WO2011032663A2 - Verfahren zur kombinierten rückstandsvergasung von flüssigen und festen brennstoffen - Google Patents
Verfahren zur kombinierten rückstandsvergasung von flüssigen und festen brennstoffen Download PDFInfo
- Publication number
- WO2011032663A2 WO2011032663A2 PCT/EP2010/005542 EP2010005542W WO2011032663A2 WO 2011032663 A2 WO2011032663 A2 WO 2011032663A2 EP 2010005542 W EP2010005542 W EP 2010005542W WO 2011032663 A2 WO2011032663 A2 WO 2011032663A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gasification
- ash
- reactor
- liquid
- fuel
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/50—Fuel charging devices
- C10J3/506—Fuel charging devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
- C10J2300/0933—Coal fines for producing water gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
- C10J2300/0936—Coal fines for producing producer gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0989—Hydrocarbons as additives to gasifying agents to improve caloric properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/1223—Heating the gasifier by burners
Definitions
- the invention is directed to a process for simultaneously gasifying solid fuels and ash-containing liquid fuels under pressure, wherein the solid and liquid fuels are separately fed to the gasification reactor and the ash portion of both fuels is at a temperature above 1500 ° C is discharged as molten slag from the reactor.
- coal gasification process is suitable for gasification of the residue products with molten exhaust of the slag.
- a carburetor with bricked reactor is also not suitable for the gasification of dusty tar residues, since the resulting liquid slag infiltrates the refractory masonry of the reactors and this destroyed, especially at high levels of heavy metals or alkali metals in the residue products.
- DE 38 20 013 A1 therefore proposes gasifying the dust-containing tar residues in a gasifier with a cooled reactor vessel, the tar residues being introduced into the reactor separately from the burner together with the steam, ie not in a burner own oxygen supply.
- the amount of liquid residue products is very limited in this process.
- a significantly reduced degree of conversion is to be expected in this process, since there is no intensive mixing of the tar residues with oxygen.
- Another disadvantage of the method described in DE 42 26 034 C1 and DE 43 17 319 B4 is the limited proportion of ash in the fuel.
- the solid fuel is supplied as a fuel-water mixture to the carburetor.
- the aim and object of the invention is therefore to use the ash-containing liquid residues from a fixed-bed gasification and fine coal particles, which can not be used in a fixed-bed gasification, together flexible in an entrainment gasification and at the same time to minimize the formation of soot.
- the invention solves this problem by a method according to the features of the first claim.
- the solution of the invention provides a process for the production of synthesis gas by the gasification of ash-containing liquid residues from a fixed bed gasification at a pressure between 0.3 to 8.0 MPa and a temperature greater than 1400 ° C with oxygen-containing gaseous gasification agents in one cooled reactor,
- the ash-containing liquid fuel is fed to the reactor together with ash-containing solid fuel, and
- the ash-containing, solid fuel in a gas supplied is fed to the reactor in a disperse manner, and
- the ashy solid fuel is at least partially the fraction of fine coal particles from coal mining which can not be used for fixed bed gasification.
- An economical operation of a fixed bed gasification thus requires a flexible use of the resulting solid and liquid residues from the fixed bed gasification.
- An entrainment gasification with a cooled reactor and separate delivery of ash-containing, liquid and solid fuels, wherein the solid fuel is conveyed in a transport gas is an ideal solution for this purpose.
- the transport gas consists of 100% or less of nitrogen or carbon dioxide or a combination of the two gases.
- the cooled reactor can be operated at temperatures above 1400.degree. C., preferably above 1500.degree. C., so that the ash-containing constituents of the fuels can be removed as granulated slag.
- the slag requires no further aftertreatment, since possible impurities, in contrast to the ash of the fixed-bed gasification, are not washed out.
- the cooled reactor resists the possible impurities in the fuels, such as e.g. Heavy metals.
- the separate supply of solid and liquid fuels allows the optimal use of fuels.
- the carbonaceous solid fuel is typically a fine grain coal, preferably less than 5 mm, which can not be used in a fixed bed gasification process.
- the fine, not suitable for the fixed-bed gasification coal particles from the coal mining can thus be used particularly advantageous for the promotion in a transport gas, since a diameter smaller than 0.1 mm is required for the promotion of coal in a transport gas.
- the usual effort for the grinding of the coal is thus reduced.
- the separate feeding of the solid fuel makes it possible to compensate for any fluctuation in the quality or quantity of the liquid fuel. moreover For example, additional coal can be added to the solid fuel to increase overall performance.
- a burner can be used for the ash-containing, liquid fuel, which reduces the soot formation as much as possible.
- a burner is described in EP 00 95 103 A1.
- This consists of three concentrically arranged tubes, which provide a central feed tube and two enclosing annular gaps.
- the liquid fuel is supplied via the middle, formed from the inner and outer tube annular gap.
- the oxygen or the oxygen-containing gas is supplied via the feed tube and the outer annular gap.
- the burner system in a typical embodiment has three concentric tubes and a tapered end. The escaping fuel is thus finely distributed after exiting. This increases the degree of conversion and thus reduces soot formation to a minimum.
- the burner system may have a cooling chamber in the region of the burner outlet.
- the carbonaceous, solid fuel is preferably supplied via two opposing burner systems and, to offset by 90 ° in the horizontal plane, the ash-containing, liquid fuel is also supplied via two opposing combustion systems.
- the burner systems can also be provided in any other number and thus also be offset by an angle greater or less than 90 °. Also, parallel burner levels for power adjustment are possible.
- a further reduction in soot formation is achieved in that all the burners have a firing angle of greater than 0 ° and preferably 3 ° -6 °. This produces a swirl within the reactor, which, on the one hand, increases the residence time and thus also the degree of conversion.
- the firing angle here is the angle between the outflow direction of the fuel and the horizontal connecting line between the burner nozzle and the axis of symmetry of the reactor, where appropriate, the outflow direction of the fuel can also be inclined to the horizontal, and secondly the deposition of the molten slag and unreacted carbon particles to the reactor wall The unreacted carbon particles are further converted there or are incorporated into the slag.
- the burner a plurality of horizontal planes.
- the burner systems can thus be distributed over one or more horizontal planes.
- the firing angle differs from the horizon- talen plane an angle 0 °.
- the firing angle with respect to the horizontal plane has an angle of more than 0 °.
- FIG. 1 shows a process according to the invention for a fixed-bed and entrained-flow gasification.
- FIG. Fig. 2 shows a carburettor with burner for solid and liquid fuel in lateral view and in vertical view.
- FIG. Figure 3 shows a burner suitable for carrying out the method according to the invention.
- the drawings illustrate only embodiments of the invention, the invention is not limited to these embodiments.
- the residual products of a fixed-bed gasification are fed to an entrained-flow gasifier.
- the residue products here are a liquid tar / fine coal mixture as a residue from the fixed bed gasification and non-usable, fine coal particles from the coal mining.
- the solid carbon content of the tar oils is about 5%.
- the amount of energy of the 95 t / h residue product corresponds to approximately 25% of the energy that was introduced into the fixed-bed gasification via the coarse-particulate 280 t / h coal.
- the total amount of synthesis gas produced can thus be increased from 270,000 Nm 3 / h to 490,000 Nm 3 / h by the described combination of fixed-bed and entrained-flow gasification.
- the residue products from the fixed bed gasification and the fine coal are introduced in the preferred embodiment, Fig. 2, separated by four burners in the gasification reactor (4) of the entrained flow gasifier.
- Two burners are provided for the fixed (5a, 5c) and two burners for the liquid fuel (5b, 5d). All burners (5a-d) are in a horizontal plane, with two burners facing each other.
- the burners are designed in the way that the fuel sekantial to the reactor circumference flows out of the burner (10), wherein the firing angle (9) between the outflow direction of the fuel (11) and the line connecting the burner nozzle and the axis of symmetry of the reactor greater than 0 °, preferably between 3 and 6 °, is.
- Fig. 3 shows the preferred burner for the gasification of the tar oils with fine coal content.
- This consists of three concentrically arranged tubes (6,7,8), which give a central feed tube (6) and two enclosing annular gaps (7,8).
- the liquid fuel is supplied via the central supply pipe (6).
- the fuel is supplied via the annular gap (7).
- the three tubes have a tapered end. The escaping fuel is thus finely divided after discharge. This increases the degree of conversion and thus reduces soot formation to a minimum.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Industrial Gases (AREA)
- Processing Of Solid Wastes (AREA)
- Combustion Of Fluid Fuel (AREA)
- Gasification And Melting Of Waste (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10760911A EP2478072A2 (de) | 2009-09-18 | 2010-09-09 | Verfahren zur kombinierten rückstandsvergasung von flüssigen und festen brennstoffen |
UAA201203012A UA107470C2 (uk) | 2009-09-18 | 2010-09-09 | Спосіб комбінованої газифікації залишків рідких і твердих палив |
RU2012113135/02A RU2553156C2 (ru) | 2009-09-18 | 2010-09-09 | Способ объединенной газификации остатков жидкого и твердого топлива |
US13/496,986 US20120266539A1 (en) | 2009-09-18 | 2010-09-09 | Method for the combined residue gasification of liquid and solid fuels |
CN2010800413714A CN102549117A (zh) | 2009-09-18 | 2010-09-09 | 用于液体燃料和固体燃料的混合残渣气化的方法 |
BR112012005838A BR112012005838A2 (pt) | 2009-09-18 | 2010-09-09 | método para a obtenção de gás de síntese através da gaseificação de produtos residuais líquidos com cinzas da gaseificação em leito fixo a uma pressão entre 0,3 e 8,0 mpa e a uma temperatura maior que 1400°c com gás de gaseamento rico em oxigênio em um reator refrigerado |
CA2774445A CA2774445A1 (en) | 2009-09-18 | 2010-09-09 | Process for combined residues gasification of liquid and solid fuels |
AU2010294844A AU2010294844B2 (en) | 2009-09-18 | 2010-09-09 | Method for the combined residue gasification of liquid and solid fuels |
ZA2012/02798A ZA201202798B (en) | 2009-09-18 | 2012-04-17 | Method for the combined residue gasification of liquid and solid fuels |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009041854.7 | 2009-09-18 | ||
DE102009041854A DE102009041854A1 (de) | 2009-09-18 | 2009-09-18 | Verfahren zur kombinierten Rückstandsvergasung von flüssigen und festen Brennstoffen |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2011032663A2 true WO2011032663A2 (de) | 2011-03-24 |
WO2011032663A3 WO2011032663A3 (de) | 2011-12-08 |
Family
ID=43603419
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2010/005542 WO2011032663A2 (de) | 2009-09-18 | 2010-09-09 | Verfahren zur kombinierten rückstandsvergasung von flüssigen und festen brennstoffen |
Country Status (13)
Country | Link |
---|---|
US (1) | US20120266539A1 (de) |
EP (1) | EP2478072A2 (de) |
KR (1) | KR20120093881A (de) |
CN (1) | CN102549117A (de) |
AU (1) | AU2010294844B2 (de) |
BR (1) | BR112012005838A2 (de) |
CA (1) | CA2774445A1 (de) |
DE (1) | DE102009041854A1 (de) |
RU (1) | RU2553156C2 (de) |
TW (1) | TWI500755B (de) |
UA (1) | UA107470C2 (de) |
WO (1) | WO2011032663A2 (de) |
ZA (1) | ZA201202798B (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101353783B1 (ko) | 2011-12-27 | 2014-01-22 | 주식회사 포스코 | 이산화탄소 발생이 저감된 석탄 가스화 방법 및 장치 |
CN104694170A (zh) * | 2015-03-25 | 2015-06-10 | 西北化工研究院 | 一种以炭质粉体和天然气/甲烷为原料生产合成气的方法 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2012324965B2 (en) * | 2011-10-21 | 2015-06-11 | Air Products And Chemicals, Inc. | Gasification reactor |
RU2695180C1 (ru) * | 2016-03-04 | 2019-07-22 | ЛАММУС ТЕКНОЛОДЖИ ЭлЭлСи | Двухступенчатый газогенератор и способ газификации с универсальностью относительно перерабатываемого сырья |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0095103A1 (de) | 1982-05-22 | 1983-11-30 | Ruhrchemie Aktiengesellschaft | Verfahren und Vorrichtung zur Herstellung von Synthesegas durch partielle Oxidation von Kohle-Wasser-Suspensionen |
DE3820013A1 (de) | 1987-08-17 | 1989-03-02 | Freiberg Brennstoffinst | Verfahren zur gemeinsamen vergasung von fluessigen und festen, staubfoermigen brennstoffen |
DE4226015C1 (de) | 1992-08-06 | 1994-01-13 | Schwarze Pumpe Energiewerke Ag | Verfahren zur Entsorgung von festen und flüssigen Abfallstoffen im Vergasungsprozeß bei der Festbettdruckvergasung |
DE4226034C1 (de) | 1992-08-06 | 1994-02-17 | Schwarze Pumpe Energiewerke Ag | Kombiniertes Verfahren zur Vergasung von festen, pastösen und flüssigen Rest- und/oder Abfallstoffen |
DE4317319B4 (de) | 1993-05-25 | 2005-10-20 | Schwarze Pumpe Energiewerke Ag | Verfahren der flexiblen und integrierten Reststoffvergasung |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE543003C (de) * | 1927-10-02 | 1932-02-02 | Carl Salat | Brenner fuer staubfoermige, fluessige und gasfoermige Brennstoffe |
DE4125521C1 (de) * | 1991-08-01 | 1992-10-29 | Energiewerke Schwarze Pumpe Ag, O-7610 Schwarze Pumpe, De | |
CN1054080C (zh) * | 1995-09-07 | 2000-07-05 | 华东理工大学 | 带有旋流器的三通道组合式水煤浆气化喷嘴 |
DE19608093C2 (de) * | 1996-03-02 | 2000-08-10 | Krc Umwelttechnik Gmbh | Verfahren zur Verwertung von Rest- und Abfallstoffen sowie heizwertarmen Brennstoffen in einem Zementofen |
DE19829385C1 (de) * | 1998-07-01 | 1999-10-28 | Krc Umwelttechnik Gmbh | Vorrichtung zur Flugstromvergasung von kohlenstoffhaltigen Brenn-, Rest- und Abfallstoffen |
DE102005035921B4 (de) * | 2005-07-28 | 2008-07-10 | Choren Industries Gmbh | Verfahren zur endothermen Vergasung von Kohlenstoff |
CN101003755B (zh) * | 2006-01-19 | 2010-09-29 | 神华集团有限责任公司 | 一种多喷嘴气化炉及其气化方法 |
DE102006059149B4 (de) * | 2006-12-14 | 2009-06-25 | Siemens Ag | Flugstromreaktor zur Vergasung fester und flüssiger Energieträger |
DE102007006981B4 (de) * | 2007-02-07 | 2009-01-29 | Technische Universität Bergakademie Freiberg | Verfahren, Vergasungsreaktor und Anlage zur Flugstromvergasung fester Brennstoffe unter Druck |
RU2333929C1 (ru) * | 2007-02-26 | 2008-09-20 | Институт химии и химической технологии СО РАН (ИХХТ СО РАН) | Способ и установка для газификации твердого топлива |
WO2008110592A1 (en) * | 2007-03-15 | 2008-09-18 | Shell Internationale Research Maatschappij B.V. | Gasification reactor vessel with inner multi-pipe wall and several burners |
-
2009
- 2009-09-18 DE DE102009041854A patent/DE102009041854A1/de not_active Withdrawn
-
2010
- 2010-09-09 CN CN2010800413714A patent/CN102549117A/zh active Pending
- 2010-09-09 UA UAA201203012A patent/UA107470C2/uk unknown
- 2010-09-09 AU AU2010294844A patent/AU2010294844B2/en not_active Ceased
- 2010-09-09 EP EP10760911A patent/EP2478072A2/de not_active Withdrawn
- 2010-09-09 US US13/496,986 patent/US20120266539A1/en not_active Abandoned
- 2010-09-09 KR KR1020127009542A patent/KR20120093881A/ko active IP Right Grant
- 2010-09-09 BR BR112012005838A patent/BR112012005838A2/pt not_active IP Right Cessation
- 2010-09-09 WO PCT/EP2010/005542 patent/WO2011032663A2/de active Application Filing
- 2010-09-09 CA CA2774445A patent/CA2774445A1/en not_active Abandoned
- 2010-09-09 RU RU2012113135/02A patent/RU2553156C2/ru not_active IP Right Cessation
- 2010-09-16 TW TW099131400A patent/TWI500755B/zh not_active IP Right Cessation
-
2012
- 2012-04-17 ZA ZA2012/02798A patent/ZA201202798B/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0095103A1 (de) | 1982-05-22 | 1983-11-30 | Ruhrchemie Aktiengesellschaft | Verfahren und Vorrichtung zur Herstellung von Synthesegas durch partielle Oxidation von Kohle-Wasser-Suspensionen |
DE3820013A1 (de) | 1987-08-17 | 1989-03-02 | Freiberg Brennstoffinst | Verfahren zur gemeinsamen vergasung von fluessigen und festen, staubfoermigen brennstoffen |
DE4226015C1 (de) | 1992-08-06 | 1994-01-13 | Schwarze Pumpe Energiewerke Ag | Verfahren zur Entsorgung von festen und flüssigen Abfallstoffen im Vergasungsprozeß bei der Festbettdruckvergasung |
DE4226034C1 (de) | 1992-08-06 | 1994-02-17 | Schwarze Pumpe Energiewerke Ag | Kombiniertes Verfahren zur Vergasung von festen, pastösen und flüssigen Rest- und/oder Abfallstoffen |
DE4317319B4 (de) | 1993-05-25 | 2005-10-20 | Schwarze Pumpe Energiewerke Ag | Verfahren der flexiblen und integrierten Reststoffvergasung |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101353783B1 (ko) | 2011-12-27 | 2014-01-22 | 주식회사 포스코 | 이산화탄소 발생이 저감된 석탄 가스화 방법 및 장치 |
CN104694170A (zh) * | 2015-03-25 | 2015-06-10 | 西北化工研究院 | 一种以炭质粉体和天然气/甲烷为原料生产合成气的方法 |
Also Published As
Publication number | Publication date |
---|---|
ZA201202798B (en) | 2012-12-27 |
WO2011032663A3 (de) | 2011-12-08 |
AU2010294844A1 (en) | 2012-04-05 |
CN102549117A (zh) | 2012-07-04 |
RU2012113135A (ru) | 2013-11-10 |
RU2553156C2 (ru) | 2015-06-10 |
AU2010294844B2 (en) | 2015-05-07 |
DE102009041854A1 (de) | 2011-03-24 |
US20120266539A1 (en) | 2012-10-25 |
TWI500755B (zh) | 2015-09-21 |
UA107470C2 (uk) | 2015-01-12 |
EP2478072A2 (de) | 2012-07-25 |
KR20120093881A (ko) | 2012-08-23 |
CA2774445A1 (en) | 2011-03-24 |
TW201116616A (en) | 2011-05-16 |
BR112012005838A2 (pt) | 2017-05-30 |
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