WO2010041876A3 - 고분자 이온성 액체를 이용한 전도성 고분자 유기용매 분산용액 제조 방법 및 이에 의해 제조되는 전도성 고분자 - Google Patents

고분자 이온성 액체를 이용한 전도성 고분자 유기용매 분산용액 제조 방법 및 이에 의해 제조되는 전도성 고분자 Download PDF

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WO2010041876A3
WO2010041876A3 PCT/KR2009/005743 KR2009005743W WO2010041876A3 WO 2010041876 A3 WO2010041876 A3 WO 2010041876A3 KR 2009005743 W KR2009005743 W KR 2009005743W WO 2010041876 A3 WO2010041876 A3 WO 2010041876A3
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conductive polymer
organic solvent
dispersed
polymer
present
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PCT/KR2009/005743
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English (en)
French (fr)
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WO2010041876A2 (ko
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서광석
김종은
김태영
이태희
Original Assignee
Suh Kwang Suck
Kim Jong Eun
Kim Tae Young
Lee Tae Hee
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Application filed by Suh Kwang Suck, Kim Jong Eun, Kim Tae Young, Lee Tae Hee filed Critical Suh Kwang Suck
Publication of WO2010041876A2 publication Critical patent/WO2010041876A2/ko
Publication of WO2010041876A3 publication Critical patent/WO2010041876A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/07—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from polymer solutions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/32—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain
    • C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
    • C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
    • C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Conductive Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

본 발명은 고분자 이온성 액체를 이용하여 유기용매에 분산이 용이하면서 전기전도도가 20 S/cm 정도로 우수한 전도성 고분자의 제조방법에 관한 것으로, 보다 상세하게는 고분자 이온성 액체 사용 시, 고분자 이온성 액체와 전도성 고분자 합성용 모노머를 혼합하여 수계 전도성 고분자를 먼저 만든 뒤 이온 교환을 통해 유기 용매 분산성 전도성 고분자를 만드는 방법 대신, 고분자 이온성 액체를 미리 이온 교환을 거쳐 유기 용매에 용해되도록 만든 후 이를 중합분산제로 사용하여 유기 용매에 분산되는 전도성 고분자를 합성하는 방법이다. 또한 본 기술은 전도성 고분자 합성 시 유기 용매 내에서 합성이 이루어지도록 해 합성된 전도성 고분자가 유기용매에 균일하고 안정적으로 분산되도록 하는 방법에 관한 것이다. 본 발명에 따라 제조되는 전도성 고분자는 유기용매에 대한 분산성이 매우 우수할 뿐만 아니라, 제조공정이 간단하고 전기전도도가 20 S/cm 정도로 높은 것을 특징으로 한다. 따라서 기존의 수분산 전도성 고분자로는 응용이 제한되었던 유기 용매 분산성을 필요로 하는 여러 응용소재 분야에 적용이 가능하다.
PCT/KR2009/005743 2008-10-08 2009-10-08 고분자 이온성 액체를 이용한 전도성 고분자 유기용매 분산용액 제조 방법 및 이에 의해 제조되는 전도성 고분자 WO2010041876A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020080098874A KR101022208B1 (ko) 2008-10-08 2008-10-08 고분자 이온성 액체를 이용한 전도성 고분자 유기용매 분산용액 제조 방법 및 이에 의해 제조되는 전도성 고분자
KR10-2008-0098874 2008-10-08

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WO2010041876A2 WO2010041876A2 (ko) 2010-04-15
WO2010041876A3 true WO2010041876A3 (ko) 2010-07-29

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PCT/KR2009/005743 WO2010041876A2 (ko) 2008-10-08 2009-10-08 고분자 이온성 액체를 이용한 전도성 고분자 유기용매 분산용액 제조 방법 및 이에 의해 제조되는 전도성 고분자

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KR (1) KR101022208B1 (ko)
TW (1) TW201030048A (ko)
WO (1) WO2010041876A2 (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI567130B (zh) * 2012-08-01 2017-01-21 長興材料工業股份有限公司 導電性高分子複合物及其製備方法與用途
KR102026428B1 (ko) 2018-03-13 2019-09-27 한양대학교 산학협력단 복수의 전도성 처리를 포함하는 고전도성 고분자 박막의 제조 방법
KR102613050B1 (ko) * 2018-04-20 2023-12-15 삼성전자주식회사 이차전지용 복합막, 그 제조방법 및 이를 포함하는 이차전지
KR102400192B1 (ko) * 2020-06-26 2022-05-20 광주과학기술원 전도성 나노 다공성 멤브레인 및 이의 제조 방법
KR102398273B1 (ko) 2020-10-20 2022-05-16 이화여자대학교 산학협력단 개질된 전도성 고분자 박막의 제조 방법 및 이를 이용하여 제조된 개질된 전도성 고분자 박막

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4981729A (en) * 1989-05-25 1991-01-01 Man-Gill Chemical Company Electroconductive aqueous coating compositions, process, and coated substrates
JP2000119336A (ja) * 1998-10-16 2000-04-25 Tosoh Corp 単一イオン伝導性高分子固体電解質
JP2006257288A (ja) * 2005-03-17 2006-09-28 Kaneka Corp 金属表面コーティング用組成物、導電性高分子の製造方法、金属表面のコーティング方法、ならびに電解コンデンサおよびその製造方法
WO2007148639A1 (ja) * 2006-06-23 2007-12-27 Eintesla, Inc. 高分子膜の製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4981729A (en) * 1989-05-25 1991-01-01 Man-Gill Chemical Company Electroconductive aqueous coating compositions, process, and coated substrates
JP2000119336A (ja) * 1998-10-16 2000-04-25 Tosoh Corp 単一イオン伝導性高分子固体電解質
JP2006257288A (ja) * 2005-03-17 2006-09-28 Kaneka Corp 金属表面コーティング用組成物、導電性高分子の製造方法、金属表面のコーティング方法、ならびに電解コンデンサおよびその製造方法
WO2007148639A1 (ja) * 2006-06-23 2007-12-27 Eintesla, Inc. 高分子膜の製造方法

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KR101022208B1 (ko) 2011-03-16
TW201030048A (en) 2010-08-16
WO2010041876A2 (ko) 2010-04-15
KR20100039783A (ko) 2010-04-16

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