WO2011046078A1 - 非破壊検査方法及びその装置 - Google Patents
非破壊検査方法及びその装置 Download PDFInfo
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- WO2011046078A1 WO2011046078A1 PCT/JP2010/067743 JP2010067743W WO2011046078A1 WO 2011046078 A1 WO2011046078 A1 WO 2011046078A1 JP 2010067743 W JP2010067743 W JP 2010067743W WO 2011046078 A1 WO2011046078 A1 WO 2011046078A1
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- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N23/00—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00
- G01N23/22—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material
- G01N23/221—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material by activation analysis
- G01N23/222—Investigating or analysing materials by the use of wave or particle radiation, e.g. X-rays or neutrons, not covered by groups G01N3/00 – G01N17/00, G01N21/00 or G01N22/00 by measuring secondary emission from the material by activation analysis using neutron activation analysis [NAA]
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- the present invention relates to a non-destructive inspection method and apparatus for inspecting an object without destroying the object.
- Non-Patent Document 1 discloses an analysis method using prompt ⁇ -rays.
- Prompt ⁇ -rays are generally ⁇ -rays emitted in a very short time by nuclear reaction, and here, in particular, mean ⁇ -rays emitted immediately after epithermal neutrons are resonantly absorbed.
- non-destructive inspection can be performed when the object is small.
- a test piece must be cut out from the object, and an analysis method using prompt ⁇ rays is difficult to implement as a nondestructive inspection.
- Prompt ⁇ -rays have inherent energy in the element, so they can be used for elemental analysis.
- higher-energy ⁇ -rays derived from Compton scattering are mixed as noise, Problems arise.
- the present invention has been made in view of the above circumstances, and an object of the present invention is a non-destructive inspection method in which accurate state inspection of an object is not restricted by the shape or location of the object, and is suitable for this method. It is to provide a non-destructive inspection device.
- a method for non-destructively inspecting an object including one or more elements irradiates the object with a neutron beam along an axis passing through a reference point, and a diameter from the axis.
- ⁇ rays from directions inclined by an equal angle from the axis line are detected in synchronization at a plurality of measurement points arranged at equal distances in the direction, and each detected ⁇ ray is Count for each energy region, determine for each energy region whether the counted value exceeds the threshold value, and determine the energy region where all of the counted values exceed the threshold value. Analyzing the kind of element from the determined energy region, and based on the reference point, the relative position between each measurement point and the surface of the object, and the direction, In the object of the element Each step is detected.
- an apparatus for non-destructively inspecting an object including one or more elements has a reference point, and applies a neutron beam to the object along an axis passing through the reference point.
- a neutron source positioned to irradiate and arranged at a plurality of measurement points spaced at equal distances from the axis in the radial direction, and configured to detect ⁇ rays from directions inclined by an equal angle from the axis, respectively.
- a plurality of ⁇ -ray monitors a plurality of wave height analyzers that are electrically connected to each of the ⁇ -ray monitors and configured to count each detected ⁇ -ray for each of a plurality of energy regions; It is electrically connected to the plurality of wave height analyzers, and for each energy region, it is determined whether the counted value exceeds the threshold value, and all of the counted values exceed the threshold value.
- FIG. 1 is a schematic configuration diagram showing a nondestructive inspection apparatus according to an embodiment of the present invention to which a nondestructive inspection method according to the present invention is applied.
- the nondestructive inspection apparatus 1 uses the fact that nuclei that have captured neutrons emit prompt ⁇ -rays, and detects the prompt ⁇ -rays from the target irradiated with neutrons, thereby inspecting the state of the target.
- the reinforced concrete 3 which comprises a bridge etc. is a target object, and it test
- the distribution of reinforcing bars in the reinforced concrete 3 and the distribution of chlorine (chloride ions) that cause salt damage are the objects of measurement.
- the nondestructive inspection apparatus 1 of this embodiment includes a movable table 11 that can move on a reinforced concrete 3, a neutron source 13 that outputs a neutron beam, and two ⁇ -ray detectors that detect prompt ⁇ -rays from the reinforced concrete 3. 15a and 15b.
- the neutron source 13 and the ⁇ -ray detectors 15 a and 15 b are installed on the moving table 11.
- the nondestructive inspection apparatus 1 of the present embodiment includes wave height analyzers 17a and 17b connected to the respective ⁇ -ray detectors 15a and 15b, a simultaneous coefficient device 19 connected to both wave height analyzers 17a and 17b, and these And a control device 21 for controlling.
- the wave height analyzers 17a and 17b count prompt ⁇ -rays according to the outputs of the ⁇ -ray detectors 15a and 15b, respectively.
- the wave height analyzers 17a and 17b can decompose the intensity of ⁇ rays as a spectrum relating to energy and count the ⁇ ray intensity for each energy region.
- the coincidence device 19 can set a threshold value for each output of the wave height analyzers 17a and 17b, and is configured to output a detection signal to the control device 21 when a signal exceeding the threshold value is input. .
- the moving table 11 can be a cart that can move on the reinforced concrete 3.
- a self-propelled carriage having a drive source may be applied, or a driven carriage having no drive source may be applied.
- the position of the moving table 11 on the reinforced concrete 3 is always grasped by the control device 21 regardless of whether the moving table 11 is automatic or driven. It is preferable.
- one axle of the moving base 11 includes a tachometer, and the control device 21 integrates the output of the tachometer to grasp the position.
- the movable table 11 may include a distance meter, an accelerometer, or a position sensor.
- a known neutron source 13 can be applied.
- the neutron source 13 shown in FIG. 2 includes a target T irradiated with ions I, a moderator M that decelerates the fast neutrons N, and protection for shielding the fast neutrons N and moderator M from the outside.
- the target T includes a material such as Be or 2 H in order to efficiently generate neutrons from the ions I such as H, 2 H, and 4 He irradiated from an external ion generator.
- the moderator M is made of an appropriate material that decelerates the fast neutrons N generated from the target T, such as polyethylene, heavy water, light water, and the like.
- the moderator M converts the fast neutron N into a neutron beam 13a having a continuous spectrum including thermal neutrons (0.5 eV or less) and epithermal neutrons (0.5 to 10 3 eV).
- the appropriate moderator protective wall S seals the moderator M and prevents fast neutrons N from leaking out.
- One end of the protective wall S (usually the side opposite to the target) is open, and the neutron beam 13a is emitted from there.
- the neutron source 13 is installed on the upper part of a chamber-shaped protective body 14 installed on the moving table 11.
- a neutron beam 13a (see FIG. 1) output from the neutron beam source 13 passes through the inside of the protection body 14 and the moving table 11, and is irradiated onto the reinforced concrete 3 from the normal direction of the surface thereof.
- FIGS. 3 and 4 show the relationship between the energy of irradiated neutrons and the neutron capture cross section for chlorine 35 and chlorine 37, respectively.
- FIG. 3 chlorine 35
- FIG. 4 chlorine 37
- resonant neutrons are "resonantly absorbed by such elements by having an energy corresponding to the resonance level inherent in the element among the neutrons contained in the neutron beam having a continuous spectrum. It is used by defining as "neutron”.
- the reinforced concrete 3 is irradiated with neutron beams 13 a by epithermal neutrons from the neutron beam source 13 and is emitted from the reinforced concrete 3 (specific elements contained therein). Prompt ⁇ -rays are detected by the ⁇ -ray detectors 15a and 15b.
- Each ⁇ -ray detection unit 15a, 15b is accommodated in a protective body 14 on a movable table 11, as shown in FIG. As shown in FIG. 5, each ⁇ -ray detection unit 15a, 15b has an equal interval r in the radial direction orthogonal to the irradiation axis from the reference point 13b on the irradiation axis of the neutron beam 13a from the neutron beam source 13. It arrange
- the reference point 13b is set at a location separated from the surface of the reinforced concrete 3 by a distance L.
- Each ⁇ -ray detection unit 15a, 15b includes a ⁇ -ray sensor 15c and a collimator 15d that covers the ⁇ -ray sensor 15c.
- a known ⁇ -ray sensor can be applied to the ⁇ -ray sensor 15c.
- a scintillation detector including a scintillator that emits fluorescence upon receiving ⁇ rays and a photomultiplier tube or a photodiode that measures the intensity of the fluorescence can be used.
- a known semiconductor detector can be used.
- the collimator 15d is configured to regulate the incident direction of ⁇ rays that can be detected by the ⁇ ray sensor 15c.
- the collimator 15d of each ⁇ -ray detection unit 15a, 15b collimates prompt ⁇ -rays from the reinforced concrete 3 and generates ⁇ -rays from a direction inclined by an angle ⁇ with respect to the irradiation axis of the neutron beam 13a. It reaches the ⁇ -ray sensor 15c. Therefore, the ⁇ -ray sensor 15c detects only ⁇ -rays from a direction inclined by an angle ⁇ with respect to the irradiation axis of the neutron beam 13a.
- FIG. 5 shows an example in which a nondestructive inspection apparatus 1 detects a chloride when a specific portion P in the reinforced concrete 3 is present.
- each ⁇ -ray detection unit 15a and 15b has an immediate ⁇ from the specific location P when directed to the angle ⁇ according to the position of the specific location P. Accept the line. Therefore, if prompt ⁇ -rays are detected, the control device 21 can calculate the position of the specific portion P by a simple calculation formula.
- each of the wave height analyzers 17a and 17b is triggered by the control device 21 in synchronization with the output of the neutron beam 13a from the neutron beam source 13, for each ⁇ ray detected by the corresponding ⁇ ray detectors 15a and 15b, The energy is divided into a plurality of energy regions and counted for each energy region.
- the coincidence counting device 19 When the coincidence counting device 19 is triggered by the control device 21 in synchronization with the output of the neutron beam 13a from the neutron beam source 13, the coincidence device 19 obtains the intensity of the ⁇ -rays counted by the wave height analyzers 17a and 17b for each energy region. To do.
- the coincidence counting device 19 compares each intensity acquired from each of the wave height analyzers 17a and 17b with the above-described threshold value.
- the coincidence device 19 determines, for each energy region, whether the intensity of any ⁇ ray detected by each ⁇ ray detection unit 15a, 15b is higher than a threshold value.
- the predetermined threshold is set by the control device 21 for each energy region of ⁇ rays.
- the threshold value for each energy region is common between the wave height analyzers 17a and 17b.
- the coincidence counting device 19 is configured so that the intensity of the ⁇ -rays simultaneously detected by the ⁇ -ray detectors 15a and 15b by the energy regions discriminated by the wave height analyzers 17a and 17b is in a specific energy region.
- a determination signal indicating the energy region is output.
- the control device 21 analyzes and specifies the elements present in the reinforced concrete 3 irradiated with the neutron beam 13a from the neutron beam source 13 based on the discrimination signal output from the coincidence device 19, and each ⁇ -ray detector 15a. , 15b, the position of the specified element in the reinforced concrete 3 (depth d from the surface of the reinforced concrete 3) is calculated using the above-described formula.
- the position of the moving table 11 on the reinforced concrete 3 in other words, irradiation of the neutron beam 13 a on the reinforced concrete 3 in one cycle inspection.
- the position is sequentially changed, for example, in a matrix shape over the entire surface of the reinforced concrete 3.
- the following steps (1) to (4) (1) irradiating a neutron beam 13a from the neutron beam source 13 toward the reinforced concrete 3 to emit prompt ⁇ -rays from the nuclei of the elements contained in the reinforced concrete 3 capturing the neutrons of the neutron beam 13a; (2) At measurement points 13c and 13d that are spaced from each other by a distance r equal to the radial direction orthogonal to the irradiation axis from the reference point 13b on the irradiation axis of the neutron beam 13a, it is inclined by an angle ⁇ with respect to the irradiation axis of the neutron beam 13a.
- the control device 21 analyzes the type of element contained in the reinforced concrete 3 based on the energy region, and this The position of the analyzed element in the reinforced concrete 3, that is, the depth d from the surface of the three reinforced concretes irradiated with the neutron beam 13a, the reference point 13b on the neutron beam 13a with respect to the reinforced concrete 3 and each measurement point 13c, 13d (each and detecting based on the relative positions of the ⁇ -ray detectors 15a and 15b). .
- the series of steps are repeatedly executed while moving the nondestructive inspection apparatus 1 and changing the position.
- the distance L from the surface of the reinforced concrete 3 to the reference point 13b on the irradiation axis of the neutron beam 13a, the distance r from the reference point 13b to each measurement point 13c, 13d (each ⁇ -ray detection unit 15a, 15b), and
- the incident direction of ⁇ rays (inclination angle ⁇ with respect to the irradiation axis of the neutron beam 13a) that can be detected by each of the ⁇ ray detectors 15a and 15b as appropriate,
- the position of the layer (the value of the depth d from the surface) can be changed.
- the predetermined threshold value for each energy region used in the determination by the coincidence device 19 is determined according to the energy spectrum of prompt ⁇ -rays emitted from the nuclei of the element according to the element whose distribution is to be examined. You only have to set it. For example, when inspecting the distribution of reinforcing bars in reinforced concrete 3, the predetermined threshold for each energy region of prompt ⁇ -rays is set according to the energy spectrum of prompt ⁇ -rays that iron nuclei capture and emit neutrons. Set.
- the predetermined threshold for each energy region of the prompt ⁇ -ray set by the control apparatus 21 is set to the iron (rebar). Only for the energy region where the intensity of prompt ⁇ -rays emitted by the nuclei is high, the value is slightly lower than that value, and the other energy region is set to a different value (for example, a value close to infinity).
- a predetermined threshold for each energy region of prompt ⁇ rays set by the control apparatus 21 is set to chlorine. Only in the energy region where the intensity of prompt ⁇ -rays radiated from the (chloride ion) nucleus is high, the value is slightly lower than that value, and the other energy region is set to a different value (for example, a value close to infinity). .
- control apparatus 21 sets the predetermined threshold value according to energy area to the value corresponding to iron, and performs the inspection of 1 cycle mentioned above over the whole surface direction and depth direction of the reinforced concrete 3, The distribution of iron (rebar) in the reinforced concrete 3 is analyzed.
- control device 21 sets the predetermined threshold value for each energy region to a value corresponding to chlorine, and performs the above-described one cycle inspection over the entire surface direction and depth direction of the reinforced concrete 3, The distribution of chlorine (chloride ions) in reinforced concrete 3 is analyzed.
- control device 21 correlates the distribution of iron (rebar) and the distribution of chlorine (chloride ions) in the reinforced concrete 3 and the state of corrosion due to salt damage of the reinforced concrete 3 (presence of corrosion occurrence, occurrence of corrosion). Probability, expected corrosion occurrence time, etc.).
- the predetermined threshold value for each energy region used in the determination by the coincidence device 19 is a spectrum for each energy region of prompt ⁇ rays emitted from the nuclei of the element according to the element whose distribution is to be examined.
- the reinforced concrete 3 is sequentially changed over the entire surface direction and depth direction of the reinforced concrete 3 while the irradiation position of the neutron beam 13a on the reinforced concrete 3 is sequentially changed.
- the element contained in the reinforced concrete 3 can be analyzed by nondestructive inspection by detecting the energy spectrum specific to the element of prompt ⁇ -rays emitted from the nuclei of the contained elements as neutrons are captured.
- the time from the generation of resonant neutrons until reaching the target examination region is limited to a very short time.
- ⁇ -rays are released immediately after the resonance neutrons are absorbed by the target nucleus (here, chlorine 35). Therefore, the time it takes for resonant neutrons to be generated and absorbed by chlorine 35 and the generated ⁇ -rays to reach the detector is uniquely determined. For detectors with the same distance to chlorine 35, these ⁇ -rays are at the same time. To reach.
- simultaneous counting with a plurality of detectors, it is possible to extract only ⁇ -rays derived from chlorine 35 and improve measurement accuracy.
- the movable stand 11 may be abbreviate
- the ⁇ -ray detectors 15a and 15b of the present embodiment may be arranged with a 180 ° phase shift around the irradiation axis of the neutron beam 13a, or may be arranged with a phase shifted by another angle. .
- the number of measurement points on which the ⁇ -ray monitor ( ⁇ -ray detector) in the present invention is arranged may be two as in this embodiment, or may be three or more. Even when the ⁇ -ray monitors are arranged and used at three or more measurement points, each measurement point is located at a position spaced in the radial direction of the irradiation axis from the reference point 13b on the irradiation axis of the neutron beam 13a. The phase is shifted around the irradiation axis of the neutron beam 13a by an arbitrary angle. Further, the ⁇ -ray monitors arranged at the respective measurement points respectively detect the direction components inclined by the same angle with respect to the irradiation axis of the neutron beam 13a among the prompt ⁇ -rays from the object.
- display means for visualizing and displaying the position of a specific contained element in the reinforced concrete 3 analyzed as described above may be provided in the nondestructive inspection apparatuses 1 and 1A.
- a display form by the display means for example, data indicating the analysis result of the chlorine distribution in the depth direction from the surface of the reinforced concrete 3 and the moving direction of the moving table 11 is set according to the level of the chlorine concentration.
- a display format using contour lines and a display format such as density display based on display density can be considered.
- the analysis result is visualized on the spot, so that the analysis result can be quickly grasped at the site where the non-destructive inspection of the reinforced concrete 3 is performed.
- nondestructive inspection method that is not restricted by the shape and location of an object, and a nondestructive inspection device suitable for this method.
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Abstract
Description
(1)中性子線源13から鉄筋コンクリート3に向けて中性子線13aを照射して、中性子線13aの中性子を捕獲した鉄筋コンクリート3の含有元素の原子核から即発γ線を放射させるステップと、
(2)中性子線13aの照射軸線上の基準点13bから照射軸線と直交する径方向にそれぞれ等しい間隔rをおいた測定点13c,13dにおいて、中性子線13aの照射軸線に対して角度θだけ傾斜した方向からのγ線を、γ線検出部15a,15bによって検出するステップと、
(3)γ線検出部15a,15bによって検出されたγ線の強度をエネルギー領域別に弁別するステップと、
(4)中性子線源13から鉄筋コンクリート3への中性子線13aの照射に同期してγ線検出部15a,15bによって同時に検出されたγ線の、同一のエネルギー領域どうしにおける強度が、そのエネルギー領域に対応する所定の閾値よりいずれも高いと、同時計数装置19において判別された場合に、制御装置21が、そのエネルギー領域に基づいて、鉄筋コンクリート3中に含有される元素の種類を解析すると共に、この解析した元素の鉄筋コンクリート3中における位置、つまり、中性子線13aを照射した鉄筋コンクリート3箇所の表面からの深さdを、鉄筋コンクリート3に対する中性子線13a上の基準点13bや各測定点13c,13d(各γ線検出部15a,15b)の相対位置に基づいて検出するステップと、が実行される。
Claims (6)
- 一以上の元素を含む対象物を非破壊に検査する方法であって、
基準点を通る軸線に沿って前記対象物に中性子線を照射し、
前記軸線から径方向に等しい距離を置いて離れて配置された複数の測定点において、前記軸線から等しい角度だけ傾斜した方向からのγ線をそれぞれ同期して検出し、
検出された前記各γ線を、複数のエネルギー領域ごとに計数し、
前記各エネルギー領域ごとに、計数された値を閾値と比較して越えているかどうか判定し、
前記計数された値の全てが前記閾値を越えているエネルギー領域を決定し、
決定されたエネルギー領域から元素の種類を解析し、
前記基準点と、前記各測定点と、前記対象物の表面との間の相対位置と、前記方向とに基づいて、前記解析した種類の元素の前記対象物における位置を検出する、
各ステップを含む、方法。 - 前記中性子線の前記対象物に対する照射位置を、前記対象物の表面に沿って順次変えつつ、前記各ステップを実行することを特徴とする請求項1の方法。
- 前記基準点から前記対象物までの前記軸線に沿った距離と、前記軸線からの前記各測定点の距離と、前記γ線の前記方向と、よりなる群より選択された一を順次変えつつ、前記各ステップを実行することを特徴とする請求項1の方法。
- 一以上の元素を含む対象物を非破壊に検査する装置であって、
基準点を有し、前記基準点を通る軸線に沿って前記対象物に中性子線を照射するべく位置した中性子線源と、
前記軸線から径方向に等しい距離を置いて離れた複数の測定点に配置され、前記軸線から等しい角度だけ傾斜した方向からのγ線をそれぞれ検出するべく構成された複数のγ線モニタと、
前記γ線モニタとそれぞれ電気的に接続され、検出された前記各γ線を、複数のエネルギー領域ごとにそれぞれ計数するべく構成された複数の波高分析器と、
前記複数の波高分析器と電気的に接続され、前記各エネルギー領域ごとに、計数された値を閾値と比較して越えているかどうか判定し、前記計数された値の全てが前記閾値を越えているエネルギー領域を決定し、決定されたエネルギー領域から元素の種類を解析し、前記基準点と、前記各測定点と、前記対象物の表面との間の相対位置と、前記方向とに基づいて、前記解析した種類の元素の前記対象物における位置を検出するべく構成された制御装置と、
を備えた装置。 - 前記各γ線モニタは、前記基準点から前記対象物までの前記軸線に沿った距離と、前記軸線からの前記各測定点の距離と、前記γ線の前記方向と、よりなる群より選択された一を変更可能に構成されている請求項4の装置。
- 前記対象物上を移動可能に構成され、前記中性子線源と前記各γ線モニタとが設置される移動台をさらに備えていることを特徴とする請求項4の装置。
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JPH07294652A (ja) * | 1994-02-18 | 1995-11-10 | Westinghouse Electric Corp <We> | 物質表面下のガンマ線放出元素の深さを求める方法及び装置 |
JPH07301610A (ja) * | 1992-10-08 | 1995-11-14 | Westinghouse Electric Corp <We> | 土壌中の有毒元素の濃度の深さプロフィールを求める方法及び装置 |
JP3144641B2 (ja) * | 1990-01-10 | 2001-03-12 | サイエンス・アプリケーションズ・インターナショナル・コーポレーション | 高速中性子放射化を使用した禁輸品を検出する装置および方法 |
JP2004125639A (ja) * | 2002-10-03 | 2004-04-22 | Japan Atom Energy Res Inst | 多重ガンマ線検出法と放射化分析を組み合わせた新微量分析法において検出器の不感時間を補正する方法 |
US20070069145A1 (en) * | 2003-05-16 | 2007-03-29 | Institut Fur Umwelttechnologien Gmbh | Procedure and facility for providing proof of dangerous goods in pieces of baggage |
WO2008012360A1 (en) * | 2006-07-28 | 2008-01-31 | Sage Innovations Inc. | A detection system and a detection method based on pulsed energetic particles. |
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JPH03144641A (ja) | 1989-10-31 | 1991-06-20 | Brother Ind Ltd | 画像形成装置 |
US5410575A (en) * | 1993-01-27 | 1995-04-25 | The United States Of America As Represented By The Secretary Of The Navy | Detection of buried nitrogen rich materials |
RU2206080C1 (ru) * | 2001-11-08 | 2003-06-10 | Открытое акционерное общество "Научно-технический центр "РАТЭК" | Способ обнаружения взрывчатого вещества в контролируемом предмете |
US7361886B2 (en) * | 2005-02-28 | 2008-04-22 | Schlumberger Technology Corporation | Corrections of gamma-ray responses |
US8080808B2 (en) * | 2006-07-18 | 2011-12-20 | BOSS Physical Sciences, LLC | Remote detection of explosive substances |
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2009
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JP3144641B2 (ja) * | 1990-01-10 | 2001-03-12 | サイエンス・アプリケーションズ・インターナショナル・コーポレーション | 高速中性子放射化を使用した禁輸品を検出する装置および方法 |
JPH07301610A (ja) * | 1992-10-08 | 1995-11-14 | Westinghouse Electric Corp <We> | 土壌中の有毒元素の濃度の深さプロフィールを求める方法及び装置 |
JPH07294652A (ja) * | 1994-02-18 | 1995-11-10 | Westinghouse Electric Corp <We> | 物質表面下のガンマ線放出元素の深さを求める方法及び装置 |
JP2004125639A (ja) * | 2002-10-03 | 2004-04-22 | Japan Atom Energy Res Inst | 多重ガンマ線検出法と放射化分析を組み合わせた新微量分析法において検出器の不感時間を補正する方法 |
US20070069145A1 (en) * | 2003-05-16 | 2007-03-29 | Institut Fur Umwelttechnologien Gmbh | Procedure and facility for providing proof of dangerous goods in pieces of baggage |
WO2008012360A1 (en) * | 2006-07-28 | 2008-01-31 | Sage Innovations Inc. | A detection system and a detection method based on pulsed energetic particles. |
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WO2021230201A1 (ja) * | 2020-05-13 | 2021-11-18 | 国立研究開発法人理化学研究所 | 濃度検出装置と濃度検出方法 |
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US20120199754A1 (en) | 2012-08-09 |
JP2011085481A (ja) | 2011-04-28 |
TR201204076T1 (tr) | 2012-09-21 |
JP5347896B2 (ja) | 2013-11-20 |
US8680477B2 (en) | 2014-03-25 |
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