WO2010127671A2 - Procédé de stockage de gaz techniques et réservoir de gaz techniques - Google Patents

Procédé de stockage de gaz techniques et réservoir de gaz techniques Download PDF

Info

Publication number
WO2010127671A2
WO2010127671A2 PCT/DE2010/000537 DE2010000537W WO2010127671A2 WO 2010127671 A2 WO2010127671 A2 WO 2010127671A2 DE 2010000537 W DE2010000537 W DE 2010000537W WO 2010127671 A2 WO2010127671 A2 WO 2010127671A2
Authority
WO
WIPO (PCT)
Prior art keywords
storage
gas
pressure
container
bar
Prior art date
Application number
PCT/DE2010/000537
Other languages
German (de)
English (en)
Other versions
WO2010127671A4 (fr
WO2010127671A3 (fr
Inventor
Gunter Kaiser
Jürgen Klier
Original Assignee
Institut Für Luft- Und Kältetechnik Gemeinnützige Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102010010108A external-priority patent/DE102010010108B4/de
Application filed by Institut Für Luft- Und Kältetechnik Gemeinnützige Gmbh filed Critical Institut Für Luft- Und Kältetechnik Gemeinnützige Gmbh
Priority to EP10726881A priority Critical patent/EP2427687A2/fr
Publication of WO2010127671A2 publication Critical patent/WO2010127671A2/fr
Publication of WO2010127671A3 publication Critical patent/WO2010127671A3/fr
Publication of WO2010127671A4 publication Critical patent/WO2010127671A4/fr

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00—Vessels not under pressure
    • F17C3/02—Vessels not under pressure with provision for thermal insulation
    • F17C3/08—Vessels not under pressure with provision for thermal insulation by vacuum spaces, e.g. Dewar flask
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0021—Carbon, e.g. active carbon, carbon nanotubes, fullerenes; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0026—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C3/00—Vessels not under pressure
    • F17C3/02—Vessels not under pressure with provision for thermal insulation
    • F17C3/04—Vessels not under pressure with provision for thermal insulation by insulating layers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C7/00—Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01—Shape
    • F17C2201/0104—Shape cylindrical
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01—Shape
    • F17C2201/0138—Shape tubular
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01—Shape
    • F17C2201/0147—Shape complex
    • F17C2201/0166—Shape complex divided in several chambers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01—Shape
    • F17C2201/0147—Shape complex
    • F17C2201/0171—Shape complex comprising a communication hole between chambers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05—Size
    • F17C2201/054—Size medium (>1 m3)
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05—Size
    • F17C2201/056—Small (<1 m3)
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0304—Thermal insulations by solid means
    • F17C2203/0308—Radiation shield
    • F17C2203/0312—Radiation shield cooled by external means
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/03—Thermal insulations
    • F17C2203/0391—Thermal insulations by vacuum
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602—Wall structures; Special features thereof
    • F17C2203/0612—Wall structures
    • F17C2203/0626—Multiple walls
    • F17C2203/0629—Two walls
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602—Wall structures; Special features thereof
    • F17C2203/0612—Wall structures
    • F17C2203/0626—Multiple walls
    • F17C2203/0631—Three or more walls
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/01—Mounting arrangements
    • F17C2205/0123—Mounting arrangements characterised by number of vessels
    • F17C2205/013—Two or more vessels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/01—Mounting arrangements
    • F17C2205/0123—Mounting arrangements characterised by number of vessels
    • F17C2205/013—Two or more vessels
    • F17C2205/0134—Two or more vessels characterised by the presence of fluid connection between vessels
    • F17C2205/0142—Two or more vessels characterised by the presence of fluid connection between vessels bundled in parallel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/01—Mounting arrangements
    • F17C2205/0123—Mounting arrangements characterised by number of vessels
    • F17C2205/013—Two or more vessels
    • F17C2205/0149—Vessel mounted inside another one
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00—Handled fluid, in particular type of fluid
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00—Handled fluid, in particular type of fluid
    • F17C2221/01—Pure fluids
    • F17C2221/012—Hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00—Handled fluid, in particular type of fluid
    • F17C2221/03—Mixtures
    • F17C2221/032—Hydrocarbons
    • F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0107—Single phase
    • F17C2223/0115—Single phase dense or supercritical, i.e. at high pressure and high density
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/036—Very high pressure (>80 bar)
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/01—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the phase
    • F17C2225/0107—Single phase
    • F17C2225/0115—Single phase dense or supercritical, i.e. at high pressure and high density
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/01—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the phase
    • F17C2225/0107—Single phase
    • F17C2225/0123—Single phase gaseous, e.g. CNG, GNC
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/01—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the phase
    • F17C2225/0146—Two-phase
    • F17C2225/0153—Liquefied gas, e.g. LPG, GPL
    • F17C2225/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/03—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the pressure level
    • F17C2225/033—Small pressure, e.g. for liquefied gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/03—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the pressure level
    • F17C2225/035—High pressure, i.e. between 10 and 80 bars
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03—Heat exchange with the fluid
    • F17C2227/0337—Heat exchange with the fluid by cooling
    • F17C2227/0339—Heat exchange with the fluid by cooling using the same fluid
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03—Heat exchange with the fluid
    • F17C2227/0337—Heat exchange with the fluid by cooling
    • F17C2227/0341—Heat exchange with the fluid by cooling using another fluid
    • F17C2227/0353—Heat exchange with the fluid by cooling using another fluid using cryocooler
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03—Heat exchange with the fluid
    • F17C2227/0337—Heat exchange with the fluid by cooling
    • F17C2227/0358—Heat exchange with the fluid by cooling by expansion
    • F17C2227/036—"Joule-Thompson" effect
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03—Heat exchange with the fluid
    • F17C2227/0367—Localisation of heat exchange
    • F17C2227/0369—Localisation of heat exchange in or on a vessel
    • F17C2227/0376—Localisation of heat exchange in or on a vessel in wall contact
    • F17C2227/0379—Localisation of heat exchange in or on a vessel in wall contact inside the vessel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03—Heat exchange with the fluid
    • F17C2227/0367—Localisation of heat exchange
    • F17C2227/0369—Localisation of heat exchange in or on a vessel
    • F17C2227/0376—Localisation of heat exchange in or on a vessel in wall contact
    • F17C2227/0381—Localisation of heat exchange in or on a vessel in wall contact integrated in the wall
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
    • F17C2227/03—Heat exchange with the fluid
    • F17C2227/0367—Localisation of heat exchange
    • F17C2227/0369—Localisation of heat exchange in or on a vessel
    • F17C2227/0376—Localisation of heat exchange in or on a vessel in wall contact
    • F17C2227/0383—Localisation of heat exchange in or on a vessel in wall contact outside the vessel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00—Purposes of gas storage and gas handling
    • F17C2260/02—Improving properties related to fluid or fluid transfer
    • F17C2260/021—Avoiding over pressurising
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00—Purposes of gas storage and gas handling
    • F17C2260/02—Improving properties related to fluid or fluid transfer
    • F17C2260/027—Making transfer independent of vessel orientation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00—Purposes of gas storage and gas handling
    • F17C2260/04—Reducing risks and environmental impact
    • F17C2260/046—Enhancing energy recovery
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2265/00—Effects achieved by gas storage or gas handling
    • F17C2265/06—Fluid distribution
    • F17C2265/065—Fluid distribution for refueling vehicle fuel tanks
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2265/00—Effects achieved by gas storage or gas handling
    • F17C2265/06—Fluid distribution
    • F17C2265/066—Fluid distribution for feeding engines for propulsion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/01—Applications for fluid transport or storage
    • F17C2270/0134—Applications for fluid transport or storage placed above the ground
    • F17C2270/0139—Fuel stations
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/01—Applications for fluid transport or storage
    • F17C2270/0165—Applications for fluid transport or storage on the road
    • F17C2270/0168—Applications for fluid transport or storage on the road by vehicles
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/01—Applications for fluid transport or storage
    • F17C2270/0165—Applications for fluid transport or storage on the road
    • F17C2270/0168—Applications for fluid transport or storage on the road by vehicles
    • F17C2270/0178—Cars
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/01—Applications for fluid transport or storage
    • F17C2270/0165—Applications for fluid transport or storage on the road
    • F17C2270/0184—Fuel cells
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/05—Applications for industrial use
    • F17C2270/0509—"Dewar" vessels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/05—Applications for industrial use
    • F17C2270/0581—Power plants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

Definitions

  • the invention relates to a process for the storage of industrial gases, which makes it possible to increase the density of stored under pressure technical gases without pressure increase significantly.
  • the store is suitable for the storage and transport of industrial gases in general, for the storage of technical fuel gases, such as. Hydrogen or natural gas, at service stations and for use as a fuel-gas vehicle tank.
  • natural gas has been used as fuel for automobiles for many years, and accordingly there is also a well-developed network of filling stations.
  • the natural gas is typically kept ready at a pressure of 200 bar; at this pressure, it has a density of about 155 kg / m 3 or a calorific value of about 6.25 MJ / I.
  • the energy density of compressed natural gas (200 bar) compared to other fossil fuels, such as gasoline with an energy density of 32 MJ / I or diesel fuel with an energy density of 36 MJ / I or regenerative fuels, such as bio-diesel with 32 MJ / I or bioethanol at 21 MJ / I, very low.
  • Liquefied Natural Gas has only about 1 / 600th of the volume of gaseous natural gas, very high storage densities can be achieved with the storage of LNG.
  • the natural gas must be cooled to about 110 K for liquefaction;
  • energy is required for its phase transformation from gaseous to. liquid.
  • the LNG due to the comparatively low storage temperature
  • the LNG must be constantly cooled with high refrigeration capacities in order to avoid vaporization of the LNG.
  • DE 25 36 993 C2 and US Pat. No. 6,672,077 B1 propose storing hydrogen at temperatures far below the ambient temperature in absorbent or nanostructured material.
  • EP 1 130 06 A1 and WO 00/01980 solutions are shown, in which hydrogen is also stored at low temperatures, but in addition by means of an adjuvant in the storing material quasi "encapsulated" is.
  • DE 103 92 240 T5 a solution is presented in which hydrogen is stored under increased pressure in an absorbent material.
  • WO 97/26082 A1 and WO 01/13032 A1 show hydrogen storage devices which have a special layer or film structure
  • US 2004/0250552 A1 proposes the use of a liquid storage material.
  • DE 10 2005 023 036 A1 shows a method for hydrogen storage in which hydrogen is stored in gaseous, cooled and compressed form under high pressure on a physically adsorbing material, in particular carbon powder.
  • the invention has for its object to find a method for storing industrial gases, which makes it possible to increase the density of stored under pressure technical gases, in particular natural gas and hydrogen, without pressure increase and with low energy use significantly.
  • the technical gas is stored in a storage container which, depending on the gas stored therein, has to withstand pressures of up to 1200 bar, above its critical pressure and above the critical temperature, or in the compressible phase range below the critical temperature.
  • the storage above the critical temperature is preferably used when the storage is carried out at pressures which are substantially greater than the critical pressure. At pressures that are only slightly above the critical pressure, the storage is preferably applied in the compressible phase range. Materials which are suitable for adsorption or absorption of the technical gas in appreciable amount, ie in a larger amount than in the case of virtually all materials occurring surface absorption or absorption, are not used.
  • the gas can advantageously be throttled when it is withdrawn from the storage container, the gas remaining in the container being removed by means of the exiting gas, whose temperature drops sharply during the relaxation due to the Joule-Thomson effect, is cooled.
  • the storage of hydrogen takes place at a temperature above 33 K and at a pressure above 13 bar. Again, a storage in the compressible phase range at a temperature below 33 K in the same pressure range is possible.
  • the hydrogen is stored at a temperature of 33 to 100 K and above the critical pressure at 13 to 1200 bar.
  • a hydrogen density of 100 kg / m 3 can be achieved.
  • the storage density at the same pressure drops by only 12%, ie to 88 kg / m 3 .
  • storage densities above that of the liquid hydrogen and about three times the high pressure hydrogen at ambient temperature are achievable.
  • the storage tank for the technical gas consists of a thermally insulated, pressure-tight container with a closable opening for removal and filling.
  • the container is equipped with a refrigerating machine, which is mounted on the container so that it can deliver the cold produced by it to the natural gas in the container, and / or equipped with the throttled relaxing the leaking technical glass relaxation device, which in thermal Contact with the stored in the storage tank technical gas is.
  • the cold part / the cold finger of the chiller must be in thermal contact with the technical gas in the interior of the container.
  • the basic structure of the Speicherbefflel- ter 's thin-walled tubes (0.1 to 30 mm wall thickness) with small inner diameters (0.1 to 100 mm), which are thermally connected to each other and possibly with other structural elements of the memory , Due to the thin walls of the tubes, a good thermal connection of the technical gas stored in the tube bundles to the tubes and structural elements serving as heat storage is achieved.
  • the small inner diameters of the tubes make it possible, despite the comparatively low wall thicknesses, to achieve the required storage pressures of up to 1200 bar.
  • the expansion device which serves to reduce the release of technical gases during removal, consists either of at least one capillary larrohr or it is designed as at least one porous element which covers the at least one outlet opening for the technical gas (eg hydrogen).
  • technical gas eg hydrogen
  • a particularly good heat transfer between the exiting and in the Spei- rather remaining technical gas is achieved with an embodiment in which the basic structure of the storage container consists of thin-walled tube bundles, wherein the capillary tubes are integrated into the thin-walled tube bundles.
  • the storage container may additionally be equipped with at least one latent storage element, for which storage elements based on the Gibbs-Thomson effect are particularly suitable.
  • the memory can be used particularly advantageously in conjunction with natural gas or hydrogen as a motor vehicle tank.
  • the thermal insulation of the storage container is carried out as a multilayer vacuum superinsulation, which is equipped with actively cooled radiant screens.
  • the radiation screens can be thermally connected to the gas outlet, whereby the sensible heat of the escaping technical gas is used to cool the radiation shields.
  • FIG. 1 shows a memory, preferably for supercritical and transcritical natural gas, in a schematic representation
  • Fig. 2 the diagram of the temperature dependence of density and calorific value for natural gas at different pressures
  • 3 shows a memory, preferably for supercritical and transcritical hydrogen, in a schematic representation; 4 shows various embodiments of the expansion device.
  • the storage for natural gas consists of the container 1 and the refrigerating machine 2.
  • the container 1 has a closable by means of a valve 3 opening 4, which serves for filling with and for the removal of natural gas.
  • the container 1 is equipped with an insulation layer 5 designed either as a solid or vacuum insulation, which minimizes the heat transfer from the environment into the supercritical natural gas 6 in the reservoir.
  • the chiller 2 has a cooling capacity which is sufficient to compensate for the thermal losses and is either as a compression refrigeration cascade or as
  • the cold part 7 of the refrigerator 2 communicates with the interior 8 of the container 1 and thus with the supercritical natural gas 6 in thermal contact. It does not matter at which point of the container 1, the chiller 2 is arranged (up or down), since the supercritical natural gas 6 evenly fills the interior space 8 (no liquid phase).
  • the storage of natural gas at a pressure above the critical pressure (46 bar) and a temperature of 190 K results in an increase in the density of the stored supercritical natural gas.
  • the density of natural gas compared to that at ambient temperature (at 200 bar) from 155 kg / m 3 to 330 kg / m 3 , ie increased to 2.13 times become.
  • the volumetric energy density increases in the same ratio from 6.25 MJ / I to 13.3 MJ / I, which saves more than twice as much energy when the tank is used as a vehicle tank with the same tank volume and consequently increases the range of the vehicle.
  • the container 11 of the hydrogen storage (Fig. 3) consists of numerous, parallel arranged storage tubes 12, wherein one side of the tubes 12 with a Collecting device 13 is connected, which connects all tubes 12 with the hydrogen outlet 14.
  • the storage container 11 composed of the tube bundles is surrounded by a multilayer vacuum superinsulation 15, which is surrounded by radiation shields 16 for further improvement of the thermal insulation.
  • the radiation screens 16 are thermally connected to the hydrogen outlet line 14 so that the radiation screens 16 are actively cooled by the sensible heat of the exiting hydrogen.
  • the entire assembly is located in a Dewar vessel 17, which ensures a first thermal insulation against the comparatively high ambient temperature.
  • Fig. 4 are arranged from top to bottom, several embodiments of relaxation devices 18.
  • the capillary tubes 19 are arranged coaxially in the interior of the storage tubes 12. When hydrogen is withdrawn, the hydrogen remaining in the respective storage tube 12 is cooled directly through the capillary tube 19.
  • the cross sections of the storage tubes 12 are chosen so small with an inner diameter of about 1 mm that they simultaneously take over the function of the capillary 19, while in the third variant, the storage tubes 12 are spirally surrounded by the capillary tubes 18.
  • outlet openings of the storage tubes 12 are each covered with porous plugs 20, which serve as an alternative to the capillary tubes 19 for the throttled relaxation of the hydrogen.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

L'invention concerne un procédé de stockage de gaz techniques permettant d'augmenter sensiblement la densité de gaz techniques stockés sous pression sans augmentation de pression. Le réservoir est particulièrement adapté en tant que réservoir de véhicules fonctionnant avec des gaz combustibles tels que par ex. du gaz naturel ou de l'hydrogène. Selon le procédé, le gaz technique est stocké à une température proche de la température critique et à une pression supérieure à la pression critique, jusqu'à maximum 1200 bar. Le réservoir fonctionnant selon le procédé comporte un contenant isolé thermiquement, étanche à la pression (1, 10), pourvu d'une ouverture refermable (4) pour le prélèvement et le remplissage, conçu pour des pressions intérieures jusqu'à maximum 1200 bar. Le gaz technique est refroidi au moyen d'une machine frigorifique (2) et/ou au moyen d'un dispositif de détente (18) servant à la détente étranglée du gaz technique sortant.
PCT/DE2010/000537 2009-05-06 2010-05-05 Procédé de stockage de gaz techniques et réservoir de gaz techniques WO2010127671A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP10726881A EP2427687A2 (fr) 2009-05-06 2010-05-05 Procédé de stockage de gaz techniques et réservoir de gaz techniques

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE102009020138A DE102009020138B3 (de) 2009-05-06 2009-05-06 Verfahren zur Speicherung von Wasserstoff und Speicher für Wasserstoff
DE102009020138.6 2009-05-06
DE102010010108A DE102010010108B4 (de) 2010-02-23 2010-03-04 Verfahren zur Speicherung von und Speicher für Erdgas
DE102010010108.7 2010-03-04

Publications (3)

Publication Number Publication Date
WO2010127671A2 true WO2010127671A2 (fr) 2010-11-11
WO2010127671A3 WO2010127671A3 (fr) 2010-12-29
WO2010127671A4 WO2010127671A4 (fr) 2011-02-17

Family

ID=43028787

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2010/000537 WO2010127671A2 (fr) 2009-05-06 2010-05-05 Procédé de stockage de gaz techniques et réservoir de gaz techniques

Country Status (3)

Country Link
EP (1) EP2427687A2 (fr)
DE (1) DE102009020138B3 (fr)
WO (1) WO2010127671A2 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014127886A1 (fr) * 2013-02-19 2014-08-28 Linde Aktiengesellschaft Stockage de gaz, en particulier de gaz naturel
FR3006742A1 (fr) * 2013-06-05 2014-12-12 Air Liquide Dispositif et procede de remplissage d'un reservoir
FR3041061A1 (fr) * 2015-09-15 2017-03-17 Air Liquide Reservoir de stockage de fluide liquefie
JP2017194166A (ja) * 2013-06-21 2017-10-26 川崎重工業株式会社 液化ガス保持タンクおよび液化ガス運搬船
EP3992519A1 (fr) * 2020-10-29 2022-05-04 Linde Kryotechnik AG Procédé et dispositif de fourniture d'un gaz cryogène tel que l'hydrogène

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010010108B4 (de) * 2010-02-23 2012-01-26 Institut für Luft- und Kältetechnik gGmbH Verfahren zur Speicherung von und Speicher für Erdgas
FR3028305A1 (fr) * 2014-11-10 2016-05-13 Gaztransport Et Technigaz Dispositif et procede de refroidissement d'un gaz liquefie

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2536993A1 (fr) 1975-08-20 1976-12-23
EP0113006A2 (fr) 1982-12-29 1984-07-11 International Business Machines Corporation Butée d'amortissement pour le dispositif d'entraînement du levier d'impression
CA2113774A1 (fr) 1994-01-19 1995-07-20 Harold L. Gier Appareil et methode de chargement, de stockage et de livraison d'un fluide a cryotemperature
US5582016A (en) 1992-05-07 1996-12-10 Aerospace Design & Development, Inc. Conditioning and loading apparatus and method for gas storage at cryogenic temperature and supercritical pressure
WO1997026082A1 (fr) 1995-01-17 1997-07-24 Catalytic Materials Limited Stockage de l'hydrogene dans des nanostructures en couches
US5709203A (en) 1992-05-07 1998-01-20 Aerospace Design And Development, Inc. Self contained, cryogenic mixed gas single phase storage and delivery system and method for body cooling, gas conditioning and utilization
WO2000001980A2 (fr) 1998-07-03 2000-01-13 Toyota Jidosha Kabushiki Kaisha Procede et systeme pour le stockage de gaz, materiau utilise pour enfermer du gaz
US6089226A (en) 1996-11-22 2000-07-18 Aerospace Design & Development, Inc. Self contained, cryogenic mixed gas single phase storage and delivery
CN2389281Y (zh) 1999-10-08 2000-07-26 朱立 天然气等超临界压力深冷液化气体贮运罐装置
WO2001013032A1 (fr) 1999-08-11 2001-02-22 Hennara Investments Limited Stockage de gaz sur un adsorbant muni de lamelles exfoliees
US6672077B1 (en) 2001-12-11 2004-01-06 Nanomix, Inc. Hydrogen storage in nanostructure with physisorption
US20040250552A1 (en) 2003-06-16 2004-12-16 The Regents Of The University Of California Storage of H2 by absorption and/or mixture within a fluid medium
DE10392240T5 (de) 2002-01-31 2005-05-12 Jfe Steel Corp. Hybrid-Wasserstoffvorratsbehälter und Verfahren zur Lagerung von Wasserstoff in solch einem Behälter
DE102005023036A1 (de) 2005-05-13 2006-11-16 Deutsches Zentrum für Luft- und Raumfahrt e.V. Wasserstoffspeicher und Verfahren zur Wasserstoffspeicherung
DE102006056821A1 (de) 2006-12-01 2008-06-05 Institut für Luft- und Kältetechnik gGmbH Thermisches Isolationssystem, insbesondere für LNG-Tankschiffe und Verfahren zu dessen Herstellung

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1245998B (de) * 1963-09-06 1967-08-03 Arthur D. Little, Inc., Cambridge, Mass. (V. St. A.) Einrichtung zum Verflüssigen von Gasen wie Helium
US3422632A (en) * 1966-06-03 1969-01-21 Air Prod & Chem Cryogenic refrigeration system
US5382797A (en) * 1990-12-21 1995-01-17 Santa Barbara Research Center Fast cooldown cryostat for large infrared focal plane arrays
CH683368A5 (de) * 1991-06-26 1994-02-28 Linde Ag Verfahren und Vorrichtung zum Transport und Verteilen von Helium.
IL132035A0 (en) * 1999-09-23 2001-03-19 Israel State Infrared detector
US6581409B2 (en) * 2001-05-04 2003-06-24 Bechtel Bwxt Idaho, Llc Apparatus for the liquefaction of natural gas and methods related to same
DE102004004379A1 (de) * 2004-01-29 2005-08-11 Bayerische Motoren Werke Ag Kryotankanlage, insbesondere für ein Kraftfahrzeug
US7165408B2 (en) * 2004-02-19 2007-01-23 General Motors Corporation Method of operating a cryogenic liquid gas storage tank
US7305836B2 (en) * 2004-05-19 2007-12-11 Eden Innovations Ltd. Cryogenic container and superconductivity magnetic energy storage (SMES) system
DE102006019993B3 (de) * 2006-04-26 2007-12-27 Daimlerchrysler Ag Druckgasspeicher, insbesondere für Wasserstoff
KR20090125265A (ko) * 2007-03-02 2009-12-04 에너씨 트랜스포트 엘엘씨 압축 유체를 저장, 운반 및 취급하기 위한 장치 및 방법
US20090019886A1 (en) * 2007-07-20 2009-01-22 Inspired Technologies, Inc. Method and Apparatus for liquefaction of a Gas
FR2933475B1 (fr) * 2008-07-04 2010-08-27 Snecma Systeme de stockage de liquide cryogenique pour engin spatial
DE102008053463A1 (de) * 2008-10-28 2010-05-12 Linde Aktiengesellschaft Speicherung von komprimierten Medien

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2536993A1 (fr) 1975-08-20 1976-12-23
EP0113006A2 (fr) 1982-12-29 1984-07-11 International Business Machines Corporation Butée d'amortissement pour le dispositif d'entraînement du levier d'impression
US5582016A (en) 1992-05-07 1996-12-10 Aerospace Design & Development, Inc. Conditioning and loading apparatus and method for gas storage at cryogenic temperature and supercritical pressure
US5709203A (en) 1992-05-07 1998-01-20 Aerospace Design And Development, Inc. Self contained, cryogenic mixed gas single phase storage and delivery system and method for body cooling, gas conditioning and utilization
US6513521B1 (en) 1992-05-07 2003-02-04 Aerospace Design & Development, Inc. Cryogenic mixed gas single phase storage and delivery
CA2113774A1 (fr) 1994-01-19 1995-07-20 Harold L. Gier Appareil et methode de chargement, de stockage et de livraison d'un fluide a cryotemperature
EP0670452A1 (fr) 1994-01-19 1995-09-06 AEROSPACE DESIGN &amp; DEVELOPMENT, INC. Dispositif et procédé pour le chargement, le stockage et de distribution de fluides à températures cryogéniques
WO1997026082A1 (fr) 1995-01-17 1997-07-24 Catalytic Materials Limited Stockage de l'hydrogene dans des nanostructures en couches
US6089226A (en) 1996-11-22 2000-07-18 Aerospace Design & Development, Inc. Self contained, cryogenic mixed gas single phase storage and delivery
WO2000001980A2 (fr) 1998-07-03 2000-01-13 Toyota Jidosha Kabushiki Kaisha Procede et systeme pour le stockage de gaz, materiau utilise pour enfermer du gaz
WO2001013032A1 (fr) 1999-08-11 2001-02-22 Hennara Investments Limited Stockage de gaz sur un adsorbant muni de lamelles exfoliees
CN2389281Y (zh) 1999-10-08 2000-07-26 朱立 天然气等超临界压力深冷液化气体贮运罐装置
US6672077B1 (en) 2001-12-11 2004-01-06 Nanomix, Inc. Hydrogen storage in nanostructure with physisorption
DE10392240T5 (de) 2002-01-31 2005-05-12 Jfe Steel Corp. Hybrid-Wasserstoffvorratsbehälter und Verfahren zur Lagerung von Wasserstoff in solch einem Behälter
US20040250552A1 (en) 2003-06-16 2004-12-16 The Regents Of The University Of California Storage of H2 by absorption and/or mixture within a fluid medium
DE102005023036A1 (de) 2005-05-13 2006-11-16 Deutsches Zentrum für Luft- und Raumfahrt e.V. Wasserstoffspeicher und Verfahren zur Wasserstoffspeicherung
DE102006056821A1 (de) 2006-12-01 2008-06-05 Institut für Luft- und Kältetechnik gGmbH Thermisches Isolationssystem, insbesondere für LNG-Tankschiffe und Verfahren zu dessen Herstellung

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014127886A1 (fr) * 2013-02-19 2014-08-28 Linde Aktiengesellschaft Stockage de gaz, en particulier de gaz naturel
FR3006742A1 (fr) * 2013-06-05 2014-12-12 Air Liquide Dispositif et procede de remplissage d'un reservoir
JP2017194166A (ja) * 2013-06-21 2017-10-26 川崎重工業株式会社 液化ガス保持タンクおよび液化ガス運搬船
FR3041061A1 (fr) * 2015-09-15 2017-03-17 Air Liquide Reservoir de stockage de fluide liquefie
WO2017046463A1 (fr) * 2015-09-15 2017-03-23 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Réservoir de stockage de fluide liquéfié
CN108040488A (zh) * 2015-09-15 2018-05-15 乔治洛德方法研究和开发液化空气有限公司 液化流体储存罐
CN108040488B (zh) * 2015-09-15 2020-04-10 乔治洛德方法研究和开发液化空气有限公司 液化流体储存罐
US10781975B2 (en) 2015-09-15 2020-09-22 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Liquefied-fluid storage tank
EP3992519A1 (fr) * 2020-10-29 2022-05-04 Linde Kryotechnik AG Procédé et dispositif de fourniture d'un gaz cryogène tel que l'hydrogène

Also Published As

Publication number Publication date
DE102009020138B3 (de) 2010-12-02
EP2427687A2 (fr) 2012-03-14
WO2010127671A4 (fr) 2011-02-17
WO2010127671A3 (fr) 2010-12-29

Similar Documents

Publication Publication Date Title
WO2010127671A2 (fr) Procédé de stockage de gaz techniques et réservoir de gaz techniques
EP3027955B1 (fr) Réservoir
DE102008003610B4 (de) Gasspeichersystem basierend auf Gasadsorption an Materialien mit hoher Oberfläche
DE102010020476B4 (de) Verwendung einer Vorrichtung zum Speichern, Umfüllen und/oder Transportieren von tiefkalt verflüssigtem brennbarem Gas in einem Fahrzeug
DE102006025656B4 (de) Vorrichtung zur Kraftstoffspeicherung und -förderung von kryogenem Kraftstoff
EP1330620B1 (fr) Reservoir destine a des agents cryogenes
DE102006019993B3 (de) Druckgasspeicher, insbesondere für Wasserstoff
EP2132476A2 (fr) Procédé de remplissage d&#39;un réservoir sous pression prévu pour un fluide à stocker cryogénique, notamment de l&#39;hydrogène
DE102005028199A1 (de) Speicherbehälter für kyrogene Medien
EP1364152B1 (fr) Procede et dispositif de remplissage de reservoirs sous pression a l&#39;aide de gaz ou de melanges de gaz permanents a bas point d&#39;ebullition
WO2006018146A1 (fr) Recipient de stockage pour substances cryogenes
DE102007023821B4 (de) Verfahren zum Befüllen eines kryogenen Wasserstoff vorgesehenen Speicherbehälters insbesondere eines Kraftfahrzeugs
DE102007011742A1 (de) Verfahren zum Befüllen eines für ein tiefkaltes Speichermedium, insbesondere Wasserstoff, vorgesehenen Druckspeichers
DE102005023036B4 (de) Wasserstoffspeicher und Verfahren zur Wasserstoffspeicherung
DE10021681C2 (de) Energiespeichersystem, insbesondere System zum Speichern von Wasserstoff
DE102008060127A1 (de) Anlage zum Betanken von Kraftfahrzeugen mit Wasserstoff
WO2006069681A1 (fr) Dispositif d&#39;alimentation en carburant pour vehicule a moteur a hydrogene
WO2008000103A1 (fr) Installation pouvant être transportée par route pour la liquéfaction et le stockage temporaire de gaz naturel et le ravitaillement de véhicules en gaz naturel
DE102016006121A1 (de) Verfahren und Wärmeaustauscher zur Rückgewinnung von Kälte bei der Regasifizierung tiefkalter Flüssigkeiten
DE19945462A1 (de) Verfahren zum Entnehmen eines gasförmigen und flüssigen kryogenen Mediums aus einem Speicherbehälter und Speicherbehälter
DE102007057979B4 (de) Verfahren zum Befüllen eines Speicherbehälters mit kryogenem Wasserstoff
DE102010010108B4 (de) Verfahren zur Speicherung von und Speicher für Erdgas
DE102008043927A1 (de) Vorrichtung zur Speicherung eines Gases sowie Verfahren zur Entnahme eines Gases aus einem Sorptionsspeicher
DE102015209028A1 (de) Kryogenes Druckbehältersystem
DE102014209919A1 (de) Kryodruckbehälter

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10726881

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2010726881

Country of ref document: EP