WO2010098575A2 - 이산화티탄 복합 분체 및 이를 함유하는 메이크업 화장료 조성물 - Google Patents
이산화티탄 복합 분체 및 이를 함유하는 메이크업 화장료 조성물 Download PDFInfo
- Publication number
- WO2010098575A2 WO2010098575A2 PCT/KR2010/001141 KR2010001141W WO2010098575A2 WO 2010098575 A2 WO2010098575 A2 WO 2010098575A2 KR 2010001141 W KR2010001141 W KR 2010001141W WO 2010098575 A2 WO2010098575 A2 WO 2010098575A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- titanium dioxide
- dioxide composite
- composite powder
- composition containing
- same
- Prior art date
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/893—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by an alkoxy or aryloxy group, e.g. behenoxy dimethicone or stearoxy dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/61—Surface treated
- A61K2800/62—Coated
- A61K2800/624—Coated by macromolecular compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
Definitions
- the present invention relates to a titanium dioxide composite powder and a makeup composition containing the same, and more particularly, to a composite of silicon elastomer in titanium dioxide and then coated with polymethylsilsesquioxane to form a smooth, smooth formulation without clumping.
- the present invention relates to a titanium dioxide composite powder prepared to have applicability, and a base makeup composition containing the same.
- Powders commonly used in cosmetics have their own characteristics and have different functions depending on the characteristics.
- inorganic pigment powder undergoes compounding, surface modification, etc. in accordance with the characteristics used in cosmetics, and improves the disadvantages of each in this way.
- the compounding technique is commonly used as a method of changing the overall characteristics of the powder to meet the desired purpose.
- powders can be classified into colored pigments, white pigments, extender pigments and functional pigments according to their role.
- Colored pigments serve to adjust the color tone of products, such as bengara, iron sulfate, black iron oxide, chromium oxide and carbon black.
- white pigments can control the hiding power in addition to the color tone, titanium dioxide and zinc oxide belong to this.
- the extender pigment is used as a diluent to adjust the color tone, adjust the usability (extension, adhesion), gloss, etc. of the product, and is also used to maintain the formulation of the product. These include talc, mica, sericite, boron nitride, and the like.
- Titanium dioxide (TiO 2 ) in white pigments is commonly used to express clean and bright skin by covering irregularities, wrinkles, and the like.
- disadvantages of titanium dioxide (TiO 2 ) include stiffness, agglomeration, unnaturalness, and the like, a method of improving the above disadvantages through compounding and surface modification is widely used.
- the disadvantages of titanium dioxide are solved through complexing techniques using sieving pigments such as Talc, Mica, sericite, and boron nitride. It is being used to change to have a new characteristic, but the disadvantages such as agglomeration due to the stiffness and unstretched properties remain.
- the present inventors have studied to improve the rough feeling and agglomeration which are disadvantages while maintaining the high hiding power of titanium dioxide.
- a composite of silicon elastomer in titanium dioxide and coating with polymethylsilsesquioxane was prepared.
- the present invention has been completed by discovering the use of a titanium dioxide composite powder to produce a base makeup composition having natural coverage and smooth spreadability.
- the present invention provides a composite powder in which a silicon elastomer is composited with titanium dioxide and coated with polymethylsilsesquioxane (PMSQ).
- PMSQ polymethylsilsesquioxane
- Titanium dioxide (TiO 2 ) used in the present invention is preferably an average particle size of 0.1 ⁇ 10 ⁇ m. The smaller the particle size, the higher the coverage. On the other hand, when the particle size is larger than 10 ⁇ m, the coverage is inferior and the powdery cosmetics are not suitable for use as a cosmetic.
- Silicone elastomer used in the present invention is characterized in that the dimethicone / vinyl dimethicone crosspolymer (Dimethicone / vinyl dimethicone crosspolymer).
- the silicone elastomer is contained in an amount of 30.0 to 50.0% by weight based on the total weight of the composited titanium dioxide.
- the content of the silicone elastomer to be compounded exceeds 50% by weight, the coverage of the titanium dioxide is deteriorated, and when less than 30% by weight, a rough feeling of titanium dioxide appears and a problem of not being uniformly applied.
- a silicone-based resin used in the present invention refers to a resin that T- Si-O bonds are present three as indicated by the formula (1), typically attached to the Si-CH 3 Called organo polysiloxane, it has an OH reactor capable of chemically coating titanium dioxide surfaces and silicone elastomers (dimethicone / vinyl dimethicone crosspolymer), and serves to impart water and oil resistance.
- the polymethylsilsesquioxane is used to coat the composite powder of titanium dioxide and silicone elastomer in an amount of 2 to 5% by weight based on the total weight of the titanium dioxide composite powder. If the coating content is less than 2% by weight, there is a problem that the skin adhesion characteristics are lowered, and when the coating content is greater than 5% by weight, a problem of uneven application occurs.
- Step 1 Drying titanium dioxide.
- Titanium dioxide to be coated is dried in a 105 ° C. dryer for at least 4 hours.
- the titanium dioxide dried in the first step is introduced into the Henschel mixer, and the silicon elastomer is mixed at high speed to complex titanium dioxide.
- the titanium dioxide powder and the silicon elastomer in the composite titanium dioxide powder are 5 to 5 to 7 to 3 in weight ratio. In the case of more than 5 to 5, the usability is smooth but the hiding power is remarkably lowered. In the case of less than 7 to 3, the silver penetrating force is excellent but the ratio of the roughness of titanium dioxide is exhibited.
- polymethylsilsesquioxane 2-5 wt% of polymethylsilsesquioxane is sprayed with respect to the total weight of the powder complexed in step 2, and then mixed and dispersed for 15 to 600 seconds, preferably for 30 to 300 seconds.
- step 4 heat treatment.
- step 3 After dispersing as in step 3 and dried at 120 ⁇ 150 °C for more than 4 hours to finish the polymerization coating process.
- Makeup cosmetic composition according to the present invention contains the titanium dioxide composite powder prepared by the above method in an amount of 0.1 to 10.0% by weight based on the total weight of the composition. If less than 0.1% by weight of the powder exhibiting a smooth and uniform coating and coverage does not appear, if more than 10% by weight affects the stability of the formulation has a problem of poor stability.
- the makeup composition containing the titanium dioxide composite powder can be applied smoothly without clumping when the formulation is used, and it is not only expressed naturally but also excellent in hiding effect of skin blemishes.
- composition may be formulated in the form of a makeup primer, foundation, makeup base, two-way cake, fact, powder, eye shadow and the like.
- the present invention also provides a makeup cosmetic composition containing the titanium dioxide composite powder.
- Titanium dioxide composite powder according to the present invention by complexing a silicone elastomer in titanium dioxide and coating it with polymethylsilsesquioxane, the base makeup composition using the same is applied smoothly without agglomeration, it can provide a natural skin texture and concealment effect have.
- titanium dioxide was dried at 105 ° C. for at least 4 hours, and then placed in a Henschel mixer, and 30 g of silicone elastomer (Dimethicone / vinyl dimethicone crosspolymer) was mixed. Thereafter, 2.1 g of PMSQ was sprayed and mixed, followed by heat treatment at 120 to 150 ° C. for 4 hours to obtain 100.3 g of composite titanium dioxide.
- titanium dioxide was used US Sun Chemical (C47-056)
- silicon elastomer was used Dow Corning, DC 9506C
- PMSQ is GE.
- PMSQ prepared by polymerizing with TOSHIBA's methyltriethoxysilane was used.
- Titanium dioxide was dried by Ishihara Co., Ltd., Japan's CR50 100g at 105 ° C. for 4 hours or more, and then mixed in a Henschel mixer by spraying 2.1 g of triethoxycaprylic silane. After mixing, heat treatment was performed at 120 to 150 ° C. for 4 hours to obtain 102.1 g of titanium dioxide coated with alkyl silane.
- Table 1 Ingredient Name Formulation Example 1 (% by weight) Comparative Formulation Example 1 (wt%) Talc 44.7 44.7 Serisite 20.0 20.0 Silica 10.0 10.0 Micro Titanium Dioxide 8.0 8.0 Zinc oxide 3.0 3.0 Titanium Dioxide Composite Powder of Example 1 5.0 Titanium Dioxide Coating Powder of Comparative Example 1 - 5.0 Iron oxide 2.0 2.0 Mineral oil 7.0 7.0 antiseptic 0.3 0.3
- Formulation Example 1 and Comparative Formulation Example 1 prepared as described above were applied to the wrist region according to the cosmetic method, and the wrinkles on the surface of the skin were measured using a Primos hand held device of German GFM, an image analyzer. The skin texture correction effect was evaluated.
- the puffs were applied to the wrists of two women in their twenties and two in their thirties. Two puffs were applied in the longitudinal direction and measured. .
- Example 1 The powders prepared in Example 1 and Comparative Example 1 were each applied 0.015 g on the artificial leather, and the rheometer was placed on the artificial leather to which the powder was applied to evaluate the smoothness. The results are shown in Table 3 below.
- Comparative Example 1 exhibits a value of 140 or more that is rough, the feeling of use of the cosmetic containing powder of Comparative Example 1 may not be good, but in the case of Example 1 is usually smooth Numerical value of 110 or less is shown, and it can be confirmed that the cosmetics using the titanium dioxide composite powder according to the present invention can exhibit smooth applicability.
- Formulation Example 1 and Comparative Formulation Example 1 were evaluated by applying directly to the face of 20 female consumer panel tests in their 20s and 30s. Each of Formulation Example 1 and Comparative Formulation Example 1 was applied to the skin to evaluate the actual sensory before and after the application and compared, and the results are shown in Table 4 below.
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
성분명 | 제형예 1 (중량%) | 비교제형예 1 (중량%) |
탈크 | 44.7 | 44.7 |
세리사이트 | 20.0 | 20.0 |
실리카 | 10.0 | 10.0 |
마이크로이산화티탄 | 8.0 | 8.0 |
산화아연 | 3.0 | 3.0 |
실시예 1의 이산화티탄 복합 분체 | 5.0 | |
비교예 1의 이산화티탄 코팅 분체 | - | 5.0 |
산화철 | 2.0 | 2.0 |
미네랄 오일 | 7.0 | 7.0 |
방부제 | 0.3 | 0.3 |
제형예 1 | 비교제형예 1 | |
피부결 보정 | 37% | 20% |
매끄러움 | |
실시예1 | 104 |
비교예1 | 150 |
은폐력 | 매끄러움 | 두께감 | 펴발림성 | |
제형예 1 | ○ (우수) | ◎ (매우 우수) | ◎(얇음) | ◎(매우 우수) |
비교제형예 1 | ◎(매우 우수) | △(약간) | △(두꺼움) | △ (약간) |
Claims (8)
- 이산화티탄 분체에 실리콘 엘라스토머를 복합화하고, 폴리메틸실세스퀴옥산으로 코팅한 이산화티탄 복합 분체.
- 제 1항에 있어서, 상기 이산화티탄은 평균 입자 사이즈가 0.1~10㎛임을 특징으로 하는 이산화티탄 복합 분체.
- 제 1항에 있어서, 상기 실리콘 엘라스토머는 디메치콘/비닐디메치콘 크로스 폴리머임을 특징으로 하는 이산화티탄 복합 분체.
- 제 1항에 있어서, 상기 이산화티탄에 복합화된 실리콘 엘라스토머의 함량은 이산화티탄 복합 분체 전체 중량에 대하여 30.0~50.0중량%임을 특징으로 하는 이산화티탄 복합 분체.
- 제 1항에 있어서, 상기 폴리메틸실세스퀴옥산은 이산화티탄 복합 분체 전체 중량에 대하여 2~5중량%의 양으로 이산화티탄 분체를 코팅함을 특징으로 하는 이산화티탄 복합 분체.
- 제 1항 내지 제 5항 중 어느 한 항에 의한 이산화티탄 복합 분체의 메이크업 화장료로서의 용도.
- 제 1항 내지 제 5항 중 어느 한 항에 의한 이산화티탄 복합 분체를 함유하는 메이크업 화장료 조성물.
- 제 7항에 있어서, 상기 조성물은 이산화티탄 복합 분체를 조성물 총 중량에 대하여0.1~10.0중량%의 양으로 함유함을 특징으로 하는 메이크업 화장료 조성물.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010800091320A CN102333514B (zh) | 2009-02-24 | 2010-02-24 | 二氧化钛复合粉末及含有该复合粉末的化妆品组合物 |
Applications Claiming Priority (2)
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KR10-2009-0015342 | 2009-02-24 | ||
KR1020090015342A KR101081199B1 (ko) | 2009-02-24 | 2009-02-24 | 이산화티탄 복합 분체 및 이를 함유하는 메이크업 화장료 조성물 |
Publications (2)
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WO2010098575A2 true WO2010098575A2 (ko) | 2010-09-02 |
WO2010098575A3 WO2010098575A3 (ko) | 2011-01-06 |
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PCT/KR2010/001141 WO2010098575A2 (ko) | 2009-02-24 | 2010-02-24 | 이산화티탄 복합 분체 및 이를 함유하는 메이크업 화장료 조성물 |
Country Status (3)
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KR (1) | KR101081199B1 (ko) |
CN (1) | CN102333514B (ko) |
WO (1) | WO2010098575A2 (ko) |
Families Citing this family (3)
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KR101290339B1 (ko) * | 2010-12-30 | 2013-08-07 | 주식회사 안느 | 식물성 버터가 코팅된 엘라스토머 비드 복합분체를 포함한 화장료 조성물 |
CN106619194B (zh) * | 2016-12-27 | 2019-11-19 | 广州市科能化妆品科研有限公司 | 包含复合固体粉末和高分子成膜剂的防晒化妆品组合物 |
CN110934776B (zh) * | 2019-12-17 | 2022-09-13 | 中南林业科技大学 | 聚三氟丙基甲基硅氧烷包覆的二氧化钛复合材料及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004082644A1 (ja) * | 2003-03-19 | 2004-09-30 | Kanebo Cosmetics Inc. | 化粧料 |
KR20070006088A (ko) * | 2005-07-07 | 2007-01-11 | 주식회사 엘지생활건강 | 표면 탄성을 지닌 프레스 타입의 색조 화장료 |
JP2007246521A (ja) * | 2006-02-20 | 2007-09-27 | Shiseido Co Ltd | 油中水型乳化日焼け止め化粧料 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US6524598B2 (en) * | 2000-07-10 | 2003-02-25 | The Procter & Gamble Company | Cosmetic compositions |
KR101212905B1 (ko) * | 2005-11-11 | 2012-12-14 | (주)아모레퍼시픽 | 간섭색 안료를 함유하는 메이크업 화장료 조성물 및 그의제조방법 |
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2009
- 2009-02-24 KR KR1020090015342A patent/KR101081199B1/ko active IP Right Grant
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2010
- 2010-02-24 CN CN2010800091320A patent/CN102333514B/zh active Active
- 2010-02-24 WO PCT/KR2010/001141 patent/WO2010098575A2/ko active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004082644A1 (ja) * | 2003-03-19 | 2004-09-30 | Kanebo Cosmetics Inc. | 化粧料 |
KR20070006088A (ko) * | 2005-07-07 | 2007-01-11 | 주식회사 엘지생활건강 | 표면 탄성을 지닌 프레스 타입의 색조 화장료 |
JP2007246521A (ja) * | 2006-02-20 | 2007-09-27 | Shiseido Co Ltd | 油中水型乳化日焼け止め化粧料 |
Also Published As
Publication number | Publication date |
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KR20100096454A (ko) | 2010-09-02 |
CN102333514B (zh) | 2013-04-17 |
KR101081199B1 (ko) | 2011-11-07 |
WO2010098575A3 (ko) | 2011-01-06 |
CN102333514A (zh) | 2012-01-25 |
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