WO2010044253A1 - Thermoplastic resin composition for cleaning molding machine - Google Patents
Thermoplastic resin composition for cleaning molding machine Download PDFInfo
- Publication number
- WO2010044253A1 WO2010044253A1 PCT/JP2009/005333 JP2009005333W WO2010044253A1 WO 2010044253 A1 WO2010044253 A1 WO 2010044253A1 JP 2009005333 W JP2009005333 W JP 2009005333W WO 2010044253 A1 WO2010044253 A1 WO 2010044253A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- resin composition
- thermoplastic resin
- surfactant
- mass
- surfactants
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
Definitions
- the present invention relates to a cleaning resin composition used for cleaning the inside of a molding machine such as an extruder or an injection molding machine.
- a combination of a base resin and a surfactant is known as a cleaning agent for a thermoplastic resin molding machine.
- a cleaning agent for a thermoplastic resin molding machine A combination of a base resin and a surfactant is known as a cleaning agent for a thermoplastic resin molding machine.
- an AS resin blended with sodium dodecylbenzene sulfonate or sodium ⁇ -olefin sulfonate is described. Summary of the Invention
- This invention makes it a subject to provide the thermoplastic resin composition used as a washing
- the invention of the present application is one or more selected from aliphatic surfactants and aromatic surfactants with respect to 100 parts by mass of AS resin having an acrylonitrile content of 28% by mass or less as means for solving the problems.
- a thermoplastic resin composition for washing a molding machine, comprising 0.5 to 10 parts by mass of the surfactant is provided. Moreover, this invention provides the molding processor washing
- thermoplastic resin composition for cleaning a molding machine of the present invention has high cleaning performance by combining a specific base resin with an aliphatic surfactant, an aromatic surfactant or a mixture thereof. . Detailed Description of the Invention
- the AS resin used in the present invention has an acrylonitrile content of 28% by mass or less, preferably an acrylonitrile content of 20 to 28% by mass, more preferably an acrylonitrile content of 23 to 27% by mass. is there.
- the content of acrylonitrile is an analytical value obtained by the measurement method described in Examples.
- the surfactant used in the present invention is one or more surfactants selected from aliphatic surfactants and aromatic surfactants, and preferably one or more aliphatic surfactants and aromatic surfactants. It is a mixture of one or more surfactants.
- alkane sulfonic acid sodium salt and ⁇ -olefin sulfonic acid sodium salt are preferable, and as the aromatic surfactant, alkylbenzene sulfonic acid sodium salt is preferable.
- alkane, ⁇ -olefin and alkylbenzene in alkanesulfonic acid sodium salt, ⁇ -olefinsulfonic acid sodium salt and alkylbenzenesulfonic acid sodium salt preferably has 8 to 20 carbon atoms.
- the metal species to be a salt is at least one selected from alkali metals or alkaline earth metals.
- the content of the surfactant or surfactant mixture in the composition of the present invention is preferably 0.5 to 10 parts by mass, more preferably 0.5 to 6 parts by mass with respect to 100 parts by mass of the AS resin. To 6 is more preferable, and 1 to 3 parts by mass is still more preferable.
- the blending ratio is from 1/10 to the blending ratio (aliphatic surfactant / aromatic surfactant).
- the range of 10/1 is preferable, the range of 1/6 to 6/1 is more preferable, and the range of 1/3 to 3/1 is still more preferable.
- the composition of the present invention may further contain a known inorganic filler such as glass fiber or rock wool.
- the content of the inorganic filler is preferably 0.5 to 150 parts by weight, more preferably 20 to 140 parts by weight, and still more preferably 40 to 120 parts by weight with respect to 100 parts by weight of the AS resin.
- composition of the present invention can contain various known additives within a range that can solve the problems of the present invention.
- Known additives include, for example, polyhydric alcohols and metal soaps in addition to the alkylene glycol fatty acid esters described in paragraphs 12 and 13 of the above-mentioned JP-A-2000-119464, and phosphorus compounds described in JP-A-2002-1734. Acid ester compounds can be used.
- composition of the present invention applies a method in which each component is premixed with a mixer such as a Henschel mixer, tumbler blender, kneader, etc., and then melt kneaded with an extruder, or melt kneaded with a heating roll or a Banbury mixer. Can be obtained.
- a mixer such as a Henschel mixer, tumbler blender, kneader, etc.
- AS-1 AS resin (AN amount 24.3% by mass)
- AS-2 AS resin (AN amount 27.0% by mass)
- AS-3 AS resin (Cebian N 080 AN amount 29.5% by mass, manufactured by Daicel Polymer Ltd.)
- Surfactant 1 Sodium dodecylbenzenesulfonate
- Surfactant 2 Sodium ⁇ -olefin sulfonate GF; Glass fiber (“ECS03T351 / P” manufactured by Nippon Electric Glass Co., Ltd. (fiber diameter 13 ⁇ m, fiber length 3.2 mm) Surface treated with an aminosilane-based silane coupling agent and focused with an acrylic resin-based sizing agent).
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
Abstract
A thermoplastic resin composition for cleaning molding machines, which has an excellent cleaning performance. The thermoplastic resin composition for cleaning molding machines contains 0.5-10 parts by mass of one or more surfactants which are selected from aliphatic surfactants and aromatic surfactants per 100 parts by mass of an AS resin which has an acrylonitrile content of not more than 28% by mass.
Description
本発明は、押出機、射出成形機器等の成形加工機用の内部を洗浄するために用いる洗浄用樹脂組成物に関する。
背景技術 The present invention relates to a cleaning resin composition used for cleaning the inside of a molding machine such as an extruder or an injection molding machine.
Background art
背景技術 The present invention relates to a cleaning resin composition used for cleaning the inside of a molding machine such as an extruder or an injection molding machine.
Background art
熱可塑性樹脂の成形加工機用の洗浄剤として、ベース樹脂と界面活性剤を組み合わせたものが知られている。特開２０００－１１９４６４号公報の実施例では、ＡＳ樹脂に対して、ドデシルベンゼンスルホン酸ナトリウム又はα－オレフィンスルホン酸ナトリウムを配合したものが記載されている。
発明の概要 A combination of a base resin and a surfactant is known as a cleaning agent for a thermoplastic resin molding machine. In the examples of Japanese Patent Application Laid-Open No. 2000-119464, an AS resin blended with sodium dodecylbenzene sulfonate or sodium α-olefin sulfonate is described.
Summary of the Invention
発明の概要 A combination of a base resin and a surfactant is known as a cleaning agent for a thermoplastic resin molding machine. In the examples of Japanese Patent Application Laid-Open No. 2000-119464, an AS resin blended with sodium dodecylbenzene sulfonate or sodium α-olefin sulfonate is described.
Summary of the Invention
本願発明は、より洗浄力が向上された、熱可塑性樹脂の成形加工機用の洗浄剤として使用する熱可塑性樹脂組成物を提供することを課題とする。
This invention makes it a subject to provide the thermoplastic resin composition used as a washing | cleaning agent for the molding processing machine of a thermoplastic resin with which the detergency was improved more.
本願発明は、課題の解決手段として、アクリロニトリルの含有量が２８質量％以下であるＡＳ樹脂１００質量部に対して、脂肪族系界面活性剤と芳香族系界面活性剤から選ばれる１又は２以上の界面活性剤０．５～１０質量部を含有している、成形加工機洗浄用の熱可塑性樹脂組成物を提供する。
また、本発明は、上記組成物の成形加工機洗浄用途を提供する。 The invention of the present application is one or more selected from aliphatic surfactants and aromatic surfactants with respect to 100 parts by mass of AS resin having an acrylonitrile content of 28% by mass or less as means for solving the problems. A thermoplastic resin composition for washing a molding machine, comprising 0.5 to 10 parts by mass of the surfactant is provided.
Moreover, this invention provides the molding processor washing | cleaning use of the said composition.
また、本発明は、上記組成物の成形加工機洗浄用途を提供する。 The invention of the present application is one or more selected from aliphatic surfactants and aromatic surfactants with respect to 100 parts by mass of AS resin having an acrylonitrile content of 28% by mass or less as means for solving the problems. A thermoplastic resin composition for washing a molding machine, comprising 0.5 to 10 parts by mass of the surfactant is provided.
Moreover, this invention provides the molding processor washing | cleaning use of the said composition.
本発明の成形加工機洗浄用の熱可塑性樹脂組成物は、特定のベース樹脂と脂肪族系界面活性剤や芳香族系界面活性剤又はそれらの混合物の組み合わせにより、高い洗浄性能を有している。
発明の詳細な説明 The thermoplastic resin composition for cleaning a molding machine of the present invention has high cleaning performance by combining a specific base resin with an aliphatic surfactant, an aromatic surfactant or a mixture thereof. .
Detailed Description of the Invention
発明の詳細な説明 The thermoplastic resin composition for cleaning a molding machine of the present invention has high cleaning performance by combining a specific base resin with an aliphatic surfactant, an aromatic surfactant or a mixture thereof. .
Detailed Description of the Invention
＜ＡＳ樹脂＞
本発明で用いるＡＳ樹脂は、アクリロニトリルの含有量が２８質量％以下のものであり、好ましくはアクリロニトリルの含有量が２０～２８質量％であり、より好ましくはアクリロニトリル含有量が２３～２７質量％である。前記アクリロニトリルの含有量は、実施例に記載の測定法による分析値である。 <AS resin>
The AS resin used in the present invention has an acrylonitrile content of 28% by mass or less, preferably an acrylonitrile content of 20 to 28% by mass, more preferably an acrylonitrile content of 23 to 27% by mass. is there. The content of acrylonitrile is an analytical value obtained by the measurement method described in Examples.
本発明で用いるＡＳ樹脂は、アクリロニトリルの含有量が２８質量％以下のものであり、好ましくはアクリロニトリルの含有量が２０～２８質量％であり、より好ましくはアクリロニトリル含有量が２３～２７質量％である。前記アクリロニトリルの含有量は、実施例に記載の測定法による分析値である。 <AS resin>
The AS resin used in the present invention has an acrylonitrile content of 28% by mass or less, preferably an acrylonitrile content of 20 to 28% by mass, more preferably an acrylonitrile content of 23 to 27% by mass. is there. The content of acrylonitrile is an analytical value obtained by the measurement method described in Examples.
＜界面活性剤＞
本発明で用いる界面活性剤は、脂肪族系界面活性剤と芳香族系界面活性剤から選ばれる１又は２以上の界面活性剤であり、好ましくは脂肪族系界面活性剤の１以上と芳香族系界面活性剤１以上の混合物である。 <Surfactant>
The surfactant used in the present invention is one or more surfactants selected from aliphatic surfactants and aromatic surfactants, and preferably one or more aliphatic surfactants and aromatic surfactants. It is a mixture of one or more surfactants.
本発明で用いる界面活性剤は、脂肪族系界面活性剤と芳香族系界面活性剤から選ばれる１又は２以上の界面活性剤であり、好ましくは脂肪族系界面活性剤の１以上と芳香族系界面活性剤１以上の混合物である。 <Surfactant>
The surfactant used in the present invention is one or more surfactants selected from aliphatic surfactants and aromatic surfactants, and preferably one or more aliphatic surfactants and aromatic surfactants. It is a mixture of one or more surfactants.
脂肪族系界面活性剤としては、アルカンスルホン酸ナトリウム塩、α-オレフィンスルホン酸ナトリウム塩が好ましく、芳香族系界面活性剤としてはアルキルベンゼンスルホン酸ナトリウム塩が好ましい。アルカンスルホン酸ナトリウム塩、α-オレフィンスルホン酸ナトリウム塩、アルキルベンゼンスルホン酸ナトリウム塩中のアルカン、αーオレフィン及びアルキルベンゼンそれぞれは、炭素数８～２０が好ましい。塩となる金属種は、アルカリ金属またはアルカリ土類金属から選ばれる１種以上である。
As the aliphatic surfactant, alkane sulfonic acid sodium salt and α-olefin sulfonic acid sodium salt are preferable, and as the aromatic surfactant, alkylbenzene sulfonic acid sodium salt is preferable. Each of alkane, α-olefin and alkylbenzene in alkanesulfonic acid sodium salt, α-olefinsulfonic acid sodium salt and alkylbenzenesulfonic acid sodium salt preferably has 8 to 20 carbon atoms. The metal species to be a salt is at least one selected from alkali metals or alkaline earth metals.
本発明の組成物中の界面活性剤又は界面活性剤混合物の含有量は、ＡＳ樹脂１００質量部に対して０．５～１０質量部が好ましく、０．５～６質量部がより好ましく、３～６がより好ましく、１～３質量部が更に好ましい。
The content of the surfactant or surfactant mixture in the composition of the present invention is preferably 0.5 to 10 parts by mass, more preferably 0.5 to 6 parts by mass with respect to 100 parts by mass of the AS resin. To 6 is more preferable, and 1 to 3 parts by mass is still more preferable.
脂肪族系界面活性剤と芳香族系界面活性剤の混合物を用いるときの配合比（質量比）は、前記配合比（脂肪族系界面活性剤／芳香族系界面活性剤）は１／１０～１０／１の範囲が好ましく、１／６～６／１の範囲がより好ましく、１／３～３／１の範囲が更に好ましい。
When using a mixture of an aliphatic surfactant and an aromatic surfactant, the blending ratio (mass ratio) is from 1/10 to the blending ratio (aliphatic surfactant / aromatic surfactant). The range of 10/1 is preferable, the range of 1/6 to 6/1 is more preferable, and the range of 1/3 to 3/1 is still more preferable.
＜その他の成分＞
本発明の組成物は、更にガラスファイバー、ロックウール等の公知の無機フィラーを配合することができる。無機フィラーの含有量は、ＡＳ樹脂１００質量部に対して０．５～１５０重量部が好ましく、２０～１４０質量部がより好ましく、４０～１２０質量部が更に好ましい。 <Other ingredients>
The composition of the present invention may further contain a known inorganic filler such as glass fiber or rock wool. The content of the inorganic filler is preferably 0.5 to 150 parts by weight, more preferably 20 to 140 parts by weight, and still more preferably 40 to 120 parts by weight with respect to 100 parts by weight of the AS resin.
本発明の組成物は、更にガラスファイバー、ロックウール等の公知の無機フィラーを配合することができる。無機フィラーの含有量は、ＡＳ樹脂１００質量部に対して０．５～１５０重量部が好ましく、２０～１４０質量部がより好ましく、４０～１２０質量部が更に好ましい。 <Other ingredients>
The composition of the present invention may further contain a known inorganic filler such as glass fiber or rock wool. The content of the inorganic filler is preferably 0.5 to 150 parts by weight, more preferably 20 to 140 parts by weight, and still more preferably 40 to 120 parts by weight with respect to 100 parts by weight of the AS resin.
本発明の組成物には、本発明の課題を解決できる範囲内で、公知の各種添加剤を含有することができる。公知の添加剤としては、例えば、上記の特開２０００－１１９４６４号公報の段落１２、１３に記載のアルキレングリコール脂肪酸エステルの他、多価アルコールや金属石鹸、また特開２００２－１７３４に記載のリン酸エステル系化合物を用いることができる。
The composition of the present invention can contain various known additives within a range that can solve the problems of the present invention. Known additives include, for example, polyhydric alcohols and metal soaps in addition to the alkylene glycol fatty acid esters described in paragraphs 12 and 13 of the above-mentioned JP-A-2000-119464, and phosphorus compounds described in JP-A-2002-1734. Acid ester compounds can be used.
本発明の組成物は、各成分をヘンシェルミキサー、タンブラーブレンダー、ニーダー等の混合機で予備混合した後、押出機で溶融混練したり、加熱ロール、バンバリーミキサーで溶融混練したりする方法を適用して得ることができる。
実施例 The composition of the present invention applies a method in which each component is premixed with a mixer such as a Henschel mixer, tumbler blender, kneader, etc., and then melt kneaded with an extruder, or melt kneaded with a heating roll or a Banbury mixer. Can be obtained.
Example
実施例 The composition of the present invention applies a method in which each component is premixed with a mixer such as a Henschel mixer, tumbler blender, kneader, etc., and then melt kneaded with an extruder, or melt kneaded with a heating roll or a Banbury mixer. Can be obtained.
Example
実施例１～７、比較例１～６
表１に示す組成の各成分をタンブラーブレンダーで混合後、押出機にて溶融混練し、ペレット状の洗浄用樹脂組成物を得た。これらの組成物を使用し、下記の方法で洗浄試験を行った。結果を表１に示す。 Examples 1-7, Comparative Examples 1-6
After mixing each component of the composition shown in Table 1 with a tumbler blender, it was melt-kneaded with an extruder to obtain a pellet-shaped cleaning resin composition. Using these compositions, a cleaning test was conducted by the following method. The results are shown in Table 1.
表１に示す組成の各成分をタンブラーブレンダーで混合後、押出機にて溶融混練し、ペレット状の洗浄用樹脂組成物を得た。これらの組成物を使用し、下記の方法で洗浄試験を行った。結果を表１に示す。 Examples 1-7, Comparative Examples 1-6
After mixing each component of the composition shown in Table 1 with a tumbler blender, it was melt-kneaded with an extruder to obtain a pellet-shaped cleaning resin composition. Using these compositions, a cleaning test was conducted by the following method. The results are shown in Table 1.
射出成形機（三菱重工業製「三菱射出成形機２６５／１００ＭＳII」；シリンダー温度２５０℃）に、先行使用樹脂としてＡＢＳ樹脂（ダイセルポリマー製セビアンV５５０SF）の黒着色品（ドライカラー；カーボンブラック濃度２％）１ｋｇを流した。その後、表１の組成の各洗浄用樹脂組成物を流して黒色が消えるまでの組成物の使用量による評価と、続いてＡＳ樹脂（ダイセルポリマー製セビアンＮ ０５０ＳＦ）を流して射出成形し、成形品に黒色が残っているかどうかを確認した。
Injection molding machine (Mitsubishi Heavy Industries “Mitsubishi Injection Molding Machine 265 / 100MSII”; cylinder temperature 250 ° C.), ABS resin (Cebian V550SF made by Daicel Polymer) as a pre-used resin (dry color; carbon black concentration 2%) ) 1 kg was poured. Thereafter, each cleaning resin composition having the composition shown in Table 1 was poured and evaluation was made based on the amount of the composition used until the black color disappeared. Subsequently, AS resin (Cebian N 050SF made by Daicel Polymer) was poured and injection molded, and molding was performed. It was checked whether black color remained on the product.
（ＡＳ樹脂中のＡＮ含有割合の測定方法）
窒素分析装置（住化分析センター（株）製）を使用して窒素量から測定。この窒素分析装置は、スミグラフNC-90A（住化分析センター（株）製）、GC-8A（株式会社島津製作所製）、C-R6A（株式会社島津製作所製）から構成されている。 (Measurement method of AN content ratio in AS resin)
Measured from the amount of nitrogen using a nitrogen analyzer (manufactured by Sumika Chemical Research Center) This nitrogen analyzer is composed of Sumigraph NC-90A (manufactured by Sumika Chemical Analysis Co., Ltd.), GC-8A (manufactured by Shimadzu Corporation), and C-R6A (manufactured by Shimadzu Corporation).
窒素分析装置（住化分析センター（株）製）を使用して窒素量から測定。この窒素分析装置は、スミグラフNC-90A（住化分析センター（株）製）、GC-8A（株式会社島津製作所製）、C-R6A（株式会社島津製作所製）から構成されている。 (Measurement method of AN content ratio in AS resin)
Measured from the amount of nitrogen using a nitrogen analyzer (manufactured by Sumika Chemical Research Center) This nitrogen analyzer is composed of Sumigraph NC-90A (manufactured by Sumika Chemical Analysis Co., Ltd.), GC-8A (manufactured by Shimadzu Corporation), and C-R6A (manufactured by Shimadzu Corporation).
ＡＳ－１：ＡＳ樹脂（AN量２４.３質量％）
ＡＳ－２：ＡＳ樹脂（AN量２７.０質量％）
ＡＳ－３：ＡＳ樹脂（ダイセルポリマー株式会社製 セビアンN 080 AN量２９.５質量％）
界面活性剤１：ドデシルベンゼンスルホン酸ナトリウム
界面活性剤２：α－オレフィンスルホン酸ナトリウム
ＧＦ；ガラス繊維（日本電気硝子（株）製「ＥＣＳ０３Ｔ３５１／Ｐ”」（繊維径１３μm、繊維長３．２mmで、アミノシラン系のシランカップリング剤で表面処理され、アクリル樹脂系集束剤により集束処理されたもの）。 AS-1: AS resin (AN amount 24.3% by mass)
AS-2: AS resin (AN amount 27.0% by mass)
AS-3: AS resin (Cebian N 080 AN amount 29.5% by mass, manufactured by Daicel Polymer Ltd.)
Surfactant 1: Sodium dodecylbenzenesulfonate Surfactant 2: Sodium α-olefin sulfonate GF; Glass fiber (“ECS03T351 / P” manufactured by Nippon Electric Glass Co., Ltd. (fiber diameter 13 μm, fiber length 3.2 mm) Surface treated with an aminosilane-based silane coupling agent and focused with an acrylic resin-based sizing agent).
ＡＳ－２：ＡＳ樹脂（AN量２７.０質量％）
ＡＳ－３：ＡＳ樹脂（ダイセルポリマー株式会社製 セビアンN 080 AN量２９.５質量％）
界面活性剤１：ドデシルベンゼンスルホン酸ナトリウム
界面活性剤２：α－オレフィンスルホン酸ナトリウム
ＧＦ；ガラス繊維（日本電気硝子（株）製「ＥＣＳ０３Ｔ３５１／Ｐ”」（繊維径１３μm、繊維長３．２mmで、アミノシラン系のシランカップリング剤で表面処理され、アクリル樹脂系集束剤により集束処理されたもの）。 AS-1: AS resin (AN amount 24.3% by mass)
AS-2: AS resin (AN amount 27.0% by mass)
AS-3: AS resin (Cebian N 080 AN amount 29.5% by mass, manufactured by Daicel Polymer Ltd.)
Surfactant 1: Sodium dodecylbenzenesulfonate Surfactant 2: Sodium α-olefin sulfonate GF; Glass fiber (“ECS03T351 / P” manufactured by Nippon Electric Glass Co., Ltd. (fiber diameter 13 μm, fiber length 3.2 mm) Surface treated with an aminosilane-based silane coupling agent and focused with an acrylic resin-based sizing agent).
実施例と比較例の対比から明らかなとおり、ＡＳ樹脂としてＡＮ量が２８質量％以下のものを用いることにより、洗浄性能が高められた。また、界面活性剤として、脂肪族系と芳香族系の混合物を用いた例（実施例１～５）は、界面活性剤単独の例（実施例６、７）と比べて洗浄性能が高かった。
As is clear from the comparison between Examples and Comparative Examples, the cleaning performance was enhanced by using AS resin having an AN amount of 28% by mass or less. In addition, examples (Examples 1 to 5) using a mixture of aliphatic and aromatic as the surfactant had higher cleaning performance than the examples of the surfactant alone (Examples 6 and 7). .
Claims (5)
- アクリロニトリルの含有量が２８質量％以下であるＡＳ樹脂１００質量部に対して、脂肪族系界面活性剤と芳香族系界面活性剤から選ばれる１又は２以上の界面活性剤０．５～１０質量部を含有している、成形加工機洗浄用の熱可塑性樹脂組成物。 One or more surfactants selected from aliphatic surfactants and aromatic surfactants in an amount of 0.5 to 10 masses selected from aliphatic surfactants and aromatic surfactants per 100 mass parts of AS resin having an acrylonitrile content of 28 mass% or less. A thermoplastic resin composition for washing a molding machine, containing a part.
- 前記ＡＳ樹脂中のアクリロニトリルの含有量が２０～２８質量％である、請求項１記載の熱可塑性樹脂組成物。 The thermoplastic resin composition according to claim 1, wherein the content of acrylonitrile in the AS resin is 20 to 28% by mass.
- 前記界面活性剤が、脂肪族系界面活性剤と芳香族系界面活性剤から選ばれる混合物である、請求項１又は２記載の成形加工機洗浄用の熱可塑性樹脂組成物。 The thermoplastic resin composition for washing a molding machine according to claim 1 or 2, wherein the surfactant is a mixture selected from an aliphatic surfactant and an aromatic surfactant.
- 前記配合比（脂肪族系界面活性剤／芳香族系界面活性剤）が１／１０～１０／１の範囲である、請求項３記載の熱可塑性樹脂組成物。 The thermoplastic resin composition according to claim 3, wherein the blending ratio (aliphatic surfactant / aromatic surfactant) is in the range of 1/10 to 10/1.
- 更にＡＳ樹脂１００質量部に対して無機フィラーを０．５～１５０重量部含有する、請求項１～４のいずれか１項に記載の熱可塑性樹脂組成物。 The thermoplastic resin composition according to any one of claims 1 to 4, further comprising 0.5 to 150 parts by weight of an inorganic filler with respect to 100 parts by weight of the AS resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009801383516A CN102171286A (en) | 2008-10-16 | 2009-10-14 | Thermoplastic resin composition for cleaning molding machine |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008-267454 | 2008-10-16 | ||
| JP2008267454A JP5550226B2 (en) | 2008-10-16 | 2008-10-16 | Thermoplastic resin composition for washing molding machine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2010044253A1 true WO2010044253A1 (en) | 2010-04-22 |
Family
ID=42106424
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2009/005333 WO2010044253A1 (en) | 2008-10-16 | 2009-10-14 | Thermoplastic resin composition for cleaning molding machine |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5550226B2 (en) |
| KR (1) | KR101619426B1 (en) |
| CN (1) | CN102171286A (en) |
| WO (1) | WO2010044253A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3685980A4 (en) * | 2017-09-19 | 2020-10-14 | Masanori Fujita | Cleaning agent for molding-machine cleaning and cleaning method |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5552036B2 (en) * | 2010-12-07 | 2014-07-16 | ダイセルポリマー株式会社 | Thermoplastic resin composition for washing molding machine |
| JP5792647B2 (en) * | 2012-01-27 | 2015-10-14 | ダイセルポリマー株式会社 | Thermoplastic resin composition for washing molding machine |
| JP5839564B2 (en) | 2012-01-27 | 2016-01-06 | ダイセルポリマー株式会社 | Thermoplastic resin composition for washing molding machine |
| CN105924931B (en) * | 2016-05-04 | 2018-10-09 | 重庆理工大学 | A kind of plastic screw cleaning agent and production and application method |
| CN106366476B (en) * | 2016-08-26 | 2019-04-05 | 江苏金发科技新材料有限公司 | Coloured plastics material process equipment cleaning agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000119464A (en) * | 1998-10-15 | 2000-04-25 | Daicel Chem Ind Ltd | Resin composition for cleaning |
| JP2002001734A (en) * | 2000-06-23 | 2002-01-08 | Daicel Chem Ind Ltd | Resin composition for cleaning |
| JP2006257297A (en) * | 2005-03-17 | 2006-09-28 | Daicel Polymer Ltd | Cleaning resin composition |
| WO2008102891A1 (en) * | 2007-02-22 | 2008-08-28 | Daicel Polymer Ltd. | Resin composition for cleaning |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001105489A (en) * | 1999-10-06 | 2001-04-17 | Daicel Chem Ind Ltd | Styrene resin sheet and method of manufacturing the same |
| JP2007077183A (en) * | 2005-09-12 | 2007-03-29 | Daicel Polymer Ltd | Cleaning agent resin composition for molding machine |
-
2008
- 2008-10-16 JP JP2008267454A patent/JP5550226B2/en active Active
-
2009
- 2009-10-14 WO PCT/JP2009/005333 patent/WO2010044253A1/en active Application Filing
- 2009-10-14 KR KR1020117005875A patent/KR101619426B1/en active IP Right Grant
- 2009-10-14 CN CN2009801383516A patent/CN102171286A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000119464A (en) * | 1998-10-15 | 2000-04-25 | Daicel Chem Ind Ltd | Resin composition for cleaning |
| JP2002001734A (en) * | 2000-06-23 | 2002-01-08 | Daicel Chem Ind Ltd | Resin composition for cleaning |
| JP2006257297A (en) * | 2005-03-17 | 2006-09-28 | Daicel Polymer Ltd | Cleaning resin composition |
| WO2008102891A1 (en) * | 2007-02-22 | 2008-08-28 | Daicel Polymer Ltd. | Resin composition for cleaning |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3685980A4 (en) * | 2017-09-19 | 2020-10-14 | Masanori Fujita | Cleaning agent for molding-machine cleaning and cleaning method |
| US11524428B2 (en) | 2017-09-19 | 2022-12-13 | Masanori Fujita | Cleaning agent for molding-machine cleaning and cleaning method |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20110091644A (en) | 2011-08-12 |
| KR101619426B1 (en) | 2016-05-10 |
| CN102171286A (en) | 2011-08-31 |
| JP2010095624A (en) | 2010-04-30 |
| JP5550226B2 (en) | 2014-07-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5792647B2 (en) | Thermoplastic resin composition for washing molding machine | |
| WO2010044253A1 (en) | Thermoplastic resin composition for cleaning molding machine | |
| TWI509010B (en) | Thermoplastic resin composition for cleaning | |
| JP5329907B2 (en) | Thermoplastic resin composition for washing molding machine | |
| JP5552036B2 (en) | Thermoplastic resin composition for washing molding machine | |
| JP4552975B2 (en) | COMPOSITE MATERIAL COMPOSITION AND MOLDED BODY OF THE SAME | |
| TWI570234B (en) | Thermoplastic resin composition for cleaning molding machine | |
| WO2014057787A1 (en) | Thermoplastic resin composition for cleaning molding processing machine | |
| JP6084803B2 (en) | Thermoplastic resin composition for washing molding machine | |
| CN1109078A (en) | Resin compositions having excellent antistatic properties | |
| WO2022202649A1 (en) | Resin composition for cleaning | |
| JP5067293B2 (en) | Polyolefin resin composition | |
| CN104845215A (en) | Antistatic modified toughening PTT composite material | |
| JP2013028730A (en) | Polyphenylene ether-based resin composition, and molding | |
| CN106589679A (en) | Antistatic and flame-retardant laundry detergent barrel | |
| JPS62295925A (en) | Preparation of polyolefin resin composition | |
| JP2016153443A (en) | Polycarbonate resin composition | |
| CN104861537A (en) | Flame retardation composite material with excellent aging resistance and based PTT polyesters | |
| JP2009167284A (en) | Antistatic thermoplastic resin composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WWE | Wipo information: entry into national phase |
Ref document number: 200980138351.6 Country of ref document: CN |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09820431 Country of ref document: EP Kind code of ref document: A1 |
|
| ENP | Entry into the national phase |
Ref document number: 20117005875 Country of ref document: KR Kind code of ref document: A |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 09820431 Country of ref document: EP Kind code of ref document: A1 |