WO2010140958A1

WO2010140958A1 - Nanolaminated coated cutting tool

Info

Publication number: WO2010140958A1
Application number: PCT/SE2010/050580
Authority: WO
Inventors: Jon Andersson; Rachid M'saoubi; Hindrik ENGSTRÖM; Mats Johansson
Original assignee: Seco Tools Ab
Priority date: 2009-06-01
Filing date: 2010-05-28
Publication date: 2010-12-09
Also published as: SE533884C2; JP2012528732A; KR20120015338A; EP2438209A4; EP2438209B1; EP2438209A1; US8852305B2; CN102449194B; SE0900739A1; CN102449194A; US20120114436A1; KR101764101B1

Abstract

The present invention relates to a cutting tool insert for machining by chip removal comprising a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel, onto which a hard and wear resistant coating is deposited by physical vapour deposition (PVD). Said coating comprises a polycrystalline nanolaminated structure of alternating layers A and B where layer A is (Ti,Al,Me1)N and Me1 is optionally one or more of the metal elements from group 3, 4, 5 or 6 in the periodic table, layer B is (Ti,Si,Me2)N and Me2 is optionally one or more of the metal elements from group 3, 4, 5 or 6 in the periodic table including Al with a thickness between 0.5 and 20 um and method of making the same. This insert is particularly useful in metal cutting applications generating high temperatures with im-proved edge integrity, e.g., machining of super alloys, stainless steels and hardened steels.

Description

NANOLAMINATED COATED CUTTING TOOL BACKGROUND OF THE INVENTION The present invention relates to a cutting tool insert coated with a hard and wear resistant coating comprising a nanolaminated structure based on (Ti₅Al)N and (Ti₅Si)N layers, respectively. This insert is particularly useful in metal cutting applications generating high temperatures, e.g., machining of super alloys, stainless steels and hardened steels. The coating is grown by physical vapour deposition (PVD) and preferably by ca- thodic arc evaporation.

US 7,056,602 discloses a cutting tool insert coated with a cubic structured (Ti_yAl_xMei-_x-y)N based layer where Me is one of the elements: Zr, Hf, V, Nb, Ta, Cr, Mo, W or Si, and: x is between 0.50 and 0.80; the ratio, x/(x+y), is between 0.50 and 0.85; the sum of Ti and Al subscripts, x+y, is between 0.7 and 1.0.

EP 1736565 discloses a cutting tool cubic boron nitride based insert coated with a cubic structured (Me₅Si)X phase, where Me is one or more of the elements Ti, V, Cr, Zr, Nb, Mo, Hf, Ta and Al, and X is one or more of the elements N, C, O or B

EP 0588350 discloses a hard layer of Ti-Si-N composite material on a body, the layer being deposited using a source of evaporation possessing a composition of Ti_aSib with a in the range of 75 - 85 at% and b 15 - 25 at%. Coating optimization has also been obtained by applying different concepts of multilayers as; alternating Ti and Al containing layers (US 6,309,738), oxygen and non- oxygen containing layers (US 6,254,984), one of the layers stacked in the multilayer consists itself of a multilayer (US 6,077,596), alternating nitrogen content (US 5,330,853) or using one metastable compound (US 5,503,912) or as aperiodic multilayer (US 6,103,357).

Further improvements in thermal stability and hardness have been achieved by the introduction of Si into TiN- or TiAlN-based coatings. JP 2000-334607 discloses a coated tool with laminated layers comprising TiSi (layer a) and TiAl (layer b) compounds. The (a) layer is selected among nitride, carbonitride, oxynitride and oxycarbonitride containing 10% < Si < 60% with a NaCl type crystalline structure. Layer (b) is selected among nitride, carbonitride, oxynitride and oxycarbonitride containing 40% < Al < 75% with a NaCl type crystalline structure. The (a) layer and (b) layers are applied alternately and the (b) layer is located just above the surface of the base material. EP 1939327 discloses a cutting tool comprising a hard coating giving improved crater and flank wear resistance, said coating comprising an aperiodic multilayer X+Y+X+Y+... with average layer thickness of X and Y layers of between 0.1 and 100 nm and with average chemical composition Al_aTibSi_cCrdC_eNi-e, where 0 < a < 0.5, 0.1 < b < 0.9, 0.01 < c < 0.17, 0 < d < 0.06, a+b+c+d=l, and 0 < e < 1.

The trends towards dry-work processes for environmental protection, i.e., metal cutting operation without using cutting fluids (lubricants) and accelerated machining speed with improved process put even higher demands on the characteristics of the tool materials due to an increased tool cutting-edge temperature. In particular, coating stability at high temperatures, e.g., oxidation- and wear-resistance have become even more crucial. It is an object of the present invention to provide a coated cutting tool yielding improved performance in metal cutting applications at elevated temperatures.

It is a further object of the present invention to provide a coated cutting tool with improved edge integrity.

It has been found that combining layers based on (Ti₅Si)N and (Ti₅Al)N, respectively, in a nanolaminated coating structure onto a cutting tool insert significantly improves the tool life due to increased crater wear resistance, flank wear resistance and edge integrity, especially in machining operations generating high tool temperatures.

BRIEF DESCRIPTION OF THE DRAWINGS

Fig 1 ; Scanning electron microscopy (SEM) image showing a fractured cross section of a Ti0.38Al0.6₂N/Ti0.93Si0.07N nanolaminated structure.

Fig 2; X-ray diffraction patterns from (a) Tio.3sAlo.6₂N single layer, (b) Tio.sβSio.πN single layer, and (c) Tio.3sAlo.6₂N/Tio.86Sio.₁₄N nanolaminated structure. The diffraction peaks are indexed as cubic phase (Ti₅Si)N (marked with 1), cubic phase (Ti₅Al)N (marked with 2) and the peaks originating from the WC or Co (dotted lines).

Fig 3; Scanning electron microscopy (SEM) images showing examples of the cutting edges after 11 minutes of turning in stainless steel showing (a) Tio.3sAlo.6₂N single layer, (b) Tio.66Alo.₂9Sio.o5N single layer, and (c) Ti0.3sAl0.6₂N/Ti0.93Si0.07N nanolaminated structure.

DETAILED DESCRIPTION OF THE INVENTION

According to the present invention, there is provided a cutting tool for machining by chip removal comprising a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel, preferably cemented carbide and cermet, onto which is deposited a hard and wear resistant coating comprising a poly- crystalline nanolaminated structure of alternating A and B layers with a thickness between 0.5 and 20 μm, preferably between 0.5 and 10 μm, most preferably between 0.5 and 5 μm. Preferably the nanolaminated structure has an overall columnar structure with average column width between 20 and 1000 nm, preferably between 20 and 500 nm, as determined by, e.g., cross section scanning electron microscopy of a middle region of the nanolaminated structure, i.e., in a region within 30 to 70 % of the thickness in the growth direction, and said average columnar width is the average from measuring the width of at least ten adjacent columns.

Said layer A is (Tii__xAl_xMel_p)N_a, where 0.3 < x < 0.95, preferably 0.45 < x < 0.75, and 0.90 < a < 1.10, preferably 0.96 < a < 1.04, 0 < p < 0.15, and Mel is one or more of the metal elements from group 3, 4, 5 or 6 in the periodic table, preferably one or more of Zr, Y, V, Nb, Mo and W, most preferably one or more of Zr, Y, V and Nb. Said layer B is (Tii__y__zSi_yMe2_z)Nb, where 0.05 < y < 0.25 preferably 0.05 < y < 0.18, 0 ≤ z < 0.4, 0.9 < b < 1.1, preferably 0.96 < b < 1.04, and Me2 is one or more of the metal elements from group 3, 4, 5 or 6 in the periodic table including Al, preferably one or more of Y, V, Nb, Mo, W and Al, most preferably one or more of Y, V, Nb and Al. Layers A and B have an average individual layer thickness between 1 nm and 50 nm, as measured by, e.g., cross sectional transmission electron microscopy of a middle region of the nano laminated structure, i.e., a region within 30 to 70 % of the thickness in the growth direc- tion, and said average layer thickness is the average from measuring the thickness of at least ten adjacent layers. Said nanolaminated structure comprises a phase mixture of cubic and hexagonal phases, preferably only cubic phases, as determined by X-ray diffraction. In a first preferred embodiment z = p = 0.

In a second preferred embodiment Mel is one or more of Zr, Y, V and Nb with 0 < p < 0.05. In a third preferred embodiment Me2 is Y, 0 < z < 0.15.

In a fourth preferred embodiment Me2 is one or both of V and Nb with 0 < z < 0.3.

In a fifth preferred embodiment Me2 is Al, 0.2 < z < 0.4.

Within the nanolaminated structure, Layer A has a stress level of -5.0 < σ < 0 GPa, preferably -3.0 < σ < -0.5 GPa.

Said coating may comprise an inner single- and/or multilayer coating of TiN, TiC, Ti(C,N) or (Ti₅Al)N, preferably (Ti₅Al)N, and/or an outer single- and/or multilayer coating ofTiN, TiC, Ti(C,N), (Ti₅Si)N or (Ti₅Al)N, preferably (Ti₅Si)N or (Ti₅Al)N₅ according to prior art, to a total coating thickness, including the thickness of the nanolaminated structure, of between 0.5 and 30 μm, preferably between 0.5 and 15 μm, and most preferably between 0.5 and 10 μm.

The deposition method for the coatings of the present invention is physical vapour deposition (PVD), preferably cathodic arc evaporation, using alloy or composite cathodes under the following conditions; (Ti,Al,Mel)N and (Ti,Si,Me2)N layers are grown from cathodes yielding the desired layer composition. The evaporation current is between 50 A and 200 A. The layers are grown in an Ar + N₂ atmosphere, preferably in a pure N₂ atmosphere, at a total pressure of 0.5 Pa to 9.0 Pa, preferably 1.5 Pa to 5.0 Pa. The bias is -10 V to -300 V, preferably -20 V to -200V. The deposition temperature is between 350 ⁰C and 700 ⁰C, preferably between 400 ⁰C and 650 ⁰C. The invention also relates to the use of cutting tool inserts according to the above for machining of stainless steel, super alloys and hardened steel at cutting speeds of 50 - 500 m/min, preferably 50 - 300 m/min, with an average feed of 0.08 - 0.5 mm/rev, preferably 0.1 - 0.4 mm/rev, depending on cutting speed and insert geometry.

Example 1

The coatings of Table 1 were deposited by cathodic arc evaporation onto the following inserts:

Sl : Cemented carbide with (90 wt% WC + 10 wt% Co) S2: Cemented carbide with (94 wt% WC + 6 wt% Co)

S3: Seco Tools commercial cermet grade, CM

Before deposition, the inserts were cleaned in ultrasonic baths of an alkali solution and alcohol. The deposition chamber was evacuated to a base pressure of less than 2.OxIO^"3 Pa, after which the inserts were sputter cleaned with Ar ions. The coatings were deposited from alloy or composite cathodes in 99.995% pure N₂ atmosphere at a total pressure of 2-6 Pa, using a bias of -20 to -60 V and an evaporation current of 60-200 A at 450 ⁰C. The cathodes were selected to yield the composition of Layer A and Layer B, respectively, and mounted on opposing sides of the deposition chamber in order to obtain the nanolaminated structure by fixture rotation. The average individual layer thickness was varied by altering the cathode current (60-200 A) and the rotation speed of the fixture (1- 5 rpm). The total coating thickness was about 2 μm for all inserts as measured on the flank face. Fig 1 shows a scanning electron microscopy (SEM) image of a Ti0.38Al0.62N/Ti0.93Si0.07N nanolaminated structure (coating 9). The individual layers are clearly seen, indicating minimal intermixing between adjacent layers. The individual layer thickness varies due to a 3-fold fixture rotation and a columnar micro structure extends throughout the nanolaminated structure.

X-ray diffractograms of as-deposited coatings were obtained using Cu Ka radiation and a Θ-2Θ configuration. Fig 2 shows (a) Tio.3sAlo.62N single layer (coating 39), (b) Tio.8eSio.14N single layer (coating 41), and (c) Tio.3sAlo.62N/Tio.86Sio.14N nanolaminated structure (coating 1). All three coatings display only cubic NaCl crystal structures.

The average residual stress, σ, is shown in Table 1. The stresses were evaluated by XRD measurements using the sin ψ method. The measurements were performed using CuKa- radiation on the NaCl (422)-reflections. Data was obtained with eleven Ψ-angles (positive and negative), equidistant within a sin²Ψ range of 0 to 0.75 (Ψ=0-60°). The residual stress values were evaluated using a Poisson's ratio of v=0.22 and Young's modulus of E=450 GPa. For the nanolaminated structures stress values were measured for the (Ti₅Al)N layers.

The total average composition of the nanolaminated structure was measured by energy dispersive x-ray spectroscopy (EDS) analysis area using a LEO Ultra 55 scanning elec- tron microscope with a Thermo Noran EDS detector operating at 10 kV. The data were evaluated using the Noran System Six (NSS version 2) software.

Table 1 summarizes the results for the example coatings, both according to the invention and comparative coatings according to prior art.

Table 1.

Example 2.

Coatings 1-8, 10, 12, 22, 29, 34-45 on Sl inserts were tested under the following conditions: Geometry: CNMG 120408 -MFl

Application: Longitudinal turning

Work piece material: AISI 316L

Cutting speed: 230 m/min Feed: 0.15 mm/rev

Depth of cut: 1.5 mm

Tool life criteria: Flank wear (vb) > 0.3 mm

The results are presented in Table 2.

Figure 3 shows SEM images of used edges after 11 minutes turning with (a) comparative coating 39, (b) comparative coating 43, and (c) inventive coating 8. It is clearly seen that the inventive coating show improved crater and edge wear characteristics. Example 3.

Coatings 1, 4, 6, 15, 33, 37, 39, 41, 45 on S2 inserts were tested under the following conditions: Geometry: CNMG 120408 -MFl

Application: Longitudinal turning

Work piece material: Inconel 718

Cutting speed: 70 m/min

Feed: 0.2 mm/rev Depth of cut: a_p = 0.5 mm

Tool life criteria: Flank wear (vb) > 0.3 mm

The results are presented in Table 2. Example 4.

Coatings 1, 3, 9, 17, 36, 39-45 on S3 inserts were tested under the following conditions:

Geometry: DCMTl 1T304-F1 Application: Longitudinal turning

Work piece material: DIN 100Cr6

Cutting speed: 250 m/min

Feed: 0.15 mm/rev

Depth of cut: a_p = 0.5 mm Tool life criteria: Flank wear (vb) > 0.2 mm

The results are presented in Table 2. Table 2.

It is obvious from the above examples 2 - 4 that the inserts according to the invention show an increased tool performance with improved edge and crater wear characteristics.

Claims

1. Cutting tool insert for machining by chip removal comprising a body of a hard alloy of cemented carbide, cermet, ceramics, cubic boron nitride based material or high speed steel, onto which is deposited a hard and wear resistant PVD coating characterised in that said coating comprises a columnar and polycrystalline nanolaminated structure of alternating A and B layers where layer A is (Tii__xAl_xMe I_p)Na, with 0.3 < x < 0.95, preferably 0.45 < x < 0.75, 0.90 < a < 1.10, preferably 0.96 < a < 1.04, 0 < p < 0.15, and Mel is one or more of Zr, Y, V, Nb, Mo and W, and where layer B is (Tii__y__zSi_yMe2_z)N_b, with 0.05 < y < 0.25, preferably 0.05 <y<0.18,0≤z< 0.4, 0.9 < b < 1.1, preferably 0.96 < b < 1.04, and Me2 is one or more of Y, V, Nb, Mo, W and Al, with a thickness of the nanolaminated structure between 0.5 and 20 μm, preferably between 0.5 and 10 μm, an average column width between 20 and 1000 nm, and an average individual thickness of A and B layers between 1 and 50 nm.

2. Cutting tool insert according to claim 1 characterised in that said nanolaminated structure comprises a phase mixture of cubic and hexagonal phases, preferably only cubic phases, as determined by X-ray diffraction.

3. Cutting tool insert according to any of claims 1 and 2characterisedin that z = p = 0.

4. Cutting tool insert according to any of the preceding claims characterised in that said coating comprises an inner single- and/or multilayer coating of TiN, TiC, Ti(C,N) or (Ti₅Al)N, preferably (Ti₅Al)N, and/or an outer single- and/or multilayer coating ofTiN, TiC, Ti(C,N), (Ti₅Si)N or (Ti₅Al)N, preferably (Ti₅Si)N or (Ti₅Al)N₅ to a total coating thickness, including the thickness of the nanolaminated structure, of between 0.5 and 30 μm, preferably between 0.5 and 15 μm.

5. Cutting tool insert according to any of the preceding claims characterised in that said body is cemented carbide or cermet.

6. Method of making a cutting tool insert according to claim 1 characterised in that said coating is deposited by cathodic arc evaporation of alloyed or composite cath- odes yielding the desired composition of the (Ti,Al,Mel)N and (Ti,Si,Me2)N layers using an evaporation current between 50 A and 200 A, in an Ar + N₂ atmosphere, preferably in a pure N₂ atmosphere, at a total pressure of 0.5 Pa to 9.0 Pa, preferably 1.5 Pa to 5.0 Pa, a bias between -10 V and -300 V, preferably between -20 V and -200 V, at 350 ⁰C to 700⁰C, preferably 400⁰C to 650⁰C.

7. Use of cutting tool inserts according to any of claims 1 to 5 for machining of stainless steel, super alloys and hardened steel at cutting speeds of 50 - 500 m/min, preferably 50 - 300 m/min, with an average feed of 0.08 - 0.5 mm/rev, preferably 0.1 - 0.4 mm/rev.