WO2010131943A1 - Procédé pour faire fonctionner un moteur - Google Patents
Procédé pour faire fonctionner un moteur Download PDFInfo
- Publication number
- WO2010131943A1 WO2010131943A1 PCT/MY2010/000076 MY2010000076W WO2010131943A1 WO 2010131943 A1 WO2010131943 A1 WO 2010131943A1 MY 2010000076 W MY2010000076 W MY 2010000076W WO 2010131943 A1 WO2010131943 A1 WO 2010131943A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- engine
- water
- fuel
- carbon dioxide
- oxygen
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
- F02B43/10—Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
- F02B43/08—Plants characterised by the engines using gaseous fuel generated in the plant from solid fuel, e.g. wood
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
- F02B43/10—Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen
- F02B2043/106—Hydrogen obtained by electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/30—Use of alternative fuels, e.g. biofuels
Definitions
- the present invention relates to a method of operating an engine.
- Coal fired power stations are known whereby coal is burnt to create steam which in turn drives a turbine.
- the turbine drives a generator which produces electricity for distribution to end users.
- coal fired power stations generate significant amounts of pollutants including greenhouse gases such as carbon dioxide. If these exhaust gases are sent into the atmosphere there will be a consequential damage to the environment. Alternatively the exhaust gases may be treated to remove pollutants but such treatment is expensive.
- a method of operating an engine comprising the steps of: a) producing work from the engine by burning a fuel in a gas in the engine, b) using said work to produce electricity, c) using said electricity to electrolyse water into hydrogen and oxygen, d) using said oxygen in said gas.
- a method of operating an engine comprising the steps of producing work from an engine by burning a fuel in an oxygen rich environment in the engine, producing an exhaust gas including carbon dioxide, sequestrating said carbon dioxide.
- a method of operating an engine comprising the steps of producing work from an engine by burning a fuel in an oxygen poor environment in the engine, producing an exhaust gas including carbon monoxide and hydrogen; and harvesting the exhaust gas.
- the figure shows the interaction between various features of the present invention.
- a heat engine 10 burns fuel 12/13 in oxygen 14 to produce work 16.
- the work drives a generator 18 which produces electricity, some of which (20) can be used to supply electricity grid for end users, and some of which (22) can be used in an electrolysis plant 24 to generate hydrogen 26 and the above mentioned oxygen 14.
- electricity some of which (20) can be used to supply electricity grid for end users, and some of which (22) can be used in an electrolysis plant 24 to generate hydrogen 26 and the above mentioned oxygen 14.
- an additional synergistic effect is that the exhaust gas from the heat engine is relatively pure carbon dioxide 28.
- the electrolysis 24 also generates hydrogen 26 and the hydrogen 26 can therefore be combined with the carbon dioxide 28 in a reactor 30 to produce methanol 32.
- the carbon dioxide by-product from the heat engine is combined with the hydrogen byproduct from the electrolysis plant to produce a useful fuel, methanol.
- palm oil trees 40 use sunlight 42 from the sun 44 to photosynthesise carbon dioxide 46 from the ambient air 48 into oxygen 50.
- the palm oil fruit 52 can be harvested and processed in a palm oil mill 54 to produce triglyceride fuel 12.
- the biomass 56 from the palm oil trees together with the biomass 58 from the palm oil mill can together be processed in a pyrolysis oil plant 60 to produce either an oil or a gas pyrolysis fuel 13.
- the fuel 12 and/or fuel 13 are burnt in the heat engine 10 in an oxygen rich atmosphere.
- the oxygen rich atmosphere will primarily comprise oxygen 14 from the electrolysis plant 24, though under certain circumstances additional oxygen 62 may be required from a secondary oxygen generator 64. Additional oxygen 62 may be needed from oxygen generator 64 during start up and at a time when either thermal energy from sun is not available (e.g. at night) or is not enough (e.g. on a cloudy day) to sufficiently heat the water in the heat collector 74 (see below). During start up, when there may not be enough electricity available to generate oxygen through electrolysis, additional oxygen 62 can be made available from oxygen generator 64.
- the usage ratio between fuel 12 and fuel 13 changes from time to time according to season and weather resulting in changes in the carbon dioxide and water combustion by-product ratio.
- the 2:1 production ratio between hydrogen (2H) and oxygen (O) from the electrolysis of water (H 2 O) is fixed, there is a need for additional oxygen from the oxygen generator to optimally balance all the chemical reactions involved.
- the heat engine 10 produces work 16 which drives a kinetic to electric converter, in this case a generator 18.
- a generator 18 Some of the electricity 20 supplied by the generator 18 is provided to a grid for use by an end user.
- Other of the electricity 22 is fed to the electrolysis plant 24 which generates oxygen 14 which is used to create the above mentioned oxygen rich atmosphere for burning the fuel 12 and 13 in the heat engine 10.
- the oxygen rich atmosphere used to burn fuel 12 and 13 is relatively pure oxygen, in this example 99% by volume of oxygen.
- the exhaust gas will include carbon dioxide 28 and water 66 typically in the form of steam.
- the provision of an exhaust gas containing only carbon dioxide 28 and water 66, without nitrogen oxides, removes the need for a catalytic converter to be present. In the systems of the invention it is preferred that no catalytic converter be fitted.
- Both the carbon dioxide 28 and the water 66 will be at an elevated temperature and therefore the exhaust gas includes heat 68.
- the heat 68 which is carried by both carbon dioxide 28 and water 66 assists reaction occurring at the reactor 30.
- the reactor 30 is any form of reactor to produce methanol from carbon dioxide and hydrogen 26 including any known type of reactor, such as catalytic hydrogenation of carbon dioxide with hydrogen. It is assumed that if gas compression is needed to increase the pressure in the reactor for the process to happen, the gas compressor is assumed to be part of the reactor. It is preferable that the reactor 30 is placed as close as possible to the heat engine 10 in order to retain the heat.
- the reactor 30 can be integrated to the exhaust port itself. For instance, the reactor 30 could be placed at the point in the exhaust system where a catalytic converter would be found in conventional engines.
- the reactor 30 can be placed at the entrance of the exhaust system. This is to ensure that heat losses are minimized.
- Water within the reservoir can be fed to a heat collector (or heat exchanger) 74 to heat the water from external heat sources such as heat 76 from the sun or heat 78 from the heat engine.
- the heated water 80 can be fed to the electrolysis plant. This is advantageous since electrolysis becomes more efficient using heated water. Some of the heated water will be electrolysed into oxygen 14 and hydrogen 28, whereas the remainder of the heated water can be passed as heated water 82 to be injected into the heat engine as described above.
- the fuel 12 and 13 are derived from palm oil trees.
- the fuel could be any type of fuel including mineral derived fuels or other types of plant derived fuels.
- plant derived fuels such as fuel derived from palm oil trees can be used since this is a sustainable fuel.
- the fuel could be a fluid fuel e.g. a gas or a liquid.
- the fuel may have long chain carbon molecules, for example molecules having eight or more carbon atoms. The carbon atoms within the molecules may be in a straight chain, or alternatively the carbon atoms may be branched.
- the heat engine bums the fuel in an oxygen rich atmosphere.
- Air contains approximately 21% by volume of oxygen and the term oxygen rich atmosphere means that the atmosphere includes more than 21% by volume of oxygen.
- One method of producing oxygen is to remove the nitrogen from air. Such a process will produce a gas with 95% by volume of oxygen.
- the oxygen rich atmosphere used to burn the fuel in the heat engine may comprise 95% or more by volume of oxygen, alternatively it may comprise 90% or more by volume of oxygen, alternatively it may comprise 80% or more by volume of oxygen.
- the oxygen rich environment is substantially nitrogen free. Under these circumstances the exhaust gases will not include any NO x gases.
- the exhaust gases from a heat engine will comprise substantially only carbon dioxide and water, for example there will be substantially no NO x gases.
- gas with a relatively low percentage of carbon dioxide is considered a waste product which requires expensive carbon dioxide scrubbers to remove the carbon dioxide therefrom, a gas comprising substantially only carbon dioxide and water is commercially valuable because it is relatively cheap to remove the water and hence produce a gas which substantially only contains carbon dioxide.
- Carbon dioxide in a pure form is commercially useful for producing methanol.
- the exhaust gas exiting the engine may comprise at least 80% by volume of carbon dioxide and water, preferably it may comprise at least 90% by volume of carbon dioxide and water, more preferably it may comprise at least 95% by volume of carbon dioxide and water, more preferably it may comprise at least 99% by volume of carbon dioxide and water.
- the gas may comprise at least 90% by volume of carbon dioxide, more preferably it may comprise at least 95% by volume of carbon dioxide, more preferably it may comprise at least 99% by volume of carbon dioxide.
- water is injected into the heat engine and turns to steam because of the combustion temperature of the fuel.
- the water can typically be injected at a relatively high pressure, for example 150 to 200 bar.
- the boiling point of the water at this pressure is significantly above boiling point of water at atmospheric pressure (approximately 100 0 C) and therefore the water can be heated to above 100 °C without vaporising. Injecting pressurised water which has been heated to just below its boiling point at that pressure means that less of the combustion energy is required to convert the water to steam.
- excess heat 78 from the heat engine can be fed to the heat collector 74 to heat the heated water 80 which improves the efficiency of the electrolysis plant, and excess heated water 82 can be fed to the heat engine itself which in turn improves the efficiency of the heat engine.
- an external heat source such as the sun can be used to provide heat 76.
- any form of external heat source could be used, for example geothermal energy could be used.
- the heat engine 10 produces an exhaust gas which comprises substantially only carbon dioxide and water. Because it is easy to condense the water out of the exhaust gas to leave a relatively pure carbon dioxide gas, this carbon dioxide gas can be sequestrated, i.e. it does not have to be returned to the atmosphere. Sequestration can be by any known type, for example it can be used for enhanced oil recovery (EOR) by injecting the gas into an oil bearing stratum under high pressure and that pressure will push the oil or gas or both (oil and gas) into the oil pipe and up to the surface. Alternatively the carbon dioxide could be sequestrated by using it as part of an enhanced coal bed methane recovery system.
- EOR enhanced oil recovery
- the carbon dioxide could be sequestrated by using it as part of an enhanced coal bed methane recovery system.
- the high purity carbon dioxide gas can also be directed to an enclosed volume with plants.
- the carbon dioxide is then photosynthesized into oxygen.
- An enclosed volume having plants that can easily be used for biofuel production is preferred.
- the heat engine 10 can be operated in an oxygen poor atmosphere, so that the burning of the fuel 12 and 13 will result in an exhaust gas containing carbon monoxide and hydrogen (syngas - not illustrated).
- syngas is produced from an internal or external combustion engine
- the generation of work 167 from the heat engine 10 may be regarded as a by-product of the syngas production process.
- the many uses for this work 167 would be well known to the person skilled in the art and include the generation of electricity 20, or direct conversion to kinetic energy 18 for the movement of mechanical devices.
- the oxygen 14 will be supplied primarily from the electrolysis plant 24, the secondary oxygen generator 64 will generally either be absent or inactive, although as described above, during start up or at times when the thermal energy from the sun 44 is either not available or insufficient, the secondary oxygen generator 64 may be used.
- heat 68 will be produced.
- the heat 68 can be of use where the syngas is processed further, for instance to form methanol 32 or other fuels, by providing the energy necessary for further reaction to occur.
- reactors 30 such as that described above will typically be used.
- the harvested syngas, a fuel may be stored or further oxidized. Further, the carbon monoxide and hydrogen forming the syngas may be separated using known techniques for future use in different applications.
- the heat engine 10 burns the fuel 12, 13 in an oxygen poor environment.
- oxygen poor means that only 50-70% of the oxygen 14, 62 required to completely oxidize the fuel 12, 13 is supplied to the combustion chamber, the precise amounts of oxygen 14, 62 will depend upon the fuel 12, 13 ratio selected, hi other words, the heat engine 10 is run at about 40% richer (in the range 30 - 60% richer, often 40 - 50% richer) than stoichiometric in order to produce the carbon monoxide and hydrogen.
- the heat released from the initial fuel oxidation breaks down the hydrocarbon chain from the injected foel into mostly carbon monoxide and hydrogen with low levels of carbon dioxide and hydrocarbons.
- the production of carbon dioxide can be expected in the early stages of the foel oxidation process, a small amount of soot can be expected as a result of the partial oxidation of long chain hydrocarbons within the foel after oxygen 14, 62 depletion.
- the exhaust gas exiting the engine may comprise at least 80% by volume of carbon monoxide and hydrogen, preferably it may comprise at least 90% by volume of carbon monoxide and hydrogen, more preferably it may comprise at least 95% by volume of carbon monoxide and hydrogen, more preferably it may comprise at least 99% by volume of carbon monoxide and hydrogen.
- purification to remove water 66 will be required, and this can be achieved using simple condensation techniques. Other known purification methods may also be used.
- carbon dioxide 28 may be removed using the methods described above, for instance sequestration; or by reaction with amine solvents or hydroxides (such as sodium hydroxide). However, if the syngas is to be converted to methanol 32, carbon dioxide 28 will generally not be removed.
- the oxygen-to-fuel ratio can be tuned to alter the final mixture of products in the exhaust gas, in particular, to control the levels of carbon dioxide, water, low molecular weight hydrocarbons and soot which are present. For instance, where conversion of the syngas to methanol is desired, the presence of low levels of carbon dioxide are acceptable, and may even be preferred to increase the yield of the methanol production process.
- the heat engine may be an internal combustion engine.
- the internal combustion engine may be a reciprocating four stroke engine.
- the internal combustion engine may be a reciprocating two stroke engine.
- the engine may be a spark ignition engine.
- the engine may be a compression ignition engine.
- the engine may be a gas turbine engine, hi embodiments where syngas is produced, the engine will typically be a compression ignition engine.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Output Control And Ontrol Of Special Type Engine (AREA)
Abstract
L'invention porte sur un procédé pour faire fonctionner un moteur, lequel procédé comprend les étapes consistant à : a) produire un travail à partir du moteur par combustion d'un carburant pour obtenir un gaz dans le moteur, b) utiliser ledit travail pour produire de l'électricité, c) utiliser ladite électricité pour électrolyser de l'eau en hydrogène et en oxygène, d) utiliser ledit oxygène dans ledit gaz.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MYPI20091966 | 2009-05-14 | ||
MYPI20091966 | 2009-05-14 |
Publications (1)
Publication Number | Publication Date |
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WO2010131943A1 true WO2010131943A1 (fr) | 2010-11-18 |
Family
ID=43085194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/MY2010/000076 WO2010131943A1 (fr) | 2009-05-14 | 2010-05-13 | Procédé pour faire fonctionner un moteur |
Country Status (1)
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WO (1) | WO2010131943A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2016761A (nl) * | 2016-05-12 | 2017-11-15 | Tieluk B V | Gasmenger, warmwaterinstallatie en werkwijze voor het produceren van een gasmengsel |
RU179378U1 (ru) * | 2017-04-19 | 2018-05-11 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный архитектурно-строительный университет" | Силовая установка с двигателем внутреннего сгорания |
US10465631B2 (en) | 2017-01-07 | 2019-11-05 | General Electric Company | System for generating an improved H2:CO ratio in syngas and an associated method thereof |
Citations (13)
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FR2255482A1 (en) * | 1973-12-24 | 1975-07-18 | Kempf Rene | Fuel economiser for IC engine - has system injecting water vapour in air-fuel mixture |
DE3419783A1 (de) * | 1983-11-11 | 1985-05-23 | Edgar 5441 Mertloch Morgenweg | Wasserstoffaggregat fuer kraftfahrzeuge und verbrennungsmotoren |
DE4129330A1 (de) * | 1991-07-12 | 1993-01-14 | Campobasso Andreas P | Verfahren fuer wasserstoffaufbereitung in fahrzeugen unter nutzung der abwaerme eines verbrennungsmotors |
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CN1353240A (zh) * | 2000-12-14 | 2002-06-12 | 范军飞 | 循环使用氢气、氧气和水作为燃料的内燃机制造方法及其内燃机 |
CN1366131A (zh) * | 2001-01-18 | 2002-08-28 | 蔡绍森 | 将水电解产生的氢气和氧气送入发动机作为燃料的方法及其相应的发电方法 |
CN1388308A (zh) * | 2002-04-09 | 2003-01-01 | 姜伟 | 内燃机废气发电及制氢的方法与装置 |
US20070001462A1 (en) * | 2003-04-15 | 2007-01-04 | H-Empower Corp. | Integrated renewable energy system |
US7401578B2 (en) * | 2004-05-21 | 2008-07-22 | Gemini Energy Technologies, Inc. | System and method for the co-generation of fuel having a closed-loop energy cycle |
WO2009051788A2 (fr) * | 2007-10-15 | 2009-04-23 | Transphorm, Inc. | Appareil électrique compact produisant des injections d'hydrogène pour améliorer le fonctionnement des moteurs à combustion interne |
-
2010
- 2010-05-13 WO PCT/MY2010/000076 patent/WO2010131943A1/fr active Application Filing
Patent Citations (13)
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FR2255482A1 (en) * | 1973-12-24 | 1975-07-18 | Kempf Rene | Fuel economiser for IC engine - has system injecting water vapour in air-fuel mixture |
DE3419783A1 (de) * | 1983-11-11 | 1985-05-23 | Edgar 5441 Mertloch Morgenweg | Wasserstoffaggregat fuer kraftfahrzeuge und verbrennungsmotoren |
DE4129330A1 (de) * | 1991-07-12 | 1993-01-14 | Campobasso Andreas P | Verfahren fuer wasserstoffaufbereitung in fahrzeugen unter nutzung der abwaerme eines verbrennungsmotors |
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JPH11315727A (ja) * | 1998-05-01 | 1999-11-16 | Ishikawajima Harima Heavy Ind Co Ltd | 炭酸ガス除去用のガス化複合発電設備 |
US6148602A (en) * | 1998-08-12 | 2000-11-21 | Norther Research & Engineering Corporation | Solid-fueled power generation system with carbon dioxide sequestration and method therefor |
CN1310291A (zh) * | 2000-02-24 | 2001-08-29 | 范军飞 | 循环使用氢气和氧气、水作为燃料的内燃机的制造方法 |
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CN1366131A (zh) * | 2001-01-18 | 2002-08-28 | 蔡绍森 | 将水电解产生的氢气和氧气送入发动机作为燃料的方法及其相应的发电方法 |
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US20070001462A1 (en) * | 2003-04-15 | 2007-01-04 | H-Empower Corp. | Integrated renewable energy system |
US7401578B2 (en) * | 2004-05-21 | 2008-07-22 | Gemini Energy Technologies, Inc. | System and method for the co-generation of fuel having a closed-loop energy cycle |
WO2009051788A2 (fr) * | 2007-10-15 | 2009-04-23 | Transphorm, Inc. | Appareil électrique compact produisant des injections d'hydrogène pour améliorer le fonctionnement des moteurs à combustion interne |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2016761A (nl) * | 2016-05-12 | 2017-11-15 | Tieluk B V | Gasmenger, warmwaterinstallatie en werkwijze voor het produceren van een gasmengsel |
WO2017196174A1 (fr) * | 2016-05-12 | 2017-11-16 | Tieluk B.V. | Mélangeur de gaz, installation d'eau chaude et procédé de production de mélange gazeux |
US10465631B2 (en) | 2017-01-07 | 2019-11-05 | General Electric Company | System for generating an improved H2:CO ratio in syngas and an associated method thereof |
RU179378U1 (ru) * | 2017-04-19 | 2018-05-11 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный архитектурно-строительный университет" | Силовая установка с двигателем внутреннего сгорания |
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