WO2010001608A1 - Substrate heating apparatus, liquid material applying apparatus provided with substrate heating apparatus, and substrate heating method - Google Patents
Substrate heating apparatus, liquid material applying apparatus provided with substrate heating apparatus, and substrate heating method Download PDFInfo
- Publication number
- WO2010001608A1 WO2010001608A1 PCT/JP2009/003064 JP2009003064W WO2010001608A1 WO 2010001608 A1 WO2010001608 A1 WO 2010001608A1 JP 2009003064 W JP2009003064 W JP 2009003064W WO 2010001608 A1 WO2010001608 A1 WO 2010001608A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- substrate
- heating
- contact
- opening
- gas
- Prior art date
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 253
- 238000010438 heat treatment Methods 0.000 title claims abstract description 245
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000011344 liquid material Substances 0.000 title claims abstract description 18
- 230000007246 mechanism Effects 0.000 claims abstract description 51
- 239000011248 coating agent Substances 0.000 claims description 68
- 238000000576 coating method Methods 0.000 claims description 68
- 230000008569 process Effects 0.000 claims description 19
- 230000007723 transport mechanism Effects 0.000 claims description 14
- 230000032258 transport Effects 0.000 claims description 13
- 230000003028 elevating effect Effects 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 3
- 239000004065 semiconductor Substances 0.000 abstract description 20
- 230000008859 change Effects 0.000 abstract description 8
- 239000007789 gas Substances 0.000 description 52
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 238000010586 diagram Methods 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 238000004891 communication Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000007664 blowing Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/50—Assembly of semiconductor devices using processes or apparatus not provided for in a single one of the subgroups H01L21/06 - H01L21/326, e.g. sealing of a cap to a base of a container
- H01L21/56—Encapsulations, e.g. encapsulation layers, coatings
- H01L21/563—Encapsulation of active face of flip-chip device, e.g. underfilling or underencapsulation of flip-chip, encapsulation preform on chip or mounting substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/74—Apparatus for manufacturing arrangements for connecting or disconnecting semiconductor or solid-state bodies
- H01L24/741—Apparatus for manufacturing means for bonding, e.g. connectors
- H01L24/743—Apparatus for manufacturing layer connectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73201—Location after the connecting process on the same surface
- H01L2224/73203—Bump and layer connectors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/73—Means for bonding being of different types provided for in two or more of groups H01L2224/10, H01L2224/18, H01L2224/26, H01L2224/34, H01L2224/42, H01L2224/50, H01L2224/63, H01L2224/71
- H01L2224/732—Location after the connecting process
- H01L2224/73201—Location after the connecting process on the same surface
- H01L2224/73203—Bump and layer connectors
- H01L2224/73204—Bump and layer connectors the bump connector being embedded into the layer connector
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/01—Chemical elements
- H01L2924/01004—Beryllium [Be]
Definitions
- the present invention relates to a substrate heating apparatus that heats a substrate to which a liquid material is applied, a coating apparatus including the substrate heating apparatus, and a substrate heating method.
- the present invention relates to a substrate heating apparatus that prevents damage to a substrate and a chip placed thereon in a semiconductor packaging underfill process until the underfill process is completed, a coating apparatus including the substrate heating apparatus, and a substrate heating method.
- a substrate on which a workpiece such as a semiconductor chip is placed may be simply referred to as a substrate.
- One of the semiconductor chip mounting techniques is a technique called a flip chip method.
- a protruding electrode is formed on the surface of the semiconductor chip 1 and is directly connected to an electrode pad on the substrate 2.
- Resin 4 is reinforced by filling the gap with resin 4. This process is called underfill (see FIG. 1).
- the liquid resin 4 is applied along the outer periphery of the semiconductor chip 1, the resin 4 is filled in the gap between the semiconductor chip 1 and the substrate 2 by utilizing a capillary phenomenon, and then heated in an oven or the like. 4 is cured.
- products have been further reduced in size and thickness, and accordingly, the semiconductor chip 1 and the substrate 2 in the flip chip system have also been reduced in size and thickness.
- the substrate is heated to reduce the viscosity of the resin and facilitate filling.
- Patent Document 1 discloses a substrate heating apparatus that heats a substrate by blowing heated gas, and has a protruding portion that protrudes upward toward the bottom surface of the substrate, and one end is a protruding portion.
- a heating unit in which a gas channel whose other end communicates with the gas supply unit is formed in the blow-out hole opened on the upper surface of the gas, a gas heating means for heating the gas flowing in the gas channel, and a gas to the gas channel There is disclosed a substrate heating apparatus comprising an opening / closing valve for turning on / off the inflow of the substrate and a valve controller for heating the substrate to a target temperature by controlling the opening / closing operation of the opening / closing valve.
- Patent Document 2 when injecting resin between an IC chip and a substrate in an underfill process, the IC chip is energized and a heated plate heated only to the IC chip is contacted, or the IC An electronic component mounting method is disclosed in which the viscosity of the resin between the IC chip and the substrate facing each other is made lower than the viscosity of the resin at other portions by applying vibration only to the chip.
- Patent Document 3 discloses a semiconductor device manufacturing apparatus that has a coating stage on which a TAB tape on which a semiconductor chip is mounted is placed and supplies resin between the semiconductor chip and the TAB tape. A semiconductor device manufacturing apparatus having a heating means for heating a tape is disclosed.
- JP 2006-314861 A Japanese Patent Laid-Open No. 2005-45284 JP 2007-227558 A
- the present invention provides a substrate heating device that can reduce the temperature change of the substrate on which the semiconductor chip is placed before and after the coating operation and prevent the connection portion from being broken, a coating device including the substrate heating device, and a substrate heating method.
- the purpose is to do.
- 1st invention is a board
- substrate heating apparatus for heating the board
- substrate heating apparatus comprising:
- the heating member includes a suction opening that causes a suction force to act on a bottom surface of the substrate on an upper surface thereof, and is sucked from the suction opening at a rising position of the elevating mechanism.
- a force is applied to heat the substrate by bringing the upper surface of the heating member into contact with the bottom surface of the substrate, and at the lowered position of the elevating mechanism, the heated gas is ejected from the ejection opening to heat the substrate. It is characterized by doing.
- the ejection opening and the suction opening are configured by the same opening, and the opening is connected to a negative pressure source and a pressure source via a switching valve.
- the opening is connected to a negative pressure source and a pressure source via a switching valve.
- a seventh invention is a substrate heating device according to any one of the first to sixth inventions, a discharge device that discharges the liquid material, a drive mechanism that moves the discharge device relative to the substrate, and the substrate It is a liquid material application apparatus provided with the conveyance mechanism which conveys these in one direction, and the control part which controls these operation
- the control unit when the control unit performs a coating operation on a workpiece arranged on the substrate, the upper surface of the heating member is brought into contact with the bottom surface of the substrate with the elevating mechanism as the raised position.
- heated gas is ejected from the ejection port by using the elevating mechanism as a lowered position.
- a ninth invention is a substrate heating method for heating from below a substrate that is transported in one direction and on which a coating operation is performed on a workpiece that is placed on the workpiece in the middle of the transport, and is described above by a lifting mechanism.
- a contact heating process in which the flat top surface of the heating member is brought into contact with the bottom surface of the substrate and the substrate is heated, and the bottom surface of the substrate and the top surface of the heating member are separated from each other by an elevating mechanism.
- a non-contact heating step of jetting heating gas from the jetting opening is applied from a suction opening formed on an upper surface of the heating member.
- the ejection opening and the suction opening are configured by the same opening, and the opening is connected to a negative pressure source and a pressure source via a switching valve, and the contact In the heating step, the opening and the negative pressure source are communicated, and in the non-contact heating step, the opening and the pressure source are communicated.
- the contact heating step is performed when a coating operation is performed on the workpiece disposed on the substrate, and the non-contact heating is performed when the substrate is transported.
- a process is performed.
- a thirteenth invention is characterized in that, in the twelfth invention, the non-contact heating step is performed before and after the coating operation.
- a fourteenth invention is characterized in that, in the twelfth or thirteenth invention, the coating operation is an underfill process.
- the entire bottom surface of the substrate is uniformly heated in the contact heating step and the non-contact heating step. By uniformly heating the entire bottom surface of the substrate, the connection portion can be more effectively protected.
- a substrate heating apparatus is a substrate heating apparatus that is disposed below a transport mechanism that transports a substrate to which a liquid material is applied, and that heats the substrate.
- a flow path communicating with a switching valve that switches communication between the negative pressure source and the pressurization source, a heating block in which the flow port is formed in a surface facing the substrate, and the flow path is provided; and the heating A heater installed in the block for heating the heating block and heating the gas in the flow path, a temperature sensor installed in the heating block for detecting the temperature of the heating block, and the temperature sensor
- a temperature control unit that controls the heater based on the signal, a raised position that supports the substrate in contact with the bottom surface when applying a liquid material, and the substrate of the heating block that faces the substrate when the substrate is transported There characterized by and a lifting mechanism for raising and lowering movement of the heated block between a lowered position that apart from the substrate.
- the switching valve communicates with a negative pressure source to suck gas from the flow port, and adsorbs the substrate supported from the bottom by the heating block.
- the substrate is heated by bringing the heating block into contact with the substrate.
- the substrate bottom surface is in a position separated from the heating block by communicating with a pressurizing source by a switching valve.
- the substrate is heated by ejecting the gas in the flow path heated by the heater from the flow port.
- the heating block is provided with a plurality of flow ports and a plurality of flow paths.
- the flow path has one end communicating with the first flow port and the other end communicating with the first valve for switching communication with the negative pressure source, and one end with the second flow path. And the other end is divided into a second flow path that communicates with a second valve that switches communication with the pressurizing source, and the heating block is arranged on the surface facing the substrate. A port and the second flow port are bored, and the first channel and the second channel are internally provided.
- the heating block when the heating block is in the raised position, the first valve communicates with a negative pressure source to suck gas from the first circulation port, and the heating block has a bottom surface.
- the heating block Adsorbing the substrate supported from and heating the substrate by bringing the heating block into contact with the substrate; when in the lowered position, the second valve communicates with a pressure source; The substrate is heated by ejecting the gas in the second flow path heated by the heater from the second circulation port toward the bottom surface of the substrate at a position separated from the heating block. More preferably, the heating block has a plurality of the first flow ports and the second flow ports, and a plurality of the first flow channels and the second flow channels. Is installed.
- a coating apparatus includes any one of the above-described substrate heating apparatuses, a discharge apparatus that discharges a liquid material, a drive mechanism that moves the discharge apparatus relative to the substrate, and the substrate extending in the coating apparatus. And a control unit that controls these operations.
- the transport mechanism is divided into a plurality of parts, and a plurality of the substrate heating devices are provided for each of the plurality of parts of the transport mechanism.
- the present invention since heating is performed not only at the time of coating but also at the time of conveyance before and after the coating, for example, in the underfill process, the temperature change of the substrate on which the semiconductor chip is placed is extremely small and the connection portion is destroyed. Can be prevented. Further, since the temperature change of the substrate can be made extremely small during the coating operation, the state of the liquid material is stable and the coating can be performed stably. Furthermore, since two different heating systems can be implemented with one heating mechanism, both heating during coating and during non-coating (during conveyance) can be handled with one heating mechanism. For this reason, it is possible to reduce the size of the apparatus.
- FIG. 1 is a schematic perspective view of a coating apparatus according to Example 1.
- FIG. FIG. 3 is an explanatory diagram for explaining a transport mechanism of the coating apparatus according to the first embodiment. 3 is a flowchart illustrating a flow of operations in the coating apparatus according to the first embodiment.
- 3 is a flowchart illustrating a flow of operations in the coating apparatus according to the first embodiment.
- 3 is a flowchart illustrating a flow of operations in the coating apparatus according to the first embodiment.
- 3 is a flowchart illustrating a flow of operations in the coating apparatus according to the first embodiment.
- 6 is a cross-sectional view of a main part of a heating mechanism according to Embodiment 2.
- 6 is a block diagram of a heating mechanism according to Embodiment 2.
- FIG. 3 is a cross-sectional view of the main part
- FIG. 4 is a block diagram.
- the heating block 11, which is a main part of the heating mechanism 105 in the present embodiment, has a substantially rectangular parallelepiped shape, and the upper surface 12 facing the substrate has a surface that is approximately the same size as the substrate 2.
- the substrate 2 is arranged. An equal arrangement was adopted so that there was no temperature difference across the entire bottom surface of the plate.
- the plurality of first circulation ports 13 are openings for suction and communicate with a plurality of first flow paths 15 provided in the heating block 11.
- the plurality of second circulation ports 14 are ejection openings, and communicate with a plurality of second flow paths 16 provided in the heating block 11, respectively.
- the plurality of first flow paths 15 communicate with the negative pressure source 19 via the first valve 17, and the plurality of second flow paths 16 communicate with the pressurization source 20 via the second valve 18. .
- first valve 17 and the second valve 18 By opening and closing the first valve 17 and the second valve 18, the gas in the flow path (15, 16) can be sucked in or the gas can be blown out into the flow path.
- first valve 17 and the second valve 18 are installed in a place different from the heating block 11.
- a plurality of first valves 17 and second valves 18 may be provided according to the strength of the negative pressure source 19 and the pressurization source 20.
- air flows as a working gas in the flow paths (15, 16) the present invention is not limited to this. For example, when an inert gas is preferable, nitrogen or the like may be used.
- the heater 21 is provided inside the heating block 11 and heats the gas in the heating block 11 and the second flow path 16.
- an electric heater is used as the heater 21, but the invention is not limited to this.
- a Peltier element or the like may be used.
- the number of heaters to be installed may be any number, and the arrangement thereof can be changed as appropriate. However, from the viewpoint of protecting the connection portion, the number does not cause a temperature difference across the entire bottom surface of the substrate 2. It is preferable to employ the arrangement.
- a temperature sensor 22 is installed inside the heating block 11.
- the heater 21 and the temperature sensor 22 are connected to a temperature control unit 23, and the temperature control unit 23 controls the heater 21 based on a signal from the temperature sensor 22 so that the temperature becomes constant.
- the control method is not particularly limited, and PID (proportional, integral, derivative) control, general feedback control, simple on / off control, and the like often used in temperature control are used.
- the arrangement and number of the temperature sensors 22 can be changed and applied as appropriate.
- the substrate 2 is transported in one direction by the transport mechanism 104.
- the transport mechanism 104 includes two rail-like members 109, and a heating mechanism 105 is disposed therebetween.
- the heating block 11, which is a main part of the heating mechanism 105, is placed on the lifting mechanism 24 (see FIG. 2).
- the elevating mechanism 24 has a raised position that supports the substrate 2 positioned above the heating block 11 from the bottom surface, and a lowered position that separates the heating block 11 from the substrate 2. In the raised position, the substrate 2 is tightly fixed by the bowl-shaped substrate pressing member 106 and the upper surface 12 of the heating block.
- an apparatus for driving the elevating mechanism 24 for example, an air cylinder in which a piston is driven by compressed gas, or a combination of a motor and a ball screw can be used.
- the heating block 11 When applying the liquid material 4, the heating block 11 serves as an application stage by moving to the raised position and supporting the substrate 2 from the bottom surface. On the other hand, at the time of substrate transfer, the heating block 11 moves to a lowered position separated from the substrate 2 so that the substrate transfer is performed smoothly. In order to efficiently maintain the substrate temperature by the heated gas, it is preferable that the distance between the upper surface 12 of the heating block and the bottom surface of the substrate 2 is not too large, for example, several mm. Details of the transport mechanism 104 will be described in an embodiment.
- the heating mode of the heating mechanism 105 is roughly divided into two depending on the position of the heating block 11.
- the first valve 17 communicates the first flow path 15 in the heating block 11 and the negative pressure source 19.
- gas is suck
- the substrate 2 is positioned immediately above the first flow port 13, and the substrate 2 is adsorbed by the suction action from the first flow port 13, so that the upper surface 12 of the heating block and the bottom surface of the substrate 2 are in close contact with each other. Abut.
- the heat from the heater 21 is directly and rapidly transmitted through the heating block 11.
- substrate 2 can be kept constant by controlling the heater 21 so that temperature may become fixed by the temperature control part 23.
- FIG. According to the above heating method, the upper surface 12 of the heating block is brought into contact with the bottom surface of the substrate 2, so that heat from the heater 21 can be efficiently transmitted and the temperature of the substrate 2 can be stably controlled. . Controlling the temperature stably not only prevents the connection portion 3 from being broken, but also stabilizes the state of the liquid material 4 and stabilizes the application. Moreover, since it can adsorb
- FIG. 6 Heating in the lowered position (FIG. 6)
- the second valve 18 communicates the second flow path 16 in the heating block 11 and the pressure source 20. Then, gas is blown out from the second flow port 14 communicating with the second flow path 16 in the heating block 11 at the other end (27). Since the second circulation port 14 is separated from the substrate 2, the gas is ejected toward the bottom surface of the substrate 2. The ejected gas is heated by the heater 21 in the heating block 11, and heat is transmitted to the substrate 2 by the heated gas. And the temperature of the board
- substrate 2 can be kept constant by controlling the heater 21 so that temperature may become constant by the temperature control part 23.
- heat can be transferred to the moving substrate 2 by ejecting the heated gas from a remote location. That is, since the temperature can be controlled also for the moving substrate 2, the temperature change in the underfill process can be extremely reduced. Moreover, since the heated gas is ejected from the 2nd circulation port 14 opened in multiple numbers over the board
- the heating at the lowered position [2] is preferably performed before and after the coating operation step. Heating before the coating operation step is preliminary heating, and heating after the coating operation step is temperature holding heating that suppresses the temperature change of the substrate within a predetermined range.
- the flatness of the substrate 2 is improved and the coating accuracy is improved. These effects are particularly remarkable when the substrate 2 is thin.
- the configuration in which the distribution port for applying the suction force is not provided and the substrate pressing member 106 is tightly attached there is a problem that the central portion of the substrate is warped. For the above reason, it is preferable to employ a configuration in which a circulation port for applying a suction force to the heating block 11 is provided.
- the coating apparatus 101 includes a discharge device 102, a drive mechanism 103, a transport mechanism 104, a heating mechanism 105, and a control unit 124 that controls them.
- the discharge device 102 includes a storage container 107 (not shown) for storing the liquid material 4 and a nozzle 108 (see FIG. 1) for discharging the liquid material 4.
- the discharge device 102 is attached to the XYZ drive mechanism 103 so that the nozzle 108 faces the application surface of the application target substrate 2, and can be moved onto the application target substrate 2 conveyed by the conveyance mechanism 104.
- the transport mechanism 104 is installed across the width of the coating apparatus 101, and includes three transport units (114, 115, 116), each of which can operate independently. Since the transport mechanism 104 is constituted by three transport units, it is possible to perform the carry-in and carry-out operations individually even during the coating operation, and the process processing time can be shortened.
- the transport mechanism 104 of this embodiment has a structure in which two rail-shaped members 109 extending in the width of the substrate 2 to be transported are installed in parallel, and above the rail-shaped member 109.
- a belt 111 rotated by the roller 110 is provided. By rotating the roller 110, the belt 111 rotates, and the substrate 2 placed on the belt 111 is conveyed.
- the width of the two rail-like members 109 can be changed according to the size of the substrate 2.
- the substrate 2 is carried into the coating apparatus 101 from the left conveyance mechanism 114, and unloaded from the right conveyance mechanism 116 to the outside of the coating apparatus 101 via the central conveyance mechanism 115. .
- the heating mechanism 105 includes three heating units (121, 122, 123). Each heating unit is disposed between the two rail-like members 109 constituting the transport mechanism 104 so as to correspond to the transport units (114, 115, 116). By configuring the heating mechanism 105 with three heating units, it is possible to heat the substrate 2 corresponding to individual transport operations. Since the heating block 11 is approximately the same size as the substrate 2, the heating unit may not be installed in a space that is less than the size of the substrate 2, such as the carry-in side or the carry-out side. Therefore, in this embodiment, the auxiliary heating unit (118, 119, 120) smaller than the heating unit is provided.
- the auxiliary heating unit is fixed at a lowered position separated from the substrate 2 without moving up and down, and only ejects heated gas from the second circulation port 14 without providing the first circulation port 13. This is different from the heating unit described above.
- the size of the auxiliary heating units (118, 119, 120) may be any size as long as the space between the three heating units (121, 122, 123) can be filled, and can be appropriately changed.
- the auxiliary heating unit 118 is installed at the position of the carry-in section
- the auxiliary heating unit 119 is installed at the position between the central heating unit 122 and the right heating unit 123
- the auxiliary heating unit 120 is installed at the position of the carry-out section.
- the set temperature in the heating mechanism 105 varies depending on the size of the substrate 2 and the number of semiconductor chips 1, but is generally set in the range of 100 to 150 degrees Celsius. Within the range, it may be controlled to perform heating according to the purpose of preheating, optimum temperature at the time of application, and temperature holding heating.
- each of the heating unit and the auxiliary heating unit is referred to as a stage.
- the temperature of the carry-in stage 118 and the front stage 121 is read before carrying the substrate 2 into the coating apparatus 101 (STEP 101), and it is determined whether it is within the set temperature range (STEP 102).
- the set temperature If the set temperature has not been reached, read the temperature again and repeat until the set temperature is reached. If the set temperature has been reached, it is determined whether the substrate 2 remains on the previous stage 121 (STEP 103). When the board
- the temperature of the coating stage 122 is read (STEP 107), and it is determined whether it is within the set temperature range (STEP 108). If the set temperature has not been reached, the temperature is read again while controlling the temperature to be constant with respect to the substrate 2 fixed to the previous stage 121 (STEP 110) and repeated until the set temperature is reached. When the set temperature is reached, it is determined whether or not the substrate 2 remains on the coating stage 122 (STEP 109). If the substrate 2 remains, the control waits until the substrate 2 is removed while controlling the temperature to be constant with respect to the substrate 2 fixed to the front stage 121 (STEP 110). When the substrate 2 does not remain, the gas ejection from the coating stage 122 is started (STEP 111).
- the suction of the front stage 121 is cut off, the front stage 121 is lowered, and the ejection of gas from the front stage 121 is started (STEP 112).
- the substrate 2 is transported to the position of the coating stage 122 (STEP 113).
- the gas ejection from the coating stage 122 is stopped, the coating stage 122 rises to support the substrate 2, and the suction of the coating stage 122 is started to fix the substrate 2 by suction. (STEP 114).
- the liquid material 4 is applied by the discharge device 102 (STEP 115).
- the temperatures of the intermediate stage 119 and the rear stage 123 are read (STEP 116), and it is determined whether they are within the set temperature range (STEP 117). If the set temperature has not been reached, the temperature is read again while controlling the temperature to be constant with respect to the substrate 2 fixed to the coating stage 122 (STEP 119) and repeated until the set temperature is reached. If the set temperature has been reached, it is determined whether the substrate 2 remains on the rear stage 123 (STEP 118).
- control is performed so that the temperature is constant with respect to the substrate 2 fixed to the coating stage 122 (STEP 119), and the process waits until the substrate 2 is removed.
- gas ejection from the intermediate stage 119 and the rear stage 123 is started (STEP 120).
- the suction of the coating stage 122 is cut, the coating stage 122 is lowered, and the ejection of gas from the coating stage 122 is started (STEP 121).
- the substrate 2 is transported to the position of the rear stage 123 (STEP 122).
- the temperature of the carry-out stage 120 is read (STEP 124), and it is determined whether it is within the set temperature range (STEP 125). If the set temperature has not been reached, the temperature is read again while controlling the substrate 2 fixed to the rear stage 123 so that the temperature becomes constant (STEP 127), and the process is repeated until the set temperature is reached. If the set temperature has been reached, it is determined whether the substrate 2 can be carried out of the apparatus 101 (STEP 126). If unloading is not possible, control is performed so that the temperature is constant with respect to the substrate 2 fixed to the rear stage 123 (STEP 127), and the process waits until unloading becomes possible.
- gas ejection from the carry-out stage 120 is started (STPE 128). Then, the suction of the rear stage 123 is cut off, the rear stage 123 descends, and the gas ejection from the rear stage 123 is started (STEP 129). Thereafter, the substrate 2 is transported outside the apparatus 101 (STEP 130).
- FIG. 13 is a cross-sectional view of a main part of the heating mechanism according to the second embodiment
- FIG. 14 is a block diagram.
- the heating block 201 in the second embodiment has a substantially rectangular parallelepiped shape, and the upper surface 202 facing the substrate is a surface having almost the same size as the size of the substrate 2.
- a plurality of circulation ports 203 are evenly opened on the upper surface 202 at regular intervals. Each circulation port 203 communicates with a flow path 204 provided in the heating block 201.
- the flow path 204 communicates with a switching valve 205 installed at a location different from the heating block 201, and communicates with the negative pressure source 206 and the pressurizing source 207 via the switching valve 205.
- a switching valve 205 installed at a location different from the heating block 201, and communicates with the negative pressure source 206 and the pressurizing source 207 via the switching valve 205.
- the switching valve 205 By switching the switching valve 205 and communicating either the negative pressure source 206 or the pressurization source 207 with the flow path 204, the gas in the flow path 204 is sucked in or the gas is blown out into the flow path.
- a plurality of switching valves 205 may be provided in accordance with the pressure level of the negative pressure source 206 or the pressure source 207.
- Other heaters 21, temperature sensor 22, elevating mechanism 24 and the like are the same as those in the first embodiment.
- the switching valve 205 connects the flow path 204 in the heating block 201 and the negative pressure source 206. Thereby, the gas is sucked from the flow port 203 communicating with the flow path 204 in the heating block 201 at the other end.
- the substrate 2 is positioned immediately above the circulation port 203, and the substrate 2 is adsorbed by the suction action from the circulation port 203, and the upper surface 202 of the heating block and the bottom surface of the substrate 2 are in close contact with each other.
- the heat from the heater is directly and quickly transmitted through the heating block 201.
- the temperature of the substrate 2 can be kept constant.
- the switching valve 205 communicates the flow path 204 in the heating block 201 and the pressurizing source 207. Then, gas is blown out from the flow port 203 communicating with the flow path 204 in the heating block 201 at the other end. Since the circulation port 203 is separated from the substrate 2, the gas is blown out toward the bottom surface of the substrate 2. The blown out gas is heated by a heater in the heating block 201, and heat is transmitted to the substrate 2 by the heated gas. Then, the temperature of the substrate 2 can be kept constant by controlling the heater so that the temperature becomes constant by the temperature control unit 208.
- the heating block 201 of the present embodiment by using a single channel, the number of valves and piping connected to the channel can be reduced, and space saving can be realized.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Coating Apparatus (AREA)
- Encapsulation Of And Coatings For Semiconductor Or Solid State Devices (AREA)
- Container, Conveyance, Adherence, Positioning, Of Wafer (AREA)
Abstract
Description
なお、本明細書では、半導体チップ等のワークが載置された基板を単に基板という場合がある。 The present invention relates to a substrate heating apparatus that heats a substrate to which a liquid material is applied, a coating apparatus including the substrate heating apparatus, and a substrate heating method. In particular, the present invention relates to a substrate heating apparatus that prevents damage to a substrate and a chip placed thereon in a semiconductor packaging underfill process until the underfill process is completed, a coating apparatus including the substrate heating apparatus, and a substrate heating method.
In this specification, a substrate on which a workpiece such as a semiconductor chip is placed may be simply referred to as a substrate.
フリップチップパッケージでは、半導体チップ1と基板2との熱膨張係数の差により発生する応力が、接続部3に集中して接続部3が破壊することを防ぐために、半導体チップ1と基板2との隙間に樹脂4を充填して接続部3を補強する。この工程をアンダーフィルと呼ぶ(図1参照)。 One of the semiconductor chip mounting techniques is a technique called a flip chip method. In the flip chip method, a protruding electrode is formed on the surface of the
In the flip chip package, in order to prevent stress generated due to the difference in thermal expansion coefficient between the
近年は、製品の小型化、薄型化がさらに進み、それに伴い、フリップチップ方式における半導体チップ1や基板2自体も小型化、薄型化が進んできている。小型、薄型になると半導体チップ1や基板2に熱が伝わりやすいため、周囲温度の影響を受けやすく、これにより発生した前述の応力により、接続部3が破壊しやすくなっていた。そこで、アンダーフィル工程における補強を確実にすべく、樹脂の粘度を下げ、充填を行いやすくするために基板を加熱することが行われていた。 In the underfill process, the
In recent years, products have been further reduced in size and thickness, and accordingly, the
また、特許文献2には、アンダーフィル工程において、ICチップと基板との間に樹脂を注入する際に、ICチップに通電し、ICチップのみに加熱された熱板を接触させ、或いは、ICチップのみに振動を加えることにより、ICチップと基板との対向間における樹脂の粘性をそれ以外の部位における樹脂の粘性よりも低くするようにする電子部品の実装方法が開示されている。
特許文献3には、半導体チップを搭載したTABテープを載置する塗布ステージを有し、半導体チップとTABテープの間に樹脂を供給する半導体装置の製造装置において、塗布ステージ上で半導体チップとTABテープを加熱する加熱手段を有することを特徴とする半導体装置の製造装置、が開示されている。 For example,
Further, in
そこで本発明は、塗布作業の前後を通じて、半導体チップの載置された基板の温度変化を小さくし、接続部の破壊を防ぐことができる基板加熱装置、それを備える塗布装置および基板加熱方法を提供することを目的とする。 As described in each of the above patent documents, there has conventionally been a substrate heating apparatus that heats a substrate only at the time of coating. However, as far as the applicant knows, there is no apparatus for heating the substrate before and after coating. That is, in the conventional substrate heating apparatus, since it is in a non-heated state at the time of conveyance before and after coating, the temperature change between coating and conveyance becomes large, and the change in stress generated due to the above-described difference in thermal expansion coefficient becomes large. For this reason, there is a problem that the connecting portion is easily broken.
Therefore, the present invention provides a substrate heating device that can reduce the temperature change of the substrate on which the semiconductor chip is placed before and after the coating operation and prevent the connection portion from being broken, a coating device including the substrate heating device, and a substrate heating method. The purpose is to do.
第2の発明は、第1の発明において、前記加熱部材は、その上面に前記基板の底面に吸引力を作用させる吸引用開口を備え、前記昇降機構の上昇位置において、前記吸引用開口から吸引力を作用させ、前記加熱部材の上面を前記基板の底面に接触させて前記基板を加熱し、前記昇降機構の下降位置において、前記噴出用開口から加熱された気体を噴出させて前記基板を加熱することを特徴とする。
第3の発明は、第2の発明において、前記噴出用開口と前記吸引用開口は同一の開口により構成され、該開口は切換弁を介して負圧源および加圧源に接続されることを特徴とする。
第4の発明は、第1ないし3のいずれかの発明において、前記開口が複数あることを特徴とする。
第5の発明は、第1ないし4のいずれかの発明において、複数の加熱部材が、前記基板の搬送方向に連続して配設されることを特徴とする。
第6の発明は、第5の発明において、前記加熱部材が、長さが異なる複数の種類の加熱ブロックにより構成されることを特徴とする。 1st invention is a board | substrate heating apparatus for heating the board | substrate from which a coating operation | work is performed with respect to the workpiece | work arrange | positioned in the middle of conveyance in one direction, Comprising: The bottom face of the said board | substrate A flat upper surface that heats the substrate, a heating member that is formed on the upper surface and that has a jetting opening for jetting a heating gas on the bottom surface of the substrate, and a lifting mechanism that raises and lowers the heating member; A substrate heating apparatus comprising:
According to a second aspect, in the first aspect, the heating member includes a suction opening that causes a suction force to act on a bottom surface of the substrate on an upper surface thereof, and is sucked from the suction opening at a rising position of the elevating mechanism. A force is applied to heat the substrate by bringing the upper surface of the heating member into contact with the bottom surface of the substrate, and at the lowered position of the elevating mechanism, the heated gas is ejected from the ejection opening to heat the substrate. It is characterized by doing.
According to a third aspect, in the second aspect, the ejection opening and the suction opening are configured by the same opening, and the opening is connected to a negative pressure source and a pressure source via a switching valve. Features.
According to a fourth invention, in any one of the first to third inventions, there are a plurality of the openings.
A fifth invention is characterized in that, in any one of the first to fourth inventions, the plurality of heating members are continuously arranged in the transport direction of the substrate.
According to a sixth invention, in the fifth invention, the heating member includes a plurality of types of heating blocks having different lengths.
第8の発明は、第7の発明において、前記制御部が、基板上に配置されたワークに対し塗布作業を行う際には前記昇降機構を上昇位置として加熱部材の上面を基板の底面に接触させ、基板の搬送時には前記昇降機構を下降位置として前記噴出口から加熱された気体を噴出することを特徴とする。 A seventh invention is a substrate heating device according to any one of the first to sixth inventions, a discharge device that discharges the liquid material, a drive mechanism that moves the discharge device relative to the substrate, and the substrate It is a liquid material application apparatus provided with the conveyance mechanism which conveys these in one direction, and the control part which controls these operation | movement.
According to an eighth invention, in the seventh invention, when the control unit performs a coating operation on a workpiece arranged on the substrate, the upper surface of the heating member is brought into contact with the bottom surface of the substrate with the elevating mechanism as the raised position. When the substrate is transported, heated gas is ejected from the ejection port by using the elevating mechanism as a lowered position.
第10の発明は、第9の発明において、前記接触加熱工程において、前記加熱部材の上面に形成された吸引用開口から吸引力を作用させることを特徴とする。
第11の発明は、第10の発明において、前記噴出用開口と前記吸引用開口を同一の開口により構成し、該開口を切換弁を介して負圧源および加圧源に接続し、前記接触加熱工程において、前記開口と負圧源とを連通させ、前記非接触加熱工程において、前記開口と加圧源とを連通させることを特徴とする。
第12の発明は、第9ないし11のいずれかの発明において、前記基板上に配置されたワークに対し塗布作業を行う際に前記接触加熱工程を実施し、前記基板の搬送時に前記非接触加熱工程を実施することを特徴とする。
第13の発明は、第12の発明において、前記塗布作業の前後で前記非接触加熱工程を実施することを特徴とする。
第14の発明は、第12または13の発明において、前記塗布作業が、アンダーフィル工程であることを特徴とする。
第15の発明は、第14の発明において、前記接触加熱工程および前記非接触加熱工程において、前記基板の底面全体を均等加熱することを特徴とする。基板の底面全体を均等加熱することにより、接続部をより効果的に保護することが可能となる。 A ninth invention is a substrate heating method for heating from below a substrate that is transported in one direction and on which a coating operation is performed on a workpiece that is placed on the workpiece in the middle of the transport, and is described above by a lifting mechanism. A contact heating process in which the flat top surface of the heating member is brought into contact with the bottom surface of the substrate and the substrate is heated, and the bottom surface of the substrate and the top surface of the heating member are separated from each other by an elevating mechanism. And a non-contact heating step of jetting heating gas from the jetting opening.
According to a tenth aspect, in the ninth aspect, in the contact heating step, a suction force is applied from a suction opening formed on an upper surface of the heating member.
According to an eleventh aspect, in the tenth aspect, the ejection opening and the suction opening are configured by the same opening, and the opening is connected to a negative pressure source and a pressure source via a switching valve, and the contact In the heating step, the opening and the negative pressure source are communicated, and in the non-contact heating step, the opening and the pressure source are communicated.
In a twelfth aspect of the invention according to any one of the ninth to eleventh aspects, the contact heating step is performed when a coating operation is performed on the workpiece disposed on the substrate, and the non-contact heating is performed when the substrate is transported. A process is performed.
A thirteenth invention is characterized in that, in the twelfth invention, the non-contact heating step is performed before and after the coating operation.
A fourteenth invention is characterized in that, in the twelfth or thirteenth invention, the coating operation is an underfill process.
According to a fifteenth aspect, in the fourteenth aspect, the entire bottom surface of the substrate is uniformly heated in the contact heating step and the non-contact heating step. By uniformly heating the entire bottom surface of the substrate, the connection portion can be more effectively protected.
本発明の基板加熱装置は、液体材料が塗布される基板を搬送する搬送機構の下方に配設され、前記基板を加熱する基板加熱装置であって、一端が流通口に連通し、他端が負圧源と加圧源との連通を切り換える切換弁に連通する流路と、前記基板と対向する面に前記流通口が穿設され、前記流路が内設される加熱ブロックと、前記加熱ブロックに内設され、前記加熱ブロックを加熱するとともに、前記流路内の気体を加熱するヒーターと、前記加熱ブロックに内設され、前記加熱ブロックの温度を検知する温度センサと、前記温度センサからの信号に基づき前記ヒーターを制御する温度制御部と、液体材料を塗布するとき前記基板を底面より接触して支持する上昇位置、および、前記基板を搬送するとき前記加熱ブロックの前記基板と対向する面が前記基板と離間する下降位置との間で前記加熱ブロックを昇降動させる昇降機構と、を備えることを特徴とする。
好ましくは、前記加熱ブロックは、前記上昇位置にあるときは、前記切換弁により負圧源と連通して前記流通口から気体を吸引し、前記加熱ブロックに底面から支持される前記基板を吸着して、前記加熱ブロックを前記基板に接触させることにより前記基板を加熱し、前記下降位置にあるときは、切換弁により加圧源と連通して、前記加熱ブロックと離間した位置にある前記基板底面に向かって、前記ヒーターにより加熱された流路内の気体を前記流通口から噴出させることにより前記基板を加熱する。ここで、より好ましくは、前記加熱ブロックには、複数の前記流通口が穿設され、かつ、複数の前記流路が内設される。
また、好ましくは、前記流路は、一端が第一の流通口に連通し、他端が負圧源との連通を切り換える第一の弁に連通する第一の流路と、一端が第二の流通口に連通し、他端が加圧源との連通を切り換える第二の弁に連通する第二の流路とに分かれ、前記加熱ブロックは、基板と対向する面に前記第一の流通口および前記第二の流通口が穿設され、前記第一の流路および前記第二の流路が内設される。ここで、より好ましくは、前記加熱ブロックは、前記上昇位置にあるときは、前記第一の弁により負圧源と連通して前記第一の流通口から気体を吸引し、前記加熱ブロックに底面から支持される前記基板を吸着して、前記加熱ブロックを前記基板に接触させることにより前記基板を加熱し、前記下降位置にあるときは、前記第二の弁により加圧源と連通して、前記加熱ブロックと離間した位置にある前記基板底面に向かって、前記ヒーターにより加熱された第二の流路内の気体を前記第二の流通口から噴出させることにより前記基板を加熱する。ここで、さらに好ましくは、前記加熱ブロックには、複数の前記第一の流通口および前記第二の流通口が穿設され、かつ、複数の前記第一の流路および前記第二の流路が内設される。 The substrate heating apparatus of the present invention will be described from another viewpoint as follows.
A substrate heating apparatus according to the present invention is a substrate heating apparatus that is disposed below a transport mechanism that transports a substrate to which a liquid material is applied, and that heats the substrate. A flow path communicating with a switching valve that switches communication between the negative pressure source and the pressurization source, a heating block in which the flow port is formed in a surface facing the substrate, and the flow path is provided; and the heating A heater installed in the block for heating the heating block and heating the gas in the flow path, a temperature sensor installed in the heating block for detecting the temperature of the heating block, and the temperature sensor A temperature control unit that controls the heater based on the signal, a raised position that supports the substrate in contact with the bottom surface when applying a liquid material, and the substrate of the heating block that faces the substrate when the substrate is transported There characterized by and a lifting mechanism for raising and lowering movement of the heated block between a lowered position that apart from the substrate.
Preferably, when the heating block is in the raised position, the switching valve communicates with a negative pressure source to suck gas from the flow port, and adsorbs the substrate supported from the bottom by the heating block. The substrate is heated by bringing the heating block into contact with the substrate. When the substrate is in the lowered position, the substrate bottom surface is in a position separated from the heating block by communicating with a pressurizing source by a switching valve. The substrate is heated by ejecting the gas in the flow path heated by the heater from the flow port. More preferably, the heating block is provided with a plurality of flow ports and a plurality of flow paths.
Preferably, the flow path has one end communicating with the first flow port and the other end communicating with the first valve for switching communication with the negative pressure source, and one end with the second flow path. And the other end is divided into a second flow path that communicates with a second valve that switches communication with the pressurizing source, and the heating block is arranged on the surface facing the substrate. A port and the second flow port are bored, and the first channel and the second channel are internally provided. Here, more preferably, when the heating block is in the raised position, the first valve communicates with a negative pressure source to suck gas from the first circulation port, and the heating block has a bottom surface. Adsorbing the substrate supported from and heating the substrate by bringing the heating block into contact with the substrate; when in the lowered position, the second valve communicates with a pressure source; The substrate is heated by ejecting the gas in the second flow path heated by the heater from the second circulation port toward the bottom surface of the substrate at a position separated from the heating block. More preferably, the heating block has a plurality of the first flow ports and the second flow ports, and a plurality of the first flow channels and the second flow channels. Is installed.
本発明の塗布装置は、上記のいずれかの基板加熱装置と、液体材料を吐出する吐出装置と、基板に対し、前記吐出装置を相対移動させる駆動機構と、塗布装置内に延設され前記基板を搬送する搬送機構と、これらの動作を制御する制御部と、を備えることを特徴とする。ここで、好ましくは、前記搬送機構は複数部分に分かれており、前記搬送機構の複数部分のそれぞれに対して複数の前記基板加熱装置をそれぞれ設ける。 The coating apparatus of the present invention will be described from another viewpoint as follows.
A coating apparatus according to the present invention includes any one of the above-described substrate heating apparatuses, a discharge apparatus that discharges a liquid material, a drive mechanism that moves the discharge apparatus relative to the substrate, and the substrate extending in the coating apparatus. And a control unit that controls these operations. Here, preferably, the transport mechanism is divided into a plurality of parts, and a plurality of the substrate heating devices are provided for each of the plurality of parts of the transport mechanism.
また、塗布作業の間、基板の温度変化を極めて小さくできるので、液体材料の状態が安定し、塗布を安定して行うことができる。
さらに、一つの加熱機構で二つの異なる加熱方式を実施できるので、塗布時および非塗布時(搬送時)のいずれの加熱も一つの加熱機構で対応できる。このため、装置を小型化することが可能である。 According to the present invention, since heating is performed not only at the time of coating but also at the time of conveyance before and after the coating, for example, in the underfill process, the temperature change of the substrate on which the semiconductor chip is placed is extremely small and the connection portion is destroyed. Can be prevented.
Further, since the temperature change of the substrate can be made extremely small during the coating operation, the state of the liquid material is stable and the coating can be performed stably.
Furthermore, since two different heating systems can be implemented with one heating mechanism, both heating during coating and during non-coating (during conveyance) can be handled with one heating mechanism. For this reason, it is possible to reduce the size of the apparatus.
[加熱機構本体]
本発明に係る基板加熱機構105の概略斜視図を図2に示す。また、要部断面図を図3、ブロック線図を図4にそれぞれ示す。
本実施の形態における加熱機構105の主要部分である加熱ブロック11は、ほぼ直方体形状をしており、基板と対向する上面12は基板2の大きさとほぼ同じ広さの面になっている。
上面12には、複数の第一の流通口13および複数の第二の流通口14が一定の間隔で均等に配置されている。ここで、図2に示した流通口13および14の配置は一例に過ぎず、その配置は適宜変更可能であるが、本実施例の形態においては、接続部を保護するという観点から、基板2の底面全体で温度差がないようにするべく均等配置を採用した。
複数ある第一の流通口13は吸引用の開口であり、加熱ブロック11に内設される複数の第一の流路15に連通している。また、複数ある第二の流通口14は噴出用の開口であり、加熱ブロック11に内設される複数の第二の流路16にそれぞれ連通している。複数の第一の流路15は、第一の弁17を介して負圧源19と連通し、複数の第二の流路16は第二の弁18を介して加圧源20と連通する。この第一の弁17および第二の弁18を開閉することで流路(15、16)内の気体を吸い込んだり、流路内へ気体を噴き出したりすることができる。ここで、第一の弁17および第二の弁18は、加熱ブロック11とは別の場所に設置されることが好ましい。また、第一の弁17および第二の弁18は、負圧源19や加圧源20の強さに応じて複数設けてもよい。流路(15、16)には作動気体として空気が流れるがこれに限定されず、例えば、不活性な気体が好ましい場合には窒素などを用いてもよい。 One mode for carrying out the present invention will be described using an example in which an underfill process is performed on a substrate on which a semiconductor chip is arranged.
[Heating mechanism body]
A schematic perspective view of the
The
On the
The plurality of
また、ヒーター21とあわせて、加熱ブロック11内部には温度センサ22が設置されている。そして、ヒーター21および温度センサ22は温度制御部23に接続され、温度制御部23は温度センサ22からの信号に基づき、温度が一定となるようヒーター21を制御する。制御方法としては、特に限定するものではないが、温度制御でよく用いられるPID(比例、積分、微分)制御や、一般的なフィードバック制御、簡便なオン・オフ制御などを用いる。なお、温度センサ22の配置および数は、適宜変更して適用することが可能である。 The
In addition to the
昇降機構24を駆動する装置としては、例えば、圧縮気体によりピストンが駆動するエアシリンダや、モーターとボールねじを組み合わせたものなどを用いることができる。加熱ブロック11は、液体材料4を塗布する際には、上昇位置に移動して基板2を底面より支持することで塗布ステージとしての役割を果たす。一方で、基板搬送時には、基板搬送が円滑に行われるように加熱ブロック11が基板2から離間した下降位置に移動する。加熱気体による基板温度の維持を効率的に行うためには、加熱ブロックの上面12と基板2の底面との距離は離れすぎない方が好ましく、例えば、数mmとする。搬送機構104の詳細については実施例で説明する。 The
As an apparatus for driving the elevating
本発明に係る加熱機構105の加熱態様は、加熱ブロック11の位置により大きく二つに分かれる。
[1]上昇位置における加熱(図5)
加熱ブロック11が上昇位置にあるとき、第一の弁17は加熱ブロック11内の第一の流路15と負圧源19とを連通する。これにより、加熱ブロック11内の第一の流路15ともう一方の端で連通している第一の流通口13から気体が吸い込まれる(符号26の矢印参照)。第一の流通口13の直上直近には基板2が位置しており、第一の流通口13からの吸引作用により、基板2が吸着され、加熱ブロックの上面12と基板2の底面とが密に当接される。このように、基板2の底面は加熱ブロック上面12と接触することになるので、ヒーター21からの熱が加熱ブロック11を介して直接かつ迅速に伝わる。そして、温度制御部23により温度が一定となるようヒーター21の制御を行うことで、基板2の温度を一定に保つことができる。
上記の加熱手法によれば、基板2の底面に加熱ブロックの上面12を当接させるのでヒーター21からの熱を効率よく伝えることができ、かつ基板2の温度を安定して制御することができる。温度を安定して制御することは接続部3の破壊を防ぐだけでなく、液体材料4の状態を安定させ塗布を安定させることにもつながる。また、基板面12にわたって複数開けられた第一の流通口13により均一に吸着できるので、基板2に一様に接触することができ、かつ基板2の平面度を保つことができる。 [Heating mode]
The heating mode of the
[1] Heating in the raised position (FIG. 5)
When the
According to the above heating method, the
加熱ブロック11が下降位置にあるとき、第二の弁18は加熱ブロック11内の第二の流路16と加圧源20とを連通する。そうすると加熱ブロック11内の第二の流路16ともう一方の端で連通している第二の流通口14から気体を噴き出す(27)。第二の流通口14は基板2と離間しているので、気体を基板2の底面に向かって噴き出すことになる。噴き出された気体は加熱ブロック11内でヒーター21により加熱されており、基板2にはこの加熱された気体により熱が伝わる。そして温度制御部23により温度が一定となるようヒーター21の制御を行うことで、基板2の温度を一定に保つことができる。
上記の加熱手法によれば、加熱された気体を離れた場所から噴き出すことで、移動中の基板2にも熱を伝えられるようになる。つまり、移動中の基板2に対しても温度を制御することができるため、アンダーフィル工程内での温度変化を極めて小さくすることができる。また、基板面12にわたって複数開けられた第二の流通口14から加熱された気体を噴き出すので、基板2全体を加熱することができる。 [2] Heating in the lowered position (FIG. 6)
When the
According to the heating method described above, heat can be transferred to the moving
以上の理由から、加熱ブロック11に吸引力を作用させる流通口を設ける構成を採用することが好ましい。 In the above description, the structure in which the bottom surface of the
For the above reason, it is preferable to employ a configuration in which a circulation port for applying a suction force to the
本実施例に係る塗布装置101は、図7に示すように、吐出装置102と駆動機構103と搬送機構104と加熱機構105とこれらを制御する制御部124とを備えている。
吐出装置102は、液体材料4を貯留する貯留容器107(図示せず)と、液体材料4を吐出するためのノズル108(図1参照)を備えている。この吐出装置102が、塗布対象基板2の塗布面にノズル108が対向するようXYZ駆動機構103に取り付けられており、搬送機構104で搬送される塗布対象基板2上へ移動可能である。
搬送機構104は、塗布装置101の幅にわたって設置されており、三つの搬送ユニット(114、115、116)により構成され、それぞれが独立に動作可能となっている。搬送機構104が三つの搬送ユニットにより構成されているので、塗布動作の最中でも搬入、搬出動作を個別に行うことが可能となり、工程処理時間を短縮することができる。本実施例の搬送機構104は、図8に示すように、搬送する基板2の幅に広がった二本のレール状部材109を平行に設置した構造をしており、レール状部材109の上方にローラー110により回転するベルト111が設けられている。ローラー110を回転駆動することによりベルト111が回転し、ベルト111上に載置された基板2が搬送される。二本のレール状部材109の幅は、基板2の大きさに合わせて変更可能となっている。ここで基板2は、図7に矢印で図示するように、左側搬送機構114から塗布装置101内に搬入され、中央搬送機構115を経由し、右側搬送機構116から塗布装置101外へ搬出される。 [Coating equipment]
As shown in FIG. 7, the
The
The
加熱ブロック11は、基板2とほぼ同じ大きさであるため、搬入側や搬出側などの基板2の大きさに満たない空間には加熱ユニットを設置できない場合がある。そこで、本実施例では加熱ユニットよりも小型の補助加熱ユニット(118、119、120)を設ける構成としている。補助加熱ユニットは、昇降動せずに基板2から離間した下降位置で固定されている点、第一の流通口13を設けずに第二の流通口14から加熱された気体を噴き出すのみである点で前述の加熱ユニットとは異なる。補助加熱ユニット(118、119、120)の大きさは、三つの加熱ユニット(121、122、123)の間を埋められる大きさであればよく、適宜変更して配設することができる。本実施例では、搬入部の位置に補助加熱ユニット118を、中央加熱ユニット122と右側加熱ユニット123との間の位置に補助加熱ユニット119を、搬出部の位置に補助加熱ユニット120を設置した。
加熱機構105における設定温度は、基板2のサイズや半導体チップ1の数などに応じて変化するが、概ねセ氏100度から150度の範囲に設定する。その範囲の中で、予備加熱、塗布時の最適温度、温度保持加熱の目的に応じた加熱を行うよう制御してもよい。 The
Since the
The set temperature in the
本実施例に係る塗布装置101の作動を、図9から図12を参照しながら説明する。
塗布装置101の左側には、未塗布の基板2を供給するローダーまたは前工程の装置がある。塗布装置101の右側には、塗布済みの基板2を回収するアンローダーまたは後工程の装置がある。以下では説明の便宜上、加熱ユニットおよび補助加熱ユニットそれぞれをステージと呼ぶ。
動作を開始すると、基板2を塗布装置101内へ搬入する前に搬入口ステージ118および前ステージ121の温度を読み取って(STEP101)、設定温度の範囲内かを判定する(STEP102)。設定温度に達していない場合、再度温度を読み取り、設定温度に達するまで繰り返す。設定温度に達している場合、前ステージ121に基板2が残っているかどうかを判定する(STEP103)。基板2が残っている場合、基板2が除かれるまで待機する。基板2が残っていない場合、搬入口ステージ118および前ステージ121からの気体の噴出を開始する(STEP104)。そして、基板2を前ステージ121位置まで搬送する(STEP105)。基板2が前ステージ121位置に到達すると、前ステージ121からの気体の噴出を止め、前ステージ121が上昇して基板2を支持し、前ステージ121の吸引を開始して基板2を吸着固定する(STEP106)。 [Operation]
The operation of the
On the left side of the
When the operation is started, the temperature of the carry-in
実施例2における加熱ブロック201は、ほぼ直方体形状をしており、基板と対向する上面202は基板2の大きさとほぼ同じ広さの面になっている。上面202には複数の流通口203が、一定の間隔で均等に開けられている。各流通口203は、加熱ブロック201に内設される流路204に連通している。流路204は、加熱ブロック201とは別の場所に設置された切換弁205へ通じており、切換弁205を介して負圧源206および加圧源207に連通している。この切換弁205を切り換えて負圧源206または加圧源207のいずれか一方を流路204と連通することにより、流路204内の気体を吸い込んだり、流路内へ気体を噴き出したりする。負圧源206や加圧源207の圧力の強さに応じて切換弁205を複数設けてもよい。その他のヒーター21、温度センサ22、昇降機構24などは実施例1と同様である。 In the first embodiment, the flow path in the
The
加熱ブロック201が下降位置にあるとき、切換弁205は加熱ブロック201内の流路204と加圧源207とを連通する。そうすると加熱ブロック201内の流路204ともう一方の端で連通している流通口203から気体を吹き出す。流通口203は基板2と離間しているので、気体を基板2の底面に向かって吹き出すことになる。吹き出された気体は加熱ブロック201内でヒーターにより加熱されており、基板2にはこの加熱された気体により熱が伝わる。そして温度制御部208により温度が一定となるようヒーターの制御を行うことで、基板2の温度を一定に保つことができる。
また、本実施例の加熱ブロック201によれば、流路を一系統とすることで弁やそれに通じる配管などを減らすことができ、省スペースを実現できる。 When the
When the
In addition, according to the
2 基板
3 接続部(突起状電極、電極パッド)
4 液状樹脂、液体材料
11 加熱ブロック
12 基板と対向する面(上面)
13 第一の流通口(吸引用開口)
14 第二の流通口(噴出用開口)
15 第一の流路
16 第二の流路
17 第一の弁
18 第二の弁
19 負圧源
20 加圧源
21 ヒーター
22 温度センサ
23 温度制御部
24 昇降機構
25 配管継手
26 吸い込む気体の流れ
27 噴き出す気体の流れ
101 塗布装置
102 吐出装置
103 XYZ駆動機構
104 搬送機構
105 基板加熱機構
106 基板押さえ部材
107 貯留容器
108 ノズル
109 レール状部材
110 ローラー
111 ベルト
112 基板搬送方向
113 駆動方向
114 左側搬送ユニット
115 中央搬送ユニット
116 右側搬送ユニット
118 左側補助加熱ユニット(搬入口ステージ)
119 中央補助加熱ユニット(中間ステージ)
120 右側補助加熱ユニット(搬出口ステージ)
121 左側加熱ユニット(前ステージ)
122 中央加熱ユニット(塗布ステージ)
123 右側加熱ユニット(後ステージ)
124 制御部
201 加熱ブロック
202 基板と対向する面(上面)
203 流通口
204 流路
205 切換弁
206 負圧源
207 加圧源
208 温度制御部
209 気体の流れ 1 Workpiece (semiconductor chip)
2
4 Liquid resin,
13 First distribution port (suction opening)
14 Second distribution port (spout opening)
15
119 Central auxiliary heating unit (intermediate stage)
120 Right side auxiliary heating unit (carry-out stage)
121 Left heating unit (front stage)
122 Central heating unit (coating stage)
123 Right side heating unit (rear stage)
203
Claims (15)
- 一の方向に搬送され、搬送の途中でその上に配置されたワークに対し塗布作業が行われる基板を下方から加熱するための基板加熱装置であって、
前記基板の底面に当接し、基板を加熱する平らな上面、および、該上面に形成され、前記基板の底面に加熱用気体を噴出する噴出用開口を具備する加熱部材と、加熱部材を昇降させる昇降機構と、を備えることを特徴とする基板加熱装置。 A substrate heating apparatus for heating a substrate that is transported in one direction and on which a coating operation is performed with respect to a workpiece disposed thereon in the middle of transportation,
A heating member that is in contact with the bottom surface of the substrate and that heats the substrate, and a heating member that is formed on the top surface and that has an ejection opening that ejects a heating gas to the bottom surface of the substrate, and the heating member is raised and lowered And a lifting mechanism. - 前記加熱部材は、その上面に前記基板の底面に吸引力を作用させる吸引用開口を備え、
前記昇降機構の上昇位置において、前記吸引用開口から吸引力を作用させ、前記加熱部材の上面を前記基板の底面に接触させて前記基板を加熱し、前記昇降機構の下降位置において、前記噴出用開口から加熱された気体を噴出させて前記基板を加熱することを特徴とする請求項1記載の基板加熱装置。 The heating member includes a suction opening on its upper surface for applying a suction force to the bottom surface of the substrate,
At the raised position of the lifting mechanism, a suction force is applied from the suction opening, the upper surface of the heating member is brought into contact with the bottom surface of the substrate to heat the substrate, and at the lowered position of the lifting mechanism, the ejection The substrate heating apparatus according to claim 1, wherein the substrate is heated by jetting heated gas from the opening. - 前記噴出用開口と前記吸引用開口は同一の開口により構成され、該開口は切換弁を介して負圧源および加圧源に接続されることを特徴とする請求項2記載の基板加熱装置。 3. The substrate heating apparatus according to claim 2, wherein the ejection opening and the suction opening are constituted by the same opening, and the opening is connected to a negative pressure source and a pressurization source through a switching valve.
- 前記開口が複数あることを特徴とする請求項1ないし3のいずれか一項に記載の基板加熱装置。 4. The substrate heating apparatus according to claim 1, wherein there are a plurality of the openings.
- 複数の加熱部材が、前記基板の搬送方向に連続して配設されることを特徴とする請求項1ないし4のいずれか一項に記載の基板加熱装置。 5. The substrate heating apparatus according to claim 1, wherein a plurality of heating members are continuously arranged in a transport direction of the substrate.
- 前記加熱部材が、長さが異なる複数の種類の加熱ブロックにより構成されることを特徴とする請求項5記載の基板加熱装置。 6. The substrate heating apparatus according to claim 5, wherein the heating member comprises a plurality of types of heating blocks having different lengths.
- 請求項1ないし6のいずれか一項に記載の基板加熱装置と、前記液体材料を吐出する吐出装置と、前記基板に対し、前記吐出装置を相対移動させる駆動機構と、前記基板を一の方向に搬送する搬送機構と、これらの動作を制御する制御部と、を備える液体材料塗布装置。 7. The substrate heating device according to claim 1, a discharge device that discharges the liquid material, a drive mechanism that moves the discharge device relative to the substrate, and the substrate in one direction. A liquid material coating apparatus comprising: a transport mechanism that transports the liquid to the surface; and a controller that controls these operations.
- 前記制御部が、基板上に配置されたワークに対し塗布作業を行う際には前記昇降機構を上昇位置として加熱部材の上面を基板の底面に接触させ、基板の搬送時には前記昇降機構を下降位置として前記噴出口から加熱された気体を噴出することを特徴とする請求項7記載の液体材料塗布装置。 When the controller performs a coating operation on a workpiece placed on the substrate, the lifting mechanism is set to the raised position to bring the upper surface of the heating member into contact with the bottom surface of the substrate. The liquid material coating apparatus according to claim 7, wherein the heated gas is ejected from the ejection port.
- 一の方向に搬送され、搬送の途中でその上に配置されたワークに対し塗布作業が行われる基板を下方から加熱するための基板加熱方法であって、
昇降機構により前記基板の底面に加熱部材の平らな上面を当接させ、基板を加熱する接触加熱工程と、
昇降機構により前記基板の底面と加熱部材の前記上面を離間させ、前記加熱部材の上面に形成された噴出用開口から加熱用気体を噴出する非接触加熱工程と、を備えることを特徴とする基板加熱方法。 A substrate heating method for heating a substrate on which a coating operation is performed with respect to a workpiece that is conveyed in one direction and is arranged on the way in the middle of conveyance,
A contact heating step of heating the substrate by bringing the flat top surface of the heating member into contact with the bottom surface of the substrate by a lifting mechanism;
A non-contact heating step in which a bottom surface of the substrate and the upper surface of the heating member are separated by an elevating mechanism, and a heating gas is ejected from an ejection opening formed on the upper surface of the heating member. Heating method. - 前記接触加熱工程において、前記加熱部材の上面に形成された吸引用開口から吸引力を作用させることを特徴とする請求項9記載の基板加熱方法。 10. The substrate heating method according to claim 9, wherein in the contact heating step, a suction force is applied from a suction opening formed on an upper surface of the heating member.
- 前記噴出用開口と前記吸引用開口を同一の開口により構成し、該開口を切換弁を介して負圧源および加圧源に接続し、
前記接触加熱工程において、前記開口と負圧源とを連通させ、
前記非接触加熱工程において、前記開口と加圧源とを連通させることを特徴とする請求項10記載の基板加熱方法。 The ejection opening and the suction opening are constituted by the same opening, and the opening is connected to a negative pressure source and a pressurization source through a switching valve,
In the contact heating step, the opening and the negative pressure source are communicated,
The substrate heating method according to claim 10, wherein in the non-contact heating step, the opening and the pressure source are communicated. - 前記基板上に配置されたワークに対し塗布作業を行う際に前記接触加熱工程を実施し、前記基板の搬送時に前記非接触加熱工程を実施することを特徴とする請求項9ないし11のいずれか一項に記載の基板加熱方法。 12. The contact heating process is performed when a coating operation is performed on a workpiece placed on the substrate, and the non-contact heating process is performed when the substrate is transported. The substrate heating method according to one item.
- 前記塗布作業の前後で前記非接触加熱工程を実施することを特徴とする請求項12記載の基板加熱方法。 The substrate heating method according to claim 12, wherein the non-contact heating step is performed before and after the coating operation.
- 前記塗布作業が、アンダーフィル工程であることを特徴とする請求項12または13記載の基板加熱方法。 14. The substrate heating method according to claim 12, wherein the coating operation is an underfill process.
- 前記接触加熱工程および前記非接触加熱工程において、前記基板の底面全体を均等加熱することを特徴とする請求項14記載の基板加熱方法。 15. The substrate heating method according to claim 14, wherein the entire bottom surface of the substrate is uniformly heated in the contact heating step and the non-contact heating step.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009801251004A CN102077333B (en) | 2008-07-04 | 2009-07-02 | Substrate heating apparatus, liquid material applying apparatus provided with substrate heating apparatus, and substrate heating method |
HK11108358.6A HK1154118A1 (en) | 2008-07-04 | 2011-08-10 | Substrate heating apparatus, liquid material applying apparatus provided with substrate heating apparatus, and substrate heating method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008-176071 | 2008-07-04 | ||
JP2008176071A JP5465846B2 (en) | 2008-07-04 | 2008-07-04 | Substrate heating apparatus, liquid material coating apparatus including the same, and substrate heating method |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010001608A1 true WO2010001608A1 (en) | 2010-01-07 |
Family
ID=41465715
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2009/003064 WO2010001608A1 (en) | 2008-07-04 | 2009-07-02 | Substrate heating apparatus, liquid material applying apparatus provided with substrate heating apparatus, and substrate heating method |
Country Status (6)
Country | Link |
---|---|
JP (1) | JP5465846B2 (en) |
KR (1) | KR101568238B1 (en) |
CN (1) | CN102077333B (en) |
HK (1) | HK1154118A1 (en) |
TW (1) | TWI491451B (en) |
WO (1) | WO2010001608A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023082170A1 (en) * | 2021-11-12 | 2023-05-19 | Illinois Tool Works Inc. | Multi-pattern tooling plate |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9029740B2 (en) * | 2013-01-15 | 2015-05-12 | Nordson Corporation | Air impingement heater |
CN109789435B (en) | 2016-10-07 | 2022-02-22 | 武藏工业株式会社 | Liquid material discharge device with temperature control device, and coating device and coating method therefor |
CN116504686B (en) * | 2023-06-28 | 2023-10-20 | 北京中科科美科技股份有限公司 | Semiconductor heating plate based on liquid uniform temperature control |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11224889A (en) * | 1998-02-06 | 1999-08-17 | Matsushita Electric Ind Co Ltd | Heating block for eutectic bonding electronic component |
JP2001250835A (en) * | 2000-03-07 | 2001-09-14 | Matsushita Electric Ind Co Ltd | Device for heating flat work for device for mounting electronic parts |
JP2006314861A (en) * | 2005-05-10 | 2006-11-24 | Matsushita Electric Ind Co Ltd | Apparatus and method for heating substrate and coater for liquid substance |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3399367B2 (en) | 1998-06-26 | 2003-04-21 | 松下電器産業株式会社 | Work thermocompression bonding equipment |
JP3223283B2 (en) * | 1999-09-14 | 2001-10-29 | カシオ計算機株式会社 | Method for manufacturing semiconductor device |
JP3935303B2 (en) | 2000-03-17 | 2007-06-20 | 東京エレクトロン株式会社 | Heat treatment device |
-
2008
- 2008-07-04 JP JP2008176071A patent/JP5465846B2/en active Active
-
2009
- 2009-07-02 WO PCT/JP2009/003064 patent/WO2010001608A1/en active Application Filing
- 2009-07-02 CN CN2009801251004A patent/CN102077333B/en active Active
- 2009-07-02 KR KR1020117002267A patent/KR101568238B1/en active IP Right Grant
- 2009-07-03 TW TW098122529A patent/TWI491451B/en active
-
2011
- 2011-08-10 HK HK11108358.6A patent/HK1154118A1/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11224889A (en) * | 1998-02-06 | 1999-08-17 | Matsushita Electric Ind Co Ltd | Heating block for eutectic bonding electronic component |
JP2001250835A (en) * | 2000-03-07 | 2001-09-14 | Matsushita Electric Ind Co Ltd | Device for heating flat work for device for mounting electronic parts |
JP2006314861A (en) * | 2005-05-10 | 2006-11-24 | Matsushita Electric Ind Co Ltd | Apparatus and method for heating substrate and coater for liquid substance |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023082170A1 (en) * | 2021-11-12 | 2023-05-19 | Illinois Tool Works Inc. | Multi-pattern tooling plate |
Also Published As
Publication number | Publication date |
---|---|
TW201006568A (en) | 2010-02-16 |
CN102077333B (en) | 2013-12-11 |
HK1154118A1 (en) | 2012-04-20 |
JP2010016252A (en) | 2010-01-21 |
CN102077333A (en) | 2011-05-25 |
KR20110039300A (en) | 2011-04-15 |
KR101568238B1 (en) | 2015-11-20 |
TWI491451B (en) | 2015-07-11 |
JP5465846B2 (en) | 2014-04-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4571525B2 (en) | Substrate processing apparatus and substrate processing method | |
JP4429943B2 (en) | Substrate processing apparatus and substrate processing method | |
TWI460020B (en) | Smearing and smearing method | |
JP5465846B2 (en) | Substrate heating apparatus, liquid material coating apparatus including the same, and substrate heating method | |
JP5314607B2 (en) | Joining apparatus, joining method, program, and computer storage medium | |
WO2005010979A1 (en) | Laminating method and laminating device | |
KR20200033335A (en) | Semiconductor manufacturing equipment | |
JP2011056335A (en) | Apparatus for pre-drying and method of pre-drying | |
JP2014231185A (en) | Resin molding apparatus and resin molding method | |
JP5556023B2 (en) | Suction head, work transfer device, work transfer method, semiconductor chip mounting apparatus, and semiconductor chip mounting method | |
KR101619460B1 (en) | Apparatus for Manufacturing Package On Package | |
JP2023062616A (en) | Resin sealing device and resin sealing method | |
JP5221508B2 (en) | Substrate processing equipment | |
TW202249128A (en) | Resin sealing device and resin sealing method | |
TWI423359B (en) | Semiconductor mounting device and semiconductor mounting method | |
JP7335136B2 (en) | Resin protective member forming device | |
KR101176707B1 (en) | Apparatus and method for application and solidification of a chemical liquid, and recording medium | |
TWI829565B (en) | Resin sealing apparatus | |
KR20190124149A (en) | Method and apparatus for transporting adhesive tape | |
KR200208765Y1 (en) | Apparatus for checking vacuum pressure of heater block for encapsulation dispenser | |
WO2022172592A1 (en) | Transport mechanism, resin molding device, and method for producing resin molded article | |
TWI783882B (en) | Compression molding device and compression molding method | |
JP3890042B2 (en) | Component joining apparatus and method, and component mounting apparatus | |
KR102185034B1 (en) | Module for aligning bonding tool and die bonding apparatus having the same | |
JP6778676B2 (en) | Bonding tool cooling device and bonding device equipped with this and bonding tool cooling method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200980125100.4 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09773186 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 20117002267 Country of ref document: KR Kind code of ref document: A |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 09773186 Country of ref document: EP Kind code of ref document: A1 |