WO2011028394A2 - Solar panels with adhesive layers - Google Patents

Solar panels with adhesive layers Download PDF

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Publication number
WO2011028394A2
WO2011028394A2 PCT/US2010/045564 US2010045564W WO2011028394A2 WO 2011028394 A2 WO2011028394 A2 WO 2011028394A2 US 2010045564 W US2010045564 W US 2010045564W WO 2011028394 A2 WO2011028394 A2 WO 2011028394A2
Authority
WO
WIPO (PCT)
Prior art keywords
composition
panel
alpha
olefm
poly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/045564
Other languages
English (en)
French (fr)
Other versions
WO2011028394A3 (en
Inventor
Linda M. Rivard
Jeffrey G. Linert
Howard S. Creel
James R. Peterson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Priority to JP2012526832A priority Critical patent/JP2013503245A/ja
Priority to EP10814152A priority patent/EP2470614A2/en
Priority to CN201080037658XA priority patent/CN102482542A/zh
Priority to SG2012010641A priority patent/SG178438A1/en
Publication of WO2011028394A2 publication Critical patent/WO2011028394A2/en
Publication of WO2011028394A3 publication Critical patent/WO2011028394A3/en
Priority to IL218100A priority patent/IL218100A0/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/16Elastomeric ethylene-propylene or ethylene-propylene-diene copolymers, e.g. EPR and EPDM rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F10/00Individual photovoltaic cells, e.g. solar cells
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F19/00Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
    • H10F19/80Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells
    • H10F19/804Materials of encapsulations
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Definitions

  • the photovoltaic material may comprises crystalline silica, amorphous silica, cadmium telluride, cadmium sulfide, or copper indium gallium diselenium.
  • Figure 2 is a cross sectional, exploded view of a second embodiment of a solar panel using the composition of the present application as an adhesive.
  • Figure 3 is a cross sectional, exploded view of a third embodiment of a solar panel using the composition of the present application as an adhesive.
  • the composition has less than 5% of a tackifier, specifically less than 1% and in some embodiments, 0% tackifier.
  • the Melt Flow Index (MFI) of the composition is generally less than 30. MFI is measured using film samples according to ASTM D1238. In some embodiments, the MFI is below 20, and in some instances the MFI is below 15 or below 10. In specific embodiments, the MFI of the composition is less than 7, and in some embodiments less than 2, and in specific embodiments 1 or less.
  • the MFI is related to the melt viscosity of the composition. For example, the higher the melt flow index of a composition, the lower the melt viscosity of that composition. In the present application, the compositions have high melt viscosity, for example in excess of 500,000 cP at 150°C.
  • Useful low crystalline poly-alpha-olefms include polymers (including
  • Melt flow index was measured from film samples according to ASTM D1238. The films were cut into 1 in x 3 in strips and rolled to fit into the MFI inlet chamber of the TINIUS OLSEN EXTRUSION PLASTOMETER, MP600 version 4.04.
  • VESTOPLAST 206 (commercially available from EVONIK-DEGUSSA, Essen, Germany).
  • the strips of "VESTOPLAST 206" were made by heating a 55 gallon drum, unloading with a drum unloader onto an aluminum pan, cooling and storing in a desiccator for at least a week and finally cutting into strips with a scissors.
  • a 0.018" film was prepared and tested for WVTR, creep, adhesion and MFI. Melt flow index (MFI) was measured to be 0.54 g/10 min @ 190 °C/2.16 kg.
  • a 0.018" film was prepared from 100 %"ENGAGE 8842" pellets and tested for WVTR, creep, adhesion and MFI.
  • Melt flow index (MFI) was taken from Dow Chemical trade literature as 1.0 g/10 min @ 190 °C/2.16 kg.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Photovoltaic Devices (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesive Tapes (AREA)
PCT/US2010/045564 2009-08-25 2010-08-16 Solar panels with adhesive layers Ceased WO2011028394A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2012526832A JP2013503245A (ja) 2009-08-25 2010-08-16 接着層を有するソーラーパネル
EP10814152A EP2470614A2 (en) 2009-08-25 2010-08-16 Solar panels with adhesive layers
CN201080037658XA CN102482542A (zh) 2009-08-25 2010-08-16 具有粘合剂层的太阳能电池板
SG2012010641A SG178438A1 (en) 2009-08-25 2010-08-16 Solar panels with adhesive layers
IL218100A IL218100A0 (en) 2009-08-25 2012-02-14 Solar panels with adhesive layers

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/547,004 US8507792B2 (en) 2009-08-25 2009-08-25 Solar panels with adhesive layers
US12/547,004 2009-08-25

Publications (2)

Publication Number Publication Date
WO2011028394A2 true WO2011028394A2 (en) 2011-03-10
WO2011028394A3 WO2011028394A3 (en) 2011-06-30

Family

ID=43623049

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/045564 Ceased WO2011028394A2 (en) 2009-08-25 2010-08-16 Solar panels with adhesive layers

Country Status (9)

Country Link
US (1) US8507792B2 (https=)
EP (1) EP2470614A2 (https=)
JP (1) JP2013503245A (https=)
KR (1) KR20120053048A (https=)
CN (1) CN102482542A (https=)
IL (1) IL218100A0 (https=)
SG (1) SG178438A1 (https=)
TW (1) TW201113339A (https=)
WO (1) WO2011028394A2 (https=)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012243853A (ja) * 2011-05-17 2012-12-10 Yokohama Rubber Co Ltd:The 太陽電池用反応型ホットメルトシーリング剤組成物
JP2013119583A (ja) * 2011-12-07 2013-06-17 Mitsubishi Chemicals Corp シラングラフトポリオレフィン及びシラン架橋ポリオレフィン樹脂
US20140007940A1 (en) * 2011-03-31 2014-01-09 Shaofu Wu Light transmitting thermoplastic resins comprising down conversion material and their use in photovoltaic modules

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IT1398958B1 (it) * 2010-03-23 2013-03-28 Politec Polimeri Tecnici S A Ora Koscon Ind S A Lucernario integrabile in una struttura di copertura in lamiere coibentate e relativo metodo di produzione
KR20130138293A (ko) * 2010-12-16 2013-12-18 다우 글로벌 테크놀로지스 엘엘씨 실란 함유 열가소성 폴리올레핀 코폴리머 수지, 필름, 그의 제조방법 및 이 수지와 필름을 포함하는 광기전 모듈 라미네이트 구조물
US10383207B2 (en) * 2011-10-31 2019-08-13 Cellink Corporation Interdigitated foil interconnect for rear-contact solar cells
JP2015503225A (ja) 2011-11-04 2015-01-29 スリーエム イノベイティブ プロパティズ カンパニー ソーラーモジュール用の耐久性ポリオレフィン接着材料
WO2013066459A1 (en) 2011-11-04 2013-05-10 3M Innovative Properties Company Polyolefin adhesive material for use in solar modules
CN102544180A (zh) * 2012-02-08 2012-07-04 南京大学 一种硫系太阳能电池及其制作方法
US10583692B2 (en) 2014-10-24 2020-03-10 Exxonmobil Chemical Patents Inc. Chain end functionalized polyolefins for improving wet traction and rolling resistance of tire treads
WO2016093934A2 (en) * 2014-10-24 2016-06-16 Exxonmobil Chemical Patents Inc. Chain end functionalized polyolefins for improving wet traction and rolling resistance of tire treads
US10023719B2 (en) 2015-02-02 2018-07-17 Exxonmobil Chemical Patents Inc. Toughened polyolefin nanocomposites using silane functionalized polyolefins
US11116070B2 (en) 2017-07-13 2021-09-07 Cellink Corporation Interconnect circuit methods and devices
US20210082634A1 (en) 2018-02-14 2021-03-18 Lg Electronics Inc. Solar cell module comprising perovskite solar cell and manufacturing method thereof
KR102717342B1 (ko) * 2021-05-26 2024-10-16 한국전자기술연구원 집광형 창호

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140007940A1 (en) * 2011-03-31 2014-01-09 Shaofu Wu Light transmitting thermoplastic resins comprising down conversion material and their use in photovoltaic modules
JP2012243853A (ja) * 2011-05-17 2012-12-10 Yokohama Rubber Co Ltd:The 太陽電池用反応型ホットメルトシーリング剤組成物
JP2013119583A (ja) * 2011-12-07 2013-06-17 Mitsubishi Chemicals Corp シラングラフトポリオレフィン及びシラン架橋ポリオレフィン樹脂

Also Published As

Publication number Publication date
TW201113339A (en) 2011-04-16
EP2470614A2 (en) 2012-07-04
IL218100A0 (en) 2012-04-30
SG178438A1 (en) 2012-03-29
WO2011028394A3 (en) 2011-06-30
KR20120053048A (ko) 2012-05-24
JP2013503245A (ja) 2013-01-31
CN102482542A (zh) 2012-05-30
US20110048536A1 (en) 2011-03-03
US8507792B2 (en) 2013-08-13

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