WO2010131997A2 - Procédé pour modifier la composition moléculaire d'un carburant à base d'hydrocarbures sous l'effet d'un champ électrique et dispositif pour mettre en oeuvre ce procédé - Google Patents

Procédé pour modifier la composition moléculaire d'un carburant à base d'hydrocarbures sous l'effet d'un champ électrique et dispositif pour mettre en oeuvre ce procédé Download PDF

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Publication number
WO2010131997A2
WO2010131997A2 PCT/RU2010/000365 RU2010000365W WO2010131997A2 WO 2010131997 A2 WO2010131997 A2 WO 2010131997A2 RU 2010000365 W RU2010000365 W RU 2010000365W WO 2010131997 A2 WO2010131997 A2 WO 2010131997A2
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
electric field
liquid hydrocarbon
housing
molecular composition
Prior art date
Application number
PCT/RU2010/000365
Other languages
English (en)
Russian (ru)
Other versions
WO2010131997A3 (fr
Inventor
Сергей Владимирович ТУЕВ
Геннадий Федорович ТЕРЕЩЕНКО
Олег Викторович БЕЛЫЙ
Павел Федорович АНИСИМОВ
Юрий Марсович ИСКАНДЕРОВ
Виктор Григорьевич МУРАМОВИЧ
Original Assignee
Tuev Sergei Vladimirovich
Tereschenko Gennadij Fedorovich
Belyj Oleg Viktorovich
Anisimov Pavel Fedorovich
Iskanderov Jurij Marsovich
Muramovich Viktor Grigorievich
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tuev Sergei Vladimirovich, Tereschenko Gennadij Fedorovich, Belyj Oleg Viktorovich, Anisimov Pavel Fedorovich, Iskanderov Jurij Marsovich, Muramovich Viktor Grigorievich filed Critical Tuev Sergei Vladimirovich
Priority to DE212010000074U priority Critical patent/DE212010000074U1/de
Publication of WO2010131997A2 publication Critical patent/WO2010131997A2/fr
Publication of WO2010131997A3 publication Critical patent/WO2010131997A3/fr

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F02M27/04Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by electric means, ionisation, polarisation or magnetism
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0824Details relating to the shape of the electrodes
    • B01J2219/0826Details relating to the shape of the electrodes essentially linear
    • B01J2219/083Details relating to the shape of the electrodes essentially linear cylindrical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873Materials to be treated
    • B01J2219/0877Liquid

Definitions

  • the invention relates to technologies for producing liquid hydrocarbon fuels of improved quality and can be used in various technological processes, both in the petrochemical industry and in preparing liquid hydrocarbon fuels for the combustion process in various power plants in order to increase efficiency and improve environmental performance.
  • liquid fuel is activated before dispersion in an electric field of a pulsed current with a frequency of 250-300 Hz and a voltage of 20-25 kV and divided into flows of opposite polarity.
  • the activator for liquid fuel contains a housing with inlet and outlet nozzles, electrodes placed inside the activator and connected to a high voltage current source, and a semipermeable membrane for separating charged streams.
  • the disadvantages of the known method and activator are: - the separation of the processed fuel into two bipolar flows does not ensure the complete processing of the entire fuel flow, since after separation into fractions only part of the processed fuel is sent to combustion; - use of an electric field of a pulse current with a frequency
  • the closest in technical essence and the achieved result to the claimed method is a method of processing fuel, which consists in passing a fuel stream through a portion of a fuel pipe in which electrodes are mounted to which alternating voltage with a variable frequency is applied. A layer of dielectric material is placed between the bipolar electrodes in the processing chamber.
  • the parameters of the electromagnetic effect on the fuel are set in accordance with the experimentally established ratio and certain numerical values (patent RU N ° 20385506, class F02M 27/04, publ. 06/27/1995 - prototype).
  • the disadvantage of this method should include the following. Due to the additional energy potential under the influence of an electromagnetic field, the fuel is additionally energized and crushed into small fractions. Moreover, due to the finer fractions of the fuel, its more complete combustion occurs without changing the structure of the molecular composition of the fuel and increasing the heat of combustion.
  • a device for processing fuel containing the casing is in the form of a chamber with inlet and outlet openings, equipped with at least two bipolar electrodes for applying an electric constant field to the fuel flow in the treatment chamber, connected to a power source, the casing being one of the electrodes and the other internal electrode placed in the processing chamber, located coaxially to the housing (patent RU JN2156879, class F02M 27/04, publ. 09/27/2000 - prototype).
  • the disadvantages of the known device are:
  • An object of the invention is to provide a method and device for changing the structure of the molecular composition of liquid hydrocarbon fuel under the influence of an electric field, providing an improvement in the chemical structure of the fuel and increasing the heat of combustion.
  • E is the amplitude of the electric field
  • is the electrical conductivity of the fuel
  • M is the molecular mass of fissile hydrocarbons in the processed fuel.
  • V 3 is the total volume of electrodes placed inside the treatment zone, p is the density of the fuel;
  • - fuel processing is carried out in its stationary state relative to the electrodes; - fuel processing is carried out in the process of its movement through the processing zone.
  • the objective of the invention is also solved by the creation of a device for changing the structure of the molecular composition of liquid hydrocarbon fuel under the influence of an electric field, containing a housing with inlet and outlet openings, provided with electrodes for influencing the electric field on the fuel flow in the processing chamber, connected to a power source, while the housing is one of electrodes, and another internal electrode, located in the processing chamber, is located coaxial to the housing, according to the invention, the power source is full in the form of an alternating voltage generator, while the inner electrode is hollow and an additional electrode is coaxially placed inside it, electrically connected to the housing, and the length of the inner electrode corresponds to the empirical ratio
  • L ⁇ xE / 2 ⁇ xfxM, where L is the length of the middle electrode
  • M is the molecular weight of fissile hydrocarbons in the processed fuel.
  • the cross-sectional area of the inlet and the cross-sectional area of the processing chamber are in the ratio S BX ⁇ S K , where S rougex is the cross-sectional area of the inlet, $ k is the cross-sectional area of the processing chamber; - in the housing at the locations of the inlet and outlet openings, respectively, the inlet and outlet nozzles are installed;
  • the inventive method and device allows you to change the structure of the molecular composition of liquid hydrocarbon fuel under the influence of an alternating electric field, which improves the chemical structure of the fuel and increases the heat of combustion.
  • Figure l presents a longitudinal section of a device for changing the structure of the molecular composition of liquid hydrocarbon fuel under the influence of an electric field.
  • a device for changing the structure of the molecular composition of liquid hydrocarbon fuel under the influence of an electric field it is preferable:
  • the inventive method is implemented in a device for changing the structure of the molecular composition of liquid hydrocarbon fuel under the influence of an electric field as follows.
  • Fuel through the inlet 2 of the inlet pipe 7 is fed into the processing chamber 4 and is divided into two streams: the first between the housing 1 and the inner electrode 5, the second between the inner electrode 5 and the additional electrode 6.
  • the molecules of heavy hydrocarbons the carbon skeleton of which consists of 18 or more carbon atoms
  • the carbon skeleton of which consists of 5 ⁇ 10 carbon atoms are split into lighter molecules, the carbon skeleton of which consists of 5 ⁇ 10 carbon atoms.
  • the resulting light molecules are mainly alkanes, which have a higher calorific value than heavy molecules, and are oxidized by combustion to CO 2 and H 2 O.
  • Restructured fuel leaves the treatment chamber 4 through the outlet 3 of the outlet pipe 8.
  • the presence of insulating inserts 9 allow you to bring an alternating electric potential to the inner electrode 5, center the inner electrode 5 along the longitudinal axis of the processing chamber 4 and set the required distance between the housing 1 and the inner electrode m 5.
  • the introduction of an additional electrode 6 allows to reduce the electric field strength and reduce the power supply capacity.
  • the technical results of the claimed invention are confirmed by chemical research data, mass spectrometry and ICE indicator charts, during which a decrease in the content of heavy aromatic hydrocarbons in the processed fuel and an increase in the content of light alkanes are recorded.
  • the concentration of decane (Ci 0 H 22 ) increased by 3.5 times
  • the concentration of xylene (C 8 H] 0 ) increased by 8 times
  • the concentration of heavy aromatic (Ci 8 H 20 and Ci 8 H 22 ) decreased to zero.
  • the heat of combustion of the fuel increased by at least 10%.
  • the indicator diagrams of ICEs operating on processed fuel show a decrease in the time of combustion of the fuel mixture in the engine cylinders and an increase in the heat of combustion of the fuel.
  • thermotechnical measurements on boiler units an increase in the calorific value of fuel, an increase in the efficiency of boiler units and a decrease in the toxicity of exhaust gases.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne des techniques de fabrication de combustible liquides de meilleure qualité à base d'hydrocarbures. Le procédé pour modifier la composition moléculaire d'un carburant à base d'hydrocarbures en utilisant un champ électrique consiste à faire circuler du carburant entre les électrodes auxquelles on a appliqué un potentiel électrique. Les paramètres d'un champ électrique variable et de la masse de combustible dans la zone de transformation sont établis selon l'équation empirique f / E = σ / M, dans laquelle « f » est la fréquence d'oscillation du champ électrique, « E » est l'intensité du champ électrique, « σ » est la conductivité électrique du combustible, et « M » est la masse moléculaire des hydrocarbures fissiles dans le combustible traité. Le dispositif de mise en œuvre de ce procédé comprend un boîtier (1) avec une ouverture d'entrée (2), une ouverture de sortie (3) et des électrodes pour appliquer un champ électrique à un jet de combustible dans une chambre de traitement (4). Le boîtier constitue l'une des électrodes, et l'électrode interne (5) est placée dans la chambre de traitement (4) et est coaxiale avec le boîtier (1). L'alimentation des électrodes s'effectue par un générateur de tension variable. L'électrode interne (5) est creuse à l'intérieur et accueille une électrode supplémentaire (6) disposée coaxialement celle-ci et reliée électriquement au boîtier (1). La longueur de l'électrode interne (5) correspond à l'équation empirique L = σxE/2πxfxM. L'invention permet d'améliorer la structure chimique du combustible et d'augmenter son pouvoir calorifique lors de la combustion de celui-ci.
PCT/RU2010/000365 2009-05-06 2010-06-29 Procédé pour modifier la composition moléculaire d'un carburant à base d'hydrocarbures sous l'effet d'un champ électrique et dispositif pour mettre en oeuvre ce procédé WO2010131997A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE212010000074U DE212010000074U1 (de) 2009-05-06 2010-06-29 Einrichtung zur Veränderung der Struktur der molekularenZusammensetzung eines flüssigen Kohlenwasserstofftreibstoffs

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2009114360 2009-05-06
RU2009114360 2009-05-06

Publications (2)

Publication Number Publication Date
WO2010131997A2 true WO2010131997A2 (fr) 2010-11-18
WO2010131997A3 WO2010131997A3 (fr) 2010-12-23

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PCT/RU2010/000365 WO2010131997A2 (fr) 2009-05-06 2010-06-29 Procédé pour modifier la composition moléculaire d'un carburant à base d'hydrocarbures sous l'effet d'un champ électrique et dispositif pour mettre en oeuvre ce procédé

Country Status (2)

Country Link
DE (1) DE212010000074U1 (fr)
WO (1) WO2010131997A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018053607A1 (fr) * 2016-09-21 2018-03-29 Ecomoto Engineering Llc Activateur électronique de combustible

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104619978A (zh) * 2012-09-12 2015-05-13 K·库勒吉扬 用于结构化并极化燃料、燃烧混合物或水的设备
EP2902611A1 (fr) * 2014-01-29 2015-08-05 Castiel srl Dispositif pour la transmission de courants électriques dans des circuits hydrauliques, particulièrement adapté à la polarisation et/ou la reconfiguration spatiale des molécules

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2038506C1 (ru) * 1992-07-27 1995-06-27 Федотов Александр Демьянович Способ обработки топлива
RU2078241C1 (ru) * 1992-10-26 1997-04-27 Челябинский государственный технический университет Ионизатор топлива
RU2156879C1 (ru) * 1999-10-07 2000-09-27 Лыженков Василий Николаевич Устройство для обработки топлива

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2032107C1 (ru) 1991-01-11 1995-03-27 Роберт Врамшабович Дарбинян Способ электрической обработки жидкого топлива и активатор для жидкого топлива
JPH0814121A (ja) * 1994-06-27 1996-01-16 Inaba Eiko 燃焼機関の燃費向上装置

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2038506C1 (ru) * 1992-07-27 1995-06-27 Федотов Александр Демьянович Способ обработки топлива
RU2078241C1 (ru) * 1992-10-26 1997-04-27 Челябинский государственный технический университет Ионизатор топлива
RU2156879C1 (ru) * 1999-10-07 2000-09-27 Лыженков Василий Николаевич Устройство для обработки топлива

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018053607A1 (fr) * 2016-09-21 2018-03-29 Ecomoto Engineering Llc Activateur électronique de combustible

Also Published As

Publication number Publication date
DE212010000074U1 (de) 2012-03-06
WO2010131997A3 (fr) 2010-12-23

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