WO2010044253A1 - Composition de résine thermoplastique pour le nettoyage d'une machine à mouler - Google Patents

Composition de résine thermoplastique pour le nettoyage d'une machine à mouler Download PDF

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Publication number
WO2010044253A1
WO2010044253A1 PCT/JP2009/005333 JP2009005333W WO2010044253A1 WO 2010044253 A1 WO2010044253 A1 WO 2010044253A1 JP 2009005333 W JP2009005333 W JP 2009005333W WO 2010044253 A1 WO2010044253 A1 WO 2010044253A1
Authority
WO
WIPO (PCT)
Prior art keywords
resin composition
thermoplastic resin
surfactant
mass
surfactants
Prior art date
Application number
PCT/JP2009/005333
Other languages
English (en)
Japanese (ja)
Inventor
脇田直樹
Original Assignee
ダイセルポリマー株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ダイセルポリマー株式会社 filed Critical ダイセルポリマー株式会社
Priority to CN2009801383516A priority Critical patent/CN102171286A/zh
Publication of WO2010044253A1 publication Critical patent/WO2010044253A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof

Definitions

  • the present invention relates to a cleaning resin composition used for cleaning the inside of a molding machine such as an extruder or an injection molding machine.
  • a combination of a base resin and a surfactant is known as a cleaning agent for a thermoplastic resin molding machine.
  • a cleaning agent for a thermoplastic resin molding machine A combination of a base resin and a surfactant is known as a cleaning agent for a thermoplastic resin molding machine.
  • an AS resin blended with sodium dodecylbenzene sulfonate or sodium ⁇ -olefin sulfonate is described. Summary of the Invention
  • This invention makes it a subject to provide the thermoplastic resin composition used as a washing
  • the invention of the present application is one or more selected from aliphatic surfactants and aromatic surfactants with respect to 100 parts by mass of AS resin having an acrylonitrile content of 28% by mass or less as means for solving the problems.
  • a thermoplastic resin composition for washing a molding machine, comprising 0.5 to 10 parts by mass of the surfactant is provided. Moreover, this invention provides the molding processor washing
  • thermoplastic resin composition for cleaning a molding machine of the present invention has high cleaning performance by combining a specific base resin with an aliphatic surfactant, an aromatic surfactant or a mixture thereof. . Detailed Description of the Invention
  • the AS resin used in the present invention has an acrylonitrile content of 28% by mass or less, preferably an acrylonitrile content of 20 to 28% by mass, more preferably an acrylonitrile content of 23 to 27% by mass. is there.
  • the content of acrylonitrile is an analytical value obtained by the measurement method described in Examples.
  • the surfactant used in the present invention is one or more surfactants selected from aliphatic surfactants and aromatic surfactants, and preferably one or more aliphatic surfactants and aromatic surfactants. It is a mixture of one or more surfactants.
  • alkane sulfonic acid sodium salt and ⁇ -olefin sulfonic acid sodium salt are preferable, and as the aromatic surfactant, alkylbenzene sulfonic acid sodium salt is preferable.
  • alkane, ⁇ -olefin and alkylbenzene in alkanesulfonic acid sodium salt, ⁇ -olefinsulfonic acid sodium salt and alkylbenzenesulfonic acid sodium salt preferably has 8 to 20 carbon atoms.
  • the metal species to be a salt is at least one selected from alkali metals or alkaline earth metals.
  • the content of the surfactant or surfactant mixture in the composition of the present invention is preferably 0.5 to 10 parts by mass, more preferably 0.5 to 6 parts by mass with respect to 100 parts by mass of the AS resin. To 6 is more preferable, and 1 to 3 parts by mass is still more preferable.
  • the blending ratio is from 1/10 to the blending ratio (aliphatic surfactant / aromatic surfactant).
  • the range of 10/1 is preferable, the range of 1/6 to 6/1 is more preferable, and the range of 1/3 to 3/1 is still more preferable.
  • the composition of the present invention may further contain a known inorganic filler such as glass fiber or rock wool.
  • the content of the inorganic filler is preferably 0.5 to 150 parts by weight, more preferably 20 to 140 parts by weight, and still more preferably 40 to 120 parts by weight with respect to 100 parts by weight of the AS resin.
  • composition of the present invention can contain various known additives within a range that can solve the problems of the present invention.
  • Known additives include, for example, polyhydric alcohols and metal soaps in addition to the alkylene glycol fatty acid esters described in paragraphs 12 and 13 of the above-mentioned JP-A-2000-119464, and phosphorus compounds described in JP-A-2002-1734. Acid ester compounds can be used.
  • composition of the present invention applies a method in which each component is premixed with a mixer such as a Henschel mixer, tumbler blender, kneader, etc., and then melt kneaded with an extruder, or melt kneaded with a heating roll or a Banbury mixer. Can be obtained.
  • a mixer such as a Henschel mixer, tumbler blender, kneader, etc.
  • AS-1 AS resin (AN amount 24.3% by mass)
  • AS-2 AS resin (AN amount 27.0% by mass)
  • AS-3 AS resin (Cebian N 080 AN amount 29.5% by mass, manufactured by Daicel Polymer Ltd.)
  • Surfactant 1 Sodium dodecylbenzenesulfonate
  • Surfactant 2 Sodium ⁇ -olefin sulfonate GF; Glass fiber (“ECS03T351 / P” manufactured by Nippon Electric Glass Co., Ltd. (fiber diameter 13 ⁇ m, fiber length 3.2 mm) Surface treated with an aminosilane-based silane coupling agent and focused with an acrylic resin-based sizing agent).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention porte sur une composition de résine thermoplastique pour le nettoyage de machines à mouler, qui présente une excellente performance de nettoyage. La composition de résine thermoplastique pour le nettoyage de machines à mouler contient 0,5 à 10 parties en masse d'un ou plusieurs tensioactifs qui sont choisis parmi les tensioactifs aliphatiques et les tensioactifs aromatiques pour 100 parties en masse d'une résine d'AS qui a une teneur en acrylonitrile inférieure ou égale à 28 % en masse.
PCT/JP2009/005333 2008-10-16 2009-10-14 Composition de résine thermoplastique pour le nettoyage d'une machine à mouler WO2010044253A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2009801383516A CN102171286A (zh) 2008-10-16 2009-10-14 用于清洗成型加工机的热塑性树脂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2008-267454 2008-10-16
JP2008267454A JP5550226B2 (ja) 2008-10-16 2008-10-16 成形加工機洗浄用の熱可塑性樹脂組成物

Publications (1)

Publication Number Publication Date
WO2010044253A1 true WO2010044253A1 (fr) 2010-04-22

Family

ID=42106424

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2009/005333 WO2010044253A1 (fr) 2008-10-16 2009-10-14 Composition de résine thermoplastique pour le nettoyage d'une machine à mouler

Country Status (4)

Country Link
JP (1) JP5550226B2 (fr)
KR (1) KR101619426B1 (fr)
CN (1) CN102171286A (fr)
WO (1) WO2010044253A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3685980A4 (fr) * 2017-09-19 2020-10-14 Masanori Fujita Agent nettoyant pour le nettoyage d'une machine à mouler et procédé de nettoyage

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5552036B2 (ja) * 2010-12-07 2014-07-16 ダイセルポリマー株式会社 成形加工機洗浄用の熱可塑性樹脂組成物
JP5839564B2 (ja) 2012-01-27 2016-01-06 ダイセルポリマー株式会社 成形加工機洗浄用の熱可塑性樹脂組成物
JP5792647B2 (ja) 2012-01-27 2015-10-14 ダイセルポリマー株式会社 成形加工機洗浄用の熱可塑性樹脂組成物
CN105924931B (zh) * 2016-05-04 2018-10-09 重庆理工大学 一种塑料螺杆清洗剂及生产和使用方法
CN106366476B (zh) * 2016-08-26 2019-04-05 江苏金发科技新材料有限公司 有色塑料加工设备用清洗剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000119464A (ja) * 1998-10-15 2000-04-25 Daicel Chem Ind Ltd 洗浄用樹脂組成物
JP2002001734A (ja) * 2000-06-23 2002-01-08 Daicel Chem Ind Ltd 洗浄用樹脂組成物
JP2006257297A (ja) * 2005-03-17 2006-09-28 Daicel Polymer Ltd 洗浄用樹脂組成物
WO2008102891A1 (fr) * 2007-02-22 2008-08-28 Daicel Polymer Ltd. Composition de résine pour le nettoyage

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001105489A (ja) * 1999-10-06 2001-04-17 Daicel Chem Ind Ltd スチレン系樹脂シートおよびその製造方法
JP2007077183A (ja) * 2005-09-12 2007-03-29 Daicel Polymer Ltd 成形機用の洗浄剤樹脂組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000119464A (ja) * 1998-10-15 2000-04-25 Daicel Chem Ind Ltd 洗浄用樹脂組成物
JP2002001734A (ja) * 2000-06-23 2002-01-08 Daicel Chem Ind Ltd 洗浄用樹脂組成物
JP2006257297A (ja) * 2005-03-17 2006-09-28 Daicel Polymer Ltd 洗浄用樹脂組成物
WO2008102891A1 (fr) * 2007-02-22 2008-08-28 Daicel Polymer Ltd. Composition de résine pour le nettoyage

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3685980A4 (fr) * 2017-09-19 2020-10-14 Masanori Fujita Agent nettoyant pour le nettoyage d'une machine à mouler et procédé de nettoyage
US11524428B2 (en) 2017-09-19 2022-12-13 Masanori Fujita Cleaning agent for molding-machine cleaning and cleaning method

Also Published As

Publication number Publication date
KR101619426B1 (ko) 2016-05-10
KR20110091644A (ko) 2011-08-12
JP5550226B2 (ja) 2014-07-16
JP2010095624A (ja) 2010-04-30
CN102171286A (zh) 2011-08-31

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