automatic grid separation device, and the pretreatment equipment omits the sand separation device and the automatic grid Separation device.
- the mixing mill consists of 3 sets of rolls and 2 sets of high speed rotating tips.
- the first set of rolls consists of flat rolls
- the second set of rolls consists of radial rolls
- the third set of rolls consists of radial rolls.
- the mixing pulverizer also includes a high speed rotary knife pulverizing device.
- the multiphase separation pretreatment apparatus of the present invention further comprises one or more supernatant water volume adjustment tanks, and the supernatant water volume adjustment tank is connected to the supernatant liquid chamber.
- the volume of each supernatant water volume adjusting tank is, for example, 25 cubic meters, and the peak value of the absorbed sewage is, for example, three times the average water amount, and is adjusted to the low valley water supply.
- the supernatant water volume adjustment tank can be adjusted for up to 4 hours, for example, to meet system requirements.
- a fan such as a Roots blower (see Fig. 2) is further disposed between the pretreatment equipment tank and the high pressure exhaust gas storage tank, so that the entire system is free from odorous gas, and the effect is remarkable.
- both the pretreatment equipment tank I and the tank II are subjected to preliminary solid-liquid gas phase separation of the sewage by an automatic grid separation device. More specifically, the tank I separates the fecal sewage into fecal sewage waste gas, supernatant liquid, supernatant liquid, sediment liquid, and grid separator i tank II, and separates the washing sewage into washing sewage waste gas, supernatant liquid, supernatant liquid, and sediment.
- the multiphase separation technique of the present invention is composed of the following parts (see Fig. 3):
- the sandstone is first separated by the slope method using the principle that the specific gravity of the sandstone is the largest. ⁇ Shaoshi entering the system will cause damage to the equipment.
- the slope method can separate sandstones larger than 2 mm in diameter and then discharge the separated sand and gravel out of the system via a screw lifting device.
- the sand after de-sanding is separated by an automatic separation grid machine.
- the grid separator includes a profiled grille composed of a vertical section, a circular arc section and a slanted section, and a separating cymbal that moves in a circular motion by the mechanical belt.
- the separation enthalpy continuously smashes the separation from the front of the vertical section to the upper side of the circular arc section and through the inclined section to the outlet of the separation object.
- the grid separation is piped to the comminution unit.
- the grid machine operates continuously with a grid gap of less than 4 mm.
- the sewage in the above-mentioned sand removal and grid separation is laterally flowing above the pretreatment equipment tank.
- the sewage After passing through the grid, the sewage flows vertically downward to the upper floating chamber (also called the air flotation chamber), and a liquid bubble generating device is arranged in the upper floating chamber.
- the device uses the compressed exhaust gas as a gas source to make a diagonal jet in a circular cavity composed of a porous wall, so that the water body in the cavity is mixed with the gas to perform a high-speed rotary motion, and the centrifugal water and gas are simultaneously used by the hole wall. Cut and centrifuge the output to form tiny bubbles. Using tiny bubbles, the suspended matter of the sewage is adsorbed and raised to the slope-type slag collecting place to discharge the floating liquid.
- the microbubble generating device is placed in the middle of the upper floating liquid chamber, and the sewage after the air flotation treatment continues to descend.
- the sewage is taken up to the upper part and discharged as the supernatant.
- the distance from the sewage to the upstream or upward stroke of more than 5 m can separate the supernatant more effectively.
- the COD of the supernatant (chemical oxygen demand, CODcr, referred to as COD, in mg/L), T/P (general abbreviation for total phosphorus pollutants, unit is mg L), SS (short for total water suspended particles, unit
- the indicator for mg/L is greatly reduced.
- the float and supernatant are separated by a baffle, so the exit height can be the same.
- the advantage of the multiphase separation pretreatment device is that the principle of up and down movement of the water body is utilized efficiently, so the requirement for the standing time is extremely low. Moreover, except for the sediment liquid discharged from the bottom, the discharge of the vast majority of the sewage volume is only about 200 mm below the water inlet, and the water level loss is extremely small. The cost of raising the sewage level for post-treatment
- the amount of the floating liquid required in the subsequent organic garbage mixing process is larger than the output amount of the floating liquid, the sewage flowing down to the bottom is easily separated into the sediment liquid, and is not easily risen, and the sediment liquid is also continuously output. This ensures the quality of the supernatant. Moreover, no additives are required throughout the liquid separation process.
- the total water amount is a + b.
- the ratio of the amount of water a to the total amount of water (a + b ) of the mixture of the supernatant liquid and the sediment liquid does not exceed 5%.
- Organic waste enters the mixing mill through the feed port.
- the pretreatment equipment tank I and tank II separated fecal sewage and washing sewage grid separators enter the mixing mill.
- the three sets of rolls of the mixing mill and the two sets of high-speed rotating tips firstly pulverize the organic waste and the grid separation.
- the first set of rolls comminutes the possible fine sand and flattens the solids.
- the second set of rolls flatten the solid to form a fine natriene.
- the third set of rolls causes the strip solids to form dispersed particulate solids.
- the method of weighing the solid content (ie organic pollutants) is not more than 40%, which is convenient for the screw pump to output high concentration: sewage.
- the pretreatment equipment tank I and the exhaust gas in the tank are discharged through the exhaust port as a gas source for the air pump.
- the check valve compresses the exhaust gas to a gas storage tank with a height of more than 4 meters.
- the gas storage tank is installed vertically, and the gas containing sewage and particulate matter collects under the gas storage tank.
- the gas storage tank is divided into two upper and lower air outlets, the relatively clean upper air source is used for aerobic stirring of the denitrification and de-saling equipment, the lower air source is used for the initial aeration stirring of the stacking, or the pre-treatment microbubble generator The gas source is directly returned to the pretreatment supernatant chamber.
- the exhaust port of the pretreatment equipment tank I and the tank is connected to the inner chamber of the pulverizer through the grid separation passage Therefore, the feed port of the pulverizer is in a negative pressure state, and there is no problem of leaking odor gas at the feed port.
- the operation of the air pump is controlled by a pressure sensor, so that the air pump is always in continuous operation, so that the exhaust gas discharge port of the pre-treatment always has a gas source output, so that the feed port is in a negative pressure (intake).
- the method adopted is that when the pressure value of the pressure sensor is high to a certain value, the output pressure signal adjusts the power output frequency of the frequency converter. When the pressure is reduced, the inverter motor runs slower and the pump is in continuous operation.
- the operation of the multiphase separation unit is an automated process.
- the anaerobic biological sludge C sediment from the biogas generating equipment and the bottom liquid can be subjected to anaerobic sludge conditioning adjustment to improve the pretreatment separation.
- the living organic waste, the washing sewage and the fecal sewage are treated by the multiphase separation device into the washing sewage supernatant, the fecal sewage supernatant, the high concentration sewage, the high pressure exhaust gas 1 and the high pressure exhaust gas 2 (see Figure 4 ) .
- Pre-treatment microbubble generating device introduces different media: Pre-treatment The middle of the floating liquid chamber is equipped with a micro-bubble generating device, which directly introduces pressurized air to generate micro-bubbles and enhance the separation of the floating liquid chamber.
- the supernatant COD value was determined to be around 400 mg L.
- the SS value is around 300 mg/L. It shows that the flotation effect without flocculating agent is limited.
- a Nikini pump having a flow rate of 0.5 - 2 m 3 /h and a head of 15 m is introduced at the inlet of the microbubble generating device to introduce the sediment and the bottom liquid of the secondary settling tank, or The sediment and bottom liquid of the biogas generation tank are introduced.
- anaerobic sludge conditioning When the bottom sludge and bottom liquid of the biogas generation tank (referred to as anaerobic sludge conditioning) are introduced, the COD value of the supernatant is maintained below 200 mg/L, and the SS value is maintained below 160 mg/L.
- the COD of the sediment liquid is significantly higher than the COD of the supernatant liquid.
- anaerobic sludge has a gel coat
- the adsorption is better than that of aerobic sludge
- the sedimentation performance of anaerobic sludge is better than that of aerobic sludge.
- anaerobic sludge regulation has little effect on the adsorption and separation of dispersible oil droplets in raw water. This experiment is preferred for anaerobic sludge conditioning, which is most effective in improving the separation of pretreatments. 2.
- the stacking device of the present invention consists of a stacking digestion tank and seven sets of configurations (see Figure 5).
- the 7-group configuration is high-concentration sewage feed configuration A, scum return configuration B, gas agitation configuration C; sludge return configuration D, which contains a gas storage tank's decomposition gas output configuration E, clinker output configuration F and temperature control configuration 0.
- the seven groups of configurations contain valves eight, B, C, D, E, F, and G, respectively.
- the 7-group configuration is connected to the stacking digestion tank, and there is no connection between the 7 groups of configurations.
- the high-concentration sewage feed configuration A in the 7-group configuration, the scum return configuration ⁇ the gas agitation configuration C, the sludge return configuration D, and the temperature control configuration G are input configurations, respectively, high-concentration sewage, biogas tank scum, before The waste gas (high pressure waste gas 2), the biogas tank sludge/nitrogen and phosphorus removal tank sludge and the heat medium are transported to the stacking digestion tank.
- the other two sets of decomposition gas output configuration E and clinker output configuration F are output configurations: the decomposition gas and clinker generated in the digestion tank are separately output to the subsequent steps.
- the stacking digestion tank may also include a heat medium return port for recirculating the heat generated by the stack through the heat medium for subsequent steps.
- the lower part of the stacking digesting tank is also provided with a sand discharging port for discharging sand residue having a very low organic content.
- the number of stacking digesters determines the way in parallel.
- the parallel stacking device of the present invention comprises at least three stacking digestion tanks.
- the number of valves configured in the 7 sets matches the number of stacking digesters. Therefore, each of the seven sets of configurations also contains at least three valves.
- the number of parallel stacking digesters is determined by the amount of water and the concentration of the sewage. In order to keep the whole equipment in a continuous operation state, the tank is in a feeding state and the tank is in a discharging state while satisfying the stacking time of 2 to 3 days. If the number of tanks is increased, the number of parallel valves in the corresponding input and output devices will also increase. '
- the stack digestion unit employs three parallel stacks of digestion tanks I, II and III.
- the seven sets of configurations include three sets of valves corresponding to the digestion tanks I, ⁇ and III, namely the valves A1, A2 and A3 of the high-concentration sewage feed configuration A, the valves B1 and B2 of the floating-back flow configuration B, and B3, gas mixing configuration C valves Cl, C2 and C3, sludge back Valves D1, D2, and D3 of configuration D, valves El, E2, and E3 of decomposition gas output configuration E, valves F1, F2, and F3 of clinker output configuration F, and valves G1, G2, and G3 of temperature control configuration G.
- the stacking and digesting tank of the present invention is equipped with a powerful gas agitator installed at the middle bottom of the stacking digesting tank for aerobic stirring in the initial stage of stacking (see Fig. 6).
- the powerful gas agitator is made by the principle that the jet is used to centrifuge the pore walls to remove microbubbles.
- the size of the air vent depends on the diameter of the cylindrical cavity of the stacking digester. The diameter of the cylindrical cavity is larger and the air vent should be larger. The person skilled in the art knows how to determine the size of the air vent according to the size of the cylindrical diameter.
- An inclined sector plate is added to the bottom of the cylinder.
- the powerful gas agitator has a roll-up area of up to 6 m 2 .
- the high-concentration sewage separated in the multi-phase separation step is sent to the stacking digestion tank through the high-concentration sewage feed configuration A for stacking and digestion. Open the valve C of the gas agitation configuration C, introduce the exhaust gas separated in the multiphase separation step, and aerate the aeration using a powerful gas agitator, see the above-mentioned powerful gas agitator section.
- aerobic biosorption is carried out, and the hydrolysis and oxidation time is only 1 hour.
- aerobic organism + organic matter + 0 2 3 ⁇ 4 + C0 2 + N3 ⁇ 4 + energy (biodegradation reaction) aerobic organism + organic matter + 0 2 + energy - new biological cells + 0 2 (biosynthesis reaction)
- valve C When valve C is subsequently closed, the oxygen in the system is gradually consumed.
- the above biological reaction until oxygen is depleted, more than 70% of the organic matter is adsorbed, hydrolyzed, and oxidized by aerobic organisms.
- facultative organisms rely on endogenous respiration to replace aerobic organisms to further decompose organic matter, and generate C0 2 , H 2 0, NH 3 and polysaccharides.
- the reaction that occurs in the stacking digester actually involves the occurrence of aerobic bioactive periods.
- the adsorption reaction, the aerobic biological transition to the hydrolysis/oxidation reaction occurring during the anaerobic bioactive phase, and the anaerobic biological transition to the acidification/degradation reaction occurring during the anaerobic bioactive phase (see Figure 7).
- the length of the aerobic reaction time in the system depends on the opening time of the valve C. The longer the valve C is opened, the longer the reaction time for aerobic stack digestion occurs. Therefore, the length of aeration and agitation can be adjusted depending on the amount of sewage and the concentration of sewage. In a preferred embodiment of the invention, threshold C is turned off after one hour of opening.
- thermostable bacteria In the aerobic stacking process in nature, bacteria that are not resistant to high temperatures decompose easily degradable carbohydrates, fats, etc. in the organic matter, while releasing heat to raise the temperature, the temperature can reach 15 ⁇ 40. C. Then, the thermostable bacteria rapidly multiply. Under aerobic conditions, most of the proteins and fibers that are difficult to degrade continue to be oxidatively decomposed, and a large amount of heat is released to raise the temperature to 60-70. C. When the organic matter is basically degraded, the thermophilic bacteria stop growing due to lack of nutrients, and the heat production stops. The temperature of the stack gradually decreases when the temperature stabilizes at 40. C, the stacking is basically stable and forms humus.
- natural stacking can be used, preferably with a stacking temperature of 35 for natural stacking.
- Stacking agitation can reduce stacking time.
- the stacking digester can also be heated using a temperature control device, preferably to 55. C.
- the temperature rises from room temperature to 55. C takes about 1 day.
- the optimum temperature for aerobic digestion of aerobic organisms is 17 - 25.
- C its active period corresponds to the temperature at the beginning of heating.
- the main time period for stacking is the anaerobic bioactive period after 1 day, that is, the optimum temperature is 55.
- the temperature-controlled solenoid valve is automatically closed, and the high-temperature fermentation reaction is continued by using the self-heating principle of stacking.
- the temperature can be as high as 70. C.
- the gas generated in the stacking reaction enters the gas storage tank through the check valve for use in the next step of biogas generation.
- the gas generated by the digestion and decomposition of the organic matter gradually accumulates in the stack, and a certain pressure is gradually formed. Since the stacking tank is connected to the gas tank and then the gas agitator of the biogas generating tank is connected by the one-way valve, the guarantee is ensured.
- the gas is irreversibly transported, and the biogas from the biogas generation tank is discharged to a burning appliance (such as a biogas boiler, a biogas generator, etc.). Therefore, the pressure of the liquid in the gas tank of the biogas tank is about 0.07 Mpa.
- the gas storage tank is provided as a buffer device. Its pressure is between 0.07 and 0.1 Mpa.
- the stacking reaction time can determine the stacking reaction time according to the amount of sewage and the concentration of sewage. Between. In an embodiment of the invention, the anaerobic high temperature digestion time is 3 days.
- the stacking device comprises at least three stacking digestion tanks, so that there can be three different operating states at the same time to meet the requirements of 2 to 3 days of stacking time, enabling The entire device remains in continuous operation.
- the three operating states are: Heapback Status, Discharge Status, and Feed Status.
- the stack digestion unit employs three parallel stacks of digestion tanks I, II and III. The specific apparatus is described in the construction of three parallel stacking digestion tanks in the above specific embodiments.
- the stacking and digesting tank I is in a stacked state
- the stacking and digesting tank II is in a discharging state
- the stacking and dissipating flare III is in a feeding state.
- the operating procedures for a particular three stacking digestion tank are as follows: Stacking Digestion Tank I:
- the valve G1 is opened, the heat medium source enters the heating, and the temperature is raised to 55.
- the temperature control solenoid valve is automatically closed, the valve G1 can be closed at this time.
- the temperature inside the tank will continue to rise due to the self-heating of the stack, and the temperature can reach 70 Q C. ,
- valve E is the air pressure balance valve
- the gas in the feed tank is pressed to the discharge tank to reach the balance.
- the stacking liquid is discharged smoothly.
- Sand discharge There is a sand discharge port in the lower part of the stacking tank.
- the discharge of sand residue after stacking changes the traditional method of sanding and sand discharging before sewage treatment.
- the organic content of the discharged sand slag is extremely low, which is also an aspect of the process without secondary pollution.
- the switching of the feeding, stacking, and discharging processes is manually performed. It is inevitable to cause a short-term discontinuity. Because the supernatant separated by the multiphase separation pretreatment device in the process design directly enters the next processing procedure, it has a buffering effect on the entire device and does not affect the continuity of the entire device.
- the multi-group parallel stacking device also greatly improves the efficiency and operational flexibility of the entire device, and also greatly improves the time required for anaerobic digestion.
- the high pressure exhaust gas 2 is used for initial aeration agitation.
- the scum generated from the subsequent biogas generation step and the sludge from the biogas tank and the sludge generated in the nitrogen and phosphorus removal step are returned to the stacking tank for review, and finally the material is digested into a decomposition gas. And clinker.
- the biogas generating device of the present invention is composed of a batch conveying device and a biogas generating tank connected in series (see Fig. 9), and its operation is continuous and automatic.
- the ingredient delivery device contains a premixing device for mixing the fecal sewage supernatant and the stacked clinker separated by the multiphase separation device.
- the batching conveying device is provided with a stacking and decomposing pressure gas conveying pipe, a fecal sewage supernatant inlet, a stacking clinker inlet, a fecal sewage supernatant, and a stacking mixture of the clinker.
- the biogas generation may be provided with a stack of decomposition pressure gas inlets, a fecal sewage supernatant and a stack of clinker inlets, a heat medium input port, a dehydrated biogas outlet, a biogas tank outlet, a scum return port, The heat medium reflux outlet, the sludge regulating outlet and the sludge returning outlet, wherein the sludge regulating outlet and the sludge returning are; the district outlet may be the same outlet.
- the batch conveying device mixes the manure supernatant separated from the stack clinker and the multiphase separation device according to the mixing ratio and inputs the mixture into the biogas generating tank by the centrifugal pump, and the anaerobic organism Synthetic methane.
- the clinker digested by stacking is a raw material liquid which has been hydrolyzed and acidified to produce biogas.
- the fecal supernatant is also a raw material liquid for producing biogas which is easily absorbed by anaerobic organisms, and the ratio of the two does not affect the organic loading rate of biogas production.
- the clinker discharge per day of a stacking digesting tank is about 25 m 3 , while on the feces
- the clear liquid is approximately 80 m 3 per day and its ratio is approximately 1:3.2.
- the fecal supernatant acts to reduce the clinker temperature and dilute the clinker concentration.
- the fecal supernatant contains dissolved carbohydrates, amino acids, monosaccharides, etc., which are easily absorbed, digested and produced by anaerobic organisms to form decane and carbon dioxide.
- the decomposition gas is automatically stirred in the tank through a check valve and a gas agitator.
- the gas mainly contains,
- the anaerobic digestion reaction and products of the organic matter in the biogas generation tank equipment are as follows.
- Temperature is one of the important factors affecting anaerobic digestion.
- the temperature mainly affects the biochemical reaction rate of the microorganism and is therefore related to the decomposition rate of the organic matter.
- the medium temperature digestion temperature generally used is 30 ⁇ 38. C (preferably 33 ⁇ 35. C); high temperature digestion temperature is 50 ⁇ 55.
- biogas reaction is carried out using 35 C.
- anaerobic digestion requires a relatively stable temperature, for example, a daily change of less than ⁇ 2. C. The temperature abruptly changes too much, which causes equipment The gas production is stopped.
- the constant temperature method is to introduce a heated heat medium device and realize automatic control by a temperature controller, and the control precision is within ⁇ 1.
- the produced biogas is dehydrated and discharged by an expansion condensing dehydrator.
- the treated water is automatically flown to the next step for denitrification and dephosphorization.
- the operation process of the biogas generation tank device is automatic and continuous. Because of the former stacking process The sequence has completed the degradation of pollutants, the biogas generating tank device can withstand a large hydraulic load, the treated water content of organic matter is low, and the biogas production rate is also improved.
- the yield rate of biogas digesters for manure raw materials is 0.28 m 3 /m 3 . d according to the evaluation volume.
- the input raw materials are pretreated and pre-reacted biomass - fecal supernatant and stacked clinker, which are combined into a thin raw material liquid, and the total amount per day is 850.
- the average biogas production per day is 260 m 3
- the effective volume of biogas generation tank is 30 m 3 .
- the gas production rate is 0.3 mVm 3 . d.
- the gas production rate was calculated to be 8.6 m 3 /m 3 ⁇ d according to the reaction volume of the biogas tank.
- Scum return Most pollutants that are difficult to digest or need to be digested, most of which will appear in the biogas generation tank in the form of scum. Timely discharge for reclaiming can improve the conditions of biogas production, and also for non-digestible pollutants. Repeated cycle digestion, and finally a complete and complete treatment process is implemented in the equipment.
- Bio sludge recovery The remaining sludge from the biogas generation tank facility is sent to the stacking process for review. On the one hand, it supplements the need for biomass in the stacking. On the one hand, it creates an environment in which anaerobic organisms are self-acclimated, so that the organisms in the tank are mainly tropane-based, and the short-lived period is beneficial to increase the efficiency of biogas production.
- the aerobic organism has strong adsorption capacity, oxidation, and decomposing ability, and returns a large amount of aerobic biological sludge, and introduces aerobic gas agitation at the initial stage of the stacking to accelerate the adsorption, hydrolysis and oxidation processes in the initial stage of the stacking.
- anaerobic biological sludge When the stack enters the anaerobic period, a large amount of anaerobic biological sludge is introduced to rapidly acidify and degrade the treated sewage.
- the aerobic organisms and anaerobic organisms provide nutrients and generate a development environment during the reclamation process, and are digested and Domestication, reducing total sludge discharge. Sediment and bottom liquid reflux
- the sediment and the bottom liquid may be returned to the multiphase separation pretreatment tank by, for example, a nikoni pump, as an anaerobic mud water to anaerobic sludge conditioning of the sewage.
- a nikoni pump as an anaerobic mud water to anaerobic sludge conditioning of the sewage.
- the anaerobic stirring is performed using the stack decomposition gas, and the clinker produced by the stacking and the fecal supernatant separated by the multiphase separation device are mixed and generated by the high-efficiency biogas.
- the reaction generates anhydrous biogas that can be discharged, biogas tank treatment water, scum and sludge for back treatment, and the biogas reacts with a heat medium to generate heat for heat medium recirculation (see Figure 10).
- the nitrogen and phosphorus removal device includes a configuration device and a nitrogen and phosphorus removal device (see Fig. 11).
- the pre-mixing device for mixing the washing wastewater supernatant and the biogas tank treated water separated by the multi-phase separation device, and the flow passage of the high-pressure exhaust gas 1 is included in the disposition device.
- the configuration device is provided with a biogas tank treatment water inlet, a washing sewage supernatant inlet, a high pressure exhaust gas 1 inlet, and a biogas tank treatment water and a washing sewage supernatant liquid mixture outlet and a pretreatment exhaust gas upper outlet gas outlet nitrogen and phosphorus removal device.
- tank 1 and tank 2 included in one tank, or two or more tanks connected in series, such as tank 1 and tank 2, provided with biogas tank treatment water and washing sewage supernatant mixture inlet, high pressure exhaust gas 1 inlet, nitrogen vent outlet, clean water Emissions outlets, organic fertilizer recovery outlets and sludge return exports.
- the nitrogen and phosphorus removal apparatus comprises a tank 1 and a tank 2.
- the tank 1 is vertically divided into three chambers, including a plankton chamber, a biofilm device chamber, and an initial sediment chamber.
- the plankton chamber has a volume of 15 m 3 in which 5 m 3 of 1 cm x 1 cm x 1 cm square foam plastic is placed, and a powerful gas agitator is installed in the lower part, and is connected to the lower part of the biofilm device chamber.
- the upper part is connected with the device for releasing the nitrogen gas depleting body, and the nitrogen removal gas is evacuated through the venting tube.
- the square foam plastic is used as a carrier of the aerobic organism in the suspension chamber, and the concentration of the plankton is greatly increased, which is higher than that of the ordinary dispersed plankton biomass. 8 - 10 times, about 20 - 35 g / L.
- the inside and the other are tumbling in the room, and the dissolved oxygen in the water is obtained by fully contacting the water body, so that the efficiency of the biological treatment is improved.
- the secondary settling tank is a component of the nitrogen and phosphorus removal combined equipment.
- the effluent from the denitrification and dephosphorization tank contains a certain amount of SS and floating sludge, which must be precipitated before it can reach the discharge hydraulic power. National level A indicators.
- a tank having the same specifications as the nitrogen and phosphorus removal tank is designed as a secondary precipitation tank.
- the cross-sectional area of the rising chamber is 4 times that of the sinking chamber, and the upper part of the lower side sinking chamber is two water inlets, which are connected to the two water outlets of the nitrogen and phosphorus removing tank.
- the upper part of the rising chamber is the water outlet, and the discharged water after the sedimentation is discharged therefrom. When the water flow slowly descends to the bottom, the two streams merge into a single stream and begin to flow upward.
- the ascending water flow passes through a set of semi-circular tubular inverted mud layers to promote the separation of mud and water.
- the gap between the clear water and the semi-circular tubular mudguard layer continues to rise, and the sludge falls freely from the bottom.
- the water depth is designed to exceed 4.5 meters, and the sedimentation of mud water is improved.
- the semi-circular tubular mudguard layer will continue to sediment from the upper part of the sludge, and the smooth circular arc surface will slide down to the bottom by itself.
- the bottom of the secondary sedimentation tank has an outlet, and the pump is used to reflux 1/10 of the water inflow, and the sediment and the bottom liquid are refluxed, and combined with the biogas slurry output from the biogas generation tank to enter the nitrogen and phosphorus removal tank for recycling.
- the biogas tank treatment water and the washing sewage supernatant are mixed by the premixing device of the configuration device, and then enter the nitrogen and phosphorus removal device, and the relatively clean high pressure exhaust gas separated by the multiphase separation device is used for the aerobic stirring of the denitrification treatment. .
- the treated water enters the plankton chamber from the upper entrance and goes up to the biofilm through the bottom.
- a powerful gas agitator is also installed in the lower part of the biofilm chamber. Due to the blocking action of the biofilm carrier, the water flow with ultrafine bubbles generated by the agitator at this time can only move upward.
- the hydraulic force of the cutting action is formed on the surface of the biofilm, and oxygen is brought to the biofilm.
- the biofilm is detached and discharged upwards due to the effective use of the biofilm, the water force entrained by the bubble, which improves the environment of biological nascent metabolism and allows the distance of the biofilm carrier to be reduced to 10 mm.
- the biofilm carrier is made of warp knitted nylon cloth and installed vertically in an assembleable unit box.
- the box is installed in the tank at the site, and the effective area of the surface of the biofilm contacted by the water body reaches 1800 m 2 , and the biological thick skin can reach 250 - 300 g/L, and there is no blockage during processing.
- the oxygen-absorbing biological reaction relies on the biological surface part that is in contact with the water body, and its internal organisms are negligible.
- two powerful gas agitators use 1.5 M 3 /hour of gas, and the actual measured dissolved oxygen content of the treated water is > 1 ppm.
- the optimum temperature for aerobic biological reaction for nitrogen and phosphorus removal is 17 - 25 .
- C because of the treatment water output of the front biogas generation tank of the present invention reaches 35.
- C the ratio of the combined with the supernatant of the washing sewage is 1:1.5, and the range of the water temperature of the supernatant is related to the normal temperature, about 9-20. C, so the combined water temperature is about 19 - 26.
- the change between C and strong gas agitation has the effect of lowering the water temperature: Actually, the optimum temperature for the nitrogen and phosphorus removal reaction is satisfied.
- the water treated by the biofilm device chamber overflows from the upper portion and enters the initial sedimentary water chamber.
- the biological sludge adsorbing the undigested organic matter sinks to the bottom of the chamber, and the clean water from the upper mouth flows into the secondary sedimentation tank by the tooth-shaped water, and the sediment is again completed and discharged to the outside of the system.
- the remaining biological sludge of the tank 2 is transported to the stacking tank through the returning route. On the one hand, it satisfies the need for aerobic biomass of the stacking. On the other hand, the adsorbed organic matter is brought to the stack together, and the recycling process is further completed, and the reduction is performed. These contaminants have a residence time in the process of nitrogen and phosphorus removal and secondary precipitation.
- the effluent quality chemical aerobic index (CODcr) and living oxygen consumption index (BODs) can reach CODcr 50 mg/L and BODs ⁇ 5 mg L, meeting emission requirements.
- the aerobic organisms of the denitrification and dephosphorization tanks are mainly composed of facultative denitrifying bacteria and aerobic phosphorus accumulating bacteria.
- Denitrifying bacteria reduce nitrate nitrogen under aerobic conditions to achieve the purpose of denitrification.
- the polyphosphate bacteria use the oxidized carbon source to store the poly-B-hydroxybutyrate into a simple organic substance (such as acetic acid) in the sewage to obtain energy to take up the phosphate in the water, and remove the phosphorus from the water by discharging the sludge.
- the nitrogen and phosphorus removal equipment can be inoculated by collecting fresh helium oxygen sludge from the operating sewage treatment plant. After inoculation, the water from the equipment is connected to the water inlet, and the operation is cycled, and the gas is stirred to increase the oxygen content.
- the sewage is gradually injected, and the water is discharged, and the membrane is cultured and hanged.
- the sewage water is connected to the biogas generation tank and the sludge produced by denitrification and denitrification is inoculated into the biogas generation tank, and the tank is suffocated for 5 days, and then the system is turned into a normal operation state. Due to the self-domestication, variation and reproductive capacity of the organism, it is completely normal after 2 to 3 months of operation. ,
- the biogas tank effluent and the washing wastewater supernatant are thoroughly purified to be cleaned, organic fertilizer and nitrogen (see Figure 12).
- Aerobic organisms have strong adsorption capacity. Therefore, there are a large number of aerobic organisms in the sludge, and a large part of the sludge is recovered, which can meet the demand for aerobic biomass in the initial stage of the stacking, and accelerate the initial adsorption efficiency of the stacking.
- polyphosphate organisms carrying orthophosphate substances circulating in the equipment can complex heavy metal ions and toxic elements, and carry these pollutants out of the equipment.
- the aerobic biological sludge reclamation process has a good effect on sewage treatment, and the amount of sludge is small. The recycling of phosphorus can help the removal of toxic and harmful substances. 'Sediment reflow: due to the denitrification and dephosphorization process using double weight (A Yao and B tank) in series, and formed by reflux water
- OAAO cycle treatment method (circulation treatment system consisting of pre-aerobic biological treatment, anaerobic (anoxic) biological treatment, anaerobic biological treatment and post-aerobic biological treatment, abbreviated as OAAO, see Figure 17), water flow carrying The sludge caused by the sludge is completely enriched in the bottom of the B tank.
- a large number of nitrifying bacteria appear in the aerobic section of the B tank, which hinders the normal activities of the phosphorus accumulating bacteria in the B tank, commonly known as nitrification and denitrification.
- the phenomenon of phosphorus release and polyphosphorus competition for carbon sources appears; on the other hand, in the dewatering of B tanks, a considerable amount of nitrification and denitrifying bacteria will be discharged.
- a method of combining the B tank bottom mud and the bottom liquid back to the bottom of the A tank is employed.
- the amount of mud return is set to 0.5 T/h. It has been determined that after the implementation of the mud return method, the total nitrogen output index is even zero. In addition to the effect of the monument Improved. Explain that the strains can perform their duties in different areas after the implementation of the returning mud method.
- the amount of mud returned helps to denitrify and denitrify under anoxic conditions.
- the poly-coded bacteria in the mud returning amount will alternately in the anaerobic section and the aerobic section of the B tank to complete the release of the gravel and the polyphosphorus, thereby improving the phosphorus removal effect.
- the test method for the comprehensive treatment of domestic sewage and organic waste and its equipment is located at No. 1918, Tingfeng Road, Tinglin Town, Jinshan District, Shanghai.
- the raw sewage used for the test is domestic sewage from nearby enterprises, mainly discharged from the canteen discharge sewage and toilet septic tank. Sewage composition.
- the water quantity is 200-250 T/d, and the original sewage characteristics are: high COD, high T/P, high SS.
- the test equipment has a processing capacity of 300 T/d.
- the equipment of the present invention is designed in a reduced manner, with a tank diameter of 2.2 M and an area of 17 m x 8 m.
- the device configuration that makes up the system is shown in Table 1.
- Example 1 liquid phase separation ability test of multiphase separation pretreatment equipment
- the raw sewage is subjected to multiphase separation treatment using a multiphase separation device.
- the original sewage has the sampling average value shown in Table 2 after sampling test (T/ is the general abbreviation for total nitrogen pollution, the unit is mg L ):
- the original sewage inflow rate is 7.5 T/h
- the anaerobic biological sediment and bottom liquid returning from the biogas generating equipment is 0.5 T/h.
- the raw sewage entering the floating liquid chamber is subjected to sludge agitation adjustment, and the supernatant is sampled.
- the floating liquid and the sediment liquid were measured and the relevant data were determined.
- the average data and water content of the contaminants in the combined mixture are shown in Table 4.
- Table 4 The water sample separated by the liquid phase separated by the multi-phase separation pretreatment equipment shows that the water sample of the supernatant is light and clear, and the water sample of the supernatant liquid and the sediment liquid is obviously in a high concentration pollution state. See Figure 13).
- the supernatant photographic lens circular oil droplets are visible, and the dispersible oil contaminants are characterized by a smooth bead shape in the micrograph, which can be distinguished by those skilled in the art, and the oil and fat contaminants are nitrogen-containing.
- Contaminants commonly known as N; the average T/N of raw water is 16.77 mg/ml, and the average T/N of the supernatant obtained after separation is 15.60 mg/ml, with little difference, confirming the separation effect of N pollutants. Not obvious.
- the separation capacity of the multiphase separation pretreatment equipment was analyzed based on the values of the raw sewage and the supernatant, see Table 6.
- a supernatant water volume adjustment tank is added to the system, with a volume of 25 cubic meters.
- the peak value of absorption and discharge is three times the average water volume and is adjusted to the low water supply.
- the adjustment period can be up to 4 hours to meet system requirements.
- the multiphase separation pretreatment apparatus of the present invention has been tested to have the following advantages: a. 80% COD, 60% SS, 40% P pollutants in the raw sewage separated by the multi-phase separation pretreatment equipment, enriched in the floating liquid and sediment liquid which accounts for 5% of the total water, forming a high concentration of sewage , to meet the requirements of subsequent different processing methods.
- the pretreatment equipment has no obvious effect on the separation of N pollutants.
- the special grid design scheme of the automatic grille makes the size of the grille compact, and the running power consumption is only 0.75 KW.
- the exhaust gas discharged from the pre-separation processing equipment is output through the Roots blower, so that the entire system has no odor gas escape, and the effect is obvious.
- the parallel stacking and digesting equipment is composed of four stacking tanks in parallel, each of which is equipped with an automatic program control box for feeding, discharging, hydraulic stirring, stacking, heating Automatic control.
- the four stacking tanks share a feed pump through self-control switching.
- Each stacking tank is equipped with one mixing pump and one discharging pump, and adopts a rod pump with a flow rate of 2,5 T/h and a head of 15 m.
- the feeding and discharging time is 14 hours per tank, and the stacking time per tank is also 14 hours.
- the feed and discharge modes are continuous to the stacking system.
- the organic waste was fed through a pulverizer at 20 Kg/h, and the values of the feed liquid were measured. After 20 hours, the values of the output liquid were measured. Table 7 lists the removal equivalents of each item after stacking.
- 3#8 cans 1886 468 194 1214 40 6.80 0.20
- Table 9 Calculate the equivalent value of daily stacking degradation capacity (average feed value - average discharge value) x 60 T by water intake 2.5 T/h From the analysis of removal rate, the stacking equipment has strong degrading ability to SS and COD, and the hydrolysis and acidification of fat and protein organic waste are also quite obvious. The process design and equipment design are successful.
- the stacking method is obviously insufficient for the removal of phosphorus. Only 20% of the phosphorus may be bioabsorbed as a biological nutrient, and the remaining phosphorus is dried in the water or in the form of orthophosphate in the water. Further analysis of the effluent needs to be carried out to study the method for effectively removing phosphorus in the stacking process, and to reduce the phosphorus removal pressure in the subsequent treatment.
- the stacking equipment has a hydraulic agitator pump of 2.5 T/h and a head of 15 m.
- Determination of stacking time Under the condition of no stacking heating and stopping of hydraulic stirring, the stacking reaction starts to heat up after 16 hours of natural stacking, and the temperature rises to 38 - 40 °C to stop heating. The time required for natural warming was 8.5 hours. Naturally, it takes more than one day to complete the stacking. Under the condition that the stacking is not carried out, under the condition of hydraulic stirring during the feeding, it is found that the temperature rise has started at the same time as the feed, and the feed has not ended after 4 hours, and the temperature has reached 40 - 42 degrees. The time required to complete the stacking was 8 hours.
- the high-efficiency biogas generating apparatus adopts a double tank series form, and is configured to provide an internal reflux cycle of a centrifugal pump of 4 T/h and a head of 15 m.
- the hydrolyzed and acidified feed after the feed was treated was 2.5 T/h, and the supernatant was 1 T/h. After the combination, the total was 3.5 T/h.
- the feed value was measured for 10 consecutive days, and the discharge value was measured 10 hours after the feed measurement, and the treatment capacity and biogas generation capacity of the biogas generation equipment were measured.
- Methane bacteria are the main organisms in the biogas generation tank. In order to avoid the loss of bacteria, the equipment uses a fixed bed as a biological carrier. The growth of tropane bacteria is slow. The biogas production is gradually increased by the increase in biogas production in the table, which is related to the amount of sterane bacteria in the equipment.
- the SS of the scum and sediment of the sputum was sampled and found to have a content of SS above 4000 mg/L, indicating that the methane bacteria did not degrade the SS, and the removal rate of the SS by the biogas generation tank device was mainly floated. The process of slag return and sediment return works. The SS finally returns to the stacking tank to achieve loop processing.
- the biogas generation tank has no depletion effect on the treatment of phosphorus and nitrogen, and the T N and T/P values of the effluent and the influent water are similar. The only difference is the increase in the ammonia nitrogen value of the effluent.
- the tank has a heat preservation device, which naturally heats up to 35 degrees during operation, and the heating device can be eliminated.
- the denitrification and de-mining equipment adopts a double tank (A and B) in series, and a water reflux pump 15 T/h is prepared, and the B tank to the A tank sludge return pump is 0.5 T/h.
- a and B double tank
- a water reflux pump 15 T/h is prepared
- the B tank to the A tank sludge return pump is 0.5 T/h.
- the fixed influent water was used at 10.5 T/h, and the daily treatment capacity was 250 T/d.
- the COD, T/N, T/P, and SS values of the influent and effluent were measured every 8 hours, and the equivalent N value of the double tank treatment was calculated.
- Phosphorus-containing sludge is mainly concentrated in the bottom mud of nitrogen and phosphorus removal B tanks. It is an important means to remove phosphorus every day. Determine the phosphorus content of the sediment (in mg/L), remove the phosphorus equivalent to P 2 (unit Kg/d), and discharge the mud per day V - P2/P, X 10 3 .
- the nitrogen and phosphorus removal equipment has a good removal rate for COD, T/N, T/P, SS, especially the denitrification effect.
- This equipment can handle high nitrogen and high sorghum. Sewage, due to the use of special fiber cloth in the equipment to form a fixed bed to grow hypoxia and anaerobic organisms, and by adjusting the amount of aeration, to adjust the length of the anoxic section and the anaerobic section, to solve the problem of nitrogen and phosphorus removal Fighting for carbon sources. ,
- the application of the retro-return technology makes the denitrification and de-gravel equipment reduce the pressure of SS treatment.
- SS value in the reclaimed sludge up to 40,000 mg/L it is indicated that SS is treated by stacking equipment. This is also a major factor in the formation of efficient nitrogen and phosphorus removal.
- the average T/P value measured in the recovered sludge is above 10000 mg/L.
- sludge is discharged in time to reduce the T/P value of the effluent.
- the experiment shows that the mud discharge is opened for 3 minutes every day, and the mud discharge is about 1 cubic meter, so that the T/P value of the effluent can reach the discharge standard of 0.5 mg/L.
- the secondary sedimentation is equipped with a 4 T/h returning mud return pump. By timely returning the mud back to the water, the equipment has excellent sedimentation separation effect, and the measured SS value is decreased.
- the comprehensive treatment of domestic sewage and organic waste is feasible; the stacking and retanning technology of the present invention plays an important role in the treatment system.
- the device of the invention can be factory-produced, has a small footprint, and realizes a sewage treatment method without leakage and no odor.
- the amount of discharged mud is extremely small, about 1 cubic meter of muddy water per day, about 20 Kg/d after drying, can be used as phosphate fertilizer, and there is no secondary pollution problem.
- Organic waste is treated reasonably and effectively, with significant Economy, environmental protection, green energy, and social significance.
- the equipment system of the present invention can meet the requirements for the treatment of domestic sewage by the cultivation and domestication of the biological sludge collected by the conventional sewage treatment plant. In the treatment of special sewage, it is possible to add bacteria, and the apparatus and treatment method of the present invention are still applicable.
- the integrated treatment of domestic sewage and organic waste employs an innovative process of multiphase separation, stacking, biogas generation and biological nitrogen and phosphorus removal for treating various types of sewage and organic waste (see Figure 18).
- Organic waste, washing sewage and fecal sewage are basically completely converted into clean water, biogas, organic fertilizer and sand residue, which can be directly discharged into the equipment (see Figure 19).
- the new process of the present invention solves the problem of methane emission in the septic tank, eliminates the work of the environmental protection department to clean the septic tank, solves the problem of a large amount of organic waste, and reduces the pressure on the landfill. It achieves the environmental protection purpose of comprehensive treatment and minimum pollution discharge.
- the apparatus for comprehensively treating domestic sewage and organic waste of the present invention has a wide range of applications, such as the following applications.
- the water treated by the equipment for comprehensively treating domestic sewage and organic waste according to the present invention can be directly discharged into rivers and lakes, and is particularly suitable for water-developed areas, to realize sewage treatment on the spot, and to avoid investing funds to construct sewage network pipes under the river network water system, thereby reducing The huge investment that towns face in environmental protection.
- the biogas discharged from the biogas generating tank can be directly used as a fertilizer by a device that does not undergo denitrification and dephosphorization.
- the biogas produced under anaerobic conditions contains ammonia nitrogen and water-soluble gravel, and is an ecological compound fertilizer.
- the trace amount of organic monument has natural insecticidal effect, which reduces the dependence of rural fertilizers and pesticides.
- the washing supernatant is directly used in the irrigation net to reduce the pressure of irrigation water in rural areas.
- a gasoline/biogas dual-purpose power machine used in rural and mountain areas where electricity is scarce.
- the equipment is powered by gasoline when the equipment is started, and the biogas is used to generate electricity after the biogas is produced, and the equipment can be continuously operated. This can solve the power and fuel problems in such areas to some extent.
- the technical equipment of the present invention can effectively treat high bio-fat, high protein, high starch, high carbohydrate type sewage and such waste.
- the treated water can be used as a flushing water for the plant to recycle water resources.
- the technical equipment can effectively treat sewage discharged by hospitals with pathogens, bacteria and viruses. After disinfection, it can be discharged directly.
- the fully enclosed processing equipment is the best way to treat medical wastewater harmlessly.
- the equipment is powered by municipal power, and the generated biogas is used in hot water boilers to generate hot water for hospital use.
- the piled garbage is excavated and transported to the hydraulic flushing, and the digestible organic waste is mixed and washed with the flushing sewage.
- the clean water can be used for circulating the flushing water source, and the produced biogas can be used for drying the indigestible garbage.
- reuse or treatment discharge the reduced amount of sand and biological sludge and then do landfill or incineration.
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CN114790069A (zh) * | 2022-04-14 | 2022-07-26 | 北控技术服务(广东)有限公司 | 一种市政污水处理厂生物除磷效果评价办法 |
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US8691094B2 (en) | 2014-04-08 |
CN102227382A (zh) | 2011-10-26 |
CN103496823A (zh) | 2014-01-08 |
US20110315626A1 (en) | 2011-12-29 |
CN102227382B (zh) | 2013-10-30 |
CN102050546A (zh) | 2011-05-11 |
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